ES2042599T3 - Procedimiento para preparar esteres de acidos biciclo (3.3.0) octanodionacarboxilicos opticamente activos. - Google Patents
Procedimiento para preparar esteres de acidos biciclo (3.3.0) octanodionacarboxilicos opticamente activos.Info
- Publication number
- ES2042599T3 ES2042599T3 ES87730146T ES87730146T ES2042599T3 ES 2042599 T3 ES2042599 T3 ES 2042599T3 ES 87730146 T ES87730146 T ES 87730146T ES 87730146 T ES87730146 T ES 87730146T ES 2042599 T3 ES2042599 T3 ES 2042599T3
- Authority
- ES
- Spain
- Prior art keywords
- pct
- formula
- optically active
- octanodionacarboxilicos
- esteres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002253 acid Substances 0.000 title abstract 2
- 150000007513 acids Chemical class 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 108010027597 alpha-chymotrypsin Proteins 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000000911 decarboxylating effect Effects 0.000 abstract 1
- 150000005690 diesters Chemical class 0.000 abstract 1
- -1 ethyl- Chemical group 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P17/00—Preparation of heterocyclic carbon compounds with only O, N, S, Se or Te as ring hetero atoms
- C12P17/02—Oxygen as only ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P41/00—Processes using enzymes or microorganisms to separate optical isomers from a racemic mixture
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/62—Carboxylic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Zoology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Analytical Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
LA INVENCION SE REFIERE A UN PROCEDIMINETO PARA LA OBTENCION DE ESTERES DE ACIDOS BICICLO [3.3.0] OCTADIONCARBOXILICOS DE FORMULA (I), EN LA QUE R1 Y R2 REPRESENTAN AMBOS UN ATOMO DE OXIGENO O UN RESTO -O-X-O- EN EL QUE X ES UN GRUPO ALQUILENO, LINEAL O RAMIFICADO, CON 1 A 7 ATOMOS DE CARBONO, O BIEN R1 Y R2 REPRESENTAN CADA UNO EL RESTO OR4, SIENDO R4 UN GRUPO ALQUILO LINEAL O RAMIFICADO, CON 1 A 7 ATOMOS DE CARBONO, Y R3 ES UN GRUPO ALQUILO, LINEAL O RAMIFICADO, CON 1 A 10 ATOMOS DE CARBONO. EL PROCEDIMIENTO SE CARACTERIZA PORQUE UN DIESTER DE ACIDO BICICLO [3.3.0] OCTADIONCARBOXILICO DE FORMULA (II), EN LA QUE R1, R2 Y R3 SIGNIFICAN LA INDICADO ANTERIORMENTE, SE SAPONIFICA Y DESCARBOXILA EN FORMA ENANTIOSELECTIVA CON ENZIMAS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19863638760 DE3638760A1 (de) | 1986-11-13 | 1986-11-13 | Verfahren zur herstellung von optisch aktiven bicyclo(3.3.0)octandioncarbonsaeureestern |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2042599T3 true ES2042599T3 (es) | 1993-12-16 |
Family
ID=6313860
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES87730146T Expired - Lifetime ES2042599T3 (es) | 1986-11-13 | 1987-11-12 | Procedimiento para preparar esteres de acidos biciclo (3.3.0) octanodionacarboxilicos opticamente activos. |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US5093250A (es) |
| EP (1) | EP0272202B1 (es) |
| JP (1) | JPH01501204A (es) |
| AT (1) | ATE77837T1 (es) |
| AU (1) | AU612999B2 (es) |
| CA (1) | CA1335185C (es) |
