EP3800060A1 - Security element with at least one colour change area - Google Patents
Security element with at least one colour change area Download PDFInfo
- Publication number
- EP3800060A1 EP3800060A1 EP19201223.5A EP19201223A EP3800060A1 EP 3800060 A1 EP3800060 A1 EP 3800060A1 EP 19201223 A EP19201223 A EP 19201223A EP 3800060 A1 EP3800060 A1 EP 3800060A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- oxide
- layer
- color
- security element
- shifting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000694 effects Effects 0.000 claims abstract description 29
- -1 polypropylene Polymers 0.000 claims description 35
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims description 35
- 239000000049 pigment Substances 0.000 claims description 34
- 239000000463 material Substances 0.000 claims description 31
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 30
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 claims description 23
- 239000004973 liquid crystal related substance Substances 0.000 claims description 21
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 18
- 239000005083 Zinc sulfide Substances 0.000 claims description 18
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 18
- WHJFNYXPKGDKBB-UHFFFAOYSA-N hafnium;methane Chemical compound C.[Hf] WHJFNYXPKGDKBB-UHFFFAOYSA-N 0.000 claims description 18
- 239000000395 magnesium oxide Substances 0.000 claims description 18
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 18
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 18
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 15
- 239000003989 dielectric material Substances 0.000 claims description 15
- 229910001940 europium oxide Inorganic materials 0.000 claims description 15
- AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 claims description 15
- 229910003437 indium oxide Inorganic materials 0.000 claims description 15
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 15
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 15
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims description 15
- 229910003447 praseodymium oxide Inorganic materials 0.000 claims description 15
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 15
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 14
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 14
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 claims description 14
- 125000006850 spacer group Chemical group 0.000 claims description 13
- 239000006096 absorbing agent Substances 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 12
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 claims description 12
- 229920000620 organic polymer Polymers 0.000 claims description 12
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 12
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 10
- JPJALAQPGMAKDF-UHFFFAOYSA-N selenium dioxide Chemical compound O=[Se]=O JPJALAQPGMAKDF-UHFFFAOYSA-N 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 9
- 229910045601 alloy Inorganic materials 0.000 claims description 9
- 239000000956 alloy Substances 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 229910052804 chromium Inorganic materials 0.000 claims description 9
- 239000011651 chromium Substances 0.000 claims description 9
- 229910017052 cobalt Inorganic materials 0.000 claims description 9
- 239000010941 cobalt Substances 0.000 claims description 9
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 9
- 229910052735 hafnium Inorganic materials 0.000 claims description 9
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(iv) oxide Chemical compound O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 claims description 9
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 9
- 235000013980 iron oxide Nutrition 0.000 claims description 9
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims description 9
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 claims description 9
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 9
- 239000007769 metal material Substances 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 229910052758 niobium Inorganic materials 0.000 claims description 9
- 239000010955 niobium Substances 0.000 claims description 9
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 9
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 9
- MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical compound [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 claims description 9
- 229910052763 palladium Inorganic materials 0.000 claims description 9
- 229910052709 silver Inorganic materials 0.000 claims description 9
- 239000004332 silver Substances 0.000 claims description 9
- 229910001887 tin oxide Inorganic materials 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- 239000010936 titanium Substances 0.000 claims description 9
- 229910052720 vanadium Inorganic materials 0.000 claims description 9
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 9
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 9
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 8
- FKTOIHSPIPYAPE-UHFFFAOYSA-N samarium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Sm+3].[Sm+3] FKTOIHSPIPYAPE-UHFFFAOYSA-N 0.000 claims description 7
- 229920000106 Liquid crystal polymer Polymers 0.000 claims description 6
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 6
- 239000002033 PVDF binder Substances 0.000 claims description 6
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 6
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 6
- 239000004952 Polyamide Substances 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
- OYLGJCQECKOTOL-UHFFFAOYSA-L barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 claims description 6
- 229910001632 barium fluoride Inorganic materials 0.000 claims description 6
- ZGDWHDKHJKZZIQ-UHFFFAOYSA-N cobalt nickel Chemical compound [Co].[Ni].[Ni].[Ni] ZGDWHDKHJKZZIQ-UHFFFAOYSA-N 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 claims description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052737 gold Inorganic materials 0.000 claims description 6
- 239000010931 gold Substances 0.000 claims description 6
- 229910052697 platinum Inorganic materials 0.000 claims description 6
- 229920002492 poly(sulfone) Polymers 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 229920006260 polyaryletherketone Polymers 0.000 claims description 6
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 6
- 229920002530 polyetherether ketone Polymers 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
- 229920006324 polyoxymethylene Polymers 0.000 claims description 6
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 6
- 229920002620 polyvinyl fluoride Polymers 0.000 claims description 6
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 239000011135 tin Substances 0.000 claims description 6
- 229910052718 tin Inorganic materials 0.000 claims description 6
- 239000004642 Polyimide Substances 0.000 claims description 5
- 239000004922 lacquer Substances 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 229920001721 polyimide Polymers 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 5
- XRADHEAKQRNYQQ-UHFFFAOYSA-K trifluoroneodymium Chemical compound F[Nd](F)F XRADHEAKQRNYQQ-UHFFFAOYSA-K 0.000 claims description 5
- VFLXBUJKRRJAKY-UHFFFAOYSA-N 13768-86-0 Chemical compound O=[Se](=O)=O VFLXBUJKRRJAKY-UHFFFAOYSA-N 0.000 claims description 4
- 238000004049 embossing Methods 0.000 claims description 4
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminium flouride Chemical compound F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 claims description 3
- 239000004986 Cholesteric liquid crystals (ChLC) Substances 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 229920008285 Poly(ether ketone) PEK Polymers 0.000 claims description 3
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 3
- 239000011127 biaxially oriented polypropylene Substances 0.000 claims description 3
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 3
- QCCDYNYSHILRDG-UHFFFAOYSA-K cerium(3+);trifluoride Chemical compound [F-].[F-].[F-].[Ce+3] QCCDYNYSHILRDG-UHFFFAOYSA-K 0.000 claims description 3
- QHSJIZLJUFMIFP-UHFFFAOYSA-N ethene;1,1,2,2-tetrafluoroethene Chemical group C=C.FC(F)=C(F)F QHSJIZLJUFMIFP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 claims description 3
- 229910001512 metal fluoride Inorganic materials 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 239000005026 oriented polypropylene Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 229920000515 polycarbonate Polymers 0.000 claims description 3
- 239000004417 polycarbonate Substances 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 239000011112 polyethylene naphthalate Substances 0.000 claims description 3
- OJIKOZJGHCVMDC-UHFFFAOYSA-K samarium(iii) fluoride Chemical compound F[Sm](F)F OJIKOZJGHCVMDC-UHFFFAOYSA-K 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- BYMUNNMMXKDFEZ-UHFFFAOYSA-K trifluorolanthanum Chemical compound F[La](F)F BYMUNNMMXKDFEZ-UHFFFAOYSA-K 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 claims description 2
- 239000011888 foil Substances 0.000 claims description 2
- 239000004920 heat-sealing lacquer Substances 0.000 claims description 2
- 239000013615 primer Substances 0.000 claims description 2
- 239000002987 primer (paints) Substances 0.000 claims description 2
- 230000001681 protective effect Effects 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 229910006404 SnO 2 Inorganic materials 0.000 claims 3
- 239000011669 selenium Substances 0.000 claims 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 1
- 229910016036 BaF 2 Inorganic materials 0.000 claims 1
- 229910004298 SiO 2 Inorganic materials 0.000 claims 1
- 239000010409 thin film Substances 0.000 description 10
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 4
- 238000000465 moulding Methods 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910001610 cryolite Inorganic materials 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/324—Reliefs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/328—Diffraction gratings; Holograms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/364—Liquid crystals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/369—Magnetised or magnetisable materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/373—Metallic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
- B42D25/425—Marking by deformation, e.g. embossing
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/003—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using security elements
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/06—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using wave or particle radiation
- G07D7/12—Visible light, infrared or ultraviolet radiation
Definitions
- the invention relates to a security element for securities or security papers, the security element having at least one first color-changing area.
- Security elements of the type mentioned are usually used to increase the security against forgery of securities or security papers, such as bank notes, ID cards, credit cards, ATM cards, tickets, etc.
- the object of the present invention is to create a security element with increased security against forgery.
- this object is achieved by a security element of the type mentioned at the outset in that the security element additionally has at least a second area different from the first area with structures that reflect an image motif into different spatial areas, so that for the viewer when a light source moves accordingly and / or when a viewing angle is changed, a moving image is created, with a movement of the image motif and a color shift effect simultaneously arising when the light source is moved and / or the viewing angle is changed.
- the solution according to the invention significantly increases the security against forgery by combining the moving image with a color shift effect.
- the invention makes it possible for certain types of light sources to be able to perceive both effects with the naked eye at the same time. For example, when using point light sources, both the color shift effect and the moving image can be clearly perceived.
- the at least one first color-shifting area can have a layer with color-shifting pigments, in particular interference pigments, pigments with a color-shifting thin-layer structure or liquid crystal pigments, or a color-shifting thin-layer structure.
- the at least one first color-shifting area can have at least one liquid crystal layer, in particular at least one cholesteric liquid crystal layer.
- the layer that enhances the color-shifting effect can be applied to the liquid-crystal layer or the layer of color-shifting pigments, so that the layer of color-shifting pigments or the liquid crystal layer is arranged between the layer that enhances the color-shifting effect and the carrier layer.
