EP2460582B1 - Super-micro bubble generation device - Google Patents
Super-micro bubble generation device Download PDFInfo
- Publication number
- EP2460582B1 EP2460582B1 EP10804452.0A EP10804452A EP2460582B1 EP 2460582 B1 EP2460582 B1 EP 2460582B1 EP 10804452 A EP10804452 A EP 10804452A EP 2460582 B1 EP2460582 B1 EP 2460582B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- super
- liquid
- bubble generation
- micro
- micro bubbles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007788 liquid Substances 0.000 claims description 135
- 239000000463 material Substances 0.000 claims description 43
- 239000011148 porous material Substances 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 16
- 239000000126 substance Substances 0.000 claims description 10
- 238000007599 discharging Methods 0.000 claims description 3
- 239000007789 gas Substances 0.000 description 47
- 238000000034 method Methods 0.000 description 29
- 239000011248 coating agent Substances 0.000 description 27
- 238000000576 coating method Methods 0.000 description 27
- 238000009434 installation Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 9
- 238000009792 diffusion process Methods 0.000 description 7
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000010408 film Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229910010272 inorganic material Inorganic materials 0.000 description 3
- 239000011147 inorganic material Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000825 pharmaceutical preparation Substances 0.000 description 2
- 229940127557 pharmaceutical product Drugs 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 230000002123 temporal effect Effects 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000005276 aerator Methods 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 210000000887 face Anatomy 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/231—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
- B01F23/23105—Arrangement or manipulation of the gas bubbling devices
- B01F23/2312—Diffusers
- B01F23/23123—Diffusers consisting of rigid porous or perforated material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/231—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
- B01F23/23105—Arrangement or manipulation of the gas bubbling devices
- B01F23/2312—Diffusers
- B01F23/23124—Diffusers consisting of flexible porous or perforated material, e.g. fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/231—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
- B01F23/23105—Arrangement or manipulation of the gas bubbling devices
- B01F23/2312—Diffusers
- B01F23/23126—Diffusers characterised by the shape of the diffuser element
- B01F23/231265—Diffusers characterised by the shape of the diffuser element being tubes, tubular elements, cylindrical elements or set of tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/237—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media
- B01F23/2373—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids characterised by the physical or chemical properties of gases or vapours introduced in the liquid media for obtaining fine bubbles, i.e. bubbles with a size below 100 µm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/20—Jet mixers, i.e. mixers using high-speed fluid streams
- B01F25/21—Jet mixers, i.e. mixers using high-speed fluid streams with submerged injectors, e.g. nozzles, for injecting high-pressure jets into a large volume or into mixing chambers
Definitions
- the present invention relates to an art of a super-micro bubble generation device which can generate super-micro bubbles in liquid.
- the super-micro bubbles are used in liquid such as tap water, the water of lakes and marshes or rivers, or marine water or the like.
- the said super-micro bubbles have the property that the surface areas thereof are very large.
- the said super-micro bubbles also have physiochemical property such as self-pressure effect.
- Technology of utilizing the characteristics of such micro bubbles in effluent purification, purification, physical care in the bathtub, and the like has been developing.
- One method for generating the super-micro bubbles having the said properties has become public knowledge. That method has steps of, spinning around motor in liquid; raising the flow rate by pump pressure; inhaling the air; and stirring. As such, bubbles are generated. The generated bubbles are then torn into super-micro bubbles by a rotating wing or a cutting tool.
- another method for generating the super-micro bubbles has also become public knowledge. In that method, a liquid jetting nozzle is disposed around an air jetting nozzle, and bubbles jetted from the air jetting nozzle are torn into super-micro bubbles by the force of jet flow of the liquid jetting nozzle.
- another method for generating the super-micro bubbles has also become public knowledge. In that method, bubbles are generated by stirring, and the generated bubbles go through the eyes of a mesh membrane so as to fine down to super-micro bubbles (for example, see Patent Literature 1).
- Patent Literature 2 discloses an aerator nozzle and system for aerating a body of liquid which includes a combined air and liquid discharge nozzle unit respectively supplied from an air compressor and a liquid pump wherein the nozzle unit includes a liquid discharge nozzle with an air dispersing nozzle therewithin to insure maximum air absorption into the body of liquid to be aerated.
- Patent Literature 3 discloses an air diffusion nozzle capable of efficiently diffusing an air diffusing gas by installing a small-sized air diffusion pipe provided with the air diffusion nozzle in a tank, and an air diffusion tank.
- the air diffusion nozzle connected to the air diffusion pipe in a detachable manner has a pipe opened at its leading end to allow the air diffusing gas to flow and a porous hollow cylindrical body, and the pipe opened at its leading end is loosely mounted in the porous hollow cylindrical body.
- a gap is formed between the pipe and the porous hollow cylindrical body.
- the air diffusing gas flowing through the pipe from the air diffusion pipe A flows in the internal space part of the porous hollow cylindrical body from the leading end of the pipe and passes through the gap between the pipe and the porous hollow cylindrical body to be uniformly diffused over the whole surface of the porous hollow cylindrical body.
- the mesh membrane when the method of which the generated bubbles go through the eyes of the mesh membrane so as to fine down to super-micro bubbles is applied, the mesh membrane will become depleted in the long run since the mesh membrane is made of organic substance. Moreover, when the mesh membrane is provided at right angle with liquid surface, the generated super-micro bubbles will overlap with other super-micro bubbles and will coalesce in a mass bubble. To avoid this, the mesh membrane should be provided parallel to the liquid surface, that is, installation method is limited.
- the object of the present invention is to provide a super-micro bubble generation device which can generate super-micro bubbles using a simple method and can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements.
- a super-micro bubble generation device of the present invention comprises: a compressor for delivering gas under pressure, and a bubble generation medium for discharging the gas, which has been delivered under pressure, as super-micro bubbles into liquid, wherein the said bubble generation medium consists of a high-density compound which is an electrically conductive substance.
- the said super-micro bubble generation device further comprises a liquid jetting device for jetting liquid in the direction substantially perpendicular to the direction in which the bubble generation medium discharges the super-micro bubbles, said liquid being the same kind of liquid as the liquid into which the super-micro bubbles are discharged, wherein a bubble guide groove, which is formed around the bubble generation medium is provided downstream of the liquid flow jetted from the liquid jetting device, the bubble guide groove is formed into an arc-like shape in the cross section view, located downstream of the liquid flow and guides the direction of super-micro bubbles movement and wherein the bubble generation medium is porous having a lot of tiny pores of several ⁇ m to several dozen ⁇ m in diameter.
- the said bubble generation medium is formed into a conical shape.
- the gas from the said compressor passes through the said bubble generation medium from a bottom face of the cone toward a vertex, wherein the said liquid being the same kind of liquid as the liquid into which the super-micro bubbles are discharged is jetted toward the vertex of the cone of the said bubble generation medium by the said liquid jetting device.
- an outer periphery of the said bubble generation medium is covered with a covering material, wherein the said covering material has the property of lowering the contact angle at which the liquid meets the surface of the said covering material.
- the present invention constructed as the above brings the following effects.
- the bubble generation medium consisting of the high-density compound would not deteriorate due to expansion and contraction since the high-density compound is a solid substance which does not have flexibility. Also, the high-density compound would not become eroded due to temporal change since it is made of inorganic material. Thus, the super-micro bubble generation device is prevented from damage and degradation. Also, because the generated super-micro bubbles separates from the bubble generation medium as soon as they are generated, they would not coalesce in a mass bubble. Thus, the super-micro bubbles can be generated by using a simple method.
