EP1526834A2

EP1526834A2 - Soap-containing cleaning substrate

Info

Publication number: EP1526834A2
Application number: EP03766193A
Authority: EP
Inventors: Harald Albrecht; Albrecht DÖRSCHNER; Jörg KÜTHER
Original assignee: Beiersdorf AG
Current assignee: Beiersdorf AG
Priority date: 2002-07-27
Filing date: 2003-07-16
Publication date: 2005-05-04
Also published as: JP2005537289A; DE10234260A1; US20060121807A1; WO2004012698A3; WO2004012698A2

Abstract

The invention relates to a substrate impregnated with a cosmetic preparation comprising one or more fatty acids salts.

Description

Soap cleaning substrate

The present invention relates to a cleaning substrate impregnated with a cosmetic preparation containing fatty acid salts, its production and use.

The desire for clean skin is probably as old as mankind, because dirt, sweat and residues of dead skin particles provide the ideal breeding ground for

Pathogens and parasites of all kinds. Probably the oldest preparations for

Cleansing the skin are the soaps, the formulations of which are already on clay tablets 2500 BC. from the two-stream country were mentioned. Even if the use and

Soap consumption has declined since the development of cleaning surfactants, not least because of their low manufacturing costs, they still have a firm place in the range of cosmetic cleaning preparations.

Soaps are formed during the reaction ("saponification") of a fat or of fatty acids or fatty acid methyl esters obtained therefrom with sodium or potassium hydroxide solution and chemically represent the alkali salt of fatty acids.

Beef tallow, palm oil, palm kernel oil or coconut oil are usually used as neutral fats. The distribution of the chain lengths of the corresponding fatty acids is important for the properties of the soap. A high concentration of laurate soap (created from lauric acid = dodecane carboxylic acid) leads to a particularly good foaming soap. The choice of the cation required for salt formation also influences the properties of the soap. Sodium soaps are mostly solid at room temperature, while potassium soaps generally have a soft and pasty consistency [W. Limbach (ed.): Cosmetics, development, manufacture and application of cosmetic products, 2nd edition, Thieme Verlag, Stuttgart, 1995].

Solid cleaning substrates, in particular wipes, represent a special product form for cleaning preparations. These can already be impregnated with the cleaning preparation by the manufacturer and therefore have the advantage that in them the preparation is already given in the correct dosage. In addition, they avoid the disadvantage of preparations stored in bottles, the packaging of which can break and the contents can "leak". Further advantages of cleaning substrates / wipes also include the fact that they can be conveniently taken in a counted quantity when traveling and for their own Application usually no longer requires water.

Cleaning substrates / cloths are made from textiles. Textiles can be woven, knitted or knitted or available as a composite (nonwoven textile). Composites are mostly used (for reasons of cost). In the case of composites, the fabric is not formed by warp and weft or stitch formation, but by intertwining and / or cohesive and / or adhesive bonding of textile fibers. Composites can be differentiated according to DIN 61210 T2 into fleece, paper wadding and felt. Nonwovens are loose materials made of staple fibers (i.e. fibers of limited length) or filaments (continuous fibers), mostly made of polypropylene, polyester or viscose, the cohesion of which is generally given by the fibers' own liability. The individual fibers can have a preferred direction (oriented or cross-layer nonwovens) or non-directional (tangled nonwovens). The nonwovens can be mechanically consolidated by needling, meshing or by swirling using sharp water jets. Adhesively bonded nonwovens are created by gluing the fibers with liquid binders (e.g. acrylate polymers, SBR / NBR, polyvinyl esters, polyurethane dispersions) or by melting or dissolving so-called binder fibers that were added to the nonwoven during manufacture. In the case of cohesive consolidation, the fiber surfaces are dissolved by suitable chemicals and connected by pressure or welded at elevated temperatures [J. Falbe, M. Regnitz: Römpp-Chemie-Lexikon, 9th edition. Thieme-Verlag, Stuttgart (1992)].

