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ES2319065A1 - Method for producing a fabric with the appearance of tanned hide or leather, fabric produced and use thereof - Google Patents

Method for producing a fabric with the appearance of tanned hide or leather, fabric produced and use thereof Download PDF

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Publication number
ES2319065A1
ES2319065A1 ES200702706A ES200702706A ES2319065A1 ES 2319065 A1 ES2319065 A1 ES 2319065A1 ES 200702706 A ES200702706 A ES 200702706A ES 200702706 A ES200702706 A ES 200702706A ES 2319065 A1 ES2319065 A1 ES 2319065A1
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ES
Spain
Prior art keywords
fabric
finishing
leather
phase
mechanical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES200702706A
Other languages
Spanish (es)
Other versions
ES2319065B1 (en
Inventor
Jorge Sanjuan Perez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Comersan SA
Original Assignee
Comersan SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Comersan SA filed Critical Comersan SA
Priority to ES200702706A priority Critical patent/ES2319065B1/en
Priority to PCT/ES2008/000606 priority patent/WO2009050312A1/en
Publication of ES2319065A1 publication Critical patent/ES2319065A1/en
Application granted granted Critical
Publication of ES2319065B1 publication Critical patent/ES2319065B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/004—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using flocked webs or pile fabrics upon which a resin is applied; Teasing, raising web before resin application
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
    • D06N3/144—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer with polyurethane and polymerisation products, e.g. acrylics, PVC

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

The present invention concerns a method for manufacturing a fabric that imitates tanned hide or leather, said method comprising a weaving step and a series of mechanical and chemical processing operations on the surface of the material, said operations consisting in a step of mechanical pre-finishing, a chemical finishing step and a mechanical finishing step. The fabric produced, apart from its tanned hide or leather appearance, has at least impermeability, transpirability and anti-stain properties. The invention also concerns use of this fabric for the textile sector, and textile articles made totally or partly therewith.

Description

Procedimiento para la obtención de un tejido con aspecto de piel curtida o cuero, tejido obtenido a partir de él y su uso.Procedure for obtaining a tissue with look of tanned skin or leather, tissue obtained from it and its use.

Campo de la invenciónField of the Invention

La presente invención se refiere a un procedimiento para la fabricación de un tejido, al tejido obtenido a partir de dicho procedimiento, al uso del tejido y a los artículos textiles fabricados total o parcialmente con el mismo.The present invention relates to a procedure for the manufacture of a tissue, to the tissue obtained from said procedure, to the use of the tissue and to the textile articles manufactured totally or partially with the same.

En particular, la finalidad de esta invención es la de realizar un procedimiento para la fabricación de un tejido con textura y apariencia de piel curtida o cuero, que comprende al menos una fase de tejeduría, dos fases de acabado mecánico y una fase de acabado químico del material que le confieren al tejido su aspecto y propiedades.In particular, the purpose of this invention is to perform a procedure for the manufacture of a fabric with texture and appearance of tanned skin or leather, which includes minus one weaving phase, two mechanical finishing phases and one chemical finishing phase of the material that give the fabric its appearance and properties.

La invención se refiere también al tejido fabricado a partir de dicho procedimiento, con aspecto de piel curtida o cuero y con al menos las propiedades de impermeabilidad, transpirabilidad y antimanchas, para su uso en el mercado textil. El tejido objeto de invención está diseñado para ofrecer textura y apariencia estética y cumplir además la Normativa Europea respecto a las propiedades mencionadas.The invention also relates to the fabric manufactured from said procedure, with skin appearance tanned or leather and with at least the impermeability properties, breathability and anti-stain, for use in the textile market. The fabric object of the invention is designed to offer texture and aesthetic appearance and also comply with European regulations regarding to the mentioned properties.

Por último, se reivindican los artículos textiles que comprenden total o parcialmente el tejido objeto de protección.Finally, the articles are claimed textiles that comprise all or part of the fabric subject to protection.

Antecedentes de la invenciónBackground of the invention

Todos los artículos que imitan la piel en el ámbito de aplicación práctica de la invención, el mercado textil y más concretamente en el sector de la decoración y el calzado, precisan de un dificultoso proceso de fabricación y materiales de un alto valor añadido, lo que trae consigo un alto nivel de costos que lógicamente se hacen extensivos también a su posterior comercialización, especialmente los que imitan la piel curtida o cuero por el empleo de PVCs.All items that mimic the skin in the practical scope of the invention, the textile market and more specifically in the sector of decoration and footwear, they require a difficult manufacturing process and materials high added value, which brings with it a high level of costs which logically also extend to its later marketing, especially those that mimic tanned skin or leather by the use of PVCs.

