EP3922704A1 - Composition pour l'entretien du linge ou de la vaisselle comprenant un dérivé de poly alpha-1,6-glucane - Google Patents

Composition pour l'entretien du linge ou de la vaisselle comprenant un dérivé de poly alpha-1,6-glucane Download PDF

Info

Publication number: EP3922704A1
Authority: EP; European Patent Office
Prior art keywords: glucan; group; poly alpha; alpha; composition
Prior art date: 2020-06-10
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

EP20180331.9A

Other languages

German (de)

English (en)

Inventor

Gang SI

Mark Robert Sivik

Zheng-zheng HUANG

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Procter and Gamble Co

Original Assignee

Procter and Gamble Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2020-06-10

Filing date

2020-06-16

Publication date

2021-12-15

2020-06-16 Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co

2021-12-15 Publication of EP3922704A1 publication Critical patent/EP3922704A1/fr

Status Withdrawn legal-status Critical Current

Links

229920001503 Glucan Polymers 0.000 title claims abstract description 232
239000000203 mixture Substances 0.000 title claims abstract description 232
125000000962 organic group Chemical group 0.000 claims abstract description 86
230000002209 hydrophobic effect Effects 0.000 claims abstract description 84
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 73
239000008103 glucose Substances 0.000 claims abstract description 67
239000000178 monomer Substances 0.000 claims abstract description 66
238000006467 substitution reaction Methods 0.000 claims abstract description 53
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 38
238000006116 polymerization reaction Methods 0.000 claims abstract description 18
125000001033 ether group Chemical class 0.000 claims abstract description 12
-1 carbonate ester Chemical class 0.000 claims description 92
229920000642 polymer Polymers 0.000 claims description 65
239000003599 detergent Substances 0.000 claims description 62
102000004190 Enzymes Human genes 0.000 claims description 52
108090000790 Enzymes Proteins 0.000 claims description 52
229940088598 enzyme Drugs 0.000 claims description 51
125000000217 alkyl group Chemical group 0.000 claims description 50
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 41
239000003795 chemical substances by application Substances 0.000 claims description 39
108010059892 Cellulase Proteins 0.000 claims description 36
229940106157 cellulase Drugs 0.000 claims description 32
239000004721 Polyphenylene oxide Substances 0.000 claims description 26
229920000570 polyether Polymers 0.000 claims description 26
239000004094 surface-active agent Substances 0.000 claims description 24
125000002768 hydroxyalkyl group Chemical group 0.000 claims description 21
125000003118 aryl group Chemical group 0.000 claims description 20
239000007844 bleaching agent Substances 0.000 claims description 19
239000002304 perfume Substances 0.000 claims description 19
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229910052736 halogen Inorganic materials 0.000 claims description 10
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125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 9
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XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 44
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238000000034 method Methods 0.000 description 30
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239000000047 product Substances 0.000 description 28
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125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 14
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238000004140 cleaning Methods 0.000 description 13
238000004851 dishwashing Methods 0.000 description 13
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YYROPELSRYBVMQ-UHFFFAOYSA-N 4-toluenesulfonyl chloride Chemical compound CC1=CC=C(S(Cl)(=O)=O)C=C1 YYROPELSRYBVMQ-UHFFFAOYSA-N 0.000 description 12
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
239000002202 Polyethylene glycol Substances 0.000 description 12
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150000002170 ethers Chemical class 0.000 description 11
239000000835 fiber Substances 0.000 description 11
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
238000005481 NMR spectroscopy Methods 0.000 description 10
WQZGKKKJIJFFOK-DVKNGEFBSA-N alpha-D-glucose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-DVKNGEFBSA-N 0.000 description 10
229910052799 carbon Inorganic materials 0.000 description 10
235000014113 dietary fatty acids Nutrition 0.000 description 10
239000000194 fatty acid Substances 0.000 description 10
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150000002191 fatty alcohols Chemical class 0.000 description 10
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 10
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125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 9
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XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 8
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239000007787 solid Substances 0.000 description 8
QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 7
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CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 6
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
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DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 6
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239000004115 Sodium Silicate Substances 0.000 description 6
OHVGNSMTLSKTGN-BTVCFUMJSA-N [C].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O Chemical group [C].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O OHVGNSMTLSKTGN-BTVCFUMJSA-N 0.000 description 6
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125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
238000001956 neutron scattering Methods 0.000 description 1
VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 1
229920000847 nonoxynol Polymers 0.000 description 1
239000004745 nonwoven fabric Substances 0.000 description 1
125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
