ES2169543T3 - Revestimiento antiadherente resistente a la temperatura elevada y a los arañazos. - Google Patents
Revestimiento antiadherente resistente a la temperatura elevada y a los arañazos.Info
- Publication number
- ES2169543T3 ES2169543T3 ES98940130T ES98940130T ES2169543T3 ES 2169543 T3 ES2169543 T3 ES 2169543T3 ES 98940130 T ES98940130 T ES 98940130T ES 98940130 T ES98940130 T ES 98940130T ES 2169543 T3 ES2169543 T3 ES 2169543T3
- Authority
- ES
- Spain
- Prior art keywords
- surface coating
- carrier material
- substance
- inorganic
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000576 coating method Methods 0.000 title abstract 9
- 239000011248 coating agent Substances 0.000 title abstract 8
- 230000000181 anti-adherent effect Effects 0.000 title 1
- 239000003911 antiadherent Substances 0.000 title 1
- 239000012876 carrier material Substances 0.000 abstract 5
- 239000000126 substance Substances 0.000 abstract 4
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002052 molecular layer Substances 0.000 abstract 1
- 239000011368 organic material Substances 0.000 abstract 1
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J36/00—Parts, details or accessories of cooking-vessels
- A47J36/02—Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/495—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as oligomers or polymers
- C04B41/4961—Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones"
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/82—Coating or impregnation with organic materials
- C04B41/84—Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
- C23D13/00—After-treatment of the enamelled articles
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00965—Uses not provided for elsewhere in C04B2111/00 for household applications, e.g. use of materials as cooking ware
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/203—Oil-proof or grease-repellant materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Food Science & Technology (AREA)
- Composite Materials (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Glass (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Glass Compositions (AREA)
- Constitution Of High-Frequency Heating (AREA)
- Baking, Grill, Roasting (AREA)
- Cookers (AREA)
Abstract
LA INVENCION SE REFIERE A UN MATERIAL DE SOPORTE QUE TIENE UNA ESTRUCTURA MOLECULAR INORGANICA Y UN REVESTIMIENTO SUPERFICIAL PRODUCIDO POR APLICACION DE UNA SUSTANCIA Y POR TRATAMIENTO TERMICO. LA INVENCION SE REFIERE IGUALMENTE A UN PROCEDIMIENTO PARA LA PRODUCCION Y LOS USOS APROPIADOS DE DICHO REVESTIMIENTO SUPERFICIAL. LOS MATERIALES DE SOPORTE REALIZADOS DE CRISTAL, METAL O CERAMICA DEBEN RECIBIR UN REVESTIMIENTO SUPERFICIAL CON PROPIEDADES ANTI-ADHERENTES, CONTRA MATERIALES ORGANICOS A BASE DE AGUA Y/O A BASE DE ACEITE O EMULSIONES DEL TIPO "AGUA EN ACEITE", AL TIEMPO QUE MUESTRAN BASICAMENTE MEJORES CARACTERISTICAS DE RESISTENCIA A LA TEMPERATURA Y A LAS RAYADURAS QUE LOS REVESTIMIENTOS CONVENCIONALES A BASE DE PTFE O SILICONA. ESTOS REQUISITOS LOS CUMPLE UN REVESTIMIENTO SUPERFICIAL SEGUN LA INVENCION QUE CONSISTE EN UNA COMBINACION DE MOLECULAS INORGANICAS DEL MATERIAL DE SOPORTE Y MOLECULAS ORGANICAS DE UNA SUSTANCIA APLICADA SOBRE LA CAPA MOLECULAR SUPERIOR DE DICHO REVESTIMIENTO. CON EL FIN DE PRODUCIR DICHA SUPERFICIE, SE