EP2513562B1 - Burner for a turbine - Google Patents
Burner for a turbine Download PDFInfo
- Publication number
- EP2513562B1 EP2513562B1 EP10786994.3A EP10786994A EP2513562B1 EP 2513562 B1 EP2513562 B1 EP 2513562B1 EP 10786994 A EP10786994 A EP 10786994A EP 2513562 B1 EP2513562 B1 EP 2513562B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fuel
- burner
- fuel feed
- inlet passage
- fuel supply
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000000446 fuel Substances 0.000 claims description 157
- 239000007800 oxidant agent Substances 0.000 claims description 44
- 238000002485 combustion reaction Methods 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 16
- 230000001590 oxidative effect Effects 0.000 description 25
- 241001156002 Anthonomus pomorum Species 0.000 description 6
- 239000002737 fuel gas Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/02—Continuous combustion chambers using liquid or gaseous fuel characterised by the air-flow or gas-flow configuration
- F23R3/04—Air inlet arrangements
- F23R3/10—Air inlet arrangements for primary air
- F23R3/12—Air inlet arrangements for primary air inducing a vortex
- F23R3/14—Air inlet arrangements for primary air inducing a vortex by using swirl vanes
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/28—Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply
- F23R3/286—Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply having fuel-air premixing devices
Definitions
- the invention relates to a burner for a turbine, and more particularly to a burner for a turbine provided with a means for premixing oxidant and fuel.
- premix burner In order to achieve low emission levels, turbines such as e.g. Gas turbines called “premix burner” or “Premix Burner” used.
- premix technology the mixing process of fuel and oxidant, such as air, is decoupled from the actual combustion process, i. preceded by this. This allows the peak combustion temperatures to be lowered.
- the residence time of the fuel-oxidant mixture e.g., fuel-air mixture
- NOx especially thermal NOx
- premix burners in the atmospheric combustion and combustion under pressure in use. Also in the field of gas turbines different burners are used.
- the burner has a cylindrical combustion chamber for gaseous or liquid fuel and a Haupindindüsung.
- the combustion chamber is in an axial direction of the burner bounded on one side by a burner bottom and radially by a flame tube.
- the main injection is used to inject a premixed fuel-air mixture. Injection takes place radially to a burner longitudinal axis via main nozzles which open into a radial swirl generator.
- the radial swirl generator is arranged between the burner base and the flame tube and causes the fuel-air mixture to be subjected to a swirl pulse and swirled into the combustion chamber.
- US 5,394,688 and EP 0 982 545 A2 show burner for turbines according to the preamble of claim 1.
- the invention has for its object to provide a burner for a turbine, in a simple and cost-effective manner an extremely homogeneous premix to be introduced into a combustion chamber of the burner fuel-oxidizer mixture, such as For example, a fuel-air mixture is achieved.
- a burner for a turbine comprises: a flame tube, in which a combustion chamber is formed, a jacket, which surrounds the flame tube from radially outside with a predetermined distance thereof, so that an oxidant collecting space is formed between flame tube and jacket, a burner bottom defining the oxidizer plenum and the combustion chamber at an axial end of the burner, and a swirler axially the burner bottom and is arranged radially adjacent to the oxidant collecting chamber axially between the flame tube and the burner bottom, for supplying a fuel-oxidant mixture into the combustion chamber, wherein the swirl generator along with a circumferential direction of the burner Having circumferentially spaced plurality of vanes, so that the respective distances between the vanes form a plurality of in their course each having a tangential component having radial inlet passages to the combustion chamber, wherein in each Inlasströmungs Scheme at least some of the plurality of inlet passages is provided in each case one Brennstoffzu Switzerland which extends with respect
- air is provided as the oxidizing agent, which is fed at atmospheric or elevated pressure into the oxidant collecting space.
- the freedom of design of the fuel dispensing opening (s), which is preferably formed as a bore, and the arbitrary positioning of the BrennstoffzuGermanrohre and the Brennstoffausgabeö réelle (s) within the respective Einlassströmungs Kunststoffe or on the respective fuel supply pipes, can be an optimal premix of fuel (Eg fuel gas) and oxidizing agents (eg air) can be achieved.
- the fuel delivery ports may be sized and shaped.
- all inlet passages are each provided with a fuel feed pipe.
- At least one of the fuel supply tubes is in the oxidant flow direction directly in front of the respective inlet passage, that is arranged at the beginning of Einlasströmungs Kunststoffs.
- This embodiment of the invention represents a further advantageous variant for the arrangement of one or more or all BrennstoffzuFINrohre, wherein the mixing length or mixing distance of fuel and oxidant is maximally extended.
- At least one of the fuel supply pipes or a plurality or all of the fuel supply pipes is arranged centrally in the respective intake passage with respect to the longitudinal central axis of the respective intake passage.
- At least one of the fuel supply pipes has a plurality of fuel discharge openings spaced along the length of the fuel supply pipe.
- the homogeneous mixing of fuel and oxidant can be further improved.
- the fuel supply pipes are each provided with a plurality of fuel discharge openings spaced apart from each other along the length of the fuel supply pipes.
- At least one of the fuel supply pipes has two fuel discharge openings which are arranged at the same position with respect to the length of the fuel supply pipe, so that fuel can be dispensed from the fuel supply pipe via these two fuel discharge openings with two opposing directional components.
- the oxidant flow on both sides of the fuel supply pipe is utilized for fluidizing the fuel, thereby further improving homogeneous mixing of fuel and oxidant.
- the fuel supply pipes each have two fuel discharge openings, which are arranged at the same position with respect to the length of the fuel supply pipe, so that fuel can be dispensed from the fuel supply pipe via these two fuel discharge openings with two opposing directional components.
- each fuel discharge opening of a respective fuel supply pipe has such a fuel discharge port arranged at the same position with respect to the length of the fuel supply pipe to dispose its fuel with an opposite direction component.
- the two fuel discharge openings are diametrically opposed to each other or include respective longitudinal center axes of the two fuel discharge openings at an obtuse angle.
