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EP2413880B1 - Kapillarzusammensetzung zur haarbehandlung - Google Patents

Kapillarzusammensetzung zur haarbehandlung Download PDF

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Publication number
EP2413880B1
EP2413880B1 EP09784370.0A EP09784370A EP2413880B1 EP 2413880 B1 EP2413880 B1 EP 2413880B1 EP 09784370 A EP09784370 A EP 09784370A EP 2413880 B1 EP2413880 B1 EP 2413880B1
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EP
European Patent Office
Prior art keywords
hair
weight
polymers
composition
alkyl
Prior art date
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EP09784370.0A
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English (en)
French (fr)
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EP2413880A1 (de
Inventor
Samira Khenniche
Isabelle Rollat-Corvol
Sophie Bourel
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LOreal SA
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LOreal SA
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/965—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the invention aims inter alia to meet this need and it achieves this through a hair treatment process using a hair composition
  • a hair composition comprising at least pumice particles, one or more silicones with quaternary ammonium groups and one or more non-silicone polymers.
  • the treatment of the hair which is operated by implementing the invention may be more or less important, depending on the initial state of the hair and / or the desired result.
  • This treatment may in particular have the effect of including an elimination of heterogeneities on the surface of the hair, especially via an action that can be described as abrasive and, therefore, homogenize the outer surface of the hair.
  • the hair can be visibly smoother and the effect of the treatment is durable.
  • Pumice is made of fragments of rhyolite, dacite or andesite. It is considered a glass because it does not have a crystalline structure.
  • Pumice particles are abrasive solid particles. In particular, they may have a hardness greater than or equal to that of hair, ranging from 3 to 10 Mohs, or even greater than or equal to 4, for example greater than or equal to 5, and in particular ranging from 5 to 5.5 Mohs scale.
  • It may also be a decontaminated pumice powder marketed under the reference 0-D PONCE by EYRAUD, with a mean diameter by volume of less than 125 ⁇ m, or a pumice powder sold under the reference 2B D by EYRAUD Company, of average diameter by volume ranging from 100 to 500 microns.
  • the quaternary ammonium group silicone is of formula (XXIII). Even more preferentially, the quaternary ammonium group silicone is the compound referred to CTFA (INCI name) under the name Quaternium-80.
  • the non-silicone polymer (s) may be chosen from thickening, fixing or conditioning polymers, nonionic, anionic, cationic or amphoteric polymers.
  • sucgar unit means a unit derived from a carbohydrate of formula C n (H 2 O) n-1 or (CH 2 O) n which may be optionally modified by substitution and / or by oxidation and / or or by dehydration.
  • polymers can be modified physically or chemically.
  • a physical treatment mention may in particular be made of temperature.
  • nonionic guar gums which may be used according to the invention may be modified with hydroxylalkyl groups of C 1 -C 6 .
  • hydroxyalkyl groups there may be mentioned by way of example, the hydroxymethyl, hydroxyethyl, hydroxypropyl and hydroxybutyl groups.
  • guar gums are well known in the state of the art and may for example be prepared by reacting corresponding alkene oxides such as, for example, propylene oxides with guar gum so as to obtain a guar gum. modified by hydroxypropyl groups.
  • the starches can be modified chemically or physically: in particular by one or more of the following reactions: pregelatinization, oxidation, crosslinking, esterification, etherification, amidification, heat treatments.
  • the phosphorus compounds may be, for example, sodium tripolyphosphate, sodium orthophosphate, phosphorus oxychloride or sodium trimetaphosphate.
  • Diamidon phosphates or diamidon phosphate-rich compounds such as the product proposed under the references PREJEL VA-70-T AGGL (hydroxypropylated gelatinized hydroxypropyl diamidon phosphate) or PREJEL TK1 (gelatinized manioc diamidon phosphate) are preferably used.
  • PREJEL 200 (gelatinized acetylated manioc diamidon phosphate) by the company AVEBE or STRUCTURE ZEA by NATIONAL STARCH (gelatinized cornstarch).
  • a preferred starch is a starch which has undergone at least one chemical modification such as at least one esterification.
  • the starch molecules can be derived from all plant sources of starch, such as in particular corn, potato, oats, rice, tapioca, sorghum, barley or wheat. It is also possible to use the hydrolysates of the starches mentioned above.
  • the starch is preferably from the potato.
  • Starches of formula (III) or (IV) are particularly used.
  • 2-Chloroethylaminodipropionic acid-modified starches that is to say the starches of formula (III) or (IV) in which R, R ', R "and M represent a hydrogen atom, are more particularly used. and n is 2.
  • the preferred amphoteric starch is a starch chloroethylamidodipropionate.
  • the cellulose derivatives may in particular be anionic, amphoteric or nonionic.
  • the cellulose esters there are the inorganic esters of cellulose, for example the cellulose nitrates, sulphates or phosphates, the organic cellulose esters, for example the monoacetates, triacetates, amidopropionates, acetatebutyrates, cellulose acetate propionates or acetatetrimellitates and mixed organic / inorganic cellulose esters such as cellulose acetate and sulphate acetate sulphates.
  • the cellulose ether esters mention may be made of hydroxypropyl methylcellulose phthalates and ethylcellulose sulphates.
  • alkylcelluloses such as methylcelluloses and ethylcelluloses (for example Ethocel Standard 100 Premium from DOW CHEMICAL); hydroxyalkylcelluloses such as hydroxymethylcelluloses, hydroxyethylcelluloses (for example Natrosol 250 HHR proposed by AQUALON) and hydroxypropylcelluloses (for example Klucel EF from AQUALON); mixed hydroxyalkyl-alkylcellulose celluloses such as hydroxypropyl-methylcelluloses (for example Methocel E4M from Dow Chemical), hydroxyethyl-methylcelluloses, hydroxyethylethylcellulose (for example Bermocoll E 481 FQ from Akzo Nobel) and hydroxybutyl-methylcelluloses.
