ES354810A1 - Improved coating compositions - Google Patents
Improved coating compositionsInfo
- Publication number
- ES354810A1 ES354810A1 ES354810A ES354810A ES354810A1 ES 354810 A1 ES354810 A1 ES 354810A1 ES 354810 A ES354810 A ES 354810A ES 354810 A ES354810 A ES 354810A ES 354810 A1 ES354810 A1 ES 354810A1
- Authority
- ES
- Spain
- Prior art keywords
- copolymer
- film
- polymer
- egm
- polymethyl methacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000008199 coating composition Substances 0.000 title abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 9
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract 6
- 239000004926 polymethyl methacrylate Substances 0.000 abstract 6
- 239000007788 liquid Substances 0.000 abstract 5
- 239000000463 material Substances 0.000 abstract 5
- 229920000642 polymer Polymers 0.000 abstract 5
- 229920001971 elastomer Polymers 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 229920000728 polyester Polymers 0.000 abstract 3
- 239000000758 substrate Substances 0.000 abstract 3
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 abstract 2
- 229920000180 alkyd Polymers 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- -1 methacrylate ester Chemical class 0.000 abstract 2
- 229920003145 methacrylic acid copolymer Polymers 0.000 abstract 2
- 229940117841 methacrylic acid copolymer Drugs 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 239000012071 phase Substances 0.000 abstract 2
- 229920002635 polyurethane Polymers 0.000 abstract 2
- 239000004814 polyurethane Substances 0.000 abstract 2
- 239000002023 wood Substances 0.000 abstract 2
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical group CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 abstract 1
- RWHRFHQRVDUPIK-UHFFFAOYSA-N 50867-57-7 Chemical compound CC(=C)C(O)=O.CC(=C)C(O)=O RWHRFHQRVDUPIK-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- 239000004925 Acrylic resin Substances 0.000 abstract 1
- 229920000178 Acrylic resin Polymers 0.000 abstract 1
- 239000004593 Epoxy Substances 0.000 abstract 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 239000004642 Polyimide Substances 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 238000007605 air drying Methods 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- IWLBIFVMPLUHLK-UHFFFAOYSA-N azane;formaldehyde Chemical compound N.O=C IWLBIFVMPLUHLK-UHFFFAOYSA-N 0.000 abstract 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract 1
- 229920005549 butyl rubber Polymers 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 abstract 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 abstract 1
- 230000009477 glass transition Effects 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 229920000120 polyethyl acrylate Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920001721 polyimide Polymers 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
- C08F2/08—Organic solvent with the aid of dispersing agents for the polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
- C09D101/08—Cellulose derivatives
- C09D101/10—Esters of organic acids
- C09D101/14—Mixed esters, e.g. cellulose acetate-butyrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09D123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C09D123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Liquid coating compositions comprise, in a liquid continuous phase, a film-forming material, a rubbery polymer in the form of dispersed particles of average diameter in the range 0.01-10Á and, optionally, a plasticiser, the composition being capable of forming a dry coating comprising a film of polymer formed from said material, wherein the rubbery particles remain in dispersion and adhere to the plasticised or unplasticised filmform polymer and the rubbery polymer has a primary glass transition temperature of less than 0 C, a Youngs Modulus not more than a tenth of that of the film-form polymer and an extension to break at least ten times that of the film-form polymer. The film forming material may be an alkyd resin, an epoxy resin, a cellulose derivative, a polyimide, a polyester, a vinyl resin such as polystyrene or polyvinyl chloride, or an acrylic resin such as polymethyl methacrylate alternatively the film-forming material may comprise a monomeric or oligomeric material which is polymerised or cured in situ on a substrate to form the solid film, e.g. low molecular weight amine-formaldehyde, phenol-formaldehyde, epoxy or polyester condensates, and a liquid monomer may provide the liquid continuous phase. The rubbery polymer suitably has as its main component an appropriate acrylate or methacrylate ester, vinyl acetate or propionate, a low polymer of ethylene oxide alkyl-terminated at one end and