- the Brennstoffzu focusedrohre each have a cylindrical cross-section or a wing-shaped cross section or other suitable for optimum turbulence cross sections.
- all fuel supply pipes can have the same cross-sectional shape.
- Embodiments in which groups of fuel supply pipes are formed, wherein within a group all the fuel supply pipes have the same cross-sectional shape, but the groups have different cross-sectional shapes, are also possible.
- the airfoil shape may prove advantageous for reducing direct mixing in the pipe wake, which may be particularly necessary with reactive fuels (such as hydrogen).
- the fuel supply pipes are each detachably mounted so that each fuel supply pipe formed according to a predetermined fuel-in configuration is individually replaceable with a fuel supply pipe according to another predetermined fuel-in configuration when needed.
- the burner according to the invention is suitable for the use of fuel gas as fuel.
- the burner according to the invention can also be operated with liquid fuel, wherein, if necessary, special nozzles should be inserted into the fuel discharge openings.
- the use of the central fuel supply tubes in the inlet passages of the swirler enables optimum mixtures of fuel (e.g., fuel gas) and oxidant (e.g., air). This low emissions can be achieved.
- fuel e.g., fuel gas
- oxidant e.g., air
- by customizing the fuel delivery apertures and / or positioning the fuel supply tubes one may rely on locally different oxidant distributions, such as e.g. locally different air distributions, be reacted.
- Due to the central replaceable fuel supply pipes solution of the invention is very inexpensive.
- Fig.1 shows the structure of a burner 1 of a gas turbine (not fully shown) according to an embodiment of the invention.
- the burner 1 has a flame tube 10, in which a combustion chamber 11 is formed, and a tubular jacket 20, the flame tube 10 from radially outward encloses it with a predetermined distance, so that between the flame tube 10 and shell 20, an oxidant-collecting space 21 is formed.
- fuel gas is provided, and as the oxidizing agent for the fuel gas, atmospheric air is provided, which is compressed by a compressor (not shown) and then supplied to the oxidant collecting space 21.
- the burner 1 further includes a burner bottom 30 delimiting the oxidizer plenum 21 and the combustion chamber 11 at an axial end of the combustor 1, and a swirler 40 axially axially adjacent to the combustor bottom 30 and radially adjacent to the oxidizer plenum 21 Flame tube 10 and the burner bottom 30 is arranged for supplying a fuel-oxidant mixture BOG in the combustion chamber eleventh
- the swirl generator 40 has a plurality of (here eight) vanes 41, each circumferentially spaced apart along a circumferential direction UR of the burner 1.
- the guide vanes 41 are each shaped and arranged in such a way that the respective distances between the guide vanes 41 form a plurality (in this case eight) of radial inlet passages 42 each having a tangential component in their course towards the combustion chamber 11.
- a fuel supply pipe 43a, 43b, 43c, 43d each having a length in an axial direction AR (see FIG Fig.1 ) of the burner 1 and across an oxidant flow direction OR through the respective inlet passage 42.
- Fig.2 only four of the eight inlet passages 42 a Brennstoffzu Glassrohr 43a, 43b, 43c, 43d is shown, according to not shown embodiments of the invention may be provided in more or less or in all inlet passages 42 respective fuel supply pipes 43a, 43b, 43c, 43d.
- each fuel supply pipe 43a, 43b, 43c, 43d has in its wall at least one fuel discharge opening 44, 45 radial to the fuel supply pipe 43a, 43b, 43c, 43d via which fuel BS has a directional component transverse to the oxidant flow direction OS respective inlet passage 42 is einmischbar.
- each fuel dispensing opening 44, 45 is formed as a bore or as a nozzle insert.
- one or more or all fuel supply pipes 43a, 43b, 43d may be disposed directly in the respective intake passages 42.
- the fuel supply pipes 43a, 43b, 43d may be disposed within the respective intake passages 42 at different positions along the length of the respective intake passages 42.
- one, several or all of the fuel supply pipes 43c in the oxidant flow direction OS can also be arranged directly in front of the respective inlet passages 42 (ie at the inlet of the respective inlet passages 42 partially or completely in the oxidant collecting chamber 21).
- one or more or all fuel supply pipes 43a, 43b, 43c may be arranged centrally in the respective intake passages 42 with respect to longitudinal center axes L of the respective intake passages 42.
- one, several or all of the fuel supply pipes 43d are arranged eccentrically with respect to the longitudinal center axes L of the respective inlet passages 42.
- one or more or all of the fuel supply pipes 43a, 43b, 43c, 43d may have a plurality of fuel discharge openings 44, 45 spaced along the respective length of the fuel supply pipes 43a, 43b, 43c, 43d [variant a ) in Figure 4 ].
- one, several or all fuel supply pipes 43a, 43b, 43c, 43d may have only a single fuel discharge opening 44, 45 with respect to the respective length of the fuel supply pipes 43a, 43b, 43c, 43d [variant b] in FIG Figure 4 ].
- Figure 3 can be one, several or all of the central fuel supply pipes 43a, 43b, 43c (in Figure 3 43a-c) and also one, several or all off-center fuel supply pipes 43d (in FIG Figure 3 not shown) have two fuel discharge openings 44, 45, which are arranged at the same position with respect to the length of the Brennstoffzu melts, so that these two fuel discharge openings 44, 45 fuel BS with two opposite direction components (as indicated by the oppositely directed exit arrows for the fuel BS ) can be dispensed from the respective fuel supply pipe 43a, 43b, 43c, 43d.
- the two fuel dispensing openings 44, 45 can be located diametrically opposite one another in the cross section of the respective fuel feed pipe 43a, 43b, 43c, 43d [variant a) in FIG Figure 3 ] or can each longitudinal central axes L1, L2 of the two fuel discharge openings 44, 45 an obtuse angle ⁇ (45 ° ⁇ ⁇ 180 °) with each other include [variants b) and c) in Figure 3 ].
- the fuel supply pipes 43a, 43b, 43c, 43d each have a cylindrical cross section.