235000012149 noodles Nutrition 0.000 description 1
229920001778 nylon Polymers 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000011368 organic material Substances 0.000 description 1
SJGALSBBFTYSBA-UHFFFAOYSA-N oxaziridine Chemical compound C1NO1 SJGALSBBFTYSBA-UHFFFAOYSA-N 0.000 description 1
239000005022 packaging material Substances 0.000 description 1
239000006072 paste Substances 0.000 description 1
235000010603 pastilles Nutrition 0.000 description 1
125000002255 pentenyl group Chemical group C(=CCCC)* 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
150000004968 peroxymonosulfuric acids Chemical class 0.000 description 1
125000005561 phenanthryl group Chemical group 0.000 description 1
SIENSFABYFDZCL-UHFFFAOYSA-N phenyl decanoate Chemical compound CCCCCCCCCC(=O)OC1=CC=CC=C1 SIENSFABYFDZCL-UHFFFAOYSA-N 0.000 description 1
ZPORCTAUIXXZAI-UHFFFAOYSA-N phenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC1=CC=CC=C1 ZPORCTAUIXXZAI-UHFFFAOYSA-N 0.000 description 1
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000006187 pill Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920005640 poly alpha-1,3-glucan Polymers 0.000 description 1
229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
229920000196 poly(lauryl methacrylate) Polymers 0.000 description 1
229920001748 polybutylene Polymers 0.000 description 1
238000006068 polycondensation reaction Methods 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920001444 polymaleic acid Polymers 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
229920001343 polytetrafluoroethylene Polymers 0.000 description 1
239000004810 polytetrafluoroethylene Substances 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
235000019252 potassium sulphite Nutrition 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
238000007639 printing Methods 0.000 description 1
125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical compound CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
229920005604 random copolymer Polymers 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000004044 response Effects 0.000 description 1
238000000518 rheometry Methods 0.000 description 1
238000011012 sanitization Methods 0.000 description 1
235000003441 saturated fatty acids Nutrition 0.000 description 1
238000009991 scouring Methods 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
230000001953 sensory effect Effects 0.000 description 1
238000000235 small-angle X-ray scattering Methods 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
235000017281 sodium acetate Nutrition 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
235000019254 sodium formate Nutrition 0.000 description 1
239000012312 sodium hydride Substances 0.000 description 1
229910000104 sodium hydride Inorganic materials 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
235000019794 sodium silicate Nutrition 0.000 description 1
229940080313 sodium starch Drugs 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
239000013042 solid detergent Substances 0.000 description 1
LJFWQNJLLOFIJK-UHFFFAOYSA-N solvent violet 13 Chemical compound C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O LJFWQNJLLOFIJK-UHFFFAOYSA-N 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
238000004611 spectroscopical analysis Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000001370 static light scattering Methods 0.000 description 1
238000004659 sterilization and disinfection Methods 0.000 description 1
238000012916 structural analysis Methods 0.000 description 1
125000003107 substituted aryl group Chemical group 0.000 description 1
150000003457 sulfones Chemical class 0.000 description 1
150000003461 sulfonyl halides Chemical class 0.000 description 1
YEOUFHBJWTZWCZ-UHFFFAOYSA-M sulforhodamine G Chemical compound [Na+].C=12C=C(C)C(NCC)=CC2=[O+]C=2C=C(NCC)C(C)=CC=2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O YEOUFHBJWTZWCZ-UHFFFAOYSA-M 0.000 description 1
238000004381 surface treatment Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
239000013501 sustainable material Substances 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
DCQJDRNKCUQEMA-UHFFFAOYSA-N tetradecanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCCCCCC(=O)OO DCQJDRNKCUQEMA-UHFFFAOYSA-N 0.000 description 1
FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
125000001412 tetrahydropyranyl group Chemical group 0.000 description 1
UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 description 1
230000008719 thickening Effects 0.000 description 1
229930192474 thiophene Natural products 0.000 description 1
GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
150000003626 triacylglycerols Chemical class 0.000 description 1
235000011178 triphosphate Nutrition 0.000 description 1
239000001226 triphosphate Substances 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
VRVDFJOCCWSFLI-UHFFFAOYSA-K trisodium 3-[[4-[(6-anilino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-5-methoxy-2-methylphenyl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].COc1cc(N=Nc2cc(c3cccc(c3c2)S([O-])(=O)=O)S([O-])(=O)=O)c(C)cc1N=Nc1c(O)c2ccc(Nc3ccccc3)cc2cc1S([O-])(=O)=O VRVDFJOCCWSFLI-UHFFFAOYSA-K 0.000 description 1
238000005199 ultracentrifugation Methods 0.000 description 1
125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000000214 vapour pressure osmometry Methods 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
239000003981 vehicle Substances 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
229920003169 water-soluble polymer Polymers 0.000 description 1
239000002023 wood Substances 0.000 description 1
210000002268 wool Anatomy 0.000 description 1
230000037303 wrinkles Effects 0.000 description 1
229920001285 xanthan gum Polymers 0.000 description 1
239000000230 xanthan gum Substances 0.000 description 1
235000010493 xanthan gum Nutrition 0.000 description 1
229940082509 xanthan gum Drugs 0.000 description 1
239000001018 xanthene dye Substances 0.000 description 1
125000005023 xylyl group Chemical group 0.000 description 1
150000003751 zinc Chemical class 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/228—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with phosphorus- or sulfur-containing groups