| CS (1) | CS268543B2 (es) |
| DD (1) | DD264456A5 (es) |
| DE (2) | DE3638760A1 (es) |
| ES (1) | ES2042599T3 (es) |
| GR (1) | GR3005805T3 (es) |
| HU (1) | HU202290B (es) |
| IE (1) | IE59614B1 (es) |
| WO (1) | WO1988003569A1 (es) |
| ZA (1) | ZA878543B (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7267846B2 (en) | 1999-11-01 | 2007-09-11 | Praful Doshi | Tinted lenses and methods of manufacture |
| US7048375B2 (en) | 1999-11-01 | 2006-05-23 | Praful Doshi | Tinted lenses and methods of manufacture |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5847495A (ja) * | 1981-09-16 | 1983-03-19 | Sumitomo Chem Co Ltd | シクロペンテノロン誘導体の生化学的光学分割法 |
| JPS61280294A (ja) * | 1985-06-04 | 1986-12-10 | Nisshin Flour Milling Co Ltd | 光学活性カルバサイクリン中間体の製造方法 |
| DE3638758A1 (de) * | 1986-11-13 | 1988-05-26 | Schering Ag | Racematspaltung von 3-acyloxy-bicyclo(3.3.0)octan-7-on-2- carbonsaeureestern durch stereospezifische enzymatische oder mikrobiologische acylat-hydrolyse |
| US4800162A (en) * | 1987-04-01 | 1989-01-24 | Sepracor, Inc. | Method for resolution of steroisomers in multiphase and extractive membrane reactors |
-
1986
- 1986-11-13 DE DE19863638760 patent/DE3638760A1/de not_active Withdrawn
-
1987
- 1987-11-12 DD DD87308971A patent/DD264456A5/de not_active IP Right Cessation
- 1987-11-12 DE DE8787730146T patent/DE3780137D1/de not_active Expired - Lifetime
- 1987-11-12 US US07/237,113 patent/US5093250A/en not_active Expired - Fee Related
- 1987-11-12 JP JP62506956A patent/JPH01501204A/ja active Pending
- 1987-11-12 CA CA000551621A patent/CA1335185C/en not_active Expired - Fee Related
- 1987-11-12 WO PCT/DE1987/000518 patent/WO1988003569A1/de unknown
- 1987-11-12 EP EP87730146A patent/EP0272202B1/de not_active Expired - Lifetime
- 1987-11-12 AU AU82748/87A patent/AU612999B2/en not_active Ceased
- 1987-11-12 HU HU875802A patent/HU202290B/hu not_active IP Right Cessation
- 1987-11-12 IE IE304787A patent/IE59614B1/en not_active IP Right Cessation
- 1987-11-12 AT AT87730146T patent/ATE77837T1/de not_active IP Right Cessation
- 1987-11-12 ES ES87730146T patent/ES2042599T3/es not_active Expired - Lifetime
- 1987-11-13 ZA ZA878543A patent/ZA878543B/xx unknown
- 1987-11-13 CS CS878152A patent/CS268543B2/cs unknown
-
1992
- 1992-09-24 GR GR920402127T patent/GR3005805T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA878543B (en) | 1988-10-26 |
| CS815287A2 (en) | 1989-06-13 |
| DE3638760A1 (de) | 1988-05-26 |
| DE3780137D1 (de) | 1992-08-06 |
| DD264456A5 (de) | 1989-02-01 |
| CA1335185C (en) | 1995-04-11 |
| HUT47156A (en) | 1989-01-30 |
| CS268543B2 (en) | 1990-03-14 |
| WO1988003569A1 (en) | 1988-05-19 |
| AU612999B2 (en) | 1991-07-25 |
| JPH01501204A (ja) | 1989-04-27 |
| IE873047L (en) | 1988-05-13 |
| US5093250A (en) | 1992-03-03 |
| ATE77837T1 (de) | 1992-07-15 |
| HU202290B (en) | 1991-02-28 |
| GR3005805T3 (es) | 1993-06-07 |
| EP0272202A1 (de) | 1988-06-22 |
| EP0272202B1 (de) | 1992-07-01 |
| AU8274887A (en) | 1988-06-01 |
| IE59614B1 (en) | 1994-03-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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