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EP1458338B1 - Färbezusammensetzung für keratinöse fasern mit einem oxyethylen-rapssamen-fettsäureamid - Google Patents

Färbezusammensetzung für keratinöse fasern mit einem oxyethylen-rapssamen-fettsäureamid Download PDF

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Publication number
EP1458338B1
EP1458338B1 EP02805417A EP02805417A EP1458338B1 EP 1458338 B1 EP1458338 B1 EP 1458338B1 EP 02805417 A EP02805417 A EP 02805417A EP 02805417 A EP02805417 A EP 02805417A EP 1458338 B1 EP1458338 B1 EP 1458338B1
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composition
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composition according
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English (en)
French (fr)
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EP1458338A2 (de
Inventor
Patricia Desenne
Cécile Bebot
Florence Laurent
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LOreal SA
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LOreal SA
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/45—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/411—Aromatic amines, i.e. where the amino group is directly linked to the aromatic nucleus
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Definitions

  • the present invention relates to a composition for the oxidation dyeing of keratinous fibers, in particular human keratinous fibers and more particularly the hair, comprising, in a medium suitable for dyeing at least one oxidation dye, and in addition at least one an oxyethylenated rapeseed fatty acid amide.
  • the invention also relates to dyeing processes and devices using said composition.
  • oxidation bases in particular ortho- or para-phenylenediamines, ortho or or para-aminophenols, and heterocyclic bases.
  • the oxidation dye precursors are initially little or not colored compounds which develop their dyeing power within the hair in the presence of oxidizing agents, leading to the formation of colored compounds.
  • the formation of these colored compounds results either from an oxidative condensation of "oxidation bases” on themselves or from an oxidative condensation of "oxidation bases” on color-modifying compounds, or "couplers". which are generally present in the dye compositions used in oxidation dyeing and are represented more particularly by meta-phenylenediamines, meta-aminophenols and meta-diphenols, and certain heterocyclic compounds.
  • oxidation bases and these couplers are formulated in vehicles or supports allowing their application on the keratinous fibers after mixing with an oxidizing agent.
  • These vehicles are generally aqueous and so that the dye composition does not run over the face during the break time, they usually contain a thickening agent.
  • amides of fatty acids in particular coconut, have been used in the past, such as coconut acid diethanolamide or coconut acid monoisopropanolamide, or the alkyl ether carboxylic acid monoethanol amide oxyethylenated with 2 moles of ethylene oxide.
  • EP-166 100 discloses oxidation dyeing compositions containing coconut acid diethanolamide.
  • EP-386,826 discloses the utility of the oxyethylenated rapeseed fatty acid amide for compositions containing surfactants.
  • the oxidation dyeing compositions comprising an oxyethylenated rapeseed fatty acid amide thus have a rheological behavior which is much more satisfactory than those of the prior art with other fatty acid amides (increased viscosity and / or stability), especially after mixing with the oxidizing composition.
  • the subject of the present invention is thus a composition for the oxidation dyeing of keratinous fibers, in particular human keratinous fibers, and more particularly the hair, comprising, in a medium which is suitable for dyeing, at least one oxidation dye, and further comprising more than 5% by weight of the composition, at least one oxyethylenated rapeseed fatty acid amide.
  • a ready-to-use composition for the oxidation dyeing of keratin fibers which comprises, in a medium suitable for dyeing, at least one composition as described above and at least one oxidizing agent.
  • ready-to-use composition is meant in the sense of the present invention, the composition intended to be applied immediately to the keratinous fibers, that is to say that it can be stored as it is before use or result from extemporaneous mixing of two or more compositions.
  • the invention also relates to a process for the oxidation dyeing of keratinous fibers, and in particular of human keratinous fibers such as the hair, which consists in applying to the fibers a coloring composition comprising, in a medium which is suitable for dyeing, at least one oxidation dye and more than 5% by weight of the composition of at least one oxyethylenated rapeseed fatty acid amide, the color being revealed at alkaline, neutral or acidic pH using an oxidizing composition comprising in a medium suitable for dyeing, at least one oxidizing agent, which is mixed just at the time of use in the dye composition or which is applied sequentially without intermediate rinsing.
  • the subject of the invention is also a multi-compartment dyeing device or "kit" for the oxidation dyeing of keratinous fibers, in particular human keratinous fibers, and more particularly the hair which comprises a compartment containing a dye composition comprising, in a medium suitable for dyeing, at least one oxidation dye and more than 5% by weight of the composition of at least one oxyethylenated rapeseed fatty acid amide, and another compartment containing an oxidizing composition comprising, in a medium suitable for dyeing, an oxidizing agent.
  • kit for the oxidation dyeing of keratinous fibers, in particular human keratinous fibers, and more particularly the hair which comprises a compartment containing a dye composition comprising, in a medium suitable for dyeing, at least one oxidation dye and more than 5% by weight of the composition of at least one oxyethylenated rapeseed fatty acid amide, and another compartment containing an oxidizing composition comprising, in a
  • the oxyethylenated rapeseed fatty acid amides which can be used according to the present invention more particularly comprise, on average, from 1 to 20 moles of ethylene oxide, preferably from 1 to 10 moles of ethylene oxide and more particularly from 1 to 5 moles. of ethylene oxide.
  • the amide corresponds to the following formula: RCONH (CH 2 CH 2 O) n H, in which R derives from the fatty acid derived from rapeseed, n is an average number of between 1 and 20, preferably between 1 and 10, more preferably between 1 and 5.
  • RCONH (CH 2 CH 2 O) n H in which R derives from the fatty acid derived from rapeseed, n is an average number of between 1 and 20, preferably between 1 and 10, more preferably between 1 and 5.
  • the commercial product Aminol®N sold by CHEM Y which is a rapeseed fatty acid amide containing 4 moles of ethylene oxide.
  • oxyethylenated rapeseed fatty acid amide represent more than 5% by weight of the composition.
  • the content of oxyethylenated rapeseed fatty acid amide represents at least 5.5% by weight and preferably at least 6% by weight of the composition.
  • the content of oxyethylenated rapeseed fatty acid amide represents up to 20% by weight of the composition, and preferably is less than 10% by weight of the composition. It should be noted that the composition does not contain the oxidant.
  • the oxidation dyes that can be used according to the invention are chosen from oxidation bases and / or couplers.
  • the compositions according to the invention contain at least one oxidation base.
