EP1388584B1

EP1388584B1 - Grease composition and grease composition-sealed bearing

Info

Publication number: EP1388584B1
Application number: EP03254737.4A
Authority: EP
Inventors: Hidenobu Mikami; Takayuki Kawamura; Mitsunari Asao; Eiichirou Shimazu
Original assignee: NTN Corp; NTN Toyo Bearing Co Ltd
Current assignee: NTN Corp
Priority date: 2002-08-02
Filing date: 2003-07-29
Publication date: 2016-04-06
Anticipated expiration: 2023-07-29
Also published as: US8609598B2; JP2004124035A; EP1388584A1; CN102643709A; JP4883743B2; CN1487063A; US20040033911A1; CN102643709B

Description

BACKGROUND OF THE INVENTION

The present invention relates to a grease composition. More particularly, the present invention relates to a grease composition and the use of the grease composition in a ball-and-roller bearing built in automobile electric parts and accessories including an alternator, an electromagnetic clutch for an automobile air conditioner, a middle pulley, and an electric fan motor.
In the automobile industry, front engine and front driving (FF) automobiles have been widely used for reducing a size and a weight. Although a space for person in an automobile has been increased, and a space for an engine room has been inevitably decreased. Accordingly, automobile electric parts and accessories including an alternator, an electromagnetic clutch for an automobile air conditioner, a middle pulley, and an electric fan motor should have been small-sized and light-weighed. For example, a decrease in outputs of the small-sized alternator is compensated with a high-speed rotation of a rotor. In addition, whereby the engine room is tightly sealed to decrease a noise, resulting in high temperature in the engine room. It urges the parts to be withstand the high temperature.
The ball-and-roller bearing is built in the electric parts and accessories, and is mainly lubricated with a grease composition. It has been reported that when the electric parts and accessories are rotated at high speed and high temperature, a rolling surface of the ball-and-roller bearing is abnormally peeled, thereby shorting the lifetime of the bearing.
US5498357 discloses a grease composition comprising as base oil an alkyl phenylether and PAO, an aromatic diurea thickener and anti-rust agents comprising an organo sulfate, sodium nitrite and a fatty polyolester. In order to avoid the abnormal peeling on the ball-and-roller bearing, Japanese Patent Laid-Open Application No. 3-210394 discloses a method of adding a passivation agent to a grease composition. International Publication No. WO94/03565 discloses a method of adding an antimony compound or a molybdenum compound to a grease composition to prolong a lifetime of a bearing.
However, it is known that a typical passivation agent, i.e., sodium nitrite, is reacted with a secondary amine under an acid condition to produce N-nitrosoamine. Since the nitrosoamine adversely affect the environment, it is not preferable. There are, however, no alternative materials.
Sodium nitrite also acts as a rust preventative, and is widely used in a grease composition for a ball-and-roller bearing used in automobile parts into which water is penetrated from a bottom of an automobile body during the automobile runs. Thus, an alternative of sodium nitrite is needed.
Other passivation agents, antimony compounds or molybdenum compounds including no sodium nitrite contain unfavorably heavy metals, which may adversely affect human bodies and the environment.

SUMMARY OF THE INVENTION

An object of the present invention is to provide a grease composition that has a prolonged lifetime at high temperature, does not adversely affect human bodies and the environment, and provides a ball-and-roller bearing with a longer lifetime and excellent rust preventative properties. The grease composition according to the present invention comprises: a base oil, a thickener, and an additive, wherein the base oil has a kinetic viscosity of 20 to 150mm²/s at 40°C and contains synthesized hydrocarbon oil and 20% by weight or more of alkyldiphenyl ether oil; the thickener is an aromatic diurea compound represented by the following formula (2)
wherein R₂ and R₄ are the same or different, and represent each an aromatic hydrocarbon group having 6 to 15 carbon atoms, and R₃ represents an aromatic hydrocarbon group having 6 to 15 carbon atoms, and is contained in an amount of 5 to 30% by weight based on the total amount of the base oil and the thickener, characterised in that the additive contains as an essential component 0.05 to 10 parts by weight of a metal salt of a dibasic acid based on 100 parts by weight of the base oil and the thickener, the metal salt of the dibasic acid being selected from one of a metal salt of azelaic acid, sebacic acid and adipic acid, and being represented by the following formula:
where M₁ and M₂ represent the same or different alkali metal selected from lithium, sodium and potassium, and R₁ represents aliphatic hydrocarbon group, and in that the grease composition contains no sodium nitrite.
The additive preferably comprises 0.05 to 5 parts by weight of an antioxidant in addition to the metal salt of the dibasic acid based on 100 parts by weight of the base oil and the thickener.
The present invention further provides the use of the grease composition of the invention in a ball-and-roller bearing, in which a sliding part of the bearing is sealed with the grease composition
The present invention is based on such a discovery that a lubricating lifetime of the grease composition at high temperature and a lifetime of the ball-and-roller bearing can be significantly improved by adding the metal salt of the dibasic acid to the grease composition, and that rust preventative properties of the grease can be significantly improved without adding sodium nitrite.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a sectional view showing an example of a deep groove ball-and-roller bearing.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

