EP3763867A1 - Laundry dispenser with hydrophobic coating - Google Patents
Laundry dispenser with hydrophobic coating Download PDFInfo
- Publication number
- EP3763867A1 EP3763867A1 EP20181745.9A EP20181745A EP3763867A1 EP 3763867 A1 EP3763867 A1 EP 3763867A1 EP 20181745 A EP20181745 A EP 20181745A EP 3763867 A1 EP3763867 A1 EP 3763867A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- dispenser
- coating
- laundry chemistry
- laundry
- dispenser body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 119
- 239000011248 coating agent Substances 0.000 title claims abstract description 118
- 230000002209 hydrophobic effect Effects 0.000 title claims abstract description 31
- 239000002103 nanocoating Substances 0.000 claims description 21
- 230000003075 superhydrophobic effect Effects 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 19
- 238000005192 partition Methods 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 239000011787 zinc oxide Substances 0.000 description 8
- 239000002041 carbon nanotube Substances 0.000 description 7
- 229910021393 carbon nanotube Inorganic materials 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000002105 nanoparticle Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000002979 fabric softener Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000003292 diminished effect Effects 0.000 description 2
- 229910021389 graphene Inorganic materials 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002048 multi walled nanotube Substances 0.000 description 1
- 239000002135 nanosheet Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00
- D06F39/02—Devices for adding soap or other washing agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00
- D06F39/02—Devices for adding soap or other washing agents
- D06F39/022—Devices for adding soap or other washing agents in a liquid state
Definitions
- the present disclosure generally relates to a laundry chemistry dispenser, and more specifically, to a coating for a laundry chemistry dispenser.
- a laundry chemistry dispenser for an appliance includes a base having an inner surface and an outer surface.
- a plurality of sidewalls extend from the base to define at least one interior cavity.
- Each sidewall of the plurality of sidewalls has an inner surface and an outer surface.
- a coating is at least partially disposed on the inner surface of the base and the inner surface of each sidewall of the plurality of sidewalls. The coating is superhydrophobic.
- a laundry chemistry dispenser in at least another aspect, includes a base having an inner surface and an outer surface.
- a plurality of sidewalls extend from the base to define an interior cavity.
- Each sidewall of the plurality of sidewalls has an inner surface and an outer surface.
- a coating is at least partially disposed on the inner surface of the base and the inner surface of each sidewall of the plurality of sidewalls.
- a method of making a laundry chemistry dispenser includes the steps of providing a dispenser body having a base and a plurality of sidewalls.
- the base and each sidewall of the plurality of sidewalls include inner and outer surfaces.
- An interior cavity is defined by the base and the plurality of sidewalls.
- a coating is applied to at least a portion of the dispenser body.
- the coating is a nanocoating.
- the present illustrated embodiments reside primarily in combinations of method steps and apparatus components related to a coating for a laundry chemistry dispenser. Accordingly, the apparatus components and method steps have been represented, where appropriate, by conventional symbols in the drawings, showing only those specific details that are pertinent to understanding the embodiments of the present disclosure so as not to obscure the disclosure with details that will be readily apparent to those of ordinary skill in the art having the benefit of the description herein. Further, like numerals in the description and drawings represent like elements.
- the terms “upper,” “lower,” “right,” “left,” “rear,” “front,” “vertical,” “horizontal,” and derivatives thereof shall relate to the disclosure as oriented in FIG. 1 .
- the term “front” shall refer to the surface of the element closer to an intended viewer, and the term “rear” shall refer to the surface of the element further from the intended viewer.
- the disclosure may assume various alternative orientations, except where expressly specified to the contrary.
- the specific devices and processes illustrated in the attached drawings, and described in the following specification are simply exemplary embodiments of the inventive concepts defined in the appended claims. Hence, specific dimensions and other physical characteristics relating to the embodiments disclosed herein are not to be considered as limiting, unless the claims expressly state otherwise.
- reference numeral 10 generally designates an appliance shown in the form of a laundry appliance that includes a laundry chemistry dispenser 14.
- the laundry chemistry dispenser 14 further includes a base 18 having an inner surface 22 and an outer surface 26 and a plurality of sidewalls 30.
- the plurality of sidewalls 30 generally extend upward from the base 18 to define at least one interior cavity 34.
- Each sidewall 38 of the plurality of sidewalls 30 includes an inner surface 22 and an outer surface 26.
- a coating 42 may then be disposed on the inner surface 22 of the base 18 and the inner surface 22 of each sidewall 38 of the plurality of sidewalls 30.
- the coating 42 may be superhydrophobic or at least near superhydrophobic. Alternatively, the coating 42 may be hydrophobic.
- the appliance 10 is depicted as a horizontal-axis laundry machine. However, it is also contemplated that the appliance 10 may be a vertical-axis laundry machine.
- the laundry chemistry dispenser 14 is disposed within the appliance 10, such that the laundry chemistry dispenser 14 may be pulled out from a front body 50 of the appliance 10.
- the laundry chemistry dispenser 14, as shown, is positioned on rails 54 that slide the laundry chemistry dispenser 14 into and out of the appliance 10 through the front body 50 to selectively provide access to the laundry chemistry dispenser 14 to a user.
- the rails 54 define grooves 58 through which the rails 54 are coupled to the appliance 10.
- Flanges 62 extend from the sidewalls 38 of the laundry chemistry dispenser 14 and are disposed on the rails 54.
- handle 64 is affixed to the rails 54 for pushing and pulling the laundry chemistry dispenser 14 into and out of the appliance 10, respectively.
- an inlet 66 is positioned proximate to an upper portion 68 of a dispenser body 70.
- the dispenser body 70 is defined by the base 18 and the sidewalls 38 of the laundry chemistry dispenser 14.
- the inlet 66 is fluidically coupled with the dispenser body 70 and may be used to dispense a liquid (e.g., water) that mixes with a laundry chemistry 72.
- the inlet 66 may be positioned at a lower portion 74 of the dispenser body 70.
- the inlet 66 is an opening through which the liquid may pass; however, the inlet 66 may also be a tube disposed over the upper portion 68 and through an upper opening 76 of the dispenser body 70 or any other inlet configuration known in the art.
- the laundry chemistry dispenser 14 may include a cover 78 for covering the dispenser body 70.
- the inlet 66 may be integrally formed with a side portion 80 of the cover 78, such that an elongated portion 82 forms the inlet 66.
- a liquid supply line 84 ( FIG. 3 ) may encase the elongated portion 82 to provide a liquid through the inlet 66 and into the dispenser body 70.
- the dispenser body 70 is generally formed from a polycarbonate or polypropylene material; however, the dispenser body 70 may also be formed from any polymeric material known in the art.
- the polymeric material used helps to generally define the range of angles that may be used to expel liquids from the dispenser body 70.
- the dispenser body 70 may be segmented into first, second, and third dispenser bodies 70a, 70b, 70c.
- Each dispenser body 70a-70c includes the lower portion 74 and the upper portion 68.
- the flanges 62 extend outwardly from the upper portion 68.
- the upper and lower portions 68, 74 are generally delineated by an indication line 86 that is provided to help a user measure an amount of laundry chemistry 72 provided to the dispenser body 70.
- the interior cavity 34 of the laundry chemistry dispenser 14 may be divided by a partition 88 to define the first, second, and third dispenser bodies 70a, 70b, 70c. Although three dispenser bodies 70a-70c are illustrated, it is generally contemplated that less than three or more than three dispenser bodies 70a-70c may be used when forming the laundry chemistry dispenser 14. Moreover, the partition 88 may divide the interior cavity 34, such that two or more interior cavities 34 are defined. For example, the laundry chemistry dispenser 14 is divided by the partition 88 to define three interior cavities 34a-34c.
