Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B24—GRINDING; POLISHING
  • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
  • B24D11/00—Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
  • B24D11/001—Manufacture of flexible abrasive materials
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B24—GRINDING; POLISHING
  • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
  • B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
  • B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
  • B24D3/20—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
  • B24D3/28—Resins or natural or synthetic macromolecular compounds
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
  • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
  • C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
  • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
  • C08G59/4014—Nitrogen containing compounds
  • C08G59/4021—Ureas; Thioureas; Guanidines; Dicyandiamides
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
  • C08G59/62—Alcohols or phenols
  • C08G59/621—Phenols
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
  • C08G59/66—Mercaptans
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
  • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00

Definitions

• coated abrasive articles have abrasive particles secured to a backing. More typically, coated abrasive articles comprise a backing having two major opposed surfaces and an abrasive layer secured to a major surface.
• the abrasive layer typically comprises abrasive particles and a binder, wherein the binder serves to secure the abrasive particles to the backing.
• coated abrasive article has an abrasive layer comprising a make layer, a size layer, and abrasive particles.
• a make layer comprising a make layer precursor is applied to a major surface of the backing.
• Abrasive particles are then at least partially embedded into the make layer precursor (e.g., via electrostatic coating), and the make layer precursor is sufficiently cured (i.e., crosslinked) to secure the particles to the cured make layer precursor (i.e., the make layer).
• a size layer precursor is then applied over the make layer and abrasive particles, followed by at least partially curing the size layer precursor to provide a size layer.
• Some coated abrasive articles further comprise a supersize layer covering the abrasive layer.
• the supersize layer typically includes grinding aids and/or anti-loading materials.
• UV-curable compounds e g., ultraviolet (UV) and/or visible light-curable compounds
• the radiation- curable compounds are free-radically polymerizable (e.g., (meth)acrylic monomers).
• UV irradiation of the make layer precursor prior to abrasive particle coating can result in a make layer precursor that is partially gelled, so the mineral penetration into the precursor make layer can be well controlled, leading to improved mineral orientation as compared to thermal cured make layer precursors such as phenolic resins.
• such formulations typically involve free- radical polymerization (e.g., of (meth)acrylates), which can be inhibited by oxygen in the air, leading to an undercured surface and degraded abrading performance.
• methods of making coated abrasive articles according to the present disclosure can improve orientation of the abrasive particles during electrostatic deposition of the abrasive particles, and formulations exhibit good resistance to surface oxygen inhibition.
• the present disclosure provides a curable composition
• a curable composition comprising, based on the total weight of components a) through g): a) from 45 to 55 percent by weight of epoxy resin preparable by reaction of epichlorohydrin with at least one of bisphenol A or bisphenol F; b) from 6 to 12 percent by weight of an at least trifunctional (meth)aciylate; c) from 35 to 45 percent by weight of a polythiol; d) 0 to 10 percent by weight of dicyandiamide; e) 0.1 to 2 percent of free -radical photoinitiator; f) 0.5 to 1 percent by weight of 2-alkylimidazole; and g) 0 to 5 percent of phenolic resin.
• the present disclosure provides a coated abrasive article comprising a backing and an abrasive layer secured the backing, wherein the abrasive layer comprises a make layer disposed on at least a portion of a major surface of the backing, abrasive particles partially embedded in the make layer, and a size layer overlaying at least a portion of the make layer and abrasive particles, and wherein the make layer comprises a reaction product of components comprising, based on the total weight of components a) through g): a) from 45 to 55 percent by weight of epoxy resin preparable by reaction of epichlorohydrin with at least one of bisphenol A or bisphenol F; b) from 6 to 12 percent by weight of an at least trifunctional (meth)aciylate; c) from 35 to 45 percent by weight of a polythiol; d) 0 to 10 percent by weight of dicyandiamide; e) 0.1 to 2 percent of free -radical photoinitiator; f
• the present disclosure provides a method of making a coated abrasive article, the method comprising: providing a backing having first and second opposed major surfaces; disposing a curable make layer precursor on at least a portion of the first major surface, wherein the curable make layer precursor comprises, based on the total weight of components a) through g): a) from 45 to 55 percent by weight of epoxy resin preparable by reaction of epichlorohydrin with at least one of bisphenol A or bisphenol F; b) from 6 to 12 percent by weight of an at least trifiinctional (meth)acrylate; c) from 35 to 45 percent by weight of a polythiol; d) 0 to 10 percent by weight of dicyandiamide; e) 0.