  • alkylcelluloses such as methylcelluloses and ethylcelluloses (for example Ethocel Standard 100 Premium from DOW CHEMICAL); hydroxyalkylcelluloses such as hydroxymethylcelluloses, hydroxyethylcelluloses (for example Nat
  • non-associative thickening polymers without sugar units which may be used, mention may be made of homopolymers or copolymers of crosslinked acrylic or methacrylic acid, crosslinked homopolymers of 2-acrylamido-2-methylpropanesulphonic acid and their crosslinked copolymers of acrylamide, homopolymers of ammonium acrylate or copolymers of ammonium acrylate and acrylamide alone or mixtures thereof.
  • a first family of suitable nonassociative thickening polymers is represented by crosslinked acrylic acid homopolymers.
  • homopolymers of this type mention may be made of those crosslinked with an allylic alcohol ether of the sugar series, such as, for example, the products sold under the names CARBOPOL 980, 981, 954, 2984 and 5984 by the company NOVEON or the products sold under the names SYNTHALEN M and SYNTHALEN K by the company 3 VSA.
  • an allylic alcohol ether of the sugar series such as, for example, the products sold under the names CARBOPOL 980, 981, 954, 2984 and 5984 by the company NOVEON or the products sold under the names SYNTHALEN M and SYNTHALEN K by the company 3 VSA.
  • the non-associative thickening polymers may also be crosslinked (meth) acrylic acid copolymers such as the polymer sold under the name AQUA SF1 by the company NOVEON.
  • the non-associative thickening polymers may be chosen from cross-linked homopolymers of 2-acrylamido-2-methylpropanesulphonic acid and their crosslinked acrylamide copolymers.
  • polymers comprising from 90 to 99.9% by weight, relative to the total weight of the polymer, of units of formula (j) below: wherein X + denotes a cation or mixture of cations, or a proton.
  • the cations are chosen from alkali metals (such as sodium, potassium), ammonium ions substituted or not by one to three identical or different alkyl radicals, comprising 1 to 6 carbon atoms, optionally carrying at least a hydroxyl radical, the cations derived from N-methylglucamine, basic amino acids such as arginine and lysine.
  • the cation is an ammonium or sodium ion.
  • the polymer comprises from 0.01 to 10% by weight, relative to the total weight of the polymer, of crosslinking units derived from at least one monomer having at least two ethylenic unsaturations (carbon-carbon double bond).
  • the crosslinking monomers having at least two ethylenic unsaturations are chosen for example from diallyl ether, triallyl cyanurate, diallyl maleate, allyl (meth) acrylate, dipropylene glycol diallyl ether, polyglycol diallyl ether, triethylene glycol divinyl ether, hydroquinone-diallyl-ether, tetralyl-oxethanoyl, tetra- or di-ethylene glycol di (meth) acrylate, triallylamine, tetraallylethylenediamine, trimethylolpropane-diallylether, trimethylolpropane triacrylate, methylenebis (meth) acrylamide or divinylbenzene, allyl ethers of alcohols of the series of sugars, or other allyl- or vinylethers polyfunctional alcohols, as well as the allylic esters of the phosphoric and / or vinylphosphonic acid derivatives, or the mixtures of these
  • crosslinked copolymers of 2-acrylamido-2-methyl-propanesulfonic acid and of acrylamide partially or totally neutralized mention may be made in particular of the product described in Example 1 of the document EP 503 853 and reference can be made to this document with respect to these polymers.
  • composition may also comprise, as non-associative thickening polymers, homopolymers of ammonium acrylate or copolymers of ammonium acrylate and acrylamide.
  • homopolymers of ammonium acrylate mention may be made of the product sold under the name MICROSAP PAS 5193 by the company HOECHST.
  • copolymers of ammonium acrylate and acrylamide mention may be made of the product sold under the name BOZEPOL C NEW or the PAS 5193 product sold by HOECHST.
  • documents may be referred to FR 2,416,723 , US 2,798,053 and US 2,923,692 for the description and preparation of such compounds.
  • thickeners mention may also be made of thickening systems based on associative polymers well known to those skilled in the art and in particular of nonionic, anionic, cationic or amphoteric nature.
  • associative polymers are polymers capable, in an aqueous medium, to associate reversibly with each other or with other molecules.
  • Their chemical structure more particularly comprises at least one hydrophilic zone and at least one hydrophobic zone.
  • Hydrophobic group is understood to mean a radical or polymer with a saturated or unsaturated, linear or branched hydrocarbon-based chain, comprising at least 10 carbon atoms, preferably from 10 to 30 carbon atoms, in particular from 12 to 30 carbon atoms, and more preferably from 18 to 30 carbon atoms.
  • the hydrocarbon group comes from a monofunctional compound.
  • the hydrophobic group may be derived from a fatty alcohol such as stearyl alcohol, dodecyl alcohol or decyl alcohol. It can also denote a hydrocarbon polymer such as for example polybutadiene.
  • Anionic associative polymers of this type are described and prepared according to an emulsion polymerization process in the patent. EP-0 216 479 .
  • anionic associative polymers polymers formed from 20 to 60% by weight of acrylic acid and / or methacrylic acid, from 5 to 60% by weight of (meth) acrylates, are particularly preferred according to the invention. from lower alkyls, from 2 to 50% by weight of fatty-chain allyl ether of formula (VI), and from 0 to 1% by weight of a crosslinking agent which is a well-known copolymerizable polyethylenic unsaturated monomer, such as diallyl phthalate, allyl (meth) acrylate, divinylbenzene, (poly) ethylene glycol dimethacrylate, and methylenebisacrylamide.
  • a crosslinking agent which is a well-known copolymerizable polyethylenic unsaturated monomer, such as diallyl phthalate, allyl (meth) acrylate, divinylbenzene, (poly) ethylene glycol dimethacrylate, and methylenebisacrylamide.
  • these polymers are chosen from those whose hydrophilic unit of olefinic unsaturated carboxylic acid type corresponds to the following monomer of formula (VII): in which, R 1 denotes H or CH 3 or C 2 H 5 , that is to say acrylic acid, methacrylic acid or ethacrylic acid units, and whose hydrophobic unit of alkyl ester type (C 10 -C 30 ) of unsaturated carboxylic acid corresponds to the monomer of formula (VIII) below: in which, R 2 denotes H or CH 3 or C 2 H 5 (that is, acrylate, methacrylate or ethacrylate units) and preferably H (acrylate units) or CH 3 (methacrylate units), R 3 denoting a C 10 -C 30 alkyl radical, and preferably a C 12 -C 22 alkyl radical.