- the super-micro bubble generation device can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements.
- the said high-density compound is an electrically conductive substance, negatively charged ions tend to range on the surface of the high-density compound.
- the bubbles generated from the said bubble generation medium become negatively charged by receiving the negatively charged ions from the surface of the high-density compound. The bubbles would not coalesce in a mass bubble since each bubble act repulsively due to this negative electric charge.
- the liquid is jetted toward the vertex of the cone. Then, the liquid will flow along the curved surface of the cone. In this way, it is able to make the size of the injection hole smaller, and thus, lower pressure is needed for jetting the liquid.
- the generated super-micro bubbles separate from the bubble generation medium as soon as they are generated, and thus, the super-micro bubbles would not coalesce in a mass bubble.
- the super-micro bubbles can be generated by using a simple method.
- the super-micro bubble generation device can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements.
- the said high-density compound is an electrically conductive substance, bubbles generated from the bubble generation medium are negatively charged. The bubbles would not coalesce in a mass bubble since each bubble act repulsively due to this negative electric charge.
- the covering material has the property that contact angle at which the liquid meets the surface of the covering material is low. Accordingly, the surrounding liquid is attracted to the covering material. Thus, a thin liquid film is formed between the super-micro bubbles and the covering material. This makes it easy to separate the super-micro bubbles from the bubble generation medium. Thus, the super-micro bubbles would not coalesce in a mass bubble. Moreover, there is an effect of separating the super-micro bubbles by liquid flow by jetting liquid toward the bubble generation medium coated with the covering material from the liquid jetting device. There is also an effect of separating the super-micro bubbles by making the contact angle, at which the liquid interface meets the surface of the covering material, smaller. Combination of these effects makes it easy to separate super-micro bubbles.
- a super-micro bubble generation device 1 is provided with a compressor 2 as a compression machine for delivering gas under pressure, and also with a bubble generation medium 3 for discharging the gas, which has been delivered under pressure, as super-micro bubbles into liquid.
- the super-micro bubble generation device 1 is also provided with a liquid jetting device 4 for jetting liquid being the same kind of liquid as the liquid into which the super-micro bubbles are discharged.
- the compressor 2 is a device for delivering gas under pressure into an internal space 3a of the bubble generation medium 3 through the intermediary of a gas supply line 11.
- the gas delivered under pressure by the compressor 2 is not limited to air.
- the gas may be ozone gas or nitrogen gas.
- the said liquid may be such as fresh water or sea water of rivers or lakes, water, or industrial wastewater.
- the said liquid also may be solvent such as pharmaceutical products. In that case, the pharmaceutical products are stirred or mixed by using the said super-micro bubbles.
- the bubble generation medium 3 consists of a high-density compound whose solid texture is made of molecular structure consisting of ionic bonds. Moreover, the said high-density compound is an electrically conductive substance, and thus, bubbles generated from the bubble generation medium 3 are negatively charged. In other words, the super-micro bubbles are negatively charged by addition of free electrons on passing through the bubble generation medium 3, which is the electrically conductive substance. The bubbles would not coalesce in a mass bubble since each bubble act repulsively due to this negative electric charge.
- the said electrically conductive substance is made of carbon-based material.
- the bubble generation medium 3 is porous having a lot of tiny pores 3b of several ⁇ m to several dozen ⁇ m in diameter. Because of this constitution, the gas delivered under pressure by the compressor 2 passes through the said pores 3b. In other words, the super-micro bubbles are discharged from the pores 3b into liquid by gas tension of the gas delivered under pressure from compressor 2. Because of this constitution, the bubble generation medium 3 consisting of the high-density compound would not deteriorate due to expansion and contraction since the high-density compound is a solid substance which does not have flexibility. Also, the high-density compound would not become eroded due to temporal change since it is made of inorganic material. Thus, the super-micro bubble generation device 1 is prevented from damage and degradation.
- the bubble generation medium 3 consisting of the high-density compound would not become worn even though liquid flow injected from the liquid jetting device 4 hits the high-density compound because it is activated. Thus, durability of the bubble generation medium 3 has been improved.
- the liquid jetting device 4 is a device for separating super-micro bubbles generated from a surface site 3c of the bubble generation medium 3 by the liquid flow.
- the liquid jetting device 4 jets liquid being the same kind of liquid as the liquid into which the super-micro bubbles are discharged. Because of this constitution, the super-micro bubbles can be separated by the liquid flow without influencing fluid composition. Moreover, it is able to prevent different kind of liquid being mixed into the liquid.
- the said super-micro bubbles are discharged from the tiny pores 3b.
- the liquid delivered under pressure by the liquid jetting device 4 rapidly passes through the surface site 3c, from where the super-micro bubbles are discharged, so as to separate the super-micro bubbles from the surface site 3c.
- the super-micro bubbles discharged from the surface site 3c separately move around in the liquid without coalescing with subsequently generated super-micro bubbles or other super-micro bubbles discharged from surrounding pores 3b. Because of this constitution, super-micro bubbles can be generated by using a simple method. Moreover, the super-micro bubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements.
- the bubble generation medium 3 may be coated with a coating material 5 which is a covering material.
- the coating material 5 is an inorganic material which has the property that contact angle at which the liquid interface meets the surface of the coating material 5 is low (for example, if the liquid is water, the coating material 5 may be made of superhydrophilic material).
- the coating material 5 is made of silica glass.
- the contact angle signifies wetting force of materials. The value of wetting force will rise as contact angle becomes lower.
- the coating material 5 is not limited to material which is made of silica glass.
- the coating material 5 is applied to the surface site 3c of the bubble generation medium 3 so as to cover its surface.
- the silica glass that makes up the coating material 5 has the property of lowering the contact angle at which the liquid interface meets the surface of the coating material 5, and thus the coating material 5 attracts surrounding liquid instead of shedding. In other words, the liquid spreads on the surface of the coating material 5 as thin film rather than forming droplets.
- the coating material 5 is porous having a lot of tiny pores 5a of several ⁇ m to several dozen ⁇ m in diameter. The pores 5a are communicated with the pores 3b of the bubble generation medium 3.
- the said super-micro bubbles are discharged from the pores 5a of the coating material 5 into liquid after passing through the pores 3b of the bubble generation medium 3.
- the coating material 5 has the property that contact angle at which the liquid interface meets the surface of the coating material 5 is low. Because of this, the wetting force of the coating material 5 is high. The surrounding liquid is attracted to the coating material 5. Thus, a thin liquid film is formed between the super-micro bubbles and the coating material 5. This makes it easy to separate the super-micro bubbles from the bubble generation medium 3. Thus, the super-micro bubbles would not coalesce in a mass bubble.
- the super-micro bubbles are generated from the pores 5a after passing through the pores 3b.
- the super-micro bubbles are easily separated from the surface of the coating material 5 because the thin liquid film is formed on the surface of the coating material 5 whereby the super-micro bubbles are generated. In other words, the super-micro bubbles can be easily separated because the liquid film lies between the super-micro bubbles and the coating material 5.
- the super-micro bubbles are generated from the pores 5a.
- the liquid delivered under pressure by the liquid jetting device 4 rapidly passes through the surface of the coating material 5.
- the super-micro bubbles are separated from the surface site 3c of the bubble generation medium 3.