- the layer that enhances the color-shifting effect can, however, also be arranged between the carrier layer and the layer of color-shifting pigments or the at least one liquid crystal layer.
- the carrier layer it is also possible for the carrier layer to be arranged between the layer that enhances the color-shifting effect and the layer of color-shifting pigments or the liquid crystal layer.
- one or more intermediate layers can be arranged between the at least one layer that enhances the color-shifting effect and the carrier layer and / or the at least one layer of color-shifting pigments or the at least one liquid crystal layer.
- the term layer in this document is to be understood in such a way that a layer can also be made up of several sub-layers.
- the color-shifting thin-film structure or the color-shifting pigments with a color-shifting thin-film structure have at least one absorber layer and at least one spacer layer made of a dielectric material.
- the thin-film structure can have at least one reflective layer, the spacer layer being arranged between the reflective layer and the absorber layer.
- the security element has a carrier layer made of plastic, in particular made of a translucent and / or thermoplastic plastic, the carrier layer preferably having at least one of the materials from the polyimide group (PI), polypropylene (PP), monoaxially oriented polypropylene (MOPP), biaxially oriented polypropylene (BOPP), polyethylene (PE), polyphenylene sulfide (PPS), polyetheretherketone, (PEEK) polyetherketone (PEK), polyethyleneimide (PEI), polysulfone ( PSU), polyaryletherketone (PAEK), polyethylene naphthalate (PEN), liquid crystalline polymers (LCP), polyester, polybutylene terephthalate (PBT), polyethylene terephthalate (PET), polyamide (PA), polycarbonate (PC), cycloolefin copolymers (COC), polyoxymethylene (POM) , Acrylonitrile-butadiene-styrene (ABS), polyvinylene (PI),
- the carrier layer has a thickness of 5 ⁇ m to 1000 ⁇ m, particularly preferably a thickness of 10 ⁇ m-50 ⁇ m.
- the at least one absorber layer has at least one metallic material, in particular selected from the group consisting of nickel, titanium, vanadium, chromium, cobalt, palladium, iron, tungsten, molybdenum, niobium, aluminum, silver, copper and / or alloys of these materials or is made from at least one of these materials.
- the at least one spacer layer has at least one low-index dielectric material with a refractive index less than or equal to 1.65, in particular selected from the group aluminum oxide (Al2O3), metal fluorides, for example magnesium fluoride (MgF2), aluminum fluoride ( AlF3), silicon oxide (SIOx), silicon dioxide (SiO2), cerium fluoride (CeF3), sodium-aluminum fluoride (e.g.
- Al2O3 aluminum oxide
- metal fluorides for example magnesium fluoride (MgF2), aluminum fluoride ( AlF3), silicon oxide (SIOx), silicon dioxide (SiO2), cerium fluoride (CeF3), sodium-aluminum fluoride (e.g.
- Na3AlF6 or Na5Al3F14 Na3AlF6 or Na5Al3F14
- neodymium fluoride (NdF3) neodymium fluoride
- LaF3 lanthanum fluoride
- SmF3 barium fluoride
- BaF3 barium fluoride
- BaF3 barium fluoride
- LiF lithium fluoride
- low-refractive organic monomers and / or low-refractive organic polymers or at least one high-refractive dielectric material with a refractive index greater than 1.65 in particular selected from the group of zinc sulfide (ZnS), zinc oxide (ZnO), titanium dioxide ( TiO2), carbon (C), indium oxide (In2O3), indium tin oxide (ITO), tantalum pentoxide (Ta2O5), cerium oxide (CeO2), yttrium oxide d (Y2O3), europium oxide (Eu2O3), iron oxide
- the at least one reflective layer has at least one metallic material, in particular selected from the group consisting of silver, copper, aluminum, gold, platinum, niobium, tin, or from nickel, titanium, vanadium, chromium, cobalt and palladium or alloys of these materials, in particular cobalt-nickel alloys or of at least one high-index dielectric material with a refractive index greater than 1.65, in particular selected from the group consisting of zinc sulfide (ZnS), zinc oxide (ZnO), titanium dioxide (TiO2), carbon (C), indium oxide ( In2O3), indium tin oxide (ITO), tantalum pentoxide (Ta2O5), cerium oxide (CeO2), yttrium oxide (Y2O3), europium oxide (Eu2O3), iron oxides such as iron (II, III) oxide (Fe3O4) and iron (III ) oxide (Fe2O3), hafnium nitride (
- the structures of the second area can be designed as diffractive structures, as micromirrors or as ray-optically effective facets.
- several structures can form a group, the orientations of which are coordinated with one another in such a way that they depict a point of the image motif in an observation space, the image motif being composed of the sum of all the points represented by the group and by changing a direction of incidence of the one generated by the light source Light and / or when the observation angle changes, a movement of the point is generated in the observation space.
- the structures are particularly preferably introduced into the carrier layer by means of a molding device, in particular by means of an embossing process.
- the structures are formed in a layer applied directly to the carrier layer or with the arrangement of further intermediate layers, in particular an embossed lacquer layer, in particular embossed by means of a molding element.
- the layer with the structures formed therein preferably has a layer thickness between 0.5-300 ⁇ m, in particular between 0.8-50 ⁇ m, preferably between 1-10 ⁇ m.
- the security element has at least one reflective layer on a side of the carrier layer facing away from the structures and / or a reflective layer is arranged between the carrier layer and the structures and / or the structures with at least one reflective layer are coated, the at least one reflective layer preferably being a metallic material, in particular selected from the group consisting of silver, copper, aluminum, gold, platinum, niobium, tin, or of nickel, titanium, vanadium, chromium, cobalt and palladium or alloys of these materials , in particular cobalt-nickel alloys, or at least one high-index dielectric material with a refractive index greater than 1.65, in particular selected from the group consisting of zinc sulfide (ZnS), zinc oxide (ZnO), titanium dioxide (TiO2), carbon (C), indium oxide (In2O3), indium tin oxide (ITO), tantalum pentoxide (Ta2O5), cerium oxide (Ce
- the security element can be equipped with machine-readable features, the machine-readable features in particular being magnetic codings, Electrically conductive layers, electromagnetic waves absorbing and / or re-emitting substances.
- the security element can have additional layers, which additional layers comprise in particular protective lacquers, heat-sealing lacquers, adhesives, primers and / or foils
- a security element 1 according to the invention for securities or security papers has one or more first color-shifting areas 2.
- the security element has one or more second areas 3 different from the first area 2 with structures that reflect an image motif 4a in different spatial areas, see above that a movement image is created for the viewer with a corresponding movement of a light source and / or with a change in an observation angle.
- the structures are provided with the reference number 4 and the light source with the reference number 5.
- the light source 5 is moved and / or the viewing angle is changed, a movement of the image motif and a color shift effect occur at the same time.
- both effects can be perceived at the same time or only one of the two effects. It has been found that, for example, when using point light sources, both the color shift effect and the moving image are clearly perceived, while, on the other hand, with diffuse lighting, the moving image cannot be perceived or is significantly weaker.
- the color-shifting area 2 can have a color-shifting layer 6, for example with color-shifting pigments, a color-shifting liquid crystal layer or a color-shifting thin-layer structure 7.
- the area 3 described above and different from the first area 2 has the structures 4.
- the two areas 2 and 3 are shown adjacent to one another in the two exemplary embodiments.
- the color-shifting thin-film structure 7 can have an absorber layer 8 and a spacer layer 9 made of a dielectric material.
- the thin-film structure 7 can have a reflective layer 10.
- the spacer layer 9 is arranged between the reflective layer 10 and the absorber layer 8. If, for example, a paint with color-changing pigments is used to produce the layer 6, these can each have a thin-layer structure 7, as just described.
- the absorber layer 8 can comprise a metallic material, in particular selected from the group nickel, titanium, vanadium, chromium, cobalt, palladium, iron, tungsten, molybdenum, niobium, aluminum, silver, copper and / or alloys of these materials or from at least one of these Materials to be made.
- the one spacer layer 9 can, for example, have at least one low-index dielectric material with a refractive index less than or equal to 1.65, in particular selected from the group aluminum oxide (Al2O3), metal fluorides, for example magnesium fluoride (MgF2), aluminum fluoride (AlF3), silicon oxide (SIOx), Silicon dioxide (SiO2), cerium fluoride (CeF3), sodium aluminum fluoride (e.g.
- Al2O3 aluminum oxide
- metal fluorides for example magnesium fluoride (MgF2), aluminum fluoride (AlF3), silicon oxide (SIOx), Silicon dioxide (SiO2), cerium fluoride (CeF3), sodium aluminum fluoride (e.g.
- Na3AlF6 or Na5Al3F14 Na3AlF6 or Na5Al3F14
- neodymium fluoride (NdF3) neodymium fluoride
- LaF3 lanthanum fluoride
- SmF3 samarium fluoride
- LiF2 calcium fluoride
- lithium fluoride low-index organic monomers and / or low-index organic polymers or at least one high-index dielectric material with a refractive index greater than 1.65, in particular selected from the group consisting of zinc sulfide (ZnS), zinc oxide (ZnO), titanium dioxide (TiO2), carbon (C), Indium oxide (In2O3), indium tin oxide (ITO), tantalum pentoxide (Ta2O5), cerium oxide (CeO2), yttrium oxide (Y2O3), europium oxide (Eu2O3), iron oxides such as play iron (II, III) oxide (Fe3
- the reflective layer 10 can contain at least one metallic material, in particular selected from the group silver, copper, aluminum, gold, platinum, niobium, tin, or from nickel, titanium, vanadium, chromium, cobalt and palladium or alloys of these materials, in particular cobalt Nickel alloys or at least one high-index dielectric material with a refractive index of greater than 1.65, in particular selected from the group consisting of zinc sulfide (ZnS), zinc oxide (ZnO), titanium dioxide (TiO2), carbon (C), indium oxide (In2O3), Indium tin oxide (ITO), tantalum pentoxide (Ta2O5), cerium oxide (CeO2), yttrium oxide (Y2O3), europium oxide (Eu2O3), iron oxides such as iron (II, III) oxide (Fe3O4) and iron (III) oxide ( Fe2O3), hafnium nitride (HfN), hafnium carb
- color-shifting pigments can also be used.
