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EP3393448A1 - Kit de traitement capillaire comprenant un agent de protection de la peau - Google Patents

Kit de traitement capillaire comprenant un agent de protection de la peau

Info

Publication number
EP3393448A1
EP3393448A1 EP16804805.6A EP16804805A EP3393448A1 EP 3393448 A1 EP3393448 A1 EP 3393448A1 EP 16804805 A EP16804805 A EP 16804805A EP 3393448 A1 EP3393448 A1 EP 3393448A1
Authority
EP
European Patent Office
Prior art keywords
composition
weight
polysaccharide
salts
calcium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP16804805.6A
Other languages
German (de)
English (en)
Inventor
Hartmut Manneck
Stefan Hoepfner
Matthias Schweinsberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP3393448A1 publication Critical patent/EP3393448A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/733—Alginic acid; Salts thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits
    • A61K2800/884—Sequential application

Definitions

  • the present application relates to a hair treatment kit containing at least one hair treatment agent and at least one skin protection agent prior to contact with the hair treatment composition, wherein the hair treatment composition is selected from permanent remover, especially for smoothing or perming, and means for Coloring of keratinous fibers.
  • human hair is today treated in a variety of ways with hair cosmetic preparations. These include, for example, the cleansing of hair with shampoos, the care and regeneration with rinses and cures and the bleaching, dyeing and shaping of the hair with dyes, tinting agents, waving agents and styling preparations. In this case, means for changing or nuancing the color of the head hair play a prominent role. In blonding agents, an oxidative whitening of the hair caused by degradation of natural hair dyes
  • oxidation colorants For permanent, intensive colorations with corresponding fastness properties, so-called oxidation colorants are used. Such colorants usually contain oxidation dye precursors, so-called developer components and coupler components. The developer components form under the influence of oxidizing agents or of atmospheric oxygen with one another or with coupling with one or more coupler components, the actual dyes.
  • the oxidation stains are characterized by excellent, long lasting staining results.
  • dyeings usually a mixture of a larger number of oxidation dye precursors must be used; In many cases, direct dyes are still used for shading.
  • dyeing or tinting agents which contain so-called direct drawers as a coloring component. These are dye molecules that attach directly to the hair and do not require an oxidative process to form the paint. These dyes include, for example, the henna already known from antiquity for coloring body and hair. These dyeings are generally much more sensitive to shampooing than the oxidative dyeings, so that a much more undesirable change in shade or even a visible "discoloration" occurs much faster.
  • the actual colorant is usually prepared immediately prior to use by mixing the preparation of the oxidizing agent with the preparation containing the dye precursors.
  • the oxidants used are predominantly aqueous hydrogen peroxide solutions.
  • Such skin protection agents are already known in the prior art. These are usually very fatty creams intended to repel water-based hair treatment products. However, these creams are difficult to wash off.
  • the object was therefore to provide a skin protection agent for the protection of the skin from contact with the hair treatment compositions selected from permanent shaping agents, in particular for smoothing or permanent waving, and agents for coloring keratinous fibers, which is easily washable and yet effective ,
  • the present invention is in a first embodiment, a hair treatment kit comprising
  • At least one hair treatment compartment containing hair treatment agents for dyeing and / or permanent remodeling of hair
  • At least one skin protection compartment containing skin protection agents prior to contact with the hair treatment composition at least one skin protection compartment containing skin protection agents prior to contact with the hair treatment composition.
  • the hair treatment kit according to the invention comprises at least one hair treatment compartment containing hair treatment agents for dyeing or permanent hair remodeling and at least one skin protection compartment containing protection agents from contact with the hair treatment agent.
  • the kit according to the invention may comprise further components, for example a pretreatment and / or a treatment agent for the treated hair or, in particular, an instruction for use which explains the use of the kit according to the invention.
  • the kit according to the invention is preferably designed and packaged for home use.
  • the instructions for use preferably include a guide according to which the user first covers the vulnerable areas of skin or hair with the skin protection agent and then applies the hair dye or hair remover on the hair.
  • the instructions for use may recommend washing the hair after the dyeing or forming step, treating it with conditioning agents, etc. More preferably, the recommendation is to use the dyeing or shaping agent applied to the hair 5-40 minutes after application, preferably about 15 until 30 minutes after, rinse again.
  • the “kit” according to the invention comprises at least one hair treatment compartment which contains means for dyeing or permanently transforming hair and at least one skin protection compartment which contains means for protection against contact with the hair treatment agent These two compartments are in the kit according to the invention
  • "connected to each other” means any mechanism for To make clear to a consumer or user that the colorant and the skin protection agent are related to each other and should be used in combination.
  • connection to each other therefore means, for example, the joint packaging and the joint sale of both compartments within a common outer packaging.
  • the colorant and the skin protection agent may be separately packaged and distributed, with a common marketing concept recommending sharing to the consumer.
  • This compound may exist in gifts, incentive packs or other consumer benefits when purchasing both products, but may also be achieved by mapping the particular other product onto the product packaging.
  • Last but not least, joint advertising for both products or corresponding consumer advice is also possible.
  • the instructions for use contained in the kit according to the invention may also be present in non-physical, for example electronic, form, for example as an Internet page or as spoken instructions, which can be called up by telephone.
  • data carriers such as CD-ROMs or floppy disks, memory sticks, etc. is possible.
  • the kit comprises at least one hair treatment compartment.
  • the term "compartment” here (and also in the case of the skin protection compartment) characterizes a possibility of absorption, regardless of its shape, material or closure, which includes the possibility of containing substances or substance mixtures, the term “compartment” thus encompassing, without being limited thereto the interior of a tube, pouch or sack, canister, can, tub, bottle, jar or package, carton, box, envelope, vial, sack, or other container.
  • the components of the hair dyeing agent may (all) be contained in a single compartment, but it is also possible and preferable to divide them into different compartments and to guide the consumer to mix them together before use.
  • the hair dyeing agent is divided into two compartments, one of which contains the dyeing base and the other the color developer, or if the permanent hair-styling agent is divided into two compartments, one of which contains the keratin reducing agent (US Pat. Corrugating or smoothing agent) and the other contains the fixing agent.
  • the at least one hair treatment compartment contains at least one dyeing or permanent hair remover.
  • Coupler and developer components are also referred to as oxidation dye precursors.
  • the developer components are usually primary aromatic amines having a further, in the para or ortho position free or substituted hydroxy or amino group, Diaminopyridine derivatives, heterocyclic hydrazones, 4-aminopyrazolone derivatives and 2,4,5,6-tetraaminopyrimidine and its derivatives used.
  • m-phenylenediamine derivatives naphthols, resorcinol and resorcinol derivatives, pyrazolones, m-aminophenols and substituted pyridine derivatives are generally used.
