EP1373803B1 - Method for feeding a closed liquid system - Google Patents
Method for feeding a closed liquid system Download PDFInfo
- Publication number
- EP1373803B1 EP1373803B1 EP02714637A EP02714637A EP1373803B1 EP 1373803 B1 EP1373803 B1 EP 1373803B1 EP 02714637 A EP02714637 A EP 02714637A EP 02714637 A EP02714637 A EP 02714637A EP 1373803 B1 EP1373803 B1 EP 1373803B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- liquid
- plunger
- closed
- inlet
- feed buffer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D3/00—Hot-water central heating systems
- F24D3/10—Feed-line arrangements, e.g. providing for heat-accumulator tanks, expansion tanks ; Hydraulic components of a central heating system
- F24D3/1083—Filling valves or arrangements for filling
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D3/00—Hot-water central heating systems
- F24D3/10—Feed-line arrangements, e.g. providing for heat-accumulator tanks, expansion tanks ; Hydraulic components of a central heating system
Definitions
- the present invention relates to a method for automatically feeding a closed liquid system, such as, for instance, a central heating system or another heat exchange or process system designed as a closed liquid circuit, from a liquid source according to need, in which system a feed buffer formed from liquid is created and between the liquid source and the feed buffer only liquid flow in the direction of the feed buffer is allowed.
- a closed liquid system such as, for instance, a central heating system or another heat exchange or process system designed as a closed liquid circuit
- the invention also relates to a drip feeder that can be used to realize such a method and a heating system in which the method and the drip feeder are used.
- a method as described above is known from WO-A-00/19149.
- a liquid stock is maintained, which is made up according to need via a float-controlled valve from a liquid source, more in particular a public water supply system.
- a liquid source more in particular a public water supply system.
- it has to be ensured during feeding, whatever the circumstances, that from the closed liquid system no liquid can find its way into the source from which feeding takes place, for instance as a result of a pressure increase in the liquid system or a pressure reduction or pressure failure in the liquid source.
- a calamity occurs, for instance pipe fracture in the liquid system, the supply from the liquid source is cut off at least to a substantial degree, so that the calamity is not made even worse.
- the escaping amount of liquid may be so small that the liquid fully evaporates nearly immediately, in which case sweat leakage losses are involved that are hardly, if at all, traceable.
- these non-traceable sweat leakage losses were about 0.8 cc/24 h, which corresponds to about 300 cc in one heating season.
- the water leaking away with or without notice can be collected to a specific degree by the expansion tank, which can be regarded as a make-up source, but then as an only restricted or limited make-up source. If this source is exhausted, then on further leakage the pressure in the closed liquid circulation circuit will be able to fall rapidly, which, in case of falling below a specific pressure, for instance when the pressure in a heating installation falls to atmospheric pressure, leads to automatic out-of-operation of the installation. For a central heating installation, this may have disastrous consequences, for instance during a frosty night. This can be prevented by means of a make-up method as known from WO-A-00/19149.
- the object of the invention is to provide a method with which a closed liquid system is automatically fed from a liquid source according to need, without involving the risk that liquid can find its way from the liquid system into the liquid source, and in which it is also ensured that in case of a calamity in the liquid system liquid cannot be passed without restraint from the liquid source to the liquid system.
- a further object of the invention is to provide a method with which a predetermined limited amount of liquid can be instantaneously fed to the liquid system.
- An object of the invention also is to provide a drip feeder with which a method as referred to above can be carried out advantageously, which drip feeder can therefore automatically make up minor amounts of liquid escaping from the closed circulation circuit according to need from an essentially unlimited source, such as a public water supply system, and that without involving a risk of repulsion or unchecked expulsion.
- a further object of the invention is to provide a closed liquid circulation system, which, by utilizing such a drip feeder, can be held under pressure automatically, while, furthermore, it can be ensured that when a leakage occurs a specific and limited amount of liquid can be momentarily expelled to facilitate the detection of the location of leakage, after the expulsion of which limited amount of liquid the automatic feed does not lead to a continuous extra water expulsion.