  • nitrogen groups of formula (I) above mention may be made especially of amino, monoalkyl (C 1 -C 4 ) amino, dialkyl (C 1 -C 4 ) amino, trialkyl (C 1 -C 4 ) radicals. amino, monohydroxy (C 1 -C 4 ) alkylamino, imidazolinium and ammonium.
  • para-phenylenediamines of formula (I) mention may be made more particularly of para-phenylenediamine, paratoluylenediamine, 2-chloro-para-phenylene diamine, 2,3-dimethyl-para-phenylenediamine, 2,6-dimethyl-para-phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,5-dimethyl-para-phenylenediamine, N, N-dimethyl-para-phenylenediamine, N, N-diethyl-para-phenylenediamine, N, N-dipropyl-para-phenylenediamine, 4-amino-N, N-diethyl-3-methylaniline, N, N-bis- ( ⁇ -hydroxyethyl) -paraphenylenediamine, 4-N, N-bis- ( ⁇ -hydroxyethyl) amino-2-methylaniline, 4-N, N-bis- ( ⁇ -hydroxye
  • nitrogen groups of formula (II) above mention may be made especially of amino, monoalkyl (C 1 -C 4 ) amino, dialkyl (C 1 -C 4 ) amino, trialkyl (C 1 -C 4 ) radicals. amino, monohydroxy (C 1 -C 4 ) alkylamino, imidazolinium and ammonium.
  • pyridine derivatives mention may be made more particularly of the compounds described for example in patents GB 1 026 978 and GB 1 153 196, such as 2,5-diaminopyridine, 2- (4-methoxyphenyl) amino-3-amino pyridine, 2,3-diamino-6-methoxypyridine, 2- ( ⁇ -methoxyethyl) amino-3-amino-6-methoxy pyridine, 3,4-diaminopyridine, and their addition salts with an acid.
  • pyrimidine derivatives mention may be made more particularly of the compounds described for example in German Patent DE 2,359,399 or Japanese JP 88-169,571 and JP 91-10659 or patent applications WO 96/15765, such as 2,4, 5,6-tetraaminopyrimidine, 4-hydroxy-2,5,6-triaminopyrimidine, 2-hydroxy-4,5,6-triaminopyrimidine, 2,4-dihydroxy-5,6-diaminopyrimidine, 2,5 6-triaminopyrimidine, and pyrazolopyrimidine derivatives such as those mentioned in patent application FR-A-2,750,048 and among which mention may be made of pyrazolo [1,5-a] pyrimidine-3,7-diamine; 2,5-dimethyl-pyrazolo [1,5-a] pyrimidine-3,7-diamine; pyrazolo [1,5-a] pyrimidine-3,5-diamine; 2,7-dimethyl
  • the oxidation bases preferably represent from 0.0005 to 12% by weight approximately of the total weight of the composition (not including the oxidant) and still more preferably from 0.005 to 8% by weight approximately of this weight.
  • the couplers that can be used in the dyeing composition according to the invention are those conventionally used in oxidation dyeing compositions, that is to say meta-aminophenols, meta-phenylenediamines, meta-diphenols, naphthols and couplers.
  • heterocyclic compounds such as, for example, indole derivatives, indoline derivatives, sesamol and its derivatives, pyridine derivatives, pyrazolotriazole derivatives, pyrazolones, indazoles, benzimidazoles, benzothiazoles, benzoxazoles, 1,3-benzodioxoles, quinolines and their addition salts with an acid.
  • couplers are more particularly chosen from 2,4-diamino-1- ( ⁇ -hydroxyethyloxy) -benzene, 2-methyl-5-amino-phenol, 5-N- ⁇ -hydroxyethyl) amino-2-methyl-phenol , 3-amino-phenol, 1,3-dihydroxybenzene, 1,3-dihydroxy-2-methyl-benzene, 4-chloro-1,3-dihydroxybenzene, 2-amino-4- ⁇ -hydroxyethylamino) -1-methoxybenzene, 1,3-diamino-benzene, 1,3-bis (2,4-diaminophenoxy) -propane, sesamol, 1-amino-2-methoxy-4,5-methylenedioxy benzene, ⁇ -naphthol , 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy-N- ⁇ -hydroxyethylindole, 6-hydroxyindoline, 2,6-dihydroxy-4-methylpyridine
  • these couplers preferably represent from 0.0001 to 10% by weight approximately of the total weight of the composition (not including the oxidant), and even more preferably from 0.005 to 5% by weight approximately.
  • the acid addition salts of the oxidation bases and couplers are chosen in particular from hydrochlorides, hydrobromides, sulphates and tartrates, lactates and acetates.
  • the dye composition according to the invention may further comprise one or more direct dyes, in particular for modifying the shades by enriching them with reflections.
  • These direct dyes may especially be chosen from nitro, azo or anthraquinone, neutral, cationic or anionic dyes, conventionally used or those described in particular in patent applications FR-2782450, 2782451, 2782452 and EP-1025834, in the proportion by weight of d about 0.001 to 20% and preferably 0.01 to 10% of the total weight of the composition.
  • the dye composition in accordance with the invention may also comprise at least one surfactant of anionic, nonionic, cationic or amphoteric nature in a proportion ranging from 0.01 to 40% and preferably from 0.1 to 30% by weight. relative to the total weight of the composition.
  • the oxyalkylenated ether carboxylic acids or their salts represent about 2 to 15%, and preferably about 3 to 10% of the total weight of the composition.
  • nonionic surfactants which are well-known compounds per se (see in particular in this regard "Handbook of Surfactants” by MR PORTER, published Blackie & Son (Glasgow and London), 1991, pp 116-178), mention may be made of (Nonlimiting list) alcohols, alpha-diols, polyethoxylated or polypropoxylated alkylphenols, having a fatty chain comprising, for example, 8 to 22 carbon atoms, the number of ethylene oxide or propylene oxide groups being able to range from 1 to at 50.
  • lauryl alcohol with 4 moles of glycerol (INCI name: POLYGLYCERYL-4 LAURYL ETHER), lauric alcohol with 1.5 moles of glycerol, oleic alcohol with 4 moles of glycerol (INCI name: POLYGLYCERYL-4 OLEYL ETHER), oleic alcohol with 2 moles of glycerol (INCI name: POLYGLYCERYL-2 OLEYL ETHER), cetearyl alcohol with 2 moles of glycerol, cetearyl alcohol with 6 moles of glycerol, oleocetyl alcohol with 6 moles of glycerol, and octadecanol with 6 moles of glycerol.