- the fuel supply pipes 43a, 43b, 43c, 43d may also have a wing-shaped cross section or other cross-sectional shapes suitable for homogeneous mixing of oxidant and fuel.
- a hydrofoil shape is for example in DE 38 19 898 A1 in Fig.2 with reference to guide vanes.
- the fuel supply pipes 43a, 43b, 43c, 43d are each detachably mounted in the burner 1 so that each fuel supply pipe formed according to a predetermined fuel mixing configuration (position of the fuel supply pipe in the intake passage, number and arrangement of the fuel discharge ports, cross sectional shape of the fuel supply pipe) 43a, 43b, 43c, 43d, when needed, is individually replaceable with a fuel supply tube 43a, 43b, 43c, 43d according to another predetermined fuel mixing configuration.
- the fuel supply pipes 43a, 43b, 43c, 43d (in FIG Figure 4 with 43a-d) as in Figure 4 shown releasably inserted into corresponding openings in the burner bottom 30, wherein each Brennstoffzu semiconductorrohr 43 a, 43 b, 43 c, 43 d at a longitudinal end thereof a flange or head portion 46, 47th which abuts on the side facing away from the swirl generator 40 side of the burner base 30 at this and is screwed by means of screws (not shown) with the burner bottom 30, for example.
- each fuel feed tube 43a, 43b, 43c, 43d is naturally fluidly connected to a fuel source (not shown), such as a fuel gas tank, via respective conduits and control valves (both not shown).
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Gas Burners (AREA)
- Feeding And Controlling Fuel (AREA)
- Combustion Of Fluid Fuel (AREA)
Description
Die Erfindung betrifft einen Brenner für eine Turbine, und insbesondere einen mit einer Einrichtung zum Vormischen von Oxidationsmittel und Brennstoff versehenen Brenner für eine Turbine.The invention relates to a burner for a turbine, and more particularly to a burner for a turbine provided with a means for premixing oxidant and fuel.
Um niedrige Emissionswerte zu erreichen, werden in Turbinen wie z.B. Gasturbinen sogenannte "Vormisch-Brenner" bzw. "Premix Burner" eingesetzt. Durch den Einsatz der Vormisch-Technologie wird der Mischprozess von Brennstoff und Oxidationsmittel wie Luft vom eigentlichen Verbrennungsprozess entkoppelt, d.h. diesem vorangestellt. Dadurch können die Spitzentemperaturen bei der Verbrennung gesenkt werden. Gleichzeitig kann die Aufenthaltszeit des Brennstoff-Oxidationsmittel-Gemisches (z.B. Brennstoff-Luft-Gemisch) in der Reaktionszone verkürzt werden. Damit wird insbesondere die Bildung von NOx (besonders thermisches NOx) reduziert. Es sind verschiedene "Vormisch-Brenner" bei der atmosphärischen Verbrennung und bei der Verbrennung unter Druck im Einsatz. Auch auf dem Gebiet der Gasturbinen werden verschiedene Brenner eingesetzt. Bei einem optimalen Brenner sollte die Verbrennung in einem großen Betriebsbereich stabil, kontrolliert, schadstoffarm und möglichst vollständig ablaufen. Hierbei steht immer wieder die Güte der Mischung von Brennstoff und Oxidationsmittel im Mittelpunkt des Interesses. Die Mischung ist ausschlaggebend für die lokale Verbrennungstemperatur und damit für die Reaktionsprodukte, d.h. die Emissionen. Deshalb müssen der Ort und die Aerodynamik der Brennstoffeindüsung sorgfältig gewählt werden.In order to achieve low emission levels, turbines such as e.g. Gas turbines called "premix burner" or "Premix Burner" used. By using premix technology, the mixing process of fuel and oxidant, such as air, is decoupled from the actual combustion process, i. preceded by this. This allows the peak combustion temperatures to be lowered. At the same time, the residence time of the fuel-oxidant mixture (e.g., fuel-air mixture) in the reaction zone may be shortened. In particular, this reduces the formation of NOx (especially thermal NOx). There are various "premix burners" in the atmospheric combustion and combustion under pressure in use. Also in the field of gas turbines different burners are used. With an optimal burner, combustion in a large operating range should be stable, controlled, low in emissions and as complete as possible. Here again and again the quality of the mixture of fuel and oxidant is the focus of interest. The mixture is crucial for the local combustion temperature and thus for the reaction products, i. the emissions. Therefore, the location and aerodynamics of the fuel injection must be carefully chosen.
Weitere mit einer Einrichtung zum Vormischen von Oxidationsmittel und Brennstoff versehene Brenner sind in
Dies wird mit einem Brenner gemäß Anspruch 1 erreicht. Weiterbildungen der Erfindung sind in den abhängigen Ansprüchen definiert.This is achieved with a burner according to claim 1. Further developments of the invention are defined in the dependent claims.
