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ES2054154T3 - Cuerpos de moldeo de resinas macroporosas intercambiadoras de iones, asi como aplicacion de los cuerpos de moldeo. - Google Patents

Cuerpos de moldeo de resinas macroporosas intercambiadoras de iones, asi como aplicacion de los cuerpos de moldeo.

Info

Publication number
ES2054154T3
ES2054154T3 ES90111500T ES90111500T ES2054154T3 ES 2054154 T3 ES2054154 T3 ES 2054154T3 ES 90111500 T ES90111500 T ES 90111500T ES 90111500 T ES90111500 T ES 90111500T ES 2054154 T3 ES2054154 T3 ES 2054154T3
Authority
ES
Spain
Prior art keywords
rings
packing
molding bodies
macroporous
bodies
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90111500T
Other languages
English (en)
Inventor
Klaus Dr Gottlieb
Wilfried Graf
Kuno Dr Schadlich
Ulrich Prof Dr Hoffmann
Alwin Dr Ing Rehfinger
Jorg Dipl-Ing Flato
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Veba Oel AG
Original Assignee
Veba Oel AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Veba Oel AG filed Critical Veba Oel AG
Application granted granted Critical
Publication of ES2054154T3 publication Critical patent/ES2054154T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30—Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J47/00—Ion-exchange processes in general; Apparatus therefor
    • B01J47/018—Granulation; Incorporation of ion-exchangers in a matrix; Mixing with inert materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/30203—Saddle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/30207—Sphere
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/30215—Toroid or ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/30223—Cylinder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/304—Composition or microstructure of the elements
    • B01J2219/30466—Plastics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/304—Composition or microstructure of the elements
    • B01J2219/30475—Composition or microstructure of the elements comprising catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Catalysts (AREA)
  • Gas Separation By Absorption (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Peptides Or Proteins (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Feed For Specific Animals (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Abstract

CUERPOS FABRICADOS A PARTIR DE RESINAS MACROPOROSAS CAMBIADORAS DE IONES. ESTOS TIENEN LA FORMA DE DIVERSOS MOLDES POR EJEMPLO ANILLOS, RECIPIENTES, MOLDES DE ANILLOS CON LISTONES HORIZONTALES O INCLINADOS Y OTROS TIPOS DE ARMAZONES, CUBOS Y SIMILARES, ESTOS CUERPOS TENDRIAN UNA CANTIDAD DE HUECO QUE PUEDE OSCILAR DEL 5 AL 95 % DEL VOLUMEN DEL CUERPO SIN POROS, UNA SUPERFICIE-BET COMPRENDIDA ENTRE 0,01 Y 1000 M2/G (PREFERENTEMENTE COMPRENDIDA ENTRE 20 Y 600 M2/G) Y UNA CAPACIDAD DE INTERCAMBIO COMPRENDIDA ENTRE 0,05 Y 10 MEQ/G (PREFERENTEMENTE COMPRENDIDA ENTRE 3 Y 6 MEQ/G). LOS CUERPOS SON UTILIZADOS COMO MOLDES CATALITICAMENTE ACTIVOS PARA REACCIONES, ESPECIALMENTE PARA LA ETERIZACION, LA HIDRATIZACION, DIMERIZACION, OLIGOMERIZACION, ESTERIFICACION, HIHRURACIOM, ALQUILURACION O COMBINACIONES SIMILARES. MEDIANTE UNA OPERACION DE SEPARACION PARALELA COMO LA ADSORCION, LA ABSORCION, LA EXTRACCION, DESTILACION, FRACCIONAMIENTO O MEMBRANACION SE OBTIENE, EN UN APARATO, LA COMBINACION DE UNA REACCION QUIMICA Y LA PARALELA SEPARACION DE LOS ELEMENTOS REACCIONANTES. EN UNO DE LOS EJEMPLOS SE TRANSFORMAN EL METAMOL Y LOS ISOBUTILOS EN METILOBUTILOS (MTBE) A PARTIR DE ANILLOS DE COPOLIMERISATOS ESTIRO-DIVINILBENZOLICOS DE TIPO ACIDO Y MACROPOROSOS
ES90111500T 1989-09-13 1990-06-19 Cuerpos de moldeo de resinas macroporosas intercambiadoras de iones, asi como aplicacion de los cuerpos de moldeo. Expired - Lifetime ES2054154T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3930515A DE3930515A1 (de) 1989-09-13 1989-09-13 Formkoerper aus makroporoesen ionenaustauscherharzen sowie verwendung der formkoerper

Publications (1)

Publication Number Publication Date
ES2054154T3 true ES2054154T3 (es) 1994-08-01

Family

ID=6389302

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90111500T Expired - Lifetime ES2054154T3 (es) 1989-09-13 1990-06-19 Cuerpos de moldeo de resinas macroporosas intercambiadoras de iones, asi como aplicacion de los cuerpos de moldeo.

