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EP3378502A1 - Utilisation de carbonate de calcium précipité traité par du zinc dans des produits hygiéniques - Google Patents

Utilisation de carbonate de calcium précipité traité par du zinc dans des produits hygiéniques Download PDF

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Publication number
EP3378502A1
EP3378502A1 EP17162567.6A EP17162567A EP3378502A1 EP 3378502 A1 EP3378502 A1 EP 3378502A1 EP 17162567 A EP17162567 A EP 17162567A EP 3378502 A1 EP3378502 A1 EP 3378502A1
Authority
EP
European Patent Office
Prior art keywords
zinc
calcium carbonate
precipitated calcium
group
treated precipitated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP17162567.6A
Other languages
German (de)
English (en)
Inventor
Steffen Ohr
Christopher SCHRUL
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Omya International AG
Original Assignee
Omya International AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Omya International AG filed Critical Omya International AG
Priority to EP17162567.6A priority Critical patent/EP3378502A1/fr
Priority to KR1020197029893A priority patent/KR20190127819A/ko
Priority to PCT/EP2018/055784 priority patent/WO2018172096A1/fr
Priority to JP2019552134A priority patent/JP2020513984A/ja
Priority to MX2019011347A priority patent/MX2019011347A/es
Priority to AU2018240768A priority patent/AU2018240768A1/en
Priority to ES18709015T priority patent/ES2877805T3/es
Priority to US16/488,910 priority patent/US20200046869A1/en
Priority to BR112019019861A priority patent/BR112019019861A2/pt
Priority to CA3054000A priority patent/CA3054000A1/fr
Priority to EP18709015.4A priority patent/EP3600460B1/fr
Priority to RU2019133471A priority patent/RU2759668C2/ru
Priority to CN201880020430.6A priority patent/CN110446507B/zh
Priority to ARP180100700A priority patent/AR111141A1/es
Publication of EP3378502A1 publication Critical patent/EP3378502A1/fr
Priority to IL26879819A priority patent/IL268798A/en
Withdrawn legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/18—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing inorganic materials
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads
    • A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
    • A61F13/51113—Topsheet, i.e. the permeable cover or layer facing the skin comprising an additive, e.g. lotion or odour control
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads
    • A61F13/514—Backsheet, i.e. the impermeable cover or layer furthest from the skin
    • A61F13/51401—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material
    • A61F13/51405—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material treated or coated, e.g. with moisture repellent agent
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27—Zinc; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42—Use of materials characterised by their function or physical properties
    • A61L15/46—Deodorants or malodour counteractants, e.g. to inhibit the formation of ammonia or bacteria
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00—Compounds of calcium, strontium, or barium
    • C01F11/18—Carbonates
    • C01F11/181—Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by control of the carbonation conditions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00—Compounds of calcium, strontium, or barium
    • C01F11/18—Carbonates
    • C01F11/185—After-treatment, e.g. grinding, purification, conversion of crystal morphology
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads
    • A61F2013/51059—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads being sprayed with chemicals
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads
    • A61F2013/51059—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads being sprayed with chemicals
    • A61F2013/51076—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads being sprayed with chemicals with perfumes or odour-masking agents
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2300/00—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
    • A61L2300/10—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices containing or releasing inorganic materials
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2300/00—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
    • A61L2300/10—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices containing or releasing inorganic materials
    • A61L2300/102—Metals or metal compounds, e.g. salts such as bicarbonates, carbonates, oxides, zeolites, silicates

Definitions

  • the present invention relates to the use of zinc treated precipitated calcium carbonate (PCC) in hygienic products, as well as to the hygienic products comprising this zinc treated precipitated calcium carbonate.
  • PCC zinc treated precipitated calcium carbonate
  • Hygienic products such as diapers, feminine hygiene products, incontinence products, etc. are valuable means for protecting the persons in need of such products from body liquids the release of which for various reasons cannot be controlled.
  • Modem disposable baby diapers and incontinence products have a layered construction, which allows the transfer and distribution of urine to an absorbent core structure where it is locked in.
  • Basic layers may be an outer shell of breathable film or a nonwoven and film composite which prevents wetness and soil transfer, an inner absorbent layer of a mixture of air-laid paper and superabsorbent polymers for wetness, and a layer nearest the skin of nonwoven material with a distribution layer directly beneath which transfers wetness to the absorbent layer.
  • Irritant diaper dermatitis develops when skin is exposed to prolonged wetness, increased skin pH caused by urine and faeces, and resulting breakdown of the stratum corneum, or outermost layer of the skin. This may be due to diarrhea, frequent stools, tight diapers, overexposure to ammonia, or allergic reactions. Thus, skin irritations may not only occur when diapers are used, but, generally with any hygienic product.
  • the most effective treatment is to discontinue use of the hygienic product, allowing the affected skin to air out.
  • Thorough drying the skin before contacting it with the hygienic product is a good preventive measure, because it is the excess moisture, VT either from urine and faeces or from sweating or other body liquids, that sets the conditions for a dermatitis to occur.
  • Various moisture-absorbing powders such as talcum or starch, reduce moisture but may introduce other complications.
  • Airborne powders of any sort can irritate lung tissue, and powders made from starchy plants (corn, arrowroot) provide food for fungi and are not recommended.
  • zinc oxide-based ointments are quite effective, especially in prevention, because they have both a drying and an astringent effect on the skin, being mildly antiseptic without causing irritation.
  • certain zinc treated mineral material especially zinc treated precipitated calcium carbonate, may advantageously be used in hygienic products and thus provide an effective means of preventing skin irritations directly by their incorporation into the hygienic product, and thus avoid any one of the above described disadvantages of the prior art.
