EP2634383B1 - Verfahren und Anordnung zur Speicherung von Energie - Google Patents
Verfahren und Anordnung zur Speicherung von Energie Download PDFInfo
- Publication number
- EP2634383B1 EP2634383B1 EP13156878.4A EP13156878A EP2634383B1 EP 2634383 B1 EP2634383 B1 EP 2634383B1 EP 13156878 A EP13156878 A EP 13156878A EP 2634383 B1 EP2634383 B1 EP 2634383B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- air
- stage
- liquefaction
- compressor
- heat exchanger
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims description 51
- 239000007788 liquid Substances 0.000 claims description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 238000004146 energy storage Methods 0.000 claims description 7
- 239000002918 waste heat Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 5
- 238000007906 compression Methods 0.000 claims description 5
- 230000006835 compression Effects 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 150000008282 halocarbons Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000002826 coolant Substances 0.000 claims 6
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 239000003507 refrigerant Substances 0.000 description 9
- 238000001816 cooling Methods 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000004378 air conditioning Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K3/00—Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
- F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
- F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
- F01K23/10—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle with exhaust fluid of one cycle heating the fluid in another cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
- F01K25/08—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
- F01K25/10—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours the vapours being cold, e.g. ammonia, carbon dioxide, ether
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0012—Primary atmospheric gases, e.g. air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
- F25J1/0037—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work of a return stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0201—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
- F25J1/0235—Heat exchange integration
- F25J1/0242—Waste heat recovery, e.g. from heat of compression
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0244—Operation; Control and regulation; Instrumentation
- F25J1/0245—Different modes, i.e. 'runs', of operation; Process control
- F25J1/0251—Intermittent or alternating process, so-called batch process, e.g. "peak-shaving"
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/40—Processes or apparatus involving steps for increasing the pressure of gaseous process streams the fluid being air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2240/00—Processes or apparatus involving steps for expanding of process streams
- F25J2240/40—Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
- F25J2240/42—Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval the fluid being air
Definitions
- the invention relates to a method and an arrangement for storing energy in the form of liquid air, with which preferably electrical energy can be stored during off-peak periods of a power grid and removed again during peak load periods.
- pumped storage power plants can achieve relatively high efficiencies of up to 80%, they can only be installed at a few suitable locations, their size largely being determined by local conditions (not scalable).
- the invention has for its object to find a method with the comparatively inexpensive energy stored and removed again can, with a very high number of operating cycles should be achievable.
- the process should allow total efficiencies of 50% or more.
- the method should be feasible regardless of the geographical conditions at the place of use.
- the system should be able to be realized in a relatively simple, modular construction of individual components available according to the prior art.
- the inventive method for storing energy is divided into two phases (steps). In the first phase, energy available in excess is transferred into a storable form and stored (storage). In the second phase, if additional energy is needed, the stored energy is removed again (removal).
- air is drawn in at the inlet (suction side) of a single or multi-stage compressor and the pressure of the air raised to a value higher than the ambient pressure, the air liquefied by means of an isenthalpic expansion and finally a thermally insulated storage tank fed.
- the energy supplied to the compressor is thus transferred into a storable form, namely liquid air, which can be easily stored in a cryogenic tank.
- the compressed air is cooled by cold steam.
- a Gegenstromuzaschreibtragers in the line which serves to return the cold vapor formed in the liquefaction of the air (to the suction side of the compressor), introduced, and the other side of the respective Schmidtstromebenschreibtragers (fluidly) connected behind the last stage of the compressor.
- the Linde-Claude process is used by dividing the compressed air into two substreams after passing through the compressor, and passing the second mass flow through a liquefaction expansion (expander) turbine.
- the first mass flow is cooled by means of a Claude heat exchanger (usually a countercurrent heat exchanger) by the second mass flow emerging from the liquefaction expansion turbine.
- the energy gained in the liquefaction expansion turbine is fed to the compressor, z. B. by the condenser expansion turbine is coupled via a transmission to the compressor.
- a multi-stage compressor is used to liquefy the air and carried out behind each stage of the compressor (each with an intercooler) heat transfer between the compressed air and the environment.