Country Status (10)

Country Link
EP (1) EP0417407B1 (es)
JP (1) JP3148224B2 (es)
AT (1) ATE105508T1 (es)
AU (1) AU635757B2 (es)
CA (1) CA2024758C (es)
DD (1) DD299192A5 (es)
DE (2) DE3930515A1 (es)
DK (1) DK0417407T3 (es)
ES (1) ES2054154T3 (es)
FI (1) FI101267B1 (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4234779A1 (de) * 1992-10-15 1994-04-21 Veba Oel Ag Trägerkatalysator und Verwendung desselben
DE4322712A1 (de) * 1993-07-08 1995-01-12 Huels Chemische Werke Ag Verfahren zur Durchführung chemischer Reaktionen in Reaktionsdestillationskolonnen
FR2716676B1 (fr) * 1994-02-28 1996-04-05 Elf Aquitaine Procédé de décomposition oxydative de composés organiques présents dans des effluents aqueux.
TW321634B (es) 1994-07-05 1997-12-01 Mitsui Toatsu Chemicals
US6565816B1 (en) * 1997-06-25 2003-05-20 Koch-Glitsch, Inc. Saddle structure for reactive distillation
DE10000527B4 (de) * 2000-01-08 2005-12-15 Epc Engineering Und Projektmanagement Consulting Gmbh Reaktoreinbauten zur Ausgasung oder Polykondensation
US6703530B2 (en) 2002-02-28 2004-03-09 General Electric Company Chemical reactor system and process
EP1388528B1 (de) 2002-08-06 2015-04-08 Evonik Degussa GmbH Verfahren zur Oligomerisierung von Isobuten in n-Buten-haltigen Kohlenwasserstoffströmen
US7341618B2 (en) 2002-10-24 2008-03-11 Georgia Tech Research Corporation Filters and methods of making and using the same
US7025800B2 (en) 2003-10-24 2006-04-11 Georgia Tech Research Corporation Methods of measuring the diffusion rate and partition coefficient of an analyte into a polymer and methods of forming a filter media
WO2008017680A1 (de) * 2006-08-10 2008-02-14 Basf Se Katalysatorformkörper mit ionenaustauschereigenschaften
US20150148572A1 (en) * 2013-11-27 2015-05-28 Saudi Arabian Oil Company Process for the Dimerization/Oligomerization of Mixed Butenes Over an Ion-Exchange Resin Catalyst
TWI561303B (en) 2014-04-09 2016-12-11 Rohm & Haas Catalyst resin
TWI544022B (zh) 2014-04-09 2016-08-01 羅門哈斯公司 製備烷基酯之方法
US10301551B2 (en) 2016-06-30 2019-05-28 Uop Llc Modular crude refining process
CN112007483B (zh) * 2020-10-22 2021-01-26 山东神驰石化有限公司 一种甲基叔丁基醚用回收装置
CN114160055A (zh) * 2021-10-27 2022-03-11 岳阳职业技术学院 膜式干燥器、间歇酯化反应系统、己二酸二甲酯制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE635822A (es) * 1962-08-06
GB1060801A (en) * 1962-08-06 1967-03-08 Wacker Chemie Gmbh Process for the manufacture of porous shaped bodies that contain ion exchange synthetic resins
FR2064778A1 (es) * 1969-10-30 1971-07-23 Showa Denko Kk
US4007138A (en) * 1972-05-25 1977-02-08 Badische Anilin- & Soda-Fabrik Aktiengesellschaft Manufacture of ion-exchanging shaped articles
DE2225329C2 (de) * 1972-05-25 1982-05-19 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von mikroporösen ionenaustauschfähigen Formkörpern
US4012456A (en) * 1974-11-19 1977-03-15 Chaplits Donat N Method for separation of isobutylene from C4 hydrocarbon fractions
FR2297083A1 (fr) * 1975-01-10 1976-08-06 Chaplits Donat Catalyseur echangeur d'ions moule et procede de preparation dudit catalyseur
US4180688A (en) * 1977-07-29 1979-12-25 Nippon Oil Co., Ltd. Method for continuously producing tert-butyl alcohol
DE2914079C2 (de) * 1979-04-07 1984-07-12 Kernforschungsanlage Jülich GmbH, 5170 Jülich Austauschschüttkörper mit reaktivem Material
JPS58133821A (ja) * 1982-02-01 1983-08-09 Shoko Tsusho Kk 水素同位体交換反応方法
JPS5956161A (ja) * 1982-09-24 1984-03-31 Hitachi Chem Co Ltd 液体クロマトグラフイ−用カラム充てん剤

Also Published As

Publication number Publication date
CA2024758C (en) 2000-03-21
EP0417407B1 (de) 1994-05-11
CA2024758A1 (en) 1991-03-14
JPH03207728A (ja) 1991-09-11
DK0417407T3 (da) 1994-06-13
DD299192A5 (de) 1992-04-02
FI101267B (fi) 1998-05-29
EP0417407A1 (de) 1991-03-20
JP3148224B2 (ja) 2001-03-19
DE59005672D1 (de) 1994-06-16
FI101267B1 (fi) 1998-05-29
FI904507A0 (fi) 1990-09-12
AU635757B2 (en) 1993-04-01
AU5982290A (en) 1991-03-21
DE3930515A1 (de) 1991-03-21
ATE105508T1 (de) 1994-05-15

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