  • R 1 denotes H or CH 3 or C 2 H 5 , that is to say acrylic acid, methacrylic acid or ethacrylic acid units
  • (C 10 -C 20 ) alkyl esters of unsaturated carboxylic acids in accordance with the invention include, for example, lauryl acrylate, stearyl acrylate, decyl acrylate, isodecyl acrylate, and the like. , dodecyl acrylate, and corresponding methacrylates, lauryl methacrylate, stearyl methacrylate, decyl methacrylate, isodecyl methacrylate, and dodecyl methacrylate.
  • Anionic polymers of this type are, for example, described and prepared according to the patents US 3,915,921 and 4509949 .
  • anionic associative polymers use will more particularly be made of 60 to 95% by weight of acrylic acid (hydrophilic unit), 4 to 40% by weight of C 10 -C 30 alkyl acrylate ( hydrophobic unit), and 0 to 6% by weight of polymerizable crosslinking monomer, or those consisting of 96 to 98% by weight of acrylic acid (hydrophilic unit), 1 to 4% by weight of C-alkyl acrylate 10 -C 30 (hydrophobic unit), and 0.1 to 0.6% by weight of crosslinking polymerizable monomer such as those described above.
  • polymers which, in addition to the monomers of formula (VII) and of formula (VIII), contain one or more other monomers.
  • This additional monomer can be in particular a vinyllactam and in particular vinylpyrrolidone.
  • these compounds also comprise, as monomer, an ester of carboxylic acid with ⁇ , ⁇ -monoethylenic unsaturation and of C 1 -C 4 alcohol.
  • (meth) acrylamido (C 1 -C 22 ) alkylsulfonic acids such as, for example, acrylamido-methanesulfonic acid, acrylamido-ethanesulfonic acid, acrylamido-propanesulfonic acid, 2-acrylamido-2-methylpropanesulfonic acid, methacrylamido-2-methylpropanesulfonic acid, 2-acrylamido-n-butanesulfonic acid, acid 2-acrylamido-2,4,4-trimethylpentanesulfonic acid, 2-methacrylamido-dodecylsulphonic acid, 2-acrylamido-2,6-dimethyl-3-heptanesulfonic acid and their partially or totally neutralized.
  • acrylamido-methanesulfonic acid acrylamido-ethanesulfonic acid
  • acrylamido-propanesulfonic acid 2-acrylamido-2-methylpropanesulf
  • APMS 2-acrylamido-2-methylpropanesulfonic acid
  • the polymers of this family may especially be chosen from AMPS random amphiphilic polymers modified by reaction with a n-monoalkylamine or a C 6 -C 22 di-n-alkylamine, and such as those described in the patent application. WO 00/31154 , forming an integral part of the content of the description.
  • These polymers may also contain other hydrophilic ethylenically unsaturated monomers chosen, for example, from (meth) acrylic acids, their ⁇ -substituted alkyl derivatives or their esters obtained with monoalcohols or mono- or polyalkylene glycols, (meth) acrylamides vinylpyrrolidone, maleic anhydride, itaconic acid or maleic acid or mixtures of these compounds.
  • hydrophilic ethylenically unsaturated monomers chosen, for example, from (meth) acrylic acids, their ⁇ -substituted alkyl derivatives or their esters obtained with monoalcohols or mono- or polyalkylene glycols, (meth) acrylamides vinylpyrrolidone, maleic anhydride, itaconic acid or maleic acid or mixtures of these compounds.
  • the preferred polymers of this family are chosen from amphiphilic copolymers of AMPS and at least one hydrophobic monomer with ethylenic unsaturation.
  • copolymers may also contain one or more ethylenically unsaturated monomers not containing a fatty chain, such as (meth) acrylic acids, their ⁇ -substituted alkyl derivatives or their esters obtained with monoalcohols or mono- or polyalkylene glycols, (meth) acrylamides, vinylpyrrolidone, maleic anhydride, itaconic acid or maleic acid or mixtures thereof.
  • acrylic acids their ⁇ -substituted alkyl derivatives or their esters obtained with monoalcohols or mono- or polyalkylene glycols
  • (meth) acrylamides vinylpyrrolidone
  • maleic anhydride itaconic acid or maleic acid or mixtures thereof.
  • the hydrophobic monomers with ethylenic unsaturation of these particular copolymers are preferably chosen from the acrylates or acrylamides of formula (IX) below: in which R 1 and R 3 , which may be identical or different, denote a hydrogen atom or a linear or branched C 1 -C 6 alkyl radical (preferably methyl); Y is O or NH; R 2 denotes a hydrophobic hydrocarbon radical containing at least 8 and more preferably 8 to 22 carbon atoms and even more preferably 8 to 18 carbon atoms and more particularly 12 to 18 carbon atoms; x denotes a number of moles of alkylene oxide and ranges from 0 to 100.
  • R 1 and R 3 which may be identical or different, denote a hydrogen atom or a linear or branched C 1 -C 6 alkyl radical (preferably methyl); Y is O or NH; R 2 denotes a hydrophobic hydrocarbon radical containing at least 8 and more preferably 8 to 22 carbon
  • the radical R 2 is preferably chosen from linear C 8 -C 18 alkyl (for example n-hexyl, n-octyl, n-decyl, n-hexadecyl, n-dodecyl), branched or cyclic (for example cyclododecane radicals).
  • C 12 or adamantane (C 10 )); perfluorinated C 6 -C 18 alkyl radicals (for example the group of formula - (CH 2 ) 2 - (CF 2 ) 9 -CF 3 ); the cholesteryl radical (C 27 ) or a cholesteryl ester residue such as the cholesteryl oxyhexanoate group; polycyclic aromatic groups such as naphthalene or pyrene.
  • linear alkyl radicals, and more particularly the n-dodecyl radical are more particularly preferred.
  • the monomer of formula (IX) comprises at least one alkylene oxide unit (x ⁇ 1) and preferably a polyoxyalkylene chain.
