Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
  • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
  • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
  • B65D81/18—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
  • B65D81/20—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas
  • B65D81/2007—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas under vacuum
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
  • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
  • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
  • B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
  • B65B11/00—Wrapping, e.g. partially or wholly enclosing, articles or quantities of material, in strips, sheets or blanks, of flexible material
  • B65B11/50—Enclosing articles, or quantities of material, by disposing contents between two sheets, e.g. pocketed sheets, and securing their opposed free margins
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
  • B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
  • B65B31/00—Packaging articles or materials under special atmospheric or gaseous conditions; Adding propellants to aerosol containers

Definitions

• the present invention is in the field of detergents.
• it relates to a package containing detergent in unitized form.
• the package is suitable for posting.
• E-commerce is becoming common practice. It involves shopping for a product on-line and the product sent to the buyer. Commonly, the product is delivered through the letter box. Letter boxes have a slot of fix geometry and size. Detergents have traditionally been packed to be stored in warehouses and then on shops shelves. Conventional packaging does not seem to be suitable for postal delivery.
• WO2017/198564 A1 relates to a box for sending laundry detergent capsules.
• the box is made of any conventional box material, such as cardboard, plastics, wood and reinforced paper.
• the box of '564 either requires strong and expensive material or does not provide enough protection for the laundry detergent capsules. Protection is even more important in the case of liquid containing capsules because the capsules can leak and spoilt the rest of the capsules in the box.
• a vacuum pack encasing unitized detergent portions.
• the vacuum pack has an on-pack label. It has been surprisingly found that by vacuum packing the unitized detergent portions, robustness and stability is conferred to the detergent portions contributing to the physical and chemical stability of the unitized detergent portions.
• the vacuum pack protects the unitized detergent portions from air, moisture and avoids the transfer of volatiles actives, such as perfume.
• the label can be either adhered to the inside or outside of the vacuum pack or can be printed on the inside or the outside of the vacuum pack. The label not only gives information about the product but also protects the detergent portions from the light.
• Some of the detergent portions contain light sensitive ingredients, such as metal catalysts, dyes and pigments, that can deteriorate with time if they are exposed to light.
• a significant advantage of vacuum packaging is that the pack volume is virtually the same as the product volume, with no 'empty' space inside the pack. This is very useful, especially during shipping.
• the pack is flexible but at the same time very robust. Flexibility can be achieved by arranging the unitized detergent portions in parallel rows, the pack can be bent along the lines formed by the aligned portions. Alternatively, the unitized detergent portions can be arranged in an off-set fashion, this arrangement confers rigidity to the pack.
• An example of off-set arrangement is brick configuration, i.e., as bricks are arranged to make a wall. The pack is difficult to be open by pets.
• the pack may comprise a zipped lock that allows closure of the pack once it has been open to provide moisture and air protection to the unitized detergent portions after the pack has been open.
• a method of sending unitized detergent portions to a buyer comprising delivering the pack of the invention to the buyer, preferably by post.
• the vacuum pack is sent without a secondary package, ie, the vacuum pack does not need to be inserted in a box or any other container. It has been surprisingly found that the vacuum pack provides enough strength for the unitized detergent portions during transport and delivery.
• the pack of the invention is light and flexible and therefore very convenient for transport and delivery even for delivery through letter boxes with difference shape slots.
• unitized detergent portion is herein meant that the detergent is provided in a form that is sufficient for one cleaning operation, for example for one wash.
• Unitized detergent portions include tablets, sachets, capsules, pouches, etc.
• Preferred for use herein are portions enveloped by film, preferably water-soluble film, for example polyvinyl alcohol.
• Especially preferred detergent portions are wrapped in a polyvinyl alcohol film having a thickness of less than 100 ⁇ m.
• the unitized detergent portions packed in the vacuum pack of the invention preferably weigh from about 8 to about 25 grams, preferably from about 10 to about 20 grams.
• the water-soluble material may include one or more water-soluble polymers.
• the water soluble material includes polyvinyl alcohol, a modified polyvinyl alcohol, polyvinyl acetate, polyacrylates, water soluble acrylate copolymers, polyaminopropyl sulfonic acid and salts thereof, polyitaconic acid and salts thereof, polyacrylamides, polyvinylpyrrolidone, pullalan, cellulosics (such as carboxymethylcellulose and hydroxypropyl methyl cellulose), water-soluble natural polymers (such as guar gum, xanthan gum, carrageenan and starch), water-soluble polymer derivatives (such as modified starches, including ethoxylated starch and hydroxylated propylstarch, poly(sodium acryloamido-2- methylpropane sulfonate, polymonomethylmaleate and salts thereof), copolymers thereof and combinations thereof.
• the water soluble material includes, or consists essentially of, polyvinyl alcohol, a modified polyvinyl alcohol, polyvinyl acetate, carboxymethylcellulose or hydroxypropyl methyl cellulose.
• the water-soluble material includes, or consists essentially of, polyvinyl alcohol, polyvinyl acetate and/or a modified polyvinyl alcohol.
• Polyvinyl alcohol, polyvinyl acetate and modified polyvinyl alcohols can provide stable water-soluble substrates that have suitable dissolution rates.
• the water-soluble material may also contain one or more plasticizers.
• plasticizers include, but are not limited to glycerol, glycerin, diglycerin, ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, monopropylene glycol, polyethylene glycol, neopentyl glycol, trimethylpropane polyether polyols, sorbitol, ethanolamines and mixtures thereof.
• the plasticizer when present, may be included in the water-soluble material in an appropriate amount, as generally known.
