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EP3036291A1 - Colorant autoluminescent et à effet nacré dans des environnements non éclairés et son procédé de production - Google Patents

Colorant autoluminescent et à effet nacré dans des environnements non éclairés et son procédé de production

Info

Publication number
EP3036291A1
EP3036291A1 EP14742386.7A EP14742386A EP3036291A1 EP 3036291 A1 EP3036291 A1 EP 3036291A1 EP 14742386 A EP14742386 A EP 14742386A EP 3036291 A1 EP3036291 A1 EP 3036291A1
Authority
EP
European Patent Office
Prior art keywords
dye
pearl effect
mixture
shining
self
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP14742386.7A
Other languages
German (de)
English (en)
Inventor
Hasan TATAR
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of EP3036291A1 publication Critical patent/EP3036291A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/36—Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004—Reflecting paints; Signal paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22—Luminous paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/41—Organic pigments; Organic dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide

Definitions

  • the present invention is related to dyes provided in dye chemicals industry, which both provide decorative appearance and noticeability thanks to pearl effect in lighted environments (daytime) and ensure pearl effect by shining by itself in unlighted environment (night), and the production method thereof.
  • the dyes that provide pearl effect in the applications performed on wall surfaces are only applied to provide effect in lighted environments. Since, dyes with pearl effect can only be seen in lighted environment and fulfill their functions. However, the dyes with pearl effect cannot fulfill said function in dark, namely, unlighted environments.
  • the light reflectors are positioned in order to increase visibility thereof for traffic safety in both lighted and unlighted environments.
  • the visibility of closed trailers in both lighted and unlighted environments are not enough in terms of traffic safety.
  • the light reflectors are not effective as much as the dye and they have limited usage area; therefore, additional costs arise for both producer and consumer.
  • the dyes with pearl effect in the state of are not resistant against especially UV lights. In addition, they are not effective against bacterial and mold growth.
  • the present invention is related to a novelty for dye chemicals industry, which meets the abovementioned requirements, eliminates all the advantages and offers some additional advantages.
  • the dyes that provide pearl effect in the applications performed on wall surfaces are only applied to provide effect in lighted environments. Since, dyes with pearl effect can only be seen in lighted environments.
  • An object of the present invention is to provide the wall surfaces in the state of art with pearl effect by shining by itself in daytime, namely, in the lighted environments, and at night, namely, in unlighted environments, and to achieve advantage for making the areas used by the consumer while making decorative choices, more characteristic, and to increase the satisfaction of the consumer thanks to usage thereof in both ways.
  • the light reflectors are positioned in order to increase visibility thereof for traffic safety only in unlighted environments.
  • Another object of the present invention is to increase the visibility thanks to the pearl effect in both lighted (daytime) environments and thanks to self-shining pearl effect in unlighted (night) environments by dyeing the articulated lorries and closed trailers with the dye according to the present invention without additional costs and limited usage area.
  • Another object of the present invention is to provide maximum visibility in unlighted environments by reflecting the light arriving in several angles, like a light reflector no matter what the color of the light is. Thanks to said feature, the traffic safety will be' ensured and the accidents will be minimized with the facilities provided in several conditions and also, the financial and emotional damages that will caused by the accidents will be minimized.
  • Another object of the present invention is to provide the indoor and outdoor doors with decorative appearance and visibility in both lighted environments (daytime) thanks to pearl effect, and to increase the visibility of the doors in unlighted environments (night) in sudden electric cut in the conditions such as earthquake, fire and etc., and to direct the people towards a more secure way and to decrease the injuries and deaths in the situations when even a few seconds are vital thanks to more visible exit doors.
  • the dyes with pearl effect used in our daily lives will be provided with pearly effect in both lighted and unlighted environments ⁇
  • the dye with pearl effect has the characteristic of maintaining said effect for a longer time arid will appeal to a wider usage area in the related sector.
  • the dye that is self-shining in unlighted environment and has pearl effect creates a smoother layer on the application surfaces when compared to the dyes with pearl effect, which are visible in lighted environment.
  • Pigment volume concentration is used in order to increase the pigment volume in the formula of many standard dyes.
  • the dye that is self-shining in unlighted environment and has pearl effect according to the present invention provides said effect with pearl-effect acrylic copolymer emulsion based dye and the dye mixture according to the present invention is provided with the same feature with a larger volume. Therefore, the costs are minimized and the dye according to the present invention becomes more economical.
  • the composition required for preparing 2750 gr of the dye that is self-shining in lighted environments and has pearl effect comprises the following by weight; 1.79 gr titanium dioxide, 2.95 gr jojoba oil, 1.0 gr of 4% calcium octoate, 0.14 gr of 6% cobalt octoate, 52.31 gr phosphorescent pigment, 4.35 gr long oil soya based alkyd resin, 0.84 gr castor oil (liquid), 26.15 gr hydrocarbon alkyd resin, 0.72 gr anti-precipitating agent, 18.52 gr synthetic solvent, 1.23 gr flow additive, and 2640 gr dye with pearl effect.
  • the production method of the dye that is self-shining in lighted environments and has pearl effect comprises the following process steps;
  • the dye that is developed for achieving said objects is ⁇ elf-shining in lighted environments and has pearl effect is prepared.
  • the present invention is related to dyes provided in dye chemicals industry, which both provide decorative appearance and noticeability thanks to pearl effect in lighted environments (daytime) and ensure pearl effect by shining by itself in unlighted environment (night).
