ES2059837T3 - Procedimiento para la obtencion de poliisocianatos modificados que muestran grupos isocianurato y su empleo. - Google Patents
Procedimiento para la obtencion de poliisocianatos modificados que muestran grupos isocianurato y su empleo.Info
- Publication number
- ES2059837T3 ES2059837T3 ES90100700T ES90100700T ES2059837T3 ES 2059837 T3 ES2059837 T3 ES 2059837T3 ES 90100700 T ES90100700 T ES 90100700T ES 90100700 T ES90100700 T ES 90100700T ES 2059837 T3 ES2059837 T3 ES 2059837T3
- Authority
- ES
- Spain
- Prior art keywords
- isocyanate groups
- groups
- isocianurate
- employment
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/30—Only oxygen atoms
- C07D251/34—Cyanuric or isocyanuric esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D273/00—Heterocyclic compounds containing rings having nitrogen and oxygen atoms as the only ring hetero atoms, not provided for by groups C07D261/00 - C07D271/00
- C07D273/02—Heterocyclic compounds containing rings having nitrogen and oxygen atoms as the only ring hetero atoms, not provided for by groups C07D261/00 - C07D271/00 having two nitrogen atoms and only one oxygen atom
- C07D273/04—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
- C08G18/022—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only the polymeric products containing isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7875—Nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
- C08G18/7887—Nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring having two nitrogen atoms in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyurethanes Or Polyureas (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Paints Or Removers (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
Abstract
EL INVENTO SE REFIERE A UN NUEVO PROCEDIMIENTO QUE SE UTILIZA PARA PRODUCIR POLIISOCIANATOS MODIFICADOS QUE PRESENTAN GRUPOS ISOCIANURATOS Y TIENEN GRUPOS ALIFATICOS Y/O CICLOALIFATICOS Y QUE CONSISTE EN MODIFICAR QUIMICAMENTE UNA FRACCION DE GRUPOS ISOCIANATOS DE DIISOCIANATOS ORGANICOS CON GRUPOS ISOCIANATOS ALIFATICOS Y/O CICLOALIFATICOS EN PRESENCIA DE UN CATALIZADOR A BASE DE FLUORURO DE AMONIO CUATERNARIO O FOSFORINO Y DE UN DIOXIDO DE CARBONO EMPLEADO EN LA REACCION Y TRATA DE LA APLICACION DEL POLIISOCIANATO MODIFICADO EN MEDIOS BLOQUEADORES PARA MOLDES BLOQUEADOS DE GRUPOS ISOCIANATOS, LACAS DE POLIURETANO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3902078A DE3902078A1 (de) | 1989-01-25 | 1989-01-25 | Verfahren zur herstellung von modifizierten, isocyanuratgruppen aufweisenden polyisocyanaten und ihre verwendung |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2059837T3 true ES2059837T3 (es) | 1994-11-16 |
Family
ID=6372717
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES90100700T Expired - Lifetime ES2059837T3 (es) | 1989-01-25 | 1990-01-13 | Procedimiento para la obtencion de poliisocianatos modificados que muestran grupos isocianurato y su empleo. |
Country Status (8)
Country | Link |
---|---|
US (1) | US5013838A (es) |
EP (1) | EP0379914B1 (es) |
JP (1) | JP2832473B2 (es) |
AT (1) | ATE94177T1 (es) |
BR (1) | BR9000282A (es) |