- the color-shifting pigments can, for example, have a thin-layer structure which, in particular, can have a symmetrical structure on both sides of a reflector, that is to say can have a layer sequence of absorber / spacer layer / reflector / spacer layer / absorber. Such pigments do not necessarily need a layer that enhances the color shift effect.
- the color-shifting pigments can also be formed by simpler interference pigments, e.g. B. silica flakes or mica, which may require a layer that reinforces the color shift effect, in particular a layer of dark color and / or a layer of metal oxides such as, for example, substoichiometric aluminum oxide.
- the color-changing pigments can be implemented as LC pigments (liquid crystal pigments).
- the color-shifting area 2 can have one or more liquid crystal layers, in particular one or more cholesteric liquid crystal layers.
- a layer that reinforces the color-shifting effect in particular a layer of dark color and / or a layer of metal oxides such as, for example, substoichiometric aluminum oxide.
- the layer that enhances the color-shifting effect can be applied to the liquid crystal layer or the layer of color-shifting pigments, so that the layer of color-shifting pigments or the liquid crystal layer is arranged between the layer that enhances the color-shifting effect and the carrier layer.
- the layer that enhances the color-shifting effect can, however, also be arranged between the carrier layer and the layer of color-shifting pigments or the at least one liquid crystal layer.
- the carrier layer it is also possible for the carrier layer to be arranged between the layer that enhances the color-shifting effect and the layer of color-shifting pigments or the liquid crystal layer.
- One or more intermediate layers can also be arranged between the layer which reinforces the color-shifting effect and the carrier layer and / or the layer of color-shifting pigments or the liquid crystal layer.
- the security element 1 according to Fig. 2 and 3 have a carrier layer 11 made of plastic, in particular made of a translucent and / or thermoplastic plastic.
- the carrier layer 11 preferably comprises at least one of the materials from the group polyimide (PI), polypropylene (PP), monoaxially oriented polypropylene (MOPP), biaxially oriented polypropylene (BOPP), polyethylene (PE), polyphenylene sulfide (PPS), polyetheretherketone, (PEEK ) Polyetherketone (PEK), polyethyleneimide (PEI), polysulfone (PSU), polyaryletherketone (PAEK), polyethylene naphthalate (PEN), liquid crystalline polymers (LCP), polyester, polybutylene terephthalate (PBT), polyethylene terephthalate (PET), polyamide (PA), polycarbonate (PC), cycloolefin copolymers (COC), polyoxymethylene (POM), acrylonitrile butadiene styrene
- the carrier layer 11 preferably has a thickness of 5 ⁇ m to 1000 ⁇ m, particularly preferably a thickness of 10 ⁇ m-50 ⁇ m.
- the structures 4 can be embodied in a manner known per se as diffractive structures, as micromirrors or as ray-optically effective facets.
- the formation of the structures 4 as diffractive structures is, for example, from EP2782765B1 and the EP2885135B1 as well as the WO2015107347A1 known.
- an embodiment of the structures 4 as micromirrors for example from the US10189294A1 as well as the EP3362827A1 is familiar to the person skilled in the art.
- a facet-like shape of the structures 4 is based, for example, on FIG EP2632739A1 emerged. Since the design of the structures 4 for generating movement images is familiar to the person skilled in the art, it will not be discussed in more detail at this point in order to avoid unnecessary expansiveness.
- a plurality of structures 4 can form a group, the orientations of which are coordinated with one another in such a way that they image a point 12 of the image motif 4a in an observation space.
- the image motif 4a is composed of the sum of all points 12 represented by the group.
- the structures 4 can be formed in a layer 13 applied to the carrier layer 11, in particular an embossed lacquer layer. They are preferably embossed by means of an impression element.
- the layer 13 with the structures 4 formed therein preferably has a layer thickness between 0.5-300 ⁇ m, in particular between 0.8-50 ⁇ m, preferably between 1-10 ⁇ m.
- the carrier layer 11 can be completely or partially coated with the layer 10 and the layer 14.
- the layer composite resulting therefrom can then be completely or partially provided with the layer 13 and the structures 4 can be introduced into this, for example by embossing.
- the individual layers of the thin-film element 7 can be applied to this in order to produce the color-shifting area.
- Further layers can be arranged between the layer 13 and the carrier layer 11, for example an adhesion promoter layer or also a reflective layer 14 of the reflective layer 14, light rays passing through the structures 4 can be reflected in order to image the point 12 in the observation space.
- the embodiment shown here is particularly advantageous for diffractive structures. How out Fig. 2 it can be seen that the reflective layer 14 can form a layer with the reflective layer 10 of the thin-film structure 7 and can also be made of the same materials as these.
- a reflective layer 14a can also be arranged on the structures 4, so that the structures 4 come to lie between the reflective layer 14a and the carrier layer 11. In this case, the reflective layer 14a follows the shape of the structures when it is arranged on the structures 4.
- the structures 4 can be partially or completely coated with the reflective layer 14a.
- the layer 14a can be provided instead of the layer 14 or in addition to it.
- the structures 4 can also be introduced directly into the carrier layer 11 by means of a molding device, in particular by means of an embossing process, as is the case in FIG Fig. 3 is shown.
- the reflective layer 14 can be applied to a side of the carrier layer facing away from the structures 4 and / or the structures 4 can be coated over the entire area or partially with the layer 14a.
- reflective layer 14a can be arranged on the structures 4 or the structures 4 can be at least partially coated with the layer 14a.
- the reflective layer 14 and the layer 14a preferably comprise a metallic material, in particular selected from the group silver, copper, aluminum, gold, platinum, niobium, tin, or from nickel, titanium, vanadium, chromium, cobalt and palladium or alloys of these materials , in particular cobalt-nickel alloys, or at least one high-index dielectric material with a refractive index greater than 1.65, in particular selected from the group consisting of zinc sulfide (ZnS), zinc oxide (ZnO), titanium dioxide (TiO2), carbon (C), indium oxide (In2O3), indium tin oxide (ITO), tantalum pentoxide (Ta2O5), cerium oxide (CeO2), yttrium oxide (Y2O3), europium oxide (Eu2O3), iron oxides such as iron (II, III) oxide (Fe3O4) and iron ( III) oxide (Fe2O3), hafnium nitride (Hf
- the in Fig. 3 The embodiment shown could also be modified so that the carrier layer 11 could function as a spacer layer 8 and the reflective layer 14 as a reflective layer 10, so that only the layers 14, 11 and 9 are present in the color-shifting area 2.
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Abstract
Die Erfindung betrifft ein Sicherheitselement (1) für Wertpapiere oder Sicherheitspapiere, wobei das Sicherheitselement (1) zumindest einen ersten farbkippenden Bereich (2) aufweist, wobei das Sicherheitselement (1) zusätzlich zumindest einen zweiten, von dem ersten Bereich (2) verschiedenen Bereich (3) mit Strukturen (4) aufweist, die ein Bildmotiv in unterschiedliche Raumbereiche reflektieren, so dass für den Betrachter bei entsprechender Bewegung einer Lichtquelle (5) und/oder bei Veränderung eines Beobachtungswinkels ein Bewegungsbild entsteht, wobei bei Bewegung der Lichtquelle und/oder Veränderung des Beobachtungswinkels gleichzeitig eine Bewegung des Bildmotivs und ein Farbkippeffekt entsteht.The invention relates to a security element (1) for securities or security papers, the security element (1) having at least one first color-tilting area (2), the security element (1) additionally having at least one second area ( 3) with structures (4) that reflect an image motif in different spatial areas, so that a movement image is created for the viewer when a light source (5) moves accordingly and / or when an observation angle changes, with the light source moving and / or changing The angle of observation creates a movement of the subject and a color shift effect at the same time.
Description
Die Erfindung betrifft ein Sicherheitselement für Wertpapiere oder Sicherheitspapiere, wobei das Sicherheitselement zumindest einen ersten farbkippenden Bereich aufweist.The invention relates to a security element for securities or security papers, the security element having at least one first color-changing area.
Sicherheitselemente der eingangsgenannten Art werden üblicherweise verwendet um die Fälschungssicherheit von Wertpapieren oder Sicherheitspapieren, wie Banknoten, Ausweise, Kreditkarten, Bankomatkarten, Tickets etc. zu erhöhen.Security elements of the type mentioned are usually used to increase the security against forgery of securities or security papers, such as bank notes, ID cards, credit cards, ATM cards, tickets, etc.
Aufgabe der vorliegenden Erfindung ist es, ein Sicherheitselement mit erhöhter Fälschungssicherheit zu schaffen.The object of the present invention is to create a security element with increased security against forgery.