The base oil for use in the present invention has kinetic viscosity of 20 to 150 mm²/s at 40°C, and preferably 50 to 100 mm²/s. If the kinetic viscosity is less than 20 mm²/s, the base oil has insufficient heat resistance. On the other hand, if the kinetic viscosity exceeds 150 mm²/s, a heat is excessively generated by rotation, which is unfavourable.
The base oil must have at least 20% by weight of alkyldiphenyl ether oil.
Example of other components of the base oil having the kinetic viscosity defined above include mineral oils, synthesized oils and a mixture thereof that are generally used for the grease composition.
Example of the mineral oils are a paraffin-based mineral oil and a naphthene-based oil.
Examples of the synthesized oils include synthesized hydrocarbon oils, ether oils and ester oils. Specific examples of the ether oils include, alkyltriphenyl ether oils, and alkyltetraphenyl ether oils. Specific examples of the ester oils include diester oils, polyolester oils, or complex ester oils thereof, and aromatic ester oils.
The base oil contains the alkyldiphenyl ether oil, as this has excellent lubricating properties at high temperature and at high speed, and prolonged lubricating lifetime. . The base oil is a mixture of alkyldiphenyl ether oil and synthesized hydrocarbon oil and other synthesized oils or mineral oils. At least 20% by weight, preferably 60% by weight or more of alkyldiphenyl ether oil is contained in the base oil, in order to provide excellent lubricating properties and prolonged lifetime.
Specifically, the alkyldiphenyl ether oil is the monoalkyldiphenyl ether oil represented by the following formula (3) and/or the dialkyldiphenyl ether oil represented by the following formula (4):

