ES2184996T3 - Estructura multicapa, que comprende una capa fijadora del oxigeno y una capa neutralizadora de los subproductos y envase que comprende esta estructura. - Google Patents
Estructura multicapa, que comprende una capa fijadora del oxigeno y una capa neutralizadora de los subproductos y envase que comprende esta estructura.Info
- Publication number
- ES2184996T3 ES2184996T3 ES97908833T ES97908833T ES2184996T3 ES 2184996 T3 ES2184996 T3 ES 2184996T3 ES 97908833 T ES97908833 T ES 97908833T ES 97908833 T ES97908833 T ES 97908833T ES 2184996 T3 ES2184996 T3 ES 2184996T3
- Authority
- ES
- Spain
- Prior art keywords
- layer
- oxygen
- subproducts
- packaging
- understands
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title abstract 7
- 229910052760 oxygen Inorganic materials 0.000 title abstract 7
- 239000001301 oxygen Substances 0.000 title abstract 7
- 238000004806 packaging method and process Methods 0.000 title abstract 3
- 230000003472 neutralizing effect Effects 0.000 title abstract 2
- 239000000463 material Substances 0.000 abstract 3
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 230000004888 barrier function Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 238000012856 packing Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B2/00—Preservation of foods or foodstuffs, in general
- A23B2/70—Preservation of foods or foodstuffs, in general by treatment with chemicals
- A23B2/704—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
- A23B2/708—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O
- A23B2/712—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O in which an absorbent is placed or used
- A23B2/717—Oxygen absorbent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
- B32B2307/7244—Oxygen barrier
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2311/00—Metals, their alloys or their compounds
- B32B2311/24—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/70—Food packaging
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1355—Elemental metal containing [e.g., substrate, foil, film, coating, etc.]
- Y10T428/1359—Three or more layers [continuous layer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1379—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
- Y10T428/1383—Vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit is sandwiched between layers [continuous layer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
- Y10T428/31696—Including polyene monomers [e.g., butadiene, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31913—Monoolefin polymer
- Y10T428/3192—Next to vinyl or vinylidene chloride polymer
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Zoology (AREA)
- Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Wood Science & Technology (AREA)
- Packages (AREA)
- Wrappers (AREA)
- Laminated Bodies (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Gas Separation By Absorption (AREA)
Abstract
LA INVENCION SE REFIERE A UN SISTEMA UTIL PARA LA CAPTURA DE OXIGENO, QUE COMPRENDE AL MENOS DOS COMPONENTES, ES DECIR, UN MATERIAL CAPTADOR DE OXIGENO QUE FORMA AL MENOS UN SUBPRODUCTO DURANTE LA REACCION DEL MISMO CON OXIGENO, Y UNA CANTIDAD EFECTIVA DE UN MATERIAL NEUTRALIZANTE, CAPAZ DE NEUTRALIZAR AL MENOS UNA PARTE DE DICHOS SUBPRODUCTOS. EN UNA APLICACION PREFERIDA DE LA INVENCION, UNA ESTRUCTURA MULTICAPA QUE SE PUEDE EMPLEAR EN LA PRODUCCION DE EMBALAJES Y ESPECIALMENTE EMBALAJES ALIMENTARIOS, COMPRENDE UNA PRIMERA CAPA QUE INCLUYE UN MATERIAL CAPTADOR DE OXIGENOY UNA SEGUNDA CAPA QUE INCLUYE UN MATERIAL CAPAZ DE NEUTRALIZAR AL MENOS UNA PARTE DE LOS SUBPRODUCTOS PRODUCIDOS POR LA OXIDACION DEL MATERIAL CAPTADOR DE OXIGENO CONTENIDO EN LA PRIMERA CAPA. DICHAS CAPAS ESTAN DISPUESTAS DE FORMA QUE, TRAS LA FORMULACION DEL EMBALAJE, LA SEGUNDA CAPA ES INTERIOR RESPECTO A LA PRIMERA. ADEMAS, LA PELICULA MULTICAPA PUEDE INCLUIR UNO O MAS ENTRE: UNA CAPA DE BARRERA DE OXIGENO; UNA CAPA DEBARRERA SELECTIVA POLIMERICA; Y UNA CAPA TERMOSELLABLE.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/612,510 US6057013A (en) | 1996-03-07 | 1996-03-07 | Oxygen scavenging system including a by-product neutralizing material |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2184996T3 true ES2184996T3 (es) | 2003-04-16 |
