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ES2087995T3 - Revestimiento para reversos de espejos. - Google Patents

Revestimiento para reversos de espejos.

Info

Publication number
ES2087995T3
ES2087995T3 ES91902057T ES91902057T ES2087995T3 ES 2087995 T3 ES2087995 T3 ES 2087995T3 ES 91902057 T ES91902057 T ES 91902057T ES 91902057 T ES91902057 T ES 91902057T ES 2087995 T3 ES2087995 T3 ES 2087995T3
Authority
ES
Spain
Prior art keywords
resin
metallic
layer
corrosion inhibitor
organic resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91902057T
Other languages
English (en)
Inventor
Timothy J Sanford
Joseph Soltys
Charles L Cesnik
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lilly Industries Inc
Original Assignee
Lilly Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/463,424 external-priority patent/US5075134A/en
Application filed by Lilly Industries Inc filed Critical Lilly Industries Inc
Application granted granted Critical
Publication of ES2087995T3 publication Critical patent/ES2087995T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/38Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal at least one coating being a coating of an organic material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/082Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/086Organic or non-macromolecular compounds
    • G02B1/105
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • G02B1/111Anti-reflection coatings using layers comprising organic materials
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Organic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Paints Or Removers (AREA)
  • Mirrors, Picture Frames, Photograph Stands, And Related Fastening Devices (AREA)
  • Laminated Bodies (AREA)
  • Light Receiving Elements (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Manufacturing Optical Record Carriers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

UNA COMPOSICION SIN PLOMO QUE PUEDE SER APLICADA COMO UNA PELICULA Y DE ENDURECERSE PARA FORMAR UNA CAPA PROTECTORA SOBRE LA PARTE POSTERIOR DE UN ESPEJO CONSTA DE UNA RESINA ORGANICA LIQUIDA Y DE UN INHIBIDOR DE LA CORROSION SELECCIONADO DEL GRUPO QUE CONSISTE EN DICIANDIAMIDA, SALES METALICAS O ACIDAS DE DICIANDIAMIDA, CIANAMIDA DE HIDROGENO Y 2-CIANOACETAMIDA. LA RESINA ORGANICA PUEDE SER CUALQUIER RESINA TERMOPLASTICA O TERMOFRAGUANTE APTA PARA RECUBRIR LAS CAPAS REFLECTORAS Y OTRAS CAPAS METALICAS DEL ESPEJO. LAS RESINAS QUE SE PUEDEN UTILIZAR SON, POR EJEMPLO, RESINAS ALQUILICAS, RESINAS ACRILICAS, RESINAS ALQUILICAS MODIFICADAS, POLIESTERES, ACEITES DE URETANO, POLIMEROS DE HALOGENURO DE VINILO O COPOLIMEROS, BARNICES OLEORESINOSOS, COMPOSICIONES DE NITROCELULOSA, BARNICES DE RESINA DE FORMALDEHIDO DE FENOL Y RESINAS DE EPOXI. PREFERENTEMENTE, LA RESINA ES UNA RESINA ALQUIDICA O UNA RESINA ALQUIDICA MODIFICADA. EL INHIBIDOR DE CORROSION ARRIBA MENCIONADO PUEDE ENCONTRARSE PRESENTE ENUNA CANTIDAD DE UN 0,1 A UN 20 POR CIENTO EN PESO APROXIMADAMENTE, PREFERIBLEMENTE DE UN 0,5 A UN 10 POR CIENTO EN PESO, DEL SISTEMA DE REVESTIMIENTO DE RESINA ORGANICA. EL SISTEMA DE RESINA NO DEBERIA CONTENER ESENCIALMENTE NI PLOMO NI SALES DE PLOMO. PARA INHIBIR LA CORROSION DE LAS CAPAS DE PELICULA METALICA QUE HAY EN LOS ESPEJOS, SE DEBERIA HACER UN ESPEJO QUE TUVIERA UNA CAPA DE SUSTRATO DE CRISTAL Y UNA CAPA DE PELICULA METALICA SOBRE LA MISMA, DESPUES DE LO CUAL SE APLICA EL SISTEMA DE RECUBRIMIENTO DE RESINA ORGANICA LIQUIDA, QUE CONTIENE EL INHIBIDOR DE CORROSION ANTES MENCIONADO, SOBRE LA CAPA DE PELICULA METALICA. DESPUES SE ENDURECE EL SISTEMA DE RECUBRIMIENTO DE RESINA ORGANICA PARA PRODUCIR LA CAPA DE REVESTIMIENTO PROTECTORA SOBRE LA CAPA METALICA. TAMBIEN SE PUEDEN PROTEGER OTROS ARTICULOS QUE TIENEN SUPERFICIES METALICAS CON EL SISTEMA DE RESINA QUE CONTIENE EL NUEVO INHIBIDOR DE CORROSION DE LA INVENCION.
ES91902057T 1990-01-11 1991-01-04 Revestimiento para reversos de espejos. Expired - Lifetime ES2087995T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/463,424 US5075134A (en) 1990-01-11 1990-01-11 Mirrorback coating
US07/626,461 US5094881A (en) 1990-01-11 1990-12-18 Mirrorback coating

