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ES2136890T3 - Catalizadores carbocationicos y procedimiento para utilizar dichos catalizadores. - Google Patents

Catalizadores carbocationicos y procedimiento para utilizar dichos catalizadores.

Info

Publication number
ES2136890T3
ES2136890T3 ES95939811T ES95939811T ES2136890T3 ES 2136890 T3 ES2136890 T3 ES 2136890T3 ES 95939811 T ES95939811 T ES 95939811T ES 95939811 T ES95939811 T ES 95939811T ES 2136890 T3 ES2136890 T3 ES 2136890T3
Authority
ES
Spain
Prior art keywords
catalysts
carbocation
procedure
metilboro
halide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95939811T
Other languages
English (en)
Inventor
Timothy Daniel Shaffer
Maneesh Bahadur
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ES2136890T3 publication Critical patent/ES2136890T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)

Abstract

SE UTILIZA UNA COMPOSICION CARBOCATALIZADORA VIVA, QUE COMPRENDE UN INICIADOR CONSTITUIDO POR UN HALURO DE ALQUILO TERCIARIO, UN HALURO DE ARALQUILO TERCIARIO O UN HALURO POLIMERICO TERCIARIO, UN COINICIADOR DE UN COMPUESTO DE METILBORO O METILALUMINIO, Y UN MEDIO DISOLVENTE, CON UNA CONSTANTE DIELECTRICA ENTRE 2''5 Y 7, PARA PRODUCIR POLIMEROS CON UNA DISTRIBUCION DE PESO MOLECULAR REDUCIDA, ESPECIALMENTE POLIMEROS DE ISOBUTILENO.
ES95939811T 1994-11-07 1995-11-07 Catalizadores carbocationicos y procedimiento para utilizar dichos catalizadores. Expired - Lifetime ES2136890T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/335,011 US5506316A (en) 1993-02-19 1994-11-07 Carbocationic catalysts and process for using said catalysts

Publications (1)

Publication Number Publication Date
ES2136890T3 true ES2136890T3 (es) 1999-12-01

Family

ID=23309862

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95939811T Expired - Lifetime ES2136890T3 (es) 1994-11-07 1995-11-07 Catalizadores carbocationicos y procedimiento para utilizar dichos catalizadores.

Country Status (7)

Country Link
US (1) US5506316A (es)
EP (1) EP0791018B1 (es)
JP (1) JPH10508888A (es)
CA (1) CA2203693A1 (es)
DE (1) DE69511281T2 (es)
ES (1) ES2136890T3 (es)
WO (1) WO1996015156A2 (es)