- the super-micro bubbles which dwell on the surface of the coating material 5 will separately move around in the liquid without coalescing with subsequently generated super-micro bubbles or other super-micro bubbles discharged from surrounding pores 5a. Because of this constitution, the super-micro bubbles can be generated by using a simple method. Also, the super-micro bubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements.
- the bubble generation medium 3 is formed into a tabular shape.
- the super-micro bubbles are generated from the surface site 3c, whose plate area is wider than any other plate face of the bubble generation medium 3. Because the bubble generation medium 3 is formed into a tabular shape with wide surface area, the super-micro bubbles can be generated effectively. Also, because the super-micro bubbles separates from the bubble generation medium 3 as soon as they are generated, they would not coalesce in a mass bubble.
- the liquid jetting device 4 is a device for jetting liquid in the direction substantially perpendicular to the direction in which the bubble generation medium 3 discharges the super-micro bubbles, that is, jetting liquid in the direction parallel to the surface site 3c, which is the widest of all of plate faces of the generation medium 3.
- the direction of jetting liquid is sufficient if the said direction is substantially perpendicular to the direction in which the super-micro bubbles are discharged, that is, the said direction may be any direction shown in Fig. 5(a) as arrow a, arrow b, arrow c, or arrow d.
- the liquid jetting device 4 has an injection hole 4a for jetting liquid flow toward the surface site 3c of the plate face of the bubble generation medium 3.
- the said liquid flow whose width is as same as that of the surface site 3c of the plate face of the bubble generation medium 3, is jetted in the direction parallel to the plate face.
- the generated super-micro bubbles separate from the bubble generation medium 3 as soon as they are generated, and thus, the super-micro bubbles would not coalesce in a mass bubble.
- the super-micro bubbles can be generated by using a simple method.
- the super-micro bubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements.
- the super-micro bubble generation device 1 in accordance with another embodiment is formed into a hollow polygonal shape.
- the bubble generation medium 3 is formed into a hollow square pillar shape. Because of this constitution, gas is discharged from each surface site 3c of the square pillar equivalently.
- the surface sites 3c corresponds to longitudinally side walls of the square pillar shape. Thus, the super-micro bubbles can be generated effectively.
- the liquid is jetted in the same direction parallel to two side walls, which comprise opposing side walls of the square pillar shaped bubble generation medium 3, that is, along the surface of the two side walls in the same direction (direction of arrow A and arrow B).
- the liquid is also jetted in the same direction parallel to the other two side walls, that is, in the direction opposite to arrow A and arrow B (direction of arrow C and arrow D).
- the liquid jetting direction is not limited to such directions shown in this embodiment.
- the liquid may be jetted in the same direction parallel to all of the side walls.
- the liquid may be jetted in the same direction parallel to three of the side walls and in the opposite direction parallel to the other side wall.
- the super-micro bubble generation device 1 in accordance with another embodiment includes the bubble generation medium 3 which is formed into a hollow columnar shape.
- the gas which has been delivered under pressure passes through the gas supply line 11, and then the gas will be delivered in the columnar shaped internal space 3a which is provided in the central part of the bubble generation medium 3. Because of this constitution, the gas is discharged from the surface site 3c, which is the side wall of the column, equivalently in every direction. Thus, the super-micro bubbles can be generated effectively.
- the liquid jetting device 4 is provided on the periphery of the gas supply line 11.
- An injection hole 4a of the liquid jetting device 4 is formed into a circular shape having a diameter slightly larger than that of the periphery of the bubble generation medium 3.
- the liquid jetting device 4 jets zonal liquid flow along the surface site 3c in the direction same as gas supplying direction.
- the surface site 3c corresponds to longitudinally side wall of the bubble generation medium 3.
- the generated super-micro bubbles separate from the bubble generation medium 3 as soon as they are generated, and thus, the super-micro bubbles would not coalesce in a mass bubble.
- the super-micro bubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements.
- the liquid jetting direction is not limited to such directions shown in this embodiment.
- the liquid may be jetted in a direction opposite to the gas supplying direction.
- the super-micro bubble generation device 1 in accordance with another embodiment includes the bubble generation medium 3 which is formed into a conical shape.
- the internal space 3a is provided on the principal axis part of section of the said conical shape.
- the gas delivered under pressure by compressor 2 passes through the gas supply line 11, and then the gas will be delivered under pressure into the internal space 3a of the bubble generation medium 3. Because of this constitution, the gas is discharged from the surface site 3c, which is the side wall of the cone, equivalently in every direction. Thus, the super-micro bubbles can be generated effectively.
- the liquid jetting device 4 is facing the bubble generation medium 3.
- the injection hole 4a of the liquid jetting device 4 is disposed on the extension line that extends from a vertex 3d of the cone of the bubble generation medium 3.
- the liquid jetting device 4 is a device for jetting liquid toward the vertex 3d of the cone.
- the liquid since the liquid is jetted toward the vertex 3d of the cone, the liquid will flow radially along the surface site 3c, which is the side wall of the bubble generation medium 3. In other words, the liquid is jetted in the direction substantially perpendicular to the direction in which the bubble generation medium 3 discharges the super-micro bubbles.
- the super-micro bubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements.
- a gas supplying inlet port of the gas supply line 11 may be provided in the direction perpendicular to the height direction of the cone of the bubble generation medium 3. Because of this constitution, it is able to make an effective use of space downstream of the liquid flow.
- the gas supplying inlet port of the gas supply line 11 in this embodiment is provided upside of the bubble generation medium 3, the position of the gas supplying inlet port is not limited to this.
- the gas supplying inlet port may be provided in the horizontal direction.
- a bubble guide groove 55 which is formed around the bubble generation medium 3, is provided downstream of the liquid flow jetted from the liquid jetting device 4.
- the bubble guide groove 55 is formed into an arc-like shape in the cross section view, located downstream of the liquid flow.
- the bubble guide grove 55 guides the direction of super-micro bubbles movement.
- the micro bubbles move from the surface site 3c of the bubble generation medium 3 by the liquid flow jetted from the liquid jetting device 4.
- the super-micro bubbles which are separated from the bubble generation medium 3 will impinge on the bubble guide groove 55. After impingement, the super-micro bubbles will move along the bubble guide groove 55. Thus, it is able to preserve a distance between each super-micro bubble. Accordingly, the super-micro bubbles would not coalesce in a mass bubble.
- the bubble generation medium 3 and the liquid jetting device 4, which comprise the super-micro bubble generation device 1 may be configured in a unified manner. If constituted in this manner, positional relationship between the generation medium 3 and the injection hole 4a of the liquid jetting device 4 is maintained constant consistently. Accordingly, it is able to save many steps for adjusting position thereof.
- a wall surface facing the liquid jetting device 4 may be inclined in an arc-like shape when seen from a side. Because of this constitution, the direction of super-micro bubbles movement can be guided. The super-micro bubbles move along the surface site 3c of the plate face of the bubble generation medium 3 by the jetted liquid flow from the liquid jetting device 4. In this way, it is able to preserve a distance between each super-micro bubble. As such, the super-micro bubbles would not coalesce in a mass bubble.
- the bubble generation medium 3 may be formed into a tabular shape, wherein several gas supply lines 11 are provided in parallel inside the bubble generation medium 3.
- the gas passes through the gas supply lines 11, and is delivered under pressure into the internal space 3a of the bubble generation medium 3.
- the gas supply lines 11 are branched inside the bubble generation medium 3.
