EP2298851B1

EP2298851B1 - Gasoline automobile fuel comprising agent for increasing the octane number

Info

Publication number: EP2298851B1
Application number: EP09755123.8A
Authority: EP
Inventors: Sergey Dmitrievich Varfolomeev; Grigory Alexeevich Nikiforov; Violetta Borisovna Volieva; Gennady Grigorievich Makarov; Lev Iliich Trusov
Original assignee: EMANUEL INST OF BIOCHEMICAL PHYSICS OF RUSSIAN ACADEMY OF SCIENCES IBCP RAS; Emanuel Institute of Biochemical Physics of Russian Academy of Sciences (IBCP RAS)
Current assignee: EMANUEL INST OF BIOCHEMICAL PHYSICS OF RUSSIAN ACADEMY OF SCIENCES IBCP RAS; Emanuel Institute of Biochemical Physics of Russian Academy of Sciences (IBCP RAS)
Priority date: 2008-05-28
Filing date: 2009-05-27
Publication date: 2014-10-08
Anticipated expiration: 2029-05-27
Also published as: EA018090B1; EP2298851A4; US20110154725A1; WO2009145674A1; EP2298851A1; EA201001729A1

Description

FIELD OF THE INVENTION

The invention relates to a gasoline automobile fuel which is characterized by increased octane number.