- the first interior cavity 34a may be used for dispensing the laundry chemistry 72
- the second and third interior cavities 34b, 34c may be used for dispensing other liquids such as fabric softener and/or bleach.
- the sidewalls 38, the partition 88, and the base 18 of the dispenser body 70 define the second interior cavity 34b of the second dispenser body 70b.
- a port 90 may be positioned on the base 18 and may include a tab 92 inwardly extending into the interior cavity 34b of the second dispenser body 70b for measuring a maximum amount of liquid to be dispensed.
- the port 90 may be used to dispense, for example, fabric softener.
- Each of the dispenser bodies 70 may receive the laundry chemistry 72.
- the laundry chemistry 72 dispensed in the first dispenser body 70a is typically a laundry detergent.
- the first dispenser body 70a is described in more detail and referred to generally throughout as the dispenser body 70; however, each dispenser body 70 (the first, second, or third dispenser bodies 70a, 70b, 70c) may include the same general features described in association with the first dispenser body 70a.
- an outlet 94 is positioned proximate the lower portion 74 of the dispenser body 70.
- the base 18 of the dispenser body 70 is shown as generally sloped and/or angular toward the outlet 94 to provide a flow path for a liquid received in the dispenser body 70.
- the upper portion 68, the sidewalls 38, and the flanges 62 of the dispenser body 70 define an upper opening 76.
- the inlet 66 ( FIG. 2 ) may be positioned proximate the upper opening 76, such that liquids may be dispensed into the dispenser body 70 via the upper opening 76.
- the laundry chemistry 72 disposed therein condenses and remains tightly concentrated on the base 18 of the dispenser body 70. This concentration results in a surface area 112 of the laundry chemistry 72 in contact with the coating 42 being diminished due to a repulsion effect provided by the coating 42. Accordingly, the laundry chemistry 72 may be completely dispensed from the dispenser body 70 through the outlet 94. It is also contemplated that the coating 42 may be applied to the exposed surfaces of the outlet 94 to allow the laundry chemistry 72 to pass through the outlet 94 without excess laundry chemistry 72 remaining in the outlet 94.
- the coating 42 is generally hydrophobic, such that the liquid dispensed through the inlet 66 is repelled and consequently does not stick to the portions of the dispenser body 70 on which the coating 42 is applied.
- the laundry chemistry 72 is generally hydrophilic, the laundry chemistry 72 tends to remain concentrated, attracting to the liquid from the inlet 66 rather than to the base 18 or the sidewalls 38 to which the coating 42 is applied.
- the laundry chemistry 72 condenses and bonds to itself, and to the liquid supplied to the dispenser body 70.
- the laundry chemistry 72 generally includes components that have a hydrophilic tendency, such that the laundry chemistry 72 is inclined to bond with the liquid supplied to the dispenser body 70 through the inlet 66. Accordingly, the laundry chemistry 72 is more inclined to stick to portions exposed to the liquid dispensed through the inlet 66. Moreover, the laundry chemistry 72, with the hydrophilic components, is more likely to be attracted to wet clothing that may be in the appliance 10. This attraction allows the laundry chemistry 72 to clean the clothing in the appliance 10. Due to the hydrophilic nature of the laundry chemistry 72, the coating 42 may be provided on surfaces of the dispenser body 70 where contact with the laundry chemistry 72 is intended.
- the laundry chemistry 72 will partially adhere to the base 18 and the sidewalls 38 of the dispenser body 70, which would eventually create a build-up of laundry chemistry 72 within the dispenser body 70.
- the dispenser body 70 will get wet from the liquid dispensed through the inlet 66, which would otherwise attract the laundry chemistry 72.
- the coating 42 allows the dispenser body 70 to repel the laundry chemistry 72 in order to minimize potential build-up of the laundry chemistry 72.
- the coating 42 is shown as applied to the dispenser body 70.
- the coating 42 in FIG. 5 is applied to the sidewalls 38 of the dispenser body 70 to completely cover the exposed inner surfaces 22 of the sidewalls 38.
- the laundry chemistry 72 is shown as being disposed within the interior cavity 34 of the dispenser body 70.
- the coating 42 is a carbon nanotube-based nanocoating blended with other nanoparticles, such as zinc oxide nanoparticles. Due to the inherent characters of the active ingredients of the coating 42, such as their excellent water repellent properties, high stiffness and conductivity capacity, the active ingredients offer superior superhydrophobic features, which can exceptionally perform against a harsh working environment. When a controlled loading concentration of zinc oxide is used, using graphene driven carbon nanotubes as active ingredients modified by a fluorographene nanosheet, superhydrophobicity and a water contact angle of approximately 155-degrees can be achieved.
- the superhydrophobic characteristic of the coating 42 of the present concept is ascribed to the irregular microstructure constructed by randomly stacked fluorographene. Incorporation of the carbon nanotubes, allotropes of graphene, into the coating 42 affects protection performance by providing anti-oxidation and corrosion resistance properties.
- the carbon nanotube-based coating 42 blended with zinc oxide nanoparticles exhibits superhydrophobicity features where multiwalled carbon nanotubes may influence the performance of the coating 42, such as improved adhesion strength, increasing wear resistance, and overall impedance enhancement. It has been found that oxygen and water are a main factor causing metal materials to corrode. Therefore, a unique formulation of the superhydrophobic coating 42 has been developed to offer improved non-wetting features with high performance, such as easy rolling of water droplets from the surface.
- pure nano-zinc oxide is hydrophilic due to the many hydroxyl groups existing on the surface of the pure nano-zinc oxide. Modification of the nano-zinc oxide particles with stearic acid to obtain the hydrophobic nano-zinc oxide are provided to construct a fluorinated polysiloxane nano-zinc oxide nanocoating for use with the present concept.
- the coating 42 is formed from a hexagonal nanocoating 126 that is further formed from a ceramic nanoparticle compound that includes special additives.
- the coating 42 generally includes carbon nanotubes, such that a carbon nanotube forest is formed.
- the carbon nanotube forest improves the hydrophobicity of the coating 42, such that a heterogeneous surface is formed on a nano-scale.
- the coating 42 may have either hydrophobic or superhydrophobic properties, such that a contact angle 130 between the laundry chemistry 72 and the dispenser body 70 is relatively substantial.
- the hydrophobic coating 42 provides for a contact angle 130 of at least approximately 100-degrees.
- the contact angle 130 is referred to as the angle between a drop 134 of the laundry chemistry 72 and a flat and horizontal surface upon which the drop 134 is placed, for example on the base 18 of the dispenser body 70.
- the contact angle 130 between the hydrophobic coating 42 and the drop 134 may range from approximately 90-degrees to approximately 130-degrees.
- the superhydrophobic coating 42 provides for a contact angle 130 of at least approximately 130-degrees.
- the contact angle 130 between the superhydrophobic coating 42 and the drop 134 may range from approximately 130-degrees to approximately 160-degrees.
- the contact angle 130 is measured where the laundry chemistry 72 contacts a solid surface. As illustrated, the contact angle 130 is measured from a contact point 132 and outwardly extends from the edge of the laundry chemistry 72. Stated differently, the contact angle 130 refers to the amount of contact between the laundry chemistry 72 and the dispenser body 70. Without the coating 42, the laundry chemistry 72 would spread out over the dispenser body 70. Accordingly, the contact angle 130 between the dispenser body 70 and the laundry chemistry 72 would be small, and the laundry chemistry 72 would be in contact with a majority of the dispenser body 70. Thus, without the coating 42, the contact angle 130 between the laundry chemistry 72 and the dispenser body 70 would be approaching 0-degrees. Therefore, there is a direct relationship between the contact angle 130 and the hydrophobicity of the coating 42.
