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EP1215276B1 - Detergent composition comprising microdispersed particles containing silicate - Google Patents

Detergent composition comprising microdispersed particles containing silicate Download PDF

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Publication number
EP1215276B1
EP1215276B1 EP01128892A EP01128892A EP1215276B1 EP 1215276 B1 EP1215276 B1 EP 1215276B1 EP 01128892 A EP01128892 A EP 01128892A EP 01128892 A EP01128892 A EP 01128892A EP 1215276 B1 EP1215276 B1 EP 1215276B1
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EP
European Patent Office
Prior art keywords
detergent
cleaner
weight
laundry
laundry detergent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP01128892A
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German (de)
French (fr)
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EP1215276A1 (en
Inventor
Harald Dr. Bauer
Günther Dr. Schimmel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
clariant Produkte Deutschland GmbH
Original Assignee
Clariant GmbH
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0013—Liquid compositions with insoluble particles in suspension
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions

Definitions

  • washing and cleaning compositions containing microdisperse silicate-containing particles and a hydrophobizing agent containing microdisperse silicate-containing particles and a hydrophobizing agent
  • the invention relates to detergents and cleaners containing silicate-containing, microdispersed hydrophilic particles, and a hydrophobizing agent having high soil release capacity and less Resistant to soiling of the surfaces to be cleaned.
  • EP 368 559 describes the use of finely divided silica as Abrasion agents.
  • the aforementioned documents relate to the abrasive action of colloidal Silica and its thickening effect in one formulation.
  • silicate-containing particles act as surface coating agents used in the Adhering to the surfaces displace the dirt and at the same time through the Coating the surfaces makes their re-soiling difficult. In the repeated use of detergents and cleaners, the effect occurs amplified on.
  • Microdispers refers to the particle size of the silicate-containing particles. Particle, in solution or when applied to surfaces not sufficiently small or do not form particles at all, are not suitable for the invention.
  • the invention relates to a washing and cleaning agent, characterized characterized in that it comprises microdisperse, hydrophilic silicate-containing particles having a Particle size of 1 to 500 nm, preferably 9 to 50 nm, wherein the Particles around colloidal silica gels, colloidal silica, hectorites, saponites or Mixtures thereof and additionally at least one hydrophobicizing Agent, where the hydrophobizing agents are silicones, Silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and / or organic fluorine compounds is.
  • the particles are preferably electrically charged on their surface.
  • the washing and cleaning agent preferably contains 0.01 to 10% by weight. silicate-containing particles, 0.01 to 10 wt .-% hydrophobizing agents and 80 bis 99.8% by weight of other detergent / cleaner ingredients.
  • the washing and cleaning agent also contains 0.01 to 10 wt .-% silicate-containing particles, 0.01 to 10% by weight of hydrophobing agents, 0.5 to 60 Wt .-% surfactants and 20 to 99.48 wt .-% other Detergent ingredients.
  • the washing and cleaning agent also contains 0.01 to 10 wt .-% silicate-containing particles, 0.5 to 60% by weight of surfactants and 30 to 99.49 % By weight of other detergent / cleaning agent ingredients.
  • the washing and cleaning agent preferably also contains builders, cobuilders, Suppliers of alkali, anionic, nonionic, zwitterionic and nonionic Surfactants, antifoaming agents, dispersants, complexing agents, bleaching agents, Bleach activators and catalysts and / or enzymes.
  • the washing and cleaning agent is preferably a heavy-duty detergent, Compact heavy-duty detergent, Compact color detergent, heavy-duty detergent low bulk density, special detergents, such as laundry after-treatment, Fabric softeners, stain salts, bleach boosters, curtain washes, Wool detergents, building block detergents and industrial detergents.
  • the washing and cleaning agent is also about Hard surface cleaning agents, e.g. Facade, glass, metal, window, Floor and carpet cleaner.
  • Hard surface cleaning agents e.g. Facade, glass, metal, window, Floor and carpet cleaner.
  • the washing and cleaning agent is also um Hand dishwashing detergents, machine dishwashing detergents, machine dishwashing detergents and Rinse aid.