  • the polyoxyalkylene chain is preferably composed of ethylene oxide units and / or propylene oxide units and even more particularly ethylene oxide units.
  • the number of oxyalkylenated units generally varies from 3 to 100, and more preferably from 3 to 50 and even more preferably from 7 to 25, better still from 8 to 25.
  • the only hydrophobic groups are the R and R 'groups at the chain ends.
  • the number-average molecular weight of the cationic associative polyurethanes is preferably between 400 and 500,000, in particular between 1,000 and 400,000 and ideally between 1,000 and 300,000.
  • Hydrophobic group is understood to mean a radical or polymer with a hydrocarbon chain, saturated or unsaturated, linear or branched, which may contain one or more heteroatoms such as P, O, N, S, or a perfluorinated or silicone chain radical.
  • the hydrophobic group comprises at least 10 carbon atoms, preferably from 10 to 30 carbon atoms, in particular from 12 to 30 carbon atoms and more preferably from 18 to 30 carbon atoms.
  • hydrophilic group means a water-soluble polymeric group or not.
  • a first type of compound used in the preparation of the polyurethane of formula (XII) is a compound comprising at least one amine functional unit.
  • This compound can be multifunctional, but preferentially the compound is difunctional, that is to say that according to a preferred embodiment, this compound comprises two labile hydrogen atoms carried for example by a hydroxyl function, primary amine, secondary amine or thiol. It is also possible to use a mixture of multifunctional and difunctional compounds in which the percentage of multifunctional compounds is low.
  • hydrophilic polymer When it is a hydrophilic polymer, mention may be made by way of example of polyethers, sulphonated polyesters, sulphonated polyamides, or a mixture of these polymers.
  • the hydrophilic compound is a polyether and especially a poly (ethylene oxide) or poly (propylene oxide).
  • the counterion Z - monomers of formula (XIII) is chosen from halide ions, phosphate ions, methosulphate ion, tosylate ion.
  • the cationic poly (vinyllactam) polymers according to the invention may also contain one or more additional monomers, preferably cationic or nonionic monomers.
  • the terpolymers comprising, by weight, 40 to 95% of monomer (a), 0.1 to 55% of monomer (c) and 0.25 to 50% of monomer (b) will be used.
  • poly (vinyllactam) polymers particularly using the vinylpyrrolidone / dimethylaminopropylmethacrylamide / dodecyldimethylmethacrylamidopropylammonium tosylate, the terpolymers vinylpyrrolidone / dimethylaminopropylmethacrylamide / cocoyldiméthylméthacrylamidopropylammonium tosylate, the terpolymers vinylpyrrolidone / dimethylaminopropylmethacrylamide / tosylate or chloride lauryldiméthylméthacrylamidopropylammonium.
  • the monomers of formula (XX) of the present invention are preferably chosen from the group consisting of C 12 -C 22 and more particularly C 16 -C 18 alkyl acrylates or methacrylates.
  • the ratio of the number of cationic charges / anionic charges is preferably equal to about 1.
  • amphoteric associative polymers of this family may also contain other monomers such as nonionic monomers and in particular such as C 1 -C 4 alkyl acrylates or methacrylates.
  • Amphoteric associative polymers according to the invention are for example described and prepared in the patent application. WO / 9844012 .
  • amphoteric associative polymers acrylic acid / (meth) acrylamidopropyltrimethylammonium chloride / stearyl methacrylate terpolymers are preferred.
  • the polyether polyurethanes comprise at least two hydrocarbon-based lipophilic chains having from 6 to 30 carbon atoms, separated by a hydrophilic sequence, the hydrocarbon chains possibly being pendant chains or chains at the end of the hydrophilic sequence.
  • the polymer may comprise a hydrocarbon chain at one end or at both ends of a hydrophilic block.
  • the polyether polyurethanes may be multiblocked, in particular in the form of a triblock.
  • the hydrophobic sequences may be at each end of the chain (for example: hydrophilic central block triblock copolymer) or distributed at both the ends and in the chain (multiblock copolymer for example). These same polymers may also be graft or star.
  • polyether polyurethanes that can be used according to the invention are in particular those described in the article of G. Fonnum, J. Bakke and Fk. Hansen - Colloid Polym. Sci 271, 380,389 (1993) ).
  • a polyether polyurethane obtainable by polycondensation of at least three compounds comprising (i) at least one polyethylene glycol comprising from 150 to 180 moles of ethylene oxide, (ii) alcohol stearyl or decyl alcohol and (iii) at least one diisocyanate.
  • the thickening polymer or polymers of the invention are chosen from associative or non-associative sugar-containing polymers, associative or non-associative acrylic or methacrylic anionic polymers, and associative or non-associative polyurethanes.
  • the preferred conditioning polymers are preferably chosen from cationic or amphoteric and preferably cationic conditioning polymers.
  • non-silicone polymers of the invention are chosen from associative or non-associative sugar-containing polymers, and more preferably from hydroxyethylcellulose and hydroxypropyl guar polysaccharides.
  • the non-silicone polymer or polymers may in particular be present in a content ranging from 0.01% to 20% by weight, preferably from 0.1% to 10% by weight and better still from 0.2% to 5% by weight, relative to total weight of the composition.
  • the hair composition may comprise one or more additives.
  • the hair composition may thus comprise one or more additional surfactants such as anionic, amphoteric, zwitterionic or nonionic surfactants.
  • the additional surfactant or surfactants are preferably chosen from nonionic surfactants.
  • Nonionic surfactants are well known compounds per se (see in this connection in particular "Handbook of Surfactants” by MR Porter, Blackie & Son editions (Glasgow and London), 1991, pp 116-178 ). Thus, they can be chosen in particular from (nonlimiting list) alcohols, alpha-diols, alkylphenols polyethoxylated, polypropoxylated, having a fatty chain comprising for example 8 to 18 carbon atoms, the number of ethylene oxide groups or propylene oxide ranging in particular from 2 to 50.
  • polyethoxylated fatty amides preferably having from 2 to 30 moles of ethylene oxide, polyglycerolated fatty amides comprising on average 1 to 5 glycerol groups and in particular
  • the nonionic surfactant (s) may be present in the hair composition in concentrations ranging from 0.1% to 25% by weight and preferably from 1% to 20% by weight relative to the total weight of the composition.