Substrates impregnated with cosmetic preparations and in particular wipes can be produced in different ways: in the so-called “dipping process”, the wipe is immersed in a dipping bath or drawn through a bath. This process is particularly suitable for paper towels and less for nonwovens, since the latter absorb a lot of liquid (= preparation) and then find puddles of the released preparation in the outer packaging. A second variant is the "spray process", in which the preparation is sprayed onto the cloth running past. This process is suitable for all textiles, but no highly foaming preparations can be applied to the cloth, since the foam development during the spray process increases gets big.

So-called stripping methods are used as a further method. There, fleece or cloth webs run past scraper plates, beams or nozzles, which are continuously loaded with impregnation solution. Different degrees of impregnation can u. a. by varying the contact pressure and the cloth tension speed.

According to the state of the art, it has so far only been satisfactorily possible to apply strongly foaming preparations to paper towels using the “immersion method”. Strongly foaming preparations serve primarily as cleaning preparations, because the foam greatly increases their cleaning performance. The disadvantage compared to paper towels Nonwovens are their low tensile strength, and are also much softer on the skin and therefore more gentle. In particular, nonwovens are suitable for facial cleansing.

Another disadvantage of the prior art is the fact that the cleaning substrates have to be dried after the impregnation with the cleaning preparation if they are to be presented to the user in the form of so-called dry wipes. This drying process is particularly time-consuming and energy-intensive and therefore represents a decisive cost factor in the manufacture of the wipes. In the case of surfactant-containing cleaning preparations, very high surfactant concentrations must also be present in the preparation so that the end product, when used, has sufficiently large amounts of foam, high cleaning performance and has a pleasant creaminess of the foam. High surfactant concentrations can lead to problems with the formulation of the preparation and slow down the drying process.

It was therefore the object of the present invention to develop substrates which do not have the disadvantages of the prior art or only have them to a minor extent. The object is surprisingly achieved by a substrate impregnated with a cosmetic preparation containing one or more fatty acid salts.

The substrates according to the invention represent cleaning utensils which have a high cleaning performance when used and are distinguished by good foamability (high amount of foam) and a pleasant creaminess of the foam.

According to the invention, impregnated substrates are understood to be substrates which have been impregnated with the cosmetic preparation by spraying, dipping or stripping. The term impregnated includes both moist-feeling, freshly soaked

Substrates as well as substrates dried or feeling dry by a drying process, which contain the cosmetic preparation in concentrated form.

The substrates according to the invention can be smooth or also surface structured.

Surface-structured substrates are preferred according to the invention.

In the substrates according to the invention, the fabric formation can take place by warp and weft, by stitch formation or by entangling, and / or cohesive and / or adhesive connection of textile fibers. It is preferred according to the invention if the substrate is a composite.

According to the invention, preference is given to using substrates in the form of cloths which consist of nonwoven, in particular of water-jet bonded and / or water-jet embossed nonwoven. The substrates can advantageously also be designed as a bulk, perforated fleece or mesh.

Such substrates can have macro embossments of any desired pattern. The selection to be made depends on the one hand on the impregnation to be applied and on the other hand on the field of application in which the subsequent cloth is to be used.

If embossed fleeces are used, large cavities on the fleece surface and in the fleece facilitate the absorption of dirt and impurities, if is run over the skin with the soaked cloth. The cleaning effect can be increased many times over compared to non-embossed wipes.

It has proven to be advantageous for the cloth if it has a weight of 20 to 120 g / m ² , preferably 30 to 80 g / m ^2, particularly preferably 40 to 60 g / m ² (measured at 20 ° C. ± 2 ° C and with a humidity of 65% ± 5% for 24 hours).

The thickness of the substrate is preferably 0.2 mm to 2 mm, in particular 0.4 mm to 1.5 mm, very particularly preferably 0.6 mm to 0.9 mm.

