ES2069083T3 - Metodo y aparato para un sistema de sustitucion de particulas en operacion durante el contacto en contracorriente de un gas y una corriente de alimentacion liquida con un lecho compacto. - Google Patents
Metodo y aparato para un sistema de sustitucion de particulas en operacion durante el contacto en contracorriente de un gas y una corriente de alimentacion liquida con un lecho compacto.Info
- Publication number
- ES2069083T3 ES2069083T3 ES90911055T ES90911055T ES2069083T3 ES 2069083 T3 ES2069083 T3 ES 2069083T3 ES 90911055 T ES90911055 T ES 90911055T ES 90911055 T ES90911055 T ES 90911055T ES 2069083 T3 ES2069083 T3 ES 2069083T3
- Authority
- ES
- Spain
- Prior art keywords
- gas
- liquid
- vessel
- catalyst
- plenum chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
- B01J8/12—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow
- B01J8/125—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow with multiple sections one above the other separated by distribution aids, e.g. reaction and regeneration sections
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1881—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving downwards while fluidised
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/002—Apparatus for fixed bed hydrotreatment processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/10—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 with moving solid particles
- C10G49/14—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 with moving solid particles according to the "moving-bed" technique
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00884—Means for supporting the bed of particles, e.g. grids, bars, perforated plates
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
ESTA INVENCION HACE POSIBLE UN FLUJO SUBSTANCIALMENTE CONTINUO DE HIDROGENO UNIFORMEMENTE DISTRIBUIDO Y UN HIDROCARBONO LIQUIDO A LO LARGO DE UN LECHO CATALIZADOR DENSAMENTE EMPAQUETADO PARA LLENAR SUBSTANCIALMENTE EL VOLUMEN COMPLETO DEL VASO (11) DE UN REACTOR INTRODUCIENDO GAS Y LIQUIDO A TRAVES DE ANILLOS ANULARES ALTERNOS (26 Y 27) A LO LARGO DEL AREA COMPLETA DEL LECHO EN UNA RELACION DE ALIMENTACION DE DISEÑO INSUFICIENTE PARA ELEVAR O AGITAR EL LECHO EMPAQUETADO QUE CONTIENE EL CATALIZADOR SELECCIONADO POR SU DENSIDAD, FORMA Y TAMAÑO. EN LA RELACION DE FLUJO DESEADA, EL CATALIZADOR SE INTRODUCE EN LA PARTE SUPERIOR DEL LECHO HACIENDOLO FLUIR LAMINARMENTE EN UNA CORRIENTE LIQUIDA SOBRE UNA BASE PERIODICA O SEMICONTINUA, DICHO CATALIZADOR FLUYE CONTINUAMENTE HACIA ABAJO A TRAVES DEL VASO. EL CATALIZADOR SE SEPARA DEL FONDO DEL LECHO DE FORMA SIMILAR, HACIENDO FLUIR LAMINARMENTE PARTICULAS CATALIZADORAS EN UNA CORRIENTE LIQUIDA. LA TOMA DEL FLUJO DE SALIDA DEL CATALIZADOR (32) ESTA FUERA DEL CONTACTO DIRECTO CON LA CORRIENTE DE GAS QUE FLUYE A TRAVES DEL LECHO. EL CAMINO DEL FLUJO DE SALIDA DEL CATALIZADOR ES SUBSTANCIALMENTE CONSTANTE EN SU AREA SECCIONAL Y ALGUNAS VECES MAYOR EN DIAMETRO QUE EL DIAMETRO DE LA PARTICULA CATALIZADORA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/381,948 US5076908A (en) | 1989-07-19 | 1989-07-19 | Method and apparatus for an on-stream particle replacement system for countercurrent contact of a gas and liquid feed stream with a packed bed |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2069083T3 true ES2069083T3 (es) | 1995-05-01 |