where each of R₅, R₆ and R₇ is an alkyl side chain having 8 to 20 carbon atoms, and is bonded to one phenyl ring or two phenyl rings.
Of these, the dialkyldiphenyl ether oil having the alkyl side chains R₆ and R₇ is preferable, with taking heat resistance and evaporation properties into consideration.
The base oil containing the alkyldiphenyl ether oil also has a kinetic viscosity of 20 to 150 mm²/s at 40°C.
Preferably, M₁ and M₂ are the same alkali metal in the metal salt of the dibasic acid represented by the formula (1). Examples of such metal salt of the dibasic acid include sodium azelate, sodium sebacate, sodium adipate, and potassium sebacate. Sodium sebacate is more preferable, since rust preventative properties and lubricating lifetime at high temperature of the grease can be significantly improved without soda nitrite.
The metal salt of the dibasic acid represented by the formula (1) is contained in amount of 0.05 parts to 10 parts by weight, preferably 0.5 parts to 5 parts by weight based on 100 parts of the base oil and the thickener. If the metal salt of the dibasic acid is contained in amount of less than 0.05 parts by weight, no effect is provided. If the metal salt of the dibasic acid is contained in amount of more than 10 parts by weight, it is gelled and unusable.
The thickener is the aromatic diurea compound represented by the formula (2), preferably having high heat resistance properties.
In the aromatic diurea compound represented by the following formula (2), each of R₂ and R₄ represent an aromatic hydrocarbon group having 6 to 15 carbon atoms, and may the same or different. If the numbers of carbon atoms are less than 6, the thickener has poor heat resistance. If the numbers of carbon atoms are more than 15, the grease has poor thickening properties. Examples of the R₂ and R₄ include a phenyl group, a tolyl group, a xylyl group, t-butylphenyl group, a benzyl group and the like.
In the formula (2), R₃ represents an aromatic hydrocarbon group having 6 to 15 carbon atoms. If the numbers of carbon atoms are less than 6, the grease has poor thickening properties. If the numbers of carbon atoms are more than 15, the grease is easily hardened. Examples of the R₃ include an aromatic single ring, an aromatic fused ring, and a group obtained by linking these rings with a methylene chain, a cyanuric ring, an isocyanuric ring and the like. Preferably, the aromatic hydrocarbon group is represented by the following formulas (5):
Of these, particularly preferable group is represented by the following formulas (6):
The aromatic diurea compound is used as the thickener, whereby the grease composition has improved heat resistance.
The aromatic urea thickener is obtainable by reacting an isocyanate compound with an amino compound. It is preferable that an isocyanate group of the isocyanate compound and an amino group of the amino compound be approximately equivalent in order not to leave reactive free radicals.
The grease composition may be prepared by reacting the isocyanate compound with the amino compound in the base oil, or by mixing the urea compound synthesized in advance with the base oil. The former is preferable since the stability of the grease composition is easily kept.
The urea-based thickener is contained in amount of 5% to 30% by weight based on the total amount of the grease. If the amount of the urea-based thickener is less than 5% by weight, the grease composition becomes liquid with low viscosity. Such grease composition is easily leaked so that the bearing is hardly sealed. On the other hand, if the amount of the urea-based thickener exceeds 30% by weight, the grease composition is solidified, and consistency becomes 200 or less, resulting in an unusable grease composition for sealing the bearing.
The grease composition of the present invention comprises the base oil, the thickener, and the metal salt of the dibasic acid as the essential components as described above. In addition, the grease composition may comprise additives such as an extreme pressure agent, an antioxidant, a rust preventative, a metal deactivator, and an oily agent that are conventionally added to the grease.
By adding the extreme pressure agent to the grease composition, load resistance and extreme pressure properties can be improved. For example, the compounds described below can be used. Examples of the extreme pressure agent in an organic metal type include an organic zinc compound such as zinc dithiocarbamate, zinc dithiophosphate, and zinc phenate; an organic selenium compound such as selenium dithiocarbamate; an organic bismuth compound such as bismuth naphthenate, and bismuth dithiocarbamate; an organic iron compound such as iron dithiocarbamate and iron octylate; an organic copper compound such as copper dithiocarbamate and copper naphthenate; an organic lead compound such as lead naphthenate, and lead dithiocarbamate; an organic tin compound such as tin maleate, and dibutyltin sulfide. Also, an organic sulfonate, phenate, phosphate of an alkali metal or an alkali earth metal; or an organic metal compound of gold, silver, titanium, cadmium can be used as required. Examples of the extreme pressure agent in a sulfur type include a sulfide or polysulfide compound such as dibenzyldisulfide; sulfurized oil; a non-ash type carbamate compound; a thiourea compound; a thiocarponate and the like. Examples of the extreme pressure agent in a phosphoric acid type include a phosphoric acid ester such as trioctylphosphate, and tricresylphosphate; a phosphoric acid ester-based compound such as acidic phosphoric acid ester, phosphorous acid ester, and acidic phosphorous acid ester. Also, there can be used a halogen-based extreme pressure agent such as chlorinated paraffin; and a solid lubricant such as molybdenum disulfide, tungsten disulfide, graphite, polytetrafluoroethylene, antimony sulfide, and a boron compound such as boron nitride. Of these, the dithiocarmic acid-based compound and the dithiophosphoric acid-based compound are preferable.
As the antioxidant, there can be used an age resistor, an antiozonant, and an oxidation inhibitor that are added to rubber, plastic, and a lubricant, by selecting suitable one as required. Specific examples include an amine-based compound such as phenyl-1-naphtylamine, phenyl-2-naphtylamine, diphenyl-p-phenylenediamine, dipyridylamine, p,p-dioctyldiphenylamine, N,N-diisopropyl-p-phenylenediamine, and N,N-di-sec-butyl-p-phenylenediamine.
Preferably, a sulfur-containing antioxidant, and a phenol-based antioxidant can use used. Examples of the sulfur-containing antioxidant include alkyl dithio phosphate, dilauryl thiodipropionate, distearylthiodipropionate, dimyristylthiodipropionate, ditridecylthiodipropionate, phenothiazine, N-methylphenothiazine, N-ethylphenothiazine, and 3,7-dioctylphenothiazine.
Examples of the phenol-based antioxidant include 2,6-di-tert-butylphenol, n-octadecyl-3-(3',5'-di-tert-butyl-4-hydroxyphenyl)propionate, tetrakis-(methylene-3-(3',5'-di-tert-butyl-4-hydroxyphenyl)propionate)methane, 2,2'-methylenebis-(4-methyl-6-tert-butylphenol), and 4,4'-buthylidenebis-(3-methyl-6-tert-butylphenol).
Examples of the rust preventative include an ammonium salt of an organic sulfonic acid; an alkali metal such as barium, zinc, calcium, and magnesium; an organic sulfonic acid salt of an alkali earth metal; an organic carboxylic acid salt; phenate; phosphonate; an alkyl or an alkenyl succinic acid derivative such as an alkyl or an alkenyl succinic acid ester; a partially esterified multivalent alcohol such as sorbitanmonooleate; hydroxyl fatty acids such as oleoylsarcosine; mercapto fatty acids such as 1-mercapto stearic acid or metal salts thereof; higher fatty acids such as stearic acid; higher alcohol such as isostearyl alcohol; an ester of a higher alcohol and a higher fatty acid; thiazoles such as 2,5-dimercapto-1,3,4-thiadiazole, and 2-mercaptothiadiazole; an imidazole compound such as 2-(decyldithio)-benzimidazole and benzimidazole; a phosphoric acid ester such as trisnonylphenylphosphite; a thiocarboxylic acid ester compound such as dilaurylthiopropionate.
Examples of the metal inactivator include a triazole compound such as benzotriazole and tolyltriazole.
Examples of the oily agent include a fatty acid such as oleic acid and stearic acid; a fatty acid alcohol such as oleyl alcohol; a fatty acid ester such as polyoxyethylene stearic acid ester and polyglyceryloleic acid ester; phosphoric acid; a phosphoric acid ester such as tricresyl phosphate, lauryl acid ester and polyoxyethylene oleyl ether.
Fig. 1 shows an example of a ball-and-roller bearing according to the present invention, and is a sectional view of a deep groove ball bearing.
The ball-and-roller bearing 1 comprises an inner ring 2 having an inner ring rolling surface 2a on an outer perimeter, an outer ring 3 having an outer ring rolling surface 3a on an inside perimeter, and a plurality of rolling elements 4 disposed between the inner ring rolling surface 2a and the outer ring rolling surface 3a. The inner ring 2 and the outer ring 3 are disposed concentrically. The bearing 1 also comprises a holder 5 for holding the rolling elements 4, and a sealing member 6 fixed on the outer ring 3. A grease composition 7 is sealed at least around the rolling elements 4.
The ball-and-roller bearing 1 is environmentally-benign, since the grease composition 7 uses the additive containing no nitrite. Also the bearing 1 has excellent rust preventative properties, and can be suitably used in a ball-and-roller bearing built in automobile electric parts and accessories including an alternator, an electromagnetic clutch for an automobile air conditioner, a middle pulley, and an electric fan motor.