Diese Aufgabe wird durch ein Sicherheitselement der eingangs genannten Art erfindungsgemäß dadurch gelöst, dass das Sicherheitselement zusätzlich zumindest einen zweiten, von dem ersten Bereich verschiedenen Bereich mit Strukturen aufweist, die ein Bildmotiv in unterschiedliche Raumbereiche reflektieren, so dass für den Betrachter bei entsprechender Bewegung einer Lichtquelle und/oder bei Veränderung eines Beobachtungswinkels ein Bewegungsbild entsteht, wobei bei Bewegung der Lichtquelle und/oder Veränderung des Beobachtungswinkels gleichzeitig eine Bewegung des Bildmotivs und ein Farbkippeffekt entsteht.According to the invention, this object is achieved by a security element of the type mentioned at the outset in that the security element additionally has at least a second area different from the first area with structures that reflect an image motif into different spatial areas, so that for the viewer when a light source moves accordingly and / or when a viewing angle is changed, a moving image is created, with a movement of the image motif and a color shift effect simultaneously arising when the light source is moved and / or the viewing angle is changed.
Durch die erfindungsgemäße Lösung wird durch Verbindung des Bewegungsbildes mit einem Farbkippeffekt die Fälschungssicherheit wesentlich erhöht. So ermöglicht die Erfindung beispielsweise, dass bei bestimmten Arten von Lichtquellen beide Effekte gleichzeitig mit dem unbewaffneten Auge wahrgenommen werden kann. So können beispielsweise bei Verwendung von Punktlichtquellen sowohl der Farbkippeffekt als auch das Bewegungsbild deutlich wahrgenommen werden.The solution according to the invention significantly increases the security against forgery by combining the moving image with a color shift effect. For example, the invention makes it possible for certain types of light sources to be able to perceive both effects with the naked eye at the same time. For example, when using point light sources, both the color shift effect and the moving image can be clearly perceived.
Gemäß einer vorteilhaften Variante kann der zumindest eine erste farbkippende Bereich eine Schicht mit farbkippenden Pigmenten, insbesondere Interferenzpigmente, Pigmente mit einem farbkippenden Dünnschichtaufbau oder Flüssigkristallpigmente, oder einen farbkippenden Dünnschichtaufbau aufweisen.According to an advantageous variant, the at least one first color-shifting area can have a layer with color-shifting pigments, in particular interference pigments, pigments with a color-shifting thin-layer structure or liquid crystal pigments, or a color-shifting thin-layer structure.
Darüber hinaus kann der zumindest eine erste farbkippende Bereich zumindest eine Flüssigkristallschicht, insbesondere zumindest eine cholesterische Flüssigkristallschicht aufweisen.In addition, the at least one first color-shifting area can have at least one liquid crystal layer, in particular at least one cholesteric liquid crystal layer.
Bevorzugt befindet sich auf der der Sichtseite abgewandten Seite der ersten farbkippenden Schicht des ersten Bereichs eine den Farbkippeffekt verstärkende Schicht, insbesondere eine Schicht aus dunkler Farbe und/oder eine Schicht aus Metalloxiden wie beispielsweise unterstöchiometrisches Aluminiumoxid. So kann die den Farbkippeffekt verstärkende Schicht beispielsweise auf der Flüssigkristallschicht oder der Schicht aus farbkippenden Pigmenten aufgebracht sein, sodass die Schicht aus farbkippenden Pigmenten oder die Flüssigkristallschicht zwischen der den Farbkippeffekt verstärkenden Schicht und der Trägerschicht angeordnet ist. Die den Farbkippeffekt verstärkende Schicht kann aber auch zwischen der Trägerschicht und der Schicht aus farbkippenden Pigmenten oder der zumindest einen Flüssigkristallschicht angeordnet sein. Zudem ist es auch möglich, dass die Trägerschicht zwischen der den Farbkippeffekt verstärkenden Schicht und der Schicht aus farbkippenden Pigmenten oder der Flüssigkristallschicht und angeordnet ist.Preferably, on the side of the first color-shifting layer of the first region facing away from the visible side, there is a layer that reinforces the color-shifting effect, in particular a layer of dark color and / or a layer of metal oxides such as, for example, substoichiometric aluminum oxide. For example, the layer that enhances the color-shifting effect can be applied to the liquid-crystal layer or the layer of color-shifting pigments, so that the layer of color-shifting pigments or the liquid crystal layer is arranged between the layer that enhances the color-shifting effect and the carrier layer. The layer that enhances the color-shifting effect can, however, also be arranged between the carrier layer and the layer of color-shifting pigments or the at least one liquid crystal layer. In addition, it is also possible for the carrier layer to be arranged between the layer that enhances the color-shifting effect and the layer of color-shifting pigments or the liquid crystal layer.
An dieser Stelle sei darauf hingewiesen, dass zwischen der zumindest einen den Farbkippeffekt verstärkenden Schicht und der Trägerschicht und/oder der zumindest einen Schicht aus farbkippenden Pigmenten oder der zumindest einen Flüssigkristallschicht je eine oder mehrere Zwischenschichten angeordnet sein können. Weiters sei darauf hingewiesen, dass der Begriff Schicht in diesem Dokument so zu verstehen ist, dass eine Schicht auch aus mehreren Teilschichten aufgebaut sein kann.At this point it should be pointed out that one or more intermediate layers can be arranged between the at least one layer that enhances the color-shifting effect and the carrier layer and / or the at least one layer of color-shifting pigments or the at least one liquid crystal layer. It should also be pointed out that the term layer in this document is to be understood in such a way that a layer can also be made up of several sub-layers.
Bei einer Weiterbildung der Erfindung kann es vorgesehen sein, dass der farbkippende Dünnschichtaufbau oder die farbkippenden Pigmente mit einem farbkippenden Dünnfilmaufbau zumindest eine Absorberschicht und zumindest eine Distanzschicht aus einem dielektrischen Material aufweist. Zusätzlich kann der Dünnschichtaufbau zumindest eine Reflexionsschicht aufweisen, wobei die Distanzschicht zwischen Reflexionsschicht und Absorberschicht angeordnet ist.In a further development of the invention, it can be provided that the color-shifting thin-film structure or the color-shifting pigments with a color-shifting thin-film structure have at least one absorber layer and at least one spacer layer made of a dielectric material. In addition, the thin-film structure can have at least one reflective layer, the spacer layer being arranged between the reflective layer and the absorber layer.
Besonders bevorzugt ist, dass das Sicherheitselement eine Trägerschicht aus Kunststoff, insbesondere aus einem lichtdurchlässigen und/oder thermoplastischen Kunststoff, aufweist, wobei die Trägerschicht bevorzugt zumindest eines der Materialien aus der Gruppe Polyimid (PI), Polypropylen (PP), monoaxial orientiertem Polypropylen (MOPP), biaxial orientierten Polypropylen (BOPP), Polyethylen (PE), Polyphenylensulfid (PPS), Polyetheretherketon, (PEEK) Polyetherketon (PEK), Polyethylenimid (PEI), Polysulfon (PSU), Polyaryletherketon (PAEK), Polyethylennaphthalat (PEN), flüssigkristalline Polymere (LCP), Polyester, Polybutylenterephthalat (PBT), Polyethylenterephthalat (PET), Polyamid (PA), Polycarbonat (PC), Cycloolefincopolymere (COC), Polyoximethylen (POM), Acrylnitril-butadien-styrol (ABS), Polyvinylcholrid (PVC) Ethylentetrafluorethylen (ETFE), Polytetrafluorethylen (PTFE), Polyvinylfluorid (PVF), Polyvinylidenfluorid (PVDF) und Ethylen-Tetrafluorethylen-Hexafluorpropylen-Fluorterpolymer (EFEP) und/oder Mischungen und/oder Co-Polymere dieser Materialien umfasst oder aus zumindest einem dieser Materialien hergestellt ist.It is particularly preferred that the security element has a carrier layer made of plastic, in particular made of a translucent and / or thermoplastic plastic, the carrier layer preferably having at least one of the materials from the polyimide group (PI), polypropylene (PP), monoaxially oriented polypropylene (MOPP), biaxially oriented polypropylene (BOPP), polyethylene (PE), polyphenylene sulfide (PPS), polyetheretherketone, (PEEK) polyetherketone (PEK), polyethyleneimide (PEI), polysulfone ( PSU), polyaryletherketone (PAEK), polyethylene naphthalate (PEN), liquid crystalline polymers (LCP), polyester, polybutylene terephthalate (PBT), polyethylene terephthalate (PET), polyamide (PA), polycarbonate (PC), cycloolefin copolymers (COC), polyoxymethylene (POM) , Acrylonitrile-butadiene-styrene (ABS), polyvinylcholride (PVC) ethylene tetrafluoroethylene (ETFE), polytetrafluoroethylene (PTFE), polyvinyl fluoride (PVF), polyvinylidene fluoride (PVDF) and ethylene-tetrafluoroethylene-hexafluoropropylene-fluoroterpolymer (EFEP) and / or mixtures and / or mixtures and or comprises copolymers of these materials or is made from at least one of these materials.
Als besonders günstig hat sich herausgestellt, dass die Trägerschicht eine Dicke von 5 µm bis 1000 µm, besonders bevorzugt eine Dicke von 10 µm - 50 µm, aufweist.It has been found to be particularly favorable that the carrier layer has a thickness of 5 μm to 1000 μm, particularly preferably a thickness of 10 μm-50 μm.