- z As in peak periods of a power grid, the stored liquid air is converted into a continuous mass flow with some 100 bar pressure and the highest possible temperature, and used to drive an expansion turbine (main turbine), to the z.
- main turbine main turbine
- a power generator is coupled.
- liquid air is removed from the storage tank and the pressure of the air by means of a pump and / or by means of thermal compression to a pressure of several 100 bar, preferably 200 bar, increased.
- the pressure increase can in principle be mechanical, z. B. by means of a piston pump, done, but the required (electrical) energy leads to a reduction in the overall efficiency of the process.
- the pressure of the air is only increased thermally by increasing the temperature of the air in a sealed vessel until it has reached the required process pressure. Subsequently, the temperature of the air at ambient temperature, or if a waste heat source is available, brought to the temperature level of the waste heat source.
- a heat exchanger for. B. a shell and tube heat exchanger whose one side in the energy extraction with the extracted air and the other side with the temperature level of the environment (or a waste heat source) is in communication, are used.
- a waste heat source since the air is heated to a higher temperature than the ambient temperature after removal from the storage tank, the specific amount of energy recovered from the liquid air is increased.
- the efficiency of the entire process is increased up to 50% by the energy extraction, in addition to the usual use of liquid air through the main turbine, the (low) temperature level of liquid air for condensing a refrigerant (whose boiling point is usually far below that of water) is used at the lowest level of a single- or multi-stage Rankine process (steam turbine process).
- a single- or multi-stage Rankine process steam turbine process.
- the stages or one stage of the Rankine machine are usually low-boiling substances such.
- nitrogen pure or fully or partially halogenated hydrocarbons, such as. B. R134a, R600a, or natural refrigerants, such.
- water carbon dioxide, or mixtures of the aforementioned substances.
- ORC process Organic Rankine Cycle
- the individual stages of the Rankine engine drive turbines via turbines.
- the electrical energy generated by the power generators is, in addition to the electrical energy generated by the power generator of the main turbine, fed into the power grid to be supplied.
- the arrangement for carrying out the method comprises a single-stage or multi-stage compressor, a liquefaction expansion turbine, through which a second mass flow of air exiting from the last stage of the compressor is passed; at least one countercurrent heat exchanger for heat exchange between the from the liquefaction expansion turbine emerging second mass flow and the first mass flow is used, an expansion valve, via which the first mass flow isenthalp relaxed to a condensing pressure, a phase separator, in which the liquefied air from the gaseous portion (cold vapor) is separated, a thermally insulated storage tank serving for storing the liquefied air, a regasification unit adapted to increase the pressure in liquid air taken out of the storage tank and bring the temperature of the air to at least ambient temperature, and a turbine generated by means of the in the regasification unit Compressed air is drivable.
- Each compressor stage is followed by an intercooler where the compressed air is cooled to near ambient temperature after compression.
- the arrangement also has a single or multi-stage Rankine machine, which serves to increase the overall efficiency of the storage and removal process.
- the lowest stage of the Rankine machine ie the stage which is at the lowest temperature value, is thermally coupled to the temperature level of the liquid air via a countercurrent heat exchanger (condenser) (at the removal of the Air, as soon as liquid air flows out of the storage tank), ie, in the lowest stage, the cold released during the evaporation and heating of the process medium air for the condensation of a refrigerant, for. As nitrogen used.
- a countercurrent heat exchanger at the removal of the Air, as soon as liquid air flows out of the storage tank
- nitrogen used One side of the countercurrent heat exchanger is connected between the output of the storage tank and the input of the main turbine and its other side is flowed through by the refrigerant used in the bottom stage of the Rankine turbine.
- Each stage of the Rankine machine includes a regenerator, a condenser, a refrigerant pump, an evaporator and a turbine (with generator connected).
