ES417018A1 - Phosphorus derivatives of triazolin-5-ones and thiones - Google Patents
Phosphorus derivatives of triazolin-5-ones and thionesInfo
- Publication number
- ES417018A1 ES417018A1 ES417018A ES417018A ES417018A1 ES 417018 A1 ES417018 A1 ES 417018A1 ES 417018 A ES417018 A ES 417018A ES 417018 A ES417018 A ES 417018A ES 417018 A1 ES417018 A1 ES 417018A1
- Authority
- ES
- Spain
- Prior art keywords
- alkyl
- see formula
- formula
- cycloalkyl
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 241001061127 Thione Species 0.000 title 1
- 150000003017 phosphorus Chemical class 0.000 title 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 3
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 abstract 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 1
- UOXJUEWDFZNDRJ-UHFFFAOYSA-N 4,5-dihydro-1H-triazol-5-ylmethanol Chemical compound OCC1NN=NC1 UOXJUEWDFZNDRJ-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 125000003418 alkyl amino alkoxy group Chemical group 0.000 abstract 1
- 125000003282 alkyl amino group Chemical group 0.000 abstract 1
- 125000004775 chlorodifluoromethyl group Chemical group FC(F)(Cl)* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
- C07D249/10—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D249/12—Oxygen or sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having three nitrogen atoms as the only ring hetero atoms
- C07F9/6518—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
- C10M2223/065—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
A process for the preparation of a Δ 2-1,2,4-triazolin-l or 4-yl-methylphosphorous compound characterized by the formula I: **(See formula)** where R6 is R4 or ( (see formula); R8 is R5 or (see formula) where only one of the groups R6 and R8 is a group (see formula); R7 is R3 and includes C1-C6 fluororalkyl or chloro difluoromethyl groups when R8 is R5; X is oxygen; Y and Z are independently oxygen or sulfur and Z is oxygen when R8 is R5; R1 is C1-C4 alkyl, C1-C4 alkylamino, or C1-C4 alkoxy; or R2 is C1-C4 alkyl, C1-C4 alkylamino alkoxy or phenyl; R3 is C1-C6 alkyl or C3-C8 cycloalkyl, including the C3-C4 alkenyl group when R6 is R4; R4 is C1-C6 alkyl, alkenyl or C3-C8 cycloalkyl; R5 is C1-C6 alkyl, C3-C8 cycloalkyl or phenyl, optionally monosubstituted with halogen or methyl; whose procedure consists of reacting a triazoline compound of formula II: **(See formula)** where R4, R5, R7 and Z are as defined above and n is 0 or 1, with only one being 1; with formaldehyde to produce 1-4-hydroxymethyltriazoline; 1- or 4-hydroxymethyltriazoline is reacted with an appropriately substituted halogenated phosphorous derivative in the presence of a base. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US27324772A | 1972-07-19 | 1972-07-19 | |
| US27619872A | 1972-07-19 | 1972-07-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES417018A1 true ES417018A1 (en) | 1976-06-01 |
Family
ID=26956040
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES417018A Expired ES417018A1 (en) | 1972-07-19 | 1973-07-17 | Phosphorus derivatives of triazolin-5-ones and thiones |
| ES442716A Expired ES442716A1 (en) | 1972-07-19 | 1975-11-17 | Phosphorus derivatives of triazolin-5-ones and thiones |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES442716A Expired ES442716A1 (en) | 1972-07-19 | 1975-11-17 | Phosphorus derivatives of triazolin-5-ones and thiones |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS4942835A (en) |
| AR (1) | AR205693A1 (en) |
| DE (1) | DE2336827A1 (en) |
| ES (2) | ES417018A1 (en) |
| FR (1) | FR2200276B1 (en) |
| GB (1) | GB1421231A (en) |
| IL (1) | IL42712A0 (en) |
| IT (1) | IT989932B (en) |
| NL (1) | NL7309833A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3003977A1 (en) * | 1980-02-04 | 1981-08-13 | Basf Ag, 6700 Ludwigshafen | HETEROCYCLIC PHOSPHORSAEUR DERIVATIVES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE FOR CONTROLLING PESTIES |
| US5310724A (en) * | 1990-02-09 | 1994-05-10 | Fmc Corporation | Herbicidal substituted phenyl-1,2,4-triazol-5(1H)-thiones |
| DE19504627A1 (en) * | 1995-02-13 | 1996-08-14 | Bayer Ag | Process and new intermediates for the production of triazolinones |
| DE19732033A1 (en) * | 1997-07-25 | 1999-01-28 | Bayer Ag | Triazolinethione-phosphoric acid derivatives |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1670745A1 (en) * | 1966-08-30 | 1970-12-23 | Bayer Ag | Process for the production of phosphorus, phosphonic or thiophosphorus (phosphonic) acid esters |
-
1973
- 1973-01-01 AR AR249165A patent/AR205693A1/en active
- 1973-07-03 GB GB3174673A patent/GB1421231A/en not_active Expired
- 1973-07-10 IL IL42712A patent/IL42712A0/en unknown
- 1973-07-13 NL NL7309833A patent/NL7309833A/xx not_active Application Discontinuation
- 1973-07-17 ES ES417018A patent/ES417018A1/en not_active Expired
- 1973-07-18 JP JP48082424A patent/JPS4942835A/ja active Pending
- 1973-07-19 DE DE19732336827 patent/DE2336827A1/en active Pending
- 1973-07-19 IT IT51541/73A patent/IT989932B/en active
- 1973-07-19 FR FR7326532A patent/FR2200276B1/fr not_active Expired
-
1975
- 1975-11-17 ES ES442716A patent/ES442716A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2336827A1 (en) | 1974-01-31 |
| IL42712A0 (en) | 1973-10-25 |
| AR205693A1 (en) | 1976-05-31 |
| ES442716A1 (en) | 1977-12-16 |
| NL7309833A (en) | 1974-01-22 |
| FR2200276B1 (en) | 1976-05-07 |
| GB1421231A (en) | 1976-01-14 |
| IT989932B (en) | 1975-06-10 |
| AU5784273A (en) | 1975-01-09 |
| FR2200276A1 (en) | 1974-04-19 |
| JPS4942835A (en) | 1974-04-22 |
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