• Coated abrasives according to the present disclosure are useful for abrading a workpiece by a method comprising: providing a coated abrasive article according to the present disclosure; frictionally contacting at least a portion of the abrasive layer with at least a portion of a surface of the workpiece; and moving at least one of the coated abrasive article or the workpiece relative to the other to abrade at least a portion of the surface.
• (meth)acryl essentially free of' means containing less than one weight percent of (e.g., less than 0. 1 weight percent of, 0.01 weight percent of, or 0 weight percent of); refers methacryl and/or acryl groups
• weight percent and “percent by weight” are interchangeable.
• Fig. 1 is a cross-sectional side view of an exemplary coated abrasive article according to the present disclosure.
• Curable compositions comprise, based on the total weight of components a) through g): a) from 45 to 55 percent by weight of epoxy resin preparable by reaction of epichlorohydrin with at least one of bisphenol A or bisphenol F; b) from 6 to 12 percent by weight of an at least trifunctional (meth)acrylate; c) from 35 to 45 percent by weight of a polythiol; d) 0 to 10 percent by weight of dicyandiamide; e) 0.1 to 2 percent of free-radical photoinitiator; f) 0.5 to 1 percent by weight of imidazole curative; and g) 0 to 5 percent of phenolic resin.
• Curable compositions according to the present disclosure comprise from 45 to 55 percent by weight of at least one epoxy resin preparable by reaction of epichlorohydrin with at least one of bisphenol A or bisphenol F, based on the total weight of components a) through g).
• epoxy resin may be liquid or solid. Whether liquid or solid, the epoxy resin may be chosen to be soluble in compositions according to the present disclosure. In some instances, heating compositions according to the present disclosure may facilitate dissolution of the epoxy resin.
• Examples of useful epoxy resins include the epoxy resins formed by reaction of bisphenol A or bisphenol F with epichlorohydrin, and mixtures of such resins.
• D.E.R. 331, D.E.R. 332, D.E.R. 351, D.E.R. 352, D.E.R. 354, and D.E.R. 356) marketed by Olin Chemical Company, Clayton, Missouri.
• Curable compositions according to the present disclosure comprise from 6 to 12 percent by weight of at least one at least trifunctional (meth)acrylate, based on the total weight of components a) through g).
• at least one trifunctional (meth)acrylate is meant a compound comprising at least three (e.g., For example, at least 3, 4, or even 5) (meth)acryloyloxy groups.
• curable compositions according to the present disclosure may comprise from 6 to 10, or from 9 to 12 percent by weight of polyfunctional urethane (meth)acrylate, based on the total weight of components a) through g). Blends of more than one trifunctional (meth)acrylate can also be used.
• Exemplary useful at least tnfimctional (meth)acrylates include trimethylolpropane tri(meth)acrylate, glycerol tri(meth)acrylate, pentaerythritol tri(meth)acrylate, ethoxylated trimethylolpropane tri(meth)acrylate, pentaerythritol tetra(meth)acrylate, dipentaerythritol penta(meth)acrylate, sorbitol tri(meth)acrylate, sorbitol hexa(meth) acrylate, and mixtures thereof.
• Curable compositions according to the present disclosure comprises 35 to 45 percent by weight of at least one polythiol (i.e., an organic polythiol), based on the total weight of components a) to f).
• the polythiol may have 2, 3, 4, 5, 6,7, 8, or more sulfhydryl (-SH) groups.
• polythiols having more than two thiol groups examples include propane-1, 2, 3-trithiol; 1,2- bis [(2-mercaptoethyl)thio] -3 -mercaptopropane; tetrakis(7 -mercapto-2,5 -dithiaheptyl)methane; and trithiocyanuric acid.
• Exemplary useful dithiols include 1,2-ethanedithiol, 1,2-propanedithiol, 1,3 -propanedithiol, 1,3 -butanedithiol, 1,4-butanedithiol, 2,3 -butanedithiol, 1,3-pentanedithiol, 1,5 -pentanedithiol, 1,6- hexanedithiol, l,3-dimercapto-3-methylbutane, dipentenedimercaptan, ethylcyclohexyldithiol (ECHDT), dimercaptodiethyl sulfide, methyl -substituted dimercaptodiethyl sulfide, dimethylsubstituted dimercaptodiethyl sulfide, dimercaptodioxaoctane, l,5-dimercapto-3-oxapentane,benz
• polythiols having more than two thiol groups examples include propane-1, 2, 3-trithiol; l,2-bis[(2-mercaptoethyl)thio]-3- mercaptopropane; tetrakis(7-mercapto-2,5-dithiaheptyl)methane; and trithiocyanuric acid. Also useful are polythiols formed from the esterification of polyols with thiol-containing carboxylic acids or their derivatives.
• polythiol compounds examples include, but are not limited to, esters of thioglycolic acid, a-mercaptopropionic acid, and p- mercaptopropionic acid with polyhydroxy compounds (polyols) such as diols (e.g., glycols), triols, tetrols, pentols, and hexols.
• polyols such as diols (e.g., glycols), triols, tetrols, pentols, and hexols.
• polythiols include, but are not limited to, ethylene glycol bis(thioglycolate), ethylene glycol bis(P-mercaptopropionate), trimethylolpropane tris(thioglycolate), trimethylolpropane tris( -mercaptopropionate) and ethoxylated versions, pentaerythritol tetrakis(thioglycolate), pentaerythritol tetrakis( -mercaptopropionate), and tris(hydroxyethyl)isocyanurate tris( -mercaptopropionate).
