[go: up one dir, main page]

ES2525957B1 - Procedure for obtaining synthesis gas - Google Patents

Procedure for obtaining synthesis gas Download PDF

Info

Publication number
ES2525957B1
ES2525957B1 ES201330975A ES201330975A ES2525957B1 ES 2525957 B1 ES2525957 B1 ES 2525957B1 ES 201330975 A ES201330975 A ES 201330975A ES 201330975 A ES201330975 A ES 201330975A ES 2525957 B1 ES2525957 B1 ES 2525957B1
Authority
ES
Spain
Prior art keywords
sub
synthesis gas
stream
obtaining synthesis
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES201330975A
Other languages
Spanish (es)
Other versions
ES2525957A1 (en
Inventor
Antonio DE LUCAS CONSUEGRA
Jesús GONZÁLEZ COBOS
José Luis VALVERDE PALOMINO
Carmen JIMÉNEZ BORJA
Nuria GUTIÉRREZ GUERRA
José Luis Endrino Armenteros
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Abengoa Research SL
Original Assignee
Abengoa Research SL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Abengoa Research SL filed Critical Abengoa Research SL
Priority to ES201330975A priority Critical patent/ES2525957B1/en
Priority to PCT/ES2014/070470 priority patent/WO2014207279A1/en
Publication of ES2525957A1 publication Critical patent/ES2525957A1/en
Application granted granted Critical
Publication of ES2525957B1 publication Critical patent/ES2525957B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/02—Process control or regulation
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Automation & Control Theory (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Procedimiento de obtención de gas de síntesis.#La presente invención se refiere a un procedimiento de obtención de gas de síntesis (H{sub,2}/CO) de ratio controlable mediante un proceso catalítico y electroquímico que emplea una celda electroquímica formada por electrolitos sólidos conductores iónicos, aniónicos o catiónicos. El control del ratio H{sub,2}/CO se lleva a cabo en una única etapa bajo condiciones constantes de operación, es decir, a temperatura constante de la celda electroquímica y condiciones constantes de composición y concentración de la corriente de entrada. En la presente invención la corriente de entrada se selecciona de entre una corriente de hidrocarburos ligeros y una corriente de vapor de agua, o una corriente gaseosa que contiene al menos un alcohol (C{sub,1}-C{sub,3}).Method of obtaining synthesis gas. # The present invention relates to a method of obtaining synthesis gas (H {sub, 2} / CO) of controllable ratio by means of a catalytic and electrochemical process using an electrochemical cell formed by electrolytes ionic, anionic or cationic conductive solids. The control of the ratio H {sub, 2} / CO is carried out in a single stage under constant operating conditions, that is, at constant temperature of the electrochemical cell and constant conditions of composition and concentration of the input current. In the present invention the inlet stream is selected from a stream of light hydrocarbons and a stream of water vapor, or a gaseous stream containing at least one alcohol (C {sub, 1} -C {sub, 3}) .

Description

imagen1image 1

imagen2image2

imagen3image3

imagen4image4

imagen5image5

imagen6image6

imagen7image7

imagen8image8

imagen9image9

imagen10image10

imagen11image11

imagen12image12

imagen13image13

imagen14image14

imagen15image15

Claims (1)

imagen1image 1 imagen2image2 imagen3image3 imagen4image4
ES201330975A 2013-06-28 2013-06-28 Procedure for obtaining synthesis gas Expired - Fee Related ES2525957B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES201330975A ES2525957B1 (en) 2013-06-28 2013-06-28 Procedure for obtaining synthesis gas
PCT/ES2014/070470 WO2014207279A1 (en) 2013-06-28 2014-06-06 Method for producing synthesis gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES201330975A ES2525957B1 (en) 2013-06-28 2013-06-28 Procedure for obtaining synthesis gas

Publications (2)

Publication Number Publication Date
ES2525957A1 ES2525957A1 (en) 2015-01-02
ES2525957B1 true ES2525957B1 (en) 2015-10-21

Family

ID=51178953

Family Applications (1)

Application Number Title Priority Date Filing Date
ES201330975A Expired - Fee Related ES2525957B1 (en) 2013-06-28 2013-06-28 Procedure for obtaining synthesis gas

Country Status (2)

Country Link
ES (1) ES2525957B1 (en)
WO (1) WO2014207279A1 (en)