  • the fatty alcohol may represent a mixture of fatty alcohols in the same way that the value of m represents a statistical value, which means that in a commercial product several species of polyglycerolated fatty alcohols can coexist in the form of a mixture.
  • the mono- or poly-glycerolated fatty alcohols it is more particularly preferred to use the C 8 / C 10 alcohol with 1 mole of glycerol, the C 10 / C 12 alcohol with 1 mole of glycerol and the C 12 alcohol with 1, 5 moles of glycerol.
  • the nonionic surfactant (s) represent about 2 to 40% by weight, and preferably about 4 to 20% of the total weight of the composition.
  • the ready-to-use composition according to the invention may also comprise in the dye composition and / or the oxidizing composition cationic or amphoteric polymers as described below and other rheology adjusting agents such as thickeners.
  • cellulosic hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose ..
  • guar gum and its derivatives hydroxypropylguar ..
  • gums of microbial origin xanthan gum, scleroglucan gum ..
  • the coloring part comprises at least one cationic or amphoteric polymer and at least one associative polymer.
  • cationic polymer denotes any polymer containing cationic groups and / or ionizable groups in cationic groups.
  • the cationic polymers that may be used in accordance with the present invention may be chosen from all those already known per se as improving the cosmetic properties of the hair, namely in particular those described in patent application EP 337 354 and in French patents FR 2 270 846, 2,383,660, 2,598,611, 2,470,596 and 2,519,863.
  • the preferred cationic polymers are chosen from those containing units containing primary, secondary, tertiary and / or quaternary amine groups which may either be part of the main polymer chain or may be borne by a lateral substituent directly connected thereto.
  • the cationic polymers used generally have a number-average molecular weight of between about 500 and 5 ⁇ 10 6 , and preferably between about 10 3 and 3 ⁇ 10 6 .
  • cationic polymers that may be used in the context of the invention are polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and of epichlorohydrin, quaternary polyureylenes and chitin derivatives.
  • cationic polymers that may be used in the context of the present invention, it is preferred to use the polymers of families (1), (9), (10), (11), (12) and (14). and even more preferentially, polymers with recurring units of the following formulas (W) and (U): and in particular those whose molecular weight, determined by gel permeation chromatography, is between 9500 and 9900; and especially those whose molecular weight, determined by gel permeation chromatography, is about 1200.
  • the concentration of cationic polymer in the composition according to the present invention may vary from 0.01 to 10% by weight relative to the total weight of the composition, preferably from 0.05 to 5% and still more preferably from 0.1 to 10% by weight. 3%.
  • amphoteric polymers that are particularly preferred according to the invention are those of the family (1).
  • Associative polymers are water-soluble polymers capable, in an aqueous medium, to associate reversibly with each other or with other molecules. Their chemical structure comprises hydrophilic zones, and hydrophobic zones characterized by at least one fatty chain.
  • the associative polymers according to the invention may be of anionic, cationic, amphoteric and preferably nonionic or cationic type.
  • the only hydrophobic groups are the R and R 'groups at the chain ends.
  • the number-average molecular weight of the cationic associative polyurethanes is preferably between 400 and 500,000, in particular between 1,000 and 400,000 and ideally between 1,000 and 300,000.
  • Hydrophobic group is understood to mean a radical or polymer with a hydrocarbon chain, saturated or unsaturated, linear or branched, which may contain one or more heteroatoms such as P, O, N, S, or a perfluorinated or silicone chain radical.
  • the hydrophobic group comprises at least 10 carbon atoms, preferably from 10 to 30 carbon atoms, in particular from 12 to 30 carbon atoms and more preferably from 18 to 30 carbon atoms.
  • the hydrocarbon group comes from a monofunctional compound.
  • the hydrophobic group may be derived from a fatty alcohol such as stearyl alcohol, dodecyl alcohol or decyl alcohol. It can also denote a hydrocarbon polymer such as for example polybutadiene.
  • hydrophilic group means a water-soluble polymeric group or not.
  • non-polymers include ethylene glycol, diethylene glycol and propylene glycol.
  • a hydrophilic polymer there may be mentioned by way of example polyethers, sulfonated polyesters, sulfonated polyamides, or a mixture of these polymers.
  • the hydrophilic compound is a polyether and especially a poly (ethylene oxide) or poly (propylene oxide).
  • the cationic associative polyurethanes of formula (Ia) according to the invention are formed from diisocyanates and from various compounds having functions with a labile hydrogen.
  • the functions with a labile hydrogen can be alcohol functions, primary amine or secondary or thiol giving, after reaction with the diisocyanate functions, respectively polyurethanes, polyureas and polythioureas.
  • polyurethanes of the present invention encompasses these three types of polymers namely polyurethanes themselves, polyureas and polythioureas as well as copolymers thereof.
  • a first type of compound used in the preparation of the polyurethane of formula (Ia) is a compound comprising at least one amine-functional unit.
  • This compound can be multifunctional, but preferentially the compound is difunctional, that is to say that according to a preferred embodiment, this compound comprises two labile hydrogen atoms carried for example by a hydroxyl function, primary amine, secondary amine or thiol. It is also possible to use a mixture of multifunctional and difunctional compounds in which the percentage of multifunctional compounds is low. As indicated above, this compound may comprise more than one amine-functional unit. It is then a polymer bearing a repetition of the amine functional unit.
  • This type of compound can be represented by one of the following formulas: HZ- (P) n -ZH, or HZ- (P ') p -ZH in which Z, P, P ', n and p are as defined above.
  • N-methyldiethanolamine N-tert-butyl diethanolamine and N-sulfoethyldiethanolamine.
  • methylenediphenyl diisocyanate By way of example, mention may be made of methylenediphenyl diisocyanate, methylenecyclohexane diisocyanate, isophorone diisocyanate, toluene diisocyanate, naphthalene diisocyanate, butane diisocyanate and hexane diisocyanate.
  • a third compound used in the preparation of the polyurethane of formula (Ia) is a hydrophobic compound intended to form the terminal hydrophobic groups of the polymer of formula (Ia).
  • This compound consists of a hydrophobic group and a function with labile hydrogen, for example a hydroxyl function, primary or secondary amine, or thiol.
