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ES358737A1 - Procedure for preparing bis-estilben compounds. (Machine-translation by Google Translate, not legally binding) - Google Patents

Procedure for preparing bis-estilben compounds. (Machine-translation by Google Translate, not legally binding)

Info

Publication number
ES358737A1
ES358737A1 ES358737A ES358737A ES358737A1 ES 358737 A1 ES358737 A1 ES 358737A1 ES 358737 A ES358737 A ES 358737A ES 358737 A ES358737 A ES 358737A ES 358737 A1 ES358737 A1 ES 358737A1
Authority
ES
Spain
Prior art keywords
group
radical
compounds
optionally
function
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES358737A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
BASF Schweiz AG
Original Assignee
Ciba Geigy AG
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG, Ciba AG filed Critical Ciba Geigy AG
Publication of ES358737A1 publication Critical patent/ES358737A1/en
Expired legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • C07D295/182—Radicals derived from carboxylic acids
    • C07D295/192—Radicals derived from carboxylic acids from aromatic carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/324—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a phosphorus atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/2635—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions involving a phosphorus compound, e.g. Wittig synthesis
    • C—CHEMISTRY; METALLURGY
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/32—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by introduction of halogenated alkyl groups into ring compounds
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/24—Halogenated aromatic hydrocarbons with unsaturated side chains
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/29—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton of non-condensed six-membered aromatic rings
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/39—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing halogen atoms bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
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    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/63—Esters of sulfonic acids
    • C07C309/72—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/73—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings
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    • C07C309/78—Halides of sulfonic acids
    • C07C309/86—Halides of sulfonic acids having halosulfonyl groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
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    • C07C309/78—Halides of sulfonic acids
    • C07C309/86—Halides of sulfonic acids having halosulfonyl groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/87—Halides of sulfonic acids having halosulfonyl groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton
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    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/15—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C311/16—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to hydrogen atoms or to an acyclic carbon atom
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    • C07C311/15—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C311/16—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to hydrogen atoms or to an acyclic carbon atom
    • C07C311/17—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to hydrogen atoms or to an acyclic carbon atom to an acyclic carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
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    • C07C313/00—Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C313/02—Sulfinic acids; Derivatives thereof
    • C07C313/04—Sulfinic acids; Esters thereof
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    • C07—ORGANIC CHEMISTRY
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    • C07C317/00—Sulfones; Sulfoxides
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/44—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reduction and hydrolysis of nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/546—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings polycyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
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    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/55—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/30—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings
    • C07C57/42—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings having unsaturation outside the rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/64—Acyl halides
    • C07C57/72—Acyl halides containing six-membered aromatic rings
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/66—Polycyclic acids with unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
    • C07D295/26—Sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32—Esters thereof
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
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    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32—Esters thereof
    • C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/3241—Esters of arylalkanephosphinic acids
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    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041—Optical brightening agents, organic pigments
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    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
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    • C09B23/148—Stilbene dyes containing the moiety -C6H5-CH=CH-C6H5
    • D—TEXTILES; PAPER
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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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  • Paper (AREA)

Abstract

Procedure for preparing bis-stilbene compounds of the formula R1-CH = CH - X-CH = CH - R2, in which X signifies a diphenyl radical linked in position 4 and 4'to the groups = CH-; R1 and R2, independently of one another, signify a monocyclic benzene radical, a diphenyl radical or a naphthalene radical; and at least one of the cyclical systems R1, R2 and X contain a sulfonic acid group, optionally degraded in function, a sulfonic group, a carboxylic acid group, optionally degraded in function, a nitrile group, a hydroxyl group, a mercapto group or a methyl group; characterized by reacting, in the 1: 2 molecular ratio, compounds of the formula Z1 - X - Z1 with compounds of the formula R1 - Z2 or Z2 - R2 where X signifies a diphenyl radical, linked at the 4 and 4'position to Z1; R1 and R2 signify a monocyclic benzene radical, a diphenyl radical or a naphthalene radical; and one of the symbols Z1 and Z2 means one group O = CH-, while the other means one of the groupings of the formulas **(See formula)** in which R represents an alkyl radical (optionally further substituted), an aryl radical, a cycloalkyl radical or an aralkyl radical and one of at least one of the cyclic systems present in the starting materials contains a sulfonic acid group (optionally degraded in the function), a sulfonic group, a carboxylic acid group (optionally, degraded in function), a nitrile group, a hydroxy group, a mercapto group or a methyl group, and eventually, other transformations still to be carried out on these substituents. (Machine-translation by Google Translate, not legally binding)
ES358737A 1967-10-03 1968-10-02 Procedure for preparing bis-estilben compounds. (Machine-translation by Google Translate, not legally binding) Expired ES358737A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH1380667A CH513785A (en) 1967-10-03 1967-10-03 Process for the preparation of new bis-stilbene compounds
CH1251168A CH554821A (en) 1967-10-03 1968-08-20 Prepg. fluorescent bis-stilbene cpds. - for use as optical brighteners for organic materials