- the said branched gas supply lines 11 are arranged in parallel.
- the super-micro bubbles are generated from the surface site 3c of the bubble generation medium 3 by gas pressure from the gas supply lines 11. Keeping wide interval between each gas supply line 11 which is arranged in parallel respectively makes it harder for super-micro bubbles to coalesce in a mass bubble.
- the numbers or shape of the liquid jetting device is not limited to the state described in this embodiment.
- more than three liquid jetting devices may be provided.
- the shape or material of the gas supply line 11 is not limited to the state described in this embodiment.
- the gas supply line 11 may be a metallic pipe or a plastic pipe.
- the super-micro bubble generation device of the present invention is industrially useful because it can generate super-micro bubbles using a simple method and can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements. In this way, the generated super-micro bubbles separate from the bubble generation medium 3 as soon as they are generated, and thus, the super-micro bubbles would not coalesce in a mass bubble. As just described, the super-micro bubbles can be generated by using a simple method. Also, the super-micro bubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Aeration Devices For Treatment Of Activated Polluted Sludge (AREA)
- Nozzles (AREA)
Description
- The present invention relates to an art of a super-micro bubble generation device which can generate super-micro bubbles in liquid.
- In recent years, the art of utilizing super-micro bubbles of several hundred nm to several dozen µm in size (diameter) has been attracting attention. The super-micro bubbles are used in liquid such as tap water, the water of lakes and marshes or rivers, or marine water or the like. The said super-micro bubbles have the property that the surface areas thereof are very large. The said super-micro bubbles also have physiochemical property such as self-pressure effect. Technology of utilizing the characteristics of such micro bubbles in effluent purification, purification, physical care in the bathtub, and the like has been developing.
- One method for generating the super-micro bubbles having the said properties has become public knowledge. That method has steps of, spinning around motor in liquid; raising the flow rate by pump pressure; inhaling the air; and stirring. As such, bubbles are generated. The generated bubbles are then torn into super-micro bubbles by a rotating wing or a cutting tool. Moreover, another method for generating the super-micro bubbles has also become public knowledge. In that method, a liquid jetting nozzle is disposed around an air jetting nozzle, and bubbles jetted from the air jetting nozzle are torn into super-micro bubbles by the force of jet flow of the liquid jetting nozzle. Furthermore, another method for generating the super-micro bubbles has also become public knowledge. In that method, bubbles are generated by stirring, and the generated bubbles go through the eyes of a mesh membrane so as to fine down to super-micro bubbles (for example, see Patent Literature 1).
-
Patent Literature 2 discloses an aerator nozzle and system for aerating a body of liquid which includes a combined air and liquid discharge nozzle unit respectively supplied from an air compressor and a liquid pump wherein the nozzle unit includes a liquid discharge nozzle with an air dispersing nozzle therewithin to insure maximum air absorption into the body of liquid to be aerated. -
Patent Literature 3 discloses an air diffusion nozzle capable of efficiently diffusing an air diffusing gas by installing a small-sized air diffusion pipe provided with the air diffusion nozzle in a tank, and an air diffusion tank. The air diffusion nozzle connected to the air diffusion pipe in a detachable manner has a pipe opened at its leading end to allow the air diffusing gas to flow and a porous hollow cylindrical body, and the pipe opened at its leading end is loosely mounted in the porous hollow cylindrical body. By this constitution, a gap is formed between the pipe and the porous hollow cylindrical body. The air diffusing gas flowing through the pipe from the air diffusion pipe A flows in the internal space part of the porous hollow cylindrical body from the leading end of the pipe and passes through the gap between the pipe and the porous hollow cylindrical body to be uniformly diffused over the whole surface of the porous hollow cylindrical body. - A super-micro bubble generation with the features of the preamble of
claim 1 is disclosed inPatent Literature 4 -
- Patent Literature 1: the Japanese Patent Laid Open Gazette
2009-101250 - Patent Literature 2: US Patent Application
US 4,522,151 (A ) - Patent Literature 3: Japanese Patent Application
JP 2007 260 529 (A - Patent Literature 4: Japanese Patent Application
JP 2006 061 817 (A - By using the conventional method of spinning around motor in liquid; raising the flow rate by pump pressure; inhaling the air; stirring; and tearing into super-micro bubbles by the rotating wing or the cutting tool, it is able to generate large amount of super-micro bubbles. However, fast rotation of the rotating wing or the cutting tool will cause corrosion due to cavitation or abrasion of devices. These will lead to significant damage, and thus, durability will become a problem. When the process liquid, discharged water, or the lakes and marshes or rivers, or marine water or the like with very poor quality is used, deterioration will proceed because the liquid directly contact to the device.
- Meanwhile, when the method of which the generated bubbles go through the eyes of the mesh membrane so as to fine down to super-micro bubbles is applied, the mesh membrane will become depleted in the long run since the mesh membrane is made of organic substance. Moreover, when the mesh membrane is provided at right angle with liquid surface, the generated super-micro bubbles will overlap with other super-micro bubbles and will coalesce in a mass bubble. To avoid this, the mesh membrane should be provided parallel to the liquid surface, that is, installation method is limited.
- Moreover, when the method of which the liquid jetting nozzle is disposed around the air jetting nozzle and bubbles jetted from the air jetting nozzle are torn into super-micro bubbles by the force of jet flow of the liquid jetting nozzle is applied, it is difficult to stabilize the particle size because there is limitation in pore size of the nozzle.
- Therefore, considering the above-mentioned problems, the object of the present invention is to provide a super-micro bubble generation device which can generate super-micro bubbles using a simple method and can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements.
- The above-mentioned problems are solved by the following means.
- Briefly stated, a super-micro bubble generation device of the present invention comprises: a compressor for delivering gas under pressure, and a bubble generation medium for discharging the gas, which has been delivered under pressure, as super-micro bubbles into liquid, wherein the said bubble generation medium consists of a high-density compound which is an electrically conductive substance. The said super-micro bubble generation device further comprises a liquid jetting device for jetting liquid in the direction substantially perpendicular to the direction in which the bubble generation medium discharges the super-micro bubbles, said liquid being the same kind of liquid as the liquid into which the super-micro bubbles are discharged, wherein a bubble guide groove, which is formed around the bubble generation medium is provided downstream of the liquid flow jetted from the liquid jetting device, the bubble guide groove is formed into an arc-like shape in the cross section view, located downstream of the liquid flow and guides the direction of super-micro bubbles movement and wherein the bubble generation medium is porous having a lot of tiny pores of several µm to several dozen µm in diameter.
- With regard to the super-micro bubble generation device of the present invention, the said bubble generation medium is formed into a conical shape. The gas from the said compressor passes through the said bubble generation medium from a bottom face of the cone toward a vertex, wherein the said liquid being the same kind of liquid as the liquid into which the super-micro bubbles are discharged is jetted toward the vertex of the cone of the said bubble generation medium by the said liquid jetting device.
- With regard to the super-micro bubble generation device of the present invention, an outer periphery of the said bubble generation medium is covered with a covering material, wherein the said covering material has the property of lowering the contact angle at which the liquid meets the surface of the said covering material.
- The present invention constructed as the above brings the following effects.