  • this compound may be a fatty alcohol, such as in particular stearyl alcohol, dodecyl alcohol or decyl alcohol.
  • this compound comprises a polymer chain, it may be for example hydrogenated polybutadiene ⁇ -hydroxyl.
  • the hydrophobic group of the polyurethane of formula (Ia) can also result from the quaternization reaction of the tertiary amine of the compound comprising at least one unit tertiary amine.
  • the hydrophobic group is introduced by the quaternizing agent.
  • This quaternizing agent is a compound of the type RQ or R'Q, in which R and R 'are as defined above and Q denotes a leaving group such as a halide, a sulphate, etc.
  • the cationic associative polyurethane may further comprise a hydrophilic block.
  • This sequence is provided by a fourth type of compound used in the preparation of the polymer.
  • This compound can be multifunctional. It is preferably difunctional. One can also have a mixture where the percentage of multifunctional compound is low.
  • the functions with a labile hydrogen are alcohol, primary amine or secondary amine functions. or thiol.
  • This compound may be a polymer terminated at the chain ends by one of these functions with labile hydrogen.
  • non-polymers include ethylene glycol, diethylene glycol and propylene glycol.
  • hydrophilic polymer mention may be made by way of example of polyethers, sulphonated polyesters, sulphonated polyamides, or a mixture of these polymers.
  • the hydrophilic compound is a polyether and especially a poly (ethylene oxide) or poly (propylene oxide).
  • the cationic poly (vinyllactam) polymers according to the invention may be crosslinked or non-crosslinked and may also be block polymers.
  • the counterion Z - monomers of formula (I) is chosen from halide ions, phosphate ions, methosulphate ion, tosylate ion.
  • R 3 , R 4 and R 5 denote, independently of one another, a hydrogen atom or a linear or branched C 1 -C 30 alkyl radical. More preferably, the monomer b) is a monomer of formula (I) for which, still more preferably, m and n are equal to zero.
  • the monomer (IV) is vinylpyrrolidone.
  • the cationic poly (vinyllactam) polymers according to the invention may also contain one or more additional monomers, preferably cationic or nonionic monomers.
  • the terpolymers comprising, by weight, 40 to 95% of monomer (a), 0.1 to 55% of monomer (c) and 0.25 to 50% of monomer (b) will be used.
  • Such polymers are described in patent application WO-00/68282, the content of which forms an integral part of the invention.
  • poly (vinyllactam) polymers particularly using the terpolymers vinylpyrrolidone / dimethylaminopropylmethacrylamide / dodecyldimethylmethacrylamidopropylammonium tosylate, the terpolymers vinylpyrrolidone / dimethylaminopropylmethacrylamide / propylammonium tosylate cocoyldiméthylméthacrylamido, the terpolymers vinylpyrrolidone / dimethylaminopropylmethacrylamide / tosylate or chloride lauryldiméthylméthacrylamidopropylammonium ..
  • the weight-average molecular weight of the cationic poly (vinyllactam) polymers according to the present invention is preferably between 500 and 20,000,000. It is more particularly between 200,000 and 2,000,000 and even more preferentially between 400,000 and 800,000. .
  • They are preferably chosen from those comprising at least one non-cyclic cationic unit. Even more particularly, those prepared from or comprising 1 to 20 mole% of monomer having a fatty chain, and preferably 1.5 to 15 mole% and more particularly 1.5 to 6 mole%, based on the number, are preferred. total moles of monomers.
  • the monomer of formula (Ia) is chosen from acrylamidopropyltrimethylammonium chloride and methacrylamidopropyltrimethylammonium chloride.
  • the monomers of formula (II) of the present invention are preferably selected from the group consisting of acrylic acid, methacrylic acid, crotonic acid and 2-methylcrotonic acid. More particularly, the monomer of formula (II) is acrylic acid.
  • the monomers of formula (III) of the present invention are preferably chosen from the group consisting of C 12 -C 22 and more particularly C 16 -C 18 alkyl acrylates or methacrylates.
  • the monomers constituting the amphoteric fatty-chain polymers of the invention are preferably already neutralized and / or quaternized.
  • the ratio of the number of cationic charges / anionic charges is preferably equal to about 1.
  • amphoteric associative polymers according to the invention preferably comprise from 1 to 10 mol% of the monomer comprising a fatty chain (monomer of formula (Ia), (Ib) or (III)), and preferably from 1.5 to 6 mol. %.
  • the weight average molecular weight of the amphoteric associative polymers according to the invention can vary from 500 to 50,000,000 and are preferably between 10,000 and 5,000,000.
  • amphoteric associative polymers according to the invention may also contain other monomers such as nonionic monomers and in particular such as C 1 -C 4 alkyl acrylates or methacrylates.
  • Amphoteric associative polymers according to the invention are for example described and prepared in the patent application WO9844012.
  • acrylic acid / (meth) acrylamidopropyltrimethylammonium chloride / stearyl methacrylate terpolymers are preferred.
  • the polyether polyurethanes comprise at least two hydrocarbon-based lipophilic chains having from 6 to 30 carbon atoms, separated by a hydrophilic sequence, the hydrocarbon chains possibly being pendant chains or chains at the end of the hydrophilic sequence.
  • the polymer may comprise a hydrocarbon chain at one end or at both ends of a hydrophilic block.
  • the polyether polyurethanes may be multiblocked, in particular in the form of a triblock.
  • the hydrophobic sequences may be at each end of the chain (for example: hydrophilic central block triblock copolymer) or distributed at both the ends and in the chain (multiblock copolymer for example).
  • nonionic polyurethane polyethers with a fatty chain may be triblock copolymers whose hydrophilic sequence is a polyoxyethylenated chain containing from 50 to 1000 oxyethylenated groups.
  • Nonionic polyurethane polyethers have a urethane bond between the hydrophilic blocks, hence the origin of the name.
  • nonionic fatty-chain polyurethane polyethers those whose hydrophilic sequences are linked to the lipophilic blocks by other chemical bonds.
  • fatty-chain nonionic polyurethane polyethers that may be used in the invention, it is also possible to use also the urea-functional Rheolate 205® sold by Rheox or the Rheolates® 208, 204 or 212, as well as Acrysol RM 184®. Mention may also be made of the product ELFACOS T210® with a C 12-14 alkyl chain and the product ELFACOS T212® with a C 18 alkyl chain from AKZO.
