EP2663413B1 - Dispositif de changement de tube de coulée doté d'une plaque d'obturation, pour un dispositif de coulée destiné à produire des produits métallurgiques - Google Patents
Dispositif de changement de tube de coulée doté d'une plaque d'obturation, pour un dispositif de coulée destiné à produire des produits métallurgiques Download PDFInfo
- Publication number
- EP2663413B1 EP2663413B1 EP12701435.5A EP12701435A EP2663413B1 EP 2663413 B1 EP2663413 B1 EP 2663413B1 EP 12701435 A EP12701435 A EP 12701435A EP 2663413 B1 EP2663413 B1 EP 2663413B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- casting
- nozzle tube
- nozzle
- dummy plate
- changer according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005266 casting Methods 0.000 title claims description 66
- 239000000725 suspension Substances 0.000 claims description 7
- 238000006073 displacement reaction Methods 0.000 description 12
- 230000008859 change Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 230000000977 initiatory effect Effects 0.000 description 3
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/14—Closures
- B22D41/22—Closures sliding-gate type, i.e. having a fixed plate and a movable plate in sliding contact with each other for selective registry of their openings
- B22D41/28—Plates therefor
- B22D41/34—Supporting, fixing or centering means therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/50—Pouring-nozzles
- B22D41/56—Means for supporting, manipulating or changing a pouring-nozzle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/14—Closures
- B22D41/22—Closures sliding-gate type, i.e. having a fixed plate and a movable plate in sliding contact with each other for selective registry of their openings
- B22D41/24—Closures sliding-gate type, i.e. having a fixed plate and a movable plate in sliding contact with each other for selective registry of their openings characterised by a rectilinearly movable plate
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/42—Constructional features of converters
- C21C5/46—Details or accessories
- C21C5/4653—Tapholes; Opening or plugging thereof
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/15—Tapping equipment; Equipment for removing or retaining slag
- F27D3/1509—Tapping equipment
- F27D3/1518—Tapholes
Definitions
- the invention relates to a casting tube changer for a casting device for producing metallurgical products, according to the preamble of claim 1.
- pouring tube is also to be understood to mean pouring nozzles which essentially fulfill the same function as the pouring tubes and differ from these mainly due to the different overall lengths.
- Cast iron changer of the type mentioned are known to replace a worn casting pipe with a new, especially in casting devices for producing continuous casting without interrupting the operation of the casting plant. This is done by Move the new pouring tube into the casting position, taking along the worn pouring tube.
- a changing device of this kind is in the EP 0 714 332 B1 revealed.
- the casting tube changer does not contain any means for rapid closing of the pouring channel in emergencies, for example in the case of pouring pipe breaks or similar serious occurrences. This is in the view of the reliability of the system of disadvantage.
- EP-A-723 829 discloses a shutter device by means of which a blind refractory plate can be manually displaced from a supply to a standby position by manual operation, and subsequently this dummy refractory plate can be slid below the pouring channel and close it. But even with this closure device is disadvantageous that this required manual operation time-consuming and may be dangerous for the operator under certain circumstances.
- the invention has for its object to avoid this disadvantage and to provide a G confuserohrwechsler of the aforementioned type, which accomplished both the pipe replacement and an emergency closure of the casting channel with the simplest possible means.
- the invention also provides that the dummy plate in the waiting position is held in normal operation above the displacement level of the casting tubes and in an emergency can be lowered automatically to the displacement plane of the casting tubes.
- the latter can therefore also be used for the blank plate in an emergency. In this way, the structure of the changing device is simplified.
- the actuator according to the invention consists of a guided in the direction of the casting tube slide and a transversely to the direction pivotally connected driver. As a result, the plane of action of the driver is automatically adjustable.
- the blanking plate can be coupled to the driver by means of preferably hackenförmig formed suspension elements.
- the blanking plate is preferably provided on both sides with a horizontal longitudinal groove and an obliquely lying to it guide groove, which cooperate with a stationary arranged pin. It is advantageous if the blanking plate is preferably loaded on its opposite side of the suspension with a biasing spring also arranged stationary.
- the actuating member can be driven by a preferably hydraulic linear drive whose piston rod is coupled to the slide of the actuating member.
- the invention provides that the linear drive is arranged with the carriage on one longitudinal side of the changing device, and that on the opposite longitudinal side a nozzle gripper is provided, with which the worn casting nozzle is removable from the changing device.
- the nozzle gripper has a swing-out recording head with a holding magnet for the worn casting nozzle, which is attached at the end of a parallel to the direction of the casting nozzle rotating and retractable and guided operating rod. This facilitates handling and simplifies the construction of the device.