Family
ID=23506972
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES90911055T Expired - Lifetime ES2069083T3 (es) | 1989-07-19 | 1990-07-17 | Metodo y aparato para un sistema de sustitucion de particulas en operacion durante el contacto en contracorriente de un gas y una corriente de alimentacion liquida con un lecho compacto. |
Country Status (11)
Country | Link |
---|---|
US (3) | US5076908A (es) |
EP (1) | EP0441912B1 (es) |
JP (1) | JPH07119425B2 (es) |
CN (1) | CN1028111C (es) |
AT (1) | ATE118526T1 (es) |
CA (1) | CA1332496C (es) |
DE (1) | DE69017000T2 (es) |
DK (1) | DK0441912T3 (es) |
ES (1) | ES2069083T3 (es) |
MY (1) | MY105733A (es) |
WO (1) | WO1991001359A1 (es) |
Families Citing this family (72)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5472928A (en) * | 1989-07-19 | 1995-12-05 | Scheuerman; Georgieanna L. | Catalyst, method and apparatus for an on-stream particle replacement system for countercurrent contact of a gas and liquid feed stream with a packed bed |
US5492617A (en) * | 1989-07-19 | 1996-02-20 | Trimble; Harold J. | Apparatus and method for quenching in hydroprocessing of a hydrocarbon feed stream |
US5589057A (en) * | 1989-07-19 | 1996-12-31 | Chevron U.S.A. Inc. | Method for extending the life of hydroprocessing catalyst |
US5498327A (en) * | 1989-07-19 | 1996-03-12 | Stangeland; Bruce E. | Catalyst, method and apparatus for an on-stream particle replacement system for countercurrent contact of a gas and liquid feed stream with a packed bed |
US5916529A (en) * | 1989-07-19 | 1999-06-29 | Chevron U.S.A. Inc | Multistage moving-bed hydroprocessing reactor with separate catalyst addition and withdrawal systems for each stage, and method for hydroprocessing a hydrocarbon feed stream |
ES2077073T3 (es) * | 1990-07-17 | 1995-11-16 | Chevron Usa Inc | Procesamiento de hidrocarburos de una alimentacion que contiene gas en un lecho de catalizador que se mueve en contracorriente. |
FR2678944B1 (fr) * | 1991-07-10 | 1993-11-19 | Total Raffinage Distribution Sa | Procede et dispositif pour le remplacement en continu du catalyseur dans une unite a lit mobile. |
MY110356A (en) * | 1992-01-30 | 1998-04-30 | Shell Int Research | Process for upgrading a hydrocarbonaceous feedstock |
US5603904A (en) * | 1993-06-18 | 1997-02-18 | Chevron U.S.A. Inc. | Apparatus for catalyst replacement |
JP3431216B2 (ja) * | 1993-06-18 | 2003-07-28 | 千代田化工建設株式会社 | 触媒層支持構造 |
CN1134527C (zh) * | 1994-04-29 | 2004-01-14 | 切夫里昂美国公司 | 催化剂,用于连续颗粒置换体系的方法及设备 |
RU2135275C1 (ru) * | 1994-06-17 | 1999-08-27 | Шеврон Ю.Эс.Эй. Инк. | Конструкция носителя катализатора и способ его применения |
