EP2313615B2 - Blade arrangement of a gas turbine - Google Patents
Blade arrangement of a gas turbine Download PDFInfo
- Publication number
- EP2313615B2 EP2313615B2 EP09781705.0A EP09781705A EP2313615B2 EP 2313615 B2 EP2313615 B2 EP 2313615B2 EP 09781705 A EP09781705 A EP 09781705A EP 2313615 B2 EP2313615 B2 EP 2313615B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- blade
- heat shield
- layer
- heat
- blade tip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000919 ceramic Substances 0.000 claims description 5
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 40
- 239000007789 gas Substances 0.000 description 20
- 238000000227 grinding Methods 0.000 description 17
- 238000009413 insulation Methods 0.000 description 13
- 239000012790 adhesive layer Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000012720 thermal barrier coating Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D11/00—Preventing or minimising internal leakage of working-fluid, e.g. between stages
- F01D11/08—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator
- F01D11/12—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator using a rubstrip, e.g. erodible. deformable or resiliently-biased part
- F01D11/122—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator using a rubstrip, e.g. erodible. deformable or resiliently-biased part with erodable or abradable material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D11/00—Preventing or minimising internal leakage of working-fluid, e.g. between stages
- F01D11/08—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator
- F01D11/14—Adjusting or regulating tip-clearance, i.e. distance between rotor-blade tips and stator casing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/288—Protective coatings for blades
Definitions
- the present invention relates to the field of thermal fluid machines, in particular gas turbines. It relates to a blade arrangement of a thermal fluid machine according to the preamble of claim 1.
- Fig. 1 In the simplest case, like this Fig. 1 is shown based on the blade arrangement 10, no special measures are taken to optimize the gap width:
- the blade arrangement 10 of the Fig. 1 is not designed for grinding the blade tips 27 into the heat shield 12.
- the game 25 between the blade tips 27 and the heat shield 12 takes into account the different thermal expansions and is therefore comparatively large in order to avoid grinding of the components during operation.
- blade arrangements 20 are according to Fig. 2 been suggested (see e.g. the EP-A2-0 166 676 , EP-A2-1 312 760 or the US-A1-2008166225 ), in which abrasive bodies (grains) 21 (e.g. made of silicon carbide or cubic boron nitride cBN) are embedded in a carrier layer 19 on the blade tip 27 of the rotor blades, with which the blade tip 27 is in operation in a grindable thermal barrier coating 18 (Thermal Barrier Coating TBC ) can grind into the opposite heat shield 12.
- a layer of metallic MCrAlY can be used as the carrier layer 19 for the grinding wheels 21, as well as as an adhesive layer 17 under the thermal insulation layer 18.
- the abrasive layer 19, 21 of such a blade arrangement has a comparatively complex structure due to the embedded abrasive bodies and is therefore complex to produce.
- document US-A1-5 883 314 discloses a method for producing abradable coatings on thermally stressed components of gas turbines, which are characterized by good abrasion properties and at the same time high binding effect to the substrate. Areas of application are stator parts of the hot gas channel or blade parts. Layer-like, flexible preforms based on modified MCrAIY alloys are applied to the areas of the turbine component in question, for example the blade tip, and metallurgically bonded to it. The production of the multilayer preforms is comparatively complex.
- EP-A2-0 965 730 discloses suitable material combinations of interacting abrasive and abradable surfaces in gas turbines, in particular heat shield and blade tip, based on an abrasive blade tip and an abradable surface of the heat shield.
- the heat shield has an erosion-resistant surface made of a first ceramic material, which is firmly connected to the substrate by means of an adhesive layer. In a limited area, the contact area with the rotating blade tip, an abradable wear layer made of a second ceramic material is applied.
- the impacting blade tip is covered with an abrasive coating, preferably according to US-A-4,936,745 , i.e. equipped with grinding wheels made of silicon carbide or cubic boron nitride embedded in a metallic carrier layer. This solution is also characterized by elaborately finished surfaces of the components involved.
- the publication US-A1-2003/175116 describes an abradable coating for stator components of a compressor or gas turbine.
- the blade tip and heat shield have means that enable the blade tip to be specifically ground into the heat shield.