- the changing devices after the Fig. 1 to Fig. 11 and FIGS. 12 to 18 are essentially identical. As in particular from the FIGS. 12 to 18 can be seen, they have a base plate 1, which is secured by means of wedge elements 2 on the bottom wall of a casting apparatus 3 with a spout 4. On the base plate 1 guide rails 5, 6 are mounted. They form a displacement plane for the casting pipes to be replaced or the casting nozzles to be replaced.
- a drive system 7 is further mounted with a hydraulic linear drive 8 and an actuator 9 for the casting tubes or casting nozzles to be replaced.
- the actuator 9 is composed of a carriage 10 and a driver 11, wherein the coupled to the piston rod of the linear drive 8 slide 10 is guided in guides 12 in the direction of displacement of the casting tubes or casting nozzles, while the driver 11 on the carriage 10 about an axis thirteenth is articulated transversely to the direction of displacement.
- the changing devices are also provided with a blank plate 14, with which in case of emergency, the pouring channel of the casting apparatus 3 can be closed.
- a horizontal longitudinal groove 15 and an obliquely arranged to her guide groove 16 are provided on both sides, wherein both grooves cooperate with them engaging cylindrical pins 17 on the carriage 10.
- the change device after Fig. 11 are the grooves on the slide, while the cylinder pins placed on the blanking plate, so vice versa.
- the cylinder pins of the blanking plate or the grooves 15, 16 associated with the carriage is in this change device after 11 to FIG. 18 achieved that the dummy plate 14, which is not illustrated in detail, pulled back into the waiting position and that consequently a new exchange nozzle can be inserted.
- the casting process can be interrupted for a short period of time and, as a result, the casting process continues by burning the molten steel frozen in the pouring sleeve 4.
- the blanking plate 14 is then in the waiting position over the displacement plane of the casting tubes or pouring nozzles. There it is so far offset from the displacement plane that the unused casting pipe or the unused casting nozzle is unhindered inserted under the blanking plate during the change process.
- the latter can be coupled to the driver 11 by hack-shaped suspension elements 18, which can hook into corresponding recesses 19 of the carrier 11.
- the blanking plate 14 is acted upon by a biasing spring 20 supported against the base plate 1 or an equivalent means.
- the casting tube changer after the Fig. 1 / 1a to Fig. 11 / 11a works as follows: In normal operation, there is a pouring pipe 21 in the in Fig. 1 shown casting position, in which the casting tube is pressed against the him with the casting channel forming outlet sleeve 4 of the casting apparatus. Next to him is an unused spare tube 22 in waiting position. The blind plate 14 is above the replacement tube 22, also in waiting position. It is coupled to the driver 11 with the suspension elements 18 ( Fig. 1 / 1a ).
- the driver 11 by the linear drive 8 in the direction of arrow 23 (FIG. Fig. 2 / 2a ), wherein the dummy plate 14 is moved forward and the pin 17 moves into the longitudinal groove 15 to prevent the dummy plate 14 from falling down.
- the driver 11 then depends on the blanking plate 14 and is now able to push the replacement tube 22 into the previously occupied by the pouring tube 21 casting position ( Fig. 3 / 3a ).
- Fig. 4 / 4a the end position of the change process is shown.
- the driver 11 has the replacement tube 22 inserted into the casting position and pushed out the spent pouring tube 21 from the casting position, while the blanking plate 14 is still in the waiting position. Thereafter, the driver 11 by the linear drive 8 in the direction of arrow 24 ( Fig. 5 / 5a ) moved back. He hangs himself on the blind plate 14 again ( Fig. 6 / 6a ) and causes them by the interaction of the pins 17 with the oblique guide grooves 16 does not fall out ( Fig. 7 / 7a ).
- the casting tube changer is then again in the in Fig. 8 / 8a illustrated initial situation, but in which, for example, now emergency no replacement tube is inserted in the changer. Since no replacement tube is present, the blanking plate 14 is not on and thus can be down because the pins 17 now in the guide grooves 16 in the direction of the open groove along along migrate, which is supported by the spring force of the biasing spring 20 ( Fig. 9 / 9a ).
- the blank plate 14 drops down to the displacement plane of the casting tubes 21, 22, and the driver 11 can insert it in an emergency on the same displacement plane in the closed position ( Fig. 10 / 10a ), while in turn pushes the operating pipe 22 out of the casting position ( Fig. 11 / 11a ). In this way, the emergency closing of the pouring channel is accomplished by means of the blanking plate 14.