terminated by polymerisable unsaturation at the other end, an olefin or a diene polyurethanes, polyamides and polyesters are also useful as the rubbery polymer. The liquid phase may comprise a volatile liquid. In Examples the following rubbery and film-forming components are used (1) polyethyl acrylate and hexamethoxymethyl melamine (2) ethyl acrylateglycidyl methacrylate-methacrylic acid copolymer (EGM copolymer) and styrene-methacrylic acid-butoxymethylacrylamide copolymer or melamine-formaldehyde or air-drying alkyd resin (3) EGM copolymer and either cellulose acetate butyrate or polymethyl methacrylate (4) EGM copolymer and polymethyl methacrylate (5) and (6) as for (2) or (3) but wherein the ethyl acrylate of the EGM copolymer is replaced by n-propyl acrylate or #-(#-butoxyethoxy)-ethyl acrylate respectively (7) EGM copolymer and a mixture of diphenylolpropane diglycidyl ether and oligomers thereof (8) vinyl acetate-2-ethyl-hexyl acrylate copolymer and polyvinyl alcohol (9) vulcanised butyl rubber and polymethyl methacrylate (10) polyurethane and polymethyl methacrylate (11) polythene and polymethyl methacrylate (12) polypropylene and styrenehydroxyethyl methacrylate copolymer (13) EGM copolymer (additionally containing units of dimethylaminoethyl methacrylate) and methyl methcarylate-methacrylic acid copolymer. The compositions are suitable for application to substrates such as metal, wood and plastic substrates. The coatings can be crosslinked by stoving. In Examples, the compositions are applied to metals, e.g. tin foil or sheet metal, and to wood panels.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB26791/67A GB1242054A (en) | 1967-06-08 | 1967-06-08 | Improved coating compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES354810A1 true ES354810A1 (en) | 1970-02-16 |
Family
ID=10249268
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES354810A Expired ES354810A1 (en) | 1967-06-08 | 1968-06-08 | Improved coating compositions |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE716285A (en) |
| DE (1) | DE1769557A1 (en) |
| ES (1) | ES354810A1 (en) |
| FR (1) | FR1570799A (en) |
| GB (1) | GB1242054A (en) |
| NL (1) | NL6808006A (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1064637A (en) * | 1975-03-19 | 1979-10-16 | Samuel Porter (Jr.) | Method of preparing gelled polymeric microparticles, product produced thereby, and compositions containing the same |
| GB1599045A (en) * | 1977-04-25 | 1981-09-30 | Ici Ltd | Coating compositions |
| GB1588976A (en) * | 1977-04-25 | 1981-05-07 | Ici Ltd | Coating composition containing metallic pigmentation |
| GB1588978A (en) | 1977-07-19 | 1981-05-07 | Ici Ltd | Coating processes |
| GB1594123A (en) * | 1977-04-25 | 1981-07-30 | Ici Ltd | Autoxidisable coating compositions containing dispersed crosslinked polymer particles |
| NZ186925A (en) | 1977-04-25 | 1979-12-11 | Ici Ltd | Top-coating based on a basecoat and top-coat compositions not requiring an intermediate baking operation |
| FR2412581A1 (en) * | 1977-12-23 | 1979-07-20 | Formica Corp | Melamine formaldehyde! resin used in decorative laminates - mixed with ethylene! vinyl! chloride copolymer or polyurethane elastomer |
| US4232135A (en) | 1978-01-10 | 1980-11-04 | Imperial Chemical Industries Limited | Coating compositions |
| GB1598419A (en) | 1978-05-17 | 1981-09-23 | Ici Ltd | Coating process |
| FR2541296B1 (en) * | 1983-02-21 | 1986-07-11 | Boulenger Ets | MASTIC FOR ELASTIC FLOOR COVERINGS |
| GB8420005D0 (en) * | 1984-08-06 | 1984-09-12 | Ici Plc | Coating compositions |
| GB2170810B (en) * | 1985-02-11 | 1989-09-06 | Coates Brothers Plc | Coating compositions |
| US5331025A (en) * | 1992-11-04 | 1994-07-19 | Rohm And Haas Company | Coating compositions incorporating composite polymer particles |
| JP3329049B2 (en) * | 1994-01-24 | 2002-09-30 | 日本油脂ビーエーエスエフコーティングス株式会社 | Thermosetting coating composition for clear coat of automotive topcoat |
| JPH07224236A (en) * | 1994-02-14 | 1995-08-22 | Nippon Oil & Fats Co Ltd | Elasticity improver for coating material, its production, and coating material |
-
1967
- 1967-06-08 GB GB26791/67A patent/GB1242054A/en not_active Expired
-
1968
- 1968-06-07 NL NL6808006A patent/NL6808006A/xx unknown
- 1968-06-07 FR FR1570799D patent/FR1570799A/fr not_active Expired
- 1968-06-07 BE BE716285D patent/BE716285A/xx unknown
- 1968-06-08 ES ES354810A patent/ES354810A1/en not_active Expired
- 1968-06-08 DE DE19681769557 patent/DE1769557A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| NL6808006A (en) | 1968-12-10 |
| FR1570799A (en) | 1969-06-13 |
| BE716285A (en) | 1968-12-09 |
| GB1242054A (en) | 1971-08-11 |
| DE1769557A1 (en) | 1972-02-03 |
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