• these polyols are typically less desirable.
• Suitable polythiols also include those preparable by esterification of polyols with thiol- containing carboxylic acids or their derivatives, those prepared from a ring-opening reaction of epoxides with H2S (or its equivalent), those prepared from the addition of H2S (or its equivalent) across carbon-carbon double bonds, polysulfides, polythioethers, and polydiorganosiloxanes.
• these include the 3 -mercaptopropionates (also referred to as P-mercaptopropionates) of ethylene glycol and trimethylolpropane (the former from Chemische Fabrik GmbH & Co.
• polythiols can be formed from the addition of hydrogen sulfide (EfjS) (or its equivalent) across carbon-carbon double bonds.
• EfjS hydrogen sulfide
• dipentene and triglycerides which have been reacted with H2S (or its equivalent).
• specific examples include dipentene dimercaptan and those polythiols available as POLYMERCAPTAN 358 (mercaptanized soybean oil) and POLYMERCAPTAN 805C (mercaptanized castor oil) from Chevron Phillips Chemical Co. LLP.
• Useful polythiols of this type also include those derived from the reaction of H2S (or its equivalent) with the glycidyl ethers of bisphenol A epoxy resins, bisphenol F epoxy resins, and novolac epoxy resins.
• a preferred polythiol of this type is QX11, derived from bisphenol A epoxy resin, from Japan Epoxy Resins (JER) as EPOMATE.
• Other polythiols suitable include those available as EPOMATE QX10 and EPOMATE QX20 from JER.
• Still other useful polythiols are polysulfides that contain thiol groups such as those available as THIOKOL LP-2, LP-3, LP-12, LP-31, LP-32, LP-33, LP-977, and LP-980 from Toray Fine Chemicals Co., Ltd., and polythioether oligomers and polymers such as those described in PCT Publ. No. WO 2016/130673 Al (DeMoss et ak).
• Curable compositions according to the present disclosure comprise an optional amount of dicyandiamide for accelerating the cure of the composition.
• the curable composition comprises 2-alkylimidazole and may comprise 0 to 10 percent by weight of dicyandiamide, based on the total weight of components a) through g).
• Curable compositions according to the present disclosure comprise an effective amount of photoinitiator for curing the composition.
• the curable composition may comprise from 0.1 to 2 percent, or 0.3 to 1 percent, by weight of free-radical photoinitiator, based on the total weight of components a) through g).
• Useful free-radical photoinitiator may be a single photoinitiator or a combination of two or more photoinitiators.
• Photoinitiators useful in the practice of disclosure include those known as useful for free-radical photocuring of (meth)acrylates.
• Exemplary photoinitiators include benzoin and its derivatives such as a-methylbenzoin; a-phenylbenzoin; a-allylbenzoin; a-benzylbenzoin; benzoin ethers such as benzil dimethyl ketal, benzoin methyl ether, benzoin ethyl ether, benzoin n-butyl ether; acetophenone and its derivatives such as 2-hydroxy-2-methyl-l-phenyl-l-propanone, and 1- hydroxycyclohexyl phenyl ketone, 2-methyl-l-[4-(methylthio)phenyl]-2-(4-morpholinyl)-l-propanone, and 2-benzyl-2-(dimethylamino)- 1 -[4-(4-morpholinyl)phenyl] - 1 - butanone .
• benzoin and its derivatives such as a-methylbenzoin; a-phenylbenzo
• Curable compositions according to the present disclosure include 0 to 5 percent by weight (i.e., it is optional), based on the total weight of components a) to g) of phenolic resin. In some embodiments, 4 to 5 percent by weight, based on the total weight of components a) to g).
• Useful phenolic resins may include novolac phenolic and/or resole phenolic resin(s).
• novolac resins are made by reacting a phenolic monomer (e.g., phenol, cresol, xylenol, resorcinol, catechol, bisphenol A, naphthol, or a combination thereof) with an aldehyde in the presence of an acid catalyst, with the molar ratio of the aldehyde to phenol being less than one.
• aldehydes used to prepare novolacs include formaldehyde, acetaldehyde, propionaldehyde, glyoxal, and furfural.
• these novolac resins have a molecular weight ranging from 300 to 1,500, although higher and lower molecular weights may also be useful.
• the starting phenolic monomer can be substituted with various groups such as alkyl, alkoxy, carboxyl, and sulfo, as long as there are at least two reactive sites remaining to form the novolac.
• novolac phenolic resins are readily available from commercial suppliers including, for example, Georgia Pacific Resins, Atlanta, Georgia (e.g., as marketed under the trade designations "GP 2074", “GP 5300", “GP 5833", “RESI-FLAKE GP-2049", “RESI-FLAKE GP-2050", or “RESI- FLAKE GP-2211”); Bakelite AG, Frielendorf, Germany (e.g., as marketed under the trade designation "RUTAPHEN 8656F”); Borden Chemical, Inc (e.g., as marketed under the trade designations "DURITE 423 A” or “DURITE SD1731”). While novolac resins are typically useful, resole phenolic resins may tend to interfere with curing of curable compositions according to the present invention, and if included should be used with discretion.
• Curable compositions according to the present disclosure may further comprise an optional bireactive polymerizable component, for example, a compound having at least one free-radically polymerizable group, and at least one cationically polymerizable group.