- the outer layer of the heat shield itself has a porous thermal insulation layer with polygonal depressions (Fig. 6) or grooves running in the circumferential direction, delimited by wall projections (Fig. 7, 8), while the rotor blade tip has a circumferential cutting edge (Fig. 4, 5 ) is equipped to cut into the abradable coating of the heat shield. Equipping the blade tip with circumferential cutting edges increases the manufacturing effort and - at least when used in gas turbines - the effort for blade cooling in this area.
- the invention aims to provide a remedy here. It is therefore the object of the invention to provide a blade arrangement which avoids the disadvantages of known blade arrangements and, with a simple structure, produces a comparable grinding behavior without the need for a special abrasive layer on the blade tip must become.
- the heat shield has a porous thermal insulation layer made of a porous ceramic layer as an outer, abradable layer, and that the blade tip is only provided with a homogeneous metallic cover layer made of MCrAIY.
- the porous thermal insulation layer enables the blade tip covered with the covering layer to grind into the heat shield even without a special grinding wheel or abrasive layer, thus optimally minimizing the play between the blade tip and the opposite heat shield.
- the blade is a rotor blade or a guide blade of a thermal turbomachine, in particular a gas turbine, with a heat shield attached to the rotor opposite the blade tip in the case of a guide blade.
- the blade is a blade rotating about the axis, while the heat shield is mounted in a stationary manner on the stator of the gas turbine.
- porous ceramic layer consists of YSZ.
- the porosity of the thermal insulation layer is preferably greater than 20%.
- An adhesive layer in particular made of MCrAIY, is advantageously arranged between the heat shield and the thermal insulation layer.
- Another embodiment is characterized in that the rotor blade is part of the first row of rotor blades in the turbine part of the gas turbine.
- a preferred exemplary embodiment of a blade arrangement 30 is shown.
- the clearance 25 and thus the efficiency of the turbine are optimized by grinding the blade tip 27 into the coating 22, 23 of the heat shield 12 (in Fig. 3 the possible grinding area 28 on the heat shield is indicated by a dashed line).
- a thermal insulation layer 23 is provided on the heat shield 12 as the layer to be abraded during grinding, which is connected to the substrate of the heat shield 12 via an adhesive layer 22 located therebetween.
- a metallic oxidation protection layer made of MCrAlY can be provided in the usual way as the adhesive layer 22.
- thermal insulation layer 23 is sufficiently easy to sand - without losing its thermal properties.
- a porous thermal insulation layer 23 made of a porous ceramic layer, which can consist in particular of YSZ (yttrium oxide-stabilized zirconium oxide), the porosity being created, for example, by embedded polymers that are later baked out. It has proven to be advantageous if the porosity of the thermal insulation layer is greater than 20%, for example in the range of 22-24%.
- the abrasion on the blade tip 27 during grinding is comparatively small compared to the depth of the grinding area 28, so that a special grinding layer on the blade tip 27 can be dispensed with. It is therefore sufficient if the blade tip 27 is covered with a homogeneous cover layer 24 (without abrasive media) made of MCrAlY, which is anyway provided as a protective layer against oxidation of the blade material.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Description
Die vorliegende Erfindung bezieht sich auf das Gebiet der thermischen Strömungsmaschinen, insbesondere der Gasturbinen. Sie betrifft eine Schaufelanordnung einer thermischen Strömungsmaschine gemäss dem Oberbegriff des Anspruchs 1.The present invention relates to the field of thermal fluid machines, in particular gas turbines. It relates to a blade arrangement of a thermal fluid machine according to the preamble of claim 1.
Für den Wirkungsgrad einer Gasturbine ist es von grosser Wichtigkeit, insbesondere im Turbinenteil, in dem die heissen Gase aus der Brennkammer entspannt werden, die zwischen dem beschaufelten drehenden Rotor und dem umgebenden Stator auftretenden Spalte im Bereich der Beschaufelung möglichst klein zu halten.For the efficiency of a gas turbine, it is of great importance, especially in the turbine part in which the hot gases from the combustion chamber are expanded, to keep the gaps in the area of the blading that occur between the bladed rotating rotor and the surrounding stator as small as possible.