  • the present invention relates to the use of zinc treated precipitated calcium carbonate (PCC) in hygienic products, wherein the zinc treated precipitated calcium carbonate is obtained by
  • Precipitated calcium carbonate in general is a synthesized material, obtained by precipitation following a reaction of carbon dioxide and calcium hydroxide (hydrated lime) in an aqueous environment or by precipitation of a calcium- and a carbonate source in water. Additionally, precipitated calcium carbonate can also be the product of introducing calcium- and carbonate salts, calcium chloride and sodium carbonate for example, in an aqueous environment.
  • PCC may have a vateritic, calcitic or aragonitic crystalline form. PCCs are described, for example, in EP 2 447 213 A1 , EP 2 524 898 A1 , EP 2 371 766 A1 , EP 2 840 065 A1 , or WO 2013/142473 A1 .
  • the calcium hydroxide slurry may be screened to remove any residual impurities and/or non-reactive unburnt lime, and then carbonated by reacting the calcium hydroxide with carbon dioxide or soluble carbonates.
  • calcium oxide in a first step, may be slaked with water as usual according to methods well-known in the art.
  • the calcium oxide used according to the present invention may be any commercially available product, or may be obtained by calcining calcium compounds, especially calcium carbonate. Calcination is a thermal treatment process, especially applied to calcium carbonate containing materials in order to bring about a thermal decomposition resulting in the formation of calcium oxide and gaseous carbon dioxide.
  • Calcium carbonate comprising material which may be used for calcination may be any calcium carbonate comprising materials such as those selected from the group comprising precipitated calcium carbonates or natural calcium carbonate containing minerals such as marble, limestone and chalk.
  • calcination step may be carried out under conditions and using equipment well-known to the person skilled in the art. Generally, calcination may be carried out in furnaces or reactors (sometimes referred to as kilns) of various designs including shaft furnaces, rotary kilns, multiple hearth furnaces, and fluidized bed reactors.
  • the end of the calcination reaction may be determined, e.g. by monitoring the density change, the residual carbonate content, e.g. by x-ray diffraction, or the slaking reactivity by common methods.
  • the slaking step i.e. the combination of calcium oxide with water to obtain calcium hydroxide, may, in principle, be carried out according to known methods, as well.
  • the calcium oxide may be added to the water in a weight ratio of CaO : water of between 1 : 3 and 1 : 20, preferably between 1 : 5 and 1 : 12, most preferably between 1 : 7 and 1 : 10.
  • the progress of the reaction may be observed by measuring the conductivity of the reaction mixture, which initially quickly decreases and reaches an essentially constant level as soon as the reaction is completed. As well, it may be monitored by temperature and turbidity control.
  • the obtained calcium hydroxide slurry may be screened, e.g. on a 100 ⁇ m screen as appropriate, to remove any residual impurities and/or non-reactive unburnt lime.
  • the carbonation step is carried out in the presence of at least one Zn 2+ ion provider.
  • the Zn 2+ ion provider preferably is a water soluble compound, wherein, for the purpose of the present application, "water-soluble" compounds are defined as materials which, when 100 g of said material is mixed with 100 g deionised water and filtered on a filter having a 0.2 ⁇ m pore size at 20 °C to recover the liquid filtrate, provide more than 0.1 g of recovered solid material following evaporation at 95 to 100 °C of 100 g of said liquid filtrate at ambient pressure.
  • the Zn 2+ ion provider may be selected from the group comprising zinc sulphate; zinc halides such as zinc chloride, zinc bromide, zinc iodide; zinc nitrate; zinc phosphates, e.g. Zn 3 (PO 4 ) 2 , ZnHPO 4 ; zinc carbonates, e.g. ZnCO 3 , Zn(HCO 3 ) 2 ; zinc oxide; zinc hydroxide; hydrates and mixtures thereof.
  • zinc sulphate heptahydrate ZnSO 4 ⁇ 7 H 2 O.
  • the Zn 2+ ion provider is added in an amount of from 0.1 to 30 wt%, preferably of from 2 to 25 wt%, more preferably of from 5 to 20 wt%, most preferably of from 10 to 15 wt%, e.g. 11.5 wt% based on the dry weight of calcium oxide.
  • the Zn 2+ ion provider is added in combination with one or more Group I and/or Group II and/or Group III metal sulphates, which are preferably selected from the group comprising sodium sulphate, calcium sulphate, magnesium sulphate, aluminium sulphate; hydrates and mixtures thereof. Especially preferred is a combination with magnesium sulphate heptahydrate (MgSO 4 ⁇ 7 H 2 O).
  • the one or more Group I and/or Group II and/or Group III metal sulphates advantageously are added in an amount of from 0.1 to 30 wt%, preferably of from 1 to 25 wt%, more preferably of from 2 to 15 wt%, most preferably of from 4 to 8 wt%, e.g. 6 wt% based on the dry weight of calcium oxide.
  • the Zn 2+ ion provider and/or the Group I and/or Group II and/or Group III metal sulphates, independently from each other may be added before and/or during the carbonation.
  • the Zn 2+ ion provider and/or the Group I and/or Group II and/or Group III metal sulphates are added after the slaking step.
  • the Zn 2+ ion provider especially zinc sulphate
  • the Group I and/or Group II and/or Group III metal sulphate especially magnesium sulphate
  • one or more acids may be added before and/or during the carbonation step, e.g. sulphuric acid.
  • the carbonation of the calcium hydroxide suspension may be carried out by feeding pure gaseous carbon dioxide or technical gases containing at least 10 vol.% of carbon dioxide into the alkaline calcium chloride solution.
  • any technical flue gases provided that they do not contain any components causing undesired side reaction, or introducing impurities in the process of the present invention.
  • the carbonation is carried out by means and under conditions and equipment well-known by the person skilled in the art.
  • the carbonation is conducted at a carbonation gas flow rate of below 30 litres per minute, preferably at a rate of from 1 to 30, more preferably of from 10 to 20, most preferably about 20 litres per minute, and/or preferably at a temperature of from 10 to 70 °C, more preferably 15 to 50 °C, and most preferably 20 to 30 °C during precipitation.