Bei einer besonders bevorzugten Ausführungsform ist es vorgesehen, dass die zumindest eine Absorberschicht zumindest ein metallisches Material, insbesondere ausgewählt aus der Gruppe Nickel, Titan, Vanadium, Chrom, Kobalt, Palladium, Eisen, Wolfram, Molybdän, Niob, Aluminium, Silber, Kupfer und/oder Legierungen dieser Materialien umfasst oder aus zumindest einem dieser Materialien hergestellt ist.In a particularly preferred embodiment, it is provided that the at least one absorber layer has at least one metallic material, in particular selected from the group consisting of nickel, titanium, vanadium, chromium, cobalt, palladium, iron, tungsten, molybdenum, niobium, aluminum, silver, copper and / or alloys of these materials or is made from at least one of these materials.
Gemäß einer vorteilhaften Weiterbildung der Erfindung ist es vorgesehen, dass die zumindest eine Distanzschicht zumindest ein niederbrechendes dielektrisches Material mit einem Brechungsindex kleiner oder gleich 1,65, insbesondere ausgewählt aus der Gruppe Aluminiumoxid (Al2O3), Metallfluoride, beispielsweise Magnesiumfluorid (MgF2), Aluminiumfluorid (AlF3), Siliziumoxid (SIOx), Siliziumdioxid (SiO2), Cerfluorid (CeF3), Natrium-Aluminium-Fluoride (z.B. Na3AlF6 oder Na5Al3F14), Neodymfluorid (NdF3), Lanthanfluorid (LaF3), Samariumfluorid (SmF3) Bariumfluorid (BaF2), Calciumfluorid (CaF2), Lithiumfluorid (LiF), niederbrechende organische Monomere und/oder niederbrechende organische Polymere oder zumindest ein hochbrechendes dielektrisches Material mit einem Brechungsindex größer als 1,65, insbesondere ausgewählt aus der Gruppe Zinksulfid (ZnS), Zinkoxid (ZnO), Titandioxid (TiO2), Kohlenstoff (C), Indiumoxid (In2O3), Indium-Zinn-Oxid (ITO), Tantalpentoxid (Ta2O5), Ceroxid (CeO2), Yttriumoxid (Y2O3), Europiumoxid (Eu2O3), Eisenoxide wie zum Beispiel Eisen(II,III)oxid (Fe3O4) und Eisen(III)oxid (Fe2O3), Hafniumnitrid (HfN), Hafniumcarbid (HfC), Hafniumoxid (HfO2), Lanthanoxid (La2O3), Magnesiumoxid (MgO), Neodymoxid (Nd2O3), Praseodymoxid (Pr6O11), Samariumoxid (Sm2O3), Antimontrioxid (Sb2O3), Siliziumcarbid (SiC), Siliziumnitrid (Si3N4), Siliziummonoxid (SiO), Selentrioxid (Se2O3), Zinnoxid (SnO2), Wolframtrioxid (WO3), hochbrechende organische Monomere und/oder hochbrechende organische Polymere umfasst oder aus zumindest einem dieser Materialien hergestellt ist.According to an advantageous development of the invention, it is provided that the at least one spacer layer has at least one low-index dielectric material with a refractive index less than or equal to 1.65, in particular selected from the group aluminum oxide (Al2O3), metal fluorides, for example magnesium fluoride (MgF2), aluminum fluoride ( AlF3), silicon oxide (SIOx), silicon dioxide (SiO2), cerium fluoride (CeF3), sodium-aluminum fluoride (e.g. Na3AlF6 or Na5Al3F14), neodymium fluoride (NdF3), lanthanum fluoride (LaF3), samarium fluoride (SmF3), barium fluoride (BaF3), barium fluoride (BaF3) (CaF2), lithium fluoride (LiF), low-refractive organic monomers and / or low-refractive organic polymers or at least one high-refractive dielectric material with a refractive index greater than 1.65, in particular selected from the group of zinc sulfide (ZnS), zinc oxide (ZnO), titanium dioxide ( TiO2), carbon (C), indium oxide (In2O3), indium tin oxide (ITO), tantalum pentoxide (Ta2O5), cerium oxide (CeO2), yttrium oxide d (Y2O3), europium oxide (Eu2O3), iron oxides such as iron (II, III) oxide (Fe3O4) and iron (III) oxide (Fe2O3), hafnium nitride (HfN), hafnium carbide (HfC), hafnium oxide (HfO2), lanthanum oxide (La2O3), magnesium oxide (MgO), neodymium oxide (Nd2O3), praseodymium oxide (Pr6O11), samarium oxide (Sm2O3), antimony trioxide (Sb2O3), silicon c (Si3N4), silicon monoxide (SiO), selenium trioxide (Se2O3), tin oxide (SnO2), tungsten trioxide (WO3), high refractive index organic monomers and / or high refractive index organic polymers or is made from at least one of these materials.
Bevorzugt ist, dass die zumindest eine Reflexionsschicht zumindest ein metallisches Material, insbesondere ausgewählt aus der Gruppe Silber, Kupfer, Aluminium, Gold, Platin, Niob, Zinn, oder aus Nickel, Titan, Vanadium, Chrom, Kobalt und Palladium oder Legierungen dieser Materialien, insbesondere Kobalt-Nickel-Legierungen oder aus zumindest ein hochbrechendes dielektrisches Material mit einem Brechungsindex von größer als 1,65, insbesondere ausgewählt aus der Gruppe Zinksulfid (ZnS), Zinkoxid (ZnO), Titandioxid (TiO2), Kohlenstoff (C), Indiumoxid (In2O3), Indium-Zinn-Oxid (ITO), Tantalpentoxid (Ta2O5), Ceroxid (CeO2), Yttriumoxid (Y2O3), Europiumoxid (Eu2O3), Eisenoxide wie zum Beispiel Eisen(II,III)oxid (Fe3O4) und Eisen(III)oxid (Fe2O3), Hafniumnitrid (HfN), Hafniumcarbid (HfC), Hafniumoxid (HfO2), Lanthanoxid (La2O3), Magnesiumoxid (MgO), Neodymoxid (Nd2O2), Praseodymoxid (Pr6O11), Samariumoxid (Sm2O3), Antimontrioxid (Sb2O3), Siliziumcarbid (SiC), Siliziumnitrid (Si3N4), Siliziummonoxid (SiO), Selentrioxid (Se2O3), Zinnoxid (SnO2), Wolframtrioxid (WO3), hochbrechende organische Monomere und/oder hochbrechende organische Polymere umfasst oder aus zumindest einem dieser Materialien hergestellt ist.It is preferred that the at least one reflective layer has at least one metallic material, in particular selected from the group consisting of silver, copper, aluminum, gold, platinum, niobium, tin, or from nickel, titanium, vanadium, chromium, cobalt and palladium or alloys of these materials, in particular cobalt-nickel alloys or of at least one high-index dielectric material with a refractive index greater than 1.65, in particular selected from the group consisting of zinc sulfide (ZnS), zinc oxide (ZnO), titanium dioxide (TiO2), carbon (C), indium oxide ( In2O3), indium tin oxide (ITO), tantalum pentoxide (Ta2O5), cerium oxide (CeO2), yttrium oxide (Y2O3), europium oxide (Eu2O3), iron oxides such as iron (II, III) oxide (Fe3O4) and iron (III ) oxide (Fe2O3), hafnium nitride (HfN), hafnium carbide (HfC), hafnium oxide (HfO2), lanthanum oxide (La2O3), magnesium oxide (MgO), neodymium oxide (Nd2O2), praseodymium oxide (Pr6O3), samonium oxide (Sm2O3ioxide) , Silicon carbide (SiC), silicon nitride (Si3N4), silicon mo noxide (SiO), selenium trioxide (Se2O3), tin oxide (SnO2), tungsten trioxide (WO3), high refractive index organic monomers and / or high refractive index organic polymers or is made from at least one of these materials.
Bei einer günstigen Ausführungsform können die Strukturen des zweiten Bereichs als diffraktive Strukturen, als Mikrospiegel oder als strahlenoptisch wirksame Facetten ausgebildet sein.In a favorable embodiment, the structures of the second area can be designed as diffractive structures, as micromirrors or as ray-optically effective facets.
Weiters können mehrere Strukturen eine Gruppe bilden, deren Ausrichtungen derart aufeinander abgestimmt sind, dass sie in einem Beobachtungsraum einen Punkt des Bildmotivs abbilden, wobei sich das Bildmotiv aus der Summe aller von Gruppe dargestellten Punkte zusammensetzt und wobei durch Veränderung einer Einfallsrichtung des von der Lichtquelle erzeugten Lichtes und/oder bei Veränderung des Beobachtungswinkels eine Bewegung des Punktes in dem Beobachtungsraum erzeugt ist.Furthermore, several structures can form a group, the orientations of which are coordinated with one another in such a way that they depict a point of the image motif in an observation space, the image motif being composed of the sum of all the points represented by the group and by changing a direction of incidence of the one generated by the light source Light and / or when the observation angle changes, a movement of the point is generated in the observation space.
Besonders bevorzugt sind die Strukturen in die Trägerschicht mittels einer Abformvorrichtung, insbesondere durch ein Prägeverfahren, eingebracht.The structures are particularly preferably introduced into the carrier layer by means of a molding device, in particular by means of an embossing process.
Weiters hat es sich als vorteilhaft erwiesen, dass die Strukturen in einer auf die Trägerschicht direkt oder unter Anordnung weiterer Zwischenschichtung aufgebrachten Schicht, insbesondere eine Prägelackschicht, ausgeformt sind, insbesondere mittels eines Abformelements eingeprägt sind.Furthermore, it has proven to be advantageous that the structures are formed in a layer applied directly to the carrier layer or with the arrangement of further intermediate layers, in particular an embossed lacquer layer, in particular embossed by means of a molding element.