All organic and inorganic fiber materials on a natural and synthetic basis can generally be used as starting materials for the nonwoven fabric of the cloth. Examples include viscose, cotton, cellulose, jute, hemp, sisal, silk, wool, polypropylene, polyester, polyethylene terephthalate (PET), aramid, nylon, polyvinyl derivatives, polyurethanes, polylactide, polyhydroxyalkanoate, cellulose esters and / or polyethylene, as well as mineral fibers such as glass fibers or carbon fibers. However, the present invention is not limited to the materials mentioned, but a large number of further fibers can be used for the formation of nonwovens. For the purposes of the present invention, it is particularly advantageous if the fibers used are not water-soluble.

In an advantageous embodiment of the fleece, the fibers consist of a mixture of 60% to 80% viscose with 40% to 20% PET, in particular 70% viscose and 30% PET. A mixture of 70% viscose and 30% PET is particularly advantageous.

Fibers made of high-strength polymers such as polyamide, polyester and / or highly stretched polyethylene are also particularly advantageous.

In addition, the fibers can also be colored in order to emphasize and / or increase the visual attractiveness of the fleece. The fibers can additionally contain UV stabilizers and / or preservatives. The fibers used to form the cloth preferably have a water absorption rate of more than 60 mm / [10 min] (measured with the EDANA test 10.1-72), in particular more than 80 mm / [10 min].

Furthermore, the fibers used to form the cloth preferably have a water absorption capacity of more than 5 g / g (measured with the EDANA test 10.1-72), in particular more than 8 g / g.

Advantageous wipes in the sense of the present invention have a tear strength of in particular

[N / 50mm] in _. dry state machine direction> 60, preferably> 80

Cross direction> 20, preferably> 30 in the impregnated state, machine direction> 4, preferably> 60

Transverse direction> 10, preferably> 20

The elasticity of advantageous cloth is preferably 15% to 100%, preferably in the machine direction when dry

20% and 50%

Transverse direction 40% to 120%, preferred

50% and 85% in the impregnated state machine direction 15% to 100%, preferred

20% and 40%

Transverse direction 40% to 120%, preferred

50% and 85%

It is preferred according to the invention if the weight ratio of substrate to cleaning preparation after the direct application thereof is from 1: 0.5 to 1: 5 and particularly preferably from 1: 0.7 to 1: 3.

The fatty acid salts which are advantageous according to the invention are selected from the group of fatty acids which consist of 8 to 20 carbon atoms per molecule. The fatty acids lauric acid (dodecanecarboxylic acid), myristic acid (tetradecanecarboxylic acid), palmitic acid (hexadecanecarboxylic acid), stearic acid (octadecanecarboxylic acid) are preferred according to the invention. It is also preferred according to the invention to use the sodium or potassium salts of the fatty acids according to the invention.

It is particularly preferred in the sense of the present invention if the fatty acid salt (s) are selected from the group potassium laurate, potassium myristate, potassium palmitate, potassium stearate, potassium oleate.

It is advantageous according to the invention if the cosmetic preparation at the time of application to the substrate contains one or more fatty acid salts in a concentration of 0.1 to 20% by weight, preferably 1 to 15% by weight and very particularly preferably 2 to 10% by weight -% based on the total weight of the preparation contains.

It is advantageous according to the invention if the cosmetic cleaning preparation contains, in addition to one or more fatty acid salts, further cosmetic active ingredients, auxiliaries and / or additives.

For example, it is advantageous according to the invention if the cosmetic preparation contains one or more surfactants.

It is particularly advantageous to choose the wash-active surfactant or surfactants according to the invention from the group of surfactants which have an HLB value of more than 25, very particularly advantageous are those which have an HLB value of more than 35.

Anionic surfactants which are advantageous in accordance with the invention are acylamino acids and their salts, such as

^■ acylglutamates, especially sodium acylglutamate

^■ sarcosinates, roylsarcosinat for example myristoyl sarcosine, TEA-lauroyl sarcosinate, sodium and sodium, Sulfonic acids and their salts, such as

Acyl isethionates, e.g. Sodium / ammonium cocoyl isethionate,

• Sulfosuccinates, for example dioctyl sodium sulfosuccinate, disodium laureth sulfosuccinate, disodium lauryl sulfosuccinate and disodium undecylenamido MEA sulfosuccinate

as well as sulfuric acid esters, such as

■ alkyl ether sulfate, for example sodium, ammonium, magnesium, MIPA, TIPA laureth sulfate, sodium pareth sulfate, and sodium C ₁₂ -13, "alkyl sulfates, for example sodium, ammonium and TEA lauryl sulfate.