CA (1) | CA2008064C (es) |
DE (2) | DE3902078A1 (es) |
ES (1) | ES2059837T3 (es) |
Families Citing this family (73)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4005762A1 (de) * | 1990-02-23 | 1991-08-29 | Bayer Ag | Trimerisierungskatalysatoren, ein verfahren zu ihrer herstellung und ihre verwendung bei der herstellung von isocyanuratgruppen aufweisenden polyisocyanaten |
DE4026705A1 (de) * | 1990-08-24 | 1992-02-27 | Bayer Ag | Dimerisierungskatalysatoren, ein verfahren zu ihrer herstellung und ihre verwendung bei der herstellung von uretdion- und isocyanuratgruppen aufweisenden polyisocyanaten |
DE4310593C2 (de) * | 1993-03-31 | 1996-11-28 | Wacker Chemie Gmbh | Stabilisierte Organopolysiloxanöle und deren Verwendung |
DE4331084A1 (de) * | 1993-09-13 | 1995-03-16 | Basf Ag | Verfahren zur Herstellung von Isocyanurat- und Uretdiongruppen enthaltenden Polyisocyanatmischungen mit reduzierter Farbzahl |
DE4405055A1 (de) * | 1994-02-17 | 1995-08-24 | Basf Ag | Verfahren zur Herstellung von Isocyanuratgruppen aufweisenden Polyisocyanaten und ihre Verwendung |
DE19532060A1 (de) * | 1995-08-31 | 1997-03-06 | Bayer Ag | Polycyclische Iminooxadiazindione, deren Herstellung und Verwendung |
DE19611849A1 (de) * | 1996-03-26 | 1997-10-02 | Bayer Ag | Neue Isocyanattrimerisate und Isocyanattrimerisatmischungen, deren Herstellung und Verwendung |
DE19646110A1 (de) * | 1996-11-08 | 1998-05-14 | Bayer Ag | Mikrokapseln unter Verwendung von Iminooxadiazindion-Polyisocyanaten |
DE19653583A1 (de) * | 1996-12-20 | 1998-06-25 | Bayer Ag | Polycyclische Iminooxadiazindione aus (cyclo)aliphatischen 1,4-Diisocyanaten |
DE19734048A1 (de) * | 1997-08-06 | 1999-02-11 | Bayer Ag | Verfahren zur Herstellung von Polyisocyanaten, damit hergestellte Polyisocyanate und deren Verwendung |
EP0962454B1 (de) * | 1998-06-02 | 2002-10-09 | Bayer Aktiengesellschaft | Verfahren zur Herstellung Iminooxadiazindiongruppen enhaltender Polyisocyanate |
DE19853569A1 (de) * | 1998-11-20 | 2000-05-25 | Bayer Ag | Neue Urethanacrylate, Verfahren zu ihrer Herstellung sowie ihre Verwendung |
JP3804736B2 (ja) * | 1998-12-17 | 2006-08-02 | 三井化学株式会社 | イソシアヌレート環含有ポリイソシアナートの製造方法 |
DE19944373A1 (de) | 1999-09-16 | 2001-03-22 | Degussa | Katalysator und Verfahren zur Herstellung von farbreduzierten isocyanuratgruppenhaltigen Polyisocyananten |
WO2001053277A1 (fr) | 2000-01-20 | 2001-07-26 | Rhodia Chimie | Procede d'obtention de polyisocyanate(s) ramifie(s) faiblement colore(s), et composition en decoulant |
CA2353005A1 (en) * | 2000-08-01 | 2002-02-01 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Blocked urethane prepolymers as paper wet strength agent |
DE10065176A1 (de) * | 2000-12-23 | 2002-06-27 | Degussa | Katalysator und Verfahren zur Herstellung von niedrigviskosen und farbreduzierten isocyanuratgruppenhaltigen Polyisocyanaten |
JP2003138497A (ja) * | 2001-10-31 | 2003-05-14 | Dai Ichi Kogyo Seiyaku Co Ltd | 湿潤紙力増強剤 |
DE10159803A1 (de) * | 2001-12-05 | 2003-07-03 | Degussa | Katalysatoren und Verfahren zur Herstellung von Isocyanuratgruppen enthaltenden Polyisocyanaten und deren Verwendung |
