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EP1294343B1 - Agents pour la coloration des fibres keratiniques comprenant un systeme epaississant - Google Patents

Agents pour la coloration des fibres keratiniques comprenant un systeme epaississant Download PDF

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Publication number
EP1294343B1
EP1294343B1 EP01940575A EP01940575A EP1294343B1 EP 1294343 B1 EP1294343 B1 EP 1294343B1 EP 01940575 A EP01940575 A EP 01940575A EP 01940575 A EP01940575 A EP 01940575A EP 1294343 B1 EP1294343 B1 EP 1294343B1
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Prior art keywords
und
alkyl
bis
component
chosen
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EP01940575A
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German (de)
English (en)
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EP1294343A2 (fr
Inventor
Ullrich Bernecker
Horst Höffkes
Manuela Ehlert
Ulrike Schumacher
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers

Definitions

  • the present application relates to agents with a special thickening system and a method for thickening oxidative systems.
  • Human hair is used today in a variety of ways with hair cosmetic preparations treated. These include cleaning the hair with shampoos, care and regeneration with rinses and cures as well as bleaching, dyeing and deforming the hair with Colorants, tints, waving and styling preparations. This means to play Change or nuance of the color of the head hair plays a prominent role.
  • oxidation colorants For permanent, intense colorations with corresponding fastness properties so-called oxidation colorants used. Such colorants usually contain Oxidation dye precursors, so-called developer components and coupler components. The developer components form under the influence of oxidizing agents with each other or under coupling with one or more coupler components, the actual dyes. The oxidation stains are characterized by excellent, long lasting staining results out.
  • Blondier processor applied.
  • the basics of the bleaching processes are known to the person skilled in the art and in relevant monographs, e.g. by K. Schrader, Basics and Formulations of Cosmetics, 2nd edition, 1989, Dr. Alfred Hüthig Verlag, Heidelberg, or W. Umbach (ed.), Cosmetics, 2nd edition, 1995, Georg Thieme Verlag, Stuttgart, New York, summarized.
  • keratinic fibers are furs, wool, feathers and, in particular, furs understood human hair.
  • Both the ethylenically unsaturated monomers of the general formula (I) and the Monomer units of component (B) are preferably selected from the group formed from acrylic acid, methacrylic acid and / or itaconic acid and their Derivatives.
  • the group Y of the formula (I) is selected from C (OO) O and CH 2 O, that R 2 is selected from hydrogen and methyl or that the monomer of the formula (I) is a Itaconklarederivat acts. It is likewise preferred that the monomer of the formula (II) is acrylic acid, methacrylic acid or one of its C 1 - to C 4 -alkyl esters.
  • Suitable copolymers are, for example, acrylic or methacrylic acid / acrylic or Methacrylklad- 20 Methacrylate copolymers (INCI name: Acrylates / Steareth- 20 Methacrylate copolymer), as described by the company Rohm and Haas / USA under the designations Acrysol®-22, Acrysol® ICS or Aculyn®-22 and acrylic or Methacrylic acid / Polyethoxyalkylallylether copolymers (INCI name: steareth-10 allyl Ether / Acrylates Copolymer), as described by the company Allied Colloids / Great Britain under the Designation Salcare® SC 90 are sold and acrylic or Methacrylic acid / itaconic acid polyethoxyalkyl ester copolymers (INCI names: Acrylates / Steareth-20 Itaconate Copolymer and Acrylates / Ceteth-20 Itaconate Copolymer), such as from the company National Starch / USA under
  • Components (B) which are preferred according to the invention are thickeners which are formed from two or more monomers selected from acrylic acid, methacrylic acid and their C 1 -C 6 -alkyl esters, and are sold under the INCI name Acrylates Copolymer.