Also

■ taurates, for example sodium lauroyl taurate and sodium methyl cocoyl taurate,

Ether carboxylic acids, for example sodium laureth-13 carboxylate and sodium PEG-6 cocarnide carboxylate, sodium PEG-7 olive oil carboxylate,

Phosphoric acid esters and salts, such as DEA-Oleth-10 phosphate and dilaureth-4 phosphate,

Alkyl sulfonates, for example sodium cocosmonoglyceride sulfate, sodium C ₁₂ . ₁₄ olefin sulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate can be used advantageously according to the invention.

It is preferred according to the invention if, as anionic surfactants, alkyleter sulfates, acylaminosauret surfactants, sarcosinates, sulfosuccinates, sulfosuccinate citrates,

Monoalkyl phosphates, olefin sulfonates are used.

It is particularly preferred according to the invention if acylamino-acetone surfactants such as sodium cocoyl glutamate (e.g., Aminoft CS-11 from Ajinomoto), sodium lauroyl glutamate, sodium capryloyl glutamate, sodium caprinoyl glutamate and / or di-TEA-palmitoylaspartate are used as anionic surfactants.

Quaternary surfactants are particularly advantageous washing-active cationic surfactants for the purposes of the present invention. Quaternary surfactants contain at least one N atom that is covalently linked to 4 alkyl or aryl groups. Benz- are advantageous alkonium chloride, alkyl betaine, alkyl amidopropyl betaln and alkyl amidopropyl hydroxysultain.

Particularly advantageous washing-active amphoteric surfactants in the sense of the present invention are

Acyl / dialkyl ethylenediamines, for example sodium acyl amphoacetate, disodium acyl amphodipropionate, disodium alkyl amphodiacetate, sodium acyl amphohydroxypropyl sulfonate, disodium acyl amphodiacetate and sodium acyl amphopropionate,

Particularly advantageous washing-active nonionic surfactants in the sense of the present invention are

«Alkanolamides, such as Cocamide MEA / DEA / MIPA,

“Esters that are formed by esterification of carboxylic acids with ethylene oxide, glycerin, sorbitan or other alcohols, ■ ethers, for example ethoxylated alcohols, ethoxylated lanolin, ethoxylated polysiloxanes, propoxylated POE ethers and alkyl polyglycosides such as lauryl glucoside, decyl glycoside and cocoglycoside.

Further advantageous anionic surfactants are taurates, for example sodium lauroyl taurate and sodium methyl cocoyl taurate,

Ether carboxylic acids, for example sodium laureth-13 carboxylate and sodium PEO-6 cocamide carboxylate,

^■ phosphoric acid esters and salts, such as, for example, DEA-Oleth-10 phosphate and dilaureth-4 ^' phosphate, ^■ alkyl sulfonates, for example sodium cocosmonoglyceride sulfate, sodium C ₁₂ . ₁₄ olefin sulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate.

Other advantageous amphoteric surfactants are

^■ N-alkylamino acids, for example aminopropylalkylglutamide, alkylaminopropionic acid, sodium alkylimidodipropionate and lauroamphocarboxyglycinate.

Further advantageous non-ionic surfactants are alcohols.

Other suitable anionic surfactants for the purposes of the present invention are also Acylglutamates such as di-TEA-palmitoylaspartate and sodium caprylic / capric glutamate,

■ Acyl peptides, for example palmitoyl hydrolyzed milk protein, sodium cocoyl hydrolyzed soy protein and sodium / potassium cocoyl hydrolyzed collagen

as well as carboxylic acids and derivatives, such as

For example lauric acid, aluminum stearate, magnesium alkanolate and zinc decylate,

■ ester carboxylic acids, for example calcium stearoyl lactylate, laureth-6 citrate and sodium PEG-4 lauramide carboxylate, ■ alkylarylsulfonates.