- the contact angle 130 between the laundry chemistry 72 and the dispenser body 70 increases as the level of hydrophobicity of the coating 42 increases.
- This measurement of hydrophobicity is also known as wetting, which may be defined as how a liquid deposited on a substrate spreads out, or the ability of the liquid to form a boundary with the substrate.
- wetting may be defined as how a liquid deposited on a substrate spreads out, or the ability of the liquid to form a boundary with the substrate.
- the drop 134 of laundry chemistry 72 dispensed onto the base 18 of the dispenser body 70 forms a boundary in response to the hydrophobicity of the coating 42.
- the laundry chemistry 72 is repelled by the coating 42 and minimally spreads out relative the base 18, such that the drop 134 remains in a bead-like configuration.
- the contact angle 130 increases there is a smaller contact point 132 between the laundry chemistry 72 and the coating 42, such that the highest level of hydrophobicity would result in a single contact point 132 of the laundry chemistry 72 contacting the coating 42 to form the drop 134.
- the drop 134 will ultimately roll along the coating 42 until it passes through the outlet 94 and into a washtub 142 ( FIG. 1 ) of the appliance 10 when a washing cycle releases the laundry chemistry 72.
- the coating 42 applied to the dispenser body 70 provides for a large contact angle 130 between the coating 42 and the laundry chemistry 72, such that the coating 42 is at least hydrophobic.
- the laundry chemistry 72 when in contact with the coating 42, will minimize contact with the surface of the dispenser body 70 and instead will condense to form compact drops 134 in order to minimize the surface area 112.
- the drops 134 of the laundry chemistry 72 will have a generally spherical shape resulting in the drops 134, at least partially, rolling relative the coating 42.
- the coating 42 is superhydrophobic, the drops 134 of the laundry chemistry 72 will roll relative the coating 42, in that the laundry chemistry 72 will not stick to the coating 42.
- a sliding angle 150 of the laundry chemistry dispenser 14 is improved by applying the coating 42.
- the sliding angle 150 measures the level of resistance of a substance to a particular liquid, such that the smaller the sliding angle 150 the more repellant the surface of the substance.
- the sliding angle 150 is defined by the angle between a surface (e.g., the dispenser body 70 and/or the coating 42) and a liquid drop (e.g., the drop 134 of laundry chemistry 72) at which the liquid drop starts to slide off the sample surface under the influence of gravitational force.
- the sliding angle 150 is indicated by the dashed line to illustrate the slightly angled dispenser body 70.
- the coating 42 decreases the sliding angle 150 of the dispenser body 70, such that relatively small angling of the base 18 will allow the laundry chemistry 72 to roll or slide off the base 18 and through the outlet 94.
- the laundry chemistry 72 When the laundry chemistry 72 is dispensed into the washtub 142, the laundry chemistry 72 is typically mixed with water, which further increases the sliding angle 150 between the laundry chemistry 72 and the hydrophobic or superhydrophobic coating 42.
- the laundry chemistry 72 generally has a high viscosity, which is lessened by the mixture of water with the laundry chemistry 72.
- the mixture of the water and the laundry chemistry 72 improves the liquid flow, such that the mixture is more likely to be easily dispensed from the laundry chemistry dispenser 14.
- a strong bond is formed between the water and the laundry chemistry 72 as a result of the hydrophilic properties of the laundry chemistry 72.
- the base 18 of the dispenser body 70 is slightly angled to direct the mix of water and laundry chemistry 72 out of the dispenser body 70 via the outlet 94.
- the sliding angle 150 between the laundry chemistry 72 and the base 18 of the dispenser body 70 is minimal.
- the coating 42 may be applied to various parts of the laundry chemistry dispenser 14, but the coating 42 is applied at least to portions in which the laundry chemistry 72 will come into contact most directly, such as the base 18, the lower portion 74 of the dispenser body 70, and the outlet 94.
- other liquids e.g., bleach, fabric softener, vinegar, etc.
- the coating 42 may be applied to all three of the dispenser bodies 70a-70c.
- the coating 42 is formed from a hard coating formulation, such as the ceramic nanoparticle compound with special additives mentioned above, in order to minimize reactions with the additives in the laundry chemistry 72.
- the use of the hard coating formulation lengthens the lifespan of the coating 42.
- the coating 42 provides the laundry chemistry dispenser 14 with hydrophobic properties.
- a conventional container is generally formed from a polymeric material that alone will result in a generally small contact angle 130 between the laundry chemistry 72 and the container. Accordingly, a high sliding angle 150 is required to remove the laundry chemistry 72 from the container. Applying the coating 42 to the inner surfaces 22 of each sidewall 38 and the inner surface 22 of the base 18 results in the dispenser body 70 being fully coated with the coating 42.
- the dispenser body 70 may be partially coated, such that only the lower portion 74 of the dispenser body 70 is covered by the coating 42.
- the dispenser body 70 includes the indication line 86 ( FIG. 4 ) to illustrate the maximum fill point for the laundry chemistry 72. Accordingly, the dispenser body 70 may be coated approximately up to the indication line 86 and/or slightly above the indication line 86 such that the upper portion 68 remains generally uncoated.
- the laundry chemistry 72 is washed out of the container in an attempt to cleanse the container of the laundry chemistry 72.
- the polymeric material of most conventional containers has a low level of hydrophobicity, such that the water used to wash out the container is not repelled by the container itself. Accordingly, some water and laundry chemistry 72 residue will stick to the container, which will result in a build-up of laundry chemistry 72 in the container.
- the consumer must clean the container regularly to avoid the build-up of laundry chemistry 72. If regular cleaning is not maintained then the build-up of laundry chemistry 72 will occur in the container and ultimately affect the clothes to be washed in the laundry appliance. The build-up will eventually breakdown and will be dispensed with the fresh laundry chemistry 72 during the wash cycle. As a result, the build-up will be attracted to the wet clothing due to its hydrophilic properties resulting in black spots on the clothes in the laundry appliance.
- the black spots are unsightly on otherwise clean clothing, but the black spots also exude an odor. Unless the build-up in the container is entirely removed, the odor-inducing black spots will continue to stain the clothes in the laundry appliance during the wash cycle. Accordingly, the use of the coating 42 prevents such build-up from occurring in the first place. Due to the hydrophilic properties of the laundry chemistry 72, it will be repelled by the hydrophobic properties of the coating 42. This repulsion is amplified once water is mixed with the laundry chemistry 72 in order to dispense the laundry chemistry 72 from the dispenser body 70 into the appliance 10.
- the laundry chemistry 72 is attracted to the water, and the mixture of water with the laundry chemistry 72 will further minimize contact with the dispenser body 70 because of the coating 42.
- the coating 42 repels the laundry chemistry 72 out of the dispenser body 70 and into the washtub 142. Accordingly, the build-up is eliminated as the laundry chemistry 72, along with the water, has been removed during the washout of the dispenser body 70 by the water and aided by the coating 42.
- the coating 42 By applying the coating 42 to the laundry chemistry dispenser 14 in areas that the laundry chemistry 72 will come into contact, the clothes to be washed will not be ruined by build-up residue and an unpleasant odor, because the laundry chemistry 72 will fully washout avoiding build-up in the laundry chemistry dispenser 14.
- a method 200 for making a laundry chemistry dispenser 14.
- a dispenser body 70 having a base 18 and a plurality of sidewalls 30 is provided (step 204).
- the base 18 and each sidewall 38 of the plurality of sidewalls 30 include inner and outer surfaces 22, 26.
- An interior cavity 34 is defined by the base 18 and the plurality of sidewalls 30 (step 208).
- a coating 42 is applied to at least a portion of the dispenser body 70 (step 212).
