ES2985429A1 - Eco-sustainable method of regeneration of products (Machine-translation by Google Translate, not legally binding) - Google Patents
Eco-sustainable method of regeneration of products (Machine-translation by Google Translate, not legally binding) Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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- Chemical Kinetics & Catalysis (AREA)
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- Dermatology (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
DESCRIPCIÓNDESCRIPTION
Método de regeneración ecosostenible de productos Eco-sustainable method of regeneration of products
SECTOR DE LA TÉCNICATECHNICAL SECTOR
La presente invención se refiere a un nuevo método ecosostenible de regeneración de productos por micro encapsulado químico de sus partículas o nano partículas, a partir de una preselección de productos que pueden ser minerales, vegetales, plásticos, orgánicos, sintéticos e incluso híbridos (mezcla compuesta de más de un producto), procedentes preferentemente de residuales y subproductos industriales, agrícolas, urbanos diversos, ya sean minerales, vegetales, plásticos, orgánicos o sintéticos así como híbridos o compuestos, mediante su clasificación, tratamiento posterior y mezclado o batido convenientemente con una dispersión polimérica acuosa translúcida pero coloreable y su posterior proceso de aplicación ecosostenible en su destino, como puede ser sobre un objeto o directamente sobre una obra. The present invention relates to a new eco-sustainable method of regenerating products by chemical micro-encapsulation of their particles or nanoparticles, from a preselection of products that may be mineral, vegetable, plastic, organic, synthetic and even hybrid (mixture composed of more than one product), preferably originating from various industrial, agricultural, urban waste and by-products, whether mineral, vegetable, plastic, organic or synthetic as well as hybrids or compounds, through their classification, subsequent treatment and convenient mixing or beating with a translucent but colorable aqueous polymeric dispersion and its subsequent eco-sustainable application process at its destination, such as on an object or directly on a work.
La invención es aplicable en el sector de la construcción, la industria del cuero, automovilística, mobiliario, artesanía, aislamiento termoacústico, impermeabilización, de la moda, decoración, etc. The invention is applicable in the construction sector, the leather industry, the automotive industry, furniture, crafts, thermal and acoustic insulation, waterproofing, fashion, decoration, etc.
OBJETO DE LA INVENCIÓNOBJECT OF THE INVENTION
El objeto de la invención es por tanto ofrecer una importante mejora medioambiental y funcional, además de estética, en los diferentes ámbitos de aplicación práctica anteriormente descritos, sin descuidar una contribución al ahorro energético, al determinar una barrera protectora termo-decorativa que conformará la piel visible interior o exterior de cualquier elemento constructivo, decorativo, etc. recubierto o encapsulado con la misma. The object of the invention is therefore to offer a significant environmental and functional improvement, as well as an aesthetic one, in the different areas of practical application described above, without neglecting a contribution to energy savings, by determining a thermo-decorative protective barrier that will form the visible interior or exterior skin of any constructive, decorative, etc. element coated or encapsulated with it.
ANTECEDENTES DE LA INVENCIÓNBACKGROUND OF THE INVENTION
Hasta la fecha, los numerosos residuos procedentes, por ejemplo, del curtido, elaboración y pulido de pieles tenían su triste final en vertederos controlados. Until now, the vast majority of waste products from, for example, tanning, processing and polishing leather have ended up in controlled landfills.
Similar situación se da con otros subproductos de diferentes industrias. A similar situation occurs with other by-products from different industries.
La presente solicitud viene a solucionar estos problemas mediante el total encapsulamiento y ensamblaje de todas y cada una de las partículas residuales y su posterior aglomerado, formando de nuevo, en este caso, una hidro-argamasa orgánica con múltiples aplicaciones industriales, térmicas, funcionales y al mismo tiempo, decorativas, así como para la industria de la moda. The present application aims to solve these problems by means of the total encapsulation and assembly of each and every one of the residual particles and their subsequent agglomeration, forming again, in this case, an organic hydro-mortar with multiple industrial, thermal, functional and at the same time, decorative applications, as well as for the fashion industry.