  • the progress of the carbonation reaction can be readily observed by measuring the conductivity density, turbidity and/or pH.
  • the pH of the calcium hydroxide suspension before addition of carbon dioxide will be more than 10 and will constantly decrease until a pH of below 8 is reached. At this point the reaction can be stopped.
  • the temperature in the carbonation tank is observed to rise up to between 40 and 80 °C, preferably up to between 50 and 60 °C, most preferably up to between 56 and 57 °C.
  • the final slurry product consists of a slurry of zinc treated precipitated calcium carbonate and may have a solids content of 1 to 30 wt%, preferably 5 to 25 wt%, more preferably 10 to 20 wt%, most preferably 15 to 18 wt%.
  • the zinc treated precipitated calcium carbonate is in the form of agglomerates and/or aggregates.
  • Agglomerates in the meaning of the present invention are accumulations of weakly bound particles or aggregates or mixtures thereof, the resulting surface of which is comparable to the sum of the surfaces of the respective components. Agglomerates are held together by weak forces, e.g. van-der-Waals forces or ordinary physical catching. Agglomerates are also designated as secondary particles, the original particles as primary particles (cf. e.g. DIN SPEC 1121 (DIN ISO/TS 27687), Deutsches Institut für Normung e.V.).
  • Aggregates in the meaning of the present invention are strongly bound or fused particles, the resulting surface of which may be significantly smaller than the sum of the calculated surfaces of the respective components. Aggregates are held together by strong forces, such as covalent forces or forces based on sintering or complex physical catching. Also aggregates are designated as secondary particles. (cf. e.g. DIN SPEC 1121 (DIN ISO/TS 27687), Deutsches Institut für Normung e.V.).
  • the slurry of zinc treated precipitated calcium carbonate may be concentrated by means of pressurized filters, centrifuges, vacuum filtration, thermal evaporation, optionally in the presence of cationic and/or anionic dispersants, preferably until a solids content of from 15 to 60 wt%, more preferably of from 20 to 55 wt%, especially preferably of from 25 to 50 wt%, most preferably of from 30 to 45 wt%, e.g. 35 to 40 wt% is obtained, or until dryness.
  • Dispersants which may be advantageously used are those well-known in the art, and preferably are selected from the group comprising sodium, potassium, calcium, magnesium, lithium, strontium, primary amine, secondary amine, tertiary amine and/or ammonium salts, whereby the amine salts are linear or cyclic, of at least partly neutralized homopolymers or copolymers of (meth)acrylic acid, maleic acid, fumaric acid, itaconic acid and derivatives of these acids, preferably esters or amides such as methyl methacrylate, methyl acrylate, acrylamide, sodium hydrogen phosphate or polyphosphates such as alkalipolyphosphates, carboxymethylcellulose, steric dispersants, comb polymers, and/or mixtures thereof, preferably sodium polyacrylate having a molecular weight M w of from
  • dispersants in an amount of from 0.001 to 10 wt%, preferably from 0.1 to 7 wt%, more preferably from 0.5 to 6 wt%, especially from 1 to 5 wt%, e.g. from 3 to 4 wt% may be added based on the dry weight of calcium carbonate.
  • approximately 5 to 10 wt% of a 40 wt% solution of a sodium salt of polyacrylic acid relative to dry calcium carbonate may be added to the slurry or filter cake containing the zinc treated precipitated calcium carbonate of the invention, corresponding to approximately 2 to 4 wt% dry polyacrylic acid salt on dry calcium carbonate.
  • the slurry Before concentrating the slurry, it may be screened, e.g. on a 45 ⁇ m screen, in order to remove coarse residual impurities and/or non-reactive unburnt lime, when the Brookfield viscosity of the material exiting from the carbonation tank is sufficiently low, namely less than 100 mPa ⁇ s at 100 rpm.
  • the concentrated slurry may be washed and, subsequently, re-dispersed, optionally in the presence of one or more dispersants as mentioned above, such as alkali salts of polyacrylic acid, carboxy methyl cellulose, mixtures of carboxy methyl cellulose with sodium citrate, etc.
  • one or more dispersants such as alkali salts of polyacrylic acid, carboxy methyl cellulose, mixtures of carboxy methyl cellulose with sodium citrate, etc.
  • the precipitated calcium carbonate may have aragonitic, calcitic, or vateritic crystal structure, or mixtures thereof, wherein the crystal structure and morphology of the precipitated calcium carbonate can optionally be controlled, e.g. by addition of seed crystals or other structure modifying chemicals.
  • Aggregates / agglomerates of zinc treated precipitated calcium carbonate used according to the present invention may have a volume median aggregate / agglomerate diameter d 50 (vol) of from 0.1 to 10 ⁇ m, more preferably 0.25 to 8 ⁇ m, most preferably 0.5 to 7 ⁇ m, especially 1 to 6 ⁇ m, e.g. 4 to 5.5 ⁇ m.
  • the primary acicular particle size preferably is in the nanometer range, and may be from 1 to 100 nm, preferably from 10 to 80 nm, more preferably from 20 to 50 nm.
  • the BET specific surface area of the aggregates / agglomerates of zinc treated precipitated calcium carbonate according to the present invention may be from 1 to 100 m 2 /g, preferably from 20 to 85 m 2 /g, more preferably from 40 to 80 m 2 /g, especially from 60 to 75 m 2 /g, e.g. 70 m 2 /g, measured using nitrogen and the BET method according to ISO 9277.
  • the zinc treated precipitated calcium carbonate may be used in the form of a slurry, a filter cake or dry as described above, or in the form of a formulation suitable for such applications, especially an aqueous formulation, preferably selected from the group comprising coating formulations, spray coating formulations, lotions, and printing ink formulations.
  • the zinc treated precipitated calcium carbonate advantageously is provided dry, in the form of a filter cake, or in the form of an aqueous slurry.