Publications (1)

Publication Number Publication Date
ES358737A1 true ES358737A1 (en) 1970-10-16

Family

ID=4395511

Family Applications (2)

Application Number Title Priority Date Filing Date
ES358737A Expired ES358737A1 (en) 1967-10-03 1968-10-02 Procedure for preparing bis-estilben compounds. (Machine-translation by Google Translate, not legally binding)
ES378656A Expired ES378656A1 (en) 1967-10-03 1970-04-16 Procedure for the optical clarification of organic materials. (Machine-translation by Google Translate, not legally binding)

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES378656A Expired ES378656A1 (en) 1967-10-03 1970-04-16 Procedure for the optical clarification of organic materials. (Machine-translation by Google Translate, not legally binding)

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JP (1) JPS54929B1 (en)
AT (2) AT299171B (en)
BE (1) BE721754A (en)
BR (1) BR6802828D0 (en)
CH (4) CH513785A (en)
CS (2) CS174800B2 (en)
DE (1) DE1793482C3 (en)
DK (1) DK139845B (en)
ES (2) ES358737A1 (en)
FI (1) FI50238C (en)
FR (1) FR1583595A (en)
GB (1) GB1247934A (en)
HK (1) HK53076A (en)
IE (1) IE32388B1 (en)
IL (1) IL30776A (en)
NL (1) NL145531B (en)
NO (1) NO131456C (en)
PL (1) PL79354B1 (en)
RO (1) RO55806A (en)
SE (1) SE367399B (en)
SU (2) SU476748A3 (en)
YU (1) YU35093B (en)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH540233A (en) * 1969-06-05 1973-08-15 Ciba Geigy Ag Process for the preparation of new di-styrylbenzene derivatives
US3880841A (en) * 1971-03-18 1975-04-29 Sandoz Ltd Triazolyl ethenyl phenylene derivatives
CH554911A (en) * 1971-12-30 1974-10-15 Ciba Geigy Ag USE OUTSIDE THE TEXTILE INDUSTRY OF NEW 4,4'-DIVINYLDIPHENYL COMPOUNDS AS OPTICAL LIGHTENING AGENTS FOR ORGANIC MATERIALS.
FR2168210A2 (en) * 1972-01-20 1973-08-31 Ciba Geigy Ag Bis-stilbene cpds - as optical brighteners
DE2326467B2 (en) * 1972-06-01 1979-02-22 Colgate-Palmolive Co., New York, N.Y. (V.St.A.) Liquid heavy duty detergent
CH569043A5 (en) * 1973-01-23 1975-11-14 Ciba Geigy Ag
CH630215B (en) * 1976-07-09 Ciba Geigy Ag LIGHTENING AGENTS AND THEIR USE FOR LIGHTENING TEXTILES.
ZA802160B (en) * 1979-04-11 1981-04-29 Ciba Geigy Ag Distyrylbiphenyls
US4339393A (en) * 1979-04-11 1982-07-13 Ciba-Geigy Corporation Distyrylbiphenyls
ZA802159B (en) * 1979-04-11 1981-04-29 Ciba Geigy Ag Distyrylbenzenes
DE3176183D1 (en) * 1980-12-12 1987-06-19 Ciba Geigy Ag 4-styryl-4'-vinylbifenyls, methods for their preparation and their use as optical whiteners
US4925595A (en) * 1987-07-03 1990-05-15 Ciba-Geigy Corporation Liquid detergent compositions containing disulfonated fluorescent whitening agents: di-styryl-biphenyl or di-styryl-benzene derivatives
EP0364403B1 (en) * 1988-10-13 1993-03-24 Ciba-Geigy Ag Distyryl biphenyl compounds
DE4019309A1 (en) * 1990-06-16 1991-12-19 Bayer Ag NEW LIGHT-POLARIZING FILMS OR FILMS AND DYES FOR THEIR PRODUCTION
MY109837A (en) * 1992-06-30 1997-08-30 Ciba Specialty Chemicals Holding Inc Hydrates of the disodium salt or dipotassium salt of 4, 4''-bis (2-sulfostyryl)bipheny]
TW229199B (en) * 1992-09-03 1994-09-01 Ciba Geigy
GB2277749B (en) * 1993-05-08 1996-12-04 Ciba Geigy Ag Fluorescent whitening of paper
US6168776B1 (en) 1994-07-19 2001-01-02 University Of Pittsburgh Alkyl, alkenyl and alkynyl Chrysamine G derivatives for the antemortem diagnosis of Alzheimer's disease and in vivo imaging and prevention of amyloid deposition
GB9422280D0 (en) * 1994-11-04 1994-12-21 Ciba Geigy Ag Fluorescent whitening agent formulation
GB9718353D0 (en) * 1997-08-30 1997-11-05 Ciba Geigy Ag Sulphonated distyryl - Biphenyl compounds
ID25593A (en) 1998-03-19 2000-10-19 Ciba Sc Holding Ag THE PROCESS OF MAKING SULFONATED DISTRIL-BEFENIL COMPOUNDS
KR100274871B1 (en) * 1998-11-12 2000-12-15 김순택 Photoluminescence compound and display device adopting photoluminescence compound as color-developing substance
DE10334046A1 (en) * 2003-07-25 2005-02-10 Clariant Gmbh Process for the preparation of granulated acyloxybenzenesulfonates or acyloxybenzenecarboxylic acids and their salts
GB0405193D0 (en) * 2004-03-08 2004-04-21 Medical Res Council Compounds
CN102906239B (en) 2010-05-18 2015-09-09 美利肯公司 White dyes and containing its composition
WO2011146602A2 (en) * 2010-05-18 2011-11-24 Milliken & Company Optical brighteners and compositions comprising the same
CN109912465B (en) * 2019-04-17 2021-08-24 沈阳新纪化学有限公司 Synthesis method of distyrylbiphenyl fluorescent whitening agent with bluish tone
US11292957B2 (en) 2020-01-21 2022-04-05 King Fahd University Of Petroleum And Minerals Gemini surfactants containing an arylene linker for clay swelling inhibition
CN114230509A (en) * 2021-04-19 2022-03-25 闽都创新实验室 Stilbene derivative containing fluorine substituted biphenyl and preparation method and application thereof
JP2023056635A (en) * 2021-10-08 2023-04-20 セイコーエプソン株式会社 Binding material and method for manufacturing molded body