  • Coupler substances are in particular a-naphthol, 1, 5, 2,7- and 1, 7-dihydroxynaphthalene, 5-amino-2-methylphenol, m-aminophenol, resorcinol, resorcinol monomethyl ether, m-phenylenediamine, 2,4-diaminophenoxyethanol, 2-Amino-4- (2-hydroxyethylamino) -anisole (Lehmann's Blue), 1-phenyl-3-methyl-pyrazol-5-one, 2,4-dichloro-3-aminophenol, 1, 3-bis (2 , 4-diaminophenoxy) propane, 2-chlororesorcinol, 4-chlororesorcinol, 2-chloro-6-methyl-3-aminophenol, 2-methylresorcinol, 5-methylresorcinol, 3-amino-6-methoxy-2-methylamino-pyridine and 3,5-diamino-2,6-dimethoxy.
  • dyeing or tinting agents which contain so-called direct drawers as a coloring component. These are dye molecules that attach directly to the hair and do not require an oxidative process to form the paint. These dyes include, for example, the henna already known from antiquity for coloring body and hair. These dyeings are generally much more sensitive to shampooing than the oxidative dyeings, so that a much more undesirable change in shade or even a visible "discoloration" occurs much faster.
  • Colorants preferred according to the present invention contain at least one developer-type oxidation dye precursor and / or optionally at least one coupler-type oxidation dye precursor.
  • the present invention is not subject to any restrictions.
  • the colorants according to the invention can be used as further dye precursors
  • Preferred hair dyeing compositions of the present invention are characterized by having at least one dye precursor selected from the group consisting of aromatic and heteroaromatic diamines, aminophenols, naphthols, polyphenols CH-acidic coupler components and their derivatives in amounts of from 0.01 to 25 wt. %, preferably from 0.5 to 10 wt.%, In particular from 1 to 5 wt .-%, each based on the total hair colorant.
  • the colorants contained in the kit according to the invention for shading may contain one or more substantive dyes.
  • Direct dyes are usually nitrophenylenediamines, nitroaminophenols, azo dyes, anthraquinones or indophenols.
  • Preferred substantive dyes are those having the international designations or trade names HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow 6, HC Yellow 12, Acid Yellow 1, Acid Yellow 10, Acid Yellow 23, Acid Yellow 36, HC Orange 1, HC Red 1, HC Red 1, HC Red 13, Acid Red 33, Acid Red 52, HC Red BN, Pigment Red 57: 1, HC Blue 2, HC Blue 12, Disperse Blue 3, Acid Blue 7, Acid Green 50, HC Violet 1, Disperse Violet 1, Disperse Violet 4, Acid Violet 43, Disperse Black 9, Acid Black 1, and Acid Black 52 well-known compounds as well 1, 4-diamino-2-nitrobenzene, 2-amino-4-nitrophenol, 1,4-bis ( ⁇ -hydroxyethyl) amino-2-nitrobenzene, 3-nitro-4- ( ⁇ -hydroxyethyl) aminophenol, 2- (2'-hydroxyethyl) amino-4,6-dinitrophenol, 1- (2'-hydroxyethyl) amino-4-methyl-2-nitrobenzene, 1-amino-4- (2'-hydroxyeth
  • Ureidoethyl) amino-4-nitrobenzene 4-amino-2-nitrodiphenylamine-2'-carboxylic acid, 6-nitro-1,2,3,4-tetrahydroquinoxaline, 2-hydroxy-1,4-naphthoquinone, picramic acid and its salts, 2-amino-6-chloro-4-nitrophenol, 4-ethylamino-3-nitrobenzoic acid and 2-chloro-6-ethylamino-1-hydroxy-4-nitrobenzene.
  • the hair colorants present in the kit according to the invention may furthermore contain all active ingredients, additives and auxiliaries known for such preparations.
  • the colorants contain at least one surfactant, wherein in principle both anionic and zwitterionic, ampholytic, nonionic and cationic surfactants are suitable. In many cases, however, it has proved to be advantageous to select the surfactants from anionic, zwitterionic or nonionic surfactants.
  • the agents for dyeing hair contained in the kit according to the invention preferably contain the active substances in a suitable aqueous, alcoholic or aqueous-alcoholic carrier.
  • a suitable aqueous, alcoholic or aqueous-alcoholic carrier are, for example, creams, emulsions, gels or surfactant-containing foaming solutions, such as shampoos, foam aerosols or other preparations which are suitable for use on the hair.
  • surfactant-containing foaming solutions such as shampoos, foam aerosols or other preparations which are suitable for use on the hair.
  • aqueous-alcoholic solutions are to be understood as meaning aqueous solutions containing from 3 to 70% by weight of a C 1 -C 4 -alcohol, in particular ethanol or isopropanol.
  • the agents according to the invention may additionally contain further organic Solvents such as methoxybutanol, benzyl alcohol, ethyl diglycol or 1, 2-propylene glycol. Preference is given to all water-soluble organic solvents.
  • the pH of the hair dyeing agent contained in the kit of the present invention can be adjusted in a wide range by suitable ingredients such as acidifying agent or alkalizing agent.
  • suitable ingredients such as acidifying agent or alkalizing agent.
  • Preferred agents according to the invention are characterized in that the pH of the composition is 6-1.1, preferably 7.5-10 and more preferably 8-9.
  • Oxidative dyeing of the fibers can in principle be carried out with atmospheric oxygen in the presence of oxidation dye precursors.
  • a chemical oxidizing agent other than atmospheric oxygen is preferably used, especially if, in addition to the coloring, a lightening effect on human hair is desired. This lightening effect may be desired regardless of the staining method.
  • the presence of oxidation dye precursors is therefore not a mandatory requirement for the use of oxidizing agents in the compositions of the invention.
  • Suitable oxidizing agents are persulfates, chlorites and in particular hydrogen peroxide or its addition products of urea, melamine and sodium borate.
  • the actual colorant is conveniently prepared immediately prior to use by mixing the preparation of the oxidizing agent with the preparation containing the compounds of formula I and optionally dye precursors.
  • the resulting ready-to-use hair dye preparation should preferably have a pH in the range from 6 to 12. Particularly preferred is the use of the hair dye in a weakly alkaline medium.
  • the application temperatures can range between 15 and 40 ° C. After a contact time of 5 to 45 minutes, the hair dye is removed by rinsing of the hair to be dyed. The washing with a shampoo is omitted if a strong surfactant-containing carrier, e.g. a dyeing shampoo was used.
  • a hair dyeing agent present in the kit according to the invention can optionally be applied to the hair with additional dye precursors but also without prior mixing with the oxidation component.
  • the oxidation component is then applied, if appropriate after an intermediate rinse.
  • the corresponding agent is adjusted to a pH of about 4 to 7.
  • an air oxidation is initially desired, wherein the applied agent preferably has a pH of 7 to 10.
  • the use of acidified Peroxidisulfat- solutions may be preferred as the oxidizing agent.
