EP1693138B1 - Schneidwerkzeug - Google Patents
Schneidwerkzeug Download PDFInfo
- Publication number
- EP1693138B1 EP1693138B1 EP06450021A EP06450021A EP1693138B1 EP 1693138 B1 EP1693138 B1 EP 1693138B1 EP 06450021 A EP06450021 A EP 06450021A EP 06450021 A EP06450021 A EP 06450021A EP 1693138 B1 EP1693138 B1 EP 1693138B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cutting tool
- content
- well
- less
- tool according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005520 cutting process Methods 0.000 title claims abstract description 21
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 6
- 239000000956 alloy Substances 0.000 claims abstract description 6
- 239000011651 chromium Substances 0.000 claims abstract description 6
- 229910000734 martensite Inorganic materials 0.000 claims abstract description 5
- 239000011159 matrix material Substances 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 24
- 229910000831 Steel Inorganic materials 0.000 claims description 11
- 239000010959 steel Substances 0.000 claims description 11
- 239000002023 wood Substances 0.000 claims description 6
- 238000012360 testing method Methods 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 3
- 238000003754 machining Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 239000011093 chipboard Substances 0.000 claims 1
- 150000001845 chromium compounds Chemical class 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000011109 contamination Methods 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 abstract description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052720 vanadium Inorganic materials 0.000 abstract description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052804 chromium Inorganic materials 0.000 abstract description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 3
- 239000011733 molybdenum Substances 0.000 abstract description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 2
- 239000011572 manganese Substances 0.000 abstract description 2
- 229910052759 nickel Inorganic materials 0.000 abstract description 2
- 229910052717 sulfur Inorganic materials 0.000 abstract description 2
- 239000011593 sulfur Substances 0.000 abstract description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052721 tungsten Inorganic materials 0.000 abstract description 2
- 239000010937 tungsten Substances 0.000 abstract description 2
- 229910000640 Fe alloy Inorganic materials 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 229910001566 austenite Inorganic materials 0.000 description 7
- 238000005496 tempering Methods 0.000 description 6
- 238000005275 alloying Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 150000001247 metal acetylides Chemical class 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- -1 C 6 carbides Chemical class 0.000 description 1
- 241000237536 Mytilus edulis Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000009527 percussion Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- CADICXFYUNYKGD-UHFFFAOYSA-N sulfanylidenemanganese Chemical compound [Mn]=S CADICXFYUNYKGD-UHFFFAOYSA-N 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
- C21D1/22—Martempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
Definitions
- the invention relates to a cutting tool, in particular a knife for a wood chip.
- Knives made of this steel have a high material toughness in the thermally tempered state, but their wear resistance, the dimensional stability of the cutting area and the corrosion resistance are usually too low.
- knives or blade strips are often made of steel according to material no. 1.2363 manufactured, which cutting tools usually have no sufficient wear resistance. It has already been tried, as a cutting tool material according to an alloy AT 393 387 B respectively.
- EP 0425471 A1 with the best results in terms of wear behavior, but occasionally errors occurred which pointed to too low material toughness.
- the invention has the object to overcome the respective disadvantages of the prior art and to provide a cutting tool, in particular a knife, of the type mentioned, which due to a narrow selection of the concentration of the respective elements in the steel or the chemical composition and the thermal compensation and the microstructure of the material synergistically improved performance characteristics in a machining, in particular a chip, wood with intermittent load or interrupted cut.
- a high toughness of the tool material has been found to be required because at a stroke value measured on a percussion test in the longitudinal direction of less than 100J, breakouts at the cutting edges and even knife breaks may occur.
- high material hardness values which ensure a high dimensional stability of the entire cutting area at high impact loads are necessary.
- a hardness of less than 60 HRC allows plastic deformation of the tool material, which can lead to a deterioration of the tool function in the cutting operation.
- the concentration of the respective alloying elements is important in accordance with the invention because they determine the precipitation and transformation kinetics and the microstructure in the case of a thermal treatment.
- the content of carbon is to be considered simultaneously with the content or the activity of the respective carbide-forming elements in relation to carbon.
- carbon produced by 0.5 to 0.7 wt .-% vanadium monocarbides, which have a small diameter, and are homogeneously distributed and thus with a content of at least 0.35 vol .-% make a significant contribution to the wear resistance of the material without negatively affecting its toughness.
- Higher levels of carbon and vanadium may be detrimental to the interaction of the alloying elements and tend to result in coarser carbide structure, thereby degrading material toughness.
- Low concentrations of these elements of less than 0.7% by weight Carbon and 0.5 wt .-% vanadium reduce disproportionately the wear resistance of the material.
- the carbon content of the alloy is also defined with respect to a shaping of M 7 C 3 and M 23 C 6 carbides with the other carbide-forming elements of the steel in the range of 0.7 to 0.9 wt .-%, with what content the desired properties of the matrix consisting of tempered martensite can be achieved.
- the respective concentration of chromium and molybdenum in the range of 7.5 to 8.5 or 1.4 to 1.8 are essential for a desired total carbide content of greater than 3.0 vol .-%, however, is a material embrittling effect because of Tungsten content limited to a value of less than 0.3 wt .-%.
- Manganese at levels of 0.35 to 0.45, promotes hardenability of the steel and binds the sulfur, which is believed to have a concentration level below 0.005 weight percent, to manganese sulfide.
- Nickel has a disruptive effect on the precipitation and conversion kinetics of this cutting steel in a tempering treatment, so that a Ni content of less than 0.4% by weight is essential for the desired quality of the tool.