- According to the super-micro bubble generation device of the present disclosure, the bubble generation medium consisting of the high-density compound would not deteriorate due to expansion and contraction since the high-density compound is a solid substance which does not have flexibility. Also, the high-density compound would not become eroded due to temporal change since it is made of inorganic material. Thus, the super-micro bubble generation device is prevented from damage and degradation. Also, because the generated super-micro bubbles separates from the bubble generation medium as soon as they are generated, they would not coalesce in a mass bubble. Thus, the super-micro bubbles can be generated by using a simple method. Also, the super-micro bubble generation device can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements. Moreover, since the said high-density compound is an electrically conductive substance, negatively charged ions tend to range on the surface of the high-density compound. The bubbles generated from the said bubble generation medium become negatively charged by receiving the negatively charged ions from the surface of the high-density compound. The bubbles would not coalesce in a mass bubble since each bubble act repulsively due to this negative electric charge.
- According to the super-micro bubble generation device of the present disclosure, the liquid is jetted toward the vertex of the cone. Then, the liquid will flow along the curved surface of the cone. In this way, it is able to make the size of the injection hole smaller, and thus, lower pressure is needed for jetting the liquid. The generated super-micro bubbles separate from the bubble generation medium as soon as they are generated, and thus, the super-micro bubbles would not coalesce in a mass bubble. As just described, the super-micro bubbles can be generated by using a simple method. Also, the super-micro bubble generation device can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements. Also, since the said high-density compound is an electrically conductive substance, bubbles generated from the bubble generation medium are negatively charged. The bubbles would not coalesce in a mass bubble since each bubble act repulsively due to this negative electric charge.
- According to the super-micro bubble generation device of the present disclosure the covering material has the property that contact angle at which the liquid meets the surface of the covering material is low. Accordingly, the surrounding liquid is attracted to the covering material. Thus, a thin liquid film is formed between the super-micro bubbles and the covering material. This makes it easy to separate the super-micro bubbles from the bubble generation medium. Thus, the super-micro bubbles would not coalesce in a mass bubble. Moreover, there is an effect of separating the super-micro bubbles by liquid flow by jetting liquid toward the bubble generation medium coated with the covering material from the liquid jetting device. There is also an effect of separating the super-micro bubbles by making the contact angle, at which the liquid interface meets the surface of the covering material, smaller. Combination of these effects makes it easy to separate super-micro bubbles.
-
- [
Fig. 1] Fig. 1(a) is a schematic drawing showing the overall configuration of a super-micro bubble generation device which is one embodiment of the present disclosure.Fig. 1(b) is an enlarged cross-section view of a bubble generation medium. - [
Fig. 2 ] It is an enlarged cross-section view of the bubble generation medium:Fig 2(a) shows the point when a super-micro bubble is generated,Fig. 2(b) shows the point when the super-micro bubble separates from the bubble generation medium, andFig. 2(c) shows the point when a next super-micro bubble is generated. - [
Fig. 3 ] It is an enlarged cross-section view of the bubble generation medium coated with a coating material. - [
Fig. 4 ] It is an enlarged cross-section view of the bubble generation medium:Fig 4(a) shows the point when a super-micro bubble is generated,Fig. 4(b) shows the point when the super-micro bubble separates from the bubble generation medium, andFig. 4(c) shows the point when a next super-micro bubble is generated. - [
Fig. 5] Fig. 5(a) is a schematic drawing showing the overall configuration of a super-micro bubble generation device which is another embodiment of the present disclosure.Fig. 5(b) is an enlarged cross-section view of a bubble generation medium in accordance with another embodiment. - [
Fig. 6] Fig. 6(a) is an oblique drawing showing the overall configuration of a super-micro bubble generation device which is another embodiment of the present disclosure.Fig. 6(b) is an oblique drawing showing the overall configuration of a super-micro bubble generation device which is another embodiment of the present disclosureFig. 6(c) is an oblique drawing showing the overall configuration of a super-micro bubble generation device which is another embodiment of the present disclosure. - [
Fig. 7 ] It is a cross-section view of the super-micro bubble generation device in accordance with another embodiment of the present invention. - Next, explanation will be given on the mode for carrying out the invention.
- As shown in
Fig. 1(a) and (b) , a super-microbubble generation device 1 is provided with acompressor 2 as a compression machine for delivering gas under pressure, and also with abubble generation medium 3 for discharging the gas, which has been delivered under pressure, as super-micro bubbles into liquid. The super-microbubble generation device 1 is also provided with aliquid jetting device 4 for jetting liquid being the same kind of liquid as the liquid into which the super-micro bubbles are discharged. - The
compressor 2 is a device for delivering gas under pressure into aninternal space 3a of thebubble generation medium 3 through the intermediary of agas supply line 11. The gas delivered under pressure by thecompressor 2 is not limited to air. For example, the gas may be ozone gas or nitrogen gas. And the said liquid may be such as fresh water or sea water of rivers or lakes, water, or industrial wastewater. Furthermore, the said liquid also may be solvent such as pharmaceutical products. In that case, the pharmaceutical products are stirred or mixed by using the said super-micro bubbles. - The gas delivered under pressure by the
compressor 2 passes through thegas supply line 11, and then the gas will be delivered under pressure into theinternal space 3a of thebubble generation medium 3. Thebubble generation medium 3 consists of a high-density compound whose solid texture is made of molecular structure consisting of ionic bonds. Moreover, the said high-density compound is an electrically conductive substance, and thus, bubbles generated from thebubble generation medium 3 are negatively charged. In other words, the super-micro bubbles are negatively charged by addition of free electrons on passing through thebubble generation medium 3, which is the electrically conductive substance. The bubbles would not coalesce in a mass bubble since each bubble act repulsively due to this negative electric charge. For instance, the said electrically conductive substance is made of carbon-based material. - Moreover, as shown in
Fig. 1(b) , thebubble generation medium 3 is porous having a lot oftiny pores 3b of several µm to several dozen µm in diameter. Because of this constitution, the gas delivered under pressure by thecompressor 2 passes through the said pores 3b. In other words, the super-micro bubbles are discharged from thepores 3b into liquid by gas tension of the gas delivered under pressure fromcompressor 2. Because of this constitution, thebubble generation medium 3 consisting of the high-density compound would not deteriorate due to expansion and contraction since the high-density compound is a solid substance which does not have flexibility. Also, the high-density compound would not become eroded due to temporal change since it is made of inorganic material. Thus, the super-microbubble generation device 1 is prevented from damage and degradation. - Moreover, the
bubble generation medium 3 consisting of the high-density compound would not become worn even though liquid flow injected from theliquid jetting device 4 hits the high-density compound because it is activated. Thus, durability of thebubble generation medium 3 has been improved. - The
liquid jetting device 4 is a device for separating super-micro bubbles generated from asurface site 3c of thebubble generation medium 3 by the liquid flow. Theliquid jetting device 4 jets liquid being the same kind of liquid as the liquid into which the super-micro bubbles are discharged. Because of this constitution, the super-micro bubbles can be separated by the liquid flow without influencing fluid composition. Moreover, it is able to prevent different kind of liquid being mixed into the liquid. - As shown in
Fig. 2(a) , the said super-micro bubbles are discharged from thetiny pores 3b. In that split second, as shown inFig. 2(b) , the liquid delivered under pressure by theliquid jetting device 4 rapidly passes through thesurface site 3c, from where the super-micro bubbles are discharged, so as to separate the super-micro bubbles from thesurface site 3c. - Thus, as shown in