BACKGROUND OF THE INVENTION

The progress in construction of motor engines and the increased requirements for ecological parameters of automobile fuel influenced the ever-growing demand for a high octane gasoline with the proper toxicity level of the exhaust gases according to the present-day standards. The growth in the industrial share of high octane gasoline is impossible without a wide use of antiknock additives promoting increase in the detonation resistance of automobile fuel.
Nowadays oxygenates including a wide range of oxygen-containing compounds are used as antiknock agents. These are usually the mixtures with difficult to control compositions and containing alcohols, alkyl ethers and esters, carbonyl compounds and their interaction products. Most of them, under the action of air oxygen, can convert into peroxides, leading to a decrease in chemical stability of gasoline and to accumulation of carboxylic acids, causing corrosion of engine and containers and tanks for gasoline storage. A serious drawback of currently widely used methyl-tert-butyl ether is its appreciable toxicity and a low capacity for decomposition that leads to accumulation of toxic products in soil and natural water.
It is known that cyclic ketals (1.3-dioxolanes), derived via interaction between glycols and carbonyl compounds used as components in fuel compositions, improve ecological characteristics of motor engines. For instance, they reduce the content of solid particles and toxic products of incomplete combustion in the exhaust gases of diesel-fuel engines [ US 2004025417 , publ. 12.02.2004, FR 2833607 , publ. 20.06.2003, AT 311428T , publ. 15.12.2005, JP 7331262 , publ. 19.12.1995], improve the ecological characteristics of biodiesel [ US 2006199970 , publ. 07.09.2006, WO 2006084048 , publ. 10.08.2006] and motor gasoline [ US 4390345 , publ. 28.06.1983, WO 8903242 , publ. 20.04.1989].
WO 2004/000976 A2 filed on November 8, 2001 discloses an additive composition for increasing the octane number of gasoline. This additive composition comprises an alcohol having a first blending octane number and a non-cyclic ketal or acetal having a second blending octane number. The resulting composition has a third blending octane number substantially greater than a linear addition of the first and second blending octane numbers of the components of the mixture. The fuel additive composition significantly increases the octane number of a gasoline fuel without detrimentally affecting the environment.
CA Pat. 2530219 , publ. 03.02.2005 discloses an oxygenate product and its application as an additive increasing the capacity of gasoline for inflammation and reducing the content of detrimental emissions into the air. The oxygenate is a product of interaction between glycerol and carbonyl compound, for example acetone, alkylated by tertiary olefin. Alkylation is necessary to reach sufficient solubility of such 1.3-dioxolanes in hydrocarbon fuel and to avoid the influence of non-substituted hydroxyl on solubility. This fact significantly limits the use of glycerol-based 1.3-dioxolanes as an additive to gasoline.
The said documents do not contain any information about the capacity of 1.3-dioxolanes to exhibit the antiknock properties towards gasoline.
Other patent documents disclose glycerol alkylation with isobutylene to obtain glycerol polyalkyl ethers as additives to gasoline [ DE 4445635 , publ. 27.06.1996, EP 0718270 , publ. 26.06.1996]. If acetone is used as a solvent, the reaction mixture is a mixture of glycerol tert-butyl ethers with various rate of substitution and having an additive of free glycerol and also it additionally contains the cyclic ketal - 2.2-dimethyl-4-tert-butoxymetyl-1.3-dioxolane and the additive 2.2-dimethyl-4-hydroxymethyl-1.3-dioxolane, containing a free hydroxyl. These reaction mixtures when added to gasoline shown to exhibit the properties of efficient additives increasing the octane number. To provide the phase compatibility, it is necessary to perform the alkylation of glycerol free hydroxyls, which requires intensive labor and energy. However, the presence in the mixture of monoalkylated glycerol as well as the admixtures of free glycerol and non-alkylated 4-hydroxymethyl-1.3-dioxolane increases the probability of stratification of the gasoline composition containing this additive. A complex changeable composition of the additive depending on the reaction conditions in a multicomponent system results in instability and unpredictability of its antiknock properties.
It is known a multifunctional ethanol-based additive to gasoline, providing increased octane number, a lower turbidity temperature, decreased toxicity of exhaust emissions and containing, in addition to ethanol, N-methyl aniline, acetic aldehyde, crotonaldehyde, ethyl ether and multifunctional additive AUTOMAG [ RU Pat. 2148077 , publ. 27.04.2000].
RU Pat. 2068871 C1 , publ. 10.11.1996 refers to an ethanol-based additive to gasoline, containing a co-solvent as a stabilizer which is a waste of hydrolytic production of ethanol from of raw wood, so called "aldehyde-ether-ethanol fraction"(8 - 80 mass %). Introduction of this additive (2 -20 mass %) into gasoline allows to increase its octane number and prevents its stratification at lower temperatures. The hydrolytic production waste in the additive is a mixture of aliphatic alcohols C₃-C₅, esters of methanol and ethanol and formic and acetic acids, furfural and other organic compounds.
RU Pat. 2129141 , publ. 20.04.1999 is directed to a stabilized ethanol-based additive to gasoline, containing N-methyl aniline, ferrocene, and/or its derivatives; wherein ethanol is stabilized with lower aliphatic alcohols, ethers or aldehyde-ether-alcohol fraction derived from the waste of ethanol production from raw wood.
Therefore, the problem to be solved by the present invention is to provide an alternative additive agent for gasoline as to improve the octane number thereof.

SUMMARY OF THE INVENTION

The present invention provides a gasoline automobile fuel comprising an additive agent that is a combination between a C₁-C₅ alcohol and a cyclic product of the interaction between a lower aldehyde selected from formaldehyde and acetaldehyde or a lower ketone selected from acetone, methyl ethyl ketone, diethyl ketone and cyclohexanone, and a compound containing at least two hydroxyl groups.
The combination of alcohol with the product of interaction between lower carbonyl compounds and a compound containing at least two hydroxyl groups allows the formation of cycles with carbonyl compounds, or mixtures of said products, and therefore, due to a synergic effect, an increased octane number of gasoline is obtained in a more effective way than when any of said components is used alone.
Moreover, said combination can be easily obtained from usual products available from the chemical industry or from waste or intermediates of carbohydrate-containing raw material processing.
In addition, the problem of phase incompatibility with gasoline fuel arising from the presence of free hydroxyl in the products of interaction between a lower carbonyl compound and a compound containing at least two hydroxyl groups allowing the formation of cycles with carbonyl compounds is thus avoided.