- the inventively provided content of aluminum in the steel within the limits of 0.003 to 1.0 wt .-% on the one hand has a particularly favorable effect on the hardness and tempering behavior or on the remuneration structure and the mechanical properties of the material, on the other hand by aluminum as well the quality of a surface layer, such as a nitride layer, or the adhesion of a coating, such as a deposited after the PVD or CVD nitride, carbonitride or oxide carbonitride layer of metals, in particular of titanium and / or chromium promoted.
- Aluminum increases the activity and the diffusion coefficient of carbon in austenite.
- the diffusion coefficients of chromium, molybdenum and vanadium are reduced by aluminum in the austenite and in the ferrite. This means a reduction in the solubility of carbon in the austenite, so that the stability of the austenite is lowered and therefore the martensite starting point is increased, which in turn reduces the residual austenite content in the austenite hardened structure is greatly lowered.
- Aluminum is mainly dissolved in the matrix and contributes to the solid solution hardness. The high affinity of aluminum for nitrogen increases the hardness of the diffusion layer of nitrided steels.
- An aluminum content of 0.15 to 0.25 wt .-% in the alloy is preferred.
- a "chipper knife” made according to the invention parallel to the testing tool, was used in a device for cutting logs in difficult conditions by adhering earth particles and provided the market in comparison with a high-performance knife arranged next to it Service life improvement of 120%.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Heat Treatment Of Articles (AREA)
- Auxiliary Devices For Machine Tools (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Steel (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL06450021T PL1693138T3 (pl) | 2005-02-21 | 2006-02-15 | Narzędzie skrawające |
SI200630007T SI1693138T1 (sl) | 2005-02-21 | 2006-02-15 | Rezalno orodje |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0028605A AT500728B8 (de) | 2005-02-21 | 2005-02-21 | Schneidwerkzeug |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1693138A1 EP1693138A1 (de) | 2006-08-23 |
EP1693138B1 true EP1693138B1 (de) | 2007-08-29 |
Family
ID=36037228
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06450021A Active EP1693138B1 (de) | 2005-02-21 | 2006-02-15 | Schneidwerkzeug |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP1693138B1 (sl) |
AT (2) | AT500728B8 (sl) |
BR (1) | BRPI0600508B1 (sl) |
CA (1) | CA2537018C (sl) |
DE (1) | DE502006000071D1 (sl) |
ES (1) | ES2292161T3 (sl) |
PL (1) | PL1693138T3 (sl) |
SI (1) | SI1693138T1 (sl) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008066438A1 (en) * | 2006-11-27 | 2008-06-05 | E2 Forestry Hb | Wear resistant tool for wood chipping |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS53130217A (en) * | 1977-04-20 | 1978-11-14 | Hitachi Metals Ltd | Precipitation hardening type abrasionn resistant steel for nitriding use |
US4353743A (en) * | 1979-05-29 | 1982-10-12 | Bethlehem Steel Corporation | Steel composition for chipper knife |
US4287007A (en) * | 1979-05-29 | 1981-09-01 | Bethlehem Steel Corporation | Steel composition chipper knife |
US4353756A (en) * | 1979-05-29 | 1982-10-12 | Bethlehem Steel Corporation | Method of heat treating a steel composition for chipper knife |
AT372709B (de) * | 1979-12-20 | 1983-11-10 | Ver Edelstahlwerke Ag | Schneidwerkzeug aus legiertem stahl |
FI854000L (fi) * | 1985-10-25 | 1987-04-16 | Vsesojuzny Nauchno-Issledovatelsky Instrumentalny Institut | Skaerverktyg med en slitbestaendig belaeggning. |
AT393387B (de) | 1989-10-23 | 1991-10-10 | Boehler Gmbh | Kaltarbeitsstahl mit hoher druckfestigkeit und verwendung dieses stahles |
JP3461041B2 (ja) * | 1994-09-13 | 2003-10-27 | 日立金属株式会社 | 鋼板の剪断用刃物 |
SE518958C2 (sv) * | 2001-04-25 | 2002-12-10 | Uddeholm Tooling Ab | Föremål av stål |
AT412285B (de) * | 2003-06-23 | 2004-12-27 | Boehler Bleche Gmbh | Stahl für spanabhebende werkzeuge |
-
2005
- 2005-02-21 AT AT0028605A patent/AT500728B8/de not_active IP Right Cessation
-
2006
- 2006-02-15 ES ES06450021T patent/ES2292161T3/es active Active
- 2006-02-15 SI SI200630007T patent/SI1693138T1/sl unknown
- 2006-02-15 DE DE502006000071T patent/DE502006000071D1/de active Active
- 2006-02-15 PL PL06450021T patent/PL1693138T3/pl unknown
- 2006-02-15 EP EP06450021A patent/EP1693138B1/de active Active
- 2006-02-15 AT AT06450021T patent/ATE371513T1/de not_active IP Right Cessation
- 2006-02-20 CA CA2537018A patent/CA2537018C/en active Active
- 2006-02-20 BR BRPI0600508A patent/BRPI0600508B1/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
AT500728B1 (de) | 2006-03-15 |
CA2537018C (en) | 2010-08-03 |
CA2537018A1 (en) | 2006-08-21 |
PL1693138T3 (pl) | 2008-01-31 |
ES2292161T3 (es) | 2008-03-01 |
SI1693138T1 (sl) | 2007-12-31 |
EP1693138A1 (de) | 2006-08-23 |
DE502006000071D1 (de) | 2007-10-11 |
ATE371513T1 (de) | 2007-09-15 |
BRPI0600508B1 (pt) | 2015-09-22 |
AT500728B8 (de) | 2007-02-15 |
AT500728A4 (de) | 2006-03-15 |
BRPI0600508A (pt) | 2006-11-07 |
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