Gemäß der Erfindung weist ein Brenner für eine Turbine auf: ein Flammrohr, in dem ein Brennraum ausgebildet ist, einen Mantel, der das Flammrohr von radial außen mit einem vorbestimmten Abstand davon umschließt, so dass zwischen Flammrohr und Mantel ein Oxidationsmittel-Sammelraum gebildet ist, einen Brennerboden, der den Oxidationsmittel-Sammelraum und den Brennraum an einem Axialende des Brenners begrenzt, und einen Drallerzeuger, der axial an den Brennerboden und radial an den Oxidationsmittel-Sammelraum angrenzend axial zwischen Flammrohr und Brennerboden angeordnet ist, zum Zuführen eines Brennstoff-Oxidationsmittel-Gemisches in den Brennraum, wobei der Drallerzeuger eine entlang einer Umfangsrichtung des Brenners jeweils mit umfänglichem Abstand voneinander angeordnete Mehrzahl von Leitschaufeln aufweist, so dass die jeweiligen Abstände zwischen den Leitschaufeln eine Mehrzahl von in ihrem Verlauf jeweils eine Tangentialkomponente aufweisenden radialen Einlasspassagen zum Brennraum hin bilden, wobei in einem jeweiligen Einlasströmungsbereich wenigstens einiger der Mehrzahl von Einlasspassagen jeweils ein Brennstoffzuführrohr vorgesehen ist, welches sich bezüglich seiner Länge in einer Axialrichtung des Brenners und quer zu einer Oxidationsmittel-Strömungsrichtung durch die jeweilige Einlasspassage hindurch erstreckt, und wobei jedes Brennstoffzuführrohr in seiner Wandung wenigstens eine bezüglich des Brennstoffzuführrohrs radiale Brennstoffausgabeöffnung aufweist, über die Brennstoff mit einer quer zur Oxidationsmittel-Strömungsrichtung verlaufenden Richtungskomponente in die jeweilige Einlasspassage einmischbar ist und wenigstens eines der Brennstoffzuführrohre bezüglich der Längsmittelachse der jeweiligen Einlasspassage außermittig in der jeweiligen Einlasspassage angeordnet ist. Gemäß der Erfindung ist diese Anordnung eines oder mehrerer oder aller Brennstoffzuführrohre vorteilhaft, da die jeweilige außermittige Position in der Einlasspassage quer zu deren Längsmittelachse frei wählbar und damit die Verwirbelungsstärke des Brennstoffs frei veränderbar ist.According to the invention, a burner for a turbine comprises: a flame tube, in which a combustion chamber is formed, a jacket, which surrounds the flame tube from radially outside with a predetermined distance thereof, so that an oxidant collecting space is formed between flame tube and jacket, a burner bottom defining the oxidizer plenum and the combustion chamber at an axial end of the burner, and a swirler axially the burner bottom and is arranged radially adjacent to the oxidant collecting chamber axially between the flame tube and the burner bottom, for supplying a fuel-oxidant mixture into the combustion chamber, wherein the swirl generator along with a circumferential direction of the burner Having circumferentially spaced plurality of vanes, so that the respective distances between the vanes form a plurality of in their course each having a tangential component having radial inlet passages to the combustion chamber, wherein in each Inlasströmungsbereich at least some of the plurality of inlet passages is provided in each case one Brennstoffzuführrohr which extends with respect to its length in an axial direction of the burner and transversely to an oxidant flow direction through the respective inlet passage, and wherein each fuel feed tube has in its wall at least one with respect to the Brennstoffzuführrohrs radial fuel discharge opening, via the fuel with a transverse to the Oxidationsmittel- Flow direction extending direction component is einmischbar in the respective inlet passage and at least one of the fuel supply pipes with respect to the Längsmittelach se of the respective intake passage is arranged off-center in the respective intake passage. According to the invention, this arrangement of one or more or all Brennstoffzuführrohre is advantageous because the respective eccentric position in the inlet passage transverse to the longitudinal central axis freely selectable and thus the turbulence of the fuel is freely changeable.
Bevorzugt ist als Oxidationsmittel Luft vorgesehen, welche mit atmosphärischem oder mit erhöhtem Druck in den Oxidationsmittel-Sammelraum eingespeist wird.Preferably, air is provided as the oxidizing agent, which is fed at atmospheric or elevated pressure into the oxidant collecting space.
Dadurch, dass bei dem erfindungsgemäßen Brenner die Brennstoffeindüsung innerhalb der Einlasspassagen bzw. Luftkanäle des Drallerzeugers durch einzelne Brennstoffzuführrohre mit einer quer zur Oxidationsmittel-Strömungsrichtung verlaufenden Richtungskomponente erfolgt, wird auf einfache und kostengünstige Weise eine äußerst homogene Vormischung des in die Brennkammer des Brenners einzubringenden Brennstoff-Oxidationsmittel-Gemisches, wie z.B. eines Brennstoff-Luft-Gemisches, erzielt.Due to the fact that in the burner according to the invention the fuel injection takes place inside the inlet passages or air passages of the swirl generator through individual fuel supply pipes with a directional component running transversely to the oxidant flow direction, an extremely homogeneous premix of the catalyst into the combustion chamber of the swirl generator is produced in a simple and cost-effective manner Brenners introduced fuel-oxidizer mixture, such as a fuel-air mixture achieved.
Durch die freie Gestaltungsmöglichkeit der Brennstoffausgabeöffnung(en), welche bevorzugt als Bohrung ausgebildet ist bzw. sind, und die frei wählbare Positionierung der Brennstoffzuführrohre und der Brennstoffausgabeöffnung(en) innerhalb der jeweiligen Einlasströmungsbereiche bzw. an den jeweiligen Brennstoffzuführrohren, kann eine optimale Vormischung von Brennstoff (z.B. Brenngas) und Oxydationsmittel (z.B. Luft) erreicht werden. Sofern sich die Brennstoffzusammensetzung ändert, können die Brennstoffausgabeöffnungen in Größe und Form angepasst werden.The freedom of design of the fuel dispensing opening (s), which is preferably formed as a bore, and the arbitrary positioning of the Brennstoffzuführrohre and the Brennstoffausgabeöffnung (s) within the respective Einlassströmungsbereiche or on the respective fuel supply pipes, can be an optimal premix of fuel (Eg fuel gas) and oxidizing agents (eg air) can be achieved. As the fuel composition changes, the fuel delivery ports may be sized and shaped.
Gemäß einer Ausführungsform der Erfindung sind alle Einlasspassagen jeweils mit einem Brennstoffzuführrohr versehen.According to one embodiment of the invention, all inlet passages are each provided with a fuel feed pipe.
Dies befördert auf vorteilhafte Weise eine besonders homogene Vermischung von Brennstoff und Oxidationsmittel vor der Einbringung in die Brennkammer.This advantageously promotes particularly homogeneous mixing of fuel and oxidant prior to introduction into the combustion chamber.
Gemäß noch einer weiteren Ausführungsform der Erfindung ist wenigstens eines der Brennstoffzuführrohre in Oxidationsmittel-Strömungsrichtung direkt vor der jeweiligen Einlasspassage, d.h. am Beginn des Einlasströmungsbereichs, angeordnet.According to yet another embodiment of the invention, at least one of the fuel supply tubes is in the oxidant flow direction directly in front of the respective inlet passage, that is arranged at the beginning of Einlasströmungsbereichs.