Im einfachsten Fall, wie dies in
Um das Spiel 25 reduzieren zu können, sind Schaufelanordnungen 20 gemäss
Die Schleifschicht 19, 21 einer solchen Schaufelanordnung ist durch die eingelagerten Schleifkörper vergleichsweise komplex aufgebaut und daher aufwändig in der Herstellung.The
Dokument
Die Druckschrift
Hier will die Erfindung Abhilfe schaffen. Es ist daher Aufgabe der Erfindung, eine Schaufelanordnung anzugeben, welche die Nachteile bekannter Schaufelanordnungen vermeidet und bei einfachem Aufbau ein vergleichbares Einschleifverhalten erzeugt, ohne dass an der Schaufelspitze eine spezielle Schleifschicht vorgesehen werden muss.The invention aims to provide a remedy here. It is therefore the object of the invention to provide a blade arrangement which avoids the disadvantages of known blade arrangements and, with a simple structure, produces a comparable grinding behavior without the need for a special abrasive layer on the blade tip must become.
Die Aufgabe wird durch die Gesamtheit der Merkmale des Anspruchs 1 gelöst. Wesentlich für die Erfindung ist, dass der Hitzeschild als äussere, abschleifbare Schicht eine poröse Wärmedämmschicht aus einer porösen Keramikschicht aufweist, und dass die Schaufelspitze lediglich mit einer homogenen metallischen Abdeckschicht aus MCrAIY versehen ist. Die poröse Wärmedämmschicht ermöglicht es der mit der Abdeckschicht bedeckten Schaufelspitze, sich auch ohne spezielle Schleifkörper bzw. Schleifschicht in den Hitzeschild einzuschleifen und so das Spiel zwischen Schaufelspitze und gegenüberliegendem Hitzeschild optimal zu minimieren.The task is solved by the entirety of the features of claim 1. It is essential for the invention that the heat shield has a porous thermal insulation layer made of a porous ceramic layer as an outer, abradable layer, and that the blade tip is only provided with a homogeneous metallic cover layer made of MCrAIY. The porous thermal insulation layer enables the blade tip covered with the covering layer to grind into the heat shield even without a special grinding wheel or abrasive layer, thus optimally minimizing the play between the blade tip and the opposite heat shield.
Grundsätzlich ist die Schaufel eine Laufschaufel oder eine Leitschaufel einer thermischen Strömungsmaschine, insbesondere einer Gasturbine, wobei im Falle einer Leitschaufel der Schaufelspitze ein am Rotor befestigter Hitzeschild gegenüberliegt. Gemäss einer bevorzugten Ausgestaltung ist die Schaufel eine um die Achse rotierende Laufschaufel, während der Hitzeschild am Stator der Gasturbine ortsfest montiert ist.Basically, the blade is a rotor blade or a guide blade of a thermal turbomachine, in particular a gas turbine, with a heat shield attached to the rotor opposite the blade tip in the case of a guide blade. According to a preferred embodiment, the blade is a blade rotating about the axis, while the heat shield is mounted in a stationary manner on the stator of the gas turbine.
Eine andere Ausgestaltung der Erfindung zeichnet sich dadurch aus, dass die poröse Keramikschicht aus YSZ, besteht. Vorzugsweise ist dabei die Porosität der Wärmedämmschicht grösser als 20 %.Another embodiment of the invention is characterized in that the porous ceramic layer consists of YSZ. The porosity of the thermal insulation layer is preferably greater than 20%.
Zwischen dem Hitzeschild und der Wärmedämmschicht ist mit Vorteil eine Haftschicht, insbesondere aus MCrAIY, angeordnet.An adhesive layer, in particular made of MCrAIY, is advantageously arranged between the heat shield and the thermal insulation layer.
Eine andere Ausgestaltung ist dadurch gekennzeichnet, dass die Laufschaufel Teil der ersten Laufschaufelreihe im Turbinenteil der Gasturbine ist.Another embodiment is characterized in that the rotor blade is part of the first row of rotor blades in the turbine part of the gas turbine.