Bevorzugt weist die Schicht mit den darin ausgeformten Strukturen eine Schichtdicke zwischen 0,5 - 300 µm, insbesondere zwischen 0,8 - 50 µm, bevorzugt zwischen 1 - 10 µm auf.The layer with the structures formed therein preferably has a layer thickness between 0.5-300 μm, in particular between 0.8-50 μm, preferably between 1-10 μm.
Bei einer weiteren Ausführungsform des erfindungsgemäßen Sicherheitselements ist es vorgesehen, dass es an einer den Strukturen abgewandten Seite der Trägerschicht zumindest eine reflektierende Schicht aufweist und/oder zwischen der Trägerschicht und den Strukturen eine reflektierende Schicht angeordnet ist und/oder die Strukturen mit zumindest einer reflektierenden Schicht beschichtet sind, wobei die zumindest eine reflektierende Schicht bevorzugt ein metallisches Material, insbesondere ausgewählt aus der Gruppe, Silber, Kupfer, Aluminium Gold, Platin, Niob, Zinn, oder aus Nickel, Titan, Vanadium, Chrom, Kobalt und Palladium oder Legierungen dieser Materialien, insbesondere Kobalt-Nickel-Legierungen, oder zumindest ein hochbrechendes dielektrisches Material mit einem Brechungsindex von größer als 1,65, insbesondere ausgewählt aus der Gruppe Zinksulfid (ZnS), Zinkoxid (ZnO), Titandioxid (TiO2), Kohlenstoff (C), Indiumoxid (In2O3), Indium-Zinn-Oxid (ITO), Tantalpentoxid (Ta2O5), Ceroxid (CeO2), Yttriumoxid (Y2O3), Europiumoxid (Eu2O3), Eisenoxide wie zum Beispiel Eisen(II,III)oxid (Fe3O4) und Eisen(III)oxid (Fe2O3), Hafniumnitrid (HfN), Hafniumcarbid (HfC), Hafniumoxid (HfO2), Lanthanoxid (La2O3), Magnesiumoxid (MgO), Neodymoxid (Nd2O3), Praseodymoxid (Pr6O11), Samariumoxid (Sm2O3), Antimontrioxid (Sb2O3), Siliziumcarbid (SiC), Siliziumnitrid (Si3N4), Siliziummonoxid (SiO), Selentrioxid (Se2O3), Zinnoxid (SnO2), Wolframtrioxid (WO3), hochbrechende organische Monomere und/oder hochbrechende organische Polymere umfasst oder aus zumindest einem dieser Materialien hergestellt ist.In a further embodiment of the security element according to the invention, it is provided that it has at least one reflective layer on a side of the carrier layer facing away from the structures and / or a reflective layer is arranged between the carrier layer and the structures and / or the structures with at least one reflective layer are coated, the at least one reflective layer preferably being a metallic material, in particular selected from the group consisting of silver, copper, aluminum, gold, platinum, niobium, tin, or of nickel, titanium, vanadium, chromium, cobalt and palladium or alloys of these materials , in particular cobalt-nickel alloys, or at least one high-index dielectric material with a refractive index greater than 1.65, in particular selected from the group consisting of zinc sulfide (ZnS), zinc oxide (ZnO), titanium dioxide (TiO2), carbon (C), indium oxide (In2O3), indium tin oxide (ITO), tantalum pentoxide (Ta2O5), cerium oxide (CeO2), yttrium oxide (Y2O3), europium oxide (Eu2O3), iron oxides such as iron (II, III) oxide (Fe3O4) and iron (III) oxide (Fe2O3), hafnium nitride (HfN), hafnium carbide (HfC), hafnium oxide ( HfO2), lanthanum oxide (La2O3), magnesium oxide (MgO), neodymium oxide (Nd2O3), praseodymium oxide (Pr6O11), samarium oxide (Sm2O3), antimony trioxide (Sb2O3), silicon carbide (SiC), silicon nitride (Si3N4), silicon monoxide (SiO) Se2O3), tin oxide (SnO2), tungsten trioxide (WO3), high refractive index organic monomers and / or high refractive index organic polymers or is made from at least one of these materials.
Weiters kann das Sicherheitselement mit maschinenlesbaren Merkmalen, ausgestattet sein, wobei es sich bei den maschinenlesbaren Merkmalen insbesondere um Magnetcodierungen, elektrisch leitfähige Schichten, elektromagnetische Wellen absorbierende und/oder reemittierende Stoffe handelt.Furthermore, the security element can be equipped with machine-readable features, the machine-readable features in particular being magnetic codings, Electrically conductive layers, electromagnetic waves absorbing and / or re-emitting substances.
Darüber hinaus kann das Sicherheitselement zusätzliche Schichten aufweisen, welche zusätzlichen Schichten insbesondere Schutzlacke, Heißsiegellacke, Kleber, Primer und/oder Folien umfassenIn addition, the security element can have additional layers, which additional layers comprise in particular protective lacquers, heat-sealing lacquers, adhesives, primers and / or foils
Zum besseren Verständnis der Erfindung wird diese anhand der nachfolgenden Figuren näher erläutert.For a better understanding of the invention, it is explained in more detail with reference to the following figures.
Es zeigen jeweils in stark vereinfachter, schematischer Darstellung:
- Fig. 1
- ein erfindungsgemäßes Sicherheitselement;
- Fig. 2
- einen Schnitt durch eine erste Ausführungsform eines Sicherheitselements;
- Fig. 3
- einen Schnitt durch eine zweite Ausführungsform eines Sicherheitselements.
- Fig. 1
- a security element according to the invention;
- Fig. 2
- a section through a first embodiment of a security element;
- Fig. 3
- a section through a second embodiment of a security element.
Einführend sei festgehalten, dass in den unterschiedlich beschriebenen Ausführungsformen gleiche Teile mit gleichen Bezugszeichen bzw. gleichen Bauteilbezeichnungen versehen werden, wobei die in der gesamten Beschreibung enthaltenen Offenbarungen sinngemäß auf gleiche Teile mit gleichen Bezugszeichen bzw. gleichen Bauteilbezeichnungen übertragen werden können. Auch sind die in der Beschreibung gewählten Lageangaben, wie z.B. oben, unten, seitlich usw. auf die unmittelbar beschriebene sowie dargestellte Figur bezogen und sind diese Lageangaben bei einer Lageänderung sinngemäß auf die neue Lage zu übertragen.By way of introduction, it should be noted that in the differently described embodiments, the same parts are provided with the same reference symbols or the same component names, whereby the disclosures contained in the entire description can be transferred accordingly to the same parts with the same reference symbols or the same component names. The position details selected in the description, such as above, below, to the side, etc., also relate to the figure immediately described and shown and these position details are to be transferred accordingly to the new position in the event of a change in position.
Die Figuren sind übergreifend beschrieben.The figures are described across the board.
Gemäß
In der
Abhängig von der Beleuchtung können beide Effekte gleichzeitig oder nur einer der beiden Effekte wahrgenommen werden. Es hat sich herausgestellt, dass beispielsweise bei Verwendung von Punktlichtquellen sowohl der Farbkippeffekt als auch das Bewegungsbild deutlich wahrgenommen werden, während hingegen bei diffuser Beleuchtung das Bewegungsbild nicht oder deutlich schwächer wahrgenommen werden kann.Depending on the lighting, both effects can be perceived at the same time or only one of the two effects. It has been found that, for example, when using point light sources, both the color shift effect and the moving image are clearly perceived, while, on the other hand, with diffuse lighting, the moving image cannot be perceived or is significantly weaker.
