EP2555867A4 - Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same - Google Patents

Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same

Info

Publication number: EP2555867A4
Authority: EP; European Patent Office
Prior art keywords: bea; same; gas streams; zeolite catalyst; mixed zeolite
Prior art date: 2010-04-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

EP11765158.8A

Other languages

German (de)

French (fr)

Other versions

EP2555867A1 (en

Inventor

Susanne Stiebels

Claudia Wendt

Torsten Neubauer

Edith Schneider

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF SE

Original Assignee

BASF SE

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2010-04-08

Filing date

2011-04-08

Publication date

2014-12-10

2011-04-08 Application filed by BASF SE filed Critical BASF SE

2011-04-08 Priority to EP11765158.8A priority Critical patent/EP2555867A4/en

2013-02-13 Publication of EP2555867A1 publication Critical patent/EP2555867A1/en

2014-12-10 Publication of EP2555867A4 publication Critical patent/EP2555867A4/en

Status Withdrawn legal-status Critical Current

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/46—Iron group metals or copper
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/80—Mixtures of different zeolites
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/7215—Zeolite Beta
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2067—Urea
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20738—Iron
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/92—Dimensions
- B01D2255/9205—Porosity
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Crystallography & Structural Chemistry (AREA)
Health & Medical Sciences (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Analytical Chemistry (AREA)
Environmental & Geological Engineering (AREA)
Biomedical Technology (AREA)
Combustion & Propulsion (AREA)
Catalysts (AREA)
Exhaust Gas After Treatment (AREA)

EP11765158.8A 2010-04-08 2011-04-08 Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same Withdrawn EP2555867A4 (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
EP11765158.8A EP2555867A4 (en)	2010-04-08	2011-04-08	Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
EP10159369		2010-04-08
PCT/IB2011/051526 WO2011125050A1 (en)	2010-04-08	2011-04-08	Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same
EP11765158.8A EP2555867A4 (en)	2010-04-08	2011-04-08	Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same

Publications (2)

Publication Number	Publication Date
EP2555867A1 EP2555867A1 (en)	2013-02-13
EP2555867A4 true EP2555867A4 (en)	2014-12-10

Family

ID=44762074

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP11765158.8A Withdrawn EP2555867A4 (en)	2010-04-08	2011-04-08	Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same

Country Status (9)

Country	Link
EP (1)	EP2555867A4 (en)
JP (1)	JP2013523442A (en)
KR (1)	KR20130091638A (en)
CN (1)	CN102958610A (en)
BR (1)	BR112012025744A2 (en)
CA (1)	CA2795522A1 (en)
MX (1)	MX2012011540A (en)
WO (1)	WO2011125050A1 (en)
ZA (1)	ZA201208258B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP6294127B2 (en) *	2014-03-31	2018-03-14	株式会社キャタラー	SCR catalyst and exhaust gas purification catalyst system
DE102015204012A1 (en) *	2015-03-05	2016-09-08	Clariant International Ltd.	SCR catalyst with improved adhesion
US11298692B2 (en) *	2017-10-09	2022-04-12	Umicore Ag & Co. Kg	Active SCR catalyst
WO2019198014A1 (en) *	2018-04-11	2019-10-17	Basf Corporation	Mixed zeolite-containing scr catalyst
CN109289508B (en) *	2018-10-24	2021-09-24	昆山工统环保科技有限公司	Preparation method of high-hydrophobicity zeolite material
CN109592687B (en) *	2018-12-03	2023-06-06	南京理工大学	Method for preparing porous silicon dioxide material by utilizing TOB