Die Erfindung soll nachfolgend anhand von Ausführungsbeispielen im Zusammenhang mit der Zeichnung näher erläutert werden. Es zeigen
- Fig. 1
- in einer stark vereinfachten Darstellung eine frühere Schaufelanordnung ohne die Möglichkeit des Einschleifens;
- Fig. 2
- in einer zu
Fig. 1 vergleichbaren Darstellung eine andere frĂĽhere Schaufelanordnung mit einer speziellen Schleifschicht auf der Schaufelspitze und - Fig. 3
- in einer zu
Fig. 1 vergleichbaren Darstellung eine für das Einschleifen vorgesehen Schaufelanordnung mit einer einfachen Abdeckschicht auf der Schaufelspitze gemäss einem Ausführungsbeispiel der Erfindung.
- Fig. 1
- In a highly simplified representation, an earlier blade arrangement without the possibility of grinding in;
- Fig. 2
- in one too
Fig. 1 Comparable representation shows another earlier blade arrangement with a special abrasive layer on the blade tip and - Fig. 3
- in one too
Fig. 1 Comparable illustration of a blade arrangement intended for grinding with a simple covering layer on the blade tip according to an exemplary embodiment of the invention.
In
Als beim Einschleifen abzuschleifende Schicht ist am Hitzeschild 12 eine Wärmedämmschicht 23 vorgesehen, die über eine dazwischen liegende Haftschicht 22 mit dem Substrat des Hitzeschilds 12 verbunden ist. Als Haftschicht 22 kann in üblicher Weise eine metallische Oxidationsschutzschicht aus MCrAIY vorgesehen werden.A
Bei Versuchen hat sich nun herausgestellt, dass ein Einschleifen der Schaufelspitze in die Wärmedämmschicht 23 auch ohne spezielle Schleifschicht auf der Schaufelspitze 27 möglich ist und zu guten Resultaten führt, wenn die Wärmedämmschicht 23 - ohne ihre thermischen Eigenschaften zu verlieren - ausreichend leicht abzuschleifen ist. Dies lässt sich dadurch erreichen, dass eine poröse Wärmedämmschicht 23 aus einer porösen Keramikschicht, die insbesondere aus YSZ (Yttriumoxid-stabilisiertem Zirkoniumoxid) bestehen kann, verwendet wird, wobei die Porosität beispielsweise durch eingelagerte Polymere erzeugt wird, die später ausgeheizt werden. Es hat sich dabei als vorteilhaft herausgestellt, wenn die Porosität der Wärmedämmschicht grösser als 20 % ist, also beispielsweise im Bereich von 22-24 % liegt.Experiments have now shown that grinding the blade tip into the
Bei einer solchen porösen Wärmedämmschicht 23 ist beim Einschleifen der Abrieb an der Schaufelspitze 27 gegenüber der Tiefe des Einschleifbereichs 28 vergleichsweise klein, so dass auf eine spezielle Schleifschicht an der Schaufelspitze 27 verzichtet werden kann. Es reicht daher aus, wenn die Schaufelspitze 27 mit einer homogenen Abdeckschicht 24 (ohne Schleifkörper) aus MCrAIY bedeckt ist, die als Schutzschicht gegen die Oxidation des Schaufelmaterials ohnehin vorgesehen ist.With such a porous
Auf diese Weise brauchen an der Schaufel 11 keine besonderen Vorkehrungen fĂĽr das Einschleifen getroffen werden, wodurch sich die Herstellung der Schaufel 11 wesentlich vereinfacht.In this way, no special precautions need to be taken for grinding on the
- 10,20.3010.20.30
- Schaufelanordnung (Gasturbine)Blade arrangement (gas turbine)
- 1111
- Laufschaufelblade
- 1212
- HitzeschildHeat shield
- 1313
- HeissgaskanalHot gas channel
- 14,15,2414,15,24
- AbdeckschichtCover layer
- 1616
- Achseaxis
- 17,2217.22
- HaftschichtAdhesive layer
- 18,2318.23
- Wärmedämmschicht (TBC)Thermal insulation layer (TBC)
- 1919
- TrägerschichtBacking layer
- 2121
- SchleifkörperAbrasive body
- 2525
- SpielGame
- 2626
- Wand (Heissgaskanal)Wall (hot gas duct)
- 2727
- SchaufelspitzeShovel tip
- 2828
- EinschleifbereichGrinding area
Claims (6)
- Blade arrangement (30) of a thermal flow machine with at least one blade (11) protruding in the radial direction into a channel (13), through which hot gas flows and which is arranged concentrically to an axis (16), and ending in a blade tip (27) which lies opposite, with a clearance (25), a heat shield (12) delimiting the channel (13), wherein the blade (11) and the heat shield (12) are movable relative to one another in the circumferential direction, and the blade tip (27) and the heat shield (12) are covered with layers (22, 23, 24) which allow the blade tip (27) to grind into the heat shield (12) in a targeted manner, and wherein the heat shield (12) has a porous heat-insulating layer (23) as an outer layer which can be ground away, characterized in that the porous heat-insulating layer (23) is a porous ceramic layer, and the blade tip (27) is provided merely with a homogeneous metallic cover layer (24) of MCrAlY.