Other suitable cationic surfactants for the purposes of the present invention are also

■ alkylamines,

■ alkylimidazoles and ■ ethoxylated amines.

Other suitable nonionic surfactants for the purposes of the present invention are also amine oxides, such as cocoamidopropylamine oxide.

It is advantageous in the sense of the present invention if the content of one or more detergent surfactants in the cosmetic preparation is in the range from 0.1 to 25% by weight, preferably from 1 to 15% by weight and very particularly preferably from 2 to 10% by weight is selected, in each case based on the total weight of the preparations.

The preparations according to the invention can advantageously contain polysorbates. Polysorbates are a class of compounds derived from sorbitan, a furan derivative obtained from sorbitol by splitting off two equivalents of water. The hydroxyl groups of sorbitan are etherified with polyethylene glycols, the ends of which may be esterified with fatty acids. They can be generalized by the formula Ri, R∑, R3 = H, fatty acid residue.

represent.

Polysorbates which are advantageous in the sense of the invention are, for example

- Polyoxyethylene (20) sorbitan monolaurate (Tween 20, CAS No. 9005-64-5)

- Polyoxyethylene (4) sorbitan monolaurate (Tween 21, CAS No. 9005-64-5)

- Polyoxyethylene (4) sorbitan monostearate (Tween 61, CAS No. 9005-67-8)

- Polyoxyethylene (20) sorbitan tristearate (Tween 65, CAS No. 9005-71-4) - Polyoxyethylene (20) sorbitan monooleate (Tween 80, CAS No. 9005-65-6)

- Polyoxyethylene (5) sorbitan monooleate (Tween 81, CAS No. 9005-65-5)

- Polyoxyethylene (20) sorbitan trioleate (Tween 85, CAS No. 90O5-70-3).

According to the invention, these are advantageously used in a concentration of 0.1 to 5% by weight and in particular in a concentration of 1.5 to 2.5% by weight, based on the total weight of the preparation, individually or as a mixture of several polysorbates.

The substrates according to the invention contain preservatives in the cleaning preparation with which they are impregnated. Advantageous preservatives for the purposes of the present invention are, for example, formaldehyde releasers (such as, for example, DMDM hydantoin, which is available, for example, from Lonza under the trade name Glydant ™), iodopropyl butyl carbamates (for example those under the trade names Glycacil-L, Glycacil -S available from the Fa. Lonza and / or Dekaben LMB from Jan Dekker), parabens (ie, p-hydroxybenzoates such as methyl, ethyl, propyl and / or butylparaben), phenoxyethanol, ethanol, benzoic acid and ^'the like. According to the invention, the preservation system usually also advantageously comprises preservation aids such as, for example Octoxyglycerin, Glycine Soy etc. The following table gives an overview of some preservatives advantageous according to the invention:

Also useful in cosmetics are preservatives or preservation aids, such as dibromodicyanobutane (2-bromo-2-bromomethylglutarodinitrile), phenoxyethanol, 3-iodo-2-propynylbutylcarbamate, 2-bromo-2-nitro-propane-1,3-diol , Imidazolidinyl urea, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-chloroacetamide, benzalkonium chloride, benzyl alcohol.

It is particularly advantageous according to the invention if benzoic acid and / or salicylic acid and / or their derivatives and / or salts of these compounds are used as preservatives.

It is also advantageous according to the invention if one or more preservatives is present in a concentration of 0.01 to 3% by weight, preferably in a concentration of 0.1 to 2% by weight, in each case based on the total weight of the preparation.

In addition to one or more water phases, the cleaning preparation according to the invention can preferably also contain one or more oil phases and for example in the form of W / O, O / W, W / O / W or O / W / O emulsions. Such formulations can preferably also be a microemulsion (e.g. a PIT emulsion).