Fig. 2(c) , the super-micro bubbles discharged from thesurface site 3c separately move around in the liquid without coalescing with subsequently generated super-micro bubbles or other super-micro bubbles discharged from surroundingpores 3b. Because of this constitution, super-micro bubbles can be generated by using a simple method. Moreover, the super-microbubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements. - Also, the
bubble generation medium 3 may be coated with acoating material 5 which is a covering material. Thecoating material 5 is an inorganic material which has the property that contact angle at which the liquid interface meets the surface of thecoating material 5 is low (for example, if the liquid is water, thecoating material 5 may be made of superhydrophilic material). In this embodiment, thecoating material 5 is made of silica glass. The contact angle signifies wetting force of materials. The value of wetting force will rise as contact angle becomes lower. However, thecoating material 5 is not limited to material which is made of silica glass. - The
coating material 5 is applied to thesurface site 3c of thebubble generation medium 3 so as to cover its surface. The silica glass that makes up thecoating material 5 has the property of lowering the contact angle at which the liquid interface meets the surface of thecoating material 5, and thus thecoating material 5 attracts surrounding liquid instead of shedding. In other words, the liquid spreads on the surface of thecoating material 5 as thin film rather than forming droplets. Also, thecoating material 5 is porous having a lot oftiny pores 5a of several µm to several dozen µm in diameter. Thepores 5a are communicated with thepores 3b of thebubble generation medium 3. - As a result, as shown in
Fig. 3 , the said super-micro bubbles are discharged from thepores 5a of thecoating material 5 into liquid after passing through thepores 3b of thebubble generation medium 3. Here, thecoating material 5 has the property that contact angle at which the liquid interface meets the surface of thecoating material 5 is low. Because of this, the wetting force of thecoating material 5 is high. The surrounding liquid is attracted to thecoating material 5. Thus, a thin liquid film is formed between the super-micro bubbles and thecoating material 5. This makes it easy to separate the super-micro bubbles from thebubble generation medium 3. Thus, the super-micro bubbles would not coalesce in a mass bubble. - Moreover, there is an effect of separating the super-micro bubbles by liquid flow by jetting liquid toward the
bubble generation medium 3 coated with thecoating material 5 from theliquid jetting device 4. There is also an effect of separating the super-micro bubbles by making the contact angle, at which the liquid interface meets the surface of thecoating material 5, smaller. Combination of these effects makes it easy to separate super-micro bubbles. - As shown in
Fig. 4(a) , the super-micro bubbles are generated from thepores 5a after passing through thepores 3b. The super-micro bubbles are easily separated from the surface of thecoating material 5 because the thin liquid film is formed on the surface of thecoating material 5 whereby the super-micro bubbles are generated. In other words, the super-micro bubbles can be easily separated because the liquid film lies between the super-micro bubbles and thecoating material 5. - Also, as shown in
Fig. 4(b) , the super-micro bubbles are generated from thepores 5a. In that split second, the liquid delivered under pressure by theliquid jetting device 4 rapidly passes through the surface of thecoating material 5. Thus, the super-micro bubbles are separated from thesurface site 3c of thebubble generation medium 3. - For this reason, as shown in
Fig. 4(c) , the super-micro bubbles which dwell on the surface of thecoating material 5 will separately move around in the liquid without coalescing with subsequently generated super-micro bubbles or other super-micro bubbles discharged from surroundingpores 5a. Because of this constitution, the super-micro bubbles can be generated by using a simple method. Also, the super-microbubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements. - Next, explanation will be given on the configuration of the
bubble generation medium 3. - As shown in
Fig. 5(a) , thebubble generation medium 3 is formed into a tabular shape. The super-micro bubbles are generated from thesurface site 3c, whose plate area is wider than any other plate face of thebubble generation medium 3. Because thebubble generation medium 3 is formed into a tabular shape with wide surface area, the super-micro bubbles can be generated effectively. Also, because the super-micro bubbles separates from thebubble generation medium 3 as soon as they are generated, they would not coalesce in a mass bubble. - Also, the
liquid jetting device 4 is a device for jetting liquid in the direction substantially perpendicular to the direction in which thebubble generation medium 3 discharges the super-micro bubbles, that is, jetting liquid in the direction parallel to thesurface site 3c, which is the widest of all of plate faces of thegeneration medium 3. The direction of jetting liquid is sufficient if the said direction is substantially perpendicular to the direction in which the super-micro bubbles are discharged, that is, the said direction may be any direction shown inFig. 5(a) as arrow a, arrow b, arrow c, or arrow d. For example, theliquid jetting device 4 has aninjection hole 4a for jetting liquid flow toward thesurface site 3c of the plate face of thebubble generation medium 3. The said liquid flow, whose width is as same as that of thesurface site 3c of the plate face of thebubble generation medium 3, is jetted in the direction parallel to the plate face. - Because of this constitution, as shown in
Fig. 2 , the generated super-micro bubbles separate from thebubble generation medium 3 as soon as they are generated, and thus, the super-micro bubbles would not coalesce in a mass bubble. As just described, the super-micro bubbles can be generated by using a simple method. Also, the super-microbubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements. - Moreover, as shown in
Fig. 5(b) , the super-microbubble generation device 1 in accordance with another embodiment is formed into a hollow polygonal shape. In this embodiment, thebubble generation medium 3 is formed into a hollow square pillar shape. Because of this constitution, gas is discharged from eachsurface site 3c of the square pillar equivalently. Thesurface sites 3c corresponds to longitudinally side walls of the square pillar shape. Thus, the super-micro bubbles can be generated effectively. - Moreover, as shown in
Fig. 5(b) , the liquid is jetted in the same direction parallel to two side walls, which comprise opposing side walls of the square pillar shapedbubble generation medium 3, that is, along the surface of the two side walls in the same direction (direction of arrow A and arrow B). The liquid is also jetted in the same direction parallel to the other two side walls, that is, in the direction opposite to arrow A and arrow B (direction of arrow C and arrow D). - Furthermore, the liquid jetting direction is not limited to such directions shown in this embodiment. For example, the liquid may be jetted in the same direction parallel to all of the side walls. Alternatively, the liquid may be jetted in the same direction parallel to three of the side walls and in the opposite direction parallel to the other side wall.
- Moreover, as shown in
Fig. 6(a) , the super-microbubble generation device 1 in accordance with another embodiment includes thebubble generation medium 3 which is formed into a hollow columnar shape. The gas which has been delivered under pressure passes through thegas supply line 11, and then the gas will be delivered in the columnar shapedinternal space 3a which is provided in the central part of thebubble generation medium 3. Because of this constitution, the gas is discharged from thesurface site 3c, which is the side wall of the column, equivalently in every direction. Thus, the super-micro bubbles can be generated effectively. - Moreover, as shown in
Fig. 6(a) , theliquid jetting device 4 is provided on the periphery of thegas supply line 11. Aninjection hole 4a of theliquid jetting device 4 is formed into a circular shape having a diameter slightly larger than that of the periphery of thebubble generation medium 3. Theliquid jetting device 4 jets zonal liquid flow along thesurface site 3c in the direction same as gas supplying direction. Thesurface site 3c corresponds to longitudinally side wall of thebubble generation medium 3. In this way, the generated super-micro bubbles separate from thebubble generation medium 3 as soon as they are generated, and thus, the super-micro bubbles would not coalesce in a mass bubble. As just described, the super-microbubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements. - Furthermore, the liquid jetting direction is not limited to such directions shown in this embodiment. For example, the liquid may be jetted in a direction opposite to the gas supplying direction.