  • composition of the dye according to the present invention comprises dye with pearl effect, flow additive, synthetic solvent, anti-precipitating agent, hydrocarbon alkyd resin, castor oil, long oil soya based alkyd resin, phosphorescent pigment, 6% cobalt octoate, 4% calcium octoate, jojoba oil and titanium dioxide.
  • Table 1 The content and rates of the dye that is self-shining in lighted environments and has pearl effect, are given in Table 1.
  • Table-1 The content and rates of the dye that is self-shining in lighted environments and has pearl effect
  • Titanium Dioxide (TiQ 7 ) : Titanium dioxide decreases the light release (loss of gloss) of the light absorbed by phosphorescent pigment in the unlighted environment and also increases the rate of light absorbance in lighted environment within the functioning of the present invention and titanium dioxide contributes to the functioning of the invention by providing conciliating balance between two functions.
  • jojoba oil is created with an alcohol group of long-chain branches and may be said to be the oil that is most resistant against temperature and beam of lights thanks to fatty acid property thereof.
  • jojoba oil is still used in the most developed motor oils of the world and even as lubricant in the rocket motors of NASA. Thanks to said property of jojoba oil, the paint makes the present invention more resistant against UV lights and time.
  • jojoba oil homogenizes the paint mixtures better and thereby, contributes to the functionality of the present invention to a great extent.
  • Jojoba oil provides the mixture it is included with the property of resistance against bacterial and mold growth.
  • This element contributes within the invention thanks to its properties such as binding with other elements, accepting pigments at a higher level and high resistance against yellowing. In addition, it also contributes to pre-drying and final drying.
  • Castor Oil This element contributes to the functioning of the present invention with its ricinoleic acid property and enables the invention to create a better film on the surface to which it is applied by ensuring binding between pigments during mixing the mixture.
  • This element strengthens the sticking of the mixture on the surface, to which it is applied, and increases the physical resistance thereof and it contributes to the functioning of the present invention by preventing the contact of elements of the invention with air during and after the mixture and preventing the oxygen inhibitors.
  • Hydrocarbon alkyd resins are the leading ones among the alkyd resins with highest resistance.
  • Anti-precipitating agent is the
  • This element contributes to the functioning of the present invention by eliminating the flowing problems while the dye is applied on the surfaces, especially when it is applied vertically, thanks to strong thixotropic effect thereof, preventing the precipitation of pigments in the dye mixture and enabling the dye mixture to spread better on the surface it is applied.
  • This element contributes to the functioning of the present invention by enabling the other element additives in the dye mixture to be mixed better.
  • said element enables to achieve applicable surface liquidity property on the surface areas, to which the dye mixture will be applied. In addition, it also contributes within the present invention by controlling the liquidity on the surface areas to be applied.
  • the dye with pearl effect is the dye that has synthetic dye properties and comprises pearl pigment.
  • the production method of the dye that is self-shining in lighted environments and has pearl effect comprises the following process steps;
  • hydrocarbon alkyd resin for cooling after liquid is achieved (the temperature of the mixture should not be below 22°C)
  • the dye that is self-shining in lighted environments and has pearl effect according to the present invention is a top coat that can be wiped.
  • the surfaces that will be applied are required to be humidity-free, smooth, durable and resistant. If the surfaces are not smooth, they are required to be smoothened by means of acrylic copolymer emulsion based paste (preferably white). Whether the surfaces are pasted or not, acrylic copolymer emulsion based paste undercoat is required to be used in order to decrease the absorbance of the surfaces and increase the adherence surfaces by creating adherence bridge. Application of said paste and paste undercoat can be performed under the directions of the product producer. In order to smoothen the surfaces, the materials such as satin plaster, which lead to dusting, should not be used.
  • the diluent is not used while applying the dye that is self-shining in lighted environments and has pearl effect according to the present invention; it is ready for use. If it is desired to be thinned, synthetic thinner can be added so as not to exceed 10% of the total weight.
  • the dye that is self-shining in lighted environments and has pearl effect according to the present invention should be applied in at least two layers.
  • the increase in the layers is in direct proportion with lumen (lighting rate) of the dye according to the present invention.
  • the dye that is self-shining in lighted environments and has pearl effect is required to be applied with max. 10% synthetic solvent by thinning, if air-free dye spray gun is desired to be used.
  • the pressure of air-free spray gun is required to be 140 bars.
  • the size of nozzle of air- free spray gun is required to be 0.013".
  • the usage area of the dye that is self-shining in lighted environments and has pearl effect may be broadened and varied by adding glitter powder and quartz sand into the dye.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition de colorant à effet nacré, constituée de 96 % d'une composition de colorant à effet nacré, de 0,26 à 0,28 % d'un additif d'écoulement, de 0,045 à 0,067 % d'un solvant de synthèse, de 0,67 à 0,80 % d'un agent anti-précipitation, de 0,95 à 0,98 % d'une résine alkyde hydrocarbonée, de 0,03 à 0,052 % d'huile de ricin, de 0,158 à 0,183 % de résine alkyde à base d'huile de soja longue en huile, de 1,90 à 2,13 % de pigment phosphorescent, de 0,0051 à 0,0069 % d'octoate de cobalt à 6 %, de 0,036 à 0,0418 % d'octoate de calcium à 4 %, de 0,11 à 0,73 % d'huile de jojoba et de 0,065 à 0,072 % de dioxyde de titane en poids. Ladite composition est produite par l'industrie chimique des colorants, est décorative et bien visible grâce à son effet nacré dans un environnement éclairé (de jour) et présente un effet nacré par autoluminescence dans un environnement non éclairé (de nuit). La présente invention concerne également le procédé de production de ladite composition.
EP14742386.7A 2013-06-14 2014-04-18 Colorant autoluminescent et à effet nacré dans des environnements non éclairés et son procédé de production Withdrawn EP3036291A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TR201307214 2013-06-14
PCT/TR2014/000122 WO2014200446A1 (fr) 2013-06-14 2014-04-18 Colorant autoluminescent et à effet nacré dans des environnements non éclairés et son procédé de production

