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ES2128431T3 - Procedimiento para producir poli-alfa-olefinas con un sistema catalitico de metal de transicion de monociclopentadienilo. - Google Patents

Procedimiento para producir poli-alfa-olefinas con un sistema catalitico de metal de transicion de monociclopentadienilo.

Info

Publication number
ES2128431T3
ES2128431T3 ES93916743T ES93916743T ES2128431T3 ES 2128431 T3 ES2128431 T3 ES 2128431T3 ES 93916743 T ES93916743 T ES 93916743T ES 93916743 T ES93916743 T ES 93916743T ES 2128431 T3 ES2128431 T3 ES 2128431T3
Authority
ES
Spain
Prior art keywords
olefins
alpha
procedure
catalytic metal
metal system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93916743T
Other languages
English (en)
Inventor
Jo Ann Marie Canich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ES2128431T3 publication Critical patent/ES2128431T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

LA INVENCION ES UN PROCESO CATALIZADOR QUE UTILIZA UN COMPONENTE DE METAL DE TRANSICION DEL GRUPO IV B Y UN COMPONENTE ALUMOXANO PARA POLIMERIZAR LAS ALFAOLEFINAS Y PRODUCIR POLIALFAOLEFINAS AMORFAS.
ES93916743T 1993-06-24 1993-06-24 Procedimiento para producir poli-alfa-olefinas con un sistema catalitico de metal de transicion de monociclopentadienilo. Expired - Lifetime ES2128431T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1993/006051 WO1995000562A1 (en) 1993-06-24 1993-06-24 PROCESS FOR PRODUCING AMORPHOUS POLY-α-OLEFINS WITH A MONOCYCLOPENTADIENYL TRANSITION METAL CATALYST SYSTEM

Publications (1)

Publication Number Publication Date
ES2128431T3 true ES2128431T3 (es) 1999-05-16

Family

ID=22236720

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93916743T Expired - Lifetime ES2128431T3 (es) 1993-06-24 1993-06-24 Procedimiento para producir poli-alfa-olefinas con un sistema catalitico de metal de transicion de monociclopentadienilo.

Country Status (6)

Country Link
EP (1) EP0705283B1 (es)
JP (1) JPH08512063A (es)
CA (1) CA2166055C (es)
DE (1) DE69323096T2 (es)
ES (1) ES2128431T3 (es)
WO (1) WO1995000562A1 (es)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69607147T2 (de) * 1995-01-31 2000-09-28 Exxon Chemical Patents, Inc. Thermoplastische propylen-elastomere und verfahren zu ihrer herstellung und zwei katalysatoren in einem reaktor
EP0891991A3 (en) * 1995-03-01 1999-02-24 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borate complexes and catalysts derived therefrom
FI104825B (fi) 1996-01-26 2000-04-14 Borealis As Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
US6124488A (en) * 1996-05-03 2000-09-26 Dsm N.V. Cyclopentadiene compound substituted with branched alkyl groups
NL1003013C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Met cyclische groepen gesubstitueerde cyclopentadieenverbinding.
NL1003006C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Met vertakte alkylgroepen gesubstitueerde cyclopentadieenverbinding.
NL1003000C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Synthese van een amine-bevattend cyclopentadieen.
NL1003004C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Met onderling verschillende groepen gesubstitueerde cyclopentadieen- verbinding.
NL1003012C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Met aralkylgroepen gesubstitueerde cyclopentadieenverbinding.
US6117811A (en) * 1996-05-03 2000-09-12 Dsm N.V. Cyclopentadiene compound substituted with linear groups
KR19990067851A (ko) 1998-01-14 1999-08-25 고오사이 아끼오 올레핀 중합체, 올레핀 중합 촉매 및 올레핀 중합체의 제조 방법
JP3533923B2 (ja) 1998-01-28 2004-06-07 住友化学工業株式会社 オレフィン重合体、オレフィン重合用触媒およびオレフィン重合体の製造方法
BR9910387A (pt) 1998-07-02 2006-08-15 Montell Technology Company Bv processo para preparação de polìmeros alfa-olefinos substancialmente amorfos e composições contendo ele e processo para preparação de ligações em ponte, filme e artigos obtidos da composição
EP1010709A1 (en) * 1998-12-14 2000-06-21 Fina Research S.A. Metallocene compound and its use for polyolefin production
JP2001261737A (ja) * 2000-03-14 2001-09-26 Chisso Corp 耐熱性に優れた柔軟性ポリプロピレン
JP2005171139A (ja) * 2003-12-12 2005-06-30 Tonen Chem Corp 変性ポリプロピレン
US7872080B2 (en) 2008-03-06 2011-01-18 Sumitomo Chemical Company, Limited Processes for producing a catalyst component for addition polymerization, a catalyst and an addition polymer
JP2011213804A (ja) 2010-03-31 2011-10-27 Sumitomo Chemical Co Ltd 予備重合方法、予備重合済付加重合触媒成分およびそれを用いる付加重合体の製造方法
JP2013082891A (ja) 2011-09-28 2013-05-09 Sumitomo Chemical Co Ltd 洗浄方法、付加重合方法、予備重合方法、予備重合済付加重合触媒成分およびそれを用いる付加重合体の製造方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
WO1993012151A1 (en) * 1991-12-13 1993-06-24 Exxon Chemical Patents Inc. Ethylene/longer alpha-olefin copolymers
JPH07504934A (ja) * 1992-03-16 1995-06-01 エクソン・ケミカル・パテンツ・インク 制御されたタクチシティーのポリ‐α‐オレフィン製造用イオン触媒

Also Published As

Publication number Publication date
EP0705283A1 (en) 1996-04-10
WO1995000562A1 (en) 1995-01-05
EP0705283B1 (en) 1999-01-13
CA2166055C (en) 2006-10-17
DE69323096D1 (de) 1999-02-25
DE69323096T2 (de) 1999-08-05
JPH08512063A (ja) 1996-12-17
CA2166055A1 (en) 1995-01-05

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