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ES378656A1 (en) 1973-02-01
SU391781A3 (en) 1973-07-25
DE1793482A1 (en) 1972-03-09
NO131456B (en) 1975-02-24
JPS54929B1 (en) 1979-01-18
FI50238C (en) 1976-01-12
DK139845C (en) 1979-10-08
NL145531B (en) 1975-04-15
CH554821A (en) 1974-10-15
FI50238B (en) 1975-09-30
SE367399B (en) 1974-05-27
HK53076A (en) 1976-09-03
FR1583595A (en) 1969-11-14
CH700070A4 (en) 1975-01-31
CS174800B2 (en) 1977-04-29
IL30776A0 (en) 1968-11-27
PL79354B1 (en) 1975-06-30
CS174763B2 (en) 1977-04-29
SU476748A3 (en) 1975-07-05
YU226368A (en) 1980-03-15
IE32388B1 (en) 1973-07-11
RO55806A (en) 1974-01-03
BE721754A (en) 1969-04-02
BR6802828D0 (en) 1973-04-17
DE1793482C3 (en) 1975-09-25
IL30776A (en) 1974-06-30
AT288306B (en) 1971-02-25
DK139845B (en) 1979-04-30
CH532106A (en) 1972-12-31
YU35093B (en) 1980-09-25
CH566420B5 (en) 1975-09-15
NL6814089A (en) 1969-04-09
CH513785A (en) 1971-10-15
GB1247934A (en) 1971-09-29
NO131456C (en) 1975-06-11
IE32388L (en) 1969-04-03
AT299171B (en) 1972-06-12
DE1793482B2 (en) 1975-02-20

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