  • aliphatic secondary or tertiary amine derivatives in which the aliphatic radical is a linear or branched chain containing from 8 to 18, may be mentioned without intending to be limited thereto.
  • Examples include the cocoamphodiacetate marketed under the trade name Miranol ® C2M concentrate by the company Rhodia Chimie.
  • salts in particular alkaline salts, in particular of sodium, ammonium salts, amine salts, aminoalcohol salts or magnesium salts
  • alkyl sulphates alkyl ether sulphates, alkyl amido ether sulphates, alkyl aryl polyether sulphates, monoglyceride sulphates
  • alkylsulfonates alkylphosphates, alkylamidesulfonates, alkylarylsulfonates, ⁇ -olefin sulfonates, paraffin sulfonates
  • C 6 -C 24 alkylsulphosuccinates, (C 6 -C 24 ) alkylsulphosuccinates, (C 6 -C 24 ) alkylamidesulfosuccinates;
  • alkyl polyglycoside carboxylic esters such as citrate alkylglucosides, alkylpolyglycoside tartrates and alkylpolyglycoside sulfosuccinates, alkylsulfosuccinamates; acylisethionates and N-acyltaurates, the alkyl or acyl radical of all these different compounds preferably comprising from 12 to 20 carbon atoms, and the aryl radical preferably denoting a phenyl or benzyl group.
  • anionic surfactants that can still be used, mention may also be made of fatty acid salts such as the salts of oleic, ricinoleic, palmitic and stearic acids, coconut oil acid or hydrogenated coconut oil acid; acyl lactylates whose acyl radical has 8 to 20 carbon atoms.
  • alkyl D galactoside uronic acids and their salts the polyoxyalkylenated (C 6 -C 24 ) alkyl carboxylic ether acids, the polyoxyalkylenated (C 6 -C 24 ) alkyl aryl ether carboxylic acids and the alkyl (C) alkyl acids. 6 -C 24 ) polyoxyalkylenated carboxylic amido ether and their salts, in particular those containing from 2 to 50 alkylene oxide groups, in particular ethylene, and mixtures thereof.
  • the optionally present anionic surfactants are preferably mild anionic surfactants.
  • polyoxyalkylenated alkyl ether carboxylic acids for example lauryl ether carboxylic acid (4.5 EO) sold, for example, under the name AKYPO RLM 45 CA from KAO.
  • anionic or amphoteric surfactants are present, then their content ranges from 0.1 to 20% by weight, relative to the total weight of the hair composition, more particularly from 1 to 10% by weight, relative to the total weight of the composition.
  • the hair composition does not contain sulfate anionic detergent surfactant (alkyl sulfate or alkyl ether sulfate, alkyl amido ether sulfate). And if it contains, its content is such that the weight ratio: anionic detergent surfactant of alkyl sulfate or alkyl ether sulfate type / sum of other non-cationic surfactants, preferably less than or equal to 1, and more particularly less than or equal to 0.75 and even more preferably less than or equal to 0.5.
  • anionic detergent surfactant of alkyl sulfate or alkyl ether sulfate type sum of other non-cationic surfactants, preferably less than or equal to 1, and more particularly less than or equal to 0.75 and even more preferably less than or equal to 0.5.
  • compositions of the invention may also contain one or more cationic surfactants.
  • cationic surfactants mention may be made, for example, of those comprising at least one ester function.
  • the hair composition may furthermore comprise the conventional additives in the field, for example those chosen from the non-exhaustive list, such as reducing agents, oxidizing agents, sequestering agents, softeners, antifoam agents, moisturizing agents, emollient agents, alkalizing agents, plasticizers, sunscreens, direct or oxidation dyes, perfumes, peptizers, preservatives, vitamins, anti-dandruff agents, antiseborrhoeic agents, hair loss agents, agents non-polymeric thickeners such as fatty amides, fatty ethers, fatty alcohols, silicas, clays, etc.
  • the conventional additives in the field for example those chosen from the non-exhaustive list, such as reducing agents, oxidizing agents, sequestering agents, softeners, antifoam agents, moisturizing agents, emollient agents, alkalizing agents, plasticizers, sunscreens, direct or oxidation dyes, perfumes, peptizers, pre
  • the adjuvants mentioned above are generally present in an amount, for each of them, between 0.01 and 20% by weight relative to the weight of the composition.
  • the hair composition may comprise one or more additional non-polymeric or non-quaternary silicone conditioning agents.
  • the hair composition contains at least one additional conditioning agent
  • it may be chosen from synthetic oils such as poly- ⁇ -olefins, fluorinated oils, fluorinated waxes, fluorinated gums and carboxylic acid esters.
  • synthetic oils such as poly- ⁇ -olefins, fluorinated oils, fluorinated waxes, fluorinated gums and carboxylic acid esters.
  • the cationic surfactants of the silicones distinct from the silicones with quaternary ammonium groups required according to the invention, mineral, vegetable or animal oils, ceramides, pseudoceramides, non-polymeric thickeners and mixtures thereof.
  • cationic surfactants mention may be made in particular (non-limiting list): salts of primary, secondary or tertiary fatty amines, optionally polyoxyalkylenated; imidazoline derivatives; quaternary ammonium salts and in particular trialkylammonium salts comprising at least one fatty chain having from 10 to 30 carbon atoms, and especially cetyltrimethymammonium or behenyltrimethylammonium salts; cationic surfactants comprising at least one ester function, and for example a diacyloxydialkyl-hydroxyalkylammonium salt or a diacyloxytrialkylammonium salt and in particular dipalmitoylethylhydroxyethylammonium methosulphate, dicudgearoylethylhydroxyethylmethylammonium methosulphate, distearoylethyldimethylammonium chloride or sodium chloride; distearoyl diethylmethyl
  • the content of additional non-polymeric or non-quaternary silicone conditioning agents in the hair composition may range from 0.001% to 10% by weight, preferably from 0.005% to 5% by weight, and still more preferably from 0.01% to 3% by weight. by weight relative to the total weight of the final composition.