Publications (1)

Publication Number Publication Date
EP3036291A1 true EP3036291A1 (fr) 2016-06-29

Family

ID=51220859

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14742386.7A Withdrawn EP3036291A1 (fr) 2013-06-14 2014-04-18 Colorant autoluminescent et à effet nacré dans des environnements non éclairés et son procédé de production

Country Status (2)

Country Link
EP (1) EP3036291A1 (fr)
WO (1) WO2014200446A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109852209A (zh) * 2018-12-21 2019-06-07 浙江天池市政建设有限公司 一种去除汽车尾气的环保型城市道路

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2318089A (en) * 1942-07-22 1943-05-04 Mearl Corp Luminescent material
US3445551A (en) * 1966-05-20 1969-05-20 Fli Back Co Inc Pearlescent,phosphorescent balls and methods for making the same
US4725316A (en) * 1985-04-09 1988-02-16 Eldon Enterprises Ltd. Color compositions and method
US5276075A (en) * 1991-10-30 1994-01-04 Binney & Smith Inc. Washable acrylic paint
US5741355A (en) * 1995-01-27 1998-04-21 Topy Industries, Limited Pearlescent pigment, and paint composition, cosmetic material, ink and plastics blended with the new pearlescent pigment
US6242056B1 (en) * 1998-05-08 2001-06-05 Innovative Concepts Unlimited, Llc Process for applying light-emission-enhancement microbead paint compositions
WO2003046089A2 (fr) * 2001-11-29 2003-06-05 Honda Canada Inc. Pigment blanc destine a etre utilise dans des formulations comprenant de la peinture perlee blanche
DE102008050605A1 (de) * 2008-10-09 2010-04-15 Merck Patent Gmbh Beschichtungsverfahren

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
None *
See also references of WO2014200446A1 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109852209A (zh) * 2018-12-21 2019-06-07 浙江天池市政建设有限公司 一种去除汽车尾气的环保型城市道路
CN109852209B (zh) * 2018-12-21 2021-02-23 浙江天池市政建设有限公司 一种去除汽车尾气的环保型城市道路

Also Published As

Publication number Publication date
WO2014200446A1 (fr) 2014-12-18

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