In addition to the aforementioned substances, the cleaning preparations according to the invention can optionally contain the additives customary in cosmetics, for example perfume, dyes, antimicrobial substances, lipid-replenishing agents, complexing and sequestering agents, plant extracts, vitamins, active substances, bactericides, UV light protection filters, repellents, Self-tanners, depigmenting agents, pigments that have a coloring effect, softening, moisturizing and / or moisturizing substances, or other usual components of a cosmetic or dermatological formulation such as emulsifiers, polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives.

The cleaning preparation according to the invention can, as an aqueous solution or aqueous phase of an emulsion, contain, in addition to water, other ingredients according to the invention, for example alcohols, diols or polyols of low C number, and also their ethers, preferably ethanol, isopropanol, propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or monobutyl ether, propylene glycol monomethyl, monoethyl or monobutyl ether, diethylene glycol monomethyl or monoethyl ether and analogous products, as well as low carbon number alcohols, for example Ethanol, isopropanol, 1,2-propanediol and glycerin.

Advantageous moisturizing or moisturizing agents (so-called moisturizers) for the purposes of the present invention are, for example, glycerol, lactic acid and / or lactates, in particular sodium lactate, butylene glycol, propylene glycol, biosaccaride Gum-1, glycine soybean, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid and urea. Furthermore, it is particularly advantageous to use polymeric moisturizers from the group of water-soluble and / or water-swellable and / or water-gelable polysaccharides. Particularly advantageous are, for example, hyaluronic acid, chitosan and / or a fucose-rich polysaccharide, which is filed in the Chemical Abstracts under the registration number 178463-23-5 and z. B. is available under the name Fucogel®1000 from the company SOLABIA SA. It is advantageous according to the invention to add film formers (conditioners) to the cleaning preparations according to the invention.

Advantageous water-soluble or dispersible film formers are e.g. B. Polyurethanes (e.g. Avalure® types from Goodrich), Dimethicone Copolyol Polyacrylate (Silsoft Surface® from the Witco Organo Silicones Group), PVP / VA (VA = vinyl acetate) copolymer (Luviscol VA 64 Powder from BASF) etc ,

Advantageous fat-soluble film formers are e.g. B., the film formers from the group of polymers based on polyvinylpyrrolidone (PVP)

Copolymers of polyvinylpyrrolidone, for example the PVP hexadecene copolymer and the PVP eicosen copolymer, which are available under the trade names Antaron V216 and Antaron V220 from GAF Chemicals Cooperation, as well as Tricontayl PVP and the like, are advantageous.

Suitable film formers with at least one partially quaternized nitrogen group are preferably those which are selected from the group of substances which bear the name “Polyquaternium” according to the INCI nomenclature (international nomenclature cosmetic ingredient), for example:

Polyquatemium-2 (Chemical Abstracts No. 63451-27-4, e.g. Mirapol® A-15) Polyquatemium-5 (copolymer of the acrylamide and the ß-methacryloxyethyltrimethylammonium methosulfate, CAS No. 26006-22-4)

Polyquatium-6 (homopolymer of N, N-dimethyl-N-2-propenyl-2-propen-1-aminium chloride, CAS No. 26062-79-3, e.g. Merquat® 100

Polyquaternium-7 N, N-dimethyl-N-2-propenyl-2-propen-1-aminium chloride, polymer with 2-propenamide, CAS no. 26590-05-6, e.g. Merquat® S

Polyquaternium-10 Quaternary ammonium salt of hydroxyethyl cellulose, CAS no. 53568-66-4, 55353-19-0, 54351-50-7, 68610-92-4, 81859-24-7, e.g. Celquat® SC-230M, Polyquatemium-11 vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer / diethyl sulfate reaction product, CAS no. 53633-54-8, e.g. Gafquat® 755N

Polyquaternium-16 vinylpyrrolidone / vinylimidazolinium methochloride copolymer, CAS No. 29297-55-0, e.g. Luviquat® HM 552 Polyquaternium-17 CAS No. 90624-75-2, e.g. Mirapol® AD-1 polyquaternium-19 quaternized water-soluble polyvinyl alcohol polyquaternium-20 water-dispersible quaternized polyvinyl octadecyl ether polyquaternium-21 polysiloxane-polydimethyl-dimethylammonium acetate copolymer, Polyquaternium-22 dimethyldiallylammonium chloride / acrylic acid copolymer, CAS no. 53694-7-0, e.g. Merquat® 280