Example 1

A base oil was prepared by mixing poly-α-olefine oil (commercially available under the trade name of "Shinfluid 601" from Nippon Steel Chemical Co., Ltd.) and alkyldiphenyl ether oil (commercially available under the trade name of "LB100" from Matsumura Sekiyu:KK)in the ratio shown in Table 1. The base oil is separated into two liquids. 4,4'-diphenyl methane diisocyanate was dissolved into the first half of the liquids, and p-toluidine in amount of two equivalent weight of 4,4'-diphenyl methane diisocyanate was dissolved into the second half of the liqudis. 4,4'-diphenyl methane diisocyanate was added as an aromatic diurea compound in an amount shown in Table 1. While the first half solution in which 4,4'-diphenyl methane diisocyanate was dissolved was stirred, the second half solution in which p-toluidine was dissolved was added to the first half solution. The mixed solution was stirred at 100 to 120°C for 30 minutes, whereby the aromatic diurea compound was mixed with the base oil. Sorbitantorioleate, sodium sebacate and an antioxidant were added thereto in amount shown in Table 1, and stirred at 100 to 120°C for 10 minutes. After cooling, the mixed solution was homogenized using three-rolls to provide a grease composition.
The thus-obtained grease composition was evaluated using a high temperature and high speed test, a quick acceleration and deceleration test and rust preventative test. The results are also shown in Table 1.

High temperature and high speed test

A ball-and-roller bearing (6204) was sealed with 0.7 g of grease to be tested, rotated at 10000 rpm, at an outer diameter temperature of an outer ring of the bearing of 150°C under a radial load of 67 N and an axial load of 67 N. A time to seizure was measured. The results are also shown in Table 1.