• the detergent portions can be placed resting on one their bases and arranged side-to-side in rows without leaving space between them or leaving as little space as possible among them.
• the detergent portions can be arranged in monolayers, preferably the pack only comprises one monolayer. When the detergent portions are packed in this disposition the portions present good resistance to breakage and in the case of detergent portions containing liquid the chance of leaking is negated or greatly reduced.
• the rows are parallel. This disposition provides flexibility between the rows.
• the unitized detergent portions can be arranged off-set from one another in a brick like fashion.
• the vacuum pack is not only beneficial in terms of physical robustness of the detergent portions but also contributes to the chemical stability of the detergent portions, especially when the detergent portions contain moisture sensitive ingredients such as bleach, enzymes, etc.
• unitized detergent portions comprising compositions in different forms, for example solid and liquid, avoid the transfer of components between the different forms and also the loss of volatiles such a perfume
• the unitized detergent portions are wrapped in a film, more preferably in a water-soluble film.
• deformable unitized detergent portions such as capsules or pouches comprising loose powder and/or liquid compositions.
• Preferred unitized detergent portions include single and multi-compartment pouches, including multi-compartment pouches with liquids in the different compartments or multi-compartment pouches with powder and liquid in different compartments, as for example described in EP 1504994A1 .
• pouches comprising a powder compartment and superposed side-by side liquid compartments, as for example described in EP 1 392 812 A1 .
• the footprint of the unitized detergent portions may be circular, elliptical, triangular, square, rectangular, rounded square, rounded rectangle, truncated circle, squircle, pentagonal or hexagonal in shape.
• the footprint is square or rectangular.
• the unitized detergent portions of the present invention preferably have a height of between 1.5 and 3 cm.
• the height allows the unitized detergent portions to be packaged in a two-dimensional array with a height of less than 3.1 cm. Accordingly, the vacuum pack can fit through a conventional mail slot.
• the height of the capsule is in the range of 1.7 to 2.5 cm.
• the unitized detergent portions base has a lateral dimension of between 2.0 and 5.0 cm, preferably in the range of 2.5 to 4.5 cm.
• the detergent can be any surface treating composition.
• the surface treatment composition is selected from the group consisting of a fabric conditioner, a laundry conditioner, a fabric detergent, a laundry detergent, a laundry rinse additive, a hard surface cleaner, a hard surface treatment composition, an air care composition, a car care composition, a dishwashing composition, a composting composition, a cleaning product, and combinations thereof. Laundry and dishwashing compositions are preferred herein. If the detergent is wrapped with a water-insoluble film the film is removed before use. If the detergent is wrapped with a water-soluble film, then the water-soluble film would dissolve in water to release the detergent composition enclosed within it.
• Such detergent compositions may be in solid, granular, gel or liquid form or a combination thereof.
• the detergent composition typically comprises surfactant, enzymes, builders and optionally bleach and other cleaning adjuncts.
• laundry detergent cleaning adjuncts include optical brightener, soil suspending polymer, etc.
• the composition comprises glass care agent, dispersant polymers, bleach, metal bleach catalyst, etc.
• the detergent can also comprise perfume and dyes.
• Vacuum packing is a method of packaging that removes air from the package prior to sealing. This method involves (manually or automatically) placing items in a plastic film package, removing air from inside, and sealing the package.
• the film is flexible and have low oxygen permeability.
• Vacuum packing provides a tight fit to the contents.
• the intent of vacuum packing is usually to remove oxygen from the container package to improve the chemical stability of the unitized detergent portions. Even if the detergent portions are enveloped by a film, oxygen and moisture go through the film.
• the vacuum pack protects against oxygen and moisture transfer.
• air is evacuated either by nozzle vacuuming or by chamber vacuuming from package and same atmosphere is maintained till heat sealing, while doing so pressure difference exists between the package exterior and interior causing collapse in packages.
• O2 barrier materials and high levels of seal integrity are required. Although the requisite O2 barrier for vacuum packaging depends on the type of detergent packaged, O2 transmission rates of less than 15 cm3 m-2 day-1 atm-1 are generally desirable. Also, packaging materials with low WVTRs should be used. Typical vacuum packaging materials consist of coextruded or laminated films such as OPP/EVOH/PE, PA/PE, PET/PE, OPP/PVDC/PE, OPP/PVDC/OPP and PVC/EVOH/PVC.
• Vacuum packing can reduce the amount of packing material required to encase the unitized detergent portions.
• Chamber vacuum sealers or external sealers can be used to make the pack of the invention.
• the label can be directly printed inside or outside the pack or can be an applied label inside or outside the pack.
• Printing can be selected from the group consisting of flexographic printing, gravure printing, lithographic printing, and pad printing.
• Applied labels can be attached or glued to the pack, generally after filling and closing. Such labels are attached, most commonly by sticking them on to the package. Applied labels are available plain (they have to be stuck on with a glue), or self-adhesive ready-glued (simple wetting is required prior to application). The label can further help to make the vacuum pack moisture and abrasion resistant.
• the process comprises the step of:
• the vacuum pack can be made starting from an open pack rather than with two films.
• at least one of the films has a structured surface. It has been found that the structured surface provides better sealing.

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• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Life Sciences & Earth Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Wood Science & Technology (AREA)
• Organic Chemistry (AREA)
• Mechanical Engineering (AREA)
• Packages (AREA)

Priority Applications (2)

Applications Claiming Priority (1)

Publications (1)

Family

ID=69467457

Family Applications (1)

Country Status (2)

Citations (7)

• 2020
  • 2020-02-03 EP EP20155201.5A patent/EP3858966A1/de not_active Withdrawn
• 2021
  • 2021-01-25 WO PCT/US2021/014843 patent/WO2021158380A1/en active Application Filing

Patent Citations (7)

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