  • the kit according to the invention further comprises at least one skin protection compartment containing at least one skin protection agent.
  • This skin protection agent is applied to the potentially hazardous skin areas prior to the application of the colorant or the reshaping agent.
  • the means for protection against contact with the hair treatment agent prevents the access of the subsequently applied dyeing or forming agent by means of the skin and / or hair areas that have been treated with the skin protection agent.
  • the skin protection agent according to the invention before contact with the hair treatment composition comprises a two-part kit of the following physically separated components (D) and (C):
  • a polyvalent metal ion selected from calcium, strontium, barium and aluminum salts and, under certain conditions selected from potassium salts, each having a water solubility at 20 ° C of at least 500 mg / l
  • the at least one selected Polysaccharide forms on the treated skin a gelled film which acts as a barrier which prevents or at least reduces the contact of the skin with the coloring or reshaping hair treatment agent.
  • Another object of the present application is a method for protecting the skin from contact with a hair treatment agent during a hair treatment process, which is selected from the permanent forming, in particular for smoothing or perming, and the coloring of keratinic fibers, characterized in that before Application of the hair treatment agent on the hair, the following steps in any order:
  • 111.1 at least one polysaccharide which can form a gel with calcium ions in an aqueous medium and is preferably selected from alginic acid, kappa-carrageenan, iota-carrageenan and pectin, and / or at least one salt of the abovementioned polysaccharides, selected from the alkali metal, the ammonium the mono-, di- and trialkylammonium, the mono-, di- and trialkanolammonium and the magnesium salts, preferably in a total amount of 0.1-5 wt.%, preferably 0.5-2 wt.% , particularly preferably 0.5-2.5% by weight, in each case based on the weight of the composition (D), in the case of salts of the kappa-carrageenan whose alkali metal salt is selected from only lithium and sodium salts,
  • 111.4 optionally at least one polymer containing (meth) acrylic acid, (meth) acrylate, (meth) acrylamide and / or 2-acrylamido-2-methylpropanesulfonic acid monomers, preferably in a total amount of 0.05-3 wt. %, preferably 0.2-0.5% by weight, based on the weight of the composition (D),
  • iii.5. optionally at least one oil in a total amount of 0, 1 to 10 wt .-%, preferably 0.3 to 5 wt .-%, particularly preferably 1 to 3 wt .-%, each based on the weight of the polysaccharide composition (D. )
  • polysaccharide composition (D) by mixing a solid, preferably powdered, polysaccharide composition (D 1 ) containing iii.1 and optionally iii.3 and / or optionally iii.4, with the component iii.2 and optionally with component iii.5 produced in situ or 0.01 to 24 hours before the hair treatment process is carried out,
  • d) i. From 0.1 to 3% by weight, preferably from 0.2 to 2% by weight, particularly preferably from 0.4 to 1% by weight, based on the weight of the composition (C), of at least one salt of a polyvalent metal ion, selected from calcium, strontium, barium and aluminum salts having a water solubility at 20 ° C of at least 500 mg / l, and in the event that with Calcium gel-forming polysaccharide kappa-carrageenan or one of its salts, the gelling composition (C) 0, 1 - 3 wt .-%, preferably 0.2 - 2 wt .-%, particularly preferably 0.4 - 1 wt .-% based on the weight of the composition (C), at least one salt selected from potassium, calcium, strontium, barium and aluminum salts having a water solubility at 20 ° C of at least 500 mg / l, d) ii. 50-99% by weight, based on the weight of the
  • the gelling composition (C) has a pH in the range of 4.5 to 7.5, preferably in the range of 5-7, more preferably 5.5-6.5, measured at 20 ° C;
  • the gelling composition (C) in situ or 0.01 to 24 hours prior to the hair treatment process by mixing a solid, preferably powdered, gelling composition (C) containing the at least one salt mentioned under d) i in powder form and optionally at least one cationic polymer which is preferably selected from cationized guar ethers, in powder form, with water d) iii,
  • (D) and (C) can be applied to the skin in any order, preferably first (D) and then the gelling composition (C) is applied,
  • the potentially endangered skin areas and / or parts of the head hair application of the hair treatment agent to the hair are at least partially covered with the compositions (D) and (C) to provide protection against staining and / or the action of the keratin reducing forming agent achieve.
  • the skin protection agent can be formulated as a cream, lotion, gel, liquid, etc.
  • easily distributable presentation forms are preferred, with sprayable formulations in particular being found to be particularly suitable.
  • low-viscosity preparations may preferably be applied to the hair to be protected as part of a spraying or foaming process.
  • spray or foam preparations are preferred, which can be applied by means of propellant gases or by a pumping mechanism on the hair.
  • Preferred hair treatment kits according to the invention are characterized in that the skin protection compartment is designed as a spray applicator.
  • the propellant gas or propellant gas mixture is contained in the compositions in an amount of at least 1% by weight.
  • the propellant gas or propellant gas mixture contains at least one component which has a boiling point in the range of 0-40 ° C, preferably 15-35 ° C and especially 20-30 ° C at normal pressure.
  • the propellant preferably contains a Cs alkane.
  • 2-methylbutane isopentane
  • neopentane - is the 2-methylbutane with a Boiling point of 29 ° C preferably suitable.
  • a mixture of a C4 alkane and a Cs alkane is used as the propellant, wherein 1: 3 - 3: 1 mixtures (weight ratio) of isopentane / isobutane according to the invention are particularly well suited.
  • the agents used in the kit according to the invention are preferably filled in commercially available filling systems together with the liquefied by pressure propellant gas or propellant mixture in dispensing systems that are sufficiently resistant to pressure, that the propellant gas is present in the liquefied composition.
  • a dispenser for the composition for example, a container with a valve made of a rigid material, which is equipped with a device that uses the ejection force of a stretched rubber tube and / or a stretched product container for ejecting the stored in her composition (ie medium and propellant gas)
  • the containers offered by 3D Dispenser-Distribution GmbH under the name FlexPack ® also use the restoring force of a stretched rubber to eject the composition.
  • containers which contain a folded, substantially gas-impermeable, flexible inner bag made of a chemically inert plastic (eg PET) which is surrounded by an elastic, thick-walled rubber hose are preferred.
  • kits according to the invention are characterized in that the skin protection preparation (s) are formulated as aerosol products.
  • hair treatment kits according to the invention are preferred in which the antifoaming agent has a viscosity (Brookfield viscometer LVT-II, spindle 31, 30 rpm, 20 ° C.) of 0.01 to 100,000 mPas, preferably 0, 1 to 10,000 mPas and in particular from 1 to 1000 mPas.
  • Viscosity Brookfield viscometer LVT-II, spindle 31, 30 rpm, 20 ° C.
  • Both the colorant contained in the hair treatment compartment (s) and the skin protection agent contained in the skin protection compartment may contain other common ingredients of cosmetics.