- Moreover, as shown in
Fig. 6(b) , the super-microbubble generation device 1 in accordance with another embodiment includes thebubble generation medium 3 which is formed into a conical shape. Theinternal space 3a is provided on the principal axis part of section of the said conical shape. The gas delivered under pressure bycompressor 2 passes through thegas supply line 11, and then the gas will be delivered under pressure into theinternal space 3a of thebubble generation medium 3. Because of this constitution, the gas is discharged from thesurface site 3c, which is the side wall of the cone, equivalently in every direction. Thus, the super-micro bubbles can be generated effectively. - Moreover, the
liquid jetting device 4 is facing thebubble generation medium 3. In other words, as shown inFig. 6(b) , theinjection hole 4a of theliquid jetting device 4 is disposed on the extension line that extends from avertex 3d of the cone of thebubble generation medium 3. Theliquid jetting device 4 is a device for jetting liquid toward thevertex 3d of the cone. As just described, since the liquid is jetted toward thevertex 3d of the cone, the liquid will flow radially along thesurface site 3c, which is the side wall of thebubble generation medium 3. In other words, the liquid is jetted in the direction substantially perpendicular to the direction in which thebubble generation medium 3 discharges the super-micro bubbles. - In this way, it is able to make the size of the
injection hole 4a smaller, and thus, lower pressure is needed for jetting the liquid. The generated super-micro bubbles separate from thebubble generation medium 3 as soon as they are generated, and thus, the super-micro bubbles would not coalesce in a mass bubble. As just described, the super-micro bubbles can be generated by using a simple method. Also, the super-microbubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements. - Also, as shown in
Fig. 6(c) , a gas supplying inlet port of thegas supply line 11 may be provided in the direction perpendicular to the height direction of the cone of thebubble generation medium 3. Because of this constitution, it is able to make an effective use of space downstream of the liquid flow. Although the gas supplying inlet port of thegas supply line 11 in this embodiment is provided upside of thebubble generation medium 3, the position of the gas supplying inlet port is not limited to this. For example, the gas supplying inlet port may be provided in the horizontal direction. - Moreover, a
bubble guide groove 55, which is formed around thebubble generation medium 3, is provided downstream of the liquid flow jetted from theliquid jetting device 4. As shown inFig. 7 , thebubble guide groove 55 is formed into an arc-like shape in the cross section view, located downstream of the liquid flow. The bubble guidegrove 55 guides the direction of super-micro bubbles movement. The micro bubbles move from thesurface site 3c of thebubble generation medium 3 by the liquid flow jetted from theliquid jetting device 4. Because of existence thebubble guide groove 55, the super-micro bubbles which are separated from thebubble generation medium 3 will impinge on thebubble guide groove 55. After impingement, the super-micro bubbles will move along thebubble guide groove 55. Thus, it is able to preserve a distance between each super-micro bubble. Accordingly, the super-micro bubbles would not coalesce in a mass bubble. - Moreover, the
bubble generation medium 3 and theliquid jetting device 4, which comprise the super-microbubble generation device 1, may be configured in a unified manner. If constituted in this manner, positional relationship between thegeneration medium 3 and theinjection hole 4a of theliquid jetting device 4 is maintained constant consistently. Accordingly, it is able to save many steps for adjusting position thereof. Moreover, a wall surface facing theliquid jetting device 4 may be inclined in an arc-like shape when seen from a side. Because of this constitution, the direction of super-micro bubbles movement can be guided. The super-micro bubbles move along thesurface site 3c of the plate face of thebubble generation medium 3 by the jetted liquid flow from theliquid jetting device 4. In this way, it is able to preserve a distance between each super-micro bubble. As such, the super-micro bubbles would not coalesce in a mass bubble. - Moreover, the
bubble generation medium 3 may be formed into a tabular shape, wherein severalgas supply lines 11 are provided in parallel inside thebubble generation medium 3. In this case, the gas passes through thegas supply lines 11, and is delivered under pressure into theinternal space 3a of thebubble generation medium 3. Thegas supply lines 11 are branched inside thebubble generation medium 3. The said branchedgas supply lines 11 are arranged in parallel. The super-micro bubbles are generated from thesurface site 3c of thebubble generation medium 3 by gas pressure from thegas supply lines 11. Keeping wide interval between eachgas supply line 11 which is arranged in parallel respectively makes it harder for super-micro bubbles to coalesce in a mass bubble. - However, the numbers or shape of the liquid jetting device is not limited to the state described in this embodiment. For example, more than three liquid jetting devices may be provided. Furthermore, the shape or material of the
gas supply line 11 is not limited to the state described in this embodiment. For example, thegas supply line 11 may be a metallic pipe or a plastic pipe. - The super-micro bubble generation device of the present invention is industrially useful because it can generate super-micro bubbles using a simple method and can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements. In this way, the generated super-micro bubbles separate from the
bubble generation medium 3 as soon as they are generated, and thus, the super-micro bubbles would not coalesce in a mass bubble. As just described, the super-micro bubbles can be generated by using a simple method. Also, the super-microbubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements. -
- 1
- super-micro bubble generation device
- 2
- compressor
- 3
- bubble generation medium
- 4
- liquid jetting device
- 5
- coating material
Claims (3)
- A super-micro bubble generation device (1) comprising:a compressor (2) for delivering gas under pressure, anda bubble generation medium (3) for discharging the gas, which has been delivered under pressure, as super-micro bubbles into liquid,wherein the said bubble generation medium (3) consists of a high-density compound which is an electrically conductive substance, and wherein said bubble generation medium (3) is porous having a lot of tiny pores (3b) of several µm to several dozen µm in diameter, andfurther comprising a liquid jetting device (4) for jetting liquid in the direction substantially perpendicular to the direction in which the bubble generation medium (3) discharges the super-micro bubbles, said liquid being the same kind of liquid as the liquid into which the super-micro bubbles are discharged, characterised in that a bubble guide groove (55), which is formed around the bubble generation medium (3), is provided downstream of the liquid flow jetted from the liquid jetting device (4), the bubble guide groove (55) is formed into an arc-like shape in the cross section view, located downstream of the liquid flow and guides the direction of super-micro bubbles movement.
- The super-micro bubble generation device (1) as claimed in claim 1, characterized in that the said bubble generation medium (3) is formed into a conical shape, and in that the gas from the said compressor (2) passes through the said bubble generation medium (3) from a bottom face of the cone toward a vertex (3d), wherein the said liquid being the same kind of liquid as the liquid into which the super-micro bubbles are discharged is jetted toward the vertex (3d) of the cone of the said bubble generation medium (3) by the said liquid jetting device (4).