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2163449B (en) 1984-07-18 1988-06-02 Shell Int Research Production of gas mixtures containing hydrogen and carbon monoxide
US5714091A (en) * 1987-03-13 1998-02-03 The Standard Oil Company Process for the partial oxydation of hydrocarbons
US6287432B1 (en) * 1987-03-13 2001-09-11 The Standard Oil Company Solid multi-component membranes, electrochemical reactor components, electrochemical reactors and use of membranes, reactor components, and reactor for oxidation reactions
US4793904A (en) 1987-10-05 1988-12-27 The Standard Oil Company Process for the electrocatalytic conversion of light hydrocarbons to synthesis gas
ID20211A (en) * 1997-04-29 1998-10-29 Praxair Technology Inc HYDROGEN PRODUCTION METHOD USING SOLID ELECTROLITE MEMBRANE
US7276306B2 (en) * 2003-03-12 2007-10-02 The Regents Of The University Of California System for the co-production of electricity and hydrogen
FR2893033B1 (en) * 2005-11-04 2012-03-30 Inst Francais Du Petrole PROCESS FOR THE PRODUCTION OF SYNTHESIS GAS FROM CARBONACEOUS MATERIAL AND ELECTRICAL ENERGY
WO2008033452A2 (en) * 2006-09-13 2008-03-20 Ceramatec, Inc. High purity hydrogen and electric power co-generation apparatus and method

Also Published As

Publication number Publication date
WO2014207279A1 (en) 2014-12-31
ES2525957A1 (en) 2015-01-02

Similar Documents

Publication Publication Date Title
Eisaman et al. CO 2 extraction from seawater using bipolar membrane electrodialysis
SA518392324B1 (en) Method And Device For The Electrochemical Utilization Of Carbon Dioxide
AU2018200946B2 (en) Method and system for removing carbon dioxide from hydrocarbons
EA201690639A1 (en) MIXTURES FROM IONIC LIQUID AND SOLVENT TO REMOVE HYDROGEN
EA201390678A1 (en) EXTRACTING WATER FROM AIR
EA201591875A1 (en) DEVICE AND METHOD FOR MAKING DISPERSIONS AND SOLID PHASES
EA201390028A1 (en) LOCATED AT PRESSURE COLUMN FOR SEPARATION OF GASES AND A METHOD FOR REGULATING GAS IN HIGH PRESSURE FINAL PROCESSING
BR112014031220A2 (en) breathable electrode structure and method and system for use in water separation
Lu et al. Membrane contactor for CO2 absorption applying amino-acid salt solutions
EA201690010A1 (en) METHOD FOR PRODUCING BUTADIENE AND / OR BUTENES FROM N-BUTANE
BR112015023512A2 (en) method and apparatus for desorption using a wet-mode microporous membrane
AR100112A1 (en) HYDROGENATION PROVISION FOR AROMATIC COMPOUND
MX359580B (en) Device for separating carbon dioxide using silicone separation film and method for manufacturing same.
EA201290737A1 (en) METHOD OF OBTAINING SYNTHESIS GAS
MY181822A (en) High selectivity epoxysilicone-cross-linked polyimide membranes for gas separations
ES2525957B1 (en) Procedure for obtaining synthesis gas
RU2017120335A (en) PROCESSING DEVICES AND METHODS FOR PROCESSING ENRICHED NATURAL GAS
EA202092175A1 (en) REACTOR ON FUEL CELLS AND METHOD FOR DIRECT CONVERSION OF HYDROCARBON-CONTAINING GAS INTO HIGHER HYDROCARBON PRODUCT
BR112014019683A8 (en) ELECTROLYSIS METHOD AND APPARATUS TO PRODUCE OXYGEN AND HYDROGEN GAS
EA201391434A1 (en) METHOD OF METAL CONTAMINATION OF METAL CONTROL DEVICES FOR OBTAINING SYNTHESIS GAS
CL2018000936A1 (en) Process to produce a synthesis gas by reforming a hydrocarbon and including recovering carbon dioxide at high temperature.
EA201891052A1 (en) WATER GAS CONVERSION PROCESS
US10988427B2 (en) Olefin and methanol co-production plant and olefin and methanol co-production method
WO2016049290A3 (en) High permeability polyimide membranes: gas selectivity enhancement through uv treatment
EA201691219A1 (en) METHOD OF OBTAINING SYNTHESIS GAS

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 2525957

Country of ref document: ES

Kind code of ref document: B1

Effective date: 20151021

FD2A Announcement of lapse in spain

Effective date: 20210915