- liquid can be allowed to flow in from the liquid source continuously and without supervision, in case of pressure reduction or pressure failure in the liquid circuit, for instance as a result of a pipe fracture, further liquid can leak away from the liquid source only dropwise, until the time is found to completely close down the supply in another manner, for instance through a valve.
- the feed buffer can then be in open communication with the liquid system, therefore actually form part thereof.
- the feed buffer can be subject to pressure fluctuations, and according to a further embodiment of the invention it is preferred that the feed buffer has a minimum volume, which is increased when the pressure in the feed buffer exceeds the pressure in the liquid source.
- an expansion possibility is arranged for the feed buffer, and it may further be arranged that increase in the volume of the feed buffer is limited by a blow-off excess pressure protection.
- a feed buffer that is accommodated in a drip feeder provided with a cylindrical housing with an inlet, an outlet and a substantially cylindrical plunger arranged in the housing so as to be freely movable, which plunger, provided with at least a first part fitting into the cylindrical housing with sliding fit and a second part having a smaller diameter than the first part, can close the outlet in an abutting position while leaving clear a minuscule leakage channel and is provided with a passage that can connect the inlet with a space in the housing around the second part and is provided with a non-return valve preventing flow from the space to the inlet.
- a drip feeder in which, after connection to a liquid source under pressure, such as a public water supply system, the plunger is driven into the abutting position by the liquid pressure, with the minuscule leakage channel being of such design that it passes liquid dropwise in a limited amount only.
- a liquid source under pressure such as a public water supply system
- the plunger is driven into the abutting position by the liquid pressure, with the minuscule leakage channel being of such design that it passes liquid dropwise in a limited amount only.
- the non-return valve prevents liquid from passing this valve and thus finding its way into the make-up source via the inlet, even if the pressure difference between the outlet and the inlet increases so much that the plunger is pressed in the direction of the inlet and the minuscule leakage channel turns into a wider open connection.
- the realization and proper dimensioning of the minuscule leakage channel and the maintenance thereof in dimensioned condition depends, inter alia, on the manner in which the second part of the plunger cooperates with the outlet.
- the second part of the plunger is extended by a centrically placed pin-shaped projection, which, with sliding fit, engages a bore forming part of the outlet and is provided near the connection to the second part with a circumferential groove, to which at least a longitudinal groove extending in the longitudinal direction of the pin-shaped projection connects.
- the minuscule leakage channel can be realized in many ways.
- An example thereof may be extremely fine grooves in one or both cooperating end faces of the second part of the plunger and an end wall of the housing.
- the pin-shaped projection connects to the second part of the plunger with a foot part and terminates in a free end, with a sealing ring being arranged around the foot part and the free end in the abutting position of the second part contacting a cam face of an adjusting element, which is movable relative to the pin-shaped projection and, when moved, can shift the plunger via the pin-shaped projection in the longitudinal direction.
- the plunger is urged into the abutting position through the liquid pressure from the make-up source.
- a supplementary force towards the abutting position has to be exerted on the plunger.
- the plunger is pressed into the abutting position by a spring, which is supported on the plunger, on the one hand, and on a stop part stationarily connected with the housing, on the other hand, in which connection it may further be preferred that the stop part is adjustable relative to the housing.
- a very effective non-return valve can be realized if it is formed by an annular groove in the outer surface of the second part of the plunger, which groove is provided with side edges and a bottom, into which at least a passage communicating with the inlet opens, and is sealed at a distance from the bottom by an O-ring abutting on the side edges.
- the opening pressure of the non-return valve can be optimally adjusted, for instance such that the non-return valve already opens at a pressure in the inlet that is only a little higher than the pressure in the space around the second part, while it still remains ensured that the non-return valve is optimally blocked if the pressure in the space exceeds the pressure in the inlet.
- the non-return valve can be adjusted to a higher opening pressure, for instance if it is desired that the maximum feed pressure of the liquid added to the liquid circulation system is lower than the pressure in the inlet.