  • the aqueous medium acceptable for the hair may comprise water or a mixture of water and one or more cosmetically acceptable organic solvents.
  • the water content of the composition is preferably greater than or equal to 50% by weight relative to the total weight of the composition.
  • organic solvent there may be mentioned for example linear or branched monoalcohols, preferably saturated, comprising 2 to 10 carbon atoms, such as ethyl alcohol, isopropyl alcohol; aromatic alcohols such as benzyl alcohol, phenylethyl alcohol; polyols or polyol ethers such as, for example, ethylene glycol monomethyl, monoethyl and monobutyl ethers, propylene glycol or its ethers such as, for example, propylene glycol monomethyl ether, butylene glycol, dipropylene glycol, hexylene glycol (2 methyl 2,4-pentanediol), neopentyl glycol and 3-methyl-1,5-pentanediol; as well as the alkyl ethers of diethylene glycol, especially of C 1 -C 4 , such as, for example, diethylene glycol monoethyl ether or monobutyl ether, alone or as a mixture.
  • the organic solvent or solvents may be present in proportions of, for example, between 1 and 40% by weight approximately relative to the total weight of the hair composition, and even more preferably between 5 and 30% by weight approximately.
  • the hair composition according to the invention may be in various galenical forms such as a lotion, a shampoo, a gel, a cream or a wax.
  • the hair composition may be packaged in any type of applicator container or not.
  • the container may contain a ball or a member allowing in particular to homogenize the hair composition before application thereof on the hair.
  • the container containing the hair composition may have a capacity greater than or equal to at 15 ml, especially greater than or equal to 50 ml, or even 100 ml, especially greater than or equal to 150 ml, for example between 15 ml and 500 ml.
  • the hair composition can impregnate a wipe.
  • the hair composition may be introduced into a stream of vector fluid, and projected onto the hair.
  • the hair composition may be contained in a reservoir of a comb or a brush having, for example, orifices at the base of the teeth or bristles making it possible to bring the product and to apply it to the hair.
  • the invention also relates to a hair treatment method of applying to the hair at least one hair composition as defined above, then optionally to perform a rinse.
  • the treatment, for example abrasion, of the hair can take place immediately after the application of the hair composition to the hair, for example in a time less than one hour, in particular less than 30 minutes, or even 10 minutes after application of the hair composition to the hair.
  • a rinse of the hair, when it takes place, can intervene quickly after treatment, for example abrasion, of the hair.
  • the time between the application of the composition and rinsing may for example be less than 4 hours, especially less than 1 hour, for example less than 20 minutes.
  • the treatment step, for example of abrasion, of the hair can be carried out by rubbing the hair with the bare hands or interposing at least one surface between the hands and hair loaded with hair composition, for example a wipe or towel, a glove or other.
  • the treatment can be carried out otherwise than by means of a comb or a brush.
  • the treatment, for example abrasion, of the hair may for example be carried out using at least one surface set in motion, in vibration or in rotation in particular, by a mechanized system.
  • the treatment with the aid of the capillary composition may for example be carried out by hand, for example, wick by wick, for example in two movements: a first movement called “tangential”, that is to say substantially along hair, by example of the root to the tip, and a second movement called “shear”, that is to say substantially orthogonal to the hair, in a direction transverse thereof.
  • the two movements can be repeated several times, for example at least five times, for example ten times. Alternatively, only one of the aforementioned movements can be performed and possibly repeated several times.
  • the treatment time, for example abrasion, using the composition according to the invention may depend for example on the desired intensity of the abrasion and the condition of the hair.
  • the process according to the invention may comprise two treatment stages, for example abrasion, with the aid of two successively applied capillary compositions, each comprising particles of pumice stone according to the invention, the average diameters by volume or the hardness of the pumice particles in accordance with the invention of the two hair compositions being different.
  • a single vial may contain the two separately packaged hair compositions, or two different vials may each contain a hair composition.
  • Another mode of packaging may consist of a bottle containing a basic hair composition without particles of pumice stone according to the invention, which are packaged separately, for example in at least two separate compartments, depending on their particle size or size. their hardness.
  • the user chooses before the treatment, for example abrasion, the pumice particles according to the invention to be mixed with the base composition to form the first hair composition, the mixture being made by the user or within the bottle.
  • the user can, after the first treatment, for example the first abrasion, carry out a second treatment, for example a second abrasion, by mixing this time other particles of pumice stone in accordance with the invention with the hair composition of base to form the second hair composition. Rinsing can be done between and / or after both treatments.
  • the treatment method can be implemented after a step of characterizing the hair, for example by means of a visual examination with the naked eye or under an enlarging device or by an instrumental way, for example by recording the its product by moving a comb in the hair using a sound level meter or in optically determining the shine of the hair.
  • the characterization of the hair can still involve a chemical reagent applied to a hair sample.
  • the method according to the invention may comprise the step of combing and / or rinsing the hair after application of the hair composition. Rinsing can be done with water.
  • the method according to the invention may also comprise the step of heating the hair before or after contacting the hair composition, for example at a temperature of between 40 ° C. and 250 ° C., in particular between 60 ° C. and 220 ° C. ° C.
  • the hair can be heated after the treatment, for example abrasion, so as to shape them, for example by blowing.
  • the heating of the hair may for example be carried out by means of an iron, a liquid water / steam mixture or by means of a heating helmet.
  • the hair can be dried totally or partially.
  • the method according to the invention may further comprise the step of applying, for example before or after treatment with the aid of the hair composition according to the invention, another treatment product on the hair.
  • the treatment product may be, for example, a cosmetic product, in particular a conditioner, a perm, a relaxer, a product for discolouring or coloring the hair.
  • the treatment product can be applied before the treatment, for example of the abrasion type, and can help protect the hair during it, in particular to avoid excessive abrasion.
  • the treatment product is preferably applied after application of the composition according to the invention.
  • the method according to the invention may further comprise the step of subjecting the hair to a post-treatment, after treatment with the aid of a hair composition as defined above, the post-treatment being chosen from the application of a conditioner, a perm, a relaxer, a product for coloring or bleaching hair.
  • the hair composition is as described above.
  • the kit may further comprise a hair post-treatment composition.