DETAILED DESCRIPTION OF THE INVENTION

The present invention provides a combination of a C₁-C₅ alcohol and a product of interaction between lower aldehydes or lower ketones and a compound containing at least two hydroxyl groups allowing the formation of cycles with said carbonyl compounds or mixtures of the products, as an agent for increasing the octane number of a gasoline automobile fuel.
Preferably, dihydroxy, trihydroxy and polyhydroxy alcohols are used as compounds containing at least two hydroxyl groups allowing the formation of cycles with carbonyl compounds.
Said alcohols are preferably monosaccharides. However, oligosaccharides which convert to monosaccharides through interaction with carbonyl compounds also can be used.
Ethanol is most preferably used as a C₁-C₅ alcohol.
Pentoses or hexoses as well as their mixtures obtainable via mixing the individual monosaccharides or through technological processes of carbohydrate-containing raw material processing, can be used as monosaccharides.
Xylose or arabinose is preferably used as a pentose, and glucose as a hexose.
Glycols, such as ethylene glycol, are used as dihydroxy alcohols. Glycerol is used as trihydroxy alcohol. Erythrites, such as pentaerythritol, are used as polyhydroxy alcohols.
As carbonyl compound is used a compound belonging to lower aldehydes or lower ketones, for instance formaldehyde, acetaldehyde, acetone, methyl ethyl ketone, diethyl ketone and cyclohexanone.
An essential condition necessary to provide a high octane rating is the presence in the claimed agent of both alcohol and the products of carbonyl compound interaction with a compound containing at least two hydroxyl groups, capable of forming the cycles with carbonyl compounds or mixtures of said products. Alcohols are insufficiently effective antiknock agents. According to our data and also from US 4541836 , publ. 17.09.1985, the introduction of anhydrous ethanol (up to 10 %) into gasoline increases the octane number of the fuel by 2-4 units.
Study of octane-increasing activity of cyclic ketals of monosaccharides, which are one of the examples of the product of interaction between carbonyl compound and a compound, containing at least two hydroxyls allowing the formation of cycles with carbonyl compounds, using a standard hydrocarbon mixture, has shown that pure ketals, formed by monosaccharides and acetone, do not actually increase the octane number of hydrocarbons. For instance, introduction of acetone - arabinose ketal into the mixture of iso-octane - n-heptane (4:1) in an amount of 8 mass %, does not actually influence its octane number. A similar effect has been shown for triatomic alcohol-based ketals: the 10% content of glycerol - acetone cyclic ketal in gasoline increases the octane number by 1.4 units; for glycerol - methyl ethyl ketone ketal by 0.9 units; for other ketals the increase in the octane number is not more than the measurement error.
Addition of ethanol into the system increases the octane number of the model mixture: for arabinose - acetone ketal (weight ratio of ketal : ethanol is 0.75:1.0) by 10.4 units; for xylose - acetone ketal (weight ratio of ketal : ethanol is 0.75 : 1.0) by 13.1 units; for glycerol - acetone ketal (weight ratio of ketal : ethanol is 1.0:1.0) by 12.6 units. This suggests a synergic effect of the pair "alcohol - cyclic ketal", providing a high octane-increasing activity of the additive agents.
It should be noted that the order of introduction of alcohol and said product of interaction of carbonyl compound and a compound containing at least two hydroxyl groups allowing the formation of cyclic ketals with carbonyl compounds doesn't influence the achievement of octane-increasing effect of the claimed agent. The essential fact is only the presence of the combination of said components no matter whether they are mixed before introduction into gasoline automobile fuel or they are mixed in the gasoline automobile fuel. Due to this, the claimed agent exhibits the octane-increasing effect for both gasoline and alcohol-containing gasoline compositions.
The presence of alcohol additive helps to avoid the problem of phase compatibility with gasoline of the cyclic ketals and acetals having free hydroxyl groups. In presence of alcohol, these compounds, regardless of the nature of alkyl substituents, form a monophase stable system with gasoline.
Glycerol-based cyclic ketals are known to promote the increase in phase stability of alcohol-containing gasoline ( GB Pat. 811406 , publ. 02.04.1959, US 4390344 , publ. 28.06.1983). This fully relates to monosaccharide-based cyclic ketals. For instance, addition of cyclic ketals or mixtures of monosaccharide-based cyclic ketals (3 - 8 weight %) to the two-phase system containing gasoline and 10 volume % water-containing ethanol results in a homogeneous system. Thus, the presence of the said ketals stabilizes the gasoline phase homogeneity allowing the increase in the threshold water concentration followed by its isolation as a separate phase. Therefore, in order to compound the hydrocarbon and alcohol, it becomes possible to use not only dry ethanol but also rectificate containing 3.6 % water, and hydrous alcohol containing up to 5% water.
The following Examples illustrate the invention:

