ES8600199A1 - Novel esters of vinylcyclopropanecarboxylic acid derivatives, a process for their preparation, and insecticide containing them - Google Patents
Novel esters of vinylcyclopropanecarboxylic acid derivatives, a process for their preparation, and insecticide containing themInfo
- Publication number
- ES8600199A1 ES8600199A1 ES528023A ES528023A ES8600199A1 ES 8600199 A1 ES8600199 A1 ES 8600199A1 ES 528023 A ES528023 A ES 528023A ES 528023 A ES528023 A ES 528023A ES 8600199 A1 ES8600199 A1 ES 8600199A1
- Authority
- ES
- Spain
- Prior art keywords
- preparation
- acid derivatives
- vinylcyclopropanecarboxylic acid
- insecticide containing
- novel esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PDOBSLHNWIVQJX-UHFFFAOYSA-N 1-ethenylcyclopropane-1-carboxylic acid Chemical class OC(=O)C1(C=C)CC1 PDOBSLHNWIVQJX-UHFFFAOYSA-N 0.000 title abstract 2
- 150000002148 esters Chemical class 0.000 title abstract 2
- 239000002917 insecticide Substances 0.000 title abstract 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 abstract 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 230000000895 acaricidal effect Effects 0.000 abstract 1
- 239000000642 acaricide Substances 0.000 abstract 1
- 239000013543 active substance Substances 0.000 abstract 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 235000000484 citronellol Nutrition 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C61/16—Unsaturated compounds
- C07C61/40—Unsaturated compounds containing halogen
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a process for the preparation of esters, some of which are novel, of vinylcyclopropanecarboxylic acid derivatives of the formula < IMAGE > in which X represents a halogen, preferably chlorine or bromine, and R1 represents a geraniol- and citronellol-derived radical, and to insecticides and acaricides containing these compounds as active substances.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES528023A ES528023A0 (en) | 1983-12-13 | 1983-12-13 | PROCEDURE FOR THE PREPARATION OF NEW ESTERS OF VINYL CYCLOPROPANCARBOXYLIC ACID IN ITS RACEMIC OR OPTICALLY ACTIVE FORM, WITH PESTICIDE ACTIVITY. |
AR298930A AR240795A1 (en) | 1983-12-13 | 1984-12-12 | NEW ESTERS OF A DERIVATIVE OF VINYL CYCLOPROPANCARBOXYLIC ACID IN ITS RACEMIC OR OPTICALLY ACTIVE FORM AND PREPARATION PROCEDURE. |
BR8406360A BR8406360A (en) | 1983-12-13 | 1984-12-12 | PROCESS OF PREPARATION OF NEW ESTERS OF DERIVATIVES OF VINYLCYCLOPROPANOCABOXYLIC ACID IN ITS OTICALLY ACTIVE RACEMIC FORM |
FR8419008A FR2556342B1 (en) | 1983-12-13 | 1984-12-12 | NOVEL ESTERS OF A VINYLCYCLOPROPANECARBOXYLIC ACID DERIVATIVE IN RACEMIC OR OPTICALLY ACTIVE FORM, PROCESS FOR PREPARING SUCH NEW ESTERS, USE OF SUCH ESTERS FOR CONTROLLING INSECTS OR MITES, AND COMPOSITION IN PARTICULAR FOR CONTROLLING OR ACTING THEM CONTAINING SUCH ESTERS |
DE19843445504 DE3445504A1 (en) | 1983-12-13 | 1984-12-13 | Novel esters of vinylcyclopropanecarboxylic acid derivatives, a process for their preparation, and insecticide containing them |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES528023A ES528023A0 (en) | 1983-12-13 | 1983-12-13 | PROCEDURE FOR THE PREPARATION OF NEW ESTERS OF VINYL CYCLOPROPANCARBOXYLIC ACID IN ITS RACEMIC OR OPTICALLY ACTIVE FORM, WITH PESTICIDE ACTIVITY. |
Publications (2)
Publication Number | Publication Date |
---|---|
ES8600199A1 true ES8600199A1 (en) | 1985-10-01 |
ES528023A0 ES528023A0 (en) | 1985-10-01 |
Family
ID=8486588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES528023A Granted ES528023A0 (en) | 1983-12-13 | 1983-12-13 | PROCEDURE FOR THE PREPARATION OF NEW ESTERS OF VINYL CYCLOPROPANCARBOXYLIC ACID IN ITS RACEMIC OR OPTICALLY ACTIVE FORM, WITH PESTICIDE ACTIVITY. |
Country Status (5)
Country | Link |
---|---|
AR (1) | AR240795A1 (en) |
BR (1) | BR8406360A (en) |
DE (1) | DE3445504A1 (en) |
ES (1) | ES528023A0 (en) |
FR (1) | FR2556342B1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0494146B1 (en) * | 1990-07-27 | 1995-10-25 | CHINOIN Gyògyszer és Vegyészeti Termékek Gyára RT. | Process for the preparation of optically active or racemic cyclopropane-carboxylic-acid chlorides |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3285950A (en) * | 1963-10-02 | 1966-11-15 | Hoffmann La Roche | Unsaturated esters of chrysanthemum monocarboxylic acid |
JPS4875879A (en) * | 1972-01-17 | 1973-10-12 | ||
JPS527427A (en) * | 1975-07-08 | 1977-01-20 | Sumitomo Chem Co Ltd | Insecticide and tickicide composition comprising a cyclopropane carbox ylic acid ester and a process for its preparation |
JPS5473758A (en) | 1977-10-27 | 1979-06-13 | Sumitomo Chem Co Ltd | Asymmetric synthesis of chrysanthemumic acid derivative ester |
DE2928406A1 (en) * | 1979-07-13 | 1981-01-29 | Bayer Ag | NEW MENTHYLESTERS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE FOR ENANTIOMER SEPARATION OF CHIRAL CARBONIC ACIDS |
DE3127752A1 (en) * | 1981-07-14 | 1983-02-03 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING PERMETHRINSAEUREMENTHYLESTER |
-
1983
- 1983-12-13 ES ES528023A patent/ES528023A0/en active Granted
-
1984
- 1984-12-12 AR AR298930A patent/AR240795A1/en active
- 1984-12-12 FR FR8419008A patent/FR2556342B1/en not_active Expired
- 1984-12-12 BR BR8406360A patent/BR8406360A/en unknown
- 1984-12-13 DE DE19843445504 patent/DE3445504A1/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
AR240795A1 (en) | 1991-02-28 |
AR240795A2 (en) | 1991-02-28 |
FR2556342B1 (en) | 1988-11-25 |
DE3445504A1 (en) | 1985-06-20 |
FR2556342A1 (en) | 1985-06-14 |
ES528023A0 (en) | 1985-10-01 |
BR8406360A (en) | 1985-10-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | Patent lapsed |
Effective date: 19960507 |