  • the invention also relates to the use of microdispersed, hydrophilic silicate-containing particles having a particle size of 1 to 500 nm, preferably 9 to 50 nm, wherein the particles are colloidal silica gels, colloidal silica sols, hectorites, saponites or mixtures thereof and additionally at least a hydrophobizing agent, wherein the hydrophobizing agents are silicones, silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and / or organic fluoro-compounds as surface-coating agents for soil release and reducing the tendency to re-soak in detergents and cleaners.
  • the particles are preferably electrically charged on their surface.
  • the silicate-containing particles on the Surface ionically charged.
  • the electrical charge is the dirt better detached and the re-soiling more difficult.
  • the silicate-containing particles negatively charged.
  • silicate-containing particles are colloidal Kleselsole that of the Clariant GmbH as ®Klebosol and from Bayer as ®Baykisol to be expelled. Also particularly suitable are the synthetic Clay mineral hectorite and saponite from Laporte (®Laponite types), Südchemie (®Optigel) and Clariant GmbH (®SKS-20 and ®SKS-21).
  • the silicate-containing particles become simultaneously used with hydrophobizing agents, which enhances soiling and reduces the re-pollution propensity.
  • Preferred hydrophobizing agents are silicones, silicone oils and / or Fluorosilicone oils, e.g. the antifoam emulsions ®SE36 and ®SE39, the Antifoam ®S850 and the antifoam powders ®ASP 8, ®ASP 15, ®ASP16, ® ASP 20 and ® ASP 30 from Wacker.
  • polyorganosiloxanes e.g. polydimethylsiloxanes
  • Polysiloxanes, alkyl-modified siloxanes and amino-functional siloxanes particularly preferred ®Fish CT 34 E (silicone softener emulsions of the company Wacker).
  • hydrophobizing agents are so-called soil release polymers, for example polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular oligomeric terephthalate esters, polymers of ethylene terephthalates and polyethylene glycol terephthalates or else anionic and / or nonionic derivatives thereof.
  • cationic surfactants consisting of mono- (C 8 -C 16 ) -N-alkyl or alkenyl quaternary ammonium salts whose N-positions are occupied by methyl, hydroxymethyl or hydroxypropyl groups. Particularly preferred are distearyldimethylammonium chloride, ditallowdimethylammonium chloride, diethanolamine diester quat, triethanolamine diester quat and alkylhydroxyethyldimethylammonium chloride.
  • hydrophobizing agents are fluoro compounds, e.g. the company 3M.
  • the detergents and cleaners preferably contain from 0.01 to 10% by weight, particularly preferably 0.1 to 5 wt .-% of silicate-containing particles.
  • concentrates containing up to 80 wt .-% of silicate-containing particles contain.
  • the weight ratio of Water to silicate-containing particles between 10000 to 1 and 1: 4.
  • Nonionic surfactants are alkyl alkoxylates, gluconamides and alkylpolyglycosides particularly preferred.
  • alkyl alkoxylates are preferably ethoxylated alcohols, preferably primary alcohols, preferably having 8 to 22 carbon atoms and preferably 1 to 80 EO units per mole of alcohol used, wherein the alcohol radical is linear or preferably methyl-branched in the 2-position or linear and methyl branched Contains radicals in the mixture, as is usually the case in Oxoalkoholresten.
  • the preferred ethoxylated alcohols include, for example, C 11 alcohols having 3, 5, 7, 8 and 11 EO units, (C 12 -C 15 ) alcohols having 3, 6, 7, 8, 10 and 13 EO units, respectively , (C 14 -C 15 ) -alcohols having 4, 7 or 8 EO units, (C 16 -C 18 ) -alcohols having 8, 11, 15, 20, 25, 50 or 80 EO units and mixtures the same.
  • the degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.
  • it is also possible to use fatty alcohol EO / PO adducts for example the ®Genapol types 3970, 2909 and 2822 from Clariant GmbH.