  • the final formulation may have a solids content of from 15 to 70 wt%, preferably 20 to 60 wt%, more preferably 30 to 40 wt%, e.g. 32 wt%, and/or a viscosity of from 50 to 3000 mPa ⁇ s, preferably from 100 to 2000 mPa ⁇ s, more preferably from 200 to 1000 mPa ⁇ s, especially preferably from 300 to 700 mPa ⁇ s, most preferably from 400 to 600 mPa ⁇ s, e.g. 460 mPa ⁇ s.
  • a corresponding formulation may comprise further components, preferably selected from the group comprising dispersing agents, binding agents, biocides, defoamers, oils, pigments, coalescing agents, wetting agents, neutralizing agents, emulsifiers, solvents, colorants, and mixtures thereof.
  • the zinc treated precipitated calcium carbonate may be applied to hygienic products in the form of a slurry, dry, or in the form of a formulation.
  • Such products may be selected from ab/adsorbent products such as diapers, training panties, swim pants, feminine hygiene products such as pads, panty liners, sanitary napkins, incontinence products; deodorant formulations; nonwoven products such as wipes.
  • ab/adsorbent products such as diapers, training panties, swim pants, feminine hygiene products such as pads, panty liners, sanitary napkins, incontinence products; deodorant formulations; nonwoven products such as wipes.
  • the zinc treated precipitated calcium carbonate in the form of a slurry, dry or in the form of a formulation is applied to an ab/adsorbent product comprising one or several layers selected from the group comprising a top sheet layer, one or more acquisition/distribution layer(s) (ADLs), a tissue wrap layer, an ab/adsorbent core and a back sheet layer.
  • ADLs acquisition/distribution layer(s)
  • the zinc treated precipitated calcium carbonate in the form of a slurry, dry or in the form of a formulation may be applied to one or several of the layers of the ab/adsorbent product, selected from the group comprising a top sheet layer, one or more acquisition/distribution layer(s) (ADLs), a tissue wrap layer, an ab/adsorbent core and a back sheet layer.
  • ADLs acquisition/distribution layer(s)
  • tissue wrap layer an ab/adsorbent core and a back sheet layer.
  • the application of the zinc treated precipitated calcium carbonate may be carried out by any well-known means being suitable therefor such as spray coating, roller coating, blade coating, curtain coating, etc.
  • the amount of the zinc treated precipitated calcium carbonate will depend on the respective formulation. It may be preferred that the zinc treated precipitated calcium carbonate is applied to provide a dry coating weight of 0.05 to 15 mg/cm 2 , preferably 0.1 to 10 mg/cm 2 , more preferably 0.2 to 5 mg/cm 2 , most preferably 0.5 to 4 mg/cm 2 , e.g. 1 to 2 mg/cm 2 .
  • the zinc treated precipitated calcium carbonate in the form of a spray coating formulation.
  • a corresponding spray coating formulation preferably is an aqueous spray coating formulation and may comprise binders, such as carboxymethyl cellulose binders available under the tradename Finnfix ® CMC 5 from CPKelco.
  • such binders preferably are used in an amount of from 1 to 30 wt%, preferably from 5 to 25 wt%, more preferably from 7.5 to 20 wt%, especially from 10 to 15 wt%, e.g. 12 wt% based on the weight of dry calcium carbonate.
  • An especially suitable spray coating formulation has a solids content of from 25 to 35 wt%, e.g. 31 to 32 wt%, and/or a Brookfield viscosity (100 rpm, Spindle 4) of from 300 to 500 mPa ⁇ s, e.g. 300 to 460 mPa ⁇ s.
  • spray nozzles geometries can be used e.g. full cone nozzle, hollow cone nozzle, fan nozzle, nozzle providing a full beam or systems working with air atomization (e.g. available from BETE Deutschland GmbH, Lechler GmbH, DIVA-Sprühtechnik GmbH), preferably nozzles using the dual beam technology (available e.g. from FMP TECHNOLOGY GMBH).
  • the hygienic products comprising zinc treated precipitated calcium carbonate as described above are a further aspect of the present invention.
  • Such hygienic products preferably are selected from the group comprising ab/adsorbent products such as diapers, training panties, swim pants, feminine hygiene products such as pads, panty liners, sanitary napkins, incontinence products; deodorant formulations; nonwoven products such as wipes.
  • ab/adsorbent products such as diapers, training panties, swim pants, feminine hygiene products such as pads, panty liners, sanitary napkins, incontinence products; deodorant formulations; nonwoven products such as wipes.
  • Hygienic products such as ab/adsorbent products, e.g. diapers may comprise one or several layers selected from the group comprising a top sheet layer, one or more acquisition/distribution layer(s) (ADLs), a tissue wrap layer, an ab/adsorbent core and a back sheet layer, wherein the zinc treated precipitated calcium carbonate as defined above may be applied to at least one of said layers.
  • ADLs acquisition/distribution layer(s)
  • tissue wrap layer e.g. tissue wrap layer
  • ab/adsorbent core e.g. diapers
  • the zinc treated precipitated calcium carbonate as defined above may be applied to at least one of said layers.
  • a further aspect of the present invention accordingly is a process for the preparation of corresponding hygienic products, wherein the zinc treated precipitated calcium carbonate may be applied to the hygienic products in the form of a slurry, dry, or in the form of a formulation.
  • the zinc treated precipitated calcium carbonate is applied by spray coating or printing, e.g. flexographic printing, on one or several of the above-mentioned layers of a diaper or any other ad/absorbent product.
  • the BET specific surface area was measured via the BET process according to ISO 9277 using nitrogen, following conditioning of the sample by heating at 250 °C for a period of 30 minutes. Prior to such measurements, the sample was filtered, rinsed and dried at 110 °C in an oven for at least 12 hours.