- the non-return valve present is a very effective means. If in the liquid circulation system, through unexpected causes, for instance failure of an excess pressure protection valve, such a high pressure should be built up in the liquid circulation system that the plunger is pressed in the direction of the inlet for a specific distance, as a result of which, for instance, the pin-shaped projection could leave its guide, then a relief of the system can be advantageously realized with the drip feeder according to the invention if according to a further embodiment the housing is provided with an outlet, which is sealingly closed by the first part of the plunger if the second part of the plunger is in the abutting position, and which is released after a predetermined movement of the plunger in the direction of the inlet.
- the invention also relates to a heating installation provided with a closed liquid circulation circuit, in which at least a boiler and an expansion tank are accommodated, and which closed liquid circulation circuit is connected via a drip feeder according to the invention to a liquid source under pressure.
- a heating installation provided with a closed liquid circulation circuit, in which at least a boiler and an expansion tank are accommodated, and which closed liquid circulation circuit is connected via a drip feeder according to the invention to a liquid source under pressure.
- the outlet of the drip feeder is in open communication both with a make-up line for the closed liquid circulation circuit and with an inlet for a storage container for make-up water, with the make-up line connecting to the inlet of a make-up element, which is in open communication with the liquid circulation circuit, which inlet is provided with a valve, which is normally in a closed position, but opens in case of lack of water in the liquid circulation circuit.
- the drip feeder shown in Fig. 1 comprises a cylindrical housing 1 with an inlet 2 and an outlet 3. Slidably arranged inside the housing 1 is a plunger 4, which plunger 4 comprises a first part 4a, a second part 4b and a pin-shaped projection 4c.
- the first part 4a is internally provided with a chamber 5 for accommodating and, with interposition of a filter plate 20, supporting an end of a spring 6, which is further supported on an annular stop part 7 movably arranged in the housing 1.
- the outer circumferential surface of the first part 4a moves with sliding fit along the inner wall of the cylindrical housing 1, while sealing rings 8 sealingly separate the spaces in the housing 1 to the left and right of the first part.
- the second part 4b of the plunger 4 has a smaller diameter than the first part 4a, so that a space 9 is formed around the second part 4b inside the housing 1.
- a groove 10 into the bottom of which passages 11 open, which issue from the chamber 5 in the first part 4a.
- the groove 10 is shut off by an O-ring 12.
- the opening pressure of the non-return valve is adjustable, because one of the walls of the groove 10 is formed by an end edge of a nut part mounted by screwing on the remaining part of the second part 4b so as to be displaceable, which second part 4b is sealed by a sealing ring 19 relative to the nut part.
- the second part 4b carries the pin-shaped projection 4c, which extends with sliding fit into a bore forming part of the outlet 3.
- the pin-shaped projection 4c is provided with a circumferential groove 13, into which a longitudinal groove 14 opens.
- a sealing ring 15 is provided around the pin-shaped projection 4c and in contact with, on the one hand, the second part 4b and, on the other hand, the housing wall.
- the pin-shaped projection 4c is provided with a free end in the form of a conical surface with a rather large, obtuse apex.
- the conical surface is in contact with a cam face 16a of an adjusting element 16, which extends transversely to the pin-shaped projection 4c and is adjustably arranged in the housing 1 in the longitudinal direction and is sealed relative to the surroundings by a sealing ring 21.
- the housing 1 is further provided with an internal ring groove 17, which communicates with a drain 18 leading to the surroundings.
- the operation of the drip feeder is as follows.
- the inlet 2 is connected by means not shown to a liquid source under pressure, for instance a public water supply system. Through this pressure in cooperation with the force exerted by the spring 6 the plunger is pressed to the right into the position shown in Fig. 1. If the liquid pressure in the chamber 5 is higher than the liquid pressure in the space 9, this will have the result that the O-ring 12 moves outwards and liquid flows from the chamber 5 to the space 9. To feed a liquid circulation system connected to the outlet 3 in a manner not shown, liquid will have to be able to flow from the space 9 to the outlet 3 and will therefore have to pass the sealing ring 15.
- a liquid circulation system connected to the outlet 3 in a manner not shown, liquid will have to be able to flow from the space 9 to the outlet 3 and will therefore have to pass the sealing ring 15.