APLICA INICIALMENTE UNA SUSTANCIA INORGANICA CON REDES DEL TIPO DE LA SILICONA. POSTERIORMENTE, SE REALIZA UN TRATAMIENTO TERMICO, POR EL QUE SE ELIGEN LA TEMPERATURA Y LA DURACION DE DICHO TRATAMIENTO, DE MANERA QUE EL REVESTIMIENTO PURAMENTE ORGANICO APLICADO SE DESCOMPONE TOTALMENTE Y/O SE RETIRA, DE MANERA QUE SE FORMA UNA COMBINACION DE MOLECULAS INORGANICAS DEL MATERIAL DE SOPORTE Y DE MOLECULAS ORGANICAS DE LA SUSTANCIA APLICADA. LOS MATERIALES DE SOPORTE APROPIADOS JUNTO CON EL REVESTIMIENTO SUPERFICIAL DE LA INVENCION PUEDEN UTILIZARSE VENTAJOSAMENTE SOBRE TODO EN ELECTRODOMESTICOS Y UTENSILIOS DE COCINA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19728813 | 1997-07-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2169543T3 true ES2169543T3 (es) | 2002-07-01 |
Family
ID=7834791
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES98940130T Expired - Lifetime ES2169543T3 (es) | 1997-07-05 | 1998-07-03 | Revestimiento antiadherente resistente a la temperatura elevada y a los arañazos. |
Country Status (8)
Country | Link |
---|---|
US (1) | US6372290B1 (es) |
EP (1) | EP0937012B1 (es) |
JP (1) | JP2001500928A (es) |
AT (1) | ATE210098T1 (es) |
CA (1) | CA2264944A1 (es) |
DE (2) | DE59802320D1 (es) |
ES (1) | ES2169543T3 (es) |
WO (1) | WO1999002463A1 (es) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19920493C2 (de) * | 1999-05-05 | 2002-07-18 | Schott Glas | Zubehörteile von Backöfen und darin verwendbare Geschirre |
KR100373520B1 (ko) * | 2000-07-19 | 2003-02-25 | 비멕 주식회사 | 스테인레스 외장판넬 및 그 제조방법 |
DE20102410U1 (de) | 2001-02-12 | 2001-04-26 | BSH Bosch und Siemens Hausgeräte GmbH, 81669 München | Haushaltsgerät mit von Wrasen angeströmten beschichteten Teilen |
EP1397319A1 (de) * | 2001-05-18 | 2004-03-17 | Schott Glas | Leicht reinigbare beschichtung |
US7211329B2 (en) * | 2001-05-18 | 2007-05-01 | Schott Ag | Process for making a product with a long-lasting easily cleaned surface and product thereof |
DE20206239U1 (de) | 2002-04-19 | 2002-09-19 | Armacell Enterprise GmbH, 48153 Münster | Ummantelung für Isolierungen aus Edelstahlblech |
DE10223665B4 (de) | 2002-05-28 | 2004-04-08 | Nexpress Solutions Llc | Einrichtung und Verfahren zum Reinigen von Mikrowelleneinrichtungen |
DE10236728A1 (de) | 2002-08-09 | 2004-02-26 | Schott Glas | Reinigungsfreundliche Vorrichtung |
US20040209072A1 (en) * | 2002-08-09 | 2004-10-21 | Inka Henze | Cleaning-friendly article with an easily cleanable, heat-resistant surface coating |
DE102004027717A1 (de) * | 2004-06-07 | 2005-12-22 | Accuride International Gmbh | Beschichtete Teleskopschiene |
JP4517761B2 (ja) * | 2004-07-30 | 2010-08-04 | パナソニック株式会社 | 耐熱防汚基板およびこれを用いた加熱調理機器 |
DE102004041007B4 (de) * | 2004-08-16 | 2013-10-17 | E.G.O. Elektro-Gerätebau GmbH | Kochfeldplatte sowie Kochfeld mit einer solchen Kochfeldplatte |
US7547463B2 (en) * | 2005-07-07 | 2009-06-16 | Novelis Inc. | Method of imparting non-stick property to metal surface |
US20070147049A1 (en) * | 2005-12-27 | 2007-06-28 | Collins Byron R | Leveling of reflector |
KR101307752B1 (ko) | 2006-10-10 | 2013-09-11 | 엘지전자 주식회사 | 조리기기 및 그 청소방법 |
KR101295565B1 (ko) * | 2006-10-10 | 2013-08-09 | 엘지전자 주식회사 | 조리기기 및 그 제작방법 |
DE102008041002A1 (de) * | 2008-08-05 | 2010-02-11 | BSH Bosch und Siemens Hausgeräte GmbH | Dunstabzugsvorrichtung sowie Verfahren zur Herstellung einer solchen Dunstabzugsvorrichtung |