- the coating 42 is a nanocoating and may be formed from a hydrophobic nanocoating (step 216). Alternatively, the coating 42 may be formed from a superhydrophobic nanocoating (step 220).
- the coating 42 may be applied to a lower portion 74 of the dispenser body 70 (step 224).
- a laundry chemistry 72 is dispensed into the interior cavity 34 of the dispenser body 70 (step 228).
- the coating 42 repels the laundry chemistry 72 from the inner surface 22 of the base 18 and the inner surface 22 of each sidewall 38 of the plurality of sidewalls 30 (step 232).
- a partition 88 may divide the interior cavity 34 into a first interior cavity 34a and a second interior cavity 34b (step 236), and the coating 42 may be applied to the partition 88 (step 240).
- a laundry chemistry dispenser for an appliance includes a base.
- a base includes an inner surface and an outer surface.
- a plurality of sidewalls extends from the base and defines at least one interior cavity.
- Each sidewall of the plurality of sidewalls includes an inner surface and an outer surface, and a coating is disposed on the inner surface of the base and each sidewall of the plurality of sidewalls. The coating is superhydrophobic.
- the laundry chemistry dispenser includes a dispenser body.
- the dispenser body includes an upper opening and an outlet that is positioned at a lower portion of the dispenser body.
- the laundry chemistry dispenser includes an inlet positioned proximate an upper opening of the dispenser body.
- the laundry chemistry dispenser includes a laundry chemistry that is repelled by a coating when introduced into at least one interior cavity.
- the laundry chemistry dispenser includes a surface area of the laundry chemistry that is condensed when in contact with a coating.
- a laundry chemistry dispenser includes a partition that divides at least one interior cavity into a first interior cavity and a second interior cavity.
- the coating is disposed on the partition.
- the coating of a laundry chemistry dispenser includes a contact angle of at least 130-degrees.
- a base of a laundry chemistry dispenser includes an inner surface and an outer surface.
- a plurality of sidewalls extend from the base and define an interior cavity.
- Each sidewall of the plurality of sidewalls includes an inner surface and an outer surface, and a coating that is disposed on the inner surface of the base and the inner surface of each sidewall of the plurality of sidewalls.
- the coating of a laundry chemistry dispenser is hydrophobic nanocoating.
- the hydrophobic nanocoating includes a contact angle that is at least 100-degrees.
- the coating of a laundry chemistry dispenser is superhydrophobic nanocoating.
- the superhydrophobic nanocoating includes a contact angle that is at least 130-degrees to 160-degrees.
- the laundry chemistry dispenser includes a partition that divides at least one interior cavity into a first interior cavity and a second interior cavity.
- the coating is disposed on the partition.
- a laundry chemistry is repelled by a coating when introduced into an interior cavity.
- a laundry chemistry dispenser includes a dispenser body that has an upper portion and a lower portion.
- the plurality of sidewalls and the upper portion of the dispenser body defines an upper opening.
- the laundry chemistry dispenser includes an inlet proximate an upper portion of the dispenser body.
- the inlet is received by the upper opening, and an outlet is positioned at the lower portion of the dispenser body.
- a method of making a laundry chemistry dispenser provides a dispenser body that has a base and a plurality of sidewalls.
- the base and each sidewall of the plurality of sidewalls includes an inner surface and an outer surface.
- the method defines an interior cavity of the base and the plurality of sidewalls, and applies a coating to at least a portion of the dispenser body.
- the coating is a nanocoating.
- the method of applying the coating includes steps of forming the coating from a hydrophobic nanocoating.
- the method of applying the coating includes steps of forming the coating from a superhydrophobic nanocoating.
- the method further includes steps to dispense a laundry chemistry in an interior cavity, and repelling the laundry chemistry from an inner surface of a base and an inner surface of each sidewall of a plurality of sidewalls with the coating.
- the method includes steps of applying the coating to a lower portion of a dispenser body.
- the method includes steps to divide the interior cavity into a first interior cavity and a second interior cavity with a partition, and applying a coating to the partition.
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Abstract
Description
- The present disclosure generally relates to a laundry chemistry dispenser, and more specifically, to a coating for a laundry chemistry dispenser.
- In at least one aspect, a laundry chemistry dispenser for an appliance includes a base having an inner surface and an outer surface. A plurality of sidewalls extend from the base to define at least one interior cavity. Each sidewall of the plurality of sidewalls has an inner surface and an outer surface. A coating is at least partially disposed on the inner surface of the base and the inner surface of each sidewall of the plurality of sidewalls. The coating is superhydrophobic.
- In at least another aspect, a laundry chemistry dispenser includes a base having an inner surface and an outer surface. A plurality of sidewalls extend from the base to define an interior cavity. Each sidewall of the plurality of sidewalls has an inner surface and an outer surface. A coating is at least partially disposed on the inner surface of the base and the inner surface of each sidewall of the plurality of sidewalls.
- In at least another aspect, a method of making a laundry chemistry dispenser includes the steps of providing a dispenser body having a base and a plurality of sidewalls. The base and each sidewall of the plurality of sidewalls include inner and outer surfaces. An interior cavity is defined by the base and the plurality of sidewalls. A coating is applied to at least a portion of the dispenser body. The coating is a nanocoating.
- These and other features, advantages, and objects of the present disclosure will be further understood and appreciated by those skilled in the art by reference to the following specification, claims, and appended drawings.
- In the drawings:
-
FIG. 1 is a front perspective view of an appliance; -
FIG. 2 is a top perspective view of a laundry chemistry dispenser for an appliance; -
FIG. 3 is a partial top rear perspective view of the laundry chemistry dispenser ofFIG. 2 ; -
FIG. 4 is a partial top perspective view of a laundry chemistry dispenser for an appliance; -
FIG. 5 is a front cross-sectional plan view of a dispenser body of a laundry chemistry dispenser for an appliance; -
FIG. 6 is a representation of a laundry chemistry dispenser interacting with a coating on the dispenser body ofFIG. 3 ; and -
FIG. 7 is a flow diagram of a method of making a laundry chemistry dispenser. - The components in the figures are not necessarily to scale, emphasis instead being placed upon illustrating the principles described herein.
- The present illustrated embodiments reside primarily in combinations of method steps and apparatus components related to a coating for a laundry chemistry dispenser. Accordingly, the apparatus components and method steps have been represented, where appropriate, by conventional symbols in the drawings, showing only those specific details that are pertinent to understanding the embodiments of the present disclosure so as not to obscure the disclosure with details that will be readily apparent to those of ordinary skill in the art having the benefit of the description herein. Further, like numerals in the description and drawings represent like elements.
- For purposes of description herein, the terms "upper," "lower," "right," "left," "rear," "front," "vertical," "horizontal," and derivatives thereof shall relate to the disclosure as oriented in
FIG. 1 . Unless stated otherwise, the term "front" shall refer to the surface of the element closer to an intended viewer, and the term "rear" shall refer to the surface of the element further from the intended viewer. However, it is to be understood that the disclosure may assume various alternative orientations, except where expressly specified to the contrary. It is also to be understood that the specific devices and processes illustrated in the attached drawings, and described in the following specification are simply exemplary embodiments of the inventive concepts defined in the appended claims. Hence, specific dimensions and other physical characteristics relating to the embodiments disclosed herein are not to be considered as limiting, unless the claims expressly state otherwise. - The terms "including," "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. An element proceeded by "comprises a ... " does not, without more constraints, preclude the existence of additional identical elements in the process, method, article, or apparatus that comprises the element.