Wie aus den
Der farbkippende Dünnschichtaufbau 7 kann eine Absorberschicht 8 und eine Distanzschicht 9 aus einem dielektrischen Material aufweisen. Zusätzlich kann der Dünnschichtaufbau 7 eine Reflexionsschicht 10 aufweisen. Wie in
Weiters kann die eine Distanzschicht 9 beispielsweise mindestens ein niederbrechendes dielektrisches Material mit einem Brechungsindex kleiner oder gleich 1,65, insbesondere ausgewählt aus der Gruppe Aluminiumoxid (Al2O3), Metallfluoride, beispielsweise Magnesiumfluorid (MgF2), Aluminiumfluorid (AlF3), Siliziumoxid (SIOx), Siliziumdioxid (SiO2), Cerfluorid (CeF3), Natrium-Aluminium-Fluoride (z.B. Na3AlF6 oder Na5Al3F14), Neodymfluorid (NdF3), Lanthanfluorid (LaF3), Samariumfluorid (SmF3) Bariumfluorid (BaF2), Calciumfluorid (CaF2), Lithiumfluorid (LiF), niederbrechende organische Monomere und/oder niederbrechende organische Polymere oder mindestens ein hochbrechendes dielektrisches Material mit einem Brechungsindex größer als 1,65, insbesondere ausgewählt aus der Gruppe Zinksulfid (ZnS), Zinkoxid (ZnO), Titandioxid (TiO2), Kohlenstoff (C), Indiumoxid (In2O3), Indium-Zinn-Oxid (ITO), Tantalpentoxid (Ta2O5), Ceroxid (CeO2), Yttriumoxid (Y2O3), Europiumoxid (Eu2O3), Eisenoxide wie zum Beispiel Eisen(II,III)oxid (Fe3O4) und Eisen(III)oxid (Fe2O3), Hafniumnitrid (HfN), Hafniumcarbid (HfC), Hafniumoxid (HfO2), Lanthanoxid (La2O3), Magnesiumoxid (MgO), Neodymoxid (Nd2O3), Praseodymoxid (Pr6O11), Samariumoxid (Sm2O3), Antimontrioxid (Sb2O3), Siliziumcarbid (SiC), Siliziumnitrid (Si3N4), Siliziummonoxid (SiO), Selentrioxid (Se2O3), Zinnoxid (SnO2), Wolframtrioxid (WO3), hochbrechende organische Monomere und/oder hochbrechende organische Polymere umfassen oder aus mindestens einem dieser Materialien hergestellt sein.Furthermore, the one spacer layer 9 can, for example, have at least one low-index dielectric material with a refractive index less than or equal to 1.65, in particular selected from the group aluminum oxide (Al2O3), metal fluorides, for example magnesium fluoride (MgF2), aluminum fluoride (AlF3), silicon oxide (SIOx), Silicon dioxide (SiO2), cerium fluoride (CeF3), sodium aluminum fluoride (e.g. Na3AlF6 or Na5Al3F14), neodymium fluoride (NdF3), lanthanum fluoride (LaF3), samarium fluoride (SmF3) barium fluoride (LiF2), calcium fluoride (CaF2), lithium fluoride , low-index organic monomers and / or low-index organic polymers or at least one high-index dielectric material with a refractive index greater than 1.65, in particular selected from the group consisting of zinc sulfide (ZnS), zinc oxide (ZnO), titanium dioxide (TiO2), carbon (C), Indium oxide (In2O3), indium tin oxide (ITO), tantalum pentoxide (Ta2O5), cerium oxide (CeO2), yttrium oxide (Y2O3), europium oxide (Eu2O3), iron oxides such as play iron (II, III) oxide (Fe3O4) and iron (III) oxide (Fe2O3), hafnium nitride (HfN), hafnium carbide (HfC), hafnium oxide (HfO2), lanthanum oxide (La2O3), magnesium oxide (MgO), neodymium oxide (Nd2O3) , Praseodymium oxide (Pr6O11), samarium oxide (Sm2O3), antimony trioxide (Sb2O3), silicon carbide (SiC), silicon nitride (Si3N4), silicon monoxide (SiO), selenium oxide (Se2O3), tin oxide (SnO2), tungsten trioxide (WO3), high refractive index organic monomers / or comprise high refractive index organic polymers or be made from at least one of these materials.
Zudem kann die Reflexionsschicht 10 mindestens ein metallisches Material, insbesondere ausgewählt aus der Gruppe Silber, Kupfer, Aluminium, Gold, Platin, Niob, Zinn, oder aus Nickel, Titan, Vanadium, Chrom, Kobalt und Palladium oder Legierungen dieser Materialien, insbesondere Kobalt-Nickel-Legierungen oder aus zumindest einem hochbrechenden dielektrischen Material mit einem Brechungsindex von größer als 1,65, insbesondere ausgewählt aus der Gruppe Zinksulfid (ZnS), Zinkoxid (ZnO), Titandioxid (TiO2), Kohlenstoff (C), Indiumoxid (In2O3), Indium-Zinn-Oxid (ITO), Tantalpentoxid (Ta2O5), Ceroxid (CeO2), Yttriumoxid (Y2O3), Europiumoxid (Eu2O3), Eisenoxide wie zum Beispiel Eisen(II,III)oxid (Fe3O4) und Eisen(III)oxid (Fe2O3), Hafniumnitrid (HfN), Hafniumcarbid (HfC), Hafniumoxid (HfO2), Lanthanoxid (La2O3), Magnesiumoxid (MgO), Neodymoxid (Nd2O3), Praseodymoxid (Pr6O11), Samariumoxid (Sm2O3), Antimontrioxid (Sb2O3), Siliziumcarbid (SiC), Siliziumnitrid (Si3N4), Siliziummonoxid (SiO), Selentrioxid (Se2O3), Zinnoxid (SnO2), Wolframtrioxid (WO3), hochbrechende organische Monomere und/oder hochbrechende organische Polymere umfassen oder aus mindestens einem dieser Materialien hergestellt sein.In addition, the
Anstelle des Dünnschichtelements 7 können auch farbkippende Pigmente zum Einsatz kommen. Die farbkippenden Pigmente können beispielsweise einen Dünnschichtaufbau aufweisen, der insbesondere beidseitig von einem Reflektor symmetrisch aufgebaut sein kann, also eine Schichtfolge Absorber/Distanzschicht/Reflektor/Distanzschicht/Absorber aufweisen kann. Derartige Pigmente benötigen nicht unbedingt eine den Farbkippeffekt verstärkende Schicht. Die farbkippenden Pigmente können aber auch durch einfachere Interferenzpigmente gebildet sein, z. B. Silica Flakes oder Glimmer, welche eine den Farbkippeffekt verstärkende Schicht, insbesondere eine Schicht aus dunkler Farbe und/oder eine Schicht aus Metalloxiden wie beispielsweise unterstöchiometrisches Aluminiumoxid ,benötigen können. Weiters können die farbkippenden Pigmente als LC-Pigmente (Flüssigkristall-Pigmente) realisiert sein.Instead of the thin-
Weiters kann der farbkippende Bereich 2 eine oder mehrere Flüssigkristallschichten, insbesondere eine oder mehrere cholesterische Flüssigkristallschichten aufweisen.Furthermore, the color-shifting
Bevorzugt befindet sich auf der, der Sichtseite abgewandten Seite der farbkippenden Schicht des ersten Bereichs eine den Farbkippeffekt verstärkenden Schicht, insbesondere eine Schicht aus dunkler Farbe und/oder eine Schicht aus Metalloxiden wie beispielsweise unterstöchiometrisches Aluminiumoxid.Preferably, on the side of the color-shifting layer of the first region facing away from the visible side, there is a layer that reinforces the color-shifting effect, in particular a layer of dark color and / or a layer of metal oxides such as, for example, substoichiometric aluminum oxide.
So kann die den Farbkippeffekt verstärkende Schicht beispielsweise auf der Flüssigkristallschicht oder der Schicht aus farbkippenden Pigmenten aufgebracht sein, sodass die Schicht aus farbkippenden Pigmenten oder die Flüssigkristallschicht zwischen der den Farbkippeffekt verstärkenden Schicht und der Trägerschicht angeordnet ist. Die den Farbkippeffekt verstärkende Schicht kann aber auch zwischen der Trägerschicht und der Schicht aus farbkippenden Pigmenten oder der zumindest einen Flüssigkristallschicht angeordnet sein. Zudem ist es auch möglich, dass die Trägerschicht zwischen der den Farbkippeffekt verstärkenden Schicht und der Schicht aus farbkippenden Pigmenten oder der Flüssigkristallschicht und angeordnet ist.For example, the layer that enhances the color-shifting effect can be applied to the liquid crystal layer or the layer of color-shifting pigments, so that the layer of color-shifting pigments or the liquid crystal layer is arranged between the layer that enhances the color-shifting effect and the carrier layer. The layer that enhances the color-shifting effect can, however, also be arranged between the carrier layer and the layer of color-shifting pigments or the at least one liquid crystal layer. In addition, it is also possible for the carrier layer to be arranged between the layer that enhances the color-shifting effect and the layer of color-shifting pigments or the liquid crystal layer.
Zwischen der den Farbkippeffekt verstärkenden Schicht und der Trägerschicht und/oder der Schicht aus farbkippenden Pigmenten oder der Flüssigkristallschicht können auch je eine oder mehrere Zwischenschichten angeordnet sein.One or more intermediate layers can also be arranged between the layer which reinforces the color-shifting effect and the carrier layer and / or the layer of color-shifting pigments or the liquid crystal layer.