DE10160305A1 (de) | 2001-12-07 | 2003-06-18 | Degussa | Katalysatoren und Verfahren zur Herstellung von Isocyanuratgruppen enthaltenden Polyisocyanaten und deren Verwendung |
US20060223970A1 (en) * | 2005-03-31 | 2006-10-05 | Bayer Materialscience Llc | Low surface energy polyisocyanates and their use in one- or two-component coating compositions |
US20060223969A1 (en) * | 2005-03-31 | 2006-10-05 | Bayer Materialscience Llc | Low surface energy polyisocyanates and their use in one- or two-component coating compositions |
US20070032623A1 (en) * | 2005-08-05 | 2007-02-08 | Bayer Material Science Llc | Low surface energy polyisocyanates and their use in one-or two-component coating compositions |
US7759447B2 (en) * | 2005-11-17 | 2010-07-20 | Bayer Materialscience Llc | Low surface energy, ethylenically unsaturated polyisocyanate addition compounds and their use in coating compositions |
US20070112162A1 (en) * | 2005-11-17 | 2007-05-17 | Bayer Materialscience Llc | Low surface energy, ethylenically unsaturated polyisocyanate addition compounds and their use in coating compositions |
US20070269661A1 (en) * | 2006-05-16 | 2007-11-22 | Graham William F | Ultraproductive coating composition using a chemically mixed isocyanate system |
DE102010038845A1 (de) | 2010-08-03 | 2012-02-09 | Bayer Materialscience Aktiengesellschaft | Verfahren zur Herstellung von Polyisocyanaten und deren Verwendung |
US9440937B2 (en) | 2011-11-29 | 2016-09-13 | Covestro Deutschland Ag | Method for producing polyisocyanates and use thereof |
CN109970950A (zh) | 2011-11-30 | 2019-07-05 | 科思创德国股份有限公司 | 用于连续异氰酸酯改性的方法 |
US20160046756A1 (en) | 2013-03-22 | 2016-02-18 | Covestro Deutschland Ag | Process for preparing polyisocyanates and catalyst kit therefor |
US20160168308A1 (en) * | 2013-07-25 | 2016-06-16 | Covestro Deutschland Ag | Method for producing polyisocyanates and use of said polyisocyanates |
US9938369B2 (en) | 2013-07-25 | 2018-04-10 | Covestro Deutschland Ag | Use of succinonitrile in the production of polyisocyanates comprising iminooxadiazinedione groups |
HUE041620T2 (hu) | 2014-02-18 | 2019-05-28 | Covestro Deutschland Ag | Eljárás izocianátok módosítására katalizátorként spirociklusos ammóniumsók alkalmazásával |
HUE039602T2 (hu) | 2014-02-18 | 2019-01-28 | Covestro Deutschland Ag | Eljárás izocianátok módosítására N-P-N-szekvenciájú katalizátorok alkalmazásával |
EP3085720A1 (de) | 2015-04-21 | 2016-10-26 | Covestro Deutschland AG | Hydrophil modifizierter polyisocyanuratkunststoff und verfahren zu dessen herstellung |
CN107531862B (zh) | 2015-04-21 | 2020-11-06 | 科思创德国股份有限公司 | 在绝热条件下生产的基于聚异氰脲酸酯聚合物的固体 |
CA2980669C (en) | 2015-04-21 | 2023-09-19 | Covestro Deutschland Ag | Polyisocyanurate polymers and process for the production of polyisocyanurate polymers |
WO2016170060A1 (en) | 2015-04-21 | 2016-10-27 | Covestro Deutschland Ag | Process for producing polyisocvanurate plastics having functionalized surfaces |
EP3286242A1 (en) | 2015-04-21 | 2018-02-28 | Covestro Deutschland AG | Polyisocyanurate plastics having high thermal stability |
CN107438635B (zh) | 2015-04-21 | 2021-01-19 | 科思创德国股份有限公司 | 制造聚异氰脲酸酯塑料的方法 |