• Bireactive compounds can be made, for example, by introducing at least one ethylenically unsaturated group into a compound that already contains one or more epoxy groups, or, conversely, by introducing at least one epoxy group into a compound that already contains one or more ethylenically unsaturated group.
• Curable compositions according to the present disclosure may be applied to a variety of substrates using conventional methods such as, for example, roll coating (e.g, using soft rubber rolls), spraying, transfer coating, dip coating, screen printing, gravure coating, curtain coating, bar coating, knife coating, or die coating. Curable compositions may be applied to a substrate in a uniform or patterned manner, and may be continuous or discontinuous.
• compositions comprising solid components
• such compositions may be prepared, for example, by mixing some or all of the various materials of the curable composition in a suitable vessel at an elevated temperature, for example, less than 100 °C, sufficient to liquify at least some of the materials so that they may be efficiently mixed, with stirring, to form the curable composition, but without thermally degrading the components.
• Curable compositions may be cured by exposure to thermal energy, actinic radiation, or more typically a combination thereof.
• curing of the curable composition typically begins upon exposing it to an appropriate source of actinic radiation (e.g., ultraviolet, visible, or particulate radiation), and may continue for a period thereafter.
• an appropriate source of actinic radiation e.g., ultraviolet, visible, or particulate radiation
• thermal energy include, for example, heat and infrared radiation.
• exemplary sources of thermal energy include ovens, heated rolls, hot air blowers, infrared lamps, and combinations thereof.
• the choice of the source of actinic radiation is typically selected depending on the intended processing conditions, and to appropriately activate the photoinitiator.
• exemplary useful sources of ultraviolet and visible radiation include mercury, xenon, carbon arc, tungsten filament lamps, and sunlight.
• Ultraviolet radiation especially from a medium pressure mercury arc lamp or a microwave driven H-type, D-type, or V-type mercury lamp, such as of those commercially available from Fusion UV Systems, Gaithersburg, Maryland, is especially desirable.
• Exposure times for the actinic radiation typically range, for example, from less than about 0.01 second to 1 minute or longer providing, for example, a total energy exposure from 0.1 to 10 Joules per square centimeter (J/cm ⁇ ) depending upon the amount and the type of reactive components involved, the energy source, web speed, the distance from the energy source, and the thickness of the make layer to be cured. Filters and/or dichroic reflectors may also be useful, for example, to reduce thermal energy that accompanies the actinic radiation.
• the dosage necessary is generally from less than 1 megarad to 100 megarads or more.
• exemplary coated abrasive article 100 comprises backing 112.
• Backing 112 may optionally be saturated with saturant 111.
• backing 112 may be treated with optional backsize layer 113 and/or optional presize layer 115.
• backsize layer 113 and presize layer 115 penetrate into the backing, and may even contact each other within the porous interior of the backing in some cases.
• abrasive layer 114 comprising make layer 116 in which are embedded abrasive grits 118 and size layer 117 which overlays make layer 116 and abrasive grits 118.
• Optional supersize layer 119 overlays size layer 117.
• Curable compositions according to the present disclosure may be applied onto a backing as a make layer precursor, which is then at least partially cured at an appropriate point in the manufacturing process to partially embed abrasive particles therein.
• the thickness of the backing generally ranges from 0.02 to 5 millimeters, for example, from 0.05 to 2.5 millimeters, or from 0.1 to 1 millimeter, although thicknesses outside of these ranges may also be useful.
• the backing may also be a laminate of two materials (e.g., paper/film, cloth/paper, or film/cloth).
• the backing may also be a fibrous reinforced thermoplastic such as described, for example, as described, for example, in U.S. Pat. No. 5,417,726 (Stout et al.), or an endless spliceless belt, as described, for example, in U.S. Pat. No. 5,573,619 (Benedict et al.), the disclosures of which are incorporated herein by reference.
• the backing may be a polymeric substrate having hooking stems projecting therefrom such as that described, for example, in U.S. Pat. No. 5,505,747 (Chesley et al.), or the backing may be a loop fabric such as that described, for example, in U.S. Pat. No. 5,565,011 (Follett et al.), the disclosures of which are incorporated herein by reference.
• the choice of backing material may depend on the intended application of the coated abrasive article.
• the thickness and smoothness of the backing should also be suitable to provide the desired thickness and smoothness of the coated abrasive article, wherein such characteristics of the coated abrasive article may vary depending, for example, on the intended application or use of the coated abrasive article.
• An antistatic material may be included in any of these backing treatment materials.