Family
ID=24453464
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES97908833T Expired - Lifetime ES2184996T3 (es) | 1996-03-07 | 1997-02-26 | Estructura multicapa, que comprende una capa fijadora del oxigeno y una capa neutralizadora de los subproductos y envase que comprende esta estructura. |
Country Status (13)
Country | Link |
---|---|
US (1) | US6057013A (es) |
EP (1) | EP0889781B1 (es) |
JP (1) | JP3306071B2 (es) |
CN (1) | CN1077497C (es) |
AT (1) | ATE225253T1 (es) |
AU (1) | AU721502B2 (es) |
BR (1) | BR9707824A (es) |
CA (1) | CA2247985C (es) |
DE (1) | DE69716047T2 (es) |
ES (1) | ES2184996T3 (es) |
NZ (1) | NZ331990A (es) |
RU (1) | RU2173265C2 (es) |
WO (1) | WO1997032722A1 (es) |
Families Citing this family (73)
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US5627239A (en) | 1993-07-13 | 1997-05-06 | Chevron Chemical Company | Compositions having ethylenic backbone and benzylic, allylic, or ether-containing side-chains, oxygen scavenging compositions containing same, and process for making these compositions by esterification or transesterification of a polymer melt |
ATE219507T1 (de) | 1996-03-07 | 2002-07-15 | Cryovac Inc | Selektive barriere in sauerstoffaufnehmendem film |
US6908652B1 (en) | 1996-09-18 | 2005-06-21 | Cryovac, Inc. | Poly(lactic acid) in oxygen scavenging article |
US6139770A (en) | 1997-05-16 | 2000-10-31 | Chevron Chemical Company Llc | Photoinitiators and oxygen scavenging compositions |
US7097890B1 (en) | 1998-07-31 | 2006-08-29 | Chevron Phillips Chemical Co. Lp | Polymer with pendent cyclic olefinic functions for oxygen scavenging packaging |
US6946175B2 (en) * | 1998-07-31 | 2005-09-20 | Chevron Phillips Chemical Co., Lp | Oxygen scavenging polymers as active barrier tie layers in multilayered structures |
US6333087B1 (en) | 1998-08-27 | 2001-12-25 | Chevron Chemical Company Llc | Oxygen scavenging packaging |
US6454965B1 (en) * | 1999-03-24 | 2002-09-24 | Chevron Phillips Chemical Company Lp | Oxygen scavenging polymers in rigid polyethylene terephthalate beverage and food containers |
BR0015106A (pt) | 1999-10-27 | 2002-07-16 | Coca Cola Co | Método de reduzir a quantidade de acetaldeìdo em uma bebida em um recipiente à base de poliéster e bebida engarrafada |
US6664320B1 (en) | 2000-02-22 | 2003-12-16 | Chevron Phillips Chemical Company Lp | Using solventless metal oleate in making metal masterbatch |
US6410807B1 (en) | 2000-05-10 | 2002-06-25 | Chevron Phillips Chemical Company Lp | Synthesis of cyclohexene dimethanol compounds |
US6525123B1 (en) | 2000-05-19 | 2003-02-25 | Chevron Phillips Chemical Company Lp | Compatible blend systems from ethylene vinyl alcohol and oxygen scavenging polymers |
US7186464B2 (en) * | 2000-05-19 | 2007-03-06 | Chevron Phillips Chemical Co. Lp | Compatible blend systems of oxygen barrier polymers and oxygen scavenging polymers |
US7026417B2 (en) * | 2000-05-19 | 2006-04-11 | Chevron Phillips Chemical Co., Lp | Enhanced oxygen barrier performance from modification of vinyl alcohol polymers (PVOH) or ethylene vinyl alcohol copolymers (EVOH) |
US7247390B1 (en) | 2000-05-19 | 2007-07-24 | Chevron Phillips Chemical Company, Lp | Compatible blend systems of oxygen barrier polymers and oxygen scavenging polymers |
US20020022144A1 (en) | 2000-05-19 | 2002-02-21 | Hu Yang | Enhanced oxygen barrier performance from modification of ethylene vinyl alcohol copolymers (EVOH) |
JP2002035579A (ja) * | 2000-07-24 | 2002-02-05 | Mitsubishi Gas Chem Co Inc | 水蒸気を吸収する脱酸素剤組成物 |
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US6437086B1 (en) | 2000-10-05 | 2002-08-20 | Chevron Phillips Chemical Company Lp | Non-extractable polymeric metal salt useful in catalyzing oxygen scavenging |
US6610215B1 (en) | 2000-10-16 | 2003-08-26 | Chevron Phillips Chemical Co., Lp | Oxygen scavenging compositions suitable for heat triggering |
US6517776B1 (en) | 2000-11-03 | 2003-02-11 | Chevron Phillips Chemical Company Lp | UV oxygen scavenging initiation in angular preformed packaging articles |
US6572783B1 (en) | 2000-11-27 | 2003-06-03 | Chevron Phillips Chemical Company Lp | Vinyl crosslinked oxygen scavenging compositions and methods of preparing the same |