  • Particle / Aggregate / Agglomerate size distribution (volume % particles / aggregates / agglomerates with a diameter ⁇ X ), d 50 value (volume median particle / aggregate / agglomerate diameter) and d 98 value of a particulate material:
  • the suspension solids content (also known as "dry weight”) was determined using a Moisture Analyser MJ33 from the company Mettler-Toledo, Switzerland, with the following settings: drying temperature of 160 °C, automatic switch off, if the mass does not change more than 1 mg over a period of 30 seconds, standard drying of 5 to 20 g of suspension.
  • the pH of a suspension or solution was measured at 25 °C using a Mettler Toledo Seven Easy pH meter and a Mettler Toledo InLab® Expert Pro pH electrode.
  • a three-point calibration (according to the segment method) of the instrument was first made using commercially available buffer solutions having pH values of 4, 7 and 10 at 20 °C (from Sigma-Aldrich Corp., USA).
  • the reported pH values are the endpoint values detected by the instrument (the endpoint was when the measured signal differed by less than 0.1 mV from the average over the last 6 seconds).
  • viscosity or “Brookfield viscosity” refers to Brookfield viscosity.
  • the Brookfield viscosity is for this purpose measured by a Brookfield DV-III Ultra viscometer at 24°C ⁇ 3°C at 100 rpm using an appropriate spindle of the Brookfield RV-spindle set and is specified in mPa ⁇ s. Once the spindle has been inserted into the sample, the measurement is started with a constant rotating speed of 100 rpm. The reported Brookfield viscosity values are the values displayed 60 seconds after the start of the measurement.
  • a spindle from the Brookfield RV-spindle set which is suitable for the viscosity range to be measured. For example, for a viscosity range between 200 and 800 mPa ⁇ s spindle number 3 may be used, for a viscosity range between 400 and 1600 mPa ⁇ s spindle number 4 may be used, for a viscosity range between 800 and 3200 mPa ⁇ s spindle number 5 may be used, for a viscosity range between 1000 and 2000000 mPa ⁇ s spindle number 6 may be used, and for a viscosity range between 4000 and 8000000 mPa ⁇ s spindle number 7 may be used.
  • Scanning electron micrographs were carried out by diluting 150 ⁇ l sample slurry with 20 ml deionized water, filtering through a 0.8 ⁇ m filter, and air drying the filter residue.
  • a sample carrier provided with carbon based, electrically conductive, double sided adhesive discs is pressed onto the filter, and, subsequently, sputtered with gold (8 nm) and evaluated in the SEM at various enlargements.
  • Zinc treated precipitated calcium carbonate Zn-PCC
  • the calcium carbonate precipitation was carried out in a 1000 litre baffled cylindrical stainless steel reactor equipped with a gassing agitator having a gas dispersion unit, a stainless steel carbonation tube to direct a carbon dioxide/air gas stream to the impeller, and probes for monitoring the pH and conductivity of the suspension.
  • the agitator was then adjusted to 1480 rpm, and the slurry was carbonated by passing a gas mixture of 26 vol.% carbon dioxide in air at 118 Nm 3 /h, corresponding to 19.7 litres per minute at standard temperature (0 °C) and pressure (1000 mbar) per kilogram of calcium hydroxide, through the slurry.
  • the slurry was then screened on a 45 ⁇ m screen before being fed to a dewatering centrifuge (operating at 4440 rpm) at a rate of 350 l/h providing a filter cake having a solids content of 42 wt%.
  • This filter cake was collected and then redispersed with 2.5 wt% (active/dry) of a 100 % sodium neutralized polyacrylate dispersing agent (Mw ⁇ 12000 g/mol; polydispersity index ⁇ 3) in a mixing unit and the concentrated product was recovered as an aqueous slurry of the pigment.
  • the product of the carbonation and concentration step as stated above was an aqueous suspension of 38 wt% solids content of ultrafine primary calcium carbonate particles bound together to form aggregates / agglomerates.
  • the crystalline structure of the product was determined by SEM pictures and is exemplified by Figure 1 .
  • a spray coating formulation was prepared by adding a carboxymethyl cellulose binder available under the tradename Finnfix ® CMC 5 from CP Kelco in a high shear mixer (Disperlux Pendraulik lab dissolver) for 15 minutes without temperature regulation, and 3000 rpm with a dispersion disc with a diameter of 60 mm, which, before its addition to the zinc treated precipitated calcium carbonate suspension, has been stirred with a paddle stirrer at a temperature of 90 °C in tap water at a solids content of 15 to 20 wt% for 20 to 30 min.
  • Finnfix ® CMC 5 from CP Kelco
  • a high shear mixer Disperlux Pendraulik lab dissolver
  • Table 1 Formulation Composition Zn treated PCC [dry wt%] 25.5 Finnfix ® CMC 5 [dry wt%] 4.7 Dispersing agent [dry wt%] 1.3 Water [wt%] 68.5 Particle Size Distribution of the Zn-PCC in the formulation d 50 (vol) [ ⁇ m] 5.0 BET Specific Surface Area of the Zn - PCC in the formulation [m 2 /g] 70 Fluid characteristics of the formulation Solids Content [wt%] 31.6 pH 9.6 Brookfield Viscosity 100 rpm, Spindle 4 [mPa ⁇ s] 460
  • the dual beam technology was applied in order to generally test the sprayability of the coating formulations, which showed excellent atomization behaviour. Based on these results, the formulation was applied to diapers.
  • the formulations can be sprayed on any defined substrate using state of the art spray technology.
  • the formulation was transferred into a stainless steel vessel with a capacity of 1000 ml.
  • the vessel can be pressurized with compressed air to a maximum pressure of 30 bar.
  • the fluid was transported to a standard spraying valve (suppliers are for example: JERKEL or NORDSON or WALTHER).
  • a WALTHER Pilot valve was used.
  • an electrical control unit was used giving a signal to the valve and allowing the valve to open for a defined period of time.
  • Manual triggering was realized by an electrical control unit (1) (24V, max 4.2 amps), linked with a timer (2) (Panasonic LT4H).
  • the timer was set to 94 ms.
  • the control unit gives electrical impulse to a magnet switch (3), which opens the 6 mm pipe connected to the compressed air line (4) with 6 bar pressure.