Asimismo, se utilizan en la actualidad diferentes tejidos que imitan la piel curtida o el cuero destinados al sector de la decoración o el calzado. Sin embargo, a pesar de que pueden poseer una apariencia similar a la del tejido objeto de la presente invención, ninguno de ellos cumple además con las propiedades de impermeabilidad, transpirabilidad y antimancha. Así, son conocidos artículos con aspecto de piel vuelta que tienen propiedades de transpirabilidad y antimanchas, pero sin ser impermeables. En la misma línea, se conocen tejidos con aspecto de piel curtida mediante el empleo de recubrimientos de PVC, pero sin la propiedad de transpirabilidad.They are also used today different fabrics that mimic the tanned skin or leather destined  to the decoration or footwear sector. However, despite that may have an appearance similar to that of the tissue object of the present invention, none of them also complies with the waterproof, breathability and anti-stain properties. So, items with skin-like appearance that have Breathability and anti-stain properties, but without being waterproof. In the same line, tissues with the appearance of tanned skin by using PVC coatings, but without Breathability property.

Para solventar estos problemas, la presente invención describe un procedimiento de fabricación de un tejido para su uso en el campo textil que, además del aspecto de piel curtida o cuero, posee las propiedades de impermeabilidad, transpirabilidad y antimanchas, las cuales se consiguen mediante tratamientos mecánicos y químicos del material sin necesidad de utilizar PVCs en su fabricación.To solve these problems, this invention describes a method of manufacturing a fabric for use in the textile field which, in addition to the appearance of skin tanned or leather, has the properties of impermeability, breathability and anti-stain, which are achieved by mechanical and chemical treatments of the material without the need for Use PVCs in its manufacture.

Descripción de la invenciónDescription of the invention

La presente invención trata del procedimiento de fabricación de un tejido que comprende al menos las fases de tejeduría de un material de partida, pre-acabado mecánico, acabado químico y acabado mecánico.The present invention deals with the process of  manufacture of a fabric comprising at least the phases of weaving of a starting material, pre-finished mechanical, chemical finish and mechanical finish.

Preferentemente, el tejido será fabricado en tela convencional plana y a un ancho determinado comprendido entre 1.40 y 3 metros, ambos valores incluidos.Preferably, the fabric will be manufactured in conventional flat fabric and at a certain width between 1.40 and 3 meters, both values included.

Tras la fase de tejeduría, el material es sometido a un proceso de pre-acabado mecánico. Este proceso se compone a su vez de dos pasos, el primero de Perchado, para sacar las fibras a la superficie del tejido, y la segunda de Tundosado, para igualar las fibras sacadas mediante un corte. De este modo, se consigue modificar el aspecto físico de la superficie del material con el fin de mejorar la adherencia del producto químico que se va a aplicar posteriormente.After the weaving phase, the material is subjected to a mechanical pre-finishing process. This process consists of two steps, the first one of Perchado, to pull the fibers to the surface of the tissue, and the second of Tundosado, to match the fibers removed by a cut. From this way, it is possible to modify the physical appearance of the surface of the material in order to improve product adhesion chemical to be applied later.

Así, en la fase del procedimiento que consiste en una operación de acabado químico, se aplica un recubrimiento en base acuosa con resinas sintéticas. Dichas resinas se componen preferentemente de una resina acrílica mezclada con resinas de poliuretano y fluorocarbono. El compuesto se deposita en la parte superficial del tejido para que se entremezcle con las fibras extraídas por medio de la operación de pre-acabado mecánico. En una realización preferente, se aplica una cantidad del compuesto entre 10-100 g/m^{2} (ambos límites inclusive).Thus, in the phase of the procedure that consists In a chemical finishing operation, a coating is applied on aqueous base with synthetic resins. These resins are composed preferably of an acrylic resin mixed with resins of polyurethane and fluorocarbon. The compound is deposited in the part surface of the tissue to intermingle with the fibers extracted through the pre-finishing operation mechanic. In a preferred embodiment, an amount of the compound between 10-100 g / m2 (both limits inclusive).