• the addition of an antistatic material can reduce the tendency of the coated abrasive article to accumulate static electricity when sanding wood or wood-like materials. Additional details regarding antistatic backings and backing treatments can be found in, for example, U.S. Pat. Nos. 5,108,463 (Buchanan et al .); 5,137,542 (Buchanan et al ); 5,328,716 (Buchanan); and 5,560,753 (Buchanan et al ), the disclosures of which are incorporated herein by reference.
• a pressure-sensitive adhesive onto the backside of the coated abrasive article such that the resulting coated abrasive article can be secured to a backup pad.
• exemplary pressure -sensitive adhesives include latex crepe, rosin, acrylic polymers, and copolymers including polyacrylate esters (e.g., poly(butyl acrylate)), vinyl ethers (e.g., poly(vinyl n- butyl ether)), alkyd adhesives, rubber adhesives (e.g., natural rubber, synthetic rubber, chlorinated rubber), and mixtures thereof.
• one or more surfaces of the backing may be modified by known methods including corona discharge, ultraviolet light exposure, electron beam exposure, flame discharge, and/or scuffing.
• the basis weight of the make layer utilized may depend, for example, on the intended use(s), type(s) of abrasive particles, and nature of the coated abrasive article being prepared, but generally will be in the range of from 1, 2, or 5 to 20, 25, 400, or even 600 grams per square meter (i.e., g/m ⁇ ).
• the curable make layer precursor may be applied by any known coating method for applying a make layer precursor to a backing, including, for example, roll coating, extrusion die coating, curtain coating, knife coating, gravure coating, and spray coating.
• abrasive particles are deposited onto the make layer, although typically after gelling of the make layer precursor by exposure to actinic radiation.
• Exemplary useful abrasive particles include fused aluminum oxide based materials such as aluminum oxide, ceramic aluminum oxide (which may include one or more metal oxide modifiers and/or seeding or nucleating agents), and heat-treated aluminum oxide, silicon carbide, co-fused alumina-zirconia, diamond, ceria, titanium diboride, cubic boron nitride, boron carbide, garnet, flint, emery, sol-gel derived abrasive particles, and blends thereof.
• Examples of sol-gel abrasive particles include those described U.S. Pat. Nos.
• the abrasive particles may be in the form of, for example, individual particles, agglomerates, abrasive composite particles, and mixtures thereof.
• the abrasive particles (and especially the abrasive particles) comprise ceramic abrasive particles such as, for example, sol-gel -derived polycrystalline alpha alumina particles.
• Ceramic abrasive particles composed of crystallites of alpha alumina, magnesium alumina spinel, and a rare earth hexagonal aluminate may be prepared using sol-gel precursor alpha alumina particles according to methods described in, for example, U.S. Pat. No. 5,213,591 (Celikkaya et al.) and U.S. Publ. Pat. Appln. Nos. 2009/0165394 Al (Culler et al.) and 2009/0169816 Al (Erickson et al.).
• useful abrasive particles may be shaped abrasive particles can be found in U.S. Pat. Nos. 5,201,916 (Berg); 5,366,523 (Rowenhorst (Re 35,570)); and 5,984,988 (Berg).
• U.S. Pat. No. 8,034,137 (Erickson et al.) describes alumina abrasive particles that have been formed in a specific shape, then crushed to form shards that retain a portion of their original shape features.
• the abrasive particles are precisely-shaped (i.e., the particles have shapes that are at least partially determined by the shapes of cavities in a production tool used to make them. Details concerning such abrasive particles and methods for their preparation can be found, for example, in U.S. Pat. Nos. 8,142,531 (Adefris et al.); 8,142,891 (Culler et al ); 8,142,532 (Erickson et al.); 9,771,504 (Adefris); and in U.S. Pat. Appl. Publ. Nos.
• One particularly useful precisely-shaped abrasive particle shape is that of a platelet having three-sidewalls, any of which may be straight or concave, and which may be vertical or sloping with respect to the platelet base; for example, as set forth in the above cited references.
• Surface coatings on the abrasive particles may be used to improve the adhesion between the abrasive particles and a binder material, or to aid in electrostatic deposition of the abrasive particles.
• surface coatings as described in U.S. Pat. No. 5,352,254 (Celikkaya) in an amount of 0.1 to 2 percent surface coating to abrasive particle weight may be used. Such surface coatings are described in U.S. Pat. Nos.
• the surface coating may prevent shaped abrasive particles from capping.
• Capping is the term to describe the phenomenon where metal particles from the workpiece being abraded become welded to the tops of the abrasive particles.
• the abrasive particles may be selected to have a length and/or width in a range of from 0.1 micrometers to 3.5 millimeters (mm), more typically 0.05 mm to 3.0 mm, and more typically 0.1 mm to 2.6 mm, although other lengths and widths may also be used.
• the abrasive particles may be selected to have a thickness in a range of from 0.1 micrometer to 1.6 mm, more typically from 1 micrometer to 1.2 mm, although other thicknesses may be used. In some embodiments, abrasive particles may have an aspect ratio (length to thickness) of at least 2, 3, 4, 5, 6, or more.