EXAMPLES

Example 1

The product of a carbonyl compound interaction with a compound containing at least two hydroxyls allowing the formation of cycles with carbonyl compounds, which is needed for realization of the invention, can be obtained as follows.
One group of compounds, containing at least two hydroxyl groups allowing the formation of cycles with carbonyl compounds, is saccharides.
Both individual monosaccharides and their mixtures, for instance a pentose fraction derived, as described below from a vegetable raw material, are used as saccharides.
As a source of a mixture of saccharides to obtain the products used in the claimed agent, it is appropriate to utilize cheap agricultural wastes having no nutritional and feeding values, such as cereals straw, and other waste of grain processing used to produce bioethanol.
The raw material is pretreated. It includes refinement to form 2.0 - 0.5 mm particles, chemical separation of accompanying components (waxes, fats, terpenes, soluble pectins, proteins, lignines, inorganic substances) by extraction with ethanol - benzene mixture, subsequent acid hydrolysis and separation of a carbohydrate fraction by the known procedures [Yu.I. Kholkin "Technology of hydrolysis industries", Moscow, Timber Industry, 1989]. The resulting mixtures of monosaccharides making 25 - 30 weight % of raw material are so - called "pentose fraction", primarily containing xylose and arabinose with glucose admixture.

Table 1 lists the product composition of pretreatment and hydrolysis of various raw materials.

Table 1. The product composition of pre-treatment and hydrolysis of various raw materials

Raw material	Yield of various fractions, weight %					Overall yield of pentose fraction, weight %
	Pretreatment			Hydrolysis
	Waxes, fats, terpenes	Ashes	Pentose fraction	Cellulose, lignine	Pentose fraction
Wheat straw	6	6	4	59	25	29
Rice straw	4	5	5	61	25	30
Dried silver grass	5	5	5	55	30	35

The products are obtained by the interaction of these substances with carbonyl compounds under acid catalysis with elimination of the formed water by one of the known methods [Ed. N.K. Kochetkov, "Methods of carbohydrate chemistry", Mir, Moscow, 1967, p.165]. To separate by-products poorly soluble in hydrocarbons, the reaction mixture is extracted with benzene or other suitable solvent. The extract is evaporated and used as a component of the agent to increase the octane number. Likewise, one can use di- and oligosaccharides, hydrolyzable through interaction with carbonyl compounds, and also giving the mixtures of the corresponding products.

Example 2

As carbonyl compounds, lower aldehydes or ketones can be used; in the first case, the interaction is the acetalization reaction, and the reaction products are cyclic acetals; in the second case, the interaction reaction is the ketalization reaction, and the reaction products are cyclic ketals.
Since such monosaccharides contain at least two pairs of hydroxyl groups capable, upon interaction with carbonyl compounds, to form cycles, the derivatives, containing both one and two cyclic groups per monosaccharide molecule can be obtained. To maximize the octane-increasing effect, the reaction is conducted in presence of an excess of carbonyl compound, which provides the maximal depth of conversion to form products containing two oxygen-containing cycles. Table 2 exemplifies the physical and chemical characteristics of products of interaction between saccharides (individual monosaccharides, disaccharides, monosaccharide mixtures) and acetone

Table 2. Physical and chemical characteristics of cyclic products, derived via interaction of monosaccharides and acetone