- Fig. 1 illustrated plant for air liquefaction according to the Linde Claude process consists of a three-stage compressor 1, which is designed as a screw compressor and has an isentropic compression efficiency of about 90%, a first 2 (countercurrent heat exchanger) and a second heat exchanger 3 (Claude heat exchanger) a single-stage turboexpander 4 (liquefaction expansion turbine) having an isentropic expansion efficiency of 90%, a Joule-Thompson throttle valve 5 (expansion valve), a phase separator 6, and a heat-insulated storage tank 7 ensuring low thermal losses.
- Fig. 2 is the position of the air to be stored in the pressure-enthalpy diagram at the in the Fig. 1 registered points (points) AI (points AI apply exclusively storage); in Fig. 3 the thermodynamic states of the air at the points AI are listed in tabular form.
- the compressor 1 For the liquefaction of the air (energy storage) is at the inlet 1.1 of the compressor 1 dried and purified air from the environment and from the process recycled air (cold steam) sucked (point A), the pressure of the air to a final pressure of about 8 bar and increased the compressed air is passed through an outlet 1.2 (point B) through a countercurrent heat exchanger 2, where it is cooled with the cold steam to a temperature of about 143 K (point C).
- the compressor 1 has an intermediate cooling, d. H. behind each stage, the compressed air is cooled by a respective heat exchanger (not shown) to near ambient temperature (points A to B).
- the air After passing through the Schmidtsagenübertragers 2, the air is divided into a first and a second mass flow (the first mass flow is to be cooled by means of the second mass flow).
- the second mass flow is fed into the inlet 4.1 of the liquefaction expansion turbine 4 (expander).
- a phase separator 6 the liquid air is separated from the gaseous residue and directed into the thermally insulated storage tank 7, where it is stored at ambient pressure (non-pressurized storage) and a temperature of about 80 K (point E (f)).
- the possible storage duration is determined almost exclusively by the thermal losses of the storage tank.
- the second mass flow is not liquefied, but by means of the liquefaction-expansion turbine 4 polytropically relaxed from point C to point I. During the relaxation, the second mass flow performs mechanical work which, since the waves of the liquefaction expansion turbine 4 and the compressor 1 are mechanically coupled to each other by means of a transmission (not shown), is fed to the compression process.
- first Rankine heat exchanger 8 of a two-stage Rankine machine 9 the first / lowest stage 10 with nitrogen (as a refrigerant) and the second stage 11 with operated at a low temperature boiling refrigerant.
- the first Rankine heat exchanger 8 communicates with the nitrogen of the first stage 10 of the Rankine machine 9, which is operated at the lowest temperature level.
- the compressed air is expanded in a main turbine 12 with connected power generator 13 from 200 bar to 1 bar.
- the turboexpander is designed in six stages and equipped with an intermediate heater (not shown) after each expansion stage. In the case of the six-stage version of the turboexpander, it is ensured that the temperature of the expanded air does not become lower than 230 K.
- Fig. 4 shows the associated temperature-entropy diagram (energy extraction / regasification).
- the two stages 10, 11 of the Rankine machine 9 each use two heat exchangers 8, 15, 16, wherein one of the heat exchangers is used for coupling to a lower temperature level and the other heat exchanger for coupling to a higher temperature level.
- the second Rankine heat exchanger 16 for coupling the two stages 10, 11 of the Rankine machine 9 together since the high temperature level of the first stage 10 corresponds approximately to the low temperature level of the second stage 11.
- the third Rankine heat exchanger 15 communicates with the ambient temperature level, which corresponds to the high temperature level of the second stage 11. Also conceivable is the cascading of more than two stages.
- the stages of the Rankine machine are each closed, d. h.,
- the output of the heat exchanger at the higher temperature level is connected to the input of the heat exchanger at the lower temperature level in each case via an expansion turbine 14, is performed at the relaxation work.
- the output of the heat exchanger at the low temperature level is connected to the input 17.1 of a condensate pump 17, which serves to return the refrigerant, and the input of the heat exchanger with the higher temperature level to the output 17.2 of the condensate pump 17.