Citations (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5676912A (en) *	1995-02-22	1997-10-14	Mobil Oil Corporation	Process for exhaust gas NOx, CO, and hydrocarbon removal
US20060228283A1 (en) *	2005-02-28	2006-10-12	Catalytic Solutions, Inc.	Catalyst and method for reducing nitrogen oxides in exhaust streams with hydrocarbons or alcohols
CN101190866A (en) *	2006-11-21	2008-06-04	中国石油化工股份有限公司	Arene alkyl transferring and dealkylation reaction method of low ethyl benzene by-product
US20080286184A1 (en) *	2007-05-09	2008-11-20	N.E Chemcat Corporation	Selective catalytic reduction type catalyst, and exhaust gas purification equipment and purifying process of exhaust gas using the same
WO2009068289A2 (en) *	2007-11-28	2009-06-04	Süd-Chemie AG	Coating compostiion for diesel oxidation catalysts
US20090269265A1 (en) *	2008-04-28	2009-10-29	N.E. Chemcat Corporation	Exhaust gas purification method using selective reduction catalyst
US20090325786A1 (en) *	2006-08-31	2009-12-31	China Petroleum & Chemical Corporation	Hydrocarbon conversion catalyst

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
KR20010067096A (en) *	1999-08-25	2001-07-12	조안 엠. 젤사 ; 로버트 지. 호헨스타인 ; 도로시 엠. 보어	Novel adsorbents for preferential nitrogen adsorption from other gases
DE10001539B4 (en) *	2000-01-14	2006-01-19	Uhde Gmbh	Process for the removal of NOx and N2O
JP4425797B2 (en) *	2002-11-18	2010-03-03	株式会社アイシーティー	Exhaust gas purification catalyst manufacturing method and exhaust gas purification method
US20060088469A1 (en) *	2002-11-25	2006-04-27	Yara International Asa	Method for preparation and activation of multimetallic zeolite catalysts, a catalyst composition and application for n2o abatement
DE102006020158B4 (en) *	2006-05-02	2009-04-09	Argillon Gmbh	Extruded full catalyst and process for its preparation

2011
- 2011-04-08 EP EP11765158.8A patent/EP2555867A4/en not_active Withdrawn
- 2011-04-08 BR BR112012025744A patent/BR112012025744A2/en not_active IP Right Cessation
- 2011-04-08 WO PCT/IB2011/051526 patent/WO2011125050A1/en active Application Filing
- 2011-04-08 CA CA2795522A patent/CA2795522A1/en not_active Abandoned
- 2011-04-08 MX MX2012011540A patent/MX2012011540A/en unknown
- 2011-04-08 JP JP2013503212A patent/JP2013523442A/en active Pending
- 2011-04-08 KR KR1020127029118A patent/KR20130091638A/en not_active Application Discontinuation
- 2011-04-08 CN CN2011800268611A patent/CN102958610A/en active Pending
2012
- 2012-11-05 ZA ZA2012/08258A patent/ZA201208258B/en unknown

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5676912A (en) *	1995-02-22	1997-10-14	Mobil Oil Corporation	Process for exhaust gas NOx, CO, and hydrocarbon removal
US20060228283A1 (en) *	2005-02-28	2006-10-12	Catalytic Solutions, Inc.	Catalyst and method for reducing nitrogen oxides in exhaust streams with hydrocarbons or alcohols
US20090325786A1 (en) *	2006-08-31	2009-12-31	China Petroleum & Chemical Corporation	Hydrocarbon conversion catalyst
CN101190866A (en) *	2006-11-21	2008-06-04	中国石油化工股份有限公司	Arene alkyl transferring and dealkylation reaction method of low ethyl benzene by-product
US20080286184A1 (en) *	2007-05-09	2008-11-20	N.E Chemcat Corporation	Selective catalytic reduction type catalyst, and exhaust gas purification equipment and purifying process of exhaust gas using the same
WO2009068289A2 (en) *	2007-11-28	2009-06-04	Süd-Chemie AG	Coating compostiion for diesel oxidation catalysts
US20090269265A1 (en) *	2008-04-28	2009-10-29	N.E. Chemcat Corporation	Exhaust gas purification method using selective reduction catalyst

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2011125050A1 *

Also Published As

Publication number	Publication date
MX2012011540A (en)	2012-11-16
JP2013523442A (en)	2013-06-17
KR20130091638A (en)	2013-08-19
BR112012025744A2 (en)	2016-06-28
ZA201208258B (en)	2014-01-29
CN102958610A (en)	2013-03-06
WO2011125050A1 (en)	2011-10-13
CA2795522A1 (en)	2011-10-13
EP2555867A1 (en)	2013-02-13