Product of interaction between saccharides and acetone	Phase state, m.p. °C
Cyclic diketal obtained by ketalization of D-glucose with acetone (glucose - acetone diketal)	Solid, 110
Cyclic diketal obtained by ketalization of D-arabinose with acetone (arabinose - acetone diketal)	Solid, 48-49
Cyclic diketal obtained by ketalization of D-xylose with acetone (xylose - acetone diketal)	Thick oil
A mixture of cyclic diketals of glucose and fructose, obtained by ketalization of saccharose with acetone	Solid, 95-99
A mixture of cyclic diketals, obtained by ketalization of the mixture of monosaccharides isolated from dried silver grass with acetone	Thick oil

The cyclic diketals of monosaccharides and acetone showed in table 2 are solid at room temperature or viscous liquid products, soluble in alcohol; their mixtures with alcohol are soluble in gasoline.

Example 3

When using pentose fraction isolated from the hydrolyzate of carbohydrate-containing raw material, the total yield of the mixture of cyclic diketals is 57 - 70% depending on the type of material from which the pentose fraction was derived. The dried silver grass is a promising material for obtaining claimed additives since it is the richest source of pentoses and provides the highest yield of resulting mixture of cyclic diketals.
Table 3 shows the weight content of the mixture obtained upon acetone ketalization of pentose fraction isolated from silver grass. Table 3. Composition of the mixture obtained by acetone ketalization of pentose fraction isolated from dried silver grass

Product of ketalization Content, weight %

Xylose - acetone diketal 77

Arabinose - acetone diketal 14

Glucose - acetone diketal 6

Diacetone alcohol 3
Monosaccharides ketalization products are nontoxic. Experiments with mice of SHK line (nursery "Stolbovaja") have shown that the preparations of cyclic diketals based on arabinose and glucose in olive oil, administered per os to the animals in doses ranging from 100 to 6000 mg/kg, are well tolerated by animals during 30 days and cause no changes in their state of health.
Cyclic monosaccharides diketals are stable in the additive agent for increasing the octane number; they can be hydrolyzed to form non-toxic products. It is their major advantage over toxic, non-degradable alkyl ethers, such as methyl tert-butyl ether widely used as a component of oxygenates.
Another group of compounds containing at least two hydroxyl groups, allowing the formation of cycles with carbonyl compounds, is composed of di-, tri- and polyhydroxy alcohols.
The reaction products of di-, tri- and polyhydroxy alcohols with carbonyl compounds - cyclic acetals and ketals - are obtained by one-step synthesis using available large-tonnage products of industrial production (glycerol, ethylene glycol, pentaerythritol, paraformaldehyde, acetaldehyde, acetone, etc.) by the known procedures in the conditions of acid catalysis with azeotropic elimination of water [A. Terney "Modern Methods of Organic Chemistry," Volume 2, Moscow: Mir, 1981, pp. 20]. In the case when the azeotropic elimination of water is carried out in the presence of methyl ethyl ketone, the reaction product is a mixture of cyclic compounds, which can also be used as a part of the claimed octane-increasing agent.
Cyclic acetals and ketals of di-and trihydroxy alcohols are fluids, readily soluble in alcohol; their mixtures with alcohol are readily soluble in gasoline.
Another example of cyclic acetal, which can be used as a component of the claimed additive agent for increasing the octane number, is pentaerythritol diformal, which is the product of the interaction between pentaerythritol and formaldehyde. Pentaerythritol is available large-tonnage product of chemical industry and is a pentahydroxy alcohol with branched structure, containing four hydroxyl groups. Their paired interaction with formaldehyde forms two dioxane cycles. Pentaerythritol diformal is a solid product soluble in alcohol.

Example 4

Octane-increasing activity of the claimed additive agents has been investigated using n-heptane and model hydrocarbon mixtures of isooctane - n-heptane 1:1 and 4:1. The measurements are carried out by the standard method according to GOST (GOST is the state standard specification in Russian Federation) 8226-82 "Fuel for the engines. Research method to determine the octane number" (method 1) and by the express method (method 2) which gives similar results to those obtained by standard methods. Express method uses the instrument for measuring gasoline detonation resistance (Octanometer OK-2m (manufacturing company "Plus Radio"), applicable for express determination of the octane number of gasolines during their production and also for research works and for the inspection of gasoline quality by consumers. The operation principle of Octanometer OK-2m is based on measuring the parameters of the reaction of cold-flame oxidation of gasolines followed by determination of a detonation resistance, equivalent to the motor and research methods. In this case, the comparison standards are taken to be the parameters of the reactions of cold-oxidation control fuels, manufactured according to GOST 511-82.