  • thickeners which are formed from two or more monomers selected from acrylic acid, methacrylic acid and their C 1 -C 6 -alkyl esters, and are sold under the INCI name Acrylates Copolymer.
  • Yodosol® National Starch & Chemical Company
  • Structure® O National Starch & Chemical Company
  • Salcare® SC81 Allied Colloids, Ltd.
  • Rohagit® S Roshm GmbH Chemical Factory
  • Luviflex® Soft BASF Corporation
  • Luvimer® BASF Corporation
  • Aculyn® 33 Polymer Roshm and Haas Company, Inc.
  • Similar products of technical purity are also marketed by BASF under the name Latekoll®.
  • the acrylic or methacrylic acid groups are in the polymers used (A) and (B) preferably by organic or inorganic bases, in particular by ammonia or primary or secondary amines, e.g. neutralized by aminomethylpropanol (AMP).
  • the Thickening agent system according to the invention is in an amount in the hair treatment agent from 0.01 to 10, preferably in an amount of 0.05 to 4 wt .-%.
  • the invention thickened funds Be immediately before application to the fibers by mixing a first, alkaline set, component and a second, sour set, received component.
  • the second acidified component contains at least one oxidizing agent.
  • Oxidizing agents are preferably persulfates, chlorites and especially hydrogen peroxide or its addition products of urea, melamine and sodium borate in question.
  • Aqueous hydrogen peroxide solutions are particularly suitable according to the invention proved.
  • the Homo- or copolymers (A), which is formed from a monomer mixture containing at least an ethylenically unsaturated monomer of the general formula (I), in the acidic set component is included.
  • a particularly good thickening performance can be achieved when the entire thickening system is contained in the acidic component is.
  • the oxidative color change of keratin fibers to an oxidative hair coloring is not limited to a first preferred embodiment of the present invention.
  • the developer components form under the influence of oxidants, optionally with the help of special enzymes or metal ions as catalyst, with one another or with one another Coupling with one or more coupler components from the actual dyes.
  • Developer components preferred according to the invention are p-phenylenediamine, p-toluenediamine, p-aminophenol, o-aminophenol, 1- (2'-hydroxyethyl) -2,5-diaminobenzene, N, N-bis (2-hydroxy-ethyl) -p-phenylenediamine, 2- (2,5-diaminophenoxy) ethanol, 4-amino-3-methylphenol, 2,4,5,6-tetraaminopyrimidine, 2-hydroxy-4,5,6-triaminopyrimidine, 4-hydroxy-2,5,6-triaminopyrimidine, 2,4-dihydroxy-5,6-diaminopyrimidine, 2-dimethylamino-4,5,6-triaminopyrimidine, 2-hydroxymethylamino-4-amino-phenol, bis (4-aminophenyl) amine, 4-amino-3-fluorophenol, 2-aminomethyl-4-aminophenol, 2-hydroxy
  • Particularly preferred according to the invention are the developer components p-phenylenediamine, p-toluenediamine, p-aminophenol, 1- (2'-hydroxyethyl) -2,5-diaminobenzene, N, N-bis (2-hydroxyethyl) -p-phenylenediamine, 4-amino-3-methylphenol, 4-amino-2 - ((diethylamino) -methyl) -phenol, 2-aminomethyl-4-aminophenol, 2,4,5,6-tetraaminopyrimidine, 2-hydroxy-4,5,6-triaminopyrimidine, 4-hydroxy-2,5,6-triaminopyrimidine and 4,5-diamino-1- (2'-hydroxyethyl) pyrazole.
  • coupler components according to the invention are 1-naphthol, 1,5-, 2,7- and 1,7-dihydroxynaphthalene, 3-aminophenol, 5-amino-2-methylphenol, 2-amino-3-hydroxypyridine, Resorcinol, 4-chlororesorcinol, 2-chloro-6-methyl-3-aminophenol, 2-methylresorcinol, 5-methylresorcinol, 2,5-dimethylresorcinol and 2,6-dihydroxy-3,4-dimethylpyridine.
  • oxidative colorants can be further substantive to further nuance Dyes contain.
  • dye precursors present in oxidative colorants can also be indoles and Indolines, and their physiologically acceptable salts, be.
  • Preferred examples are 5,6-dihydroxyindole, N-methyl-5,6-dihydroxyindole, N-ethyl-5,6-dihydroxyindole, N-propyl-5,6-dihydroxyindole, N-butyl-5,6-dihydroxyindole, 5,6-dihydroxyindole-2-carboxylic acid, 6-hydroxyindole, 6-aminoindole and 4-aminoindole.