Una vez realizado el recubrimiento químico, el tejido se somete de nuevo a un proceso de acabado mecánico, esta vez de compactación del material recubierto empleando para ello una calandra de presión y calor, con lo que se modifica de nuevo la superficie y aspecto del tejido compactando las fibras superficiales extraídas en el proceso de perchado y recubiertas con la base acuosa con resinas sintéticas, dándole un brillo y apariencia especial. Este proceso de calandrado puede incluir la realización de diferentes diseños para imitar más aún si cabe la piel curtida o el cuero.Once the chemical coating is done, the fabric is subjected again to a mechanical finishing process, this instead of compacting the coated material using a pressure and heat calender, thereby modifying the tissue surface and appearance compacting the fibers surface extracted in the perching process and coated with the aqueous base with synthetic resins, giving it a shine and special appearance This calendering process may include the realization of different designs to imitate even more if it fits the Tanned skin or leather.

En una realización preferente, estos diseños se realizarán mediante un cilindro gofrado. En otra realización preferente, los diseños que imitan la piel curtida o el cuero se realizarán mediante un papel gofrado.In a preferred embodiment, these designs are They will be made using an embossed cylinder. In another embodiment Preferably, designs that mimic tanned skin or leather are They will make using embossed paper.

La invención concierne también al tejido fabricado a partir de este procedimiento, y que está especialmente concebido para su aplicación en el campo textil, como puede ser el sector de la decoración y el calzado, entre otros.The invention also concerns the fabric manufactured from this procedure, and that is especially designed for application in the textile field, such as the decoration and footwear sector, among others.

El tejido que la invención propone posee el aspecto de la piel curtida o el cuero, así como las propiedades de impermeabilidad, transpirabilidad y anti-mancha, consiguiéndose dicho aspecto y propiedades mediante los procesos mecánicos y químicos implicados en su fabricación.The fabric proposed by the invention has the appearance of tanned skin or leather, as well as the properties of impermeability, breathability and anti-stain, achieving this aspect and properties through the processes mechanics and chemists involved in its manufacture.

La invención también consiste en un artículo textil que comprende total o parcialmente el tejido objeto de la presente invención.The invention also consists of an article textile that comprises all or part of the fabric object of the present invention

Claims (13)

1. Procedimiento de fabricación de un tejido con aspecto de piel curtida o cuero y con propiedades de impermeabilidad, transpirabilidad y antimanchas, caracterizado porque comprende al menos las fases de tejeduría de un material de partida, pre-acabado mecánico, acabado químico y acabado mecánico.1. Procedure for manufacturing a fabric with the appearance of tanned leather or leather and with impermeability, breathability and anti-stain properties, characterized in that it comprises at least the weaving phases of a starting material, mechanical pre-finishing, chemical finishing and mechanical finishing . 2. Procedimiento según la reivindicación 1, caracterizado porque dicha operación de pre-acabado mecánico consiste en una primera fase de Perchado y una segunda fase de Tundosado.2. Method according to claim 1, characterized in that said mechanical pre-finishing operation consists of a first phase of Perchado and a second phase of Tundosado. 3. Procedimiento según la reivindicación 1, caracterizado porque dicha fase de acabado químico consiste en recubrir la parte superficial del material mediante una base acuosa con resinas sintéticas.3. Method according to claim 1, characterized in that said chemical finishing phase consists in coating the surface part of the material by means of an aqueous base with synthetic resins. 4. Procedimiento según la reivindicación 3, caracterizado porque dichas resinas sintéticas se componen de una resina acrílica mezclada con resinas de poliuretano y fluorocarbono.4. Method according to claim 3, characterized in that said synthetic resins are composed of an acrylic resin mixed with polyurethane and fluorocarbon resins. 5. Procedimiento según cualquiera de las reivindicaciones 3 ó 4, caracterizado porque la cantidad de mezcla de la base acuosa y las resinas depositada está comprendida entre 10-100 g/m^{2} (ambos límites inclusive).5. Method according to any of claims 3 or 4, characterized in that the amount of mixture of the aqueous base and the resins deposited is between 10-100 g / m2 (both limits inclusive). 6. Procedimiento según la reivindicación 1, caracterizado porque la fase de acabado mecánico consiste en someter al tejido recubierto en la fase de acabado químico a un proceso de calandrado, mediante una calandra de presión y calor.Method according to claim 1, characterized in that the mechanical finishing phase consists in subjecting the coated fabric in the chemical finishing phase to a calendering process, by means of a pressure and heat calender. 7. Procedimiento según la reivindicación 6, caracterizado porque en dicha fase de calandrado se realizan diseños para mejorar la imitación de la piel curtida o cuero.7. Method according to claim 6, characterized in that in said calendering phase designs are made to improve the imitation of the tanned skin or leather. 8. Procedimiento según la reivindicación 7, caracterizado porque dichos diseños se realizan mediante un cilindro gofrado.Method according to claim 7, characterized in that said designs are made by means of an embossed cylinder. 9. Procedimiento según la reivindicación 7, caracterizado porque dichos diseños se realizan mediante un papel gofrado.9. Method according to claim 7, characterized in that said designs are made by embossing paper. 10. Tejido fabricado mediante el procedimiento descrito en cualquiera de las reivindicaciones anteriores.10. Fabric manufactured by the procedure described in any of the preceding claims. 11. Uso del tejido descrito según la reivindicación 10, para la fabricación de artículos en el mercado textil.11. Use of the tissue described according to claim 10, for the manufacture of items in the market textile. 12. Uso del tejido según la reivindicación 11, caracterizado porque se engloba en el sector de la decoración y el calzado.12. Use of the fabric according to claim 11, characterized in that it is included in the decoration and footwear sector. 13. Artículo textil, caracterizado por comprender total o parcialmente un tejido según la reivindicación 10.13. Textile article, characterized by fully or partially comprising a fabric according to claim 10.
ES200702706A 2007-10-16 2007-10-16 PROCEDURE FOR OBTAINING A FABRIC WITH ASPECT OF CURED SKIN OR LEATHER, FABRIC OBTAINED FROM IT AND ITS USE. Expired - Fee Related ES2319065B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES200702706A ES2319065B1 (en) 2007-10-16 2007-10-16 PROCEDURE FOR OBTAINING A FABRIC WITH ASPECT OF CURED SKIN OR LEATHER, FABRIC OBTAINED FROM IT AND ITS USE.
PCT/ES2008/000606 WO2009050312A1 (en) 2007-10-16 2008-09-25 Method for producing a fabric with the appearance of tanned hide or leather, fabric produced and use thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200702706A ES2319065B1 (en) 2007-10-16 2007-10-16 PROCEDURE FOR OBTAINING A FABRIC WITH ASPECT OF CURED SKIN OR LEATHER, FABRIC OBTAINED FROM IT AND ITS USE.