  • the post-treatment composition may be chosen from a conditioner, a perm, a relaxer, a product for coloring or bleaching the hair.
  • the post-treatment product may for example be chosen from those described above.
  • composition AT B Caprylyl glycol 0.5 0.5 Cetrimonium chloride 0.5 0.5 Pumice (Pierre Ponce 0 1 ⁇ 2 D of EYRAUD) 18 0 Quaternium-80 (ABIL QUAT 3272 from GOLDSCHMIDT) 0.2 0.2 Glyceryl stearate 1.2 1.2 Hydroxypropyl guar (RHODIA JAGUAR HP 105) 0.1 0.1 Glycerin 2 2 Propylene glycol 0.5 0.5 Cdisputedaryl alcohol 1 1 Hydroxyethylcellulose (NATROSOL 250 HHR from AQUALON) 0.8 0.8 conservatives 0.2 0.2 Dipalmitoylethyl hydroxyethylmonium methosulfate / cetearyl alcohol (30/70 by weight) (DEHYQUART F30 from COGNIS) 4.3 4.3 Water Qs 100 Qs 100 Qs 100
  • the study is conducted on a panel of 20 women: 10 women with long natural hair and 10 women with long hair sensitized.
  • the application is wick by wick in two movements: a first movement called “tangential” and a second movement called “shear”. Both movements are repeated 10 times. The hair is combed, then rinsed and finally dried by blow drying.
  • the treated side of the process of the invention with composition A is smoother, more flexible and more homogeneous than the treated side with composition B.
  • the invention makes it possible to reduce the mass and to control the volume of the hair and to improve the discipline of the hair. The effects are all the more remarkable as the hair is sensitized and thick.
  • composition was prepared: Caprylyl glycol 0.5 Cetrimonium chloride 0.5 Pumice (Pumice 2B D from EYRAUD with a size ranging from 100 to 500 ⁇ m) 25 Quaternium-80 (ABIL QUAT 3272 from GOLDSCHMIDT) 0.2 Glyceryl stearate 1.2 Hydroxypropyl guar (RHODIA JAGUAR HP 105) 0.1 Glycerin 2 Propylene glycol 0.5 Cdisputedaryl alcohol 1 Hydroxyethylcellulose (NATROSOL 250 HHR from AQUALON) 0.8 conservatives 0.2 Dipalmitoylethyl hydroxyethylmonium methosulfate / cetearyl alcohol (30/70 by weight) (DEHYQUART F30 from COGNIS) 10 Water Qs 100
  • composition was prepared: Caprylyl glycol 0.1 Cetrimonium chloride 0.5 Pumice (Pierre Ponce 0 1 ⁇ 2 D of EYRAUD) 15 Quaternium-80 (ABIL QUAT 3474 from GOLDSCHMIDT) 0.1 Glyceryl stearate 1.2 Hydroxypropyl guar (RHODIA JAGUAR HP 105) 0.1 Glycerin 2 Propylene glycol 0.5 Cdisputedaryl alcohol 1 Hydroxyethylcellulose (NATROSOL 250 HHR from AQUALON) 0.8 conservatives 0.2 Dipalmitoylethyl hydroxyethylmonium methosulfate / cetearyl alcohol (30/70 by weight) (DEHYQUART F30 from COGNIS) 4.3 Water Qs 100

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Claims (18)

  1. Kapillarzusammensetzung umfassend mindestens Bimssteinteilchen, ein oder mehrere Silikone mit quaternären Ammoniumgruppen und ein oder mehreren nichtsilikonisierte Polymere.
  2. Zusammensetzung nach Anspruch 1, wobei die Bimssteinteilchen einen Volumenmittel-Durchmesser von kleiner oder gleich 500 µm, vorzugsweise von 50 bis 500 µm, stärker bevorzugt von kleiner oder gleich 300 µm, beispielsweise 100 bis 300 µm, aufweisen.
  3. Zusammensetzung nach einem der vorhergehenden Ansprüche, wobei die Bimssteinteilchen in einem Gehalt von 0,1 Gew.-% bis 35 Gew.-%, insbesondere von 5 Gew.-% bis 30 Gew.-%, speziell von 10 Gew.-% bis 25 Gew.-%, beispielsweise von 15 Gew.-% bis 20 Gew.-%, stärker bevorzugt von 18 Gew.-% bis 20 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, vorhanden sind.
  4. Zusammensetzung nach einem der vorhergehenden Ansprüche, wobei die Bimssteinteilchen eine Härte von 3 bis 10 Mohs, sogar auch größer oder gleich 4, beispielsweise größer oder gleich 5, und insbesondere von 5 bis 5,5, auf der Mohs-Skala aufweisen.
  5. Zusammensetzung nach einem der vorhergehenden Ansprüche, wobei das Silikon mit quaternären Ammoniumgruppen aus den Verbindungen ausgewählt ist, die den folgenden allgemeinen Formeln entsprechen:
    Figure imgb0034
    Figure imgb0035
    Figure imgb0036
    Figure imgb0037
     wobei:
    R1, gleich oder verschieden, eine lineare oder verzweigte C1-30-Alkylgruppe oder Phenyl darstellt;
    R2, gleich oder verschieden, CcH2c-O-(C2H4O)a-(C3H6O)b-(PO3H)d-R5 oder CcH2c-O-(C4H8O)a-(PO3H)d-R5 darstellt;
    R5, gleich oder verschieden, aus den Gruppen der folgenden Formel ausgewählt ist:
    Figure imgb0038
    die Reste R8 unabhängig einen C1-22-Alkylrest oder C2-22-Alkenylrest, linear oder verzweigt und gegebenenfalls eine oder mehrere OH-Gruppen tragend, darstellen, oder eine Gruppe ChH2hZCOR9 darstellen; und
    R6, R7 und R9, gleich oder verschieden, C1-22-Alkyl- oder C2-22-Alkenylreste, linear oder verzweigt, gegebenenfalls eine oder mehrere OH-Gruppen tragend, darstellen, oder R7 mit einem Teil von R8 einen Heterocyclus (Cyclus mit mindestens einem Heteroatom, wie zum Beispiele N, O, P) bilden können, der Heterocyclus insbesondere ein Imidazolin ist,
    - m von 0 bis 20 variiert;
    - n von 0 bis 500 variiert;
    - p von 1 bis 50 variiert;
    - q von 0 bis 20 variiert;
    - r von 1 bis 20 variiert;
    - a von 0 bis 50 variiert;
    - b von 0 bis 50 variiert
    - c von 0 bis 4 variiert;
    - d 0 oder 1 bezeichnet;
    - f von 0 bis 4 variiert;
    - g von 0 bis 2 variiert, vorzugsweise gleich 1 ist; und
    - h von 1 bis 4 variiert, vorzugsweise gleich 3 ist,
    - Z ein Sauerstoffatom oder NH darstellt,
    - A- ein einwertiges mineralisches oder organisches Anion, wie ein Halogenid, ein Sulfat oder ein Carboxylat, darstellt.