- The super-micro bubble generation device (1) as claimed in claim 1 or claim 2, characterized in that an outer periphery of the said bubble generation medium (3) is covered with a covering material, wherein the said covering material has the property of lowering the contact angle at which the liquid meets the surface of it.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL10804452T PL2460582T3 (en) | 2009-07-30 | 2010-07-28 | Super-micro bubble generation device |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009177693A JP5885376B2 (en) | 2008-07-30 | 2009-07-30 | Ultra-fine bubble generator |
PCT/JP2010/062705 WO2011013706A1 (en) | 2009-07-30 | 2010-07-28 | Super-micro bubble generation device |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2460582A1 EP2460582A1 (en) | 2012-06-06 |
EP2460582A4 EP2460582A4 (en) | 2015-10-28 |
EP2460582B1 true EP2460582B1 (en) | 2020-06-24 |
Family
ID=43530013
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10804452.0A Active EP2460582B1 (en) | 2009-07-30 | 2010-07-28 | Super-micro bubble generation device |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP2460582B1 (en) |
DK (1) | DK2460582T3 (en) |
ES (1) | ES2807880T3 (en) |
PL (1) | PL2460582T3 (en) |
WO (1) | WO2011013706A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110575764B (en) * | 2018-06-07 | 2024-08-20 | 芙特碳汇(北京)科技有限公司 | Heat and mass transfer device |
GB202018966D0 (en) | 2020-12-01 | 2021-01-13 | Epigenetica Ltd | Method and system to improve plant characteristics |
GB202103986D0 (en) | 2021-03-22 | 2021-05-05 | Epigenetica Ltd | Plant propagation |
WO2023214041A1 (en) | 2022-05-05 | 2023-11-09 | Epigenetica Limited | Processes, systems and media for delivering a substance to a plant |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1362789A (en) * | 1970-09-24 | 1974-08-07 | British Oxygen Co Ltd | Treatment of liquids |
JPS5647726U (en) * | 1979-09-19 | 1981-04-28 | ||
US4522151A (en) * | 1983-03-14 | 1985-06-11 | Arbisi Dominic S | Aerator |
ZA919256B (en) * | 1990-11-23 | 1992-11-25 | Atomaer Pty Ltd | Gas particle formation |
JP2003245533A (en) * | 2002-02-22 | 2003-09-02 | Mori Kikai Seisakusho:Kk | Ultrafine air bubble generator |
JP4884693B2 (en) * | 2004-04-28 | 2012-02-29 | 独立行政法人科学技術振興機構 | Micro bubble generator |
JP4140584B2 (en) * | 2004-08-26 | 2008-08-27 | Jfeエンジニアリング株式会社 | Air diffuser |
JP2007260529A (en) * | 2006-03-28 | 2007-10-11 | Kenji Ijuin | Air diffusion nozzle and air diffusion tank |
JP3958346B1 (en) | 2006-07-11 | 2007-08-15 | 南舘 誠 | Microbubble generator |
JP2008132437A (en) * | 2006-11-29 | 2008-06-12 | Kubota Corp | Microbubble generation apparatus |
-
2010
- 2010-07-28 WO PCT/JP2010/062705 patent/WO2011013706A1/en active Application Filing
- 2010-07-28 EP EP10804452.0A patent/EP2460582B1/en active Active
- 2010-07-28 DK DK10804452.0T patent/DK2460582T3/en active
- 2010-07-28 ES ES10804452T patent/ES2807880T3/en active Active
- 2010-07-28 PL PL10804452T patent/PL2460582T3/en unknown
Non-Patent Citations (1)
Title |
---|
None * |
Also Published As
Publication number | Publication date |
---|---|
WO2011013706A1 (en) | 2011-02-03 |
ES2807880T3 (en) | 2021-02-24 |
EP2460582A1 (en) | 2012-06-06 |
PL2460582T3 (en) | 2020-11-16 |
EP2460582A4 (en) | 2015-10-28 |
DK2460582T3 (en) | 2020-08-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US8919747B2 (en) | Super-micro bubble generation device | |
KR101523187B1 (en) | Bubbles generation device and method | |
JP4802154B2 (en) | Ultrafine bubble generator | |
JP4893365B2 (en) | Microbubble generator and microbubble generator system | |
EP2460582B1 (en) | Super-micro bubble generation device | |
KR101483412B1 (en) | Micro bubble nozzle | |
KR101053447B1 (en) | Rotary bubble jet diffuser | |
EA036231B1 (en) | Nano-bubble generator and method of generating nano-bubbles | |
KR101654775B1 (en) | Gas/liquid mixing circulatory flow generating device | |
KR101163089B1 (en) | Air dossoving tube and dissolved air injection type flotation tank | |
KR101213829B1 (en) | Micro-bubble generating system for purifying wastewater | |
KR100582267B1 (en) | Microbubble generation method using microfilter and apparatus for same | |
JP2003245533A (en) | Ultrafine air bubble generator | |
CN112337327B (en) | Nanometer bubble generating device | |
EP2889079B1 (en) | Nozzle for dissolved air flotation system | |
KR101130816B1 (en) | Flotation tank for rotary injection of nano size bubble | |
KR101688638B1 (en) | Apparatus for cleaning organic matter using fine ozone bubble | |
JP5774848B2 (en) | Water quality improvement device and water quality improvement method | |
KR200359766Y1 (en) | A device to manufacture micro bubble using by micro-filter | |
GB2484070A (en) | Fine bubble generation device | |
WO2002053505A1 (en) | Device and method for of water purification | |
KR102562944B1 (en) | A Head Assembly for Generating Microbubble and a Microbubble Generator Comprising the Same | |
JP4982730B2 (en) | Micro bubble generation nozzle | |
CN113060788A (en) | Novel micro-nano air supporting machine | |
JP2004136155A (en) | Dam discharge water modifying apparatus and dam discharge water modifying method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20120229 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
DAX | Request for extension of the european patent (deleted) | ||
RA4 | Supplementary search report drawn up and despatched (corrected) |
Effective date: 20150925 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: B01F 3/04 20060101ALI20150921BHEP Ipc: B01F 5/02 20060101AFI20150921BHEP |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
17Q | First examination report despatched |
Effective date: 20180221 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20191108 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: ANZAI SATOSHI Inventor name: NISHI SUSUMU |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAJ | Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted |
Free format text: ORIGINAL CODE: EPIDOSDIGR1 |
|
GRAL | Information related to payment of fee for publishing/printing deleted |
Free format text: ORIGINAL CODE: EPIDOSDIGR3 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
INTC | Intention to grant announced (deleted) | ||
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: ANZAI, SATOSHI |
|
GRAR | Information related to intention to grant a patent recorded |
Free format text: ORIGINAL CODE: EPIDOSNIGR71 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
INTG | Intention to grant announced |
Effective date: 20200513 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1283340 Country of ref document: AT Kind code of ref document: T Effective date: 20200715 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602010064740 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
REG | Reference to a national code |
Ref country code: DK Ref legal event code: T3 Effective date: 20200812 |
|
REG | Reference to a national code |
Ref country code: NO Ref legal event code: T2 Effective date: 20200624 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: FP |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200925 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200924 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 1283340 Country of ref document: AT Kind code of ref document: T Effective date: 20200624 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201026 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2807880 Country of ref document: ES Kind code of ref document: T3 Effective date: 20210224 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201024 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602010064740 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: HU Ref legal event code: AG4A Ref document number: E051647 Country of ref document: HU |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20200731 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200731 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200731 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200728 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200731 |
|
26N | No opposition filed |
Effective date: 20210325 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R079 Ref document number: 602010064740 Country of ref document: DE Free format text: PREVIOUS MAIN CLASS: B01F0005020000 Ipc: B01F0025200000 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200624 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20240726 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20240731 Year of fee payment: 15 Ref country code: IE Payment date: 20240730 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DK Payment date: 20240730 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20240730 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20240730 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20240828 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: PL Payment date: 20240723 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: HU Payment date: 20240823 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NO Payment date: 20240731 Year of fee payment: 15 Ref country code: SE Payment date: 20240730 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: TR Payment date: 20240722 Year of fee payment: 15 |