Polyquaternium-24 Polymeric quaternary ammonium salt of hydroxyethyl cellulose, reaction product with an epoxide substituted with lauryldimethylammonium, CAS no. 107987-23-5, e.g. Quatrisoft® LM-200 polyquaternium-28 vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymer, e.g. Gafquat® HS-100

Polyquaternium-29 e.g. Lexquat® CH Polyquaternium-31 CAS-No. 136505-02-7, e.g. Hypan® QT 100 Polyquatemium-32 N, N, N-trimethyl-2 - [(2-methyl-1-oxo-2-propenyl) oxy] -ethanaminium chloride, polymer with 2-propenamide, CAS no. 35429-19-7

Poiyquatemium-37 CAS-No. 26161-33-1 polyquaternium-44 copolymer quaternary ammonium salt consisting of vinyl pyrrolidones and quaternized imidazoline, e.g. Luviquat Care®

The polymers polyquaternium-10, polyquaternium-22 and polyquaternium-44 have proven to be preferred and advantageous.

A film former which is particularly preferred according to the invention is polyquartemium-10 (Ucare Polymer JR-125®, Ucare Polymer JR-400® from Amerchol).

The quaternized guar gum derivatives, such as guar hydroxypropyltrimonium chloride (Jaguar Excel®, Jaguar C 162® from Rhodia) and / or cellulose derivatives, represent further advantageous film formers. The oil phase of the cleaning preparations according to the invention is advantageously selected from the group of polar oils, for example from the group of lecithins and fatty acid triglycerides, especially the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids with a chain length of 8 to 24, in particular 12 to 18 carbon atoms. The fatty acid triglycerides can for example be advantageously selected from the group of synthetic, semi-synthetic and natural oils, such as. B. cocoglyceride, olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheat germ oil, grape seed oil, safflower oil, evening primrose oil, macadamia nut oil and the like.

For the purposes of the present invention, further advantageous polar oil components can also be selected from the group of esters from saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids with a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols with a chain length of 3 to 30 C atoms and from the group of esters from aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols with a chain length of 3 to 30 C atoms. Such ester oils can then advantageously be selected from the group octyl palmitate, octyl co-coat, octyl isostearate, octyl dodeceyl myristate, octyl dodecanol, cetearyl isononanoate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-stonolate, n-stonolate, n-stonyl-n-stonate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyldodecyl palmitate, stearyl heptanoate, oleyl oleate, olerlerucate, erucyl oleate, erucylerucate, tridecyl stearate, tfidecyltrimetic and natural gemellate, such as. B. Jojoba oil.

Furthermore, the oil phase can advantageously be selected from the group of dialkyl ethers and dialkyl carbonates. B. dicaprylyl ether (Cetiol OE) and / or dicaprylyl carbonate, for example that available under the trade name Cetiol CC from Cognis.

It is further preferred that the oil component or components from the group isoeikosan, neopentyl glycol diheptanoate, propylene glycol dicaprylate / dicaprate, caprylic / capric / diglyceryl succinate, butylene glycol dicaprylate / dicaprate, cocoglycerides (e.g. Myritol® 331 from Henkel), C ₁₂ . ₁₃ alkyl lactate, di-C ₁₂ - ₁₃ -Alkyltartrat, triisostearin, Dipentaerythrityl hexa caprylate / Hexacaprat, Propylenglykolmonoisostearat, Tricaprylin, dimethyl isosorbide. It is particularly advantageous if the oil phase of the formulations according to the invention has a content of C ₁₂ ι ₅ -alkyl or consists entirely of this.

Advantageous oil components are also z. B. butyl octyl salicylate (for example that available under the trade name Hallbrite BHB from CP Hall), hexadecyl benzoate and butyl octyl benzoate and mixtures thereof (Hallstar AB) and / or diethyl hexyl naphthalate (Corapan®TQ from Haarmann & Reimer).