EXPLICACIÓN DE LA INVENCIÓNEXPLANATION OF THE INVENTION
El método de la invención pretende dar un nuevo uso a residuos y subproductos de muy diversa índole entre los que cabe destacar a modo meramente ejemplario los siguientes: The method of the invention aims to give a new use to waste and by-products of very diverse nature, among which the following can be highlighted as merely exemplary:
Minerales: fibras y lanas minerales, cerámica, áridos, lodos de corte y pulido en cantera e industria, polvo de fundición, arenas abrasivas de chorreo etc. Minerals: mineral fibres and wool, ceramics, aggregates, cutting and polishing sludge in quarries and industry, foundry dust, abrasive blasting sands, etc.
Vegetales: Polvo y serrines de madera y corcho, de caucho, fibras vegetales, hueso de aceituna, cáscara de frutos secos, cáscara y paja de arroz etc. Vegetables: Wood and cork dust and sawdust, rubber, vegetable fibers, olive stones, nutshells, rice husks and straw, etc.
Orgánicos: Restos de curtido de cuero, lana y pelo animal, residuos hortofrutícolas secos, etc. Organic: Leather tanning waste, wool and animal hair, dry fruit and vegetable waste, etc.
Sintéticos: Restos triturados de envases y embalajes, de paneles de poliuretano, poliestireno, poliisocianurato, espumas fenólicas, gomaespumas, plásticos en general, etc. Synthetics: Crushed remains of containers and packaging, polyurethane panels, polystyrene, polyisocyanurate, phenolic foams, foam rubber, plastics in general, etc.
Este nuevo método ecosostenible de reintegración en la cadena de valores de productos residuales y subproductos, comprende además el acoplamiento mediante vertido, encolado o proyección de este nuevo producto obtenido sobre cualquier objeto a modo de recubrimiento o encapsulamiento termo elástico, impermeable, altamente funcional y decorativo tales como chapa metálica, cristal, metacrilato, plástico, poliéster, caucho, piedra, hormigón, cerámica, gres, madera, corcho, fibras minerales, vegetales y artificiales, yeso, gomaespuma, poliéster, poliestireno, poliuretano, poliisocianurato etc. This new eco-sustainable method of reintegrating waste products and by-products into the value chain also includes coupling by pouring, gluing or spraying this new product obtained onto any object as a thermo-elastic, waterproof, highly functional and decorative coating or encapsulation such as sheet metal, glass, methacrylate, plastic, polyester, rubber, stone, concrete, ceramic, stoneware, wood, cork, mineral, vegetable and artificial fibres, plaster, foam rubber, polyester, polystyrene, polyurethane, polyisocyanurate, etc.
Para ello, y de forma más concreta, el método de la invención parte de una primera fase de preselección de por lo menos uno de los productos residuales o subproductos descritos, su tratamiento, trituración y recorte o deformación si es necesario hasta conseguir las medidas y formatos deseadas, normalmente inferiores a 4 mm de longitud o de diámetro. To this end, and more specifically, the method of the invention starts with a first phase of preselection of at least one of the residual products or by-products described, their treatment, crushing and cutting or deformation if necessary until obtaining the desired measurements and formats, normally less than 4 mm in length or diameter.
Una vez tratados los productos residuales o subproductos, estos se someten a una fase de mezclado y encapsulado con una dispersión polimérica acuosa, a base de estireno y ésteres del ácido acrílico y su posterior envasado hermético conjunto, manteniéndose así inalterable mínimamente durante más de 9 meses. Once the residual products or by-products have been treated, they undergo a mixing and encapsulation phase with an aqueous polymer dispersion based on styrene and acrylic acid esters and their subsequent joint hermetic packaging, thus remaining minimally unaltered for more than 9 months.
La hidromembrana obtenida tras su aplicación y en contacto con el aire inicia su proceso de curado, durante un tiempo comprendido normalmente entre 8 y 48 horas, sobre los correspondientes soportes, si bien este tiempo puede acelerarse mediante compactación, aplicación química o mediante calor. The hydromembrane obtained after its application and in contact with the air begins its curing process, normally for a time between 8 and 48 hours, on the corresponding supports, although this time can be accelerated by compaction, chemical application or by heat.
Todo este proceso puede realizarse a temperatura ambiente, evitando así costes de energía y la generación de huellas de carbono. This entire process can be carried out at room temperature, thus avoiding energy costs and the generation of carbon footprints.