  • 5,6-dihydroxyindoline N-methyl-5,6-dihydroxyindoline, N-ethyl-5,6-dihydroxyindoline, N-propyl-5,6-dihydroxyindoline, N-butyl-5,6-dihydroxyindoline, 5,6-dihydroxyindoline-2-carboxylic acid, 6-hydroxyindoline, 6-aminoindoline and 4-aminoindoline.
  • indoline and indole derivatives can be used both as free bases and in the form of their physiologically acceptable salts with inorganic or organic acids, eg. B. the Hydrochlorides, sulfates and hydrobromides are used.
  • amino acids are aminocarboxylic acids, in particular ⁇ -aminocarboxylic acids and ⁇ -aminocarboxylic acids.
  • ⁇ -aminocarboxylic acids are arginine, lysine, ornithine and histidine are particularly preferred.
  • a very special preferred amino acid is arginine, especially in free form, but also as hydrochloride used.
  • Direct dyes are usually nitrophenylenediamines, nitroaminophenols, Azo dyes, anthraquinones or indophenols.
  • Preferred substantive dyes are the under the international names or trade names HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow 6, Basic Yellow 57, HC Orange 1, Disperse Orange 3, HC Red 1, HC Red 3, HC Red 13, HC Red BN, Basic Red 76, HC Blue 2, HC Blue 12, Disperse Blue 3, Basic Blue 7, Basic Blue 26, Basic Blue 99, HC Violet 1, Disperse Violet 1, Disperse Violet 4, Basic Violet 2, Basic Violet 14, Acid Violet 43, Disperse Black 9, Acid Black 52, Basic Brown 16 and Basic Brown 17 known compounds and 1,4-bis ( ⁇ -hydroxyethyl) amino-2-nitrobenzene, 3-nitro-4- ( ⁇ -hydroxyethyl) aminophenol, 4-amino-2-nitrodiphenylamine-2'-carboxylic acid, 6-nitro-1; 2,3,4-tetrahydroquinoxaline, 2-hydroxy
  • the dyeing preparations can also be found in nature dyes such for example henna red, henna neutral, henna black, chamomile flower, sandalwood, black Tea, Buckthorn bark, Sage, Bluewood, Madder root, Catechu, Sedre and Alkana root contain.
  • the ready-to-use hair dye is usually alkaline, i. H. to pH in the Range of about 7 to 11, set.
  • the colorants contain Alkalizing agent, usually alkali or alkaline earth hydroxides, ammonia or organic Amines.
  • Alkalizing agents are monoethanolamine, monoisopropanolamine, 2-amino-2-methyl-propanol, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-ethyl-1,3-propanediol, 2-amino-2-methylbutanol and triethanolamine and alkali and alkaline earth metal hydroxides.
  • monoethanolamine, triethanolamine and 2-amino-2-methyl-propanol and 2-amino-2-methyl-1,3-propanediol are preferred within this group.
  • ⁇ -amino acids such as ⁇ -aminocaproic acid as alkalizing agent possible.
  • the oxidative Color change of keratin fibers around a bleaching is not limited to the following preferred embodiments:
  • the bleaching agents may additionally comprise solid addition compound of hydrogen peroxide inorganic or organic compounds, such as sodium borate, Sodium carbonate, sodium carbamide, polyvinylpyrrolidone, urea and melamine.
  • the blonding effect can be increased by so-called "boosters". These are usually solid peroxo compound containing no addition products of hydrogen peroxide to others Represent components.
  • the selection of this peroxo compound is subject in principle no restrictions; customary peroxo compounds known to the person skilled in the art are, for example Ammonium peroxidisulfate, potassium peroxodisulfate, sodium peroxodisulfate, ammonium persulfate, Potassium persulfate, sodium persulfate, potassium peroxide phosphate, percarbonates such as Magnesium percarbonate and peroxides such as barium peroxide. These peroxo compounds can can also be used in combination. Particularly preferred are the peroxydisulfates, in particular Ammonium peroxydisulfate.
  • the peroxo compounds are preferred in amounts in the bleaching compositions according to the invention from 5-30% by weight, especially in amounts of 8-20% by weight.
  • bleaching agents contain an alkalizing agent which serves to adjust the alkaline pH of the use mixture.
  • alkalizing agents known to the skilled person also for bleaching agents, such as ammonium, alkali metal and alkaline earth metal hydroxides, carbonates, bicarbonates, hydroxycarbonates, silicates, especially metasilicates, as well as alkali metal phosphates.