Tables 4 and 5 list the octane-increasing effect on n-heptane, and model hydrocarbon isooctane - n-heptane mixtures of additive agents containing various individual cyclic ketals and acetals and various aliphatic alcohols.

Table 4. Octane-increasing effect on n-heptane of additive agents , based on glycerol - acetone cyclic ketal in the presence of alcohols of various structures

Additive agent composition	Content of cyclic ketal in the additive agent wt%	Content of the additive agent in n-heptane, vol%	The increase of octane number, ΔON	Method for octane number (ON) determination
Cyclic ketal of glycerol and acetone + ethanol	50	20	47.3	2
Cyclic ketal of glycerol and acetone + iso-butanol	62.5	16	30.0	2

Table 5. Octane-increasing effect on model mixtures of iso-octane - n-heptane of the additive agents, including various individual cyclic acetals and ketals as well as various alcohols

Additive agent composition	Content of cyclic ketal or acetal in the additive agent, wt %	Content of the additive agent in model hydrocarbon mixture, vol. %	The increase of octane number, ΔON		Method for octane number (ON) determination
Additive agent composition			Model mixture iso-octane - n-heptane 1:1	Model mixture iso-octane - n-heptane 4:1	Method for octane number (ON) determination
Cyclic diketal of arabinose and acetone + ethanol	25	5	2.7	2.5	2
	25	10	5.8	5.7
	33	5	2.5	2.5
	33	10	5.9	5.7
	50	5	2.5	2.5
	50	10	5.7	5.2
	43	18.2	-	10.4	1
Cyclic diketal of glucose and acetone + ethanol	25	5	2.9	2.1	2
	25	10	6.0	5.2	2
	33	5	3.6	3.0
	33	10	7.2	5.8
	20	26	-	16.0	1
Cyclic diketal of xylose and acetone + ethanol	33	30	-	9.8	2
Cyclic diketal of xylose and acetone + ethanol	43	18.2	-	13.1	1
Cyclic diketal of xylose and acetone + iso-propanol	33	30	-	9.5	2
Cyclic diketal of xylose and acetone + n-butanol	33	30	-	5.6	2
Cyclic ketal of ethylene glycol and acetone +methanol	50	20	-	6.6	2
Cyclic ketal of ethylene glycol and acetone + ethanol	50	20	-	10.3	2
Cyclic ketal of ethylene glycol and acetone + iso-propanol	50	20	-	9.8	2
Cyclic ketal of ethylene glycol and acetone + n-butanol	50	20	-	4.8	2
Cyclic ketal of ethylene glycol and acetone + n-amyl alcohol	50	20	-	4.5	2
Cyclic ketal of glycerol and acetone + ethanol	50	20	-	12.6	2
Cyclic ketal of glycerol and acetone + n-butanol	50	20	-	7.2	2
Cyclic acetal of glycerol and acetaldehyde + ethanol	50	20	-	16.5	2
Cyclic acetal of pentaerythritol and formaldehyde + ethanol	50	20	-	19.6	2

The data in Tables 4 and 5 confirm the known fact that the lower the octane number of the initial hydrocarbon mixture, the greater the effect produced by introduction of octane-increasing additive agent. The magnitude of the octane-increasing effect in the tested concentration range is approximately proportional to the weight content of the additive agent in the mixture. In addition, these data indicate that the synergetic octane-increasing effect of cyclic ketals and acetals is manifested in the presence of alcohols of various structures.

Table 6 shows the octane-increasing activity of agents containing ethanol in combination with mixtures of cyclic ketals of various structures.