Opcionalmente, antes o durante la fase de curado, podrían añadirse fibras de refuerzo, acelerantes químicos, aglomerantes o colorantes, en función de las características del producto final perseguido. Optionally, before or during the curing phase, reinforcing fibres, chemical accelerators, binders or colourants could be added, depending on the characteristics of the final product sought.
En cuanto a las proporciones de componentes empleadas, el producto residual tratado podría participar en una proporción comprendida entre el 50 y el 75% en volumen del producto final, mientras que el producto acrílico participaría en una proporción comprendida entre el 25 y el 50% en volumen. As regards the proportions of components used, the treated residual product could represent between 50 and 75% by volume of the final product, while the acrylic product would represent between 25 and 50% by volume.
El producto así obtenido consiste en una hidro-argamasa no cementosa, impermeable y flexible que permite reproducir artificialmente una pieza de aspecto y características prácticamente iguales o muy semejantes al producto original de su procedencia, así como la creación “a la carta” de nuevos productos híbridos o compuestos, de aspecto, densidad y resistencia modificables a voluntad según sea su destino o aplicación. The product thus obtained consists of a non-cementitious, impermeable and flexible hydro-mortar that allows the artificial reproduction of a piece with an appearance and characteristics practically identical or very similar to the original product of its origin, as well as the "à la carte" creation of new hybrid or composite products, with an appearance, density and resistance that can be modified at will depending on their destination or application.
En el caso de utilizarse subproductos de la industria minera, al tratarse der un proceso a la inversa del que se produce en la extracción y consumo de materias primas minerales como por ejemplo la piedra, el mármol o el granito, reutilizando sus partículas, nanopartículas o los lodos de cantera residuales, se puede conseguir nuevamente un producto aglomerado artificial compacto prácticamente de las mismas características físico-mecánicas que los minerales originales de su procedencia. In the case of using by-products from the mining industry, since it is a process that is the reverse of that which occurs in the extraction and consumption of mineral raw materials such as stone, marble or granite, reusing their particles, nanoparticles or residual quarry sludge, a compact artificial agglomerated product can be obtained again with practically the same physical-mechanical characteristics as the original minerals of its origin.
En el caso del tratamiento de sub-productos o residuos vegetales, como por ejemplo el corcho, la madera, la cáscara y paja de arroz, etc, se puede reproducir nuevamente un producto vegetal artificial prácticamente de las mismas características físico-mecánicas que los vegetales originales de su procedencia. In the case of the treatment of by-products or plant waste, such as cork, wood, rice husk and straw, etc., an artificial plant product can be reproduced again with practically the same physical-mechanical characteristics as the original plants of its origin.
En el caso del tratamiento de sub-productos o residuos orgánicos como por ejemplo el cuero, la lana o el pelo animal, se puede volver a reproducir nuevamente y en continuo un producto orgánico artificial prácticamente de las mismas características físico-mecánicas que los productos orgánicos originales de su procedencia. In the case of the treatment of by-products or organic waste such as leather, wool or animal hair, an artificial organic product with practically the same physical-mechanical characteristics as the original organic products of its origin can be reproduced again and again in a continuous manner.
En el caso del tratamiento de sub-productos o residuos mixtos, esto permite la creación, prácticamente a la carta, de nuevos productos capaces de combinar las diferentes cualidades de cada uno de ellos para conformar productos híbridos colaborantes que mejoren y compensen sus propias limitaciones pudiendo proporcionar soluciones constructivas, decorativas y arquitectónicas que no se podrían conseguir por separado, como por ejemplo, lito/cerámica (piedra líquida sobre cerámica), termo/piedra (pasta de piedra sobre aislamiento), “leather-glass” (pasta de cuero sobre cristal), pasta de cuero sobre metal, corcho en pasta sobre metal, y así un largo etc. In the case of the treatment of by-products or mixed waste, this allows the creation, practically on demand, of new products capable of combining the different qualities of each of them to form collaborative hybrid products that improve and compensate for their own limitations, being able to provide constructive, decorative and architectural solutions that could not be achieved separately, such as, for example, litho/ceramic (liquid stone on ceramic), thermo/stone (stone paste on insulation), “leather-glass” (leather paste on glass), leather paste on metal, cork paste on metal, and so on.