Definitions

the weight average molecular weight can be determined by other techniques such as static light scattering, mass spectrometry especially MALDI-TOF (matrix-assisted laser desorption/ionization time-of-flight), small angle X-ray or neutron scattering, and ultracentrifugation.
number average molecular weight refers to the statistical average molecular weight of all the polymer chains in a sample.
the number average molecular weight of a polymer can be determined by various colligative methods such as vapor pressure osmometry or end-group determination by spectroscopic methods such as proton NMR, FTIR, or UV-vis.
the glycosidic linkage profile of a glucan, dextran, substituted glucan, or substituted dextran can be determined using any method known in the art.
a linkage profile can be determined using methods that use nuclear magnetic resonance (NMR) spectroscopy (e.g., 13 C NMR or 1 H NMR). These and other methods that can be used are disclosed in Food Carbohydrates: Chemistry, Physical Properties, and Applications (S. W. Cui, Ed., Chapter 3, S. W. Cui, Structural Analysis of Polysaccharides, Taylor & Francis Group LLC, Boca Raton, FL, 2005 ), which is incorporated herein by reference.
NMR nuclear magnetic resonance
the poly alpha-1,6-glucan derivatives disclosed herein comprise water-soluble poly alpha-1,6-glucan comprising a backbone of glucose monomer units wherein greater than or equal to 40% of the glucose monomer units are linked via alpha-1,6-glycosidic linkages, and optionally at least 5% of the backbone glucose monomer units have branches via alpha-1,2 and/or alpha-1,3-glycosidic linkages.
the backbone of the poly alpha-1,6-glucan derivative can comprise, for example, 0.5%, 1%, 2%, 3%, 4%, 5%, 10%, 15%, 20%, 25%, 30%, 35%, 40%, 45%, 50%, 55%, or 60% glucose monomer units which are linked via alpha-1,2, alpha-1,3, and/or alpha-1,4 glycosidic linkages.
the poly alpha-1,6-glucan derivative comprises a backbone that is linear (unbranched).
an alkenyl group can contain one or more heteroatoms such as oxygen, sulfur, and/or nitrogen within the hydrocarbon chain, for example an alkenyl group can contain a moiety derived from ring-opening of an allyl glycidyl ether.
an alkenyl group can contain one or more heteroatoms such as oxygen and/or sulfur within the hydrocarbon chain.
the poly alpha-1,6-glucan derivative has a DoS of about 0.20 to about 0.60, at least one linkage moiety is -OSO 2 - and at least one linkage moiety is -O-, and at least one hydrophobic organic group is a methyl, ethyl, phenyl, benzyl, or p-tolyl group.
the linkage moiety is - OSO 2 -
the DoS is about 0.001 to about 1.5
at least one organic group comprises a C 1 to C 18 alkyl group, a hydroxy alkyl group, a carboxy alkyl group, a C 2 to C 18 alkenyl group, a C 2 to C 18 alkynyl group, a benzyl group, a C 6 to C 20 aryl group, a polyether comprising repeat units of (-CH 2 CH 2 O-) and/or (-CH 2 CH(CH 3 )O-) wherein the total number of repeat units is in the range of from 3 to 100, or a combination thereof.
the linkage moiety is -OSO 2 -
the DoS is about 0.001 to about 1.5
at least one organic group comprises a C 1 - C 10 alkyl group, C 1 -C 10 hydroxyl alkyl group, a polyether comprising repeat units of (-CH 2 CH 2 O-) and/or (-CH 2 CH(CH 3 )O-) wherein the total number of repeat units is in the range of from 3 to 100, a benzyl group, or a combination thereof.
the linkage moiety is -OSO 2 -
the DoS is about 0.001 to about 1.5
at least one organic group comprises a C 6 -C 20 aryl group, optionally substituted with alkyl groups.
the benzyl group of the benzylating agent can optionally substituted by one or more of halogen, a cyano, an ester, an amide, an ether group, a C 1 to C 6 alkyl group, an aryl group, a C 2 to C 6 alkene group, a C 2 to C 6 alkyne group, or any combination thereof.
the polysaccharide derivative is resistant to multiple classes of enzymes, for example, two or more cellulases, proteases, amylases, lipases, mannanases, or combinations thereof. Resistance to any particular enzyme will be defined as having at least 10, 20, 30, 40, 50, 60, 70, 80, 90, 95 or 100% of the materials remaining after treatment with the respective enzyme. The percentage remaining may be determined by measuring the supernatant after enzyme treatment using SEC-HPLC.
the assay to measure enzyme resistance can be determined using the following procedure: A sample of the poly alpha-1,6-glucan derivative is added to water in a vial and mixed using a PTFE magnetic stir bar to create a 1 percent by weight aqueous solution.
the composition may comprise from about 25% to about 99.99% by weight of the water-soluble carrier, and from about 0.01% to about 30% by weight of the poly alpha-1, 6-glucan ether compound.
the particles may further comprise an additional benefit agent, such as a poly alpha-1,6-glucan derivative, a surfactant, a perfume, a conditioning agent (e.g., a quaternary ammonium compound and/or a silicone), or mixtures thereof.
the particles may be first particles and may be part of a plurality of particles that further comprise second particles.
the plurality of particles may include first particles and second particles, where the particles that comprise the poly alpha-1,6-glucan ether compound are the first particles, and wherein the second particles comprise a different benefit agent, such as perfume, which may be unencapsulated perfume, encapsulated perfume, or a mixture thereof.
the particles may be used in combination with a detergent composition, for example concurrently during a wash cycle, or subsequently during a rinse cycle.
Suitable enzymes are known in the art and can include, for example, MAXATASE ® , MAXACAL TM , MAXAPEM TM , OPTICLEAN ® , OPTIMASE ® , PROPERASE ® , PURAFECT ® , PURAFECT ® OXP, PURAMAX TM , EXCELLASE TM , PREFERENZ TM proteases (e.g. P100, P110, P280), EFFECTENZ TM proteases (e.g. P1000, P1050, P2000), EXCELLENZ TM proteases (e.g.
the compositions can comprise from about 0.0001 % to about 10%, from about 0.01% to about 5%, or even from about 0.1 % to about 3% by weight of the dye transfer inhibiting agent, based on the total weight of the composition.
Components that may be included in certain embodiments of a dishwashing detergent composition include, for example, one or more of a phosphate; oxygen- or chlorine-based bleaching agent; non-ionic surfactant; alkaline salt (e.g., metasilicates, alkali metal hydroxides, sodium carbonate); any active enzyme disclosed herein; anti-corrosion agent (e.g., sodium silicate); anti-foaming agent; additives to slow down the removal of glaze and patterns from ceramics; perfume; anti-caking agent (in granular detergent); starch (in tablet-based detergents); gelling agent (in liquid/gel based detergents); and/or sand (powdered detergents).
alkaline salt e.g., metasilicates, alkali metal hydroxides, sodium carbonate
anti-corrosion agent e.g., sodium silicate
anti-foaming agent additives to slow down the removal of glaze and patterns from ceramics
perfume anti-caking agent (in
the treatment provides a benefit to the substrate, for example improved resistance to soil deposition, improved stain resistance, improved cleaning performance, or any combination thereof.
the step of contacting can include wiping or spraying the substrate with the composition.
hydrophobic substituent it is typically meant not a hydrophilic substituent.