Publications (2)

Publication Number Publication Date
ES2319065A1 true ES2319065A1 (en) 2009-05-01
ES2319065B1 ES2319065B1 (en) 2010-02-11

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ES200702706A Expired - Fee Related ES2319065B1 (en) 2007-10-16 2007-10-16 PROCEDURE FOR OBTAINING A FABRIC WITH ASPECT OF CURED SKIN OR LEATHER, FABRIC OBTAINED FROM IT AND ITS USE.

Country Status (2)

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ES (1) ES2319065B1 (en)
WO (1) WO2009050312A1 (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989008553A1 (en) * 1988-03-14 1989-09-21 Sili-Tex, Inc. Silicone polymer fiber encapsulated webs
US5271998A (en) * 1992-06-04 1993-12-21 Precision Fabrics Group, Inc. Lightweight metalized fabric
JP2000336348A (en) * 1999-05-28 2000-12-05 Kuraray Co Ltd Method for producing sheet product having water / oil repellency
WO2002070810A2 (en) * 2001-03-06 2002-09-12 Interface, Inc. Moisture barrier fabric and methods of making same
WO2004007832A1 (en) * 2002-07-11 2004-01-22 Viktor Achter Gmbh & Co. Kg Textile substrate with polymer foam coating
ES2246787T3 (en) * 1999-09-30 2006-03-01 Ciba Spezialitatenchemie Pfersee Gmbh COMPOSITION FOR FINISHING REPELLENT TO OIL AND WATER FIBER-BASED MATERIALS.

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989008553A1 (en) * 1988-03-14 1989-09-21 Sili-Tex, Inc. Silicone polymer fiber encapsulated webs
US5271998A (en) * 1992-06-04 1993-12-21 Precision Fabrics Group, Inc. Lightweight metalized fabric
JP2000336348A (en) * 1999-05-28 2000-12-05 Kuraray Co Ltd Method for producing sheet product having water / oil repellency
ES2246787T3 (en) * 1999-09-30 2006-03-01 Ciba Spezialitatenchemie Pfersee Gmbh COMPOSITION FOR FINISHING REPELLENT TO OIL AND WATER FIBER-BASED MATERIALS.
WO2002070810A2 (en) * 2001-03-06 2002-09-12 Interface, Inc. Moisture barrier fabric and methods of making same
WO2004007832A1 (en) * 2002-07-11 2004-01-22 Viktor Achter Gmbh & Co. Kg Textile substrate with polymer foam coating

Also Published As

Publication number Publication date
ES2319065B1 (en) 2010-02-11
WO2009050312A1 (en) 2009-04-23

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