- Referring to
FIGS. 1-7 ,reference numeral 10 generally designates an appliance shown in the form of a laundry appliance that includes alaundry chemistry dispenser 14. The laundry chemistry dispenser 14 further includes abase 18 having aninner surface 22 and anouter surface 26 and a plurality ofsidewalls 30. The plurality ofsidewalls 30 generally extend upward from thebase 18 to define at least oneinterior cavity 34. Eachsidewall 38 of the plurality ofsidewalls 30 includes aninner surface 22 and anouter surface 26. Acoating 42 may then be disposed on theinner surface 22 of thebase 18 and theinner surface 22 of eachsidewall 38 of the plurality ofsidewalls 30. Thecoating 42 may be superhydrophobic or at least near superhydrophobic. Alternatively, thecoating 42 may be hydrophobic. - Referring now to
FIG. 1 , theappliance 10 is depicted as a horizontal-axis laundry machine. However, it is also contemplated that theappliance 10 may be a vertical-axis laundry machine. Thelaundry chemistry dispenser 14 is disposed within theappliance 10, such that thelaundry chemistry dispenser 14 may be pulled out from afront body 50 of theappliance 10. The laundry chemistry dispenser 14, as shown, is positioned onrails 54 that slide thelaundry chemistry dispenser 14 into and out of theappliance 10 through thefront body 50 to selectively provide access to thelaundry chemistry dispenser 14 to a user. Therails 54 definegrooves 58 through which therails 54 are coupled to theappliance 10.Flanges 62 extend from thesidewalls 38 of thelaundry chemistry dispenser 14 and are disposed on therails 54. Additionally,handle 64 is affixed to therails 54 for pushing and pulling the laundry chemistry dispenser 14 into and out of theappliance 10, respectively. - Referring now to
FIGS. 2 and4 , aninlet 66 is positioned proximate to anupper portion 68 of adispenser body 70. Thedispenser body 70 is defined by thebase 18 and thesidewalls 38 of thelaundry chemistry dispenser 14. Theinlet 66 is fluidically coupled with thedispenser body 70 and may be used to dispense a liquid (e.g., water) that mixes with alaundry chemistry 72. Alternatively, theinlet 66 may be positioned at alower portion 74 of thedispenser body 70. As illustrated, theinlet 66 is an opening through which the liquid may pass; however, theinlet 66 may also be a tube disposed over theupper portion 68 and through anupper opening 76 of thedispenser body 70 or any other inlet configuration known in the art. In addition, thelaundry chemistry dispenser 14 may include acover 78 for covering thedispenser body 70. Theinlet 66 may be integrally formed with aside portion 80 of thecover 78, such that anelongated portion 82 forms theinlet 66. Accordingly, a liquid supply line 84 (FIG. 3 ) may encase theelongated portion 82 to provide a liquid through theinlet 66 and into thedispenser body 70. - Referring now to
FIG. 4 , thedispenser body 70 is generally formed from a polycarbonate or polypropylene material; however, thedispenser body 70 may also be formed from any polymeric material known in the art. The polymeric material used helps to generally define the range of angles that may be used to expel liquids from thedispenser body 70. Additionally or alternatively, thedispenser body 70 may be segmented into first, second, andthird dispenser bodies dispenser body 70a-70c includes thelower portion 74 and theupper portion 68. Theflanges 62 extend outwardly from theupper portion 68. The upper andlower portions indication line 86 that is provided to help a user measure an amount oflaundry chemistry 72 provided to thedispenser body 70. - Additionally, the
interior cavity 34 of thelaundry chemistry dispenser 14 may be divided by apartition 88 to define the first, second, andthird dispenser bodies dispenser bodies 70a-70c are illustrated, it is generally contemplated that less than three or more than threedispenser bodies 70a-70c may be used when forming thelaundry chemistry dispenser 14. Moreover, thepartition 88 may divide theinterior cavity 34, such that two or moreinterior cavities 34 are defined. For example, thelaundry chemistry dispenser 14 is divided by thepartition 88 to define threeinterior cavities 34a-34c. It is generally contemplated that the firstinterior cavity 34a may be used for dispensing thelaundry chemistry 72, while the second and thirdinterior cavities sidewalls 38, thepartition 88, and thebase 18 of thedispenser body 70 define the secondinterior cavity 34b of thesecond dispenser body 70b. Within thesecond dispenser body 70b, aport 90 may be positioned on thebase 18 and may include atab 92 inwardly extending into theinterior cavity 34b of thesecond dispenser body 70b for measuring a maximum amount of liquid to be dispensed. Theport 90 may be used to dispense, for example, fabric softener. Each of thedispenser bodies 70 may receive thelaundry chemistry 72. For illustrative purposes, not limitation, thelaundry chemistry 72 dispensed in thefirst dispenser body 70a is typically a laundry detergent. In addition, for illustrative purposes, not limitation, thefirst dispenser body 70a is described in more detail and referred to generally throughout as thedispenser body 70; however, each dispenser body 70 (the first, second, orthird dispenser bodies first dispenser body 70a. Additionally, anoutlet 94 is positioned proximate thelower portion 74 of thedispenser body 70. Thebase 18 of thedispenser body 70 is shown as generally sloped and/or angular toward theoutlet 94 to provide a flow path for a liquid received in thedispenser body 70. In addition, theupper portion 68, thesidewalls 38, and theflanges 62 of thedispenser body 70 define anupper opening 76. The inlet 66 (FIG. 2 ) may be positioned proximate theupper opening 76, such that liquids may be dispensed into thedispenser body 70 via theupper opening 76. - Referring now to
FIGS. 5 and6 , with thecoating 42 applied to thelaundry chemistry dispenser 14, thelaundry chemistry 72 disposed therein condenses and remains tightly concentrated on thebase 18 of thedispenser body 70. This concentration results in asurface area 112 of thelaundry chemistry 72 in contact with thecoating 42 being diminished due to a repulsion effect provided by thecoating 42. Accordingly, thelaundry chemistry 72 may be completely dispensed from thedispenser body 70 through theoutlet 94. It is also contemplated that thecoating 42 may be applied to the exposed surfaces of theoutlet 94 to allow thelaundry chemistry 72 to pass through theoutlet 94 withoutexcess laundry chemistry 72 remaining in theoutlet 94. Thecoating 42, described in more detail below, is generally hydrophobic, such that the liquid dispensed through theinlet 66 is repelled and consequently does not stick to the portions of thedispenser body 70 on which thecoating 42 is applied. As thelaundry chemistry 72 is generally hydrophilic, thelaundry chemistry 72 tends to remain concentrated, attracting to the liquid from theinlet 66 rather than to the base 18 or thesidewalls 38 to which thecoating 42 is applied. Thus, rather than spreading out along thebase 18 of thedispenser body 70, thelaundry chemistry 72 condenses and bonds to itself, and to the liquid supplied to thedispenser body 70. - As noted above, the
laundry chemistry 72 generally includes components that have a hydrophilic tendency, such that thelaundry chemistry 72 is inclined to bond with the liquid supplied to thedispenser body 70 through theinlet 66. Accordingly, thelaundry chemistry 72 is more inclined to stick to portions exposed to the liquid dispensed through theinlet 66. Moreover, thelaundry chemistry 72, with the hydrophilic components, is more likely to be attracted to wet clothing that may be in theappliance 10. This attraction allows thelaundry chemistry 72 to clean the clothing in theappliance 10. Due to the hydrophilic nature of thelaundry chemistry 72, thecoating 42 may be provided on surfaces of thedispenser body 70 where contact with thelaundry chemistry 72 is intended. Without thecoating 42, thelaundry chemistry 72 will partially adhere to thebase 18 and thesidewalls 38 of thedispenser body 70, which would eventually create a build-up oflaundry chemistry 72 within thedispenser body 70. Thedispenser body 70 will get wet from the liquid dispensed through theinlet 66, which would otherwise attract thelaundry chemistry 72. However, thecoating 42 allows thedispenser body 70 to repel thelaundry chemistry 72 in order to minimize potential build-up of thelaundry chemistry 72. - With specific reference to