• Abrasive particles may be independently sized according to an abrasives industry recognized specified nominal grade.
• Exemplary abrasive industry recognized grading standards include those promulgated by ANSI (American National Standards Institute), FEPA (Federation of European Producers of Abrasives), and JIS (Japanese Industrial Standard).
• Such industry accepted grading standards include, for example: ANSI 4, ANSI 6, ANSI 8, ANSI 16, ANSI 24, ANSI 30, ANSI 36, ANSI 40, ANSI 50, ANSI 60, ANSI 80, ANSI 100, ANSI 120, ANSI 150, ANSI 180, ANSI 220, ANSI 240, ANSI 280, ANSI 320, ANSI 360, ANSI 400, and ANSI 600; FEPA P8, FEPA P12, FEPA P16, FEPA P24, FEPA P30, FEPA P36, FEPA P40, FEPA P50, FEPA P60, FEPA P80, FEPA P100, FEPA P120, FEPA P150, FEPA P180, FEPA P220, FEPA P240, FEPA P320, FEPA P400, FEPA P500, FEPA P600, FEPA P800, FEPA P1000, FEPA P1200; FEPA F8, FEPA F12, FEPA F16, and FEPA
• the crushed aluminum oxide particles and the non-seeded sol-gel derived alumina-based abrasive particles are independently sized to ANSI 60 and 80, or FEPA F36, F46, F54 and F60 or FEPA P60 and P80 grading standards.
• the abrasive particles can be graded to a nominal screened grade using U.S.A. Standard Test Sieves conforming to ASTM E-l 1 "Standard Specification for Wire Cloth and Sieves for Testing Purposes".
• ASTM E-l 1 prescribes the requirements for the design and construction of testing sieves using a medium of woven wire cloth mounted in a frame for the classification of materials according to a designated particle size.
• a typical designation may be represented as -18+20 meaning that the shaped abrasive particles pass through a test sieve meeting ASTM E-l 1 specifications for the number 18 sieve and are retained on a test sieve meeting ASTM E- 11 specifications for the number 20 sieve.
• the shaped abrasive particles have a particle size such that most of the particles pass through an 18 mesh test sieve and can be retained on a 20, 25, 30, 35, 40, 45, or 50 mesh test sieve.
• the shaped abrasive particles can have a nominal screened grade comprising: -18+20, -20+25, -25+30, -30+35, -35+40, -40+45, -45+50, -50+60, -60+70, -70+80, -80+100, -100+120, -120+140, -140+170, -170+200, -200+230, -230+270, -270+325, -325+400, -400+450, -450+500, or -500+635.
• a custom mesh size could be used such as -90+100.
• Exemplary agglomerates are described, for example, in U.S. Pat. Nos. 4,652,275 (Bloecher et al.) and 4,799,939 (Bloecher et al ), the disclosures of which are incorporated herein by reference. It is also within the scope of the present disclosure to use diluent erodible agglomerate grains as described, for example, in U.S. Pat. No. 5,078,753 (Broberg et al.), the disclosure of which is incorporated herein by reference.
• Abrasive composite particles comprise abrasive grains in a binder.
• Exemplary abrasive composite particles are described, for example, in U.S. Pat. No. 5,549,962 (Holmes et al.), the disclosure of which is incorporated herein by reference.
• Coating weights for the abrasive particles may depend, for example, on the specific coated abrasive article desired, the process for applying the abrasive particles, and the size of the abrasive particles, but typically range from 1 to 2000 g/m .
• a size layer precursor is then applied over the partially cured make layer and abrasive particles, followed by at least partially curing the size layer precursor to provide a size layer.
• Exemplary size layer precursors include phenolic resins, epoxy resins, acrylic monomers, and combinations thereof.
• the size layer precursor may be applied by applying and curing a curable size layer precursor using any known coating method including, for example, roll coating, extrusion die coating, curtain coating, or spray coating.
• a curable size layer precursor which may be the same as or different from the curable make layer precursor may include at least one curative is deposited over the at least partially cured make layer precursor and abrasive particles.
• the selection of curative will be influenced by the resin being cured. Selection of appropriate curative and amounts is within the capabilities of those skilled in the art.
• the basis weight of the size layer will also necessarily vary depending on the intended use(s), type(s) of abrasive particles, and nature of the coated abrasive article being prepared, but generally will be in the range of from 1 or 5 g/m 7 to 300, or even 800 g/m 7. or more.
• the optional supersize typically includes grinding aids and/or anti -loading materials.
• the optional supersize may serve to prevent or reduce the accumulation of swarf (the material abraded from a workpiece) between abrasive particles, which can dramatically reduce the cutting ability of the coated abrasive disc.
• Useful supersizes typically include a grinding aid (e.g., potassium tetrafluoroborate), metal salts of fatty acids (e.g., zinc stearate or calcium stearate), salts of phosphate esters (e.g., potassium behenyl phosphate), phosphate esters, urea-formaldehyde resins, mineral oils, crosslinked silanes, crosslinked silicones, and/or fluorochemicals.
• a grinding aid e.g., potassium tetrafluoroborate
• metal salts of fatty acids e.g., zinc stearate or calcium stearate
• salts of phosphate esters e.g., potassium behenyl phosphate
• phosphate esters e.g., potassium behenyl phosphate
• phosphate esters e.g., urea-formaldehyde resins