US5858311A (en) * | 1996-03-14 | 1999-01-12 | Chevron U.S.A. Inc. | Thermocouple well assembly with a sealing coupling and a method for eliminating leaks in hydroconversion reactors while continuing to hydroprocess |
US5885534A (en) * | 1996-03-18 | 1999-03-23 | Chevron U.S.A. Inc. | Gas pocket distributor for hydroprocessing a hydrocarbon feed stream |
US5879642A (en) * | 1996-04-24 | 1999-03-09 | Chevron U.S.A. Inc. | Fixed bed reactor assembly having a guard catalyst bed |
US6086749A (en) * | 1996-12-23 | 2000-07-11 | Chevron U.S.A. Inc. | Catalyst and method for hydroprocessing a hydrocarbon feed stream in a reactor containing two or more catalysts |
US5904907A (en) * | 1997-11-03 | 1999-05-18 | Chevron U.S.A., Inc. | Mixing system for mixing and distributing fluids in a reactor |
US6387334B1 (en) | 1997-12-30 | 2002-05-14 | Chevron U.S.A. Inc. | Balanced flow resistance OCR distributor cone |
US6554994B1 (en) | 1999-04-13 | 2003-04-29 | Chevron U.S.A. Inc. | Upflow reactor system with layered catalyst bed for hydrotreating heavy feedstocks |
ATE391726T1 (de) | 1999-10-22 | 2008-04-15 | Sanofi Pasteur Ltd | Modifiziertes gp100 und dessen verwendung |
CN1237149C (zh) * | 1999-12-16 | 2006-01-18 | 切夫里昂美国公司 | 预硫化加氢处理催化剂替换批料 |
WO2002030864A1 (fr) * | 2000-10-13 | 2002-04-18 | Mitsubishi Chemical Corporation | Procede de production de diacetoxybutene |
US7074740B2 (en) * | 2002-07-02 | 2006-07-11 | Chevron U.S.A. Inc. | Catalyst for conversion processes |
US20040009108A1 (en) * | 2002-07-09 | 2004-01-15 | Meier Paul F. | Enhanced fluid/solids contacting in a fluidization reactor |
US7807110B2 (en) | 2004-03-12 | 2010-10-05 | Cormetech Inc. | Catalyst systems |
US7776786B2 (en) | 2004-05-04 | 2010-08-17 | Cormetech, Inc. | Catalyst systems advantageous for high particulate matter environments |
US7638039B2 (en) * | 2004-06-15 | 2009-12-29 | Cormetech, Inc. | In-situ catalyst replacement |
FR2877589B1 (fr) | 2004-11-09 | 2007-01-12 | Inst Francais Du Petrole | Reacteur a plusieurs zones en lit fixe ou mobile avec echangeur thermique integre |
DE102005012942B4 (de) * | 2005-03-21 | 2018-12-13 | Robert Bosch Gmbh | Verfahren und Vorrichtung zum Betreiben einer Brennkraftmaschine |
US7638673B2 (en) * | 2005-05-04 | 2009-12-29 | Exxonmobil Chemical Patents Inc. | Process for hydrocarbon conversion with on-line solid particulate material removal |
US7763767B2 (en) * | 2005-05-04 | 2010-07-27 | Exxonmobil Chemicals Patents Inc. | Adsorption process with on-line adsorbent removal |
US20070012305A1 (en) * | 2005-07-18 | 2007-01-18 | Williams Russell K | Toy Water Rocket Launcher |
DK2054139T3 (da) * | 2006-08-01 | 2011-06-06 | Cormetech Inc | Fremgangsmåde til behandling af udstødningsgasser |
FR2917306B1 (fr) * | 2007-06-12 | 2011-04-15 | Inst Francais Du Petrole | Enceinte contenant un lit granulaire et une distribution d'une phase gazeuse et d'une phase liquide circulant en un ecoulement ascendant dans cette enceinte |