  • Suitable surfactants are polyhydroxy fatty acid amides of the formula R 2 -CO-N (R 3 ) -Z, in which R 2 CO is an aliphatic acyl radical having 6 to 22 carbon atoms, R 3 is hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and Z is a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
  • alkyl glycosides of the general formula RO (G) x in which R is a primary straight-chain or methyl-branched, in particular 2-methyl-branched, aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms, and G is a glycose unit having 5 or 6 carbon atoms, preferably glucose.
  • the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4.
  • Suitable anionic surfactants of the sulfonate type are preferably the known (C 9 -C 13 ) -alkylbenzenesulfonates, alpha-olefinsulfonates and alkanesulfonates. Also suitable are esters of sulfo fatty acids or the disalts of the alpha-sulfo fatty acids. Other suitable anionic surfactants are sulfated Fettklareglycerinester which mono-, di- and triesters and mixtures thereof, as in the preparation by esterification by 1 mole of monoglycerol with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 Mole of glycerol can be obtained.
  • alkyl sulfates are the sulfuric acid monoesters of (C 12 -C 18 ) -fatty alcohols, such as lauryl, myristyl, cetyl or stearyl alcohol, and the fatty alcohol mixtures obtained from coconut oil, palm and palm kernel oil, which additionally contain portions of unsaturated alcohols, For example, oleyl alcohol may contain.
  • anionic surfactants are particularly soaps into consideration. Suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, Palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, as well especially from natural fatty acids, e.g. Coconut, palm kernel or Tallow fatty acids, derived soap mixtures.
  • the anionic surfactants can be used in Form their sodium, potassium or ammonium salts, as well as soluble salts organic bases, such as mono-, di- or triethanolamine.
  • the anionic surfactants are in the form of their sodium or potassium salts, especially in the form of the sodium salts.
  • the buildem are preferably crystalline aluminosilicates, Alkali metal carbonates, alkali ortho, alkali pyro and alkali polyphosphates, crystalline Phyllosilicates, crystalline alkali metal silicates without layer structure and / or X-ray amorphous alkali silicates.
  • the co-builders are preferably monomeric, oligomeric, polymeric or copolymeric carboxylic acids.
  • the bleaching systems are preferably active chlorine carriers and / or organic or inorganic active oxygen carriers, bleach activators (e.g., TAED), Bleach catalysts, removal of discoloration, perborates and / or Percarbonates.
  • bleach activators e.g., TAED
  • Bleach catalysts removal of discoloration, perborates and / or Percarbonates.
  • the pH regulators are preferably soda, citric acid, Sodium citrate and / or bicarbonate.
  • detergents and cleaners may also contain enzymes, such as. Proteases, amylases, lipases and cellulases.
  • the detergents and cleaners can be used to treat fiber and fiber Textile surfaces, but also for the treatment of hard surfaces from the various materials, e.g. Metals, glass, ceramics, plastics etc., be used.
  • Further preferred cleaning agents are automotive and paint cleaners for the manual application and for automatic use in car washes.
  • compositions of the agents according to the invention are specified in percent by weight.
  • the Gardnertest is a cleaning test for hard surfaces, mainly floors etc ..
  • test strips maximal 45cm long and 5-6 cm wide
  • the cleaning solution add 10 g of the cleaning solution to the strip and attach a piece of wipe to a holder.
  • the cloth is driven by tensioning cables, driven by an eccentric, back and forth on the prepared sample strip.
  • the number of swipes is read on a counter.
  • the number of wiping movements is evaluated up to the absolute cleanliness, or after a maximum of 50 wiping movements the rating of the cleaning result on the scale of 1 (clean) to 5.
  • the rating 50/3 means here that after the maximum number of 50 wipes the matching gave the grade 3 on the scale of 1 to 5.
  • the rating 5/1 means here that after only 5 wipes the matching gave the grade 1 (clean) on the scale from 1 to 5.
  • Ceramic wall tiles and PVC floor tiles were used as surfaces. As stains were Edding permanent pen, marking pencil and pencil (Graphite) used.
  • the stains were:
  • the measurements were arithmetically averaged and averaged Scale spread from 0 to 100%.
  • Example 1 As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water Klebosol 30 V 