FIG. 5 , thecoating 42 is shown as applied to thedispenser body 70. Thecoating 42 inFIG. 5 is applied to thesidewalls 38 of thedispenser body 70 to completely cover the exposedinner surfaces 22 of thesidewalls 38. As further shown inFIG. 5 , thelaundry chemistry 72 is shown as being disposed within theinterior cavity 34 of thedispenser body 70. - With reference now to
FIG. 6 , for purposes of illustration and depiction, thecoating 42 and thelaundry chemistry 72 have been exaggerated to show details of the interactions therebetween. Thecoating 42 is a carbon nanotube-based nanocoating blended with other nanoparticles, such as zinc oxide nanoparticles. Due to the inherent characters of the active ingredients of thecoating 42, such as their excellent water repellent properties, high stiffness and conductivity capacity, the active ingredients offer superior superhydrophobic features, which can exceptionally perform against a harsh working environment. When a controlled loading concentration of zinc oxide is used, using graphene driven carbon nanotubes as active ingredients modified by a fluorographene nanosheet, superhydrophobicity and a water contact angle of approximately 155-degrees can be achieved. The superhydrophobic characteristic of thecoating 42 of the present concept is ascribed to the irregular microstructure constructed by randomly stacked fluorographene. Incorporation of the carbon nanotubes, allotropes of graphene, into thecoating 42 affects protection performance by providing anti-oxidation and corrosion resistance properties. - Additionally, the carbon nanotube-based
coating 42 blended with zinc oxide nanoparticles exhibits superhydrophobicity features where multiwalled carbon nanotubes may influence the performance of thecoating 42, such as improved adhesion strength, increasing wear resistance, and overall impedance enhancement. It has been found that oxygen and water are a main factor causing metal materials to corrode. Therefore, a unique formulation of thesuperhydrophobic coating 42 has been developed to offer improved non-wetting features with high performance, such as easy rolling of water droplets from the surface. Traditionally pure nano-zinc oxide is hydrophilic due to the many hydroxyl groups existing on the surface of the pure nano-zinc oxide. Modification of the nano-zinc oxide particles with stearic acid to obtain the hydrophobic nano-zinc oxide are provided to construct a fluorinated polysiloxane nano-zinc oxide nanocoating for use with the present concept. - More generally, the
coating 42 is formed from ahexagonal nanocoating 126 that is further formed from a ceramic nanoparticle compound that includes special additives. In addition, thecoating 42 generally includes carbon nanotubes, such that a carbon nanotube forest is formed. The carbon nanotube forest improves the hydrophobicity of thecoating 42, such that a heterogeneous surface is formed on a nano-scale. Thus, even a minuscule amount of thelaundry chemistry 72 will still be repelled by thecoating 42. Accordingly, thecoating 42 may have either hydrophobic or superhydrophobic properties, such that acontact angle 130 between thelaundry chemistry 72 and thedispenser body 70 is relatively substantial. For example, in distinguishing hydrophobic and superhydrophobic coatings, thehydrophobic coating 42 provides for acontact angle 130 of at least approximately 100-degrees. Thecontact angle 130 is referred to as the angle between adrop 134 of thelaundry chemistry 72 and a flat and horizontal surface upon which thedrop 134 is placed, for example on thebase 18 of thedispenser body 70. Generally, thecontact angle 130 between thehydrophobic coating 42 and thedrop 134 may range from approximately 90-degrees to approximately 130-degrees. Comparatively, thesuperhydrophobic coating 42, provides for acontact angle 130 of at least approximately 130-degrees. Generally, thecontact angle 130 between thesuperhydrophobic coating 42 and thedrop 134 may range from approximately 130-degrees to approximately 160-degrees. - As shown in
FIG. 6 , thecontact angle 130 is measured where thelaundry chemistry 72 contacts a solid surface. As illustrated, thecontact angle 130 is measured from acontact point 132 and outwardly extends from the edge of thelaundry chemistry 72. Stated differently, thecontact angle 130 refers to the amount of contact between thelaundry chemistry 72 and thedispenser body 70. Without thecoating 42, thelaundry chemistry 72 would spread out over thedispenser body 70. Accordingly, thecontact angle 130 between thedispenser body 70 and thelaundry chemistry 72 would be small, and thelaundry chemistry 72 would be in contact with a majority of thedispenser body 70. Thus, without thecoating 42, thecontact angle 130 between thelaundry chemistry 72 and thedispenser body 70 would be approaching 0-degrees. Therefore, there is a direct relationship between thecontact angle 130 and the hydrophobicity of thecoating 42. - The
contact angle 130 between thelaundry chemistry 72 and thedispenser body 70 increases as the level of hydrophobicity of thecoating 42 increases. This measurement of hydrophobicity is also known as wetting, which may be defined as how a liquid deposited on a substrate spreads out, or the ability of the liquid to form a boundary with the substrate. For example, thedrop 134 oflaundry chemistry 72 dispensed onto thebase 18 of thedispenser body 70 forms a boundary in response to the hydrophobicity of thecoating 42. Thelaundry chemistry 72 is repelled by thecoating 42 and minimally spreads out relative thebase 18, such that thedrop 134 remains in a bead-like configuration. Accordingly, as thecontact angle 130 increases there is asmaller contact point 132 between thelaundry chemistry 72 and thecoating 42, such that the highest level of hydrophobicity would result in asingle contact point 132 of thelaundry chemistry 72 contacting thecoating 42 to form thedrop 134. Having a diminished area of contact, thedrop 134 will ultimately roll along thecoating 42 until it passes through theoutlet 94 and into a washtub 142 (FIG. 1 ) of theappliance 10 when a washing cycle releases thelaundry chemistry 72. - The
coating 42 applied to thedispenser body 70 provides for alarge contact angle 130 between thecoating 42 and thelaundry chemistry 72, such that thecoating 42 is at least hydrophobic. Thelaundry chemistry 72, when in contact with thecoating 42, will minimize contact with the surface of thedispenser body 70 and instead will condense to form compact drops 134 in order to minimize thesurface area 112. Thus, thedrops 134 of thelaundry chemistry 72 will have a generally spherical shape resulting in thedrops 134, at least partially, rolling relative thecoating 42. Where thecoating 42 is superhydrophobic, thedrops 134 of thelaundry chemistry 72 will roll relative thecoating 42, in that thelaundry chemistry 72 will not stick to thecoating 42. Consequently, a slidingangle 150 of thelaundry chemistry dispenser 14 is improved by applying thecoating 42. The slidingangle 150 measures the level of resistance of a substance to a particular liquid, such that the smaller the slidingangle 150 the more repellant the surface of the substance. Typically, the slidingangle 150 is defined by the angle between a surface (e.g., thedispenser body 70 and/or the coating 42) and a liquid drop (e.g., thedrop 134 of laundry chemistry 72) at which the liquid drop starts to slide off the sample surface under the influence of gravitational force. As illustrated inFIG. 6 , the slidingangle 150 is indicated by the dashed line to illustrate the slightly angleddispenser body 70. Thecoating 42 decreases the slidingangle 150 of thedispenser body 70, such that relatively small angling of the base 18 will allow thelaundry chemistry 72 to roll or slide off thebase 18 and through theoutlet 94. - When the
laundry chemistry 72 is dispensed into thewashtub 142, thelaundry chemistry 72 is typically mixed with water, which further increases the slidingangle 150 between thelaundry chemistry 72 and the hydrophobic orsuperhydrophobic coating 42. Thelaundry chemistry 72 generally has a high viscosity, which is lessened by the mixture of water with thelaundry chemistry 72. The mixture of the water and thelaundry chemistry 72 improves the liquid flow, such that the mixture is more likely to be easily dispensed from thelaundry chemistry dispenser 14. Moreover, as the water mixes with the laundry chemistry 72 a strong bond is formed between the water and thelaundry chemistry 72 as a result of the hydrophilic properties of thelaundry chemistry 72. - Accordingly, the