According to the invention, Paraffinum Liquidum can also advantageously be used as an oil component.

Embodiments of the substrates according to the invention which are advantageous according to the invention are characterized in that the cleaning preparation contains skin-care oils and / or emulsions. It is preferred according to the invention if the cleaning preparation contains skin-care oils and / or emulsions in concentrations of less than 0.5% by weight.

The method for producing substrates is also in accordance with the invention, which is characterized in that the cosmetic preparation is applied to the substrate at a temperature of 40 ° C. or greater than 40 ° C. and then cooled. It is preferred according to the invention to cool the preparation applied to the substrate to room temperature, temperatures from 15 ° C. to 25 ° C. being particularly preferred.

As the heated preparation cools, the fatty acid salts are deposited (or crystallized out) on and / or in the substrate. Included in and / or adhering to the separated fatty acid salts, the further constituents of the preparation according to the invention are fixed on the substrate. Accordingly, the method for impregnating and / or fixing cosmetic preparations on substrates is characterized in that fatty acid salts in one heated cosmetic preparation is dissolved on the substrate and deposited on the substrate by subsequent cooling, according to the invention.

According to the invention, the preparations according to the invention can advantageously be applied to the substrate by the following methods:

a) coating by stripping

A wiping device (wiping bar, counter-rotating roller system, etc.) is continuously supplied with impregnation solution. This is transferred to a passing substrate by the contact.

b) coating by spraying

The liquid impregnation solution is sprayed onto the passing substrate.

, c) coating by dipping

The cloth material runs through a bath filled with the liquid impregnation solution or a complete roll of cloth is dipped into the impregnation solution.

According to the invention is also the method for producing substrates according to the invention, which is characterized in that the impregnated substrate is dried after cooling.

According to the invention, the substrates according to the invention are used for cleaning and caring for the body and face.

According to the invention, the substrates according to the invention are used for cleaning and care of the skin.

According to the invention, the substrates according to the invention are used for cleaning the facial skin from decorative cosmetics (so-called “make-up removal”) and for cleaning impure skin.

Last but not least, the use of the substrates according to the invention for cleaning and maintaining the skin appendages, in particular hair and nails, according to the invention. The use of the cloth according to the invention as a mild, foaming cleaning utensil is also in accordance with the invention.

The following examples are intended to illustrate the present invention without restricting it. Unless otherwise stated, all quantities, parts and percentages are based on the weight and the total amount or on the total weight of the preparations.

Claims

claims

1. Substrate impregnated with a cosmetic preparation containing one or more

Fatty acid salts.

2. Substrate according to claim 1, characterized in that the substrate is a fleece cloth.

3. Substrate according to one of claims 1 or 2, characterized in that the fatty acid salt or salts are selected from the group of fatty acids consisting of 8 to 20

There are carbon atoms per molecule.

4. Substrate according to one of claims 1 to 3, characterized in that the fatty acid salt or salts are selected from the group potassium laurate, potassium myristate,

Potassium palmitate, potassium stearate, potassium oleate

5. Substrate according to one of claims 1 to 4, characterized in that the cosmetic preparation at the time of application to the substrate contains one or more fatty acid salts in a concentration of 0.1 to 20% by weight based on the total weight of the preparation.

6. Substrate according to one of claims 1 to 5, characterized in that the cosmetic preparation contains one or more surfactants.

7. A method for impregnating and / or fixing cosmetic preparations on substrates, characterized in that fatty acid salts are dissolved in a heated cosmetic preparation and applied to the substrate and then deposited on the substrate by cooling.

8. A method for producing substrates according to one of claims 1 to 7, characterized in that the cosmetic preparation is applied to the substrate at a temperature of 40 ° C or greater than 40 ^C C and then cooled.

9. A method for producing substrates according to claim 8, characterized in that the impregnated substrate is dried after cooling.

10. Use of a substrate according to one of the preceding claims for cleaning and care of the body and face.