EP3337836B1 (de) | 2015-08-17 | 2019-07-31 | Covestro Deutschland AG | Verfahren zur modifizierung von isocyanaten unter verwendung von cyclischen ammoniumsalzen als katalysator |
US9815739B2 (en) | 2015-10-30 | 2017-11-14 | Covestro Llc | Polyisocyanurate based cement for wellbore fluid loss prevention |
JP2019536849A (ja) | 2016-10-18 | 2019-12-19 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | ブロックトポリイソシアネートの触媒架橋によるプラスチックの製造 |
EP3529292A1 (en) | 2016-10-18 | 2019-08-28 | Covestro Deutschland AG | Coating of wires with catalytically crosslinked blocked polyisocyanates |
CN110062794B (zh) | 2016-10-18 | 2022-05-13 | 科思创德国股份有限公司 | 具有高化学和机械耐受性的硬涂层 |
US20190367666A1 (en) | 2016-11-14 | 2019-12-05 | Covestro Deutschland Ag | Dual-curing coating compositions |
WO2018095869A1 (de) | 2016-11-22 | 2018-05-31 | Basf Se | Verfahren zur herstellung von trimeren isocyanaten |
CN110312747B (zh) | 2017-02-22 | 2022-07-15 | 科思创德国股份有限公司 | 使用螺环铵盐作为催化剂至少改性五亚甲基二异氰酸酯的方法 |
FR3064008B1 (fr) * | 2017-03-15 | 2020-02-14 | Vencorex France | Catalyseurs de trimerisation d'isocyanates |
EP3381962A1 (de) | 2017-03-29 | 2018-10-03 | Covestro Deutschland AG | Erzeugung von polyisocyanuratschichten durch getrennte auftragung von isocyanatkomponenten und katalysatoren |
EP3421516A1 (de) | 2017-06-28 | 2019-01-02 | Covestro Deutschland AG | Gefärbte kunststoffe basierend auf vernetzten polyisocyanaten |
EP3444288A1 (de) | 2017-08-15 | 2019-02-20 | Covestro Deutschland AG | Verfahren zur herstellung iminooxadiazindiongruppen enthaltender polyisocyanate unter verwendung von katalysatorenmischungen |
WO2019061019A1 (en) | 2017-09-26 | 2019-04-04 | Covestro Deutschland Ag | TWO-COMPONENT SYSTEM FOR ELASTIC COATINGS |
ES2981974T3 (es) | 2017-11-14 | 2024-10-14 | Covestro Deutschland Ag | Productos semiacabados basados en el mecanismo de reticulación dual |
US11124682B2 (en) | 2017-12-21 | 2021-09-21 | Covestro Deutschland Ag | Frost-resistant adhesives based on polyisocyanates |
EP3728380B1 (de) | 2017-12-21 | 2022-01-12 | Covestro Deutschland AG | Frostbeständige wasserlacke auf basis von polyisocyanaten |
WO2019157625A1 (en) | 2018-02-13 | 2019-08-22 | Covestro Deutschland Ag | Aromatic polyisocyanates with a high solids content |
WO2019219614A1 (de) | 2018-05-17 | 2019-11-21 | Covestro Deutschland Ag | Verfahren zur herstellung von verbundwerkstoffen aus polyethylenfasern mit ultrahohem molekulargewicht und vernetzten polyisocyanaten |
WO2019219603A1 (de) | 2018-05-17 | 2019-11-21 | Covestro Deutschland Ag | Verfahren zur herstellung eines polyisocyanatpolymers und eines polyisocyanuratkunststoffs |
US12247144B2 (en) | 2018-10-19 | 2025-03-11 | Covestro Deutschland Ag | Anhydrously curing polyisocyanate-based adhesives |
WO2020152107A1 (de) | 2019-01-22 | 2020-07-30 | Covestro Intellectual Property Gmbh & Co. Kg | Kompositwerkstoffe basierend auf urethan- und isocyanuratpolymeren mit dualer härtung |
CN113631545B (zh) | 2019-02-27 | 2025-01-07 | 科思创德国股份有限公司 | 作为电灌封料的聚异氰脲酸酯材料 |
WO2021004842A1 (de) * | 2019-07-08 | 2021-01-14 | Covestro Intellectual Property Gmbh & Co. Kg | Polymerisierbare zusammensetzungen zur herstellung von polyisocyanuratkunststoffen mit verlängerter topfzeit |