  • the bleaching agents according to the invention contain at least two different alkalizing agents. Mixtures of a metasilicate and a hydroxycarbonate may be preferred.
  • Bleaching agents contain alkalizing agents, preferably in amounts of 5-25% by weight, in particular 10-20% by weight.
  • the Blondierstoff immediately before Apply mixed with a hydrogen peroxide solution.
  • concentration of this Hydrogen peroxide solution is on the one hand by the legal requirements and on the other determines the desired effect; As a rule, 6- to 12-percent acidified Solutions used in water.
  • the proportions of Blondierstoff and hydrogen peroxide solution are usually in the range 1: 1 to 1: 2, with an excess of Hydrogen peroxide solution is chosen especially if none too pronounced Blondier Dam is desired.
  • the bleaching agents may also dye precursors and / or direct dyes contain. In this context, let me turn to the above statements directed.
  • the enzymes both to produce be used by oxidizing per-compounds as well as to enhance the effect a small amount of existing oxidizing agent.
  • the enzymes (enzyme class 1: Oxidoreductases) electrons from suitable substrates (reducing agent) to atmospheric oxygen transfer. Oxidases such as tyrosinase and laccase but also glucose oxidase are preferred, Uricase or pyruvate oxidase.
  • the procedure is called the effect small amounts (e.g., 1% and less, based on total agent) of hydrogen peroxide to amplify by peroxidases.
  • the variation of coloration can be promoted and enhanced by adding certain metal ions to the agent.
  • metal ions are, for example, Zn 2+ , Cu 2+ , Fe 2+ , Fe 3+ , Mn 2+ , Ru 3+ , Mn 4+ , Li + , Mg 2+ , Ca 2+ and Al 3+ .
  • Particularly suitable are Zn 2+ , Cu 2+ and Mn 2+ .
  • the metal ions can in principle be used in the form of any physiologically acceptable salt.
  • Preferred salts are the acetates, sulfates, halides, lactates and tartrates.
  • the application temperatures may be within the scope of the oxidative Color change in a range between 15 and 40 ° C, preferably at the temperature of Scalp, lying.
  • the exposure time of the application preparation on the fibers is preferably between 5 and 45, in particular 15 to 30, minutes. Following this Exposure time, the fibers are usually mixed with water and optionally one thoroughly washed out suitable shampoo.
  • the washing with a shampoo is eliminated if a strong surfactant-containing carrier, eg. B. a Dyeing shampoo, was used.
  • a strong surfactant-containing carrier eg. B. a Dyeing shampoo
  • the agents according to the invention contain at least one surfactant.
  • surfactants according to the invention surface-active Substances understood to be nonionic, anionic, cationic or zwitterionic amphoteric nature.
  • sugar building block Z it is possible to use any desired mono- or oligosaccharides.
  • sugars with 5 or 6 carbon atoms and the corresponding Used oligosaccharides are, for example, glucose, fructose, galactose, Arabinose, ribose, xylose, lyxose, allose, altrose, mannose, gulose, idose, talose and Sucrose.
  • Preferred sugar building blocks are glucose, fructose, galactose, arabinose and sucrose; Glucose is particularly preferred.
  • the alkyl polyglycosides which can be used according to the invention contain on average from 1.1 to 5 sugar units. Alkyl polyglycosides having x values of 1.1 to 2.0 are preferred. Most notably preferred are alkyl glycosides in which x is 1.1 to 1.8.
  • the alkoxylated homologs of said alkylpolyglycosides can also be used according to the invention be used. These homologs can average up to 10 ethylene oxide and / or Propylene oxide units per Alkylglykosidillon included.
  • Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and Ethercarbonklaren having 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule and sulfosuccinic acid mono- and dialkyl esters having 8 to 18 carbon atoms in the alkyl group and sulfosuccinic acid mono-alkyl polyoxyethyl esters having 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups.