- the non-return valve prevents liquid from entering the chamber 5 from the space 9. If the pressure difference between the outlet 3 and the inlet 2 increases so much that the plunger 4 in its totality is urged to the left, that is to say in the direction of the inlet 2, then after a specific movement of the plunger 4 the space 9 will enter into communication with the ring groove 17 and the pressure will be blown off outwards via the outlet 18.
- Fig. 3 shows a heating system comprising a closed liquid circulation circuit 20 with radiators 21 and a boiler 22.
- a membraneless expansion tank 24 connected to the liquid circulation circuit 20 via an air collector 23 is equipped with an element 25 provided with a make-up valve 26 and a deaerating valve 27.
- the valves 26 and 27 are normally in closed condition and can be opened by a float in the expansion tank 24, while through a fall of the liquid level in the expansion tank 24 as a result of the escape of liquid from the closed liquid circulation system 20 the co-falling float will open the deaerating valve 27 after reaching a first level and the make-up valve 26 in case of a further fall to a second level.
- a make-up line 28 connects, which is in open communication with, on the one hand, a drip feeder 29 connected to a line 30 of a public water supply system and, on the other hand, a storage container 31.
- the float in the expansion tank 24 will at a given moment fall so far that the make-up valve 26 is opened and water is supplied from the storage container 31, after which the make-up valve closes again and the water withdrawn from the storage container 31 is made up again by the drip feeder 29.
- the advantage of using the storage container 31 in combination with the drip feeder 29 is that in spite of the dropwise supply of the liquid a specific stock of make-up liquid under high pressure is always immediately available. This amount of liquid is immediately available if a calamity occurs, for instance in case of accidental lack of water.
- the limited expulsion from the storage container 31 prevents further damage and, through the liquid pulse, immediately shows the location where a repair has to be carried out.
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Infusion, Injection, And Reservoir Apparatuses (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Air Transport Of Granular Materials (AREA)
- Details Of Reciprocating Pumps (AREA)
- Pipeline Systems (AREA)
- Steam Or Hot-Water Central Heating Systems (AREA)
- Basic Packing Technique (AREA)
- Jet Pumps And Other Pumps (AREA)
Abstract
Description
Claims (14)
- A method for automatically feeding a closed liquid system (20) from a liquid source according to need, in which system a feed buffer (9) formed from liquid is created between the liquid source and the closed system (20) and between the liquid source and the feed buffer (9) only liquid flow in the direction of the feed buffer (9) is allowed, characterized in that from the feed buffer (9) to the closed liquid system (20) only dropwise liquid transport is admitted.
- A method according to claim 1, characterized in that that the feed buffer (9) has a minimum volume, which is increased when the pressure in the feed buffer exceeds the pressure in the liquid source.
- A method according to claim 2, characterized in that increase in the volume of the feed buffer (9) is limited by a blow-off excess pressure protection.
- A method according to any one of the preceding claims, characterized in that between the feed buffer (9) and the closed liquid system (20) a liquid stock (31) is created, which is fed via an open connection through the dropwise transport from the feed buffer (9), and which is connected with the liquid system via a closable passage (28), while the opening and closing of the passage is controlled depending on magnitudes generated by the closed liquid system.
- A drip feeder, provided with a cylindrical housing (1) with an inlet (2), an outlet (3) and a substantially cylindrical plunger (4) arranged in the housing (1) so as to be freely movable, which plunger (4), provided with at least a first part (4a) fitting into the cylindrical housing (1) with sliding fit and a second part (4b) having a smaller diameter than the first part (4a), can close the outlet (3) in an abutting position while leaving clear a minuscule leakage channel and is provided with a passage (11) that can connect the inlet (2) with a space (9) in the housing around the second part (4b) and is provided with a non-return valve preventing flow from the space to the inlet.