  • an instruction for use is additionally included which instructs the consumer to avoid undesired staining of the skin and / or hair with the aid of the stain protection agent.
  • the abovementioned kit according to the invention comprises an instruction manual which gives the consumer instructions for use of the compositions according to the invention.
  • "Instructions for use” in the sense of the present application can not only be written versions in any language, but also visual representations such as pictograms.
  • the instructions for use may be permanently attached to or attached to the packaging.
  • the instructions for use may be applied to the outside of the package.
  • the instructions may also be applied to the inside of the package in preferred embodiments of the present invention become. This embodiment is particularly recommended in kits according to the invention, which have an outer packaging.
  • the instructions for use may be printed directly on the outside and / or inside of the packaging, but it is also possible and, preferably, separately prefabricated instructions for use, which may be designed fragrant, adherent to the packaging to connect., These include, but are not limited to the sticking of labels, shrinking of films, the mechanical attachment of labels, papers, boxes, cards, etc. by means , Snap or clamp connections.
  • kits according to the invention which have an additional outer packaging.
  • the separate instructions for use can be made on paper, cardboard, plastic, etc. in the form of sheets, sheets, cards, cards, flyers, fanfolds, etc.
  • the separate instructions for use have the advantage that the consumer can fix them in an exposed position and read repeatedly when using the product. Also, such a separate instructions for use can be taken out of the packaging and read several times in changing locations, without always the complete kit must be carried.
  • Kits according to the invention in which the instructions for use are designed as a separate supplement, are a further preferred embodiment of the present invention.
  • the instructions for use guide the consumer to apply the anti-staining agent to the potentially endangered major species and / or the hairspheres to be protected against final staining before the actual staining procedure is performed.
  • the instructions for use may also instruct you to rinse off the dye after a dyeing process after the dyeing process.
  • the kit may be accompanied by another rinsing agent (shampoo, conditioning shampoo, etc.) as indicated in the instructions for use.
  • methods according to the invention are preferred in which the hair is rinsed off after dyeing or reshaping.
  • Preferred processes according to the invention are characterized in that the hair dye contains at least one substantive dye and / or at least one oxidation dye precursor.
  • the corresponding compounds have been described in detail above. Again, the corresponding compounds have been described in detail above.
  • keratinic fibers and “keratin fibers” according to the invention preferably human hair, but also to understand fur, wool and feathers. By “subsequently”, according to the invention, a period of 1 to 600 seconds is preferably understood.
  • An essential component of skin protection methods according to the invention and preferred according to the invention is at least one salt of a polyvalent metal ion selected from calcium, strontium, barium and aluminum salts having a water solubility of at least 500 mg / l at 20 ° C. and, under certain conditions, also selected from potassium salts a water solubility at 20 ° C of at least 500 mg / l.
  • a polyvalent metal ion selected from calcium, strontium, barium and aluminum salts having a water solubility of at least 500 mg / l at 20 ° C. and, under certain conditions, also selected from potassium salts a water solubility at 20 ° C of at least 500 mg / l.
  • this calcium ion-gelling polysaccharide is selected from alginic acid, kappa-carrageenan, iota-carrageenan and pectin and / or at least one salt of the aforementioned polysaccharides, which in turn is selected from the alkali metal, the ammonium, the mono-, di- and Trialkylammonium-, mono-, di- and Trialkanolammonium- and magnesium salts, wherein in the case of salts of kappa-Carragheenans whose alkali metal salt is selected only from lithium and sodium salts.
  • the at least one gel-forming salt has at 20 ° C a water solubility of at least 500 mg / l, preferably of at least 40 g / l, more preferably of at least 200 g / l, most preferably of at least 350 g / l on.
  • the calcium chloride which is extraordinarily preferred according to the invention, has a water solubility of 740 g / l at 20 ° C.
  • Other gel-forming salts which are particularly preferred according to the invention are selected from calcium acetate (water solubility 374 g / l), calcium lactate, calcium gluconate, calcium gluconate lactate.
  • aluminum chloride aluminum hydroxychloride, aluminum sulfate, aluminum lactate, aluminum acetate, aluminum gluconate.
  • potassium chloride, potassium acetate, potassium lactate, potassium gluconate and potassium sulfate are preferred, with potassium chloride, potassium lactate, and potassium gluconate being particularly preferred.
  • strontium chloride and barium chloride Preference may also be given to mixtures of the abovementioned salts.
  • Polysaccharide selected from alginic acid, kappa-carrageenan, iota-carrageenan and pectin, and / or at least one salt of these polysaccharides
  • Another essential component of skin protection methods which are preferred according to the invention and which are preferred according to the invention is at least one polysaccharide which forms a gel with calcium ions in an aqueous medium.
  • Preferred polysaccharides according to the invention which can form a gel with calcium ions in an aqueous medium are selected from alginic acid, kappa-carrageenan, iota-carrageenan and pectin and at least one salt of the abovementioned polysaccharides selected from the alkali metal, the ammonium and the mono , Di- and trialkylammonium, the mono-, di- and Trialkanolammonium- and magnesium salts, wherein in the case of salts of kappa-Carragheenans whose alkali metal salt is selected only from lithium and sodium salts.
  • Aqueous solutions of these polysaccharides and polysaccharide salts show only slightly increased viscosity, depending on the concentration, but do not form solid gels.
  • alginic acid sodium alginate, ammonium alginate, magnesium alginate, monoethanolammonium alginate, kappa-carrageenan, the lithium salt of kappa-carrageenan, the sodium salt of kappa-carrageenan, iota-carrageenan, the lithium salt of iota-carrageenan, the sodium salt of iota-carrageenan , the potassium salt of iota-carrageenan, the ammonium salt of iota-carrageenan, pectin, sodium pectinate, ammonium pectinate, potassium pectinate and magnesium pectinate, as well as mixtures of these substances.
  • mixtures of alginic acid and sodium alginate in particular mixtures of alginic acid and sodium alginate in the weight ratio of alginic acid to sodium alginate in the range from 1: 2 to 2: 1, preferably in the range from 0.8 to 1, 25, particularly preferably in the weight ratio of 1 : 1.
  • polysaccharides and / or the salts mentioned exhibit a largely pH-independent thickening behavior. However, they gel in contact with certain polyvalent ions, such as calcium, strontium, barium and aluminum ions. In addition, kappa-carrageenan also gels in contact with potassium ions.
  • This behavior is used in the context of the present application to produce on the skin prior to the application of a forming composition or a dyeing composition a film which avoids or at least significantly reduces the contact with the skin-irritating hair treatment agent.
  • the weight ratio of polysaccharide composition (D) to the gelling composition (C) is in the range from 0.2: 1 to 2: 1, preferably in the range from 0.5: 1 to 1, 5: 1 and more preferably 1: 1.