Diese Ausgestaltung der Erfindung stellt eine weitere vorteilhafte Variante für die Anordnung eines oder mehrerer oder aller Brennstoffzuführrohre dar, wobei die die Vermischungslänge bzw. Mischstrecke von Brennstoff und Oxidationsmittel maximal ausgedehnt ist.This embodiment of the invention represents a further advantageous variant for the arrangement of one or more or all Brennstoffzuführrohre, wherein the mixing length or mixing distance of fuel and oxidant is maximally extended.
Gemäß einer Ausführungsform der Erfindung ist wenigstens eines der Brennstoffzuführrohre oder sind mehrere oder alle Brennstoffzuführrohre bezüglich der Längsmittelachse der jeweiligen Einlasspassage mittig in der jeweiligen Einlasspassage angeordnet.According to an embodiment of the invention, at least one of the fuel supply pipes or a plurality or all of the fuel supply pipes is arranged centrally in the respective intake passage with respect to the longitudinal central axis of the respective intake passage.
Gemäß einer weiteren Ausführungsform der Erfindung weist wenigstens eines der Brennstoffzuführrohre eine Mehrzahl von Brennstoffausgabeöffnungen auf, die entlang der Länge des Brennstoffzuführrohrs mit Abstand voneinander angeordnet sind.According to another embodiment of the invention, at least one of the fuel supply pipes has a plurality of fuel discharge openings spaced along the length of the fuel supply pipe.
Mit dieser Ausgestaltung der Erfindung lässt sich die homogene Vermischung von Brennstoff und Oxidationsmittel noch weiter verbessern. Bevorzugt sind daher mehrere oder alle Brennstoffzuführrohre jeweils mit einer Mehrzahl von entlang der Länge der Brennstoffzuführrohre jeweils mit Abstand voneinander angeordneten Brennstoffausgabeöffnungen versehen.With this embodiment of the invention, the homogeneous mixing of fuel and oxidant can be further improved. Preferably, therefore, several or all of the fuel supply pipes are each provided with a plurality of fuel discharge openings spaced apart from each other along the length of the fuel supply pipes.
Gemäß noch einer weiteren Ausführungsform der Erfindung weist wenigstens eines der Brennstoffzuführrohre zwei Brennstoffausgabeöffnungen auf, die bezüglich der Länge des Brennstoffzuführrohrs an gleicher Position angeordnet sind, so dass über diese beiden Brennstoffausgabeöffnungen Brennstoff mit zwei einander entgegengesetzten Richtungskomponenten aus dem Brennstoffzuführrohr ausgebbar ist.According to yet another embodiment of the invention, at least one of the fuel supply pipes has two fuel discharge openings which are arranged at the same position with respect to the length of the fuel supply pipe, so that fuel can be dispensed from the fuel supply pipe via these two fuel discharge openings with two opposing directional components.
Gemäß dieser Ausgestaltung der Erfindung wird durch die gegensinnige Ausgabe des Brennstoffs in die Einlasspassage die Oxidationsmittelströmung beidseitig des Brennstoffzuführrohrs zum Verwirbeln des Brennstoffs genutzt und damit die homogene Vermischung von Brennstoff und Oxidationsmittel weiter verbessert.According to this embodiment of the invention, by oppositely outputting the fuel into the intake passage, the oxidant flow on both sides of the fuel supply pipe is utilized for fluidizing the fuel, thereby further improving homogeneous mixing of fuel and oxidant.
Bevorzugt weisen mehrere oder alle Brennstoffzuführrohre jeweils zwei Brennstoffausgabeöffnungen auf, die bezüglich der Länge des Brennstoffzuführrohrs an gleicher Position angeordnet sind, so dass über diese beiden Brennstoffausgabeöffnungen Brennstoff mit zwei einander entgegengesetzten Richtungskomponenten aus dem Brennstoffzuführrohr ausgebbar ist.Preferably, several or all of the fuel supply pipes each have two fuel discharge openings, which are arranged at the same position with respect to the length of the fuel supply pipe, so that fuel can be dispensed from the fuel supply pipe via these two fuel discharge openings with two opposing directional components.
Noch bevorzugter weist jede Brennstoffausgabeöffnung eines jeweiligen Brennstoffzuführrohr eine solche bezüglich der Länge des Brennstoffzuführrohrs an gleicher Position angeordnete ihren Brennstoff mit einer entgegengesetzten Richtungskomponente ausgebende Brennstoffausgabeöffnung auf.More preferably, each fuel discharge opening of a respective fuel supply pipe has such a fuel discharge port arranged at the same position with respect to the length of the fuel supply pipe to dispose its fuel with an opposite direction component.
Neben optimalen "Standard-Positionen" können natürlich auch individuelle Optimierungen bezüglich Emissionen und Rückzündverhalten -je nach Brennstofferfolgen.In addition to optimal "standard positions" can of course also individual optimizations in terms of emissions and Rückzündverhalten- depending on fuel consequences.
Gemäß weiteren Ausführungsformen der Erfindung liegen im Querschnitt des jeweiligen Brennstoffzuführrohrs gesehen die beiden Brennstoffausgabeöffnungen einander diametral gegenüber oder schließen jeweilige Längsmittelachsen der beiden Brennstoffausgabeöffnungen einen stumpfen Winkel miteinander ein.According to further embodiments of the invention, as seen in cross section of the respective fuel supply pipe, the two fuel discharge openings are diametrically opposed to each other or include respective longitudinal center axes of the two fuel discharge openings at an obtuse angle.
Auch mit dieser Ausgestaltung der Erfindung können auf einfache und effiziente Weise die Stärke der Verwirbelung und des Mitreißens des Brennstoffs im Oxidationsmittel beeinflusst und damit für die jeweilige Anwendung optimiert werden.Also with this embodiment of the invention can in a simple and efficient way, the strength of the turbulence and the entrainment of the fuel in the Oxidized and thus optimized for the particular application.