WO2009073436A2 (en) * | 2007-11-28 | 2009-06-11 | Saudi Arabian Oil Company | Process for catalytic hydrotreating of sour crude oils |
US7906081B2 (en) * | 2008-05-13 | 2011-03-15 | Uop Llc | Internal grids for adsorbent chambers and reactors |
US7901640B2 (en) * | 2008-05-13 | 2011-03-08 | Uop Llc | Optimized counter-current flow baffle |
US7718146B2 (en) * | 2008-05-13 | 2010-05-18 | Uop Llc | Enhanced bed separation in a styrene monomer reactor using milled plates |
EP2300566B1 (en) * | 2008-07-14 | 2016-09-07 | Saudi Arabian Oil Company | Process for the treatment of heavy oils using light hydrocarbon components as a diluent |
WO2010009082A1 (en) * | 2008-07-14 | 2010-01-21 | Saudi Arabian Oil Company | A prerefining process for the hydrodesulfurization of heavy sour crude oils to produce sweeter lighter crudes using moving catalyst system |
US8372267B2 (en) * | 2008-07-14 | 2013-02-12 | Saudi Arabian Oil Company | Process for the sequential hydroconversion and hydrodesulfurization of whole crude oil |
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US7841807B2 (en) * | 2008-10-30 | 2010-11-30 | Uop Llc | Method of transferring particles |
US7874769B2 (en) * | 2008-12-11 | 2011-01-25 | Uop Llc | Method for transferring particles |
US20100152516A1 (en) * | 2008-12-11 | 2010-06-17 | Christopher Naunheimer | Moving Bed Hydrocarbon Conversion Process |
US7887264B2 (en) * | 2008-12-11 | 2011-02-15 | Uop Llc | Apparatus for transferring particles |
US7878737B2 (en) * | 2008-12-22 | 2011-02-01 | Uop Llc | Apparatus for transferring particles |
US20100187159A1 (en) * | 2009-01-28 | 2010-07-29 | Christopher Naunheimer | Moving Bed Hydrocarbon Conversion Process |
US7841808B2 (en) * | 2009-01-28 | 2010-11-30 | Uop Llc | Method for transferring particles |
FR2946547B1 (fr) * | 2009-06-10 | 2012-09-21 | Inst Francais Du Petrole | Systeme de rigidification des plateaux d'une colonne multi-etagee de grand diametre. |
WO2011005476A2 (en) * | 2009-06-22 | 2011-01-13 | Saudi Arabian Oil Company | Alternative process for the treatment of heavy crudes in a coking refinery |
US8323476B2 (en) * | 2009-12-17 | 2012-12-04 | Uop Llc | Solid catalyst liquid phase hydroprocessing using moving bed reactors |
CN102309947A (zh) * | 2010-07-07 | 2012-01-11 | 中国石油化工股份有限公司 | 沸腾床催化剂在线加注方法 |
CN102309948A (zh) * | 2010-07-07 | 2012-01-11 | 中国石油化工股份有限公司 | 一种沸腾床催化剂在线加注方法 |
WO2014018911A1 (en) * | 2012-07-26 | 2014-01-30 | Bilfinger Water Technologies Inc. | Enhanced shape support grid |
US9636652B2 (en) * | 2013-12-05 | 2017-05-02 | Exxonmobil Research And Engineering Company | Reactor bed vessel and support assembly |
CN105419843B (zh) * | 2015-12-29 | 2017-05-31 | 北京神雾环境能源科技集团股份有限公司 | 移动床催化快速热解反应器 |
CN105419844B (zh) * | 2015-12-29 | 2017-05-03 | 北京神雾环境能源科技集团股份有限公司 | 下行床热解反应器 |
CN107790073A (zh) * | 2017-09-28 | 2018-03-13 | 北京中科诚毅科技发展有限公司 | 一种反应器新型内部结构及其设计方法和用途 |
KR101971160B1 (ko) * | 2017-10-13 | 2019-04-22 | 한국에너지기술연구원 | 피 건조물의 역흐름 다중 방해판 건조장치 |