base 18 of thedispenser body 70 is slightly angled to direct the mix of water andlaundry chemistry 72 out of thedispenser body 70 via theoutlet 94. Stated differently, the slidingangle 150 between thelaundry chemistry 72 and thebase 18 of thedispenser body 70 is minimal. Thecoating 42 may be applied to various parts of thelaundry chemistry dispenser 14, but thecoating 42 is applied at least to portions in which thelaundry chemistry 72 will come into contact most directly, such as thebase 18, thelower portion 74 of thedispenser body 70, and theoutlet 94. Additionally, due to the lower viscosity of other liquids (e.g., bleach, fabric softener, vinegar, etc.), it may be desirable to apply thecoating 42 to thefirst dispenser body 70a and leave the second andthird dispenser bodies laundry chemistry dispenser 14, thecoating 42 may be applied to all three of thedispenser bodies 70a-70c. - The
coating 42 is formed from a hard coating formulation, such as the ceramic nanoparticle compound with special additives mentioned above, in order to minimize reactions with the additives in thelaundry chemistry 72. The use of the hard coating formulation lengthens the lifespan of thecoating 42. Thecoating 42 provides thelaundry chemistry dispenser 14 with hydrophobic properties. A conventional container is generally formed from a polymeric material that alone will result in a generallysmall contact angle 130 between thelaundry chemistry 72 and the container. Accordingly, a high slidingangle 150 is required to remove thelaundry chemistry 72 from the container. Applying thecoating 42 to theinner surfaces 22 of eachsidewall 38 and theinner surface 22 of the base 18 results in thedispenser body 70 being fully coated with thecoating 42. However, it is also contemplated that thedispenser body 70 may be partially coated, such that only thelower portion 74 of thedispenser body 70 is covered by thecoating 42. For example, thedispenser body 70 includes the indication line 86 (FIG. 4 ) to illustrate the maximum fill point for thelaundry chemistry 72. Accordingly, thedispenser body 70 may be coated approximately up to theindication line 86 and/or slightly above theindication line 86 such that theupper portion 68 remains generally uncoated. - In conventional laundry appliances, the
laundry chemistry 72 is washed out of the container in an attempt to cleanse the container of thelaundry chemistry 72. However, the polymeric material of most conventional containers has a low level of hydrophobicity, such that the water used to wash out the container is not repelled by the container itself. Accordingly, some water andlaundry chemistry 72 residue will stick to the container, which will result in a build-up oflaundry chemistry 72 in the container. Thus, the consumer must clean the container regularly to avoid the build-up oflaundry chemistry 72. If regular cleaning is not maintained then the build-up oflaundry chemistry 72 will occur in the container and ultimately affect the clothes to be washed in the laundry appliance. The build-up will eventually breakdown and will be dispensed with thefresh laundry chemistry 72 during the wash cycle. As a result, the build-up will be attracted to the wet clothing due to its hydrophilic properties resulting in black spots on the clothes in the laundry appliance. - Not only are the black spots unsightly on otherwise clean clothing, but the black spots also exude an odor. Unless the build-up in the container is entirely removed, the odor-inducing black spots will continue to stain the clothes in the laundry appliance during the wash cycle. Accordingly, the use of the
coating 42 prevents such build-up from occurring in the first place. Due to the hydrophilic properties of thelaundry chemistry 72, it will be repelled by the hydrophobic properties of thecoating 42. This repulsion is amplified once water is mixed with thelaundry chemistry 72 in order to dispense thelaundry chemistry 72 from thedispenser body 70 into theappliance 10. Thelaundry chemistry 72 is attracted to the water, and the mixture of water with thelaundry chemistry 72 will further minimize contact with thedispenser body 70 because of thecoating 42. Thus, when dispensing thelaundry chemistry 72 from thedispenser body 70 thelaundry chemistry 72 will not stick to thedispenser body 70, but rather, thecoating 42 repels thelaundry chemistry 72 out of thedispenser body 70 and into thewashtub 142. Accordingly, the build-up is eliminated as thelaundry chemistry 72, along with the water, has been removed during the washout of thedispenser body 70 by the water and aided by thecoating 42. By applying thecoating 42 to thelaundry chemistry dispenser 14 in areas that thelaundry chemistry 72 will come into contact, the clothes to be washed will not be ruined by build-up residue and an unpleasant odor, because thelaundry chemistry 72 will fully washout avoiding build-up in thelaundry chemistry dispenser 14. - With reference now to
FIGS. 1-7 , having described various aspects of thelaundry chemistry dispenser 14, amethod 200 is disclosed for making alaundry chemistry dispenser 14. According to themethod 200, adispenser body 70 having a base 18 and a plurality ofsidewalls 30 is provided (step 204). Thebase 18 and eachsidewall 38 of the plurality ofsidewalls 30 include inner andouter surfaces interior cavity 34 is defined by thebase 18 and the plurality of sidewalls 30 (step 208). Acoating 42 is applied to at least a portion of the dispenser body 70 (step 212). Thecoating 42 is a nanocoating and may be formed from a hydrophobic nanocoating (step 216). Alternatively, thecoating 42 may be formed from a superhydrophobic nanocoating (step 220). Thecoating 42 may be applied to alower portion 74 of the dispenser body 70 (step 224). - A
laundry chemistry 72 is dispensed into theinterior cavity 34 of the dispenser body 70 (step 228). Thecoating 42 repels thelaundry chemistry 72 from theinner surface 22 of thebase 18 and theinner surface 22 of eachsidewall 38 of the plurality of sidewalls 30 (step 232). Apartition 88 may divide theinterior cavity 34 into a firstinterior cavity 34a and a secondinterior cavity 34b (step 236), and thecoating 42 may be applied to the partition 88 (step 240). - According to at least one aspect of the present disclosure, a laundry chemistry dispenser for an appliance includes a base. A base includes an inner surface and an outer surface. A plurality of sidewalls extends from the base and defines at least one interior cavity. Each sidewall of the plurality of sidewalls includes an inner surface and an outer surface, and a coating is disposed on the inner surface of the base and each sidewall of the plurality of sidewalls. The coating is superhydrophobic.
- According to another aspect of the present disclosure, the laundry chemistry dispenser includes a dispenser body. The dispenser body includes an upper opening and an outlet that is positioned at a lower portion of the dispenser body.
- According to yet another aspect of the present disclosure, the laundry chemistry dispenser includes an inlet positioned proximate an upper opening of the dispenser body.
- According to still another aspect of the present disclosure, the laundry chemistry dispenser includes a laundry chemistry that is repelled by a coating when introduced into at least one interior cavity.
- According to another aspect of the present disclosure, the laundry chemistry dispenser includes a surface area of the laundry chemistry that is condensed when in contact with a coating.
- According to yet another aspect of the present disclosure, a laundry chemistry dispenser includes a partition that divides at least one interior cavity into a first interior cavity and a second interior cavity. The coating is disposed on the partition.
- According to another aspect of the present disclosure, the coating of a laundry chemistry dispenser includes a contact angle of at least 130-degrees.
- According to another aspect of the present disclosure, a base of a laundry chemistry dispenser includes an inner surface and an outer surface. A plurality of sidewalls extend from the base and define an interior cavity. Each sidewall of the plurality of sidewalls includes an inner surface and an outer surface, and a coating that is disposed on the inner surface of the base and the inner surface of each sidewall of the plurality of sidewalls.