Gemäß weiteren Ausführungsformen der Erfindung weisen die Brennstoffzuführrohre jeweils einen zylindrischen Querschnitt oder einen tragflügelförmigen Querschnitt oder andere für eine optimale Verwirbelung geeignete Querschnitte auf. Gemäß der Erfindung können alle Brennstoffzuführrohre die gleiche Querschnittsform aufweisen. Ausführungsformen, bei denen Gruppen von Brennstoffzuführrohren gebildet sind, wobei innerhalb einer Gruppe alle Brennstoffzuführrohre die gleiche Querschnittsform aufweisen, jedoch die Gruppen unterschiedliche Querschnittsformen aufweisen, sind ebenfalls möglich.According to further embodiments of the invention, the Brennstoffzuführrohre each have a cylindrical cross-section or a wing-shaped cross section or other suitable for optimum turbulence cross sections. According to the invention, all fuel supply pipes can have the same cross-sectional shape. Embodiments in which groups of fuel supply pipes are formed, wherein within a group all the fuel supply pipes have the same cross-sectional shape, but the groups have different cross-sectional shapes, are also possible.
Beispielsweise kann sich die Tragflügelform als zur Reduzierung einer direkten Mischung im Rohrnachlauf vorteilhaft erweisen, was besonders bei reaktiven Brennstoffen (wie z.B. Wasserstoff) notwendig sein kann.For example, the airfoil shape may prove advantageous for reducing direct mixing in the pipe wake, which may be particularly necessary with reactive fuels (such as hydrogen).
Gemäß noch einer Ausführungsform der Erfindung sind die Brennstoffzuführrohre jeweils lösbar montiert, so dass jedes gemäß einer vorbestimmten Brennstoffeinmisch-Konfiguration ausgebildete Brennstoffzuführrohr im Bedarfsfall einzeln gegen ein Brennstoffzuführrohr gemäß einer anderen vorbestimmten Brennstoffeinmisch-Konfiguration austauschbar ist.According to another embodiment of the invention, the fuel supply pipes are each detachably mounted so that each fuel supply pipe formed according to a predetermined fuel-in configuration is individually replaceable with a fuel supply pipe according to another predetermined fuel-in configuration when needed.
Durch die einfache Austauschbarkeit der Brennstoffzuführrohre kann eine einfache und schnelle Anpassung des Brenners bei einem Brennstoffwechsel durchgeführt werden. Typischerweise eignet sich der erfindungsgemäße Brenner für den Einsatz von Brenngas als Brennstoff. Der erfindungsgemäße Brenner kann jedoch auch mit flüssigem Brennstoff betrieben werden, wobei ggf. spezielle Düsen in die Brennstoffausgabeöffnungen eingesetzt werden sollten.Due to the simple interchangeability of the fuel supply pipes, a simple and rapid adaptation of the burner during a fuel change can be carried out. Typically, the burner according to the invention is suitable for the use of fuel gas as fuel. However, the burner according to the invention can also be operated with liquid fuel, wherein, if necessary, special nozzles should be inserted into the fuel discharge openings.
Durch den Einsatz der zentralen Brennstoffzuführrohre in den Einlasspassagen des Drallerzeugers (Swirlers) sind optimale Mischungen von Brennstoff (z.B. Brenngas) und Oxidationsmittel (z.B. Luft) möglich. Damit können niedrige Emissionswerte erreicht werden. Gleichzeitig kann durch die individuelle Gestaltung der Brennstoffausgabeöffnungen und/oder Positionierung der Brennstoffzuführrohre auf lokal unterschiedliche Oxidationsmittelverteilungen, wie z.B. lokal unterschiedliche Luftverteilungen, reagiert werden. Durch die zentralen austauschbaren Brennstoffzuführrohre ist die erfindungsgemäße Lösung sehr kostengünstig.The use of the central fuel supply tubes in the inlet passages of the swirler enables optimum mixtures of fuel (e.g., fuel gas) and oxidant (e.g., air). This low emissions can be achieved. At the same time, by customizing the fuel delivery apertures and / or positioning the fuel supply tubes, one may rely on locally different oxidant distributions, such as e.g. locally different air distributions, be reacted. Due to the central replaceable fuel supply pipes solution of the invention is very inexpensive.
Im Folgenden wird die Erfindung anhand bevorzugter Ausführungsformen und unter Bezugnahme auf die beigefügten Figuren detaillierter beschrieben.
- Fig.1
- zeigt in einer schematischen Längsschnittansicht den Aufbau eines Brenners einer Gasturbine gemäß einer Ausführungsform der Erfindung.
- Fig.2
- zeigt eine schematische Querschnittsansicht eines Teils des Brenners von
Fig. 1 , gesehen entlang einer Linie A-A inFig.1 . - Fig.3
- zeigt in vergrößerten Teilansichten einer Einlasspassage des Brenners von
Fig.2 drei mögliche Konfigurationsvarianten eines Brennstoffzuführrohrs. - Fig.4
- zeigt zwei mögliche Konfigurationsvarianten eines Brennstoffzuführrohrs in einer Einlasspassage des erfindungsgemäßen Brenners, gesehen entlang einer Linie B-B in
Fig.2 .
- Fig.1
- shows in a schematic longitudinal sectional view of the structure of a burner of a gas turbine according to an embodiment of the invention.