  • Zwitterionic surfactants are those surface-active compounds which carry in the molecule at least one quaternary ammonium group and at least one -COO (-) or -SO 3 (-) group.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyl dimethylammonium glycinate, N-acylaminopropyl N, N-dimethylammonium glycinates, for example cocoacylaminopropyl-dimethylammonium glycinate, and 2-alkyl 3-carboxymethyl-3-hydroxyethyl-imidazolines having in each case 8 to 18 carbon atoms in the alkyl or acyl group and the Kokosacylaminoethylhydroxyethylcarboxymethylglycinat.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known by the INC
  • Ampholytic surfactants are understood as meaning those surface-active compounds which, apart from a C 8 -C 24 -alkyl or -acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO 3 H group and are capable of forming internal salts .
  • suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 24 C Atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C 12
  • quaternary Ammonium compounds are ammonium halides, especially chlorides and bromides, such as Alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, z.
  • the long alkyl chains of the above-mentioned surfactants preferably have 10 to 18 Carbon atoms on.
  • Esterquats are known substances which have at least one ester function as well also contain at least one quaternary ammonium group as a structural element.
  • preferred Esterquats are quaternized ester salts of fatty acids with triethanolamine, quaternized Ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of Fatty acids with 1,2-dihydroxypropyldialkylamines.
  • Such products are, for example, under the trademarks Stepantex®, Dehyquart® and Armocare®.
  • alkylamidoamines are usually made by amidation of natural or synthetic Fatty acids and fatty acid sections prepared with dialkylaminoamines.
  • An invention particularly suitable compound from this group of substances that under the name Tegoamid® S 18 is commercially available stearamidopropyl-dimethylamine.
  • the cationic surfactants are preferred in the agents used in the invention Amounts of 0.05 to 10 wt.%, Based on the total agent included. Amounts of 0.1 to 5 wt .-% are particularly preferred.
  • the surfactants which do not contain ethylene oxide and / or Propylene oxide contained in the molecule be particularly preferred.
  • the compounds used as surfactant with alkyl groups may be in each case act uniform substances. However, it is usually preferred in the manufacture of this Substances of native vegetable or animal raw materials, so that one Substance mixtures with different alkyl chain lengths depending on the respective raw material receives.
  • the addition products of ethylene and / or propylene oxide with fatty alcohols or derivatives of these addition products both products with a "normal" Homologous distribution as well as those with a narrow homolog distribution be used.
  • "normal" homolog distribution are mixtures of Homologues understood in the implementation of fatty alcohol and alkylene oxide under Use of alkali metals, alkali metal hydroxides or alkali metal alcoholates as Catalysts receives. Narrowed homolog distributions are obtained when, for example Hydrotalcites, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates are used as catalysts. The usage of Products with narrow homolog distribution may be preferred.
  • oxidizer formulations were prepared: raw material Comparative Formulation A Comparative Formulation B Comparative recipe C
  • Example E Texapon® NSO 2.0 2.0 2.0 2.0 dipicolinic 0.1 0.1 0.1 0.1 Na-pyrophosphate 0.03 0.03 0.03 0.03 Turpinal® SL 1.5 1.5 1.5 1.5 Dow Corning® DB 110 A 0.07 0.07 0.07 0.07 Aculyn® 33 12.0 4.0 --- 4.0 Structure® 2001 --- 0.5 0.5 hydrogen peroxide 22.4 22.4 22.4 22.4 Ammonia, 25% 0.65 0.65 0.65 0.65 water ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 ad 100
  • Blondiercreme was created: C 16-18 fatty alcohol 10.0 C 12-18 fatty alcohol 2.0 Texapon® NSO 26.5 ammonium sulfate 1.0 Natronwasserglas 0.5 Ammonia, 25% 7.6 Gluadin® W40 0.35 Perfume qs water ad 100