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Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Chemical & Material Sciences (AREA)
Molecular Biology (AREA)
Emergency Medicine (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Cosmetics (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)

EP20180331.9A 2020-06-10 2020-06-16 Composition pour l'entretien du linge ou de la vaisselle comprenant un dérivé de poly alpha-1,6-glucane Withdrawn EP3922704A1 (fr)

Applications Claiming Priority (1)

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US202063037016P	2020-06-10	2020-06-10

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Publication Number	Publication Date
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EP4321604A1 (fr)	2022-08-08	2024-02-14	The Procter & Gamble Company	Tissu et composition de soins à domicile comprenant un tensioactif et un polyester
WO2024094803A1 (fr)	2022-11-04	2024-05-10	The Procter & Gamble Company	Composition d'entretien textile et ménager
WO2024094802A1 (fr)	2022-11-04	2024-05-10	The Procter & Gamble Company	Tissu et composition d'entretien ménager
WO2024094800A1 (fr)	2022-11-04	2024-05-10	The Procter & Gamble Company	Composition d'entretien textile et ménager
WO2024119298A1 (fr)	2022-12-05	2024-06-13	The Procter & Gamble Company	Composition de soin textile et ménager comprenant un composé de carbonate de polyalkylène
EP4386074A1 (fr)	2022-12-16	2024-06-19	The Procter & Gamble Company	Composition de soin pour le linge et le domicile
WO2024129520A1 (fr)	2022-12-12	2024-06-20	The Procter & Gamble Company	Composition de soin textile et ménager
EP4458933A1 (fr)	2023-05-05	2024-11-06	The Procter & Gamble Company	Composition de tissu et de soins à domicile comprenant un polyol propoxylé
EP4458932A1 (fr)	2023-05-04	2024-11-06	The Procter & Gamble Company	Tissu et composition de soins à domicile
EP4484536A1 (fr)	2023-06-26	2025-01-01	The Procter & Gamble Company	Composition de soin pour le linge et le domicile

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