- Fig.2
- shows a schematic cross-sectional view of a portion of the burner of
Fig. 1 , seen along a line AA inFig.1 , - Figure 3
- shows in enlarged partial views of an inlet passage of the burner of
Fig.2 three possible configuration variants of a fuel supply pipe. - Figure 4
- shows two possible configuration variants of a Brennstoffzuführrohrs in an intake passage of the burner according to the invention, as seen along a line BB in
Fig.2 ,
Der Brenner 1 weist ein Flammrohr 10, in dem ein Brennraum 11 ausgebildet ist, und einen rohrförmigen Mantel 20 auf, der das Flammrohr 10 von radial außen her mit einem vorbestimmten Abstand davon umschließt, so dass zwischen Flammrohr 10 und Mantel 20 ein Oxidationsmittel-Sammelraum 21 gebildet ist.The burner 1 has a
Als Brennstoff für den Brenner 1 ist Brenngas vorgesehen, und als Oxidationsmittel für das Brenngas ist atmosphärische Luft vorgesehen, welche über einen Kompressor (nicht gezeigt) komprimiert wird und dann dem Oxidationsmittel-Sammelraum 21 zugeführt wird.As the fuel for the burner 1, fuel gas is provided, and as the oxidizing agent for the fuel gas, atmospheric air is provided, which is compressed by a compressor (not shown) and then supplied to the
Der Brenner 1 weist ferner einen Brennerboden 30, der den Oxidationsmittel-Sammelraum 21 und den Brennraum 11 an einem Axialende des Brenners 1 begrenzt, und einen Drallerzeuger 40 auf, der axial an den Brennerboden 30 und radial an den Oxidationsmittel-Sammelraum 21 angrenzend axial zwischen Flammrohr 10 und Brennerboden 30 angeordnet ist, zum Zuführen eines Brennstoff-Oxidationsmittel-Gemisches BOG in den Brennraum 11.The burner 1 further includes a burner bottom 30 delimiting the
Unter zusätzlicher Bezugnahme auf
Die Leitschaufeln 41 sind jeweils derart geformt und angeordnet, dass die jeweiligen Abstände zwischen den Leitschaufeln 41 eine Mehrzahl (hier acht) von in ihrem Verlauf jeweils eine Tangentialkomponente aufweisenden radialen Einlasspassagen 42 zum Brennraum 11 hin bilden.The guide vanes 41 are each shaped and arranged in such a way that the respective distances between the
In einem jeweiligen Einlasströmungsbereich wenigstens einiger der Mehrzahl von Einlasspassagen 42 ist jeweils ein Brennstoffzuführrohr 43a, 43b, 43c, 43d vorgesehen, welches sich bezüglich seiner Länge in einer Axialrichtung AR (siehe
Obwohl in
Wie in den
Wie aus
Andererseits kann bzw. können auch ein, mehrere oder alle Brennstoffzuführrohre 43c in Oxidationsmittel-Strömungsrichtung OS direkt vor den jeweiligen Einlasspassagen 42 (also am Eingang der jeweiligen Einlasspassagen 42 teilweise oder ganz im Oxidationsmittel-Sammelraum 21) angeordnet sein.On the other hand, one, several or all of the
Wie ebenfalls aus
Wie aus
Wie aus
Wie aus
Natürlich wäre es im Rahmen der Erfindung auch möglich, die sich jeweils diametral oder mit dem stumpfen Winkel α gegenüberliegenden Brennstoffausgabeöffnungen 44, 45 sich der Länge des Brennstoffzuführrohrs 43a, 43b, 43c, 43d nach abwechseln zu lassen, so dass an jeder Längenposition des Brennstoffzuführrohrs 43a, 43b, 43c, 43d nur eine einzige Brennstoffausgabeöffnungen 44, 45 angeordnet ist.Of course, it would also be possible within the scope of the invention to alternate the
Wie aus den
Obwohl in den
Zu diesem Zweck sind die Brennstoffzuführrohre 43a, 43b, 43c, 43d (in
Abschließend ist zu bemerken, dass jedes Brennstoffzuführrohr 43a, 43b, 43c, 43d natürlich über entsprechende Leitungen und Steuerventile (beides nicht dargestellt) mit einer Brennstoffquelle (nicht dargestellt), wie z.B. einem Brenngastank, fluidverbunden ist.Finally, it should be noted that each
- 11
- Brennerburner
- 1010
- Flammrohrflame tube
- 1111
- Brennraumcombustion chamber
- 2020
- Mantelcoat
- 2121
-
Oxidationsmittel-Sammelraum 21
Oxidant collecting space 21 - 3030
- BrennerbodenBrenner ground
- 4040
- Drallerzeugerswirl generator
- 4141
- Leitschaufelvane
- 4242
- Einlasspassageintake passage
- 43a43a
- Brennstoffzuführrohrfuel supply
- 43b43b
- Brennstoffzuführrohrfuel supply
- 43c43c
- Brennstoffzuführrohrfuel supply
- 43d43d
- Brennstoffzuführrohrfuel supply
- 4444
- BrennstoffausgabeöffnungFuel dispensing opening
- 4545
- BrennstoffausgabeöffnungFuel dispensing opening
- 4646
- Kopfabschnittheader
- 4747
- Kopfabschnittheader
- LL
- LängsmittelachseLongitudinal central axis
- L1L1
- LängsmittelachseLongitudinal central axis
- L2L2
- LängsmittelachseLongitudinal central axis
- αα
- stumpfer Winkeldull angle
- URUR
- Umfangsrichtungcircumferentially
- ARAR
- Axialrichtungaxially
- OROR
- Oxidationsmittel-StrömungsrichtungOxidant flow direction
- BSBS
- Brennstofffuel
- BOGBOG
- Brennstoff-Oxidationsmittel-GemischFuel-oxidant mixture
Claims (8)
- A burner (1) for a turbine, comprising:a flame tube (10), in which a combustion chamber (11) is formed,a jacket (20) which from radially outside encloses the flame tube (10) at a predetermined spacing thereof, so that between flame tube (10) and jacket (20) an oxidising agent collection space (21) is formed,a burner base (30), which delimits the oxidising agent collection space (21) and the combustion chamber (11) at an axial end of the burner (1), anda swirl generator (40), which, axially adjoining the burner base (30) and radially adjoining the oxidising agent collection space (21), is axially arranged between the flame tube (10) and burner base (30) for feeding a fuel oxidising agent mixture (BOG) into the combustion chamber (11),wherein the swirl generator comprises a plurality of guide vanes (41) each arranged along a circumferential direction (UR) of the burner (1) arranged circumferentially spaced from one another, so that the respective spacings between the guide vanes (41) form a plurality of radial inlet passages (42) towards the combustion chamber (11) each comprising a tangential component in their course,wherein in a respective inlet flow region at least of some of the plurality of inlet passages (42) a fuel feed tube (43a, 43b, 43c, 43d) is provided in each case, which with respect to its length extends in an axial direction (AR) of the burner (1) and transversely to an oxidising agent flow direction (OR) through the respective inlet passage (42), andwherein each fuel feed tube (43a, 43b, 43c, 43d) in its wall comprises at least one fuel output opening (44, 45) which is radial with respect to the fuel feed tube (43a, 43b, 43c, 43d), via which fuel (BS) can be admixed into the respective inlet passage (42) with a directional component running transversely to the oxidising agent flow direction (OR),characterizedin that at least one of the fuel feed tubes (43d) is arranged out of centre in the respective inlet passage (42) with respect to the longitudinal centre axis (L) of the respective inlet passage (42).