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Claims (10)

  1. Agent pour la modification, par oxydation, de la couleur de fibres kératiniques, contenant un système épaississant constitué de
    au moins un homo- ou copolymère (A), qui est formé d'un mélange de monomères contenant au moins un monomère éthyléniquement insaturé de formule générale (I) CHR4=CR1R2 dans laquelle
    R1 est choisi parmi Y-(CH2CH2O)x-R3 et COOH,
    Y est choisi parmi C(=O)O, C(=O)NH et CH2O,
    x est un nombre allant de 1 à 100, de préférence de 10 à 50,
    R3 représente un radical alkyle en C1 à C30, de préférence un radical alkyle en C8 à C30,
    R2 est choisi parmi H, alkyle en C1 à C30 et CH2-R1,
    R4 est choisi parmi l'hydrogène ou un groupe alkyle en C1 à C4,
    sous réserve qu'au moins un des radicaux R1 et R2 représente le groupe Y-(CH2CH2O)x-R3, et
    au moins un homo- ou copolymère (B) qui est formé d'un mélange monomère d'acides éthyléniquement insaturés et/ou de leurs esters simples d'alkyle en C1 à C6,
    caractérisé en ce qu'il est obtenu immédiatement avant l'application sur les fibres par mélange d'un premier composant, rendu acide, et d'un second composant, rendu alcalin, et en ce que l'homo- ou copolymère (A) est contenu dans le composant rendu acide.
  2. Agent selon la revendication 1, caractérisé en ce que le composant rendu acide contient au moins un oxydant.
  3. Agent selon la revendication 2, caractérisé en ce que l'oxydant est le peroxyde d'hydrogène.
  4. Agent selon l'une des revendications 1 à 3 , caractérisé en ce que l'ensemble du système épaississant est contenu dans le composant rendu acide.
  5. Agent selon l'une des revendications 1 à 4, caractérisé en ce que la viscosité de la préparation d'application est de 1000 à 7000 mPas.
  6. Agent selon la revendication 5, caractérisé en ce que la viscosité de la préparation d'application s'élève à 3000 à 6000 mPas.
  7. Agent selon l'une des revendications 1 à 6, caractérisé en ce qu'il contient au moins un précurseur de colorant d'oxydation du type des composants de développement.
  8. Agent selon l'une des revendications 1 à 7, caractérisé en ce qu'il contient au moins un précurseur de colorant du type des indoles et/ou des indolines.
  9. Agent selon l'une des revendications 1 à 8, caractérisé en ce qu'il contient au moins un composé peroxo.
  10. Procédé pour épaissir les systèmes d'oxydation que l'on obtient immédiatement avant l'application sur les fibres par mélange d'un premier composant rendu acide et d'un second composant rendu alcalin, caractérisé en ce qu'on utilise un système épaississant constitué de au moins un homo- ou copolymère (A), qui est formé d'un mélange de monomères contenant au moins un monomère éthyléniquement insaturé de formule générale (I) CHR4=CR1R2 dans laquelle R1 est choisi parmi Y-(CH2CH2O)x-R3 et COOH,
    Y est choisi parmi C(=O)O, C(=O)NH et CH2O,
    x est un nombre allant de 1 à 100, de préférence de 10 à 50,
    R3 représente un radical alkyle en C1 à C30, de préférence un radical alkyle en C8 à C30,
    R2 est choisi parmi H, alkyle en C1 à C30 et CH2-R1,
    R4 est choisi parmi l'hydrogène ou un groupe alkyle en C1 à C4,
    sous réserve qu'au moins un des radicaux R1 et R2 représente le groupe Y-(CH2CH2O)x-R3, et
    au moins un homo- ou copolymère (B) qui est formé d'un mélange monomère d'acides éthyléniquement insaturés et/ou de leurs esters simples d'alkyle en C1 à C6,
    l'homo- ou copolymère (A) étant contenu dans le composant rendu acide.
EP01940575A 2000-06-26 2001-06-15 Agents pour la coloration des fibres keratiniques comprenant un systeme epaississant Revoked EP1294343B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10029981A DE10029981A1 (de) 2000-06-26 2000-06-26 Verdickungssystem
DE10029981 2000-06-26
PCT/EP2001/006811 WO2002000177A2 (fr) 2000-06-26 2001-06-15 Systeme epaississant