- According to still another aspect of the present disclosure, the coating of a laundry chemistry dispenser is hydrophobic nanocoating. The hydrophobic nanocoating includes a contact angle that is at least 100-degrees.
- According to still another aspect of the present disclosure, the coating of a laundry chemistry dispenser is superhydrophobic nanocoating. The superhydrophobic nanocoating includes a contact angle that is at least 130-degrees to 160-degrees.
- According to yet another aspect of the present disclosure, the laundry chemistry dispenser includes a partition that divides at least one interior cavity into a first interior cavity and a second interior cavity. The coating is disposed on the partition.
- According to another aspect of the present disclosure, a laundry chemistry is repelled by a coating when introduced into an interior cavity.
- According to yet another aspect of the present disclosure, a laundry chemistry dispenser includes a dispenser body that has an upper portion and a lower portion. The plurality of sidewalls and the upper portion of the dispenser body defines an upper opening.
- According to still another aspect of the present disclosure, the laundry chemistry dispenser includes an inlet proximate an upper portion of the dispenser body. The inlet is received by the upper opening, and an outlet is positioned at the lower portion of the dispenser body.
- According to another aspect of the present disclosure, a method of making a laundry chemistry dispenser provides a dispenser body that has a base and a plurality of sidewalls. The base and each sidewall of the plurality of sidewalls includes an inner surface and an outer surface. The method defines an interior cavity of the base and the plurality of sidewalls, and applies a coating to at least a portion of the dispenser body. The coating is a nanocoating.
- According to yet another aspect of the present disclosure, the method of applying the coating includes steps of forming the coating from a hydrophobic nanocoating.
- According to yet another aspect of the present disclosure, the method of applying the coating includes steps of forming the coating from a superhydrophobic nanocoating.
- According to yet another aspect of the present disclosure, the method further includes steps to dispense a laundry chemistry in an interior cavity, and repelling the laundry chemistry from an inner surface of a base and an inner surface of each sidewall of a plurality of sidewalls with the coating.
- According to yet another aspect of the present disclosure, the method includes steps of applying the coating to a lower portion of a dispenser body.
- According to another aspect of the present disclosure, the method includes steps to divide the interior cavity into a first interior cavity and a second interior cavity with a partition, and applying a coating to the partition.
Claims (12)
- A laundry chemistry dispenser (14) for a laundry appliance (10), comprising:a base (18) including an inner surface (22) and an outer surface (26);a plurality of sidewalls (30) extending from the base (18) to define at least one interior cavity (34), wherein each sidewall (38) of the plurality of sidewalls (30) includes an inner surface (22) and an outer surface (26); anda hydrophobic coating (42) at least partially disposed on the inner surface (22) of the base (18) and the inner surface (22) of each sidewall (38) of the plurality of sidewalls (30), whereby a laundry chemistry (72) is repelled by the hydrophobic coating (42) when introduced into the interior cavity (34).
- The laundry chemistry dispenser (14) of claim 1, wherein the hydrophobic coating (42) is a hydrophobic nanocoating.
- The laundry chemistry dispenser (14) of claim 2, wherein the hydrophobic nanocoating has a contact angle (130) of at least 100 degrees.
- The laundry chemistry dispenser (14) of any one of claims 1 and 2, wherein the hydrophobic coating (42) has a contact angle (130) of at least 130 degrees.
- The laundry chemistry dispenser (14) of any one of claims 1 and 4, wherein the hydrophobic coating (42) is a superhydrophobic nanocoating.
- The laundry chemistry dispenser (14) of claim 5 wherein the superhydrophobic nanocoating has a contact angle (130) of at least 130 degrees to 160 degrees.
- The laundry chemistry dispenser (14) of any one of claims 1-6, including:
a partition (88) dividing the at least one interior cavity (34) into first and second interior cavities (34a, 34b), wherein the hydrophobic coating (42) is disposed on the partition (88). - The laundry chemistry dispenser (14) of any one of claims 1-7, including:
a dispenser body (70) including an upper portion (68) and a lower portion (74), wherein the plurality of sidewalls (30) and the upper portion (68) of the dispenser body (70) define an upper opening (76). - The laundry chemistry dispenser (14) of any one of claim 8, including:an inlet (66) proximate the upper portion (68) of the dispenser body (70), wherein the inlet (66) is received by the upper opening (76) of the dispenser body (70); andan outlet (94) positioned at the lower portion (74) of the dispenser body (70).
- A method of making a laundry chemistry dispenser (14) of any one of the claims 1-9, comprising the steps of:providing a dispenser body (70) having a base (18) and a plurality of sidewalls (30), the base (18) and each sidewall (38) of the plurality of sidewalls (30) including inner and outer surfaces (22, 26); anddefining an interior cavity (34) by the base (18) and the plurality of sidewalls (30);applying a hydrophobic coating (42) to at least a portion of the dispenser body (70), wherein the hydrophobic coating (42) is a nanocoating.
- The method of claim 10, wherein the step of applying the coating (42) includes the step of forming the hydrophobic coating (42) from a hydrophobic nanocoating.
- The method of claim 10, wherein the step of applying the hydrophobic coating (42) includes the step of forming the coating (42) from a superhydrophobic nanocoating.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US16/506,425 US20210010183A1 (en) | 2019-07-09 | 2019-07-09 | Nanoparticles reinforced laundry dispenser |
Publications (1)
Publication Number | Publication Date |
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EP3763867A1 true EP3763867A1 (en) | 2021-01-13 |
Family
ID=71138588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20181745.9A Pending EP3763867A1 (en) | 2019-07-09 | 2020-06-23 | Laundry dispenser with hydrophobic coating |
Country Status (2)
Country | Link |
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US (1) | US20210010183A1 (en) |
EP (1) | EP3763867A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20210093688A (en) * | 2020-01-20 | 2021-07-28 | 엘지전자 주식회사 | Laundry treating apparatus |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2022884A1 (en) * | 2007-07-30 | 2009-02-11 | Miele & Cie. KG | Dispensing unit for a washing machine and washing machine |
WO2013060602A2 (en) * | 2011-10-24 | 2013-05-02 | BSH Bosch und Siemens Hausgeräte GmbH | A washing machine having a component |
WO2016094650A1 (en) * | 2014-12-10 | 2016-06-16 | The Procter & Gamble Company | Container for fabric treatment composition |
WO2016203329A1 (en) * | 2015-06-16 | 2016-12-22 | BSH Hausgeräte GmbH | Household appliance component for a household appliance |
US20170037558A1 (en) * | 2015-08-04 | 2017-02-09 | Whirlpool Corporation | Laundry treating appliance with internal housing |
-
2019
- 2019-07-09 US US16/506,425 patent/US20210010183A1/en not_active Abandoned
-
2020
- 2020-06-23 EP EP20181745.9A patent/EP3763867A1/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2022884A1 (en) * | 2007-07-30 | 2009-02-11 | Miele & Cie. KG | Dispensing unit for a washing machine and washing machine |
WO2013060602A2 (en) * | 2011-10-24 | 2013-05-02 | BSH Bosch und Siemens Hausgeräte GmbH | A washing machine having a component |
WO2016094650A1 (en) * | 2014-12-10 | 2016-06-16 | The Procter & Gamble Company | Container for fabric treatment composition |
WO2016203329A1 (en) * | 2015-06-16 | 2016-12-22 | BSH Hausgeräte GmbH | Household appliance component for a household appliance |
US20170037558A1 (en) * | 2015-08-04 | 2017-02-09 | Whirlpool Corporation | Laundry treating appliance with internal housing |
Also Published As
Publication number | Publication date |
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US20210010183A1 (en) | 2021-01-14 |
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