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US6939933B2 (en) * 2000-12-20 2005-09-06 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
US6858690B2 (en) * 1999-11-15 2005-02-22 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
CA2390117A1 (en) 1999-11-15 2001-05-25 Exxon Chemical Patents, Inc. Production of isobutylene copolymers
US6906147B2 (en) * 2002-03-20 2005-06-14 Cyclics Corporation Catalytic systems
US7256241B2 (en) * 2000-01-21 2007-08-14 Cyclics Corporation Methods for polymerizing macrocyclic polyester oligomers using catalyst promoters
US7750109B2 (en) 2000-09-01 2010-07-06 Cyclics Corporation Use of a residual oligomer recyclate in the production of macrocyclic polyester oligomer
US7767781B2 (en) * 2000-09-01 2010-08-03 Cyclics Corporation Preparation of low-acid polyalkylene terephthalate and preparation of macrocyclic polyester oligomer therefrom
JP2004507599A (ja) * 2000-09-01 2004-03-11 サイクリクス　コーポレイション 線形ポリエステルを、大環状オリゴエステル組成物および大環状オリゴエステルに変換する方法
US6462131B1 (en) * 2000-10-16 2002-10-08 Exxonmobil Chemical Patents Inc. Polymer blend compatibilization using isobutylene-based block copolymers
US20060167184A1 (en) * 2000-10-18 2006-07-27 Waddell Walter H Innerliners for use in tires
WO2002050129A1 (en) * 2000-12-20 2002-06-27 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
US7304123B2 (en) * 2001-06-27 2007-12-04 Cyclics Corporation Processes for shaping macrocyclic oligoesters
US7071291B2 (en) * 2001-06-27 2006-07-04 Cyclics Corporation Isolation, formulation and shaping of macrocyclic oligoesters
US6787632B2 (en) * 2001-10-09 2004-09-07 Cyclics Corporation Organo-titanate catalysts for preparing pure macrocyclic oligoesters
JP4690195B2 (ja) * 2002-12-20 2011-06-01 エクソンモービル・ケミカル・パテンツ・インク 新しい配列分布を有するポリマー
US7196149B2 (en) * 2003-04-17 2007-03-27 The University Of Akron Polymerization of i-butane in hydrocarbon media using bis(borane) co-initiators
US7202317B2 (en) * 2003-04-17 2007-04-10 The University Of Akron Polymerization of i-butene in hydrocarbon media using bis(borane) co-initiators
US6969744B2 (en) * 2003-06-19 2005-11-29 University Of Southern Mississippi Living and quasiliving cationic telechelic polymers quenched by N-substituted pyrrole and methods for their preparation
EP1905581A1 (en) 2003-10-27 2008-04-02 ExxonMobil Chemical Patents Inc. Microlayered composites and processes for making the same
US7709580B2 (en) * 2004-08-20 2010-05-04 Chevron Oronite Company Llc Method for preparation of polylefins containing exo-olefin chain ends
US7705090B2 (en) * 2004-08-20 2010-04-27 Chevron Oronite Company Llc Method for preparing polyolefins containing a high percentage of exo-olefin chain ends
US8689846B2 (en) 2005-10-27 2014-04-08 The Yokohama Rubber Co., Ltd. Construction comprising tie layer
EP2502742B1 (en) 2005-10-27 2017-06-21 ExxonMobil Chemical Patents Inc. Construction comprising tie layer for pneumatic tire
US8013073B2 (en) * 2005-12-30 2011-09-06 Chevron Oronite Company Llc Method for preparing polyolefins containing vinylidine end groups using nonaromatic heterocyclic compounds
US7816459B2 (en) * 2005-12-30 2010-10-19 Chevron Oronite Company Llc Method for preparing polyolefins containing vinylidine end groups using polymeric nitrogen compounds
US7893176B2 (en) * 2007-03-23 2011-02-22 Exxonmobil Chemical Patents Inc. Polydispersity-controlled isoolefin polymerization with polymorphogenates
WO2008140875A1 (en) * 2007-05-16 2008-11-20 Exxonmobil Chemical Patents Inc. Catalyst system for olefin polymerization and polymers produced therefrom
