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EP1996333B1 - Reactif de flottation pour silicates - Google Patents

Reactif de flottation pour silicates Download PDF

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Publication number
EP1996333B1
EP1996333B1 EP07722940.9A EP07722940A EP1996333B1 EP 1996333 B1 EP1996333 B1 EP 1996333B1 EP 07722940 A EP07722940 A EP 07722940A EP 1996333 B1 EP1996333 B1 EP 1996333B1
Authority
EP
European Patent Office
Prior art keywords
flotation
silicate
collector
carbon atoms
alkyl ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP07722940.9A
Other languages
German (de)
English (en)
Other versions
EP1996333A1 (fr
Inventor
Klaus-Ulrich Pedain
Tobias Rau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant International Ltd
Original Assignee
Clariant Finance BVI Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=37983358&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1996333(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Clariant Finance BVI Ltd filed Critical Clariant Finance BVI Ltd
Publication of EP1996333A1 publication Critical patent/EP1996333A1/fr
Application granted granted Critical
Publication of EP1996333B1 publication Critical patent/EP1996333B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/01—Organic compounds containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/0043—Organic compounds modified so as to contain a polyether group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/02—Collectors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/04—Frothers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/06—Depressants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00—Specified materials treated by the flotation agents; Specified applications
    • B03D2203/02—Ores
    • B03D2203/04—Non-sulfide ores

Landscapes

  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Claims (12)

  1. Utilisation d'un composé de formule (I)

            R1-O-R2-NH(2-m)-[(R3)n-H]m     (I)

    dans laquelle R1 correspond à un groupe hydrocarboné ayant 6 - 40 atomes de carbone, R2 à un groupe hydrocarboné aliphatique ayant 2 - 4 atomes de carbone et R3 à un groupe alcoxy, n est un nombre compris entre 1 et 50 et m est 1 ou 2, en tant que réactif de flottation dans la flottation de silicate.
  2. Utilisation selon la revendication 1, dans laquelle R1 est un radical hydrocarboné aliphatique ayant de 8 à 14 atomes de carbone.
  3. Utilisation selon la revendication 1 et/ou la revendication 2, dans laquelle R1 est un radical 2-éthylhexane, isononane, isodécane ou isotridécane.
  4. Utilisation selon une ou plusieurs des revendications 1 à 3, dans laquelle R1 est un radical isotridécane, R2 est C3H6, R3 est C2H4-O, n vaut de 2 à 10 et m est égal à 2.
  5. Utilisation selon une ou plusieurs des revendications 1 à 4, pour la flottation de silicate à partir de minerai de fer en association avec un autre collecteur azoté de silicate, à un pH de 7-12, dans laquelle l'autre collecteur est choisi dans le groupe constitué par des alkylétheramines, alkylétherdiamines, alkylamines ou sels d'ammonium quaternaire.
  6. Utilisation selon une ou plusieurs des revendications 1 à 5, pour l'enrichissement de minerai de fer.
  7. Utilisation selon une ou plusieurs des revendications 1 à 5, dans la flottation de silicate à partir de minerai de fer, calcite, minerai de phosphate et feldspath.
  8. Utilisation selon une ou plusieurs des revendications 1 à 5, dans la flottation de silicate, le minerai contenant entre 0 et 90 % de silicate.
  9. Utilisation du réactif de flottation selon une ou plusieurs des revendications 1 à 5, en association avec des moussants et des déprimants.
  10. Utilisation du réactif de flottation selon une ou plusieurs des revendications 1 à 5, dans un intervalle de pH de 7 à 12.
  11. Utilisation du réactif de flottation selon une ou plusieurs des revendications 1 à 5, en quantités de 0,001 à 1,0 kg par tonne de minerai de fer.
  12. Composition, contenant 1 à 99 % en poids d'un collecteur pour la flottation de silicate, qui est une alkylétheramine de formule