• mineral oils e.g., crosslinked silanes, crosslinked silicones
• the optional supersize can be disposed onto the size layer using any known coating method including, for example, roll coating, extrusion die coating, curtain coating, or spray coating.
• the amount of grinding aid incorporated into coated abrasive products is about 50 to about 400 gsm, more typically about 80 to about 300 gsm.
• the supersize may contain a binder such as for example, those used to prepare the size or make layer, but it need not have any binder.
• coated abrasive articles comprising abrasive particles and make, size, and optional supersize layers are well known and are described, for example, in U.S. Pat. Nos. 4,734,104 (Broberg); 4,737,163 (Larkey); 5,203,884 (Buchanan et al.); 5,152, 917 (Pieper et al.); 5,378,251 (Culler et al ); 5,417,726 (Stout et al.); 5,436,063 (Follett et al.); 5,496,386 (Broberg et al.); 5,609,706 (Benedict et al.); 5,520,711 (Helmin); 5,954, 844 (Law et al.); 5,961,674 (Gagliardi et al ); 4,751,138 (Bange et al.); 5,766,277 (DeVoe et al.); 6,077,601 (DeV
• Coated abrasive articles according to the present disclosure can be converted, for example, into belts, tapes, rolls, discs (including perforated discs), and/or sheets.
• two free ends of the abrasive sheet may be joined together using known methods to form a spliced belt.
• a spliceless belt may also be formed as described, for example, in U.S. Pat. No. 5,573,619 (Benedict et al.), the disclosure of which is incorporated herein by reference.
• Coated abrasive articles according to the present disclosure are useful for abrading a workpiece.
• One such method includes frictionally contacting at least a portion of the abrasive layer of a coated abrasive article with at least a portion of a surface of the workpiece, and moving at least one of the coated abrasive article or the workpiece relative to the other to abrade at least a portion of the surface.
• workpiece materials include metal, metal alloys, exotic metal alloys, ceramics, glass, wood, wood-like materials, composites, painted surfaces, plastics, reinforced plastics, stone, and/or combinations thereof.
• the workpiece may be flat or have a shape or contour associated with it.
• Exemplary workpieces include metal components, plastic components, particleboard, camshafts, crankshafts, furniture, and turbine blades.
• Coated abrasive articles according to the present disclosure may be used by hand and/or used in combination with a machine. At least one or both of the coated abrasive article and the workpiece is generally moved relative to the other when abrading.
• Abrading may be conducted under wet or dry conditions.
• Exemplary liquids for wet abrading include water, water containing conventional rust inhibiting compounds, lubricant, oil, soap, and cutting fluid.
• the liquid may also contain defoamers, degreasers, and/or the like.
• the present disclosure provides a curable composition
• a curable composition comprising, based on the total weight of components a) through g): a) from 45 to 55 percent by weight of epoxy resin preparable by reaction of epichlorohydrin with at least one of bisphenol A or bisphenol F; b) from 6 to 12 percent by weight of an at least trifunctional (meth) aery late; c) from 35 to 45 percent by weight of a polythiol; d) 0 to 10 percent by weight of dicyandiamide; e) 0.1 to 2 percent of free -radical photoinitiator; f) 0.5 to 1 percent by weight of 2-alkylimidazole; and g) 0 to 5 percent of phenolic resin
• the present disclosure provides a curable composition according to the first embodiment, wherein the curable composition is essentially free of phenolic resin.
• the present disclosure provides a curable composition according to the first or second embodiment, wherein the curable composition is essentially free of dissolved thermoplastic polymer.
• the present disclosure provides a curable composition according to any of the first to third embodiments, wherein the binder is essentially free of dicyandiamide.
• the present disclosure provides a coated abrasive article comprising a backing and an abrasive layer secured the backing, wherein the abrasive layer comprises a make layer disposed on at least a portion of a major surface of the backing, abrasive particles partially embedded in the make layer, and a size layer overlaying at least a portion of the make layer and abrasive particles, and wherein the make layer comprises a reaction product of components comprising, based on the total weight of components a) through g): a) from 45 to 55 percent by weight of epoxy resin preparable by reaction of epichlorohydrin with at least one of bisphenol A or bisphenol F; b) from 6 to 12 percent by weight of an at least trifunctional (meth)acrylate; c) from 35 to 45 percent by weight of a polythiol; d) 0 to 10 percent by weight of dicyandiamide; e) 0.1 to 2 percent of free -radical photoinitiator; f
• the present disclosure provides a coated abrasive article according to the fifth embodiment, wherein the make layer is essentially free of phenolic resin.
• the present disclosure provides a coated abrasive article according to any of the fifth or sixth embodiment, wherein the make layer is essentially free of dissolved thermoplastic polymer.
• the present disclosure provides a coated abrasive article according to any of the fifth to seventh embodiments, wherein the binder is essentially free of dicyandiamide.