- Blade arrangement according to claim 1, characterized in that the thermal flow machine is a gas turbine, that the blade is a moving blade (11) rotating about the axis (16), and that the heat shield (2) is mounted stationarily on the stator of the gas turbine.
- Blade arrangement according to claim 1 and/or, characterized in that the porous ceramic layer consists of YSZ (yttrium-oxide-stabilised zirconium oxide).
- Blade arrangement according to claim 3, characterized in that the porosity of the heat-insulating layer (23) is more than 20%.
- Blade arrangement according to claim 3 or 4, characterized in that an adhesion layer (22), in particular made of MCrAlY, is arranged between the heat shield (12) and the heat-insulating layer (23).
- Blade arrangement according to claim 2, characterized in that the moving blade (11) is part of the first row of moving blades in the turbine part of the gas turbine,
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH01285/08A CH699312A1 (en) | 2008-08-15 | 2008-08-15 | Blade arrangement for a gas turbine. |
PCT/EP2009/060387 WO2010018174A1 (en) | 2008-08-15 | 2009-08-11 | Blade arrangement of a gas turbine |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2313615A1 EP2313615A1 (en) | 2011-04-27 |
EP2313615B1 EP2313615B1 (en) | 2016-03-23 |
EP2313615B2 true EP2313615B2 (en) | 2023-09-27 |
Family
ID=40090118
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09781705.0A Active EP2313615B2 (en) | 2008-08-15 | 2009-08-11 | Blade arrangement of a gas turbine |
Country Status (4)
Country | Link |
---|---|
US (1) | US20110171039A1 (en) |
EP (1) | EP2313615B2 (en) |
CH (1) | CH699312A1 (en) |
WO (1) | WO2010018174A1 (en) |
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US20130186304A1 (en) * | 2012-01-20 | 2013-07-25 | General Electric Company | Process of fabricating a thermal barrier coating and an article having a cold sprayed thermal barrier coating |
DE102013212741A1 (en) * | 2013-06-28 | 2014-12-31 | Siemens Aktiengesellschaft | Gas turbine and heat shield for a gas turbine |
US20160237832A1 (en) * | 2015-02-12 | 2016-08-18 | United Technologies Corporation | Abrasive blade tip with improved wear at high interaction rate |
US20160245110A1 (en) * | 2015-02-25 | 2016-08-25 | United Technologies Corporation | Hard phaseless metallic coating for compressor blade tip |
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DE102017207238A1 (en) * | 2017-04-28 | 2018-10-31 | Siemens Aktiengesellschaft | Sealing system for blade and housing |
US11346232B2 (en) * | 2018-04-23 | 2022-05-31 | Rolls-Royce Corporation | Turbine blade with abradable tip |
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-
2008
- 2008-08-15 CH CH01285/08A patent/CH699312A1/en not_active Application Discontinuation
-
2009
- 2009-08-11 EP EP09781705.0A patent/EP2313615B2/en active Active
- 2009-08-11 WO PCT/EP2009/060387 patent/WO2010018174A1/en active Application Filing
-
2011
- 2011-02-10 US US13/024,545 patent/US20110171039A1/en not_active Abandoned
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Also Published As
Publication number | Publication date |
---|---|
EP2313615A1 (en) | 2011-04-27 |
US20110171039A1 (en) | 2011-07-14 |
CH699312A1 (en) | 2010-02-15 |
EP2313615B1 (en) | 2016-03-23 |
WO2010018174A1 (en) | 2010-02-18 |
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