- A drip feeder according to claim 5, characterized in that the second part (4b) of the plunger is extended by a centrically placed pin-shaped projection (4c), which, with sliding fit, engages a bore forming part of the outlet (3) and is provided near the connection to the second part (4b) with a circumferential groove (13), to which at least a longitudinal groove (14) extending in the longitudinal direction of the pin-shaped projection (4c) connects.
- A drip feeder according to claim 6, characterized in that the pin-shaped projection (4c) connects to the second part (4b) of the plunger (4) with a foot part and terminates in a free end, with a sealing ring (15) being arranged around the foot part and the free end in the abutting position of the second part (4b) contacting a cam face (16a) of an adjusting element (16), which is movable relative to the pin-shaped projection (4c) and, when moved, can shift the plunger (4) via the pin-shaped projection in the longitudinal direction.
- A drip feeder according to any one of the preceding claims 5-7, characterized in that the plunger (4) is pressed into the abutting position by a spring (6), which is supported on the plunger (4), on the one hand, and on a stop part (7) stationarily connected with the housing (1), on the other hand.
- A drip feeder according to claim 8, characterized in that the stop part (7) is adjustable relative to the housing (1).
- A drip feeder according to any one of the preceding claims 5-9, characterized in that the non-return valve is formed by an annular groove (10) in the outer surface of the second part (4b) of the plunger (4), which groove (10) is provided with side edges and a bottom, into which at least a passage communicating with the inlet (2) opens, and is sealed at a distance from the bottom by an O-ring (12) abutting on the side edges.
- A drip feeder according to claim 10, characterized in that the side edges of the groove (10) are adjustable relative to each other.
- A drip feeder according to any one of the preceding claims 5-11, characterized in that the housing (1) is provided with an outlet (3), which is sealingly closed by the first part (4a) of the plunger (4) if the second part (4b) of the plunger (4) is in the abutting position, and which is released after a predetermined movement of the plunger (4) in the direction of the inlet.
- A heating installation, provided with a closed liquid circulation circuit (20), in which at least a boiler (22) and an expansion tank (24) are accommodated, and which closed liquid circulation circuit (20) is connected via a drip feeder (29) according to any one of the preceding claims to a liquid source under pressure.
- A heating installation according to claim 13, characterized in that the outlet of the drip feeder (29) is in open communication both with a make-up line (28) for the closed liquid circulation circuit (20) and with an inlet for a storage container (31) for make-up water, with the make-up line (28) connecting to the inlet of a make-up element, which is in open communication with the liquid circulation circuit (20), which inlet is provided with a valve (26), which is normally in a closed position, but opens in case of lack of water in the liquid circulation circuit (20).
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL1017756 | 2001-04-02 | ||
NL1017756A NL1017756C2 (en) | 2001-04-02 | 2001-04-02 | Automatically feeding closed liquid system, e.g. central heating system by creating feed buffer formed from liquid between liquid source and closed liquid system, and from feed buffer to closed liquid system |
NL1019043 | 2001-09-26 | ||
NL1019043A NL1019043C2 (en) | 2001-04-02 | 2001-09-26 | Method for feeding a closed liquid system as well as a suitable drip feed and heating system equipped therewith. |