Darüber hinaus kann das Sicherheitselement 1 gemäß
Bevorzugt weist die Trägerschicht 11 eine Dicke von 5 µm bis 1000 µm, besonders bevorzugt eine Dicke von 10 µm - 50 µm, auf. Die Strukturen 4 können in an sich bekannter Weise als diffraktive Strukturen, als Mikrospiegel oder als strahlenoptisch wirksame Facetten ausgebildet sein. Die Ausbildung der Strukturen 4 als diffraktive Strukturen ist beispielsweise aus der
Mehrere Strukturen 4 können eine Gruppe bilden, deren Ausrichtungen derart aufeinander abgestimmt sind, dass sie in einem Beobachtungsraum einen Punkt 12 des Bildmotivs 4a abbilden. Das Bildmotiv 4a setzt sich aus der Summe aller von Gruppe dargestellten Punkte 12 zusammen. Durch Veränderung einer Einfallsrichtung des von der Lichtquelle 5 erzeugten Lichtes oder bei Veränderung des Beobachtungswinkels ist eine Bewegung des Punktes 12 in dem Beobachtungsraum erzeugt bzw. wird eine solche Bewegung des Bildmotivs 4a wahrgenommen. So wandert bei Bewegung der Lichtquelle 5 oder bei Veränderung des Beobachtungswinkels das Bildmotiv 4a, hier in Form eines Kreises, in
Die Strukturen 4 können in einer auf die Trägerschicht 11 aufgebrachten Schicht 13, insbesondere eine Prägelackschicht, ausgeformt sein. Bevorzugt sind sie mittels eines Abformelements eingeprägt. Bevorzugt weist die Schicht 13 mit den darin ausgeformten Strukturen 4 eine Schichtdicke zwischen 0,5 - 300 µm, insbesondere zwischen 0,8 - 50 µm, bevorzugt zwischen 1 - 10 µm auf.The structures 4 can be formed in a
Zur Herstellung des erfindungsgemäßen Sicherheitselements 1 kann die Trägerschicht 11 ganz oder teilweise mit der Schicht 10 und der Schicht 14 beschichtet werden. Hierauf kann der daraus resultierende Schichtverbund ganz oder teilweise mit dem Schicht 13 versehen und die Strukturen 4 in diese, beispielsweise durch Prägung eingebracht werden. Hierauf können zur Erzeugung des farbkippenden Bereichs die einzelnen Schichten des Dünnschichtelements 7 aufgebracht werden. Hierbei ist es möglich das Dünnschichtelement 7 oder die farbkippende Schicht nur in Bereichen des farbkippenden Bereichs 2 aufzubringen oder aber auch im Bereich der Strukturen 4 die einzelnen Schichten des Dünnschichtelements 7 bzw. der farbkippenden Schicht aufzubringen und beispielsweise unter Verwendung von Waschfarbe in an sich bekannter Weise zu entfernen. Es versteht sich von selbst, dass die soeben beschriebenen Ausführungsformen nur beispielhaft zu verstehen sind und dem Fachmann grundsätzlich viele Methoden bekannt sind, um einen Aufbau, wie er dem erfindungsgemäßen Sicherheitselement 1 entspricht zu realisieren.To produce the
Zwischen der Schicht 13 und der Trägerschicht 11 können noch weitere Schichte angeordnet sein, beispielsweise eine Haftvermittlerschicht oder auch eine reflektierende Schicht 14. An der reflektierenden Schicht 14 können durch die Strukturen 4 durchtretende Lichtstrahlen reflektiert werden, um den Punkt 12 in den Beobachtungsraum abzubilden. Die hier dargestellte Ausführungsform ist besonders für diffraktive Strukturen von Vorteil. Wie aus
Alternativ zur Verwendung einer eigenen Schicht 13, in welcher die Strukturen 4 ausgebildet sind, können die Strukturen 4 auch direkt in die Trägerschicht 11 mittels einer Abformvorrichtung, insbesondere durch ein Prägeverfahren, eingebracht sein, wie die in
Auch im Falle der Ausbildung der Strukturen 4 als Mikrospiegel oder Facetten kann reflektierende Schicht 14a, auf den Strukturen 4 angeordnet bzw. können die Strukturen 4 zumindest teilweise mit der Schicht 14a beschichtet sein.Also in the case of the formation of the structures 4 as micromirrors or facets,
Die reflektierende Schicht 14 und die Schicht 14a umfassen bevorzugt ein metallisches Material, insbesondere ausgewählt aus der Gruppe Silber, Kupfer, Aluminium, Gold, Platin, Niob, Zinn, oder aus Nickel, Titan, Vanadium, Chrom, Kobalt und Palladium oder Legierungen dieser Materialien, insbesondere Kobalt-Nickel-Legierungen, oder zumindest ein hochbrechendes dielektrisches Material mit einem Brechungsindex von größer als 1,65, insbesondere ausgewählt aus der Gruppe Zinksulfid (ZnS), Zinkoxid (ZnO), Titandioxid (TiO2), Kohlenstoff (C), Indiumoxid (In2O3), Indium-Zinn-Oxid (ITO), Tantalpentoxid (Ta2O5), Ceroxid (CeO2), Yttriumoxid (Y2O3), Europiumoxid (Eu2O3), Eisenoxide wie zum Beispiel Eisen(II,III)oxid (Fe3O4) und Eisen(III)oxid (Fe2O3), Hafniumnitrid (HfN), Hafniumcarbid (HfC), Hafniumoxid (HfO2), Lanthanoxid (La2O3), Magnesiumoxid (MgO), Neodymoxid (Nd2O3), Praseodymoxid (Pr6O11), Samariumoxid (Sm2O3), Antimontrioxid (Sb2O3), Siliziumcarbid (SiC), Siliziumnitrid (Si3N4), Siliziummonoxid (SiO), Selentrioxid (Se2O3), Zinnoxid (SnO2), Wolframtrioxid (WO3), hochbrechende organische Monomere und/oder hochbrechende organische Polymere oder ist aus zumindest einem dieser Materialien hergestellt.The reflective layer 14 and the layer 14a preferably comprise a metallic material, in particular selected from the group silver, copper, aluminum, gold, platinum, niobium, tin, or from nickel, titanium, vanadium, chromium, cobalt and palladium or alloys of these materials , in particular cobalt-nickel alloys, or at least one high-index dielectric material with a refractive index greater than 1.65, in particular selected from the group consisting of zinc sulfide (ZnS), zinc oxide (ZnO), titanium dioxide (TiO2), carbon (C), indium oxide (In2O3), indium tin oxide (ITO), tantalum pentoxide (Ta2O5), cerium oxide (CeO2), yttrium oxide (Y2O3), europium oxide (Eu2O3), iron oxides such as iron (II, III) oxide (Fe3O4) and iron ( III) oxide (Fe2O3), hafnium nitride (HfN), hafnium carbide (HfC), hafnium oxide (HfO2), lanthanum oxide (La2O3), magnesium oxide (MgO), neodymium oxide (Nd2O3), praseodymium oxide (Pr6O11), samarium oxide (Sm2O3), antimony trioxide (Sb2O3), silicon carbide (SiC), silicon nitride (Si3N4), silicon monoxide (SiO), selenium oxide (Se2O3), tin oxide (SnO2), high-index tungsten trioxide ( organic monomers and / or high refractive index organic polymers or is made from at least one of these materials.
Abschließend sei auch darauf hingewiesen, dass die in
Sämtliche Angaben zu Wertebereichen in gegenständlicher Beschreibung sind so zu verstehen, dass diese beliebige und alle Teilbereiche daraus mitumfassen, z.B. ist die Angabe 1 bis 10 so zu verstehen, dass sämtliche Teilbereiche, ausgehend von der unteren Grenze 1 und der oberen Grenze 10 mit umfasst sind, d.h. sämtliche Teilbereiche beginnen mit einer unteren Grenze von 1 oder größer und enden bei einer oberen Grenze von 10 oder weniger, z.B. 1 bis 1,7, oder 3,2 bis 8,1, oder 5,5 bis 10.All information on value ranges in the present description are to be understood in such a way that they include any and all sub-areas thereof, e.g. the
Der Ordnung halber sei abschließend darauf hingewiesen, dass zum besseren Verständnis des Aufbaus Elemente teilweise unmaßstäblich und/oder vergrößert und/oder verkleinert dargestellt wurden.For the sake of clarity, it should finally be pointed out that, for a better understanding of the structure, some elements have been shown not to scale and / or enlarged and / or reduced.
- 11
- SicherheitselementSecurity element
- 22
- BereichArea
- 33
- BereichArea
- 44th
- StrukturenStructures
- 4a4a
- BildmotivMotif
- 55
- LichtquelleLight source
- 66th
- Schichtlayer
- 77th
- DünnschichtaufbauThin-film structure
- 88th
- AbsorberschichtAbsorber layer
- 99
- DistanzschichtSpacer layer
- 1010
- ReflexionsschichtReflective layer
- 1111
- TrägerschichtCarrier layer
- 1212th
- PunktPoint
- 1313th
- Schichtlayer
- 1414th
- Schichtlayer
- 14a14a
- Schichtlayer
Claims (20)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP19201223.5A EP3800060A1 (en) | 2019-10-03 | 2019-10-03 | Security element with at least one colour change area |
CA3155087A CA3155087A1 (en) | 2019-10-03 | 2020-09-17 | Security element having at least one first color-shifting region |
JP2022520456A JP7634000B2 (en) | 2019-10-03 | 2020-09-17 | Security element having at least one first color change area - Patents.com |
PCT/EP2020/075988 WO2021063691A1 (en) | 2019-10-03 | 2020-09-17 | Security element having at least one first colour-shifting area |
US17/754,476 US12157329B2 (en) | 2019-10-03 | 2020-09-17 | Security element having at least one first color-shifting area |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP19201223.5A EP3800060A1 (en) | 2019-10-03 | 2019-10-03 | Security element with at least one colour change area |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3800060A1 true EP3800060A1 (en) | 2021-04-07 |
Family
ID=68137870
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19201223.5A Pending EP3800060A1 (en) | 2019-10-03 | 2019-10-03 | Security element with at least one colour change area |
Country Status (5)
Country | Link |
---|---|
US (1) | US12157329B2 (en) |
EP (1) | EP3800060A1 (en) |
JP (1) | JP7634000B2 (en) |
CA (1) | CA3155087A1 (en) |
WO (1) | WO2021063691A1 (en) |
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WO2023082732A1 (en) * | 2021-11-11 | 2023-05-19 | 中钞特种防伪科技有限公司 | Optical anti-counterfeiting element, anti-counterfeiting product, and manufacturing method for optical anti-counterfeiting element |
EP4420889A1 (en) * | 2023-02-24 | 2024-08-28 | Hueck Folien Gesellschaft m.b.H. | Security element with electrically conductive layer |
EP4420890A1 (en) * | 2023-02-24 | 2024-08-28 | Hueck Folien Gesellschaft m.b.H. | Substrate with electrically conductive layer |
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Also Published As
Publication number | Publication date |
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WO2021063691A1 (en) | 2021-04-08 |
JP2022551597A (en) | 2022-12-12 |
JP7634000B2 (en) | 2025-02-20 |
US12157329B2 (en) | 2024-12-03 |
CA3155087A1 (en) | 2021-04-08 |
US20240042786A1 (en) | 2024-02-08 |
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