  • the forming composition (KR) is preferably liquid (0 to 500 mPas at 20 ° C), medium viscosity (> 400 to 4000 mPas at 20 ° C) or creamy (> 4000 to 10,000 mPas at 20 ° C).
  • the reshaping compositions (KR) used in accordance with the invention contain at least one keratin reducing compound selected from thioglycolic acid and its salts and / or thiolactic acid and its salts and / or cysteine and / or acetylcysteine and / or cysteamine and salts thereof and mixtures of these keratin reducing compounds ,
  • Preferred forming compositions (KR) used according to the invention are characterized in that the at least one keratin reducing compound is present in a total amount of 0.1 to 20 wt.%, Preferably 1 to 15 wt.%, Particularly preferably 3 to 13 wt. each based on the weight of the agent (KR) is included.
  • agents (KR) the thioglycolic acid and its salts and / or thiolactic acid and its salts in a total amount of 5 to 20 wt.%, Preferably 7 to 15 wt.%, Particularly preferably 10 to 13 wt. each based on the weight of the agent (KR) included.
  • the forming composition (KR) contains at least one alkalizing agent selected from ammonium hydroxide, monoethanolamine and ammonium carbonate and mixtures thereof.
  • the forming composition (KR) contains ammonium hydroxide, ie ammonia in the form of its aqueous solution.
  • Corresponding aqueous ammonia solutions may be 10 to 35 percent solutions (calculated in% by weight, 100 g of aqueous ammonia solution accordingly contain 10 to 35 g of ammonia).
  • Ammonia is preferably used in the form of a 20 to 30% strength by weight solution, particularly preferably in the form of a 25% strength by weight solution.
  • compositions (KR) used according to the invention are characterized in that they contain ammonium hydroxide in an amount of from 0.1 to 5% by weight, preferably from 0.2 to 3% by weight, more preferably from 0, 3 to 2 wt .-% and particularly preferably from 0.4 to 1, 5 wt .-% - based on the weight of the composition (KR) according to the invention - contain.
  • compositions (KR) used in this invention include monoethanolamine.
  • monoethanolamine in a total amount of 0.1 to 6.0 wt .-%, preferably from 0.5 to 4 wt .-%, more preferably from 1 to 3.0 wt. % and more preferably from 2.0 to 2.5% by weight, based on the weight of the composition (KR) used in accordance with the invention.
  • compositions (KR) used in the present invention include ammonium carbonate.
  • ammonium carbonate is present in a total amount of from 0.1 to 6.0% by weight, preferably from 0.5 to 4% by weight, more preferably from 1 to 3.0% by weight. % and more preferably from 2.0 to 2.5% by weight, based on the weight of the composition (KR) used in accordance with the invention.
  • the fixation of the transformed keratin fibers takes place only through the influence of an oxidizing agent.
  • hydrogen peroxide is used for this purpose.
  • the hydrogen peroxide is used as the aqueous solution.
  • Oxidant preparations which are preferred according to the invention are characterized in that they contain from 1.0 to 23.0% by weight, more preferably from 2.5 to 21.0% by weight, particularly preferably from 4.0 to 20.0% by weight and completely particularly preferably 5.0 to 18.0 wt .-% hydrogen peroxide (calculated as 100% H2O2) included. It has proved to be advantageous if the oxidizing agent preparations according to the invention for the stabilization of the hydrogen peroxide additionally contain at least one stabilizer or complexing agent.
  • Particularly preferred stabilizers are in particular EDTA and EDDS, and phosphonates, in particular 1-hydroxyethane-1, 1-diphosphonate (HEDP) and / or ethylenediaminetetramethylenephosphonate (EDTMP) and / or diethylenetriaminepentamethylenephosphonate (DTPMP) or their sodium salts.
  • HEDP 1-hydroxyethane-1, 1-diphosphonate
  • EDTMP ethylenediaminetetramethylenephosphonate
  • DTPMP diethylenetriaminepentamethylenephosphonate
  • compositions (C) and (D) free of anionic or cationic associative polymers, which are substituted with optionally ethoxylated, C6 - C24 alkyl or C6 - C24 alkenyl groups.
  • compositions KR), (C) and (D) used according to the invention and the fixing agent are free of anionic or cationic associative polymers which are optionally ethoxylated, C 6 -C 24 -alkyl- or C 6 -C 24 -alkenyl Groups are substituted and are selected from acrylates / ceteth-20 itaconate copolymers, polyurethane-39 polymers, acrylates / beheneth-25-methacrylate copolymers and acrylate.es / C10-30 alkyl acrylate crosspolymers.
  • compositions used according to the invention may comprise at least one organic solvent which is preferably selected from one or more monohydric or polyhydric alcohols having 2 to 9 carbon atoms, polyethylene glycols having 2 to 20 ethylene glycol units and mixtures of these solvents, preferably in a total amount of 0.001 to 80 wt .-%, particularly preferably 0.01 to 50 wt .-%, exceptionally preferably 0.5 to 20 wt .-%, more preferably 1, 5 to 10 wt .-%, each based on the weight of each composition used according to the invention.
  • Preferred organic solvents are selected from C 1 -C 4 -alcohols, in particular ethanol and isopropanol, furthermore selected from polyhydric alcohols having 2 to 9, preferably selected from 1, 2-propylene glycol, 2-methyl-
  • 1,3-propanediol 1,3-propanediol, glycerol, butylene glycols such as 1, 2-butylene glycol, 1, 3-butylene glycol and
  • 1,4-butylene glycol pentylene glycols such as 1,2-pentanediol and 1,5-pentanediol, hexanediols such as 1,2-hexanediol and 1,6-hexanediol, hexanetriols such as 1, 2,6-hexanetriol, 2-ethyl-2-hydroxymethyl- 1, 3-propanediol, dipropylene glycol, tripropylene glycol, diglycerol and triglycerol, and further selected from polyethylene glycols having from 2 to 20 ethylene glycol units, in particular PEG-3, PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG -10, PEG-12, PEG-14, PEG-16, PEG-18 and PEG-20 and mixtures thereof, with PEG-3 to PEG-8 being preferred.
  • PEG-3 to PEG-8 is likewise preferred according to the invention.
  • a gelling composition (C) is applied to the skin, for example with a brush or similar applicator, or - which is particularly preferred - by spraying, the gelling composition (C) includes:
  • the gelling composition (C) has a pH in the range of 4.5 to 7.5, preferably in the range of 5-7, more preferably 5.5-6.5, measured at 20 ° C.
  • the at least one salt c) i has a water solubility at 20 ° C. of at least 500 mg / l, preferably of at least 40 g / l, more preferably of at least 200 g / l, most preferably of at least 350 g / l.
  • the calcium chloride which is extraordinarily preferred according to the invention, has a water solubility of 740 g / l at 20 ° C.
  • Other particularly preferred salts c) i according to the invention are selected from calcium acetate (water solubility 374 g / l), calcium lactate, calcium gluconate, calcium gluconate lactate.
