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EP1274782A2 - Reduction de l'effet de frottement entre des preformes et des bouteilles en poly(ethylene terephtalate) - Google Patents

Reduction de l'effet de frottement entre des preformes et des bouteilles en poly(ethylene terephtalate)

Info

Publication number
EP1274782A2
EP1274782A2 EP01922709A EP01922709A EP1274782A2 EP 1274782 A2 EP1274782 A2 EP 1274782A2 EP 01922709 A EP01922709 A EP 01922709A EP 01922709 A EP01922709 A EP 01922709A EP 1274782 A2 EP1274782 A2 EP 1274782A2
Authority
EP
European Patent Office
Prior art keywords
primary
antioxidant
molded article
concentration
pet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01922709A
Other languages
German (de)
English (en)
Inventor
Graham H. Hall
Steven D. Jenkins
Michael A. Neal
Junaid A. Siddiqui
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority claimed from PCT/US2001/009704 external-priority patent/WO2001072886A2/fr
Publication of EP1274782A2 publication Critical patent/EP1274782A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/20—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds

Definitions

  • Fig. 1 is a graphical representation of the slip- producing effect of certain fatty acid amides in PET.
  • a range of Laser "1" PET formulations were injection moulded into parison tubes, or preforms.
  • the moulding was carried out at 260°C under identical injection moulding conditions.
  • the formulations comprised representative samples with different additives selected from oleyl palmitamide and stearyl erucamide at a concentration of 0.1% by wt and one control formulation (Laser + with no additive) .
  • the preform samples were moulded using a Negri Bossi NB90 molding machine.
  • an extra batch of Laser + control preforms were moulded using a Husky XL 160 molding machine for comparison. Each preform sample was allocated an identification number. The start and finish time/date of moulding was recorded allowing the time of moulding of each preform to be estimated.
  • a crossed cylinder apparatus gave a good reproducible contact geometry (similar to sphere on flat) .
  • the preforms had a relatively small diameter and were quite stiff, deforming only slightly with the normal load, giving a small contact spot and shear forces of a magnitude that were easily measurable.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)

Abstract

L'invention concerne un système d'additif pour des polyesters comprenant une quantité efficace (i) d'un amide d'acide gras choisi dans le groupe constitué d'oléyl palmitamide, d'éthylène bis stéaramide, d'éthylène bis oléomide et de stéaryl erucamide; (ii) d'un poly(méthylsilsequioxane) poreux partiellement ou complètement calciné; et (iii) d'un stabilisateur contenant un antioxydant primaire et secondaire.
EP01922709A 2000-03-27 2001-03-27 Reduction de l'effet de frottement entre des preformes et des bouteilles en poly(ethylene terephtalate) Withdrawn EP1274782A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US19227200P 2000-03-27 2000-03-27
US192272P 2000-03-27
PCT/US2001/009704 WO2001072886A2 (fr) 2000-03-27 2001-03-27 Reduction de l'effet de frottement entre des preformes et des bouteilles en poly(ethylene terephtalate)

Publications (1)

Publication Number Publication Date
EP1274782A2 true EP1274782A2 (fr) 2003-01-15

Family

ID=22708985

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01922709A Withdrawn EP1274782A2 (fr) 2000-03-27 2001-03-27 Reduction de l'effet de frottement entre des preformes et des bouteilles en poly(ethylene terephtalate)

Country Status (7)

Country Link
EP (1) EP1274782A2 (fr)
JP (1) JP2003528958A (fr)
KR (1) KR20020086935A (fr)
CA (1) CA2400163A1 (fr)
MX (1) MXPA02009452A (fr)
TW (1) TW593482B (fr)
ZA (1) ZA200206538B (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2025022461A (ja) * 2023-08-03 2025-02-14 日油株式会社 親水性付与剤、およびこれを含む樹脂組成物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0172886A2 *

Also Published As

Publication number Publication date
ZA200206538B (en) 2003-08-15
KR20020086935A (ko) 2002-11-20
TW593482B (en) 2004-06-21
JP2003528958A (ja) 2003-09-30
MXPA02009452A (es) 2004-05-17
CA2400163A1 (fr) 2001-10-04

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Legal Events

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Inventor name: SIDDIQUI, JUNAID A.

Inventor name: NEAL, MICHAEL A.

Inventor name: JENKINS, STEVEN D.

Inventor name: HALL, GRAHAM H.

RIN1 Information on inventor provided before grant (corrected)

Inventor name: SIDDIQUI, JUNAID A.

Inventor name: NEAL, MICHAEL A.

Inventor name: HALL, GRAHAM H.

Inventor name: JENKINS, STEVEN D.

RIN1 Information on inventor provided before grant (corrected)

Inventor name: SIDDIQUI, JUNAID A.

Inventor name: NEAL, MICHAEL A.

Inventor name: JENKINS, STEPHEN, D.

Inventor name: HALL, GRAHAM H.

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