  • the magnetic switch was connected (4) to the valve (9), which by triggering the control unit, opened the valve for 34 ms and released the fluid (8) coming from the pressurized vessel (7).
  • the vessel was pressurised by a bottle with compressed air at 250 bar (5) connected to a pressure reducer (6) to allow a reduction of the pressure vessel below 30 bar.
  • a nozzle (10) delivered by FMP TECHNOLOGY GMBH was used having two holes drilled in an angle (20 °) to each other, allowing the mass flow defined by the pressure of the vessel and the defined opening time of the valve to be separated in two beams, the two beams collide outside of the nozzle and atomize or spread the fluid.
  • the advantage of this nozzle is, that no additional pressurized air is needed to atomize or spread the fluid.
  • the nonwoven substrate (11) (a l ow bonded, hydrophilic polypropylene nonwoven having a weight of 14 g/m 2 was coated by fixing it on a substrate carrier and placing it on a conveyor belt. The conveyor belt was set to a speed of 100 m/min. The substrate on the substrate carrier was subsequently transported and passed the valve/nozzle. To coat the substrate on the substrate carrier, the opening signal from the electrical control unit to the valve was manually triggered by a rocker switch when the substrate passed the valve underneath.
  • nozzles two nozzle sizes were tested, 500 ⁇ m and 650 ⁇ m, and for both nozzles, the atomization was found to be excellent.
  • the mass output i.e. the wet coat weight per piece, was controlled by varying the pressure of the vessel mass outputs at the given parameters such as nozzle opening time given above.
  • the spray coating of the coating formulation was carried out using two nozzle sizes and different pressure settings of the vessel. After the trials, the dry coat weight was determined by drying the coated material stored in the lab under ambient temperature (22 °C) and humidity (ca. 45 %) for 20 h and determining its weight. The difference between the dried coated nonwoven sheet and the dried uncoated nonwoven sheet corresponds to the dry coat weight.
  • Table 3 Trial Vessel Pressure [bar] Nozzle Diameter [ ⁇ m] Coat Weight (dry) [mg] V1 24 650 404 V2 19 650 274 V3 15 650 204 V4 15 500 134 V5 12 500 124 V6 9 500 74
  • the target dry coat weight could be realized within the trial (V2 to V6).
  • the microbial contamination (bacterial and fungi growth) of three different zinc containing powder samples was determined by the plate count method (spread count) according to the following procedure:
  • This buffer was used to detach the bacterial cells from the zinc containing powder particles.
  • Tris tris(hydroxymethyl)aminomethane
  • the sample to be analyzed was appropriately diluted and a defined volume no greater than 0.1 ml was spread over the surface of an agar plate using a sterile glass / plastic spreader.
  • the agar plates were then incubated upside down (condensed water) for a defined period of time at a defined temperature.
  • the sample to be analyzed was diluted 1:10 in PBS and 100 ⁇ l of the dilution was spread onto the TSA plate which was incubated for 48 hours at 30 °C.
  • the sample to be analyzed was diluted 1:10 in PBS and 100 ⁇ l of the dilution were spread onto the plate which was incubated for 7 days at 25 °C.
  • the plates were evaluated by counting the grown colonies, thereby taking into account that only plates containing between 30 - 300 colonies have a high statistical significance.
  • Table 5 Determination of aerobe bacterial and fungal growth.
  • TVC [cfu/g] Sample Aerobe 1) Fungi 2) ZnCaCO 3 ⁇ 100 ⁇ 10 ZnO ⁇ 100 ⁇ 10 Zn-PCC ⁇ 100 ⁇ 10 1)
  • TSA Tryptic Soy Agar for the determination of bacterial growth. 2) SDC for the determination of fungal growth. 1ml was plated to lower the detection limit.
  • a spray coating formulation was prepared by adding a carboxymethyl cellulose binder available under the tradename Finnfix ® CMC 5 from CP Kelco in a high shear mixer (Disperlux Pendraulik lab dissolver) for 15 minutes without temperature regulation, and 3000 rpm with a dispersion disc with a diameter of 60 mm, which, before its addition to the zinc treated precipitated calcium carbonate suspension, has been stirred with a paddle stirrer at a temperature of 90 °C in tap water at a solids content of 15 to 20 wt% for 20 to 30 min.
  • Finnfix ® CMC 5 from CP Kelco
  • a high shear mixer Disperlux Pendraulik lab dissolver
  • compositions and characteristics of the resulting coating formulation are summarized below: Table 6: Formulation Composition Zn treated PCC [dry wt%] 27.4 Finnfix ® CMC 5 [dry wt%] 4.1 Water [wt%] 68.5 Fluid characteristics of the formulation Solids Content [wt%] 31.5 pH 10 Brookfield Viscosity 100 rpm, Spindle 4 [mPa ⁇ s] 600 Temperature 19 °C
  • the trial was realized on a conventional industrial diaper line.
  • the spray coating equipment (valve carrier, valve, nozzle and connectors) was provided by FMP TECHNOLOGY GMBH as described above (cf. also Fig. 2 ).
  • Two nozzle sizes were chosen for the trial to transfer an adequate fluid amount onto the top sheet: 200 ⁇ m and 500 ⁇ m.
  • the diaper to be coated was a standard baby diaper maxi size 4 as illustrated in Fig. 3 .
  • the goal was to apply the spray coating formulation on the polypropylene top sheet.
  • the spray coating equipment was positioned in a section of the diaper line where the top sheet was already merged with the ADL (acquisition/distribution layer), absorbent core (fluff pulp and super-absorber layer) and the back sheet layer to allow the coating application onto the top sheet.
  • Trial points V7 to V10 were run in this setup. During the trial, the application was slightly changed and adjusted to another position where the backside of the nonwoven top sheet could be coated.
  • Trial point V11 was conducted in this setup. A dryer was not installed due to the limited space within the machine.