  6. Zusammensetzung nach Anspruch 5, dadurch gekennzeichnet, dass das Silikon die Formel (XXII) oder (XXIII) aufweist.
  7. Zusammensetzung nach den Ansprüchen 5 oder 6, dadurch gekennzeichnet, dass das Silikon der allgemeinen Formel (XXIII) gehorcht, wobei mindestens eine der folgenden Bedingungen erfüllt ist:
    - c ist gleich 0,
    - d bezeichnet 0;
    - a ist gleich Null;
    - b ist gleich 1;
    - n variiert von 0 bis 100;
    - q ist gleich 0;
    - f = 3;
    - g = 1;
    - R6 und R7 bedeuten Methylgruppe; und
    - R8 bedeutet einen C10-22-Alkylrest.
  8. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass das Silikon Quaternium 80 ist.
  9. Zusammensetzung nach einem der vorhergehenden Ansprüche, wobei das Silikon mit quaternären Ammoniumgruppen in einem Gehalt von 0,1 Gew.-% bis 20 Gew.-%, vorzugsweise von 0,2 Gew.-% bis 10 Gew.-%, stärker bevorzugt von 0,3 bis 5 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung vorhanden ist.
  10. Zusammensetzung nach einem der vorhergehenden Ansprüche, wobei das oder die nicht-silikonisierten Polymere aus verdickenden, fixierenden oder konditionierenden, nichtionischen, anionischen, kationischen oder amphoteren Polymeren ausgewählt sind.
  11. Zusammensetzung nach dem vorhergehenden Anspruch, wobei das oder die verdickenden Polymere aus assoziativen oder nicht-assoziativen Zucker-Polymeren, anionischen assoziativen oder nicht-assoziativen Acryl- oder Methacryl-Polymeren und assoziativen oder nicht-assoziativen Polyurethanen ausgewählt sind.
  12. Zusammensetzung nach Anspruch 10, wobei das oder die konditionierenden Polymere aus quaternären Zelluloseetherderivaten, kationischen Cyclopolymeren, insbesondere Homo- oder Copolymeren von Dimethyldiallylammoniumchlorid, modifizierten kationischen Guargummen, quaternären Vinylpyrrolidon- und Vinylimidazol-Polymeren, Homopolymeren von Ethyltrimethylammoniummethacrylatsalzen und ihren Gemischen ausgewählt sind.
  13. Zusammensetzung nach einem der vorhergehenden Ansprüche, wobei das oder die nicht-silikonisierten Polymere in einem Gehalt von 0,01 Gew.-% bis 20 Gew.-%, vorzugsweise von 0,1 Gew.-% bis 10 Gew.-%, stärker bevorzugt von 0,2 bis 5 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, vorhanden sind.
  14. Verfahren zum Behandeln von Haaren bestehend aus dem Aufbringen auf die Haare von mindestens einer Kapillarzusammensetzung nach einem der vorhergehenden Ansprüche, und anschließend gegebenenfalls aus dem Durchführen einer Spülung.
  15. Verfahren nach Anspruch 14, umfassend weiterhin den Schritt des Unterziehens der Haare einer Nachbehandlung nach der Behandlung mit Hilfe einer Kapillarzusammensetzung nach einem der Ansprüche 1 bis 13, wobei die Nachbehandlung aus dem Aufbringen einen Konditionierungsmittel einer Dauerwelle, eines Entkrausers, eines Haar-Färbe- oder Haar-Entfärbeprodukts ausgewählt ist.
  16. Verfahren nach einem der Ansprüche 14 und 15, wobei der Haarbehandlungsschritt durch Frottieren der Haare mit bloßen Händen oder durch Einlegen von mindestens einer Fläche zwischen Hände und Haare, die mit Kapillarzusammensetzung befrachtet sind, durchgeführt wird.
  17. Haarbehandlungsset, umfassend:
    - eine Kapillarzusammensetzung, umfassend mindestens Bimssteinteilchen, ein oder mehreren Silikone mit quaternären Ammoniumgruppen und ein oder mehreren nicht-silikonisierte Polymeren und
    - einen Träger umfassend Anweisungen zum Gebrauch der Kapillarzusammensetzung auf den Haaren.
  18. Set nach Anspruch 17, umfassend weiterhin eine Haar-Nachbehandlungszusammensetzung, die vorzugsweise aus einem Konditionierungsmittel, einer Dauerwelle, einem Entkrauser, einem Haar-Färbe- oder Haar-Entfärbeprodukt ausgewählt ist.
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DE102009029450A1 (de) * 2009-09-15 2011-03-24 Evonik Goldschmidt Gmbh Neuartige Polysiloxane mit quaternären Ammoniumgruppen und deren Verwendung
FR2958538B1 (fr) * 2010-04-13 2012-06-15 Oreal Composition et procede de traitement utilisant des particules de pierre ponce
FR2958539B1 (fr) * 2010-04-13 2012-07-06 Oreal Composition cosmetique comprenant des particules de pierre ponce
FR2976488B1 (fr) * 2011-06-20 2013-12-27 Oreal Composition et procede de traitement utilisant des particules de pierre ponce, un amidon, un alcool gras et un ester gras
US20230145339A1 (en) * 2020-05-29 2023-05-11 Dow Global Technologies Llc Process for reducing hair damage upon exposure to heat

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