KR101104680B1 (ko) * | 2009-07-23 | 2012-01-13 | (주) 더몰론코리아 | 난스틱 세라믹 코팅층을 구비한 법랑재 가열조리기구 |
ES2613885T3 (es) | 2009-11-04 | 2017-05-26 | Ssw Holding Company, Inc. | Superficies de aparatos de cocción que tienen un patrón de confinamiento de salpicaduras y procedimientos de fabricación de las mismas |
DE102010064187B4 (de) * | 2010-12-27 | 2019-03-14 | BSH Hausgeräte GmbH | Auszugssystem für Gargutträger eines Gargeräts |
DE102012103380A1 (de) | 2011-04-21 | 2012-10-25 | Paul Hettich Gmbh & Co. Kg | Metallisches Bauteil und Verfahren zur Oberflächenmodifikation eines beschichteten Bauteils |
ITMI20122261A1 (it) * | 2012-12-28 | 2014-06-29 | Indesit Co Spa | Processo di trattamento superficiale di acciaio inox |
DE102013209709A1 (de) | 2013-05-24 | 2014-11-27 | BSH Bosch und Siemens Hausgeräte GmbH | Beschichtung von gebrauchsoberflächen mit plasmapolymeren schichten unter atmosphärendruck zur verbesserung der reinigbarkeit |
JP5694583B2 (ja) * | 2014-03-03 | 2015-04-01 | 三菱電機株式会社 | 加熱調理器 |
WO2017190796A1 (en) * | 2016-05-06 | 2017-11-09 | Arcelik Anonim Sirketi | Cooking appliance with a microwave heating function |
DE102016124056A1 (de) | 2016-12-12 | 2018-06-14 | Miele & Cie. Kg | Dichtung für ein Gargerät |
DE102017211289A1 (de) | 2017-07-03 | 2019-01-03 | BSH Hausgeräte GmbH | Koch-, Brat-, Back- oder Grillgerät mit funktioneller Beschichtung, sowie Verfahren zur Erneuerung der Beschichtung |
DE102017223680A1 (de) | 2017-12-22 | 2019-06-27 | BSH Hausgeräte GmbH | Gegenstand mit einer hochtemperaturbeständigen omniphoben Antihaftbeschichtung, sowie Verfahren zur Herstellung des Gegenstands |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU524276B2 (en) * | 1980-03-05 | 1982-09-09 | Sharp K.K. | Silicone coating self-cleaning composition |
US5240774A (en) * | 1990-10-25 | 1993-08-31 | Matsushita Electric Industrial Co., Ltd. | Fluorocarbon-based coating film and method of manufacturing the same |
EP0492417B1 (en) * | 1990-12-21 | 1996-11-20 | Matsushita Electric Industrial Co., Ltd. | Method of manufacturing chemically adsorbed film |
US5435839A (en) * | 1992-12-24 | 1995-07-25 | Matsushita Electric Industrial Co., Ltd. | Finishing agents and method of manufacturing the same |
-
1998
- 1998-07-03 DE DE59802320T patent/DE59802320D1/de not_active Expired - Lifetime
- 1998-07-03 AT AT98940130T patent/ATE210098T1/de active
- 1998-07-03 DE DE19829676A patent/DE19829676A1/de not_active Withdrawn
- 1998-07-03 WO PCT/EP1998/004126 patent/WO1999002463A1/de active IP Right Grant
- 1998-07-03 EP EP98940130A patent/EP0937012B1/de not_active Expired - Lifetime
- 1998-07-03 ES ES98940130T patent/ES2169543T3/es not_active Expired - Lifetime
- 1998-07-03 CA CA002264944A patent/CA2264944A1/en not_active Abandoned
- 1998-07-03 JP JP11508106A patent/JP2001500928A/ja active Pending
- 1998-07-03 US US09/254,520 patent/US6372290B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0937012B1 (de) | 2001-12-05 |
EP0937012A1 (de) | 1999-08-25 |
JP2001500928A (ja) | 2001-01-23 |
DE59802320D1 (de) | 2002-01-17 |
US6372290B1 (en) | 2002-04-16 |
DE19829676A1 (de) | 1999-02-11 |
CA2264944A1 (en) | 1999-01-21 |
ATE210098T1 (de) | 2001-12-15 |
WO1999002463A1 (de) | 1999-01-21 |
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