  • aluminum chloride aluminum hydroxychloride, aluminum sulfate, aluminum lactate, aluminum acetate, aluminum gluconate.
  • potassium chloride, potassium acetate, potassium lactate, potassium gluconate and potassium sulfate are preferred, with potassium chloride, potassium lactate, and potassium gluconate being particularly preferred.
  • strontium chloride and barium chloride Preference may also be given to mixtures of the abovementioned salts.
  • the gelling composition (C), based in each case on its weight, contains 50-99% by weight, preferably 70-95% by weight, particularly preferably 75-92% by weight of water.
  • the gelling composition (C) has a pH in the range of 4.5 to 7.5, preferably in the range of 5-7, more preferably 5.5-6.5, measured at 20 ° C. Whether an acidic or an alkaline pH value is set depends inter alia on whether the viscosity of the composition (C) should be increased with a thickener to improve its application properties, in particular to improve the spray pattern. For the preferably moderate thickening of the composition (C), cationic polymers are particularly suitable.
  • Preferred cationic polymers are selected from cationic guar derivatives, in particular from cationized guar ethers, in particular from polymers having the INCI names hydroxypropyl guar hydroxypropyltrimonium chlorides and guar hydroxypropyltrimonium chlorides. If the gelling composition (C) contains a cationic polymer, this is in a total amount of 0.01 to 1 wt .-%, preferably 0.1 to 0.8 wt .-%, particularly preferably 0.2 to 0.5 wt .-%, each based on the weight of the composition (C) included.
  • the gelling composition (C) contains a cationic polymer, it preferably has a pH in the range of 4-6.5, measured at 20 ° C.
  • the adjustment of the pH is carried out, as for the other compositions used according to the invention, with conventional pH adjusters, in particular citric acid, lactic acid, NaOH, KOH and similar cosmetically acceptable acids and bases.
  • the gelling composition (C) is added in situ or only 0.01 to 24 hours before carrying out the process according to the invention by mixing a solid, preferably pulverulent gelling composition (C) containing at least one of c) i Salt in powder form and optionally at least one cationic polymer, which is preferably selected from cationized guar ethers, in powder form, with water c) iii.
  • the gelling composition contains
  • (C) additionally a solid, preferably powdery, pH adjusting agent, for.
  • An acid such as citric acid, and / or an alkalizing agent such as sodium silicate.
  • a particularly preferred embodiment of the skin protection method according to the invention is characterized in that the at least one polysaccharide which can form a gel with calcium ions in an aqueous medium and which is preferably selected from alginic acid, kappa-carrageenan, iota-carrageenan and pectin, and / or at least one Salt of the abovementioned polysaccharides, which is selected from the alkali metal, ammonium, mono-, di- and trialkylammonium, mono-, di- and Trialkanolammonium- and magnesium salts, wherein in the case of salts of kappa-Carragheenans whose Alkali metal salt selected from lithium and sodium salts only, provided in the form of a polysaccharide composition
  • 111.1 at least one polysaccharide which can form a gel with calcium ions in an aqueous medium and is preferably selected from alginic acid, kappa-carrageenan, iota-carrageenan and pectin, and / or at least one salt of the abovementioned polysaccharides selected from the alkali metal, the ammonium the mono-, di- and trialkylammonium, the mono-, di- and trialkanolammonium and the magnesium salts, preferably in a total amount of 0.1 to 5 wt.%, preferably 0.5 to 2 wt. , particularly preferably 0.5-2.5% by weight, in each case based on the weight of the composition (D), wherein in the case of salts of kappa-carrageenan whose alkali metal salt is selected only from lithium and sodium salts,
  • 111.4 optionally at least one polymer containing (meth) acrylic acid, (meth) acrylate, (meth) acrylamide and / or 2-acrylamido-2-methylpropanesulfonic acid monomers, preferably in a total amount of 0.05-3 wt. %, preferably 0.2-0.5% by weight, based on the weight of the composition (D),
  • 111.5 optionally at least one oil in a total amount of 0, 1 to 10 wt .-%, preferably 0.3 to 5 Wt .-%, particularly preferably 1 to 3 wt .-%, each based on the weight of
  • polysaccharide composition (D) by mixing a solid, preferably powdered, polysaccharide composition (D 1 ) containing iii.1 and optionally iii.3 and / or optionally iii.4, with the component iii.2 and optionally with the component iii.5 in situ or 0.01 to 24 hours before the actual, potentially skin-irritating hair treatment process is carried out.
  • the polysaccharide composition (D) in situ or 0.01 to 24 hours before carrying out the forming process according to the invention by mixing a solid, preferably powdered, polysaccharide composition (D 1 ) containing i.1 and optionally iii.3 and / or optionally iii.4, with component ii.2 and optionally with component ii.5.
  • the at least one polysaccharide which can gel with calcium ions in an aqueous medium
  • 25 ° C to 40 ° C water containing at least one oil a total amount of 0, 1 to 10 wt .-%, preferably 0.3 to 5 wt .-%, particularly preferably 1 to 3 wt .-%, each based on the weight of the polysaccharide composition (D) contains.
  • the oil should be contained in the water before adding the polysaccharide. This significantly promotes the dissolution of the polysaccharide.
  • Oils which are extraordinarily preferred according to the invention are selected from natural and synthetic hydrocarbons, more preferably from mineral oils, paraffin oils, C 18 -30-isoparaffins, in particular isoeicosane, polyisobutenes and polydecenes, furthermore selected from C 8 -C 16 -isoparaffins, in particular from isodecane, isododecane, isotetradecane and isohexadecane and mixtures thereof, as well as 1, 3-di (2-ethylhexyl) cyclohexane.
  • natural and synthetic hydrocarbons more preferably from mineral oils, paraffin oils, C 18 -30-isoparaffins, in particular isoeicosane, polyisobutenes and polydecenes, furthermore selected from C 8 -C 16 -isoparaffins, in particular from isodecane, isododecane, isotetradecane and isohexadecane and mixture
  • oils which are preferred according to the invention are selected from the esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated.
  • these include cetyl 2-ethylhexanoate, 2-hexyldecyl stearate (eg Eutanol® G 16 S), 2-hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate (eg Cegesoft® C 24) and 2-ethylhexyl stearate (e.g. B.
  • Cetiol® 868 isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyldodecyl palmitate, butyloctanoic acid-2 butyl octanoate, diisotridecyl acetate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, oleyl ole
  • Further oils preferred according to the invention are selected from the benzoic acid esters of linear or branched C 8-22 alkanols. Particularly preferred are benzoic C12-C15 alkyl esters, z. B. available as a commercial product Finsolv® TN, isostearyl benzoate, z. B. available as a commercial product Finsolv® SB, ethylhexyl benzoate, z. B. available as a commercial product Finsolv® EB, and benzoic acid octyldocecylester, z. B. available as a commercial product Finsolv® BOD.
