ES468951A1 - Oxidation of butane - Google Patents
Oxidation of butaneInfo
- Publication number
- ES468951A1 ES468951A1 ES468951A ES468951A ES468951A1 ES 468951 A1 ES468951 A1 ES 468951A1 ES 468951 A ES468951 A ES 468951A ES 468951 A ES468951 A ES 468951A ES 468951 A1 ES468951 A1 ES 468951A1
- Authority
- ES
- Spain
- Prior art keywords
- butane
- oxidation
- bromine
- cobalt
- initiate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 title abstract 3
- 239000001273 butane Substances 0.000 title abstract 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 title 1
- 238000007254 oxidation reaction Methods 0.000 title 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Process for oxidizing butane to acetic acid, characterized in that it comprises contacting a sufficient concentration of a gas containing oxygen with normal butane, in the presence of a catalyst consisting essentially of bromine and cobalt, to initiate a self-supporting exothermic reaction. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US78873177A | 1977-04-19 | 1977-04-19 | |
US05/788,984 US4111986A (en) | 1977-04-19 | 1977-04-19 | Butane oxidation to acetic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
ES468951A1 true ES468951A1 (en) | 1979-09-16 |
Family
ID=27120833
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES468951A Expired ES468951A1 (en) | 1977-04-19 | 1978-04-19 | Oxidation of butane |
Country Status (9)
Country | Link |
---|---|
JP (1) | JPS53149916A (en) |
BR (1) | BR7802374A (en) |
DD (1) | DD137349A5 (en) |
DE (1) | DE2814807A1 (en) |
ES (1) | ES468951A1 (en) |
FR (1) | FR2387934A1 (en) |
GB (1) | GB1584524A (en) |
IT (1) | IT1186795B (en) |
NL (1) | NL189190C (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9175407B2 (en) | 2012-07-26 | 2015-11-03 | Liquid Light, Inc. | Integrated process for producing carboxylic acids from carbon dioxide |
US10329676B2 (en) | 2012-07-26 | 2019-06-25 | Avantium Knowledge Centre B.V. | Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode |
US8858777B2 (en) | 2012-07-26 | 2014-10-14 | Liquid Light, Inc. | Process and high surface area electrodes for the electrochemical reduction of carbon dioxide |
US8444844B1 (en) | 2012-07-26 | 2013-05-21 | Liquid Light, Inc. | Electrochemical co-production of a glycol and an alkene employing recycled halide |
US8641885B2 (en) | 2012-07-26 | 2014-02-04 | Liquid Light, Inc. | Multiphase electrochemical reduction of CO2 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1219242A (en) * | 1957-11-08 | 1960-05-16 | Ici Ltd | Improvements in the manufacture of organic compounds containing oxygen, in particular carboxylic acids |
US3293292A (en) * | 1962-12-07 | 1966-12-20 | Union Oil Co | Butane oxidation |
US3715388A (en) * | 1971-03-01 | 1973-02-06 | Halcon International Inc | Process for preparing glycol esters from ethylene and propylene |
-
1978
- 1978-04-05 DE DE19782814807 patent/DE2814807A1/en active Granted
- 1978-04-17 BR BR787802374A patent/BR7802374A/en unknown
- 1978-04-17 DD DD78204836A patent/DD137349A5/en unknown
- 1978-04-17 NL NLAANVRAGE7804058,A patent/NL189190C/en not_active IP Right Cessation
- 1978-04-17 IT IT48936/78A patent/IT1186795B/en active
- 1978-04-19 ES ES468951A patent/ES468951A1/en not_active Expired
- 1978-04-19 JP JP4545278A patent/JPS53149916A/en active Granted
- 1978-04-19 GB GB15494/78A patent/GB1584524A/en not_active Expired
- 1978-04-19 FR FR7811575A patent/FR2387934A1/en active Granted
Also Published As
Publication number | Publication date |
---|---|
DE2814807A1 (en) | 1978-10-26 |
JPS53149916A (en) | 1978-12-27 |
GB1584524A (en) | 1981-02-11 |
IT1186795B (en) | 1987-12-16 |
DE2814807C2 (en) | 1987-07-09 |
DD137349A5 (en) | 1979-08-29 |
NL189190B (en) | |
IT7848936A0 (en) | 1978-04-17 |
JPS6230176B2 (en) | 1987-07-01 |
NL7804058A (en) | 1978-10-23 |
NL189190C (en) | 1993-02-01 |
BR7802374A (en) | 1979-02-13 |
FR2387934A1 (en) | 1978-11-17 |
FR2387934B1 (en) | 1981-07-24 |
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