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US6818150B2 (en) * | 2000-12-22 | 2004-11-16 | Chevron Phillips Chemical Company Lp | UV- or heat-triggered low oxygen packaging system employing an oxidizable polymer resin and a peroxide |
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US6746622B2 (en) * | 2002-02-08 | 2004-06-08 | Chevron Phillips Chemical Company Lp | Oxygen scavenging compositions comprising polymers derived from tetrahydrofurfuryl monomers |
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JPH0649354B2 (ja) * | 1989-07-10 | 1994-06-29 | 東洋製罐株式会社 | プラスチック多層容器 |
MY106642A (en) * | 1989-10-23 | 1995-07-31 | Mitsubishi Gas Chemical Co | Inhibitor parcel and method for preserving electronic devices or electronic parts. |
MY106162A (en) * | 1990-04-25 | 1995-03-31 | Mitsubishi Gas Chemical Co | Oxygen absorbent composition and method of preserving article with same. |
CA2043301C (en) * | 1990-07-03 | 1996-06-18 | Jeffrey Michael Schuetz | Deodorized multilayer film with vinylidene chloride copolymer barrier |
CA2062083C (en) * | 1991-04-02 | 2002-03-26 | Drew Ve Speer | Compositions, articles and methods for scavenging oxygen |
US5364555A (en) * | 1991-04-30 | 1994-11-15 | Advanced Oxygen Technologies, Inc. | Polymer compositions containing salicylic acid chelates as oxygen scavengers |
US5211875A (en) * | 1991-06-27 | 1993-05-18 | W. R. Grace & Co.-Conn. | Methods and compositions for oxygen scavenging |
EP0526977A2 (en) * | 1991-07-03 | 1993-02-10 | E.I. Du Pont De Nemours And Company | Novel packaging compositions that extend shelf life of oil-containing foods |
JPH05247276A (ja) * | 1992-03-04 | 1993-09-24 | Toppan Printing Co Ltd | 酸素バリアー性樹脂組成物 |
US5258233A (en) * | 1992-04-02 | 1993-11-02 | Eastman Kodak Company | Polyester/polyamide blend having improved flavor retaining property and clarity |
JPH0623925A (ja) * | 1992-07-06 | 1994-02-01 | Mitsubishi Kasei Corp | 包装用フィルム |
US5284892A (en) * | 1992-11-10 | 1994-02-08 | E. I. Du Pont De Nemours And Company | Aldehyde scavenging compositions and methods relating thereto |
JP2699814B2 (ja) * | 1993-08-06 | 1998-01-19 | 東洋製罐株式会社 | フレーバー保持性に優れたプラスチック多層容器及び米飯包装体 |
JP3630706B2 (ja) * | 1993-09-01 | 2005-03-23 | 東洋製罐株式会社 | 内容物保存性に優れたプラスチック多層容器 |
US5744246A (en) * | 1994-09-19 | 1998-04-28 | Chevron Chemical Company | Oxygen scavenging ribbons and articles employing the same |
CA2165709A1 (en) * | 1994-12-27 | 1996-06-28 | Tadatoshi Ogawa | Oxygen absorber |
US5660761A (en) * | 1995-02-15 | 1997-08-26 | Chevron Chemical Company | Multi-component oxygen scavenger system useful in film packaging |
-
1996
- 1996-03-07 US US08/612,510 patent/US6057013A/en not_active Expired - Lifetime
-
1997
- 1997-02-26 EP EP97908833A patent/EP0889781B1/en not_active Expired - Lifetime
- 1997-02-26 ES ES97908833T patent/ES2184996T3/es not_active Expired - Lifetime
- 1997-02-26 CN CN97193528A patent/CN1077497C/zh not_active Expired - Lifetime
- 1997-02-26 AT AT97908833T patent/ATE225253T1/de not_active IP Right Cessation
- 1997-02-26 JP JP53187897A patent/JP3306071B2/ja not_active Expired - Lifetime
- 1997-02-26 BR BR9707824A patent/BR9707824A/pt not_active Application Discontinuation
- 1997-02-26 AU AU20644/97A patent/AU721502B2/en not_active Expired
- 1997-02-26 RU RU98118255/04A patent/RU2173265C2/ru not_active IP Right Cessation
- 1997-02-26 DE DE69716047T patent/DE69716047T2/de not_active Expired - Lifetime
- 1997-02-26 WO PCT/US1997/003307 patent/WO1997032722A1/en active IP Right Grant
- 1997-02-26 CA CA002247985A patent/CA2247985C/en not_active Expired - Lifetime
- 1997-02-26 NZ NZ331990A patent/NZ331990A/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
WO1997032722A1 (en) | 1997-09-12 |
US6057013A (en) | 2000-05-02 |
CA2247985C (en) | 2004-07-20 |
EP0889781A1 (en) | 1999-01-13 |
ATE225253T1 (de) | 2002-10-15 |
HK1017637A1 (en) | 1999-11-26 |
CA2247985A1 (en) | 1997-09-12 |
AU721502B2 (en) | 2000-07-06 |
EP0889781B1 (en) | 2002-10-02 |
NZ331990A (en) | 2000-02-28 |
JP3306071B2 (ja) | 2002-07-24 |
CN1077497C (zh) | 2002-01-09 |
BR9707824A (pt) | 1999-07-27 |
RU2173265C2 (ru) | 2001-09-10 |
DE69716047T2 (de) | 2003-02-06 |
AU2064497A (en) | 1997-09-22 |
JP2000506087A (ja) | 2000-05-23 |
CN1215368A (zh) | 1999-04-28 |
DE69716047D1 (de) | 2002-11-07 |
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