  • benzoic acid octyldocecylester z. B. available as a commercial product Finsolv® BOD.
  • Further oils preferred according to the invention are selected from fatty alcohols having 6 to 30 carbon atoms, which are unsaturated or branched and saturated or branched and unsaturated.
  • the branched alcohols are also often referred to as Guerbet alcohols, as they are obtainable by the Guerbet reaction.
  • Preferred alcohol oils are 2-hexyldecanol (Eutanol® G 16), 2-octyldodecanol (Eutanol® G), 2-ethylhexyl alcohol and isostearyl alcohol.
  • Further preferred oils are selected from mixtures of Guerbet alcohols and Guerbet alcohol esters, e.g. the commercial product Cetiol® PGL (2-hexyldecanol and 2-hexyldecyl laurate).
  • Amaranth seed oil apricot kernel oil, argan oil, avocado oil, babassu oil, cottonseed oil, borage seed oil, camelina oil, thistle oil, peanut oil, pomegranate seed oil, grapefruit seed oil, hemp oil, hazelnut oil, elderberry seed oil, currant seed oil, jojoba oil, linseed oil, macadamia nut oil, corn oil, almond oil, marula oil, evening primrose oil, olive oil, palm oil, Palm kernel oil, Brazil nut oil, pecan nut oil, peach kernel oil rapeseed oil, castor oil, sea buckthorn pulp oil, sea buckthorn kernel oil, sesame oil, soybean oil, sunflower oil, grapeseed oil, walnut oil, wild rose oil, wheat germ oil, and the liquid portions of coconut oil and the like.
  • Further cosmetic oils which are particularly preferred according to the invention are selected from the dicarboxylic acid esters of linear or branched C 2 -C 10 -alkanols, in particular diisopropyl adipate, di-n-butyl adipate, di- (2-ethylhexyl) adipate, dioctyl adipate, diethyl / di-n- butyl / dioctyl sebacate, diisopropyl p-racacate, dioctyl malate, dioctyl maleate, dicaprylyl maleate, diisooctyl succinate, di-2-ethylhexyl succinate and di (2-hexyldecyl) succinate.
  • diisopropyl adipate di-n-butyl adipate, di- (2-ethylhexyl) adipate, dioctyl adipate,
  • cosmetic oils are selected from the adducts of 1 to 5 propylene oxide units of monohydric or polyhydric C8-22 alkanols, such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. PPG-2 myristyl ether and PPG-3 myristyl ether (Witconol® APM).
  • monohydric or polyhydric C8-22 alkanols such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. PPG-2 myristyl ether and PPG-3 myristyl ether (Witconol® APM).
  • Further cosmetic oils preferred according to the invention are selected from the adducts of at least 6 ethylene oxide and / or propylene oxide units with monohydric or polyhydric C 3-22 alkanols such as glycerol, butanol, butanediol, myristyl alcohol and stearyl alcohol, which may be esterified if desired, z.
  • PPG-14 butyl ether Ucon Fluid® AP
  • PPG-9 butyl ether Breox® B25
  • PPG-10-butanediol Macol® 57
  • PPG-15 stearyl ether Arlamol® E
  • compositions according to the invention are selected from the C 8 -C 22 fatty alcohol esters of monohydric or polyhydric C 2 -C 7 -hydroxycarboxylic acids, in particular the esters of glycolic acid, lactic acid, malic acid, tartaric acid, citric acid and salicylic acid.
  • esters based on linear C14 / 15-alkanols, eg. B.
  • C12-C15-alkyl lactate and branched in 2-position C12 / 13-alkanols are under the trademark Cosmacol® Nordmann, Rassmann GmbH & Co., Hamburg, to obtain, in particular the commercial products Cosmacol® ESI, Cosmacol ® EMI and Cosmacol® ® EIT.
  • cosmetic oils are selected from the symmetrical, asymmetric or cyclic esters of carbonic acid with C3-22-alkanols, C3-22-alkanediols or C3-22-alkanetriols, eg. B. dicaprylyl carbonate (Cetiol ® CC) or the esters according to the teaching of DE19756454 A1, in particular glycerol carbonate.
  • cosmetic oils which may be preferred according to the invention are selected from the esters of dimers of unsaturated C 12-22 fatty acids (dimer fatty acids) with monovalent linear, branched or cyclic C 2 -C 6 alkanols or with polyfunctional linear or branched C 2 -C 6 alkanols.
  • silicone oils which are suitable according to the invention are selected from the silicone oils to which z.
  • dialkyl and alkylaryl such as cyclopentasiloxane, cyclohexane siloxane, dimethylpolysiloxane and methylphenylpolysiloxane, but also hexamethyldisiloxane, octamethyltrisiloxane and decamethyltetrasiloxane include.
  • Preferred may be volatile silicone oils, which may be cyclic, such as. For example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane and mixtures thereof, as described for.
  • volatile linear silicone oils in particular hexamethyldisiloxane (L2), octamethyltrisiloxane (L3), decamethyltetrasiloxane (L4) and any mixtures of two and three of L2, L3 and / or l_4, preferably mixtures such as those described for.
  • L2 hexamethyldisiloxane
  • L3 octamethyltrisiloxane
  • decamethyltetrasiloxane L4
  • Dow Corning® 200 (0.65 cSt)
  • Dow Corning® 200 1.5 cSt
  • Preferred nonvolatile silicone oils are selected from higher molecular weight linear dimethylpolysiloxanes, commercially available e.g. B.
  • the dissolution of the polysaccharide can be favorably influenced.
  • a surfactant content may cause the polysaccharide composition (D), which should be shaken to dissolve the polysaccharide, to foam too much, making it difficult to apply. Therefore, the polysaccharide composition (D) preferably contains no surfactant.
  • Particularly preferred polysaccharide compositions (D) and (D 1 ) used are thereby in that the at least one polysaccharide capable of gelling with calcium ions in an aqueous medium is selected from alginic acid, sodium alginate, ammonium alginate, magnesium alginate, monoethanolammonium alginate, kappa carrageenan, the lithium salt of kappa carrageenan, the sodium salt of kappa carrageenan, iota-carrageenan, the lithium salt of iota-carrageenan, the sodium salt of iota-carrageenan, the potassium salt of iota-carrageenan, the ammonium salt of iota-carrageenan, pectin, sodium pectinate, ammonium pectinate, potassium pectinate and magnesium pectinate, as well as mixtures of these substances.
  • mixtures of alginic acid and sodium alginate in particular mixtures of alginic acid and sodium alginate in the weight ratio of alginic acid to sodium alginate in the range from 1: 2 to 2: 1, preferably in the range from 0.8 to 1, 25, particularly preferably in the weight ratio of 1 : 1.