- the changing device Since only a single drive system with a common actuator and a common displacement plane are available for the change process and the emergency closing, the changing device is structurally simple and reliable, because they can only perform one or the other function by design.
- the blank plate 14 is pushed by the driver 11 on the displacement plane of the casting nozzle 25 ( Fig. 14 ) until it pushes them out of the casting position.
- the final closed position Fig. 15
- the blanking plate 14 is now in the casting position, in which it completely interrupts the casting channel of the casting device.
- the Giessdüsenwechsler after the FIGS. 16 to 18 is essentially the same as the one after the FIGS. 12 to 15 constructed, but additionally has a nozzle gripper 27 for removing the worn casting nozzles.
- the nozzle gripper 27 has a receiving head 28 with a holding magnet 29 for the worn casting nozzles, which is attached to a pivot arm 30 of a parallel to the direction of rotation and retractable and extendable operating rod 31 with a handle 32.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
- Continuous Casting (AREA)
- Sliding Valves (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Casting Devices For Molds (AREA)
- Coating Apparatus (AREA)
Claims (8)
- Dispositif de changement de tube de coulée pour un dispositif de coulée afin de produire des produits métallurgiques, comprenant un élément (9) d'actionnement pour faire passer un tube (22) de coulée d'une position d'entretien à la position de coulée, dans laquelle le tube de coulée est appliqué sur un manchon (4) de sortie, formant avec lui un canal de coulée ou analogue du dispositif de coulée, le dispositif de changement de tube de coulée étant pourvu d'une plaque (14) d'obturation, qui sert à fermer le canal de coulée, qui, en fonctionnement normal, est mise en une position d'entretien et qui, en cas d'urgence, peut, par un élément (9) d'actionnement, être insérée en repoussant le tube de coulée,
caractérisé en ce que
la plaque (14) d'obturation se trouvant en position d'entretien est maintenue, en fonctionnement normal, au-dessus du plan de déplacement du tube (22) de coulée et, en cas d'urgence, peut être abaissée automatiquement sur le plan de déplacement du tube de coulée et insérée en dessous du canal de coulée formé par le manchon (4) de sortie. - Dispositif de changement de tube suivant la revendication 1, caractérisé en ce que
l'élément (9) d'actionnement se compose d'un chariot (10) guidé dans la direction de déplacement du tube de coulée et d'un entraîneur (11) articulé à lui transversalement à la direction de déplacement. - Dispositif de changement de tube suivant la revendication 2, caractérisé en ce que
la plaque (14) d'obturation peut être accouplée à l'entraîneur (11) au moyen d'éléments (18) de suspension constitués, de préférence, en forme de crochets. - Dispositif de changement de tube suivant la revendication 3, caractérisé en ce que
la plaque (14) d'obturation est pourvue des deux côtés d'une rainure (15) longitudinale horizontale, ainsi que d'une rainure (18) de guidage inclinée par rapport à celle-ci, lesquelles coopèrent avec un doigt (17). - Dispositif de changement de tube suivant la revendication 4, caractérisé en ce que
la plaque (14) d'obturation est soumise, sur son côté opposé à la suspension, à un ressort (20) de précontrainte monté également à poste fixe. - Dispositif de changement de tube suivant l'une des revendications 2 à 5,
caractérisé en ce que
l'élément (9) d'actionnement peut être entraîné par un entraînement (8) hydraulique linéaire, dont la tige de piston est accouplée au chariot (10) de l'élément (9) d'actionnement. - Dispositif de changement de tube suivant l'une des revendications 1 à 6,
caractérisé en ce que