Publication	Publication Date	Title
EP2555866A4 (en)	2014-12-10	Cu-cha/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same
EP2766119A4 (en)	2015-07-15	CU-CHA / FE-BEA MIXED ZEOLITE CATALYST AND METHOD FOR THE TREATMENT OF NOX IN GAS STREAMS
EP2268906A4 (en)	2014-05-07	Exhaust gas additive/treatment system and mixer for use therein
EP2310650A4 (en)	2015-05-27	Exhaust gas additive/treatment system and mixer for use therein
EP2687695A4 (en)	2015-01-21	Urea solution reformer and exhaust gas purifier using same
EP2555853A4 (en)	2014-04-16	DISORDERED MOLECULAR SIEVE SUPPORTS FOR THE SELECTIVE CATALYTIC REDUCTION OF NOx
IL225597A0 (en)	2013-06-27	Pharmaceutical composition, methods for treating and uses thereof
PL2540378T3 (en)	2017-05-31	Exhaust gas treatment system, and exhaust gas treatment method
PL2540379T3 (en)	2020-06-15	Exhaust gas treatment system, and exhaust gas treatment method
EP2808081A4 (en)	2015-08-26	Alumina material containing barium sulfate and exhaust gas purifying catalyst using same
PL2576019T3 (en)	2015-06-30	Method and device for eliminating nox and n2o
PL2729151T3 (en)	2021-10-18	Pharmaceutical composition, methods for treating and uses thereof
EP2659974A4 (en)	2014-12-17	Selective reduction catalyst, and exhaust gas purification device and exhaust gas purification method using same
EP2322274A4 (en)	2012-04-11	Exhaust gas purifying catalyst and method for producing the same
EP2407238A4 (en)	2014-02-12	Exhaust gas purifying catalyst, exhaust gas purifying apparatus using same, and method for purifying exhaust gas
HRP20181984T1 (en)	2019-01-25	System and method for the absorption of pollutants in gases
ZA201205261B (en)	2013-09-25	Ferrous zeolite, method for producing ferrous zeolites, and method for catalytically reducing nitrous oxides
HK1199856A1 (en)	2015-07-24	Gas mixer and gas mixing system
EP2402295A4 (en)	2013-06-12	Honeycomb structure and device for treating gas
EP2555867A4 (en)	2014-12-10	Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same
EP2583740A4 (en)	2014-01-15	Reducing-agent supply device and an exhaust gas nitrogen-removal system using the same
ZA201404564B (en)	2016-10-26	Composite oxide, method for producing the same, and catalyst for exhaust gas purification
IL214569A0 (en)	2011-09-27	Flue gas treatment system and the method using ammonia solution
PL2353704T3 (en)	2015-03-31	Apparatus and method for mixing two gas streams
PL2626132T3 (en)	2016-12-30	Exhaust gas purification filter, and method for producing same

Legal Events

Date	Code	Title	Description
2013-01-11	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
2013-02-13	17P	Request for examination filed	Effective date: 20121108
2013-02-13	AK	Designated contracting states	Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
2013-02-20	RIN1	Information on inventor provided before grant (corrected)	Inventor name: STIEBELS, SUSANNE Inventor name: NEUBAUER, TORSTEN Inventor name: SCHNEIDER, EDITH Inventor name: WENDT, CLAUDIA
2013-07-17	DAX	Request for extension of the european patent (deleted)
2014-12-10	A4	Supplementary search report drawn up and despatched	Effective date: 20141112
2014-12-10	RIC1	Information provided on ipc code assigned before grant	Ipc: B01J 29/46 20060101ALN20141105BHEP Ipc: B01J 29/80 20060101AFI20141105BHEP Ipc: B01J 29/76 20060101ALN20141105BHEP
2017-03-10	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN
2017-04-12	18D	Application deemed to be withdrawn	Effective date: 20161101