  • the polysaccharide composition (D) contains a mixture of alginic acid and sodium alginate in a total amount of 0.1-5 wt.%, More preferably 0.2-3 wt.%, Most preferably 0.5-2, 5 wt .-%, each based on the weight of the composition (D), wherein it is preferred if the weight ratio of alginic acid to sodium alginate in the range of 1: 2 to 2: 1, preferably in the range of 0.8 to 1, 25, particularly preferably in the weight ratio 1: 1.
  • the polysaccharide composition (D) has a pH in the range from 4.5 to 7.5, preferably in the range of 5-7, particularly preferably 5.5-6.5, measured at 20 ° C.
  • the polysaccharide composition (D) or the polysaccharide composition (D 1 ) comprises at least one polymer containing (meth) acrylic acid, (meth) acrylic ester, (meth) acrylamide and / or 2 Acrylamido-2-methylpropanesulfonic acid monomers, preferably, in a total amount of 0.05 to 3 wt .-%, preferably 0.2 to 0.5 wt .-%, based on the weight of the composition (D).
  • the addition of these polymers serves primarily to improve the solubility of the polysaccharide in the in situ preparation of the composition (D).
  • the at least one polymer containing (meth) acrylic acid, (meth) acrylic ester, (meth) acrylamide and / or 2-acrylamido-2-methylpropanesulfonic acid monomers selected from crosslinked homopolymers of acrylic acid, crosslinked homopolymers of the 2- Acrylamido-2-methylpropanesulfonic acid, crosslinked copolymers consisting of acrylic acid and 2-acrylamido-2-methylpropanesulfonic acid units, crosslinked copolymers consisting of 2-methyl-2 [(1-oxo-2-propenyl) amino] -1-propanesulfonic acid units and hydroxyethyl acrylate units, crosslinked copolymers consisting of acrylamide and 2-acrylamido-2-methylpropanesulfonic acid units, crosslinked copolymers consisting of methacrylic acid units and C1-C4-alkyl acrylate units, crosslinked copolymers consisting of acrylic acid units and C1-C4- Alkyl me
  • the at least one polymer containing (meth) acrylic acid, (meth) acrylic ester, (meth) acrylamide and / or 2-acrylamido-2-methylpropanesulfonic acid monomers, no monomers, with optionally ethoxylated, C6 C24-alkyl or C6-C24 alkenyl Groups are substituted.
  • a further subject of the present invention is a hair and skin treatment kit comprising:
  • At least one hair treatment compartment containing hair treatment agents for dyeing and / or permanent remodeling of hair
  • the skin protection compartment comprising compositions (D) and (C):
  • kits have the advantage that the essential ingredients of the compositions (C) and (D) in a space and packaging-saving manner, for Example in sachets, which preferably have a water vapor-impermeable layer, can be commercialized.
  • the hairdresser can prepare the compositions (C) and (D) themselves by simply mixing with the compositions (C) and (D 1 ) with water and optionally an oily hair care composition.
  • the kit also includes an instruction for the implementation of skin protection methods according to the invention and preferred according to the invention.
  • a further subject matter of the present invention is the use of at least one polysaccharide salt selected from calcium alginate, potassium kappa carrageenate, calcium kappa carrageenate, calcium iota carrageenate, calcium pectinate, aluminum alginate, aluminum kappa carrageenate, aluminum iota Carragheenate, aluminum pectinate, strontium alginate, strontium kappa carrageenate, strontium iota carrageenate, strontium pectinate, barium alginate, barium kappa carrageenanate, barium iota carrageenate, barium pectinate, and mixtures of these polysaccharide salts, for coating keratin fibers in a permanent process Forming, in particular for smoothing or perming, keratinic fibers, wherein the forming process is preferably a method according to any one of claims 1-7 or 9.

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Abstract

La présente invention concerne un kit de traitement capillaire qui comprend au moins un produit de traitement capillaire et au moins un agent destiné à protéger la peau du contact avec le produit de traitement capillaire, ledit produit de traitement capillaire étant choisi parmi les produits de mise en forme permanente, en particulier de lissage ou d'ondulation permanente, et les produits de coloration de fibres kératiniques.
EP16804805.6A 2015-12-21 2016-12-01 Kit de traitement capillaire comprenant un agent de protection de la peau Withdrawn EP3393448A1 (fr)

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DE102015226167.0A DE102015226167A1 (de) 2015-12-21 2015-12-21 Haarbehandlungs-Kit mit Hautschutzmittel
PCT/EP2016/079384 WO2017108365A1 (fr) 2015-12-21 2016-12-01 Kit de traitement capillaire comprenant un agent de protection de la peau

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US12039732B2 (en) 2021-04-14 2024-07-16 The Procter & Gamble Company Digital imaging and learning systems and methods for analyzing pixel data of a scalp region of a users scalp to generate one or more user-specific scalp classifications

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE442705B (sv) * 1979-05-08 1986-01-27 Viktor Kare Larsson Medel for bildande av ett skyddsskikt pa ett underlag i form av hud eller slemhinna samt forfarande for att bilda ett skyddsskikt pa huden i icke-terapeutiskt syfte med hjelp av detta medel
DE3534287A1 (de) * 1985-09-26 1987-04-02 Wella Ag Verfahren zum schutz der kopfhaut vor der einwirkung alkalischer haarbehandlungsmittel
IT1248666B (it) * 1990-05-30 1995-01-26 Fidia Spa Gel in forma di film autosupportanti altamente idrati, processo per laloro preparazione e impiego nella terapia di lesioni e/o patologie cutanee
DE19756454C1 (de) 1997-12-18 1999-06-17 Henkel Kgaa Verwendung von Glycerincarbonat
FR2779638B1 (fr) * 1998-06-15 2000-08-04 Oreal Composition cosmetique contenant un polysaccharide et un terpolymere acrylique et utilisation de cette composition pour le traitement des matieres keratiniques
US20050087718A1 (en) * 2002-02-21 2005-04-28 Toru Okada Treating agent for protecting animal fiber
CN100366261C (zh) * 2002-12-10 2008-02-06 田中雅也 皮肤外用材料及使用其的外用止痒剂和去皱用品
JP2004300065A (ja) * 2003-03-31 2004-10-28 Okada Giken:Kk 皮膚保護剤
FR2904767A1 (fr) * 2006-08-10 2008-02-15 Oreal Composition comprenant un agent oxydant et un polymere acrylamide / halogenure de dialkyldiallylammonium / acide carboxylique vinylique a fort taux d'acide carboxylique vinylique
DE102006061829A1 (de) * 2006-12-21 2008-06-26 Henkel Kgaa Vorbehandlungsmittel zum Schutz der Kopfhaut
WO2010132857A1 (fr) * 2009-05-14 2010-11-18 Central Michigan University Composition et procédé de préparation d'échafaudages de peau artificielle biodégradable à base de gel polysaccharidique

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WO2017108365A1 (fr) 2017-06-29

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