l'élément (9) d'actionnement est monté sur un côté longitudinal du dispositif de changement et en ce qu'il est prévu, du côté longitudinal opposé, un preneur (27) de buse, par lequel la buse de coulée usée peut être retirée du dispositif de changement. - Dispositif de changement de tube suivant la revendication 7, caractérisé en ce que
le preneur (27) de buse a une tête (28) de réception pivotante ayant un aimant (29) de maintien de la buse de coulée usée, qui est fixé à une extrémité d'une barre (31) d'actionnement guidée à rotation, ainsi qu'avec possibilité d'entrer et de sortir, parallèlement à la direction de déplacement de la buse de coulée.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH442011 | 2011-01-11 | ||
PCT/EP2012/000046 WO2012095282A1 (fr) | 2011-01-11 | 2012-01-06 | Dispositif de changement de tube de coulée doté d'une plaque d'obturation, pour un dispositif de coulée destiné à produire des produits métallurgiques |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2663413A1 EP2663413A1 (fr) | 2013-11-20 |
EP2663413B1 true EP2663413B1 (fr) | 2016-07-13 |
Family
ID=45554607
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12701435.5A Active EP2663413B1 (fr) | 2011-01-11 | 2012-01-06 | Dispositif de changement de tube de coulée doté d'une plaque d'obturation, pour un dispositif de coulée destiné à produire des produits métallurgiques |
Country Status (16)
Country | Link |
---|---|
US (1) | US8795583B2 (fr) |
EP (1) | EP2663413B1 (fr) |
JP (1) | JP5925216B2 (fr) |
KR (1) | KR101829949B1 (fr) |
CN (1) | CN103429368B (fr) |
AU (1) | AU2012206729B2 (fr) |
BR (1) | BR112013017225B1 (fr) |
CA (1) | CA2822116C (fr) |
ES (1) | ES2597971T3 (fr) |
HU (1) | HUE030873T2 (fr) |
MX (1) | MX340039B (fr) |
MY (1) | MY183724A (fr) |
PL (1) | PL2663413T3 (fr) |
RU (1) | RU2600461C2 (fr) |
UA (1) | UA111482C2 (fr) |
WO (1) | WO2012095282A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021001279A1 (fr) | 2019-07-03 | 2021-01-07 | Refractory Intellectual Property Gmbh & Co. Kg | Installation permettant la manipulation, de préférence, d'une busette de coulée dans un dispositif de remplacement de busette en sortie d'un récipient métallurgique |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103429368B (zh) * | 2011-01-11 | 2016-09-14 | 斯托品克股份公司 | 带有用于生产冶金产品的浇注装置的盲板的浇注管更换器 |
CH707075B1 (de) | 2012-10-11 | 2021-01-15 | Refractory Intellectual Property Gmbh & Co Kg | Schiebeverschluss für ein Metallschmelze enthaltendes Gefäss. |
CN104482768B (zh) * | 2014-12-09 | 2016-04-20 | 大连华锐重工集团股份有限公司 | 套筒伸缩式自动开堵眼机 |
CH710652B1 (de) | 2015-01-23 | 2019-06-28 | Refractory Intellectual Property Gmbh & Co Kg | Schiebeverschluss für einen Metallschmelze enthaltenden Behälter. |
CH715297A2 (de) | 2018-09-04 | 2020-03-13 | Refractory Intellectual Property Gmbh & Co Kg | Verfahren zur Wartung eines Schiebeverschlusses am Ausguss eines metallurgischen Gefässes sowie ein Schiebeverschluss. |
CN110605380B (zh) * | 2019-09-23 | 2022-07-08 | 山东钢铁股份有限公司 | 一种板坯连铸机及其板坯中间包快速堵流装置 |
EP3943212A1 (fr) | 2020-07-21 | 2022-01-26 | Refractory Intellectual Property GmbH & Co. KG | Fermeture coulissante au niveau de l'orifice d'un récipient métallurgique |
AT17334U1 (de) * | 2020-08-26 | 2021-12-15 | Sheffield Hi Tech Refractories Germany Gmbh | Vorrichtung zum Verschließen eines Gießrohres eines metallurgischen Gefäßes |
CN115351270B (zh) * | 2022-06-28 | 2024-06-11 | 东北大学 | 一种中间包底部电磁旋流水口设备的固定装置 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU872014A1 (ru) * | 1979-10-10 | 1981-10-15 | Центральный научно-исследовательский институт черной металлургии им.И.П.Бардина | Устройство дл подвода металла |
US4693401A (en) * | 1984-07-28 | 1987-09-15 | Kurosaki Refractories Co., Ltd. | Apparatus for compressively holding casting nozzles |