  • the product DW 1206B® from ROHM & HAAS with a C 20 alkyl chain and a urethane linkage, proposed at 20% solids content in water, can also be used. It is also possible to use solutions or dispersions of these polymers, especially in water or in an aqueous-alcoholic medium.
  • such polymers include, for example, Rheolate® 255, Rheolate® 278 and Rheolate® 244 sold by Rheox.
  • the polyether polyurethanes that can be used according to the invention are in particular those described in the article by G. Fonnum, J.
  • a polyether polyurethane obtainable by polycondensation of at least three compounds comprising (i) at least one polyethylene glycol comprising from 150 to 180 moles of ethylene oxide, ( ii) stearyl alcohol or decyl alcohol and (iii) at least one diisocyanate.
  • ACULYN 46® is a polycondensate of polyethylene glycol with 150 or 180 moles of ethylene oxide, alcohol stearyl and methylenebis (4-cyclohexylisocyanate) (SMDI), 15% by weight in a matrix of maltodextrin (4%) and water (81%);
  • ACULYN 44® is a polycondensate of polyethylene glycol with 150 or 180 moles of ethylene oxide, decyl alcohol and methylene bis (4-cyclohexylisocyanate) (SMDI), at 35% by weight in a propylene glycol mixture ( 39%) and water (26%)].
  • the cationic polymers as well as the amphoteric polymers may represent from about 0.01% to 10% by weight, preferably from 0.05% to 5% by weight, and still more preferably from 0.1% to 3% by weight. of the total weight of the composition.
  • the associative polymers may represent from about 0.01 to 10% of the total weight of the composition and preferably from 0.1 to 5% by weight of the total weight of the composition.
  • the medium of the dyeing composition which is suitable for dyeing is preferably an aqueous medium consisting of water which may advantageously comprise one or more cosmetically acceptable organic solvents, of which, more particularly, linear or branched monoalcohols or diols. , preferably saturated, comprising 2 to 10 carbon atoms, such as ethyl alcohol, isopropyl alcohol, hexylene glycol (2-methyl 2,4-pentanediol), neopentyl glycol and 3-methyl-1,5 pentanediol; aromatic alcohols such as benzyl alcohol, phenylethyl alcohol; glycols or glycol ethers such as, for example, ethylene glycol monomethyl, monoethyl and monobutyl ethers, propylene glycol or its ethers such as, for example, propylene glycol monomethyl ether, butylene glycol, dipropylene glycol; as well as diethylene glycol alkyl (C1-C4) ether
  • the solvents can then be present, each in concentrations of between 0.5 and 20% by weight relative to the total weight of the composition. More particularly, the solvent content is at least 2% by weight, preferably at least 5% by weight relative to the total weight of the composition. Moreover, it is preferably less than or equal to 20% by weight, advantageously less than or equal to 15% by weight relative to the total weight of the composition.
  • the dye composition according to the invention may also comprise an effective amount of other agents, moreover previously known in oxidation dyeing, such as various conventional adjuvants such as sequestrants such as EDTA and etidronic acid, UV filters. , waxes, volatile or nonvolatile silicones, cyclic or linear or branched, organomodified (in particular by amine groups) or not, preservatives, ceramides, pseudoceramides, vegetable, mineral or synthetic oils, vitamins or provitamins as panthenol, opacifiers, etc.
  • agents moreover previously known in oxidation dyeing, such as various conventional adjuvants such as sequestrants such as EDTA and etidronic acid, UV filters.
  • waxes volatile or nonvolatile silicones, cyclic or linear or branched, organomodified (in particular by amine groups) or not, preservatives, ceramides, pseudoceramides, vegetable, mineral or synthetic oils, vitamins or provitamins
  • the composition may comprise at least one fatty substance, chosen in particular from saturated, linear or branched fatty alcohols, comprising at least 10 carbon atoms; oils or waxes, saturated, of vegetable origin, hydrocarbon-based.
  • fatty substance chosen in particular from saturated, linear or branched fatty alcohols, comprising at least 10 carbon atoms; oils or waxes, saturated, of vegetable origin, hydrocarbon-based.
  • their total content is less than or equal to 10% by weight of the composition.
  • Said composition may also comprise reducing agents or antioxidants. These may be chosen in particular from sodium sulphite, thioglycolic acid, thiolactic acid, sodium bisulfite, dehydroascorbic acid, hydroquinone, 2-methyl-hydroquinone, ter-butyl- hydroquinone and acid homogentisic, and they are then generally present in amounts ranging from about 0.05 to 3% by weight relative to the total weight of the composition.
  • the dye composition according to the invention may further comprise unsaturated fatty alcohols such as, for example, oleic alcohol, in a proportion by weight ranging from 0.5 to 15% relative to the total weight of the dyeing composition.
  • unsaturated fatty alcohols such as, for example, oleic alcohol
  • the composition, before mixing with the oxidizing composition is in the form of a liquid at 25 ° C and at atmospheric pressure.
  • said liquid has a viscosity of at most 150 cPs, measured with the RheoStress 1 rheometer, shear rate of 200s -1 , at 25 ° C.
  • the oxidizing agent is preferably chosen from hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, persalts such as perborates and persulfates.
  • the use of hydrogen peroxide is particularly preferred.
  • This oxidizing agent is advantageously constituted by a solution of hydrogen peroxide whose content may vary, more particularly, from about 1 to 40 volumes, and even more preferably from about 5 to 40. It is also possible to use one or more oxidation-reduction enzymes such as laccases, peroxidases and 2-electron oxidoreductases (such as uricase) as oxidizing agent, if appropriate in the presence of their respective donor or cofactor.
  • the pH of the ready-to-use composition and applied to the keratinous fibers is generally between the values 3 and 12 inclusive. It is preferably between 8.5 and 11 inclusive, and may be adjusted to the desired value by means of acidifying or alkalizing agents well known in the art for dyeing keratinous fibers.
  • alkalinizing agents that may be mentioned, for example, are ammonia, alkaline carbonates, alkanolamines such as mono-, di- and triethanolamines and their derivatives, hydroxyalkylamines and ethylene diamines ethoxylated and / or oxypropylenes, hydroxides of sodium or potassium and compounds of the following formula: in which R is a propylene residue optionally substituted by a hydroxyl group or a C 1 -C 4 alkyl radical; R 38, R 39, R 40 and R 41, identical or different, represent a hydrogen atom, an alkyl radical in C 1 -C 4 hydroxyalkyl or Ci-C 4.