Quick acceleration and deceleration test

A quick acceleration and deceleration test was conducted on a ball-and-roller bearing that supported a rotating shaft with an inner ring; the rotating shaft supporting a pulley around which a rotating belt of an alternator was wound; the alternator being one example of electrical auxiliary equipment. Operation conditions of the quick acceleration and deceleration test were set as follows: a load of 3234 N to the pulley, and a rotating speed of 0 to 18000 rpm. An endurable time (life time) was measured, which was the time to produce abnormal peeling within the bearing, to detect higher vibration than a set value by an oscillation detector, and finally to stop a generator. The results are also shown in Table 1.

Rust preventative test

A rust preventative test was conducted in accordance with, but under more severe test conditions than, the method set forth in ASTM D 1743. A conical roller bearing "30204" was degreased with an organic solvent, and dried in advance. The bearing was sealed with 1.9 to 2.1 g of the grease composition being tested. 98N of an axial load was applied to the bearing. Running-in was performed for 1 minute at 1800 rotations per minute. Thereafter, the bearing was dipped with 1% by weight of saline solution, was introduced into a sealed high humid vessel where it reaches a saturated vapor pressure at 40°C, and allowed to stand for 48 hours at 40°C. Rust generation was observed and determined. An outer ring of the bearing was divided into 32 portions to count the numbers of the portions where rust was generated. Results are presented as the average of four tests, and also shown in Table 1.

Examples 2 to 4 and Comparative Examples 1 to 4

In each example, a thickener and a base oil were selected in a ratio shown in Table 1 to prepare a base grease in a manner similar to Example 1. To the base grease, an additive was added to provide a grease composition. In Comparative Example 1, 2, 3 or 4, the base oil was constituted only with an alkyldiphenyl ether oil. The resultant grease compositions were tested for the above-mentioned tests in a manner similar to Example 1. The results are also shown in Table 1.

Comparative Examples 5 to 8

In each Comparative Example, a thickener and a base oil were selected in a ratio shown in Table 2 to prepare a base grease in a manner similar to Example 1. To the base grease, an additive was added to provide a grease composition. The resultant grease compositions were tested for the above-mentioned tests in a manner similar to Example 1. The results are shown in Table 2.
Table 1

Table1

	Example
	1	2	1*	2*	3	3*	4	4*
Component (parts by weight)
Base oil
Synthesized hydrocarbon oil*¹⁾	16	16	-	-	16	-	16	-
Alkyldiphenyl ether oil*²⁾	64	64	80	80	64	80	64	80
Thickener
Amine, p-toluidine	9.3	9.3	9.3	9.3	9.3	9.3	9.3	9.3
Diisocyanate, MDI*³⁾	10.7	10.7	10.7	10.7	10.7	10.7	10.7	10.7
Additives
Ba sulfonate	-	1	-	1	-	1	-	1
Sorbitanester*⁴⁾	1	-	1	-	1	-	1	-
Metal salt of dibasic acid (Na sebacate)	1	1	1	1	1	1	1	1
Antioxidant
Alkylated diphenylamine	2	2	2	2	-	-	-	-
Dilaurylthiodipropionate	-	-	-	-	2	2	2	2
Tetrakis-(methylene-3-(3',5'-di-t-butyl-4- hydroxyphenyl)propionate)methane	-	-	-	-	-	-	1	1
Properties
Viscosity of base oil (40°C, =mm²/s)	72	72	97	97	72	97	72	97
Worked penetration (JIS K2220)	286	264	292	288	288	300	284	298
High temperature and high speed test, h	1200	1000	1600	1400	2200	2600	2900	3000
Quick acceleration and deceleration test, h	>300	>300	>300	>300	>300	>300	>300	>300
Rust preventative properties, number	3	1	5	2	1	4	0	5

*1) "Shinfluid 601" from Nippon Steel Chemical Co., Ltd.
*2) "LB100" from Matsumura Sekiyu:KK
*3) diphenylmethandiisocyanate
*4) sorbitantrioleate
* Comparative