Publications (2)

Publication Number Publication Date
EP1294343A2 EP1294343A2 (fr) 2003-03-26
EP1294343B1 true EP1294343B1 (fr) 2005-08-24

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EP01940575A Revoked EP1294343B1 (fr) 2000-06-26 2001-06-15 Agents pour la coloration des fibres keratiniques comprenant un systeme epaississant

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EP (1) EP1294343B1 (fr)
AT (1) ATE302584T1 (fr)
AU (1) AU2001274104A1 (fr)
DE (2) DE10029981A1 (fr)
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US10625101B2 (en) 2011-09-12 2020-04-21 Noxell Corporation Method for colouring hair

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US6547833B2 (en) 2001-02-23 2003-04-15 Clairol Incorporated Two-part aqueous composition for oxidative coloration of hair
DE10142476A1 (de) * 2001-08-31 2003-03-20 Wella Ag Itaconsäuremonoester/Acrylat Copolymer enthaltendes, gelförmiges Haarbehandlungsmittel
FR2850019B1 (fr) * 2003-01-16 2006-07-07 Oreal Compositions de decoloration pretes a l'emploi, procede de preparation et procede de decoloration
DE102010003261A1 (de) * 2010-03-25 2011-09-29 Henkel Ag & Co. Kgaa Verdickende Oxidationszubereitungen II
DE102010003263A1 (de) * 2010-03-25 2011-09-29 Henkel Ag & Co. Kgaa Verdickende Oxidationszubereitungen

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EP0241707A3 (fr) * 1986-03-19 1989-02-08 Bristol-Myers Squibb Company Procédé et composition pour la teinture des cheveux
US5393305A (en) * 1993-08-26 1995-02-28 Bristol-Myers Squibb Company Two-part aqueous composition for coloring hair, which forms a gel on mixing of the two parts
DE19723538C1 (de) * 1997-06-05 1998-09-17 Wella Ag Pastenförmiges Mittel zum Bleichen von Haaren
ES2152731T3 (es) * 1997-07-31 2001-02-01 Wella Ag Producto para aumentar la conformabilidad y el brillo del cabello.
FR2773992B1 (fr) * 1998-01-23 2000-06-16 Eugene Perma Sa Composition pour la coloration de fibres keratiniques, depourvue d'ammoniaque
DE19815341C1 (de) * 1998-04-06 1999-08-26 Goldwell Gmbh Verfahren zur Herstellung von stabilen wäßrigen Haarfärbeemulsionen und wäßrige Haarfärbeemulsion
US20010002254A1 (en) * 1998-09-08 2001-05-31 Revlon Consumer Products Corporation Compositions and methods for coloring hair

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Publication number Priority date Publication date Assignee Title
US10625101B2 (en) 2011-09-12 2020-04-21 Noxell Corporation Method for colouring hair

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DE10029981A1 (de) 2002-01-03
ATE302584T1 (de) 2005-09-15
DE50107213D1 (de) 2005-09-29
WO2002000177A3 (fr) 2002-05-10
WO2002000177A2 (fr) 2002-01-03
AU2001274104A1 (en) 2002-01-08
EP1294343A2 (fr) 2003-03-26

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