  • the acidifying agents are conventionally, for example, inorganic or organic acids such as hydrochloric acid, orthophosphoric acid, carboxylic acids such as tartaric acid, citric acid, lactic acid, or acids. sulfonic.
  • the dyeing process according to the invention consists, preferably, in applying the composition ready for use, carried extemporaneously at the time of use from the dyeing and oxidizing compositions described above, on dry or moist keratin fibers. and to let it act for a pause time varying, preferably from 1 to 60 minutes, and more preferably from 10 to 45 minutes, to rinse the fibers, then optionally to wash with shampoo, then rinse them again, and dry them.
  • the coloring composition was mixed, at the time of use, in a plastic bowl and for 2 minutes, with an oxidizing composition containing 20 volumes of hydrogen peroxide at the rate of 1 part of coloring composition per 1.5 parts of oxidizing composition. .
  • the mixture obtained was applied to locks of hair containing 90% of whites and left for 30 minutes. The locks were then rinsed with water, washed with shampoo, rinsed again with water and then dried and disentangled. A greenish brown shade was then obtained.
  • Composition A Invention Composition B Comparative Propylene glycol 5 5 Amide of oxyethylenated rapeseed acids (4 EO) 7 3 Lauryl ether carboxylic acid (4.5 EO) 4.5 4.5 Decyl alcohol oxyethylenated (3 EO) 8.0 8.0 Oleic alcohol 1 1 Oxyethylenated lauryl alcohol (2 EO) 4 4 Diurethane (HMDI) of (C16 / C18) oxyethylenated (66 EO) and oxypropylenated (14 OP) alcohols 0.1 0.1 1,3-dihydroxybenzene (resorcinol) 0.3 0.3 1,4-diamino-benzene 0.3 0.3 Pure monoethanolamine 2 2 Ethylene diamine tetracetic acid 0.2 0.2 Erythorbic acid (or D-isoascorbic acid) 0.31 0.31 Homopolymer dimethyl diallyl ammonium
  • the dye composition was mixed, at the time of use, with an oxidizing composition containing 20 volumes of hydrogen peroxide at the rate of 1 part of coloring composition per 1.5 parts of oxidizing composition.
  • the mixture obtained is applied by half-head on 10 different models (one half-head with composition A mixed with the oxidizing composition and the other half-head with composition B mixed with the same oxidizing composition).
  • composition A according to the invention which contains 7% Aminol N, is much more adherent in roots and more consistent on heads (significant differences) than the comparative composition B which contains only 3% of Aminol N.

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Claims (39)

  1. Zusammensetzung zum oxidativen Färben von Keratinfasern und insbesondere menschlichen Keratinfasern, besonders Haaren, die in einem zum Färben geeigneten Medium mindestens einen Oxidationsfarbstoff enthält, dadurch gekennzeichnet, dass sie ferner mindestens ein ethoxyliertes Rapsfettsäureamid in einer Menge von mehr als 5 Gew.-% enthält.
  2. Zusammensetzung nach Anspruch 1, dadurch gekennzeichnet, dass das ethoxylierte Rapsfettsäureamid unter den Verbindungen mit 1 bis 20 Mol Ethylenoxid ausgewählt ist.
  3. Zusammensetzung nach Anspruch 2, dadurch gekennzeichnet, dass das ethoxylierte Rapsfettsäureamid unter den Verbindungen mit 1 bis 10 Mol Ethylenoxid ausgewählt ist.
  4. Zusammensetzung nach Anspruch 3, dadurch gekennzeichnet, dass das ethoxylierte Rapsfettsäureamid unter den Verbindungen mit 1 bis 5 Mol Ethylenoxid ausgewählt ist.
  5. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass der Gehalt des ethoxylierten Rapsfettsäureamids bis zu 20 Gew.-% der Zusammensetzung ausmacht und vorzugsweise unter 10 Gew.-% der Zusammensetzung liegt.
  6. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass der Gehalt des ethoxylierten Rapsfettsäureamids mindestens 5,5 Gew.-% der Zusammensetzung und vorzugsweise mindestens 6 Gew.-% der Zusammensetzung ausmacht.
  7. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass der Oxidationsfarbstoff unter den Oxidationsbasen und Kupplern ausgewählt ist.
  8. Zusammensetzung nach Anspruch 7, dadurch gekennzeichnet, dass sie mindestens eine Oxidationsbase enthält.
  9. Zusammensetzung nach den Ansprüchen 7 oder 8, dadurch gekennzeichnet, dass die Oxidationsbasen unter den o- oder p-Phenylendiaminen, Doppelbasen, o- oder p-Aminophenolen und den heterocyclischen Basen sowie den Additionssalzen dieser Verbindungen mit einer Säure ausgewählt sind.
  10. Zusammensetzung nach Anspruch 9, dadurch gekennzeichnet, dass die p-Phenylendiamine unter den Verbindungen der folgenden Formel (I) ausgewählt sind:
    Figure imgb0043
     worin bedeuten:
    R1 ein Wasserstoffatom, C1-4-Alkyl, C1-4-Monohydroxyalkyl, C2-4-Polyhydroxyalkyl, Alkoxy(C1-4)alkyl(C1-4), eine mit einer Stickstoff-haltigen Gruppe substituierte C1-4-Alkylgruppe, Phenyl oder 4'-Aminophenyl;
    R2 ein Wasserstoffatom, C1-4-Alkyl, C1-4-Monohydroxyalkyl, C2-4-Polyhydroxyalkyl, Alkoxy(C1-4)alkyl(C1-4) oder eine mit einer Stickstoff-haltigen Gruppe substituierte C1-4-Alkylgruppe, wobei R1 und R2 auch mit dem Stickstoffatom, von dem sie getragen werden, einen 5- oder 6-gliedrigen Stickstoffheterocyclus bilden können, der gegebenenfalls mit einer oder mehreren Gruppen Alkyl, Hydroxy oder Ureido substituiert ist;
    R3 ein Wasserstoffatom, ein Halogenatom, C1-4-Alkyl, Sulfo, Carboxy, C1-4-Monohydroxalkyl, C1-4-Hydroxyalkoxy, C1-4-Acetylaminoalkoxy, C1-4-Mesylaminoalkoxy oder C1-4-Carbamoylaminoalkoxy,
    R4 ein Wasserstoffatom, ein Halogenatom oder C1-4-Alkyl.