  • the rewet test is designed to show the intrinsic ability of the absorbent core of a diaper to prevent fluids from resurfacing.
  • the absorption time describes the time a diaper needs to distribute and absorb a defined quantity of a urine substitute applied on a defined area on the top sheet.
  • the baby diaper is mounted flat onto a foam support on the examination table in order to ensure a planar surface during measurement.
  • the micturition point of the urine substitute is situated 2.5 cm ahead of the middle of the absorbent core.
  • the pH value on the diaper top sheet was determined by applying a defined quantity of a urine substitute and bringing a pH measuring stripe in contact with the non-woven surface after rinsing the diaper 1 to 3 times with the urine substitute.
  • the pH values are unobtrusive with respect to a wet coat weight of 43 mg (V8). At higher coat weights, the initially taken pH value increases, but is reduced after one rinsing to about 7.
  • the pH on the diaper top sheet is a critical value because, values above 8 may increase the risk of the development of skin disorders.
  • Table 11 pH after first rinsing pH after second rinsing pH after third rinsing Reference (untreated diaper) 7 7 7 7 V8 7 7 7 V10 8 7 7 7
  • Aerobe bacteria Pseudomonas aeruginosa , Staphylococcus aureus and Candida albicans are completely absent.
  • Table 13 Sample Weeks TAMC TYMC Pseudomonas aeruginosa [g -1 ] Staphylococcus aureus [g -1 ] Candida albicans [g -1 ]
  • the TYMC count was adjusted during the tests (in week 3) to verify the acceptance criteria of the EP: 1 g of the samples were mixed with 49 ml CASO-broth. 5 ml were plated by pour plate technique to lower the detection limit to 10 cfu/g.
  • the spray coating formulation used for the coating of diapers and described in table 6 was used.
  • the nonwoven top sheet substrate was a low bonded, soft PP (polypropylene) nonwoven top sheet typically used for standard baby diapers. Its average grammage is at 14 g/m 2 , with a width of 175 mm.
  • the trial was realized on a lab printing machine (Testacolor 157, a laboratory printing press available from NSM Norbert Schläfli AG, Zofingen, Switzerland) using the above described spray coating equipment from FMP TECHNOLOGY GMBH.
  • the spray equipment was assembled and installed on the printing machine.
  • Two nozzle sizes were tested: 100 and 200 ⁇ m.
  • the pressure of the pressurized vessel was adjusted between 14 bar and 30 bar depending on the flowability of the operating nozzle. An observation of the abrasion tendency of coating material on machine parts was conducted on the transportation rolls, especially after the drying section.
  • the printing system transfers the coating formulation on a width of 150 mm and in specific pattern, depending on the characteristic of the printing plate.
  • the Elastomer printing plate allows full area coating onto the substrate.
  • Samples were taken by cutting 210 mm long pieces of spray coated or printed nonwoven from the reels.
  • Tables 15 and 16 give overviews of the results of trials V12 to V16 using spray coating and V17 to V19 using printing, the used equipment and different settings (pressure vessel, dyers, temperature, etc.). For all trial points, the machine speed was set to 100 m/min.
  • the results of the determined residual moisture, the zinc content and the recalculated dry- and wet coat weights are displayed.
  • the weight values are based on samples cut to a length of 210 mm.
  • the zinc content on the coated nonwoven was determined by extraction of solids on the coated top sheet in 25 ml of a 3% HNO 3 solution, shaking and letting stand over night. After filtration over a 0.2 ⁇ m regenerated cellulose syringe-filter, the solution was appropriately diluted before measuring. Zn-66 and Zn-68 were measured with an Inductively Coupled Plasma - Mass Spectrometer (ICP-MS) Elan DRCe from Perkin Elmer with an argon plasma flow of 15 l/min.
  • ICP-MS Inductively Coupled Plasma - Mass Spectrometer
  • the temperature measuring device Raynger ST2L from Raytek was used.
  • the device uses non-contact, infrared measuring principle. The temperature is calculated based on the emitting radiation energy from the substrate. The measuring point was 30 cm after the last dryer. The distance from measuring device to substrate was ca. 20 cm .
  • V15 As can be taken from table 15, the residual moisture content of V15 was best. However, the 100 ⁇ m nozzle tended to plug, such that a 200 ⁇ m nozzle was used, which produced nearly equally good results. V12, V13, V14 and V16 showed a residual moisture from 0.73 % to 7.45 % depending on the adjusted temperature of the dryers.
  • the preferred drying temperature was found to be 160 °C and lower. Higher drying temperatures of up to 250°C caused an increase of the temperature of the nonwoven itself and resulted in a fusing of the PP fibres.
  • the detected zinc content on the samples reflects dry coat weights from 28 mg to 52 mg or wet coat weights from 90 mg to 167 mg (using the 200 ⁇ m nozzle). With the 100 ⁇ m nozzle a low dry coat weight of 14 mg (or 45 mg wet coat weight) could be achieved.
  • Table 16 V17 V18 V19 Coating Printing Printing Printing Printing Plates Anilox Roll Pick-up volume Flinn ART 2.54 mm 360er Anilox 4.9 m 3 /m 2 Elastomer 360er Anilox 4.9 m 3 /m 2 Elastomer 120er Anilox 15.2 m 3 /m 2 Temp. Dryer 1 [°C] 120 120 130 Temp.
  • Dryer 2 [°C] 0 0 0 Nonwoven Temp. Coated Area [°C] 30 - 35 30 - 35 30 - 35 Nonwoven Temp. Uncoated Area [°C] 30 - 35 30 - 35 30 - 35 Residual Moisture [%] dry dry dry Zn content [mg] 0.03 0.03 0.1 Dry Coat Weight [mg] 2.15 2.08 7.69 Wet Coat Weight [mg] 6.84 6.59 24.42
  • the coat weight In contrast to the spray coating system, the coat weight would not be reduced by higher machine speeds in industrial scale, because the printing unit would operate at the same speed and transfer an unvarying amount of fluid. But, the coat weight, respectively, the transferred amount of fluid, can be adjusted depending on the design of the printing plate and the pick-up volume of the Anilox roll.