• the present disclosure provides a coated abrasive article according to any of the fifth to eighth embodiments, wherein the backing comprises at least one of fabric, polymeric film, paper, mesh, vulcanized fiber, foil, or foam and has a basis weight in a range of from 40 to 1200 grams per square meter.
• the present disclosure provides a coated abrasive article according to any of the fifth to ninth embodiments, further comprising a supersize disposed on at least a portion of the size layer.
• the present disclosure provides a method of abrading a workpiece comprising: providing a coated abrasive article according to any of the fourth to tenth embodiments; frictionally contacting at least a portion of the abrasive layer with at least a portion of a surface of the workpiece; and moving at least one of the coated abrasive article or the workpiece relative to the other to abrade at least a portion of the surface.
• the present disclosure provides a method of making a coated abrasive article comprising: providing a backing having first and second opposed major surfaces; disposing a curable make layer precursor on at least a portion of the first major surface, wherein the curable make layer precursor comprises, based on the total weight of components a) through g): a) from 45 to 55 percent by weight of epoxy resin preparable by reaction of epichlorohydrin with at least one of bisphenol A or bisphenol F; b) from 6 to 12 percent by weight of an at least trifunctional (meth)acrylate; c) from 35 to 45 percent by weight of a polythiol; d) 0 to 10 percent by weight of dicyandiamide; e) 0.
• the present disclosure provides a method according to the twelfth embodiment, further comprising disposing a supersize layer over at least a portion of the size layer.
• the present disclosure provides a method according to the twelfth or thirteenth embodiment, wherein the binder is essentially free of phenolic resin.
• the present disclosure provides a method according to any of the twelfth to fourteenth embodiments, wherein the binder is essentially free of dissolved thermoplastic polymer. In a sixteenth embodiment, the present disclosure provides a method according to any of the twelfth to fifteenth embodiments, wherein the binder is essentially free of dicyandiamide.
• the present disclosure provides a method according to any of the twelfth to sixteenth embodiments, wherein the backing comprises at least one of fabric, polymeric film, paper, mesh, vulcanized fiber, foil, or foam and has a basis weight in a range of from 40 to 1200 grams per square meter.
• EPOXY 47.44 parts by weight of EPOXY was mixed with 11.21 parts by weight of TMPTA at room temperature until homogeneous using a mechanical stirrer, and then 0.33 parts by weight of BDK was added during stirring. The mixture was heated to 60 °C. After BDK was completely dissolved, 40.27 parts by weight of PETMP and 0.75 parts by weight of 2-PI were added and mixed until homogeneous.
• SAP and ALO were pre-blended with a 50/50 ratio by weight.
• 0.6 grams of the blended minerals were uniformly dispersed on a 10.16 cm x 22.86 cm mineral bed.
• the treatment solution resin obtained above was coated using a draw-down scraper on a 11.4 cm x 25.4 cm sheet of PET at a gap of 25.4 pm on an area equal to the mineral bed.
• the make coat weight was 0.4 grams.
• the coated film was placed on a conveyer at 12 fpm with the make coating facing up and going through UV irradiation generated by a H bulb (300 WPI). The film was then placed right above the mineral bed with the coat side facing down to the minerals and the coating area well aligned with the mineral dispersion.
• Minerals were coated electrostatically in a 15-17 kV direct current electric field. Mineral coat weight was about 0.3 g.
• the coated sample was placed in an oven at 140 °C for 5 minutes to cure for peak count analysis.
• SAP and ALO were pre-blended with a 50/50 ratio by weight.
• 0.6 grams of the blended minerals were uniformly dispersed on a 10.16 cm x 22.86 cm mineral bed.
• MR1 was coated using a draw-down scraper on a 11.4 cm x 25.4 cm sheet of PET at a gap of 50.8 pm on an area equal to the mineral bed.
• the film was then placed right above the mineral bed with the coat side facing down to the minerals and the coating area well aligned with the mineral dispersion.
• Minerals were coated electrostatically in a 15-17 kV direct current electric field. Mineral coat weight was about 0.3 g.
• the coated sample was placed in an oven at 90 °C for 1 hour and 105 °C for 1 hour sequentially to cure for peak count analysis.

Landscapes

• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Medicinal Chemistry (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Polymers & Plastics (AREA)
• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Life Sciences & Earth Sciences (AREA)
• Materials Engineering (AREA)
• Wood Science & Technology (AREA)
• Manufacturing & Machinery (AREA)
• Polishing Bodies And Polishing Tools (AREA)
• Epoxy Resins (AREA)

Applications Claiming Priority (2)

Publications (1)

Family

ID=85873669

Family Applications (1)

Country Status (3)

Family Cites Families (77)

• 2023
  • 2023-03-16 EP EP23715233.5A patent/EP4496679A1/de active Pending
  • 2023-03-16 WO PCT/IB2023/052575 patent/WO2023180880A1/en active Application Filing
  • 2023-03-16 CN CN202380028972.9A patent/CN118900748A/zh active Pending

Also Published As

Similar Documents

Legal Events