- The burner according to Claim 1, wherein at least one of the fuel feed tubes (43c) is arranged in the oxidising agent flow direction (OR) directly before the respective inlet passage (42).
- The burner according to any one of the Claims 1 to 2, wherein at least one of the fuel feed tubes (43a, 43b, 43c) is arranged, with respect to a longitudinal centre axis (L) of the respective inlet passage (42), centrically in the respective inlet passage (42).
- The burner according to any one of the Claims 1 to 3, wherein at least one of the fuel feed tubes (43a, 43b, 43c, 43d) comprises a plurality of fuel output openings (44, 45) which are arranged spaced from one another along the length of the fuel feed tube (43a, 43b, 43c, 43d).
- The burne4 (1) according to any one of the Claims 1 to 4, wherein at least one of the fuel feed tubes (43a, 43b, 43c, 43d) comprises two fuel output openings (44, 45), which with respect to the length of the fuel feed tube (43a, 43b, 43c, 43d) are arranged in the same position that via these two fuel output openings (44, 45), fuel (BS) with two directional components opposing one another can be output from the fuel feed tube (43a, 43b, 43c, 43d).
- The burner (1) according to Claim 5, wherein seen in the cross section of the respective fuel feed tube (43a, 43b, 43c, 43d), the two fuel output openings (44, 45) are located diametrically opposite one another or respective longitudinal centre axes (L1, L2) of the two fuel output openings (44, 45) include an obtuse angle (α) with one another.
- The burner (1) according to any one of the Claims 1 to 6, wherein the fuel feed tubes (43a, 43b, 43c, 43d) each have a cylindrical cross section or a wing-shaped cross section.
- The burner (1) according to any one of the Claims 1 to 7, wherein the fuel feed tubes (43a, 43b, 43c, 43d) are each detachably mounted so that each fuel feed tube (43a, 43b, 43c, 43d) formed according to a predetermined fuel admixing configuration can be individually exchanged if required against a fuel feed tube (43a, 43b, 43c, 43d) according to another predetermined fuel admixing configuration.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009054669A DE102009054669A1 (en) | 2009-12-15 | 2009-12-15 | Burner for a turbine |
PCT/DE2010/050074 WO2011072665A1 (en) | 2009-12-15 | 2010-09-28 | Burner for a turbine |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2513562A1 EP2513562A1 (en) | 2012-10-24 |
EP2513562B1 true EP2513562B1 (en) | 2018-07-18 |
Family
ID=43568285
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10786994.3A Active EP2513562B1 (en) | 2009-12-15 | 2010-09-28 | Burner for a turbine |
Country Status (6)
Country | Link |
---|---|
US (1) | US20120227407A1 (en) |
EP (1) | EP2513562B1 (en) |
JP (1) | JP2013517440A (en) |
CA (1) | CA2782196C (en) |
DE (1) | DE102009054669A1 (en) |
WO (1) | WO2011072665A1 (en) |
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US9581333B2 (en) * | 2012-05-01 | 2017-02-28 | Aerco International, Inc. | Igniter assembly and method for operating |
US9677766B2 (en) * | 2012-11-28 | 2017-06-13 | General Electric Company | Fuel nozzle for use in a turbine engine and method of assembly |
KR102184778B1 (en) | 2013-12-19 | 2020-11-30 | 한화에어로스페이스 주식회사 | Swirler for gas turbine |
JP6602004B2 (en) * | 2014-09-29 | 2019-11-06 | 川崎重工業株式会社 | Fuel injector and gas turbine |
EP3098514A1 (en) * | 2015-05-29 | 2016-11-30 | Siemens Aktiengesellschaft | Combustor arrangement |
US10215415B2 (en) * | 2015-09-23 | 2019-02-26 | General Electric Company | Premix fuel nozzle assembly cartridge |
EP3236157A1 (en) | 2016-04-22 | 2017-10-25 | Siemens Aktiengesellschaft | Swirler for mixing fuel with air in a combustion engine |
JP6995696B2 (en) * | 2018-05-28 | 2022-01-17 | 三菱重工業株式会社 | Fuel injection system and gas turbine |
CN113310071B (en) * | 2021-06-16 | 2022-11-15 | 哈尔滨工程大学 | A Coaxial Staged Burner for Low Pollution Combustion Chamber of Gas Fuel Gas Turbine |
CN113834094B (en) * | 2021-09-15 | 2022-11-01 | 中国船舶重工集团公司第七0三研究所 | Nozzle with tangential rotational flow structure |
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- 2010-09-28 WO PCT/DE2010/050074 patent/WO2011072665A1/en active Application Filing
- 2010-09-28 CA CA2782196A patent/CA2782196C/en active Active
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- 2010-09-28 JP JP2012543473A patent/JP2013517440A/en active Pending
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Also Published As
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WO2011072665A1 (en) | 2011-06-23 |
US20120227407A1 (en) | 2012-09-13 |
CA2782196A1 (en) | 2011-06-23 |
EP2513562A1 (en) | 2012-10-24 |
DE102009054669A1 (en) | 2011-06-16 |
CA2782196C (en) | 2014-07-29 |
JP2013517440A (en) | 2013-05-16 |
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