  • connection stripe which is a results of the production process, in Figures 5a and 5b as well as a group of single fibres in Figure 5c under different magnification.
  • Figures 6a and 6b show the distribution of the spray coated zinc treated precipitated calcium carbonate solids on the nonwoven after coating according to V14.
  • connection stripes visualized in Figures 6a and 6b which are joining the fibres show accumulations of calcium carbonate. These kinds of nests are bonded to the substrate by the CMC binder which was incorporated in the formulation.
  • connection stripes solids can be found widely distributed and bonded onto the PP fibres spray coated according to V13 (see Figure 7 ).
  • Figure 7 gives a good impression how the zinc containing calcium carbonate particles are spread on the PP fibres.
  • the CMC as binding agent in the coating formulation offers good adhesion to the fibres and appears to be appropriate.
  • Figure 7 also gives an impression about the particle size which is about 2 ⁇ m in average.
  • the coated nonwoven samples were tested for their tensile strength using an ISO 527-3 tensile strength test method (typically applied on foils) on a Zwick Roell device with a 20 kN load cell. Stripes with a length of 150 mm and a width of 15 mm were punched out of the coated or uncoated area of the samples and placed into the sample holder. The test was conducted with a preload of 0.2 N and a test speed of 500 mm/min. The value are average values of 5 measurements, respectively.
  • Table 17 Ref. V12 V13 center V13 edge V14 V15 V16 Dry Coat Weight [mg] - 38.04 49.27 - 52.62 14.31 28.38 Force max [N] 7.94 9.96 10.12 15.06 10.71 9.04 8.43 Standard Deviation S [N] 0.62 0.82 1.17 0.48 1.19 0.17 0.65 Variance V [%] 7.79 8.2 11.52 3.17 11.1 1.83 7.69 Table 18 Ref.

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EP17162567.6A 2017-03-23 2017-03-23 Utilisation de carbonate de calcium précipité traité par du zinc dans des produits hygiéniques Withdrawn EP3378502A1 (fr)

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EP17162567.6A EP3378502A1 (fr) 2017-03-23 2017-03-23 Utilisation de carbonate de calcium précipité traité par du zinc dans des produits hygiéniques
US16/488,910 US20200046869A1 (en) 2017-03-23 2018-03-08 Use of zinc treated precipitated calcium carbonate in hygienic products
BR112019019861A BR112019019861A2 (pt) 2017-03-23 2018-03-08 uso de carbonato de cálcio preciptado tratado com zinco em produtos de higiene
JP2019552134A JP2020513984A (ja) 2017-03-23 2018-03-08 衛生製品における亜鉛処理された沈降炭酸カルシウムの使用
MX2019011347A MX2019011347A (es) 2017-03-23 2018-03-08 Uso de carbonato de calcio precipitado tratado con zinc en productos higienicos.
AU2018240768A AU2018240768A1 (en) 2017-03-23 2018-03-08 Use of zinc treated precipitated calcium carbonate in hygienic products
ES18709015T ES2877805T3 (es) 2017-03-23 2018-03-08 Uso de carbonato de calcio precipitado tratado con zinc en productos higiénicos
KR1020197029893A KR20190127819A (ko) 2017-03-23 2018-03-08 위생 제품에서의 아연 처리된 침강 탄산칼슘의 용도
PCT/EP2018/055784 WO2018172096A1 (fr) 2017-03-23 2018-03-08 Utilisation de carbonate de calcium précipité traité au zinc dans des produits hygiéniques
CA3054000A CA3054000A1 (fr) 2017-03-23 2018-03-08 Utilisation de carbonate de calcium precipite traite au zinc dans des produits hygieniques
EP18709015.4A EP3600460B1 (fr) 2017-03-23 2018-03-08 Utilisation de carbonate de calcium précipité traité par du zinc dans des produits hygiéniques
RU2019133471A RU2759668C2 (ru) 2017-03-23 2018-03-08 Использование обработанного цинком осажденного карбоната кальция в гигиенических продуктах
CN201880020430.6A CN110446507B (zh) 2017-03-23 2018-03-08 锌处理的沉淀碳酸钙在卫生产品中的用途
ARP180100700A AR111141A1 (es) 2017-03-23 2018-03-23 Producto higiénico de carbonato de calcio precipitado tratado con zinc, y proceso para su preparación
IL26879819A IL268798A (en) 2017-03-23 2019-08-20 Use of zinc treated precipitated calcium carbonate in hygienic products

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US20210059873A1 (en) * 2019-09-02 2021-03-04 The Procter & Gamble Company Absorbent article
EP4155268A1 (fr) * 2021-09-28 2023-03-29 Linkway Technology Co., Ltd. Matériau de zinc à atome unique, article en caoutchouc et son procédé de préparation
WO2024052171A1 (fr) * 2022-09-09 2024-03-14 Omya International Ag Composite de carbonate de calcium fonctionnalisé par un oxyde de zinc

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BR112019019861A2 (pt) 2020-04-22
CN110446507A (zh) 2019-11-12
EP3600460B1 (fr) 2021-05-05
AU2018240768A1 (en) 2019-09-19
RU2019133471A3 (fr) 2021-05-20
AR111141A1 (es) 2019-06-05
CN110446507B (zh) 2022-05-27
EP3600460A1 (fr) 2020-02-05
WO2018172096A1 (fr) 2018-09-27
RU2019133471A (ru) 2021-04-23
KR20190127819A (ko) 2019-11-13
ES2877805T3 (es) 2021-11-17
US20200046869A1 (en) 2020-02-13
JP2020513984A (ja) 2020-05-21
CA3054000A1 (fr) 2018-09-27
RU2759668C2 (ru) 2021-11-16
MX2019011347A (es) 2019-11-18

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