  11. Zusammensetzung nach Anspruch 9, dadurch gekennzeichnet, dass die Doppelbasen unter den Verbindungen der folgenden Struktur (II) ausgewählt sind:
    Figure imgb0044
     worin bedeuten:
    - die Gruppen Z1 und Z2, die gleich oder verschieden sind, die Hydroxygruppe oder die Gruppe -NH2, die mit einer C1-4-Alkylgruppe oder einer Verbindungsgruppe Y substituiert sein kann;
    - die Verbindungsgruppe Y eine geradkettige oder verzweigte Alkylenkette mit 1 bis 14 Kohlenstoffatomen, die durch eine oder mehrere Stickstoff-haltige Gruppen und/oder ein oder mehrere Heteroatome, wie Sauerstoff, Schwefel oder Stickstoff, unterbrochen oder abgeschlossen sein kann und gegebenenfalls mit einer oder mehreren Hydroxygruppen oder C1-6-Alkoxygruppen substituiert ist;
    - die Gruppen R5 und R6 ein Wasserstoffatom, ein Halogenatom, C1-4-Alkyl, C1-4-Monohydroxyalkyl, C2-4-Polyhydroxyalkyl, C1-4-Aminoalkyl oder eine Verbindungsgruppe Y;
    - die Gruppen R7, R8, R9, R10, R11 und R12, die gleich oder verschieden sind, ein Wasserstoffatom, eine Verbindungsgruppe Y oder eine C1-4-Alkylgruppe;
    mit der Maßgabe, dass die Verbindungen der Formel (II) nur eine Verbindungsgruppe Y pro Molekül enthalten.
  12. Zusammensetzung nach den Ansprüchen 10 oder 11, dadurch gekennzeichnet, dass die Stickstoff-haltigen Gruppen unter den Gruppen Amino, Monoalkyl(C1-4)amino, Dialkyl(C1-4)amino, Trialkyl(C1-4)amino, Monohydroxyalkyl(C1-4)amino, Imidazolinium und Ammonium ausgewählt sind.
  13. Zusammensetzung nach Anspruch 9, dadurch gekennzeichnet, dass die p-Aminophenole unter den Verbindungen der folgenden Struktur (III) ausgewählt sind:
    Figure imgb0045
     worin bedeuten:
    R13 ein Wasserstoffatom, ein Halogenatom, C1-4-Alkyl, C1-4-Monohydroxyalkyl, Alkoxy(C1-4)alkyl(C1-4), C1-4-Aminoalkyl oder Hydroxyalkyl(C1-4)aminoalkyl(C1-4),
    R14 ein Wasserstoffatom, ein Halogenatom, C1-4-Alkyl, C1-4-Monohydroxyalkyl, C2-4-Polyhydroxyalkyl, C1-4-Aminoalkyl, C1-4-Cyanoalkyl oder Alkoxy(C1-4)alkyl(C1-4).
  14. Zusammensetzung nach Anspruch 9, dadurch gekennzeichnet, dass die heterocyclischen Basen unter den Pyridinderivaten, Pyrimidinderivaten und darunter Pyrazolopyrimidinen und Pyrazolderivaten ausgewählt sind.
  15. Zusammensetzung nach den Ansprüchen 7 bis 14, dadurch gekennzeichnet, dass die Oxidationsbasen in Konzentrationen von 0,0005 bis 12 Gew.-% und vorzugsweise 0,005 bis 8 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, enthalten sind.
  16. Zusammensetzung nach Anspruch 7, dadurch gekennzeichnet, dass die Kuppler unter den m-Phenylendiaminen, m-Aminophenolen, m-Dihydroxybenzolen, heterocyclischen Kupplern und den Additionssalzen dieser Verbindungen mit einer Säure ausgewählt sind.
  17. Zusammensetzung nach den Ansprüchen 7 oder 16, dadurch gekennzeichnet, dass die Kuppler in Konzentrationen von 0,0001 bis 10 Gew.-% und vorzugsweise 0,005 bis 5 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, enthalten sind.
  18. Zusammensetzung nach den Ansprüchen 9 oder 16, dadurch gekennzeichnet, dass die Additionssalze der Oxidationsbasen und Kuppler mit einer Säure unter den Hydrochloriden, Hydrobromiden, Sulfaten, Tartraten, Lactaten und Acetaten ausgewählt sind.
  19. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass sie ferner Direktfarbstoffe enthält.
  20. Zusammensetzung nach dem vorhergehenden Anspruch, dadurch gekennzeichnet, dass der Mengenanteil der Direktfarbstoffe im Bereich von 0,001 bis 20 % und vorzugsweise 0,01 bis 10 % des Gesamtgewichts der Zusammensetzung liegt.
  21. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass sie ferner mindestens ein Reduktionsmittel oder Antioxidationsmittel in Mengenanteilen von 0,05 bis 3 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, enthält.
  22. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass sie mindestens einen grenzflächenaktiven Stoff enthält, der unter den anionischen, kationischen, nichtionischen oder amphoteren grenzflächenaktiven Stoffen ausgewählt ist.
  23. Zusammensetzung nach Anspruch 22, dadurch gekennzeichnet, dass sie mindestens einen anionischen grenzflächenaktiven Stoff von Typ der ethoxylierten Alkyl(C8-C30)ethercarbonsäuren oder ihrer Salze enthält.
  24. Zusammensetzung nach Anspruch 22, dadurch gekennzeichnet, dass sie mindestens einen alkoxylierten oder ein- oder mehrfach mit Glycerin veretherten, nichtionischen grenzflächenaktiven Stoff enthält.
  25. Zusammensetzung nach einem der Ansprüche 22 bis 24, dadurch gekennzeichnet, dass die grenzflächenaktiven Stoffe 0,01 bis 40 % und vorzugsweise 0,1 bis 30 Gew.-% des Gesamtgewichts der Zusammensetzung ausmachen.
  26. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass sie mindestens ein assoziatives Polymer vom nichtionischen, anionischen, kationischen oder amphoteren Typ in einer Menge von 0,01 bis 10 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, enthält.
  27. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass sie mindestens ein kationisches Polymer oder ein amphoteres Polymer in einer Menge von 0,01 bis 10 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, enthält.