Publications (1)

Publication Number Publication Date
ES2087995T3 true ES2087995T3 (es) 1996-08-01

Family

ID=27040648

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91902057T Expired - Lifetime ES2087995T3 (es) 1990-01-11 1991-01-04 Revestimiento para reversos de espejos.

Country Status (10)

Country Link
US (1) US5094881A (es)
EP (1) EP0471801B1 (es)
AT (1) ATE138899T1 (es)
AU (1) AU7161991A (es)
CA (2) CA2050923C (es)
DE (1) DE69119997T2 (es)
DK (1) DK0471801T3 (es)
ES (1) ES2087995T3 (es)
HK (1) HK1007553A1 (es)
WO (1) WO1991010563A1 (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5632810A (en) * 1991-09-04 1997-05-27 Sureguard, Inc. Pigmented mirror resin coatings
US5314532A (en) * 1991-09-04 1994-05-24 Sureguard, Inc. Soluble salt-free contaminant-free pigmented mirror coatings
DE69114142T2 (de) * 1991-12-24 1996-04-18 Fenzi Spa Antikorrosive Formulierung für die metallische Beschichtung auf Spiegeln und Gleichartigen und Verfahren zu deren Herstellung.
IT1254545B (it) * 1992-03-23 1995-09-25 Formulazione per la protezione alla corrosione di pellicole metalliche di specchi e simili e procedimento di produzione della stessa
DE4220546A1 (de) * 1992-06-24 1994-01-13 Lothar Kaesmacher Verfahren zur Herstellung eines Kunststoffspiegels, insbesondere als Bestandteil eines Behältnisses für kosmetische Produkte
DK0583871T3 (da) * 1992-07-11 1997-04-21 Pilkington Uk Ltd Fremgangsmåde til fremstilling af reflekterende belægninger på glas og spejle fremstillet derved
US5328753A (en) * 1992-10-30 1994-07-12 Ford Motor Company Glass sheets having painted exterior surfaces
US5487779A (en) * 1993-11-19 1996-01-30 Wayne Pigment Corp. Corrosion inhibiting pigment composition and method
US5558706A (en) * 1993-11-19 1996-09-24 Wayne Pigment Corp. Corrosion inhibiting pigment composition
US5419926A (en) * 1993-11-22 1995-05-30 Lilly London, Inc. Ammonia-free deposition of copper by disproportionation
GB9400321D0 (en) * 1994-01-10 1994-03-09 Pilkington Glass Ltd Coatings on glass
GB9400323D0 (en) * 1994-01-10 1994-03-09 Pilkington Glass Ltd Coatings on glass
GB9400320D0 (en) * 1994-01-10 1994-03-09 Pilkington Glass Ltd Coating on glass
GB9400319D0 (en) * 1994-01-10 1994-03-09 Pilkington Glass Ltd Coatings on glass
US6749307B2 (en) * 1994-05-12 2004-06-15 Glaverbel Silver coated mirror
GB9523674D0 (en) * 1995-11-20 1996-01-24 Glaverbel Method of forming a protective layer on a silver mirror
US5863611A (en) * 1997-05-27 1999-01-26 Lilly Industries (Usa), Inc. Iminodiacetonitrile mirror back coating corrosion inhibitor
US6979478B1 (en) 2002-08-01 2005-12-27 Hilemn, Llc Paint for silver film protection and method
EP1623964A1 (en) * 2004-08-05 2006-02-08 Ego 93, s.r.o. Reflective product and method of its production
EP1866154A1 (en) * 2005-03-24 2007-12-19 3M Innovative Properties Company Metallized films and articles containing the same
US20100143724A1 (en) * 2005-03-24 2010-06-10 Johnson Michael A Corrosion resistant metallized films and methods of making the same
WO2009128988A1 (en) * 2008-04-15 2009-10-22 Valspar Sourcing, Inc. Articles having improved corrosion resistance
CN113955949A (zh) * 2021-11-26 2022-01-21 杭州港盛卫浴有限公司 一种银镜的生产工艺