CN108148620B (zh) * | 2018-02-02 | 2023-08-15 | 上海竣铭化工工程设计有限公司 | 沸腾床加氢反应设备及沸腾床加氢方法 |
CN108144556A (zh) * | 2018-02-02 | 2018-06-12 | 上海英保能源化工科技有限公司 | 一种沸腾床加氢反应系统以及沸腾床加氢工艺方法 |
CN108130123A (zh) * | 2018-02-02 | 2018-06-08 | 上海英保能源化工科技有限公司 | 沸腾床加氢反应系统及沸腾床加氢方法 |
CN109224855A (zh) * | 2018-11-26 | 2019-01-18 | 佛山科学技术学院 | 一种有机污染物用具有非热等离子体协同催化处理设备 |
CN109847655B (zh) * | 2019-03-08 | 2024-01-05 | 中国科学技术大学 | 一种用于原位探测高压气固相催化反应产物的实验装置 |
US11084991B2 (en) * | 2019-06-25 | 2021-08-10 | Saudi Arabian Oil Company | Two-phase moving bed reactor utilizing hydrogen-enriched feed |
US10933395B1 (en) * | 2019-08-26 | 2021-03-02 | Uop Llc | Apparatus for catalytic reforming hydrocarbons having flow distributor and process for reforming hydrocarbons |
CN110665443A (zh) * | 2019-11-16 | 2020-01-10 | 安平县燕赵矿筛网业有限公司 | 一种新型双氧水楔形锥体格栅支撑 |
CN111054275A (zh) * | 2019-11-28 | 2020-04-24 | 广州维港环保科技有限公司 | 一种催化反应装置及其催化反应系统 |
CN111921460B (zh) * | 2020-06-19 | 2021-03-16 | 宁波巨化化工科技有限公司 | 一种气相醛加氢反应器 |
CN116064124B (zh) * | 2021-10-29 | 2025-01-03 | 中国石油化工股份有限公司 | 煤焦油加氢处理装置及方法 |
CN117619281B (zh) * | 2024-01-26 | 2024-04-05 | 宝鸡市六维特种材料设备制造有限公司 | 一种反应釜反应装置 |
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US3336217A (en) * | 1965-07-15 | 1967-08-15 | Cities Scrvice Res And Dev Com | Particulate solids withdrawal method |
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-
1989
- 1989-07-19 US US07/381,948 patent/US5076908A/en not_active Expired - Lifetime
- 1989-09-29 CA CA000615373A patent/CA1332496C/en not_active Expired - Fee Related
-
1990
- 1990-07-17 WO PCT/US1990/004007 patent/WO1991001359A1/en active IP Right Grant
- 1990-07-17 AT AT90911055T patent/ATE118526T1/de not_active IP Right Cessation
- 1990-07-17 ES ES90911055T patent/ES2069083T3/es not_active Expired - Lifetime
- 1990-07-17 JP JP2510470A patent/JPH07119425B2/ja not_active Expired - Lifetime
- 1990-07-17 DK DK90911055.3T patent/DK0441912T3/da active
- 1990-07-17 DE DE69017000T patent/DE69017000T2/de not_active Expired - Fee Related
- 1990-07-17 MY MYPI90001191A patent/MY105733A/en unknown
- 1990-07-17 EP EP90911055A patent/EP0441912B1/en not_active Expired - Lifetime
- 1990-08-15 CN CN90106981A patent/CN1028111C/zh not_active Expired - Lifetime
-
1993
- 1993-02-08 US US08/014,847 patent/US5302357A/en not_active Expired - Lifetime
-
1994
- 1994-03-21 US US08/215,254 patent/US5409598A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US5302357A (en) | 1994-04-12 |
DE69017000T2 (de) | 1995-07-20 |
DE69017000D1 (de) | 1995-03-23 |
DK0441912T3 (da) | 1995-05-15 |
US5409598A (en) | 1995-04-25 |
CN1059164A (zh) | 1992-03-04 |
US5076908A (en) | 1991-12-31 |
CN1028111C (zh) | 1995-04-05 |
JPH03503296A (ja) | 1991-07-25 |
ATE118526T1 (de) | 1995-03-15 |
EP0441912A1 (en) | 1991-08-21 |
EP0441912B1 (en) | 1995-02-15 |
CA1332496C (en) | 1994-10-18 |
MY105733A (en) | 1994-11-30 |
EP0441912A4 (en) | 1992-01-15 |
JPH07119425B2 (ja) | 1995-12-20 |
WO1991001359A1 (en) | 1991-02-07 |
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