US8394897B2 (en) * 2008-03-25 2013-03-12 Chevron Oronite Company Llc Production of vinylidene-terminated polyolefins via quenching with monosulfides
JP4435253B2 (ja) * 2008-03-26 2010-03-17 住友ゴム工業株式会社 インナーライナーおよび空気入りタイヤ
JP2010013647A (ja) * 2008-03-26 2010-01-21 Sumitomo Rubber Ind Ltd サイドウォール保護膜および空気入りタイヤ
US8063154B2 (en) 2008-06-24 2011-11-22 The University Of Southern Mississippi Preparation of exo-olefin terminated polyolefins via quenching with alkoxysilanes or ethers
JP5172597B2 (ja) * 2008-10-21 2013-03-27 株式会社カネカ 空気入りタイヤ用インナーライナー
US8133954B2 (en) 2008-10-22 2012-03-13 Chevron Oronite Company Llc Production of vinylidene-terminated and sulfide-terminated telechelic polyolefins via quenching with disulfides
US8344073B2 (en) 2009-01-16 2013-01-01 The University Of Southern Mississippi Functionalization of polyolefins with phenoxy derivatives
US8552122B2 (en) * 2009-03-31 2013-10-08 The University Of Southern Mississippi Amine-terminated telechelic polymers and precursors thereto and methods for their preparation
US8394898B2 (en) 2009-07-31 2013-03-12 The University Of Southern Mississippi In situ formation of hydroxy chain end functional polyolefins
JP4831706B2 (ja) 2009-09-04 2011-12-07 住友ゴム工業株式会社 ポリマー積層体およびそれをインナーライナーに用いた空気入りタイヤ
JP4888868B2 (ja) 2009-09-08 2012-02-29 住友ゴム工業株式会社 空気入りタイヤ
JP5004196B2 (ja) 2009-09-18 2012-08-22 住友ゴム工業株式会社 空気入りタイヤの製造方法
JP5300679B2 (ja) 2009-09-30 2013-09-25 住友ゴム工業株式会社 インナーライナー用ポリマー組成物およびそれを用いた空気入りタイヤ
JP5668079B2 (ja) 2009-12-17 2015-02-12 エクソンモービル・ケミカル・パテンツ・インク エラストマー性ナノ複合体、ナノ複合体組成物、及び製造方法
US8461240B2 (en) 2010-04-30 2013-06-11 Exxonmobil Chemical Patents Inc. Elastomeric nanocomposites, nanocomposite compositions, and methods of manufacture
SG184252A1 (en) 2010-04-30 2012-10-30 Exxonmobil Chem Patents Inc Method for elastomer finishing
US8242236B2 (en) 2010-05-26 2012-08-14 Exxonmobil Chemical Patents Inc. Elastomeric nanocomposite manufacturing
US8492491B2 (en) 2010-06-10 2013-07-23 Chevron Oronite Company Llc Methods for producing telechelic polyolefins from terpene initiators
US8592527B2 (en) 2010-06-14 2013-11-26 University Of Southern Mississippi Vinyl ether end-functionalized polyolefins
JP5247852B2 (ja) 2010-11-05 2013-07-24 住友ゴム工業株式会社 空気入りタイヤの製造方法
JP5225431B2 (ja) 2010-12-06 2013-07-03 住友ゴム工業株式会社 ストリップ、その製造方法および空気入りタイヤの製造方法
US9200152B2 (en) 2011-01-25 2015-12-01 Exxonmobil Chemical Patents Inc. Elastomeric nanocomposites, nanocomposite compositions, and methods of manufacture
US8969484B2 (en) 2011-07-08 2015-03-03 Chevron Oronite Company Llc Methods of producing mono- and multi-functional polymers from terpene-based initiators
US9108374B2 (en) 2011-10-05 2015-08-18 Exxonmobil Chemical Patents Inc. Tire curing bladders
WO2015130392A1 (en) 2014-02-28 2015-09-03 Exxonmobil Chemical Patents Inc. Nanocomposite mooney viscosity stability
US10781295B2 (en) 2014-02-28 2020-09-22 Exxonmobil Chemical Patents Inc. Mooney viscosity stable brominated elastomers
WO2016175938A1 (en) 2015-04-30 2016-11-03 Exxonmobil Chemical Patents Inc. System and process for halogenating olefinic-derived elastomers in the bulk phase
JP6596172B2 (ja) 2016-01-29 2019-10-23 エクソンモービル ケミカル パテンツ インコーポレイテッド 官能性オレフィンベースのポリマーの生成のためのシステム及び方法

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Also Published As

Publication number Publication date
JPH10508888A (ja) 1998-09-02
DE69511281T2 (de) 2000-04-13
EP0791018A2 (en) 1997-08-27
WO1996015156A2 (en) 1996-05-23
DE69511281D1 (de) 1999-09-09
US5506316A (en) 1996-04-09
CA2203693A1 (en) 1996-05-23
WO1996015156A3 (en) 1996-10-24
EP0791018B1 (en) 1999-08-04

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