Table 6. Octane-increasing effects on the model hydrocarbon mixture iso-octane - n-heptane 4:1 of ethanol-containing agents comprising the mixtures of cyclic ketals (data are obtained by Method 1)

Mixture of ketals containing in the additive agent	Content of the mixture of cyclic ketals in the additive agent, wt %	Content of the additive agent in model hydrocarbon mixture, vol. %	The increase of octane number, ΔON
Mixture of cyclic diketals obtained by ketalization of pentose fraction of wheat straw hydrolyzate with acetone	9.1	29.5	22.6
Mixture of cyclic diketals obtained by ketalization of pentose fraction of dried silver grass with acetone	50	20	19.6
Mixture of cyclic ketals arabinose-acetone + glycerol-acetone (1:1)	32.9	24.3	14.8

A number of octane-increasing additive agents were tested using automobile gasoline and straight-run gasoline fraction.

Table 7 shows the examples of the octane-increasing effects of additive agents based on monosaccharides, added to automobile gasoline.

Table 7. Octane-increasing effect of additive agents, containing cyclic ketals and ethanol, on automobile gasoline with ON = 77.6 (data are obtained by Method 1)

Example Nº	Ketal containing in the additive agent	Content of ketal in the additive agent, wt.%	Content of additive agent in gasoline, vol.%	The increase of octane number, ΔON
1	Cyclic diketal of arabinose and acetone	25	5	5.7
2	Cyclic diketal of arabinose and acetone	25	10	11.9
3			15	13.8
4		33	5	5.2
5			10	11.1
6			15	13.4
7			20	14.5
8		50	5	2.7
9			10	6.1
10			15	11.7
11	Cyclic diketal of glucose and acetone	25	5	5.4
12			10	11.4
13			15	14.7
14		33	5	4.9
15			10	9.7
16			15	14.3
17			20	15.0
18*	Mixture of cyclic diketals, obtained by ketalization of pentose fraction of hydrolyzate of dried silver grass by acetone	50	20	17.0*

* The results have been obtained using commercial gasoline AI-80

Table 8 lists the test results for some types of gasoline automobile fuel, including a straight-run gasoline fraction and octane-increasing additive agents containing cyclic ketals on the basis of glycerol or ethylene glycol and ethanol.

Table 8. Test results for straight-run gasoline fraction containing cyclic ketals on the basis of glycerol or ethylene glycol and ethanol

Cyclic ketal (CK)	Ratio CK : ethanol (vol.) in the additive agent	Content of the additive agent in gasoline, vol.%	The increase of octane number, ΔON	Temperature of exfoliation T_exfol., °C
Ketal of acetone and	1:2	15	9.3	below - 30
glycerol	1 : 1	20	13.4	below - 30
Ketal of methyl ethyl ketone and glycerol	1 : 1	10	5.9	-22.7
	2 : 1	15	10.3	-28.5
	1 : 2	15	7.6	-26.9
	1 : 1	20	12.5	below -30
Ketal of cyclohexanon and glycerol	1 : 1	10	4.2	below -30
	2 : 1	15	8.0	below -30
	1 : 2	15	5.7	below -30
	1 : 1	20	10.6	below -30
Ketal of acetone and ethylene glycol	1 : 1	10	2.8	-16.3
	2 : 1	15	5.7	-17.6
	1 : 2	15	5,0	-17.2
	1 : 1	20	9.3	-28.9

If a ready-for-use gasoline - alcohol composition is used as gasoline fuel, the cyclic ketal or a mixture of cyclic ketals is added in the required amount directly to the gasoline - alcohol composition.

Data in Tables 9 and 10 show the effect of cyclic ketals on octane characteristics of gasoline-alcohol composition.