            R4-O-R5-NH2     (II)

    dans laquelle R4 correspond à un groupe hydrocarboné ayant 1 - 40, de préférence 8 à 32 atomes de carbone et R5 à un groupe hydrocarboné aliphatique ayant 2 - 4 atomes de carbone, ou qui est une alkylétherdiamine, une alkylamine ou un sel d'ammonium quaternaire, ainsi que 1 à 99 % en poids d'un composé de formule I.
EP07722940.9A 2006-03-09 2007-02-26 Reactif de flottation pour silicates Not-in-force EP1996333B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006010939A DE102006010939A1 (de) 2006-03-09 2006-03-09 Flotationsreagenz für Silikate
PCT/EP2007/001628 WO2007101575A1 (fr) 2006-03-09 2007-02-26 Reactif de flottation pour silicates

Publications (2)

Publication Number Publication Date
EP1996333A1 EP1996333A1 (fr) 2008-12-03
EP1996333B1 true EP1996333B1 (fr) 2013-04-17

Family

ID=37983358

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07722940.9A Not-in-force EP1996333B1 (fr) 2006-03-09 2007-02-26 Reactif de flottation pour silicates

Country Status (10)

Country Link
US (1) US8205753B2 (fr)
EP (1) EP1996333B1 (fr)
AU (1) AU2007222691B2 (fr)
BR (1) BRPI0708724A2 (fr)
CA (1) CA2645156C (fr)
DE (1) DE102006010939A1 (fr)
NO (1) NO20083886L (fr)
RU (1) RU2426597C2 (fr)
WO (1) WO2007101575A1 (fr)
ZA (1) ZA200807347B (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006019561A1 (de) 2006-04-27 2007-10-31 Clariant International Limited Flotationsreagenz für silikathaltige Mineralien
EP2017009B1 (fr) * 2007-07-20 2013-07-03 Clariant (Brazil) S.A. Flottation inversée de minerai de fer par des collecteurs dans une nanoémulsion aqueuse
CN101337204B (zh) * 2008-08-13 2011-03-30 中南大学 一种双季铵盐类化合物在硅酸盐矿物浮选上的应用及硅酸盐矿物浮选捕收剂
DE102010004893A1 (de) 2010-01-19 2011-07-21 Clariant International Limited Flotationsreagenz für magnetit- und/oder hämatithaltige Eisenerze
MX355426B (es) 2011-04-13 2018-04-18 Basf Se Compuestos de diamina y su uso para flotacion de espuma invertida de silicato a partir de mineral de hierro.
EP2679311A1 (fr) * 2012-06-30 2014-01-01 Clariant S.A., Brazil Prévention de mousse dans le processus de flottation inverse pour purifier le carbonate de calcium
US9457357B2 (en) * 2012-11-28 2016-10-04 Georgia-Pacific Chemicals Llc Mixed collector compositions
BR112017001835B1 (pt) * 2014-08-01 2023-02-07 Samarco Mineração S.a. Processo para concentração de um minério de ferro
AU2017291956A1 (en) * 2016-07-08 2019-01-17 Akzo Nobel Chemicals International B.V. Process to treat magnetite ore and collector composition
US12168237B2 (en) * 2018-07-03 2024-12-17 Nouryon Chemicals International B.V. Collector composition containing biodegradable compound and process for treating siliceous ores
CN116903490A (zh) * 2021-08-09 2023-10-20 山东富斯特油脂科技有限公司 糖基丙胺类化合物、制备方法及其作为浮选剂的应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6617303B1 (en) * 1999-01-11 2003-09-09 Huntsman Petrochemical Corporation Surfactant compositions containing alkoxylated amines