En tal sentido, con el empleo de productos residuales de baja densidad y flexibles como por ejemplo el corcho o el cuero, debajo de productos de alta resistencia mecánica como el acero, se consigue la creación de paneles tipo azulejo de revestimiento metal/corcho o metal-cuero con sus perímetros gratuitamente redondeados y sin mordiente, más fáciles de recortar de forma automatizada y sin perjudicar el filo de sus medios de corte. In this sense, by using low-density and flexible residual products such as cork or leather, under high mechanical resistance products such as steel, it is possible to create metal/cork or metal-leather cladding tile-type panels with their perimeters freely rounded and without mordant, easier to cut automatically and without damaging the edge of their cutting means.
Cabe igualmente destacar el hecho de que gracias a la elasticidad de la hidro-membrana se consigue un producto flexible y resistente muy adecuado para su uso como puente de adherencia universal, productos anti vibratorios, acabados industriales sin retracción, reparación y sellado de todo tipo de grietas y fisuras, capas de rodadura y reparación de pavimentos, muy eficiente en la restauración arquitectónica de monumentos, etc. It is also worth highlighting the fact that thanks to the elasticity of the hydro-membrane, a flexible and resistant product is obtained, very suitable for use as a universal adhesion bridge, anti-vibration products, industrial finishes without retraction, repair and sealing of all types of cracks and fissures, tread layers and pavement repair, very efficient in the architectural restoration of monuments, etc.
DESCRIPCIÓN DE LOS DIBUJOSDESCRIPTION OF THE DRAWINGS
Para complementar la descripción que seguidamente se va a realizar y con objeto de ayudar a una mejor comprensión de las características del invento, de acuerdo con un ejemplo preferente de realización práctica del mismo, se acompaña como parte integrante de dicha descripción, un juego de planos en donde con carácter ilustrativo y no limitativo, se ha representado lo siguiente: To complement the description that will be made below and in order to help better understand the characteristics of the invention, in accordance with a preferred example of its practical implementation, a set of drawings is included as an integral part of said description, in which, for illustrative and non-limiting purposes, the following has been represented:
La figura 1.- Muestra un detalle en perspectiva ampliado de un material obtenido a partir del método de regeneración ecosostenible objeto de la presente invención. Figure 1.- Shows an enlarged perspective detail of a material obtained from the eco-sustainable regeneration method object of the present invention.
La figura 2.- Muestra una vista en perspectiva de un ejemplo de aplicación práctica de la invención en la que el material se utiliza como recubrimiento decorativo y aislante en la obtención de paramentos. Figure 2.- Shows a perspective view of an example of practical application of the invention in which the material is used as a decorative and insulating coating in obtaining walls.
La figura 3.- Muestra una vista en perspectiva de otro ejemplo de aplicación práctica de la invención en la que el material se emplea como recubrimiento termo decorativo en continuo de cuero sobre un objeto de cristal. Figure 3.- Shows a perspective view of another example of practical application of the invention in which the material is used as a continuous thermo-decorative leather coating on a glass object.
REALIZACIÓN PREFERENTE DE LA INVENCIÓNPREFERRED EMBODIMENT OF THE INVENTION
A la vista de las figuras reseñadas, y a modo meramente ejemplario, en el método de la invención se partió como material a reciclar de una mezcla de residuos o subproductos sólidos (1) tales como lana mineral, lodos, arena etc, más fibras de refuerzo. In view of the figures shown, and merely as an example, in the method of the invention the material to be recycled was started from a mixture of solid waste or by-products (1) such as mineral wool, sludge, sand, etc., plus reinforcing fibers.
Este material base participa en una proporción comprendida entre el 50 y el 75% en volumen del producto final, siendo sometido a un proceso de triturado, hasta obtener normalmente unas partículas de un tamaño inferior a los 4mm de largo o de diámetro. This base material accounts for between 50 and 75% of the volume of the final product, and is subjected to a crushing process until particles are normally obtained that are less than 4 mm long or in diameter.
Seguidamente se mezcla con una dispersión polimérica acuosa (2) en una proporción comprendida entre el 25 y el 50% en volumen, a base de estireno y ésteres del ácido acrílico. It is then mixed with an aqueous polymer dispersion (2) in a proportion between 25 and 50% by volume, based on styrene and acrylic acid esters.