Table 2

Table2

	Comparative Example
	5	6	7	8
Component (parts by weight)
Base oil
Synthesized hydrocarbon oil*¹⁾	16	16	16	-
Alkyldiphenyl ether oil*²⁾	64	64	64	80
Thickener
Amine, p-toluidine	9.3	9.3	9.3	9.3
Diisocyanate, MDI*³⁾	10.7	10.7	10.7	10.7
Additives
Ba sulfonate
	1	1	-	1
Sorbitanester*⁴⁾	1	-	1	1
Metal salt of dibasic acid (Na sebacate) Antioxidant	-	-	-	-
Alkylated diphenylamine	2	2	2	2
Dilaurylthiodipropionate	-	-	-	-
Tetrakis-(methylene-3-(3',5'-di-t-butyl-4- hydroxyphenyl)propionate)methane	-	-	-	-
Properties
Viscosity of base oil (40°C, mm²/s)	72	72	72	97
Worked penetration (JIS K2220)	272	270	280	282
High temperature and high speed test, h	250	600	600	800
Quick acceleration and deceleration test, h	130	250	220	180
Rust preventative properties, number	0	18	22	1
*1) "Shinfluid 601" from Nippon Steel Chemical Co., Ltd.
*2) "LB100" from Matsumura Sekiyu:KK
*3) diphenylmethandiisocyanate
*4) sorbitantrioleate

As apparent from the results shown in Tables 1 and 2, the grease compositions according to the present invention provide excellent results in all of the high temperature and high speed test, the quick acceleration and deceleration test and the rust preventative test.
In the grease composition according to the present invention, the base oil has a kinetic viscosity of 20 to 150 mm²/s at 40°C, and the additive contains as an essential component 0.05 to 10 parts by weight of a metal salt of a dibasic acid based on 100 parts by weight of the base oil and the thickener. The grease composition of the present invention does not adversely affect human bodies and the environment, and provides satisfactory results in all of the high temperature and high speed test, the quick acceleration and deceleration test and the rust preventative test.
Since the base oil contains alkyldiphenylether oil, and the thickener is the urea-based thickener, i.e., the aromatic diurea compound represented by the following formula (2) in the grease composition of the present invention, excellent results are obtained in all of the high temperature and high speed test, the quick acceleration and deceleration test and the rust preventative test.
Since the additive contains as an essential component 0.05 to 10 parts by weight of a metal salt of a dibasic acid based on 100 parts by weight of the base oil and the thickener in the grease composition of the present invention, excellent results are obtained in all of the high temperature and high speed test, the quick acceleration and deceleration test and the rust preventative test.
Since the ball-and-roller bearing according to the present invention is sealed with the above-mentioned grease composition of the present invention, excellent results are obtained in all of the high temperature and high speed test, the quick acceleration and deceleration test and the rust preventive test.

Claims

A grease composition comprising:
a base oil,

a thickener, and

an additive,
wherein the base oil has a kinetic viscosity of 20 to 150mm²/s at 40°C and contains synthesized hydrocarbon oil and 20% by weight or more of alkyldiphenyl ether oil; the thickener is an aromatic diurea compound represented by the following formula (2)
wherein R₂ and R₄ are the same or different, and represent each an aromatic hydrocarbon group having 6 to 15 carbon atoms, and R₃ represents an aromatic hydrocarbon group having 6 to 15 carbon atoms, and is contained in an amount of 5 to 30% by weight based on the total amount of the base oil and the thickener,
characterised in that the additive contains as an essential component 0.05 to 10 parts by weight of a metal salt of a dibasic acid based on 100 parts by weight of the base oil and the thickener, the metal salt of the dibasic acid being selected from one of a metal salt of azelaic acid, sebacic acid and adipic acid, and being represented by the following formula:
where M₁ and M₂ represent the same or different alkali metal selected from lithium, sodium and potassium, and R₁ represents aliphatic hydrocarbon group, and in that the grease composition contains no sodium nitrite.
The grease composition as claimed in Claim 1, wherein each of the R₂ and R₄ is -C₆H₄(CH₃), and the R₃ is -C₆H₄CH₂C₆H₄-.
The grease composition as claimed in Claim 1, wherein the metal salt of the dibasic acid is sodium sebacate.
The grease composition as claimed in Claim 1, wherein the additive comprises 0.05 to 5 parts by weight of an antioxidant in addition to the metal salt of the dibasic acid based on 100 parts by weight of the base oil and the thickener.
The grease composition as claimed in Claim 4, wherein the antioxidant is selected from the group consisting of a sulphur-containing antioxidant , a phenol-based antioxidant and an amine-based antioxidant.
Use of the grease composition as claimed in Claim 1 in a ball-and-roller bearing (1), in which a sliding part (2a, 3a) of the bearing is sealed with the grease composition.