- the expansion turbines 14 are each mechanically coupled to electrical generators 18. In the energy extraction both the electrical energy of the generators operated by the Rankine machine 18 and driven by the main turbine 12 generator 13 is fed back into the power network to be supplied.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Separation By Low-Temperature Treatments (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012101701 | 2012-03-01 | ||
DE102012104185 | 2012-05-14 | ||
DE102012104416A DE102012104416A1 (de) | 2012-03-01 | 2012-05-22 | Verfahren und Anordnung zur Speicherung von Energie |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2634383A1 EP2634383A1 (de) | 2013-09-04 |
EP2634383B1 true EP2634383B1 (de) | 2016-04-27 |
Family
ID=47900574
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13156878.4A Active EP2634383B1 (de) | 2012-03-01 | 2013-02-27 | Verfahren und Anordnung zur Speicherung von Energie |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP2634383B1 (pt) |
DE (1) | DE102012104416A1 (pt) |
DK (1) | DK2634383T3 (pt) |
ES (1) | ES2585090T3 (pt) |
HU (1) | HUE029505T2 (pt) |
PL (1) | PL2634383T3 (pt) |
PT (1) | PT2634383T (pt) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109630220A (zh) * | 2018-11-07 | 2019-04-16 | 清华大学 | 新型高密度空气储能发电系统 |
WO2022117407A1 (fr) * | 2020-12-03 | 2022-06-09 | IFP Energies Nouvelles | Système et procédé de stockage et de récupération d'énergie par gaz comprimé avec cycle de rankine |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103527274A (zh) * | 2013-10-23 | 2014-01-22 | 肖波 | 冷能液态空气(液氮)发动机体系 |
US10473029B2 (en) * | 2013-12-30 | 2019-11-12 | William M. Conlon | Liquid air power and storage |
WO2015123613A1 (en) * | 2014-02-14 | 2015-08-20 | Mada Energie Llc | Thermally charged liquid air energy storage systems, methods, and devices |
EP2930318A1 (de) * | 2014-04-11 | 2015-10-14 | Linde Aktiengesellschaft | Verfahren und Anlage zum Speichern und Rückgewinnen von Energie |
WO2016195968A1 (en) | 2015-06-01 | 2016-12-08 | Conlon William M | Part load operation of liquid air power and storage system |
WO2016195999A1 (en) | 2015-06-03 | 2016-12-08 | Conlon William M | Liquid air power and storage with carbon capture |
WO2016204893A1 (en) | 2015-06-16 | 2016-12-22 | Conlon William M | Cryogenic liquid energy storage |
WO2017069922A1 (en) | 2015-10-21 | 2017-04-27 | Conlon William M | High pressure liquid air power and storage |
CN105888742B (zh) * | 2016-06-02 | 2017-10-31 | 成都深冷液化设备股份有限公司 | 一种高效液空储能/释能系统 |
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2012
- 2012-05-22 DE DE102012104416A patent/DE102012104416A1/de not_active Withdrawn
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2013
- 2013-02-27 EP EP13156878.4A patent/EP2634383B1/de active Active
- 2013-02-27 HU HUE13156878A patent/HUE029505T2/en unknown
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- 2013-02-27 ES ES13156878.4T patent/ES2585090T3/es active Active
- 2013-02-27 DK DK13156878.4T patent/DK2634383T3/en active
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109630220A (zh) * | 2018-11-07 | 2019-04-16 | 清华大学 | 新型高密度空气储能发电系统 |
WO2022117407A1 (fr) * | 2020-12-03 | 2022-06-09 | IFP Energies Nouvelles | Système et procédé de stockage et de récupération d'énergie par gaz comprimé avec cycle de rankine |
FR3117164A1 (fr) * | 2020-12-03 | 2022-06-10 | IFP Energies Nouvelles | Système et procédé de stockage et de récupération d’énergie par gaz comprimé avec cycle de Rankine |
Also Published As
Publication number | Publication date |
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ES2585090T3 (es) | 2016-10-03 |
PT2634383T (pt) | 2016-08-16 |
DE102012104416A1 (de) | 2013-09-05 |
EP2634383A1 (de) | 2013-09-04 |
HUE029505T2 (en) | 2017-03-28 |
PL2634383T3 (pl) | 2016-11-30 |
DK2634383T3 (en) | 2016-08-15 |
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