  28. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass sie mindestens einen ungesättigten Fettalkohol in Mengenanteilen von 0,5 bis 15 %, bezogen auf das Gesamtgewicht der Zusammensetzung, enthält.
  29. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass sie neben Wasser mindestens ein Lösungsmittel enthält, das unter den geradkettigen oder verzweigten, vorzugsweise gesättigten Monoalkoholen oder Diolen mit 2 bis 10 Kohlenstoffatomen; aromatischen Alkoholen; Glycolen; Glycolethern, Alkyl(C1-C4)ethern von Diethylenglycol; oder deren Gemischen ausgewählt ist.
  30. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass das oder die Lösungsmittel jeweils in Konzentrationen von 0,5 bis 20 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, enthalten sind.
  31. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass sie als Flüssigkeit vorliegt.
  32. Gebrauchsfertige Zusammensetzung zum oxidativen Färben von Keratinfasern und insbesondere menschlichen Keratinfasern, wie Haaren, dadurch gekennzeichnet, dass sie durch Mischen einer Farbmittelzusammensetzung nach einem der Ansprüche 1 bis 31 und einer oxidierenden Zusammensetzung, die mindestens ein Oxidationsmittel enthält, erhältlich ist.
  33. Zusammensetzung nach Anspruch 32, dadurch gekennzeichnet, dass das Oxidationsmittel unter Wasserstoffperoxid, Harnstoff peroxid, Alkalimetallbromaten, Alkalimetallferricyaniden, Salzen von Persäuren, Redoxenzymen, wie Laccasen, Peroxidasen und Oxidoreduktasen (2 Elektronen) gegebenenfalls in Gegenwart ihres Donors oder jeweiligen Cofaktors ausgewählt ist.
  34. Zusammensetzung nach Anspruch 33, dadurch gekennzeichnet, dass es sich bei dem Oxidationsmittel um Wasserstoffperoxid handelt.
  35. Zusammensetzung nach Anspruch 34, dadurch gekennzeichnet, dass das Oxidationsmittel eine Wasserstoffperoxidlösung ist, deren Titer im Bereich von 1 bis 40 Volumina liegt.
  36. Zusammensetzung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass sie einen pH-Wert von 3 bis 12 aufweist.
  37. Verfahren zum Färben von Keratinfasern und insbesondere menschlichen Keratinfasern, besonders zum Färben der Haare, dadurch gekennzeichnet, dass es darin besteht, mindestens eine Farbmittelzusammensetzung, die in einem zum Färben geeigneten Medium mindestens einen Oxidationsfarbstoff und mehr als 5 Gew.-% mindestens eines ethoxylierten Rapsfettsäureamids enthält, auf die Fasern aufzutragen, wobei die Farbe bei einem alkalischen, neutralen oder sauren pH-Wert mit einer oxidierenden Zusammensetzung gebildet wird, die in einem zum Färben geeigneten Medium mindestens ein Oxidationsmittel enthält und die kurz vor der Anwendung mit der Farbmittelzusammensetzung vermischt wird oder die ohne zwischenzeitliches Spülen getrennt davon anschließend aufgetragen wird.
  38. Verfahren nach Anspruch 37, dadurch gekennzeichnet, dass es darin besteht, auf die trockenen oder feuchten Keratinfasern die gebrauchsfertige Zusammensetzung aufzutragen, die bedarfsgemäß bei der Anwendung aus der Farbmittelzusammensetzung und der oxidierenden Zusammensetzung gebildet wird, sie während einer Zeitspanne von etwa 1 bis 60 Minuten und vorzugsweise 10 bis 45 Minuten einwirken zu lassen, die Fasern zu spülen, gegebenenfalls mit Haarwaschmittel zu waschen, nochmals zu spülen und zu trocknen.
  39. Vorrichtung mit mehreren Abteilungen oder 'Kit' zum Färben von menschlichen Keratinfasern und insbesondere Haaren, dadurch gekennzeichnet, dass mindestens eine Abteilung eine Farbmittelzusammensetzung enthält, die in einem zum Färben geeigneten Medium mindestens einen Oxidationsfarbstoff und mehr als 5 Gew.-% mindestens eines ethoxylierten Rapsfettsäureamids enthält, und eine weitere Abteilung eine oxidierende Zusammensetzung enthält, die in einem zum Färben geeigneten Medium mindestens ein Oxidationsmittel enthält.
EP02805417A 2001-12-21 2002-12-20 Färbezusammensetzung für keratinöse fasern mit einem oxyethylen-rapssamen-fettsäureamid Expired - Lifetime EP1458338B1 (de)

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FR0116745 2001-12-21
FR0116745A FR2833837B1 (fr) 2001-12-21 2001-12-21 Composition pour la teinture d'oxydation des fibres keratiniques comprenant un amide d'acide gras de colza oxyethylene
PCT/FR2002/004519 WO2003053329A2 (fr) 2001-12-21 2002-12-20 Composition pour la teinture d'oxydation des fibres keratiniques comprenant un amide d'acide gras de colza oxyethylene

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FR2833837A1 (fr) 2003-06-27
ATE339950T1 (de) 2006-10-15
US20050125912A1 (en) 2005-06-16
US7153331B2 (en) 2006-12-26
AU2002365020A8 (en) 2003-07-09
JP2005519040A (ja) 2005-06-30
RU2281754C2 (ru) 2006-08-20
CN1620279A (zh) 2005-05-25
RU2004122396A (ru) 2005-03-27
AU2002365020A1 (en) 2003-07-09
KR20040068336A (ko) 2004-07-30
PT1458338E (pt) 2007-01-31
DK1458338T3 (da) 2007-01-29
JP4371817B2 (ja) 2009-11-25
CN100581526C (zh) 2010-01-20
ES2272819T3 (es) 2007-05-01
WO2003053329A3 (fr) 2003-12-24
CA2470444A1 (fr) 2003-07-03
MXPA04006060A (es) 2004-11-10
KR100733744B1 (ko) 2007-06-29
EP1458338A2 (de) 2004-09-22
BR0207626A (pt) 2004-07-20
WO2003053329A2 (fr) 2003-07-03
DE60214887T2 (de) 2007-01-18
DE60214887D1 (de) 2006-11-02
FR2833837B1 (fr) 2005-08-05

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