EP3763792A1 (de) | 2019-07-11 | 2021-01-13 | Covestro Deutschland AG | Verfahren zur herstellung von isocyanuraten aus uretdionen |
EP3885385A1 (en) | 2020-03-23 | 2021-09-29 | Basf Se | Process for modifying isocyanates with use of guanidinium salts as catalyst |
KR20230033654A (ko) | 2020-07-02 | 2023-03-08 | 코베스트로 도이칠란트 아게 | 폴리이소시아누레이트 코팅 (rim)으로부터의 코팅물 및 사출 성형 공정에서의 그의 용도 |
EP3985044A1 (en) | 2020-10-13 | 2022-04-20 | Basf Se | Process for modifying isocyanates |
US20240301154A1 (en) | 2021-03-29 | 2024-09-12 | Covestro Deutschland Ag | Polyisocyanurate-prepregs and fiber composite components produced therefrom |
EP4098678A1 (en) | 2021-06-02 | 2022-12-07 | Basf Se | Process for modifying isocyanates with use of difluorosilicate salts as catalyst |
CN118251435A (zh) | 2021-11-16 | 2024-06-25 | 巴斯夫欧洲公司 | 含有亚氨基噁二嗪二酮基团的多异氰酸酯的制备及其用途 |
CN118613517A (zh) | 2022-01-18 | 2024-09-06 | 巴斯夫欧洲公司 | 含有亚氨基噁二嗪二酮基团的多异氰酸酯的制备及其用途 |
EP4303246A1 (de) | 2022-07-04 | 2024-01-10 | Covestro Deutschland AG | Polyisocyanatgemisch |
WO2024165361A1 (en) | 2023-02-09 | 2024-08-15 | Basf Se | Preparation of polyisocyanates containing iminooxadiazinedione groups and their use |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3748329A (en) * | 1970-07-08 | 1973-07-24 | Bayer Ag | Compounds containing the 2,4,6-triketo-1,3,5-oxadiazine ring |
JPS579773A (en) * | 1980-06-23 | 1982-01-19 | Takeda Chem Ind Ltd | Production of polyisocyanate |
DE3420114A1 (de) * | 1984-05-30 | 1985-12-05 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von uretdiongruppen aufweisenden polyisocyanaten |
EP0235388B1 (en) * | 1985-12-28 | 1989-11-08 | MITSUI TOATSU CHEMICALS, Inc. | Preparation process of heat-resistant polymers |
JPH0623229B2 (ja) * | 1987-06-19 | 1994-03-30 | 三井東圧化学株式会社 | 熱硬化性樹脂の製造法 |
JP2609639B2 (ja) * | 1987-11-14 | 1997-05-14 | 日本ヒューレット・パッカード株式会社 | テストヘッド |
-
1989
- 1989-01-25 DE DE3902078A patent/DE3902078A1/de not_active Withdrawn
-
1990
- 1990-01-13 ES ES90100700T patent/ES2059837T3/es not_active Expired - Lifetime
- 1990-01-13 AT AT90100700T patent/ATE94177T1/de not_active IP Right Cessation
- 1990-01-13 EP EP90100700A patent/EP0379914B1/de not_active Expired - Lifetime
- 1990-01-13 DE DE90100700T patent/DE59002590D1/de not_active Expired - Fee Related
- 1990-01-18 CA CA002008064A patent/CA2008064C/en not_active Expired - Fee Related
- 1990-01-19 US US07/467,822 patent/US5013838A/en not_active Expired - Lifetime
- 1990-01-23 JP JP2011986A patent/JP2832473B2/ja not_active Expired - Fee Related
- 1990-01-24 BR BR909000282A patent/BR9000282A/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ATE94177T1 (de) | 1993-09-15 |
CA2008064C (en) | 1998-08-18 |
JP2832473B2 (ja) | 1998-12-09 |
EP0379914A3 (de) | 1991-07-17 |
JPH02258771A (ja) | 1990-10-19 |
BR9000282A (pt) | 1990-11-20 |
DE59002590D1 (de) | 1993-10-14 |
US5013838A (en) | 1991-05-07 |
EP0379914A2 (de) | 1990-08-01 |
DE3902078A1 (de) | 1990-07-26 |
CA2008064A1 (en) | 1990-07-25 |
EP0379914B1 (de) | 1993-09-08 |
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