PCT/NL2002/000203 WO2002079696A1 (en) | 2001-04-02 | 2002-03-28 | Method for feeding a closed liquid system |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1373803A1 EP1373803A1 (en) | 2004-01-02 |
EP1373803B1 true EP1373803B1 (en) | 2005-12-14 |
Family
ID=26643318
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02714637A Expired - Lifetime EP1373803B1 (en) | 2001-04-02 | 2002-03-28 | Method for feeding a closed liquid system |
Country Status (17)
Country | Link |
---|---|
EP (1) | EP1373803B1 (en) |
JP (1) | JP2004523720A (en) |
KR (1) | KR20030094321A (en) |
CN (1) | CN1250914C (en) |
AT (1) | ATE313043T1 (en) |
CA (1) | CA2442696A1 (en) |
CZ (1) | CZ20032730A3 (en) |
DE (1) | DE60208005T2 (en) |
DK (1) | DK1373803T3 (en) |
ES (1) | ES2256452T3 (en) |
NL (1) | NL1019043C2 (en) |
NO (1) | NO20034395L (en) |
PL (1) | PL363863A1 (en) |
RU (1) | RU2275556C2 (en) |
SK (1) | SK12122003A3 (en) |
TW (1) | TW548385B (en) |
WO (1) | WO2002079696A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102476400B1 (en) | 2015-12-04 | 2022-12-12 | 에이치엘만도 주식회사 | Check valve |
CN107671302A (en) * | 2017-10-31 | 2018-02-09 | 广州番禺职业技术学院 | A kind of shotting shunting collector and method |
CN112145706B (en) * | 2020-08-24 | 2022-05-31 | 九江七所精密机电科技有限公司 | Combined large-flow self-sealing structure for filtering fluid |
CN114382930B (en) * | 2022-03-26 | 2022-07-01 | 艾肯(江苏)工业技术有限公司 | High-temperature-resistant steam distribution valve set capable of preventing expansion of sealing element |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2204669A (en) * | 1987-04-27 | 1988-11-16 | Myco Engineering Limited | Water connection device |
AU2967397A (en) * | 1996-05-25 | 1998-01-05 | Euro Innovations Limited | Improvements in and relating to a valve |
-
2001
- 2001-09-26 NL NL1019043A patent/NL1019043C2/en not_active IP Right Cessation
-
2002
- 2002-03-28 DE DE60208005T patent/DE60208005T2/en not_active Expired - Fee Related
- 2002-03-28 PL PL02363863A patent/PL363863A1/en unknown
- 2002-03-28 KR KR10-2003-7013009A patent/KR20030094321A/en not_active Application Discontinuation
- 2002-03-28 AT AT02714637T patent/ATE313043T1/en not_active IP Right Cessation
- 2002-03-28 JP JP2002578072A patent/JP2004523720A/en active Pending
- 2002-03-28 CN CNB028076672A patent/CN1250914C/en not_active Expired - Fee Related
- 2002-03-28 CZ CZ20032730A patent/CZ20032730A3/en unknown
- 2002-03-28 WO PCT/NL2002/000203 patent/WO2002079696A1/en active IP Right Grant
- 2002-03-28 DK DK02714637T patent/DK1373803T3/en active
- 2002-03-28 ES ES02714637T patent/ES2256452T3/en not_active Expired - Lifetime
- 2002-03-28 SK SK1212-2003A patent/SK12122003A3/en unknown
- 2002-03-28 EP EP02714637A patent/EP1373803B1/en not_active Expired - Lifetime
- 2002-03-28 CA CA002442696A patent/CA2442696A1/en not_active Abandoned
- 2002-03-28 RU RU2003132065/06A patent/RU2275556C2/en not_active IP Right Cessation
- 2002-03-29 TW TW091106348A patent/TW548385B/en not_active IP Right Cessation
-
2003
- 2003-10-01 NO NO20034395A patent/NO20034395L/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
DE60208005T2 (en) | 2006-08-17 |
CZ20032730A3 (en) | 2004-04-14 |
CA2442696A1 (en) | 2002-10-10 |
NL1019043C2 (en) | 2002-10-25 |
NO20034395D0 (en) | 2003-10-01 |
DK1373803T3 (en) | 2006-05-01 |
WO2002079696A1 (en) | 2002-10-10 |
EP1373803A1 (en) | 2004-01-02 |
RU2003132065A (en) | 2005-04-10 |
KR20030094321A (en) | 2003-12-11 |
ES2256452T3 (en) | 2006-07-16 |
PL363863A1 (en) | 2004-11-29 |
NL1019043A1 (en) | 2002-10-07 |
RU2275556C2 (en) | 2006-04-27 |
JP2004523720A (en) | 2004-08-05 |
NO20034395L (en) | 2003-12-02 |
CN1500191A (en) | 2004-05-26 |
CN1250914C (en) | 2006-04-12 |
ATE313043T1 (en) | 2005-12-15 |
DE60208005D1 (en) | 2006-01-19 |
TW548385B (en) | 2003-08-21 |
SK12122003A3 (en) | 2004-06-08 |
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