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2103538A (en) * 1934-11-22 1937-12-28 Bausch & Lomb Reflector
US2523626A (en) * 1948-08-20 1950-09-26 Albi Mfg Co Inc Fire-retardant composition and process
US2856818A (en) * 1954-07-27 1958-10-21 Ohio Plate Glass Company Protective mirror coating
US3909200A (en) * 1967-05-22 1975-09-30 Petrolite Corp Use of guanidine derived compounds as corrosion inhibitors
US3932296A (en) * 1973-05-29 1976-01-13 The Dow Chemical Company Corrosion inhibitor
JPS604565B2 (ja) * 1974-11-21 1985-02-05 富士写真フイルム株式会社 耐食性強磁性金属粉末
GB1449871A (en) * 1975-01-13 1976-09-15 Dow Corning Heat-curable organopolysiloxanes
US4133675A (en) * 1976-07-23 1979-01-09 Ciba-Geigy Corporation Pyridyloxy-phenoxy-alkanecarboxylic acid derivatives which are effective as herbicides and as agents regulating plant growth
JPS5518472A (en) * 1978-07-27 1980-02-08 Nitto Electric Ind Co Ltd Antisagging and anticorrosive material
JPS55100501A (en) * 1979-01-24 1980-07-31 Matsushita Electric Works Ltd Mirror plate
US4758638A (en) * 1982-06-10 1988-07-19 The Dow Chemical Company Advanced epoxy resins
JPS5962369A (ja) * 1982-09-30 1984-04-09 Nitto Electric Ind Co Ltd 鋼材の防食方法
US4670021A (en) * 1983-01-10 1987-06-02 Texaco Inc. Detergent and corrosion inhibiting additive and motor fuel composition containing same
US4780372A (en) * 1984-07-20 1988-10-25 The United States Of America As Represented By The United States Department Of Energy Silicon nitride protective coatings for silvered glass mirrors
US4645714A (en) * 1984-12-24 1987-02-24 Minnesota Mining And Manufacturing Company Corrosion-resistant silver mirror
US4707405A (en) * 1985-01-02 1987-11-17 Ppg Industries, Inc. Cyanamide salts of non-lead metals as corrosion inhibitive pigments in mirror back coatings
US4581422A (en) * 1985-05-06 1986-04-08 Texaco, Inc. Epoxy resin composition containing a curing agent which is a reaction product of cyanoguanidine, formaldehyde and an amine
US4666264A (en) * 1985-06-11 1987-05-19 Marui Industry Co., Ltd. Mirror using transparent synthetic resin plate
US4880668A (en) * 1986-03-27 1989-11-14 Ppg Industries, Inc. Mirror protective composition comprising 2-mercaptothiazoline
US4745003A (en) * 1986-12-22 1988-05-17 Ppg Industries, Inc. Method for improving durability of mirrors utilizing radiation curable coatings
JPH0726080B2 (ja) * 1987-11-30 1995-03-22 サンスター技研株式会社 高防錆性付与構造用接着剤
US4873139A (en) * 1988-03-29 1989-10-10 Minnesota Mining And Manufacturing Company Corrosion resistant silver and copper surfaces

Also Published As

Publication number Publication date
WO1991010563A1 (en) 1991-07-25
US5094881A (en) 1992-03-10
EP0471801B1 (en) 1996-06-05
EP0471801A1 (en) 1992-02-26
CA2093962A1 (en) 1991-07-12
CA2050923A1 (en) 1991-07-12
ATE138899T1 (de) 1996-06-15
AU7161991A (en) 1991-08-05
EP0471801A4 (en) 1992-07-01
HK1007553A1 (en) 1999-04-16
DE69119997D1 (de) 1996-07-11
CA2093962C (en) 1994-11-22
DK0471801T3 (da) 1996-06-24
CA2050923C (en) 1994-04-19
DE69119997T2 (de) 1996-10-24

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