Table 9. Effect of monosaccharide-based cyclic diketals on octane characteristics of gasoline-alcohol composition with 10 % (vol) ethanol

Cyclic ketal (CK)	CK amount added to gasoline-alcohol composition, wt%	The increase of octane number, ΔON
Cyclic diketal of arabinose and acetone	8	7.0
Cyclic diketal of xylose and acetone	8	9.2
Cyclic diketal of glucose and acetone	5	6.1
Mixture of cyclic diketals of monosaccharides from wheat straw	3	4.3

Table 10. Effect of cyclic ketals, based on ethylene glycol and glycerol, on the change of octane number in gasoline-alcohol composition

	The increase of octane number, ΔON
Cyclic ketal (CK)	Gasoline-alcohol composition with 5% vol ethanol		Gasoline-alcohol composition with 10 vol. % ethanol
	Content of CK 5 vol. %	Content of CK 10 vol. %	Content of CK 5 vol. %	Content of CK 10 vol. %
Ketal of acetone and glycerol			5.1	8.9
Ketal of methyl ethyl ketone and glycerol	3.8	8.0	3.5	8.1
Ketal of cyclohexanon and glycerol	2.2	5.8	1.7	6.3
Ketal of acetone and ethylene glycol	0.8	3.6	1.0	5.1

Phase stability of gasoline - alcohol compositions, quantitatively characterized by exfoliation temperature, is measured according to GOST 5066-91 using low-temperature thermostat KRIO-VT (company TERMEX-II). Table 11 data show the effect of glycerol or ethylene glycol- based cyclic ketals on phase stability of alcohol - gasoline compositions at lower temperatures.

Table 11. Stabilizing effect of cyclic ketals on gasoline-alcohol composition

	Content of CK, vol. %	Temperature of exfoliation, °C
Cyclic ketal (CK)		Gasoline-alcohol composition with 5 vol. % ethanol	Gasoline-alcohol composition with 10 vol. % ethanol
Without CK	0	-5.8	-10.4
Ketal of acetone and glycerol	5		below- 30
Ketal of acetone and glycerol	10		below - 30
Ketal of methyl ethyl ketone and glycerol	5	- 22.7	- 26.9
Ketal of methyl ethyl ketone and glycerol	10	- 28.5	below - 30
Ketal of cyclohexanone and glycerol	5	below - 30	below - 30
Ketal of cyclohexanone and glycerol	10	below - 30	below - 30
Ketal of acetone and ethylene glycole	5	- 16.3	- 17.2
Ketal of acetone and ethylene glycole	10	- 17.6	- 28.9

Thus, the results listed indicate that the additives show the evident octane-increasing and stabilizing effects on alcohol-containing gasoline fuel.
Experiments on model systems showed that the claimed gasoline automobile fuel is poorly liable to gumming formation. So, Russian state standard specifications afford content of gums up to 6.0 mg/100 cm³ fuel, but the real gum formation in gasoline automobile fuel, containing 10% acetone - glycerol cyclic ketal, is 0.6 mg/100 cm³ of fuel, and in the gasoline automobile fuel, containing 30% acetone - glycerol cyclic ketal, is 3.0 mg/100 cm³. Regarding the known effects of said additives on decrease in detrimental products in exhaust gases, one can state that the claimed gasoline automobile fuel can render a complex positive effect on the internal combustion engine work.

Claims

A gasoline automobile fuel, characterized in that, it comprises an additive agent that is a combination between a C₁-C₅ alcohol and a cyclic product of the interaction between a lower aldehyde selected from formaldehyde and acetaldehyde or a lower ketone selected from acetone, methyl ethyl ketone, diethyl ketone and cyclohexanone, and a compound containing at least two hydroxyl groups.
The gasoline automobile fuel of Claim 1, wherein C₁-C₅ alcohol is ethanol.
The gasoline automobile fuel of Claim 1, wherein the compound containing at least two hydroxyl groups is selected from the group consisting of monosaccharides, glycol, glycerol and pentaerythrithol and mixtures thereof.
The gasoline automobile fuel of Claim 3, wherein the monosaccharide is a pentose or a hexose or mixtures thereof.
The gasoline automobile fuel of Claim 4, wherein the pentose is xylose or arabinose and the hexose is glucose.
The gasoline automobile fuel of Claim 3, wherein the glycol is ethylene glycol.
Use of the additive agent as defined in Claim 1, for increasing the octane number of gasoline.