El producto obtenido se aplica mediante extensión, colada o proyección sobre cualquier soporte, ya sea directamente sobre un paramento vertical u horizontal en obra o bien sobre cualquier tipo de objeto o panel prefabricado, a modo de recubrimiento termo-decorativo, que en el ejemplo de realización tiene por objeto obtener unos paneles modulares de revestimiento (3) como los mostrados en la figura 2, que son susceptibles de fijarse mediante adhesivo, grapas simples (6) o grapas dobles (6’) o por cualquier otro medio convencional sobre unos paneles aislantes (4) del tipo S.A.T.E. en la formación de un paramento (5) constituyendo un recubrimiento que además de aislar de la humedad, térmica y acústicamente, presentan una apariencia decorativa modular que los hace sumamente prácticos e interesantes para su uso en bioconstrucción. The product obtained is applied by spreading, casting or projection onto any support, either directly onto a vertical or horizontal wall on site or onto any type of prefabricated object or panel, as a thermo-decorative coating, which in the exemplary embodiment aims to obtain modular cladding panels (3) such as those shown in figure 2, which are susceptible to being fixed by means of adhesive, single staples (6) or double staples (6') or by any other conventional means on insulating panels (4) of the S.A.T.E. type in the formation of a wall (5) constituting a coating that in addition to insulating from humidity, thermally and acoustically, has a modular decorative appearance that makes them extremely practical and interesting for use in green construction.
No obstante y como se ha dicho anteriormente, la invención es aplicable en innumerables ámbitos en función de los residuos o subproductos de los que se parta, pudiendo citar, a modo meramente ejemplario la obtención de hidromembranas (3’) a base de residuos de cuero, corcho o cristal, debidamente embebidos en el material acrílico, para la obtención de envases (6) de cristal, como el mostrado en la figura 3, ofreciendo una gran capacidad termo-decorativa, manteniendo o incrementando las prestaciones del nuevo objeto a formar, en virtud de las características físico-químicas de los diferentes materiales o mezcla de los mismos de los que se parta. However, as previously stated, the invention is applicable in countless areas depending on the waste or by-products from which it is obtained, and, as a mere example, we can mention the production of hydromembranes (3') from leather, cork or glass waste, duly embedded in the acrylic material, for the production of glass containers (6), such as that shown in figure 3, offering a great thermo-decorative capacity, maintaining or increasing the performance of the new object to be formed, by virtue of the physical-chemical characteristics of the different materials or mixtures thereof from which it is obtained.
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ES2294932A1 (en) * | 2006-06-30 | 2008-04-01 | Jordi Castañe Callis | Method for obtaining light artificial stone and product thus obtained |
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US20140302337A1 (en) * | 2011-06-03 | 2014-10-09 | Patrick A.C. Gane | Process for manufacturing coated substrates |
WO2014174033A2 (en) * | 2013-04-26 | 2014-10-30 | Sika Technology Ag | Cement-free or cement-reduced low dust hybrid flooring compositions |
ES2528092B1 (en) * | 2013-08-02 | 2016-08-23 | Green Rock, Sl. | Techno-sustainable industrial bio-mortar |
US20220204707A1 (en) * | 2019-04-15 | 2022-06-30 | Nabore GmbH | Thermoplastic composite material |
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US20100066121A1 (en) * | 2005-04-01 | 2010-03-18 | Gross James R | Nonwoven material for acoustic insulation, and process for manufacture |
ES2294932A1 (en) * | 2006-06-30 | 2008-04-01 | Jordi Castañe Callis | Method for obtaining light artificial stone and product thus obtained |
US20140302337A1 (en) * | 2011-06-03 | 2014-10-09 | Patrick A.C. Gane | Process for manufacturing coated substrates |
WO2014174033A2 (en) * | 2013-04-26 | 2014-10-30 | Sika Technology Ag | Cement-free or cement-reduced low dust hybrid flooring compositions |
ES2528092B1 (en) * | 2013-08-02 | 2016-08-23 | Green Rock, Sl. | Techno-sustainable industrial bio-mortar |
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