JPS61172662A (ja) * | 1985-01-25 | 1986-08-04 | Kawasaki Heavy Ind Ltd | ノズル交換装置 |
WO1992000821A1 (fr) * | 1990-07-04 | 1992-01-23 | International Industrial Engineering S.A. | Dispositif ameliore d'amenee et d'echange d'un tube de coulee |
BE1007317A3 (fr) | 1993-07-27 | 1995-05-16 | Int Ind Eng Sa | Dispositif d'amenee et d'echange d'un tube de coulee dans une installation de coulee continue a brames minces. |
FR2716819B1 (fr) * | 1994-03-04 | 1996-04-05 | Vesuvius France Sa | Procédé et dispositif de coulée. |
US5494201A (en) | 1995-01-24 | 1996-02-27 | International Industrial Engineering S.A. | Device for inserting a retractable blank shutting off plate in a device for the conveyance and exchange of a pouring tube |
JP3118517B2 (ja) * | 1997-06-26 | 2000-12-18 | 住友重機械鋳鍛株式会社 | 連続鋳造機のタンディッシュノズル装置 |
JP3416531B2 (ja) * | 1998-07-22 | 2003-06-16 | Jfeエンジニアリング株式会社 | ノズル交換装置 |
EP1391257B1 (fr) * | 2001-05-21 | 2008-08-06 | Krosaki Harima Corporation | Dispositif de changement de tuyere immergee, tuyere immergee, plaque ignifuge de fermeture utilisee pour ledit dispositif de changement de tuyere immergee |
CN2565567Y (zh) * | 2002-09-11 | 2003-08-13 | 济南新峨嵋实业有限公司 | 中间包浸入式水口快换装置 |
AT506190B1 (de) * | 2007-12-20 | 2010-05-15 | Siemens Vai Metals Tech Gmbh | Vorrichtung zum auswechselbaren anschliessen eines giessrohres an einen ausguss eines schmelzenbehälters |
CN103429368B (zh) * | 2011-01-11 | 2016-09-14 | 斯托品克股份公司 | 带有用于生产冶金产品的浇注装置的盲板的浇注管更换器 |
-
2012
- 2012-01-06 CN CN201280005011.8A patent/CN103429368B/zh active Active
- 2012-01-06 UA UAA201309436A patent/UA111482C2/uk unknown
- 2012-01-06 RU RU2013135708/02A patent/RU2600461C2/ru active
- 2012-01-06 EP EP12701435.5A patent/EP2663413B1/fr active Active
- 2012-01-06 WO PCT/EP2012/000046 patent/WO2012095282A1/fr active Application Filing
- 2012-01-06 MX MX2013006599A patent/MX340039B/es active IP Right Grant
- 2012-01-06 US US13/976,532 patent/US8795583B2/en active Active
- 2012-01-06 JP JP2013548778A patent/JP5925216B2/ja not_active Expired - Fee Related
- 2012-01-06 BR BR112013017225-8A patent/BR112013017225B1/pt not_active IP Right Cessation
- 2012-01-06 MY MYPI2013002626A patent/MY183724A/en unknown
- 2012-01-06 PL PL12701435T patent/PL2663413T3/pl unknown
- 2012-01-06 HU HUE12701435A patent/HUE030873T2/en unknown
- 2012-01-06 KR KR1020137018098A patent/KR101829949B1/ko active IP Right Grant
- 2012-01-06 ES ES12701435.5T patent/ES2597971T3/es active Active
- 2012-01-06 AU AU2012206729A patent/AU2012206729B2/en active Active
- 2012-01-06 CA CA2822116A patent/CA2822116C/fr active Active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021001279A1 (fr) | 2019-07-03 | 2021-01-07 | Refractory Intellectual Property Gmbh & Co. Kg | Installation permettant la manipulation, de préférence, d'une busette de coulée dans un dispositif de remplacement de busette en sortie d'un récipient métallurgique |
Also Published As
Publication number | Publication date |
---|---|
EP2663413A1 (fr) | 2013-11-20 |
MY183724A (en) | 2021-03-10 |
BR112013017225B1 (pt) | 2019-11-19 |
KR20140027925A (ko) | 2014-03-07 |
CN103429368B (zh) | 2016-09-14 |
KR101829949B1 (ko) | 2018-02-19 |
BR112013017225A2 (pt) | 2018-09-11 |
JP2014502562A (ja) | 2014-02-03 |
CA2822116C (fr) | 2020-10-06 |
UA111482C2 (uk) | 2016-05-10 |
RU2013135708A (ru) | 2015-02-20 |
MX2013006599A (es) | 2013-12-06 |
ES2597971T3 (es) | 2017-01-24 |
CN103429368A (zh) | 2013-12-04 |
JP5925216B2 (ja) | 2016-05-25 |
MX340039B (es) | 2016-06-23 |
US20130299119A1 (en) | 2013-11-14 |
AU2012206729A1 (en) | 2013-07-25 |
US8795583B2 (en) | 2014-08-05 |
RU2600461C2 (ru) | 2016-10-20 |
PL2663413T3 (pl) | 2017-01-31 |
WO2012095282A1 (fr) | 2012-07-19 |
CA2822116A1 (fr) | 2012-07-19 |
AU2012206729B2 (en) | 2016-11-03 |
HUE030873T2 (en) | 2017-06-28 |
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