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US2389763A (en) * 1941-04-24 1945-11-27 Emulsol Corp Separation of mineral values from ores
US3398197A (en) 1965-02-23 1968-08-20 Armour Ind Chem Co Nu-secondary-alkyl tertiary amine compounds
FR1469430A (fr) 1965-02-23 1967-02-10 Armour & Co nu-alkyle secondaire-amines tertiaires
US3363758A (en) * 1966-12-08 1968-01-16 Ashland Oil Inc Use of primary aliphatic ether amine acid salts in froth flotation process
DE1259264B (de) 1966-12-24 1968-01-25 Hoechst Ag Verfahren zur Flotation von Sylvin aus Kali-Rohsalzen
FR2104657B1 (fr) 1970-05-08 1973-12-21 Pierrefitte Auby Sa
US3834533A (en) 1972-09-11 1974-09-10 Continental Oil Co Concentration of oxide copper ores by flotation separation
SE386083B (sv) 1975-01-15 1976-08-02 Berol Kemi Ab Forfarande for flotation av bly-, uran- och sellsynta jordartsmineral ur malmer
FR2367820A1 (fr) * 1976-10-18 1978-05-12 Ceca Sa Procede de flottation de minerais oxydes
US4304690A (en) 1979-04-02 1981-12-08 Texaco Development Corp. Compounds from aminated alkoxylated aliphatic alcohol
US4235811A (en) 1979-04-02 1980-11-25 Texaco Development Corp. Compounds from aminated alkoxylated aliphatic alcohol
WO1981000527A1 (fr) * 1979-08-15 1981-03-05 Sherex Chem Activateurs d'oxydes d'amines pour la flotation par ecumage de minerai
US4278533A (en) 1980-02-07 1981-07-14 The Dow Chemical Company Conditioner for flotation of oxidized coal
US4287052A (en) * 1980-04-07 1981-09-01 The Dow Chemical Company Alkyl-substituted phenyl ether amine collectors in flotation
US4319987A (en) * 1980-09-09 1982-03-16 Exxon Research & Engineering Co. Branched alkyl ether amines as iron ore flotation aids
CA1211235A (fr) 1983-11-22 1986-09-09 Richard R. Tamosiunis Flottation de l'insol a partir du minerai de potasse
US4830739A (en) 1985-02-20 1989-05-16 Berol Kemi Ab Process and composition for the froth flotation beneficiation of iron minerals from iron ores
EP0310720A1 (fr) 1987-10-09 1989-04-12 The Dow Chemical Company Procédé d'utilisation d'esters gras d'hydroxyalkylates d'alkanolamines comme agents de conditionnement pour du charbon oxydé
FR2625115B1 (fr) 1987-12-24 1990-10-19 Denain Anzin Mineraux Refract Procede d'enrichissement de l'andalousite
DE3818482A1 (de) 1988-05-31 1989-12-07 Henkel Kgaa Tensidmischungen als sammler fuer die flotation nichtsulfidischer erze
US4995965A (en) 1988-06-13 1991-02-26 Akzo America Inc. Calcium carbonate beneficiation
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DE4133063A1 (de) * 1991-10-04 1993-04-08 Henkel Kgaa Verfahren zur herstellung von eisenerzkonzentraten durch flotation
US5261539A (en) 1992-10-07 1993-11-16 American Cyanamid Company Flotation process for purifying calcite
FR2700976B1 (fr) 1993-02-04 1995-04-21 Mircal Procédé de récupération des micas par flottation et micas ainsi obtenus.
SE501623C2 (sv) 1993-05-19 1995-04-03 Berol Nobel Ab Sätt att flotera kalciumkarbonatmalm samt ett flotationsreagens därför
US5540337A (en) 1994-04-04 1996-07-30 Baker Hughes Incorporated Alkyloxyalkaneamines useful as cationic froth flotation collectors
SE521949C2 (sv) * 1997-11-27 2003-12-23 Akzo Nobel Nv Förfarande för skumflotation av silikatinnehållande järnmalm
SE514435C2 (sv) 1999-04-20 2001-02-26 Akzo Nobel Nv Kvartära ammoniumföreningar för skumflotation av silikater från järnmalm
DE102006019561A1 (de) 2006-04-27 2007-10-31 Clariant International Limited Flotationsreagenz für silikathaltige Mineralien

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6617303B1 (en) * 1999-01-11 2003-09-09 Huntsman Petrochemical Corporation Surfactant compositions containing alkoxylated amines

Also Published As

Publication number Publication date
BRPI0708724A2 (pt) 2011-06-07
NO20083886L (no) 2008-09-10
RU2426597C2 (ru) 2011-08-20
AU2007222691B2 (en) 2010-09-16
DE102006010939A1 (de) 2007-09-13
US8205753B2 (en) 2012-06-26
RU2008140181A (ru) 2010-04-20
WO2007101575A1 (fr) 2007-09-13
AU2007222691A1 (en) 2007-09-13
ZA200807347B (en) 2009-07-29
US20090114573A1 (en) 2009-05-07
EP1996333A1 (fr) 2008-12-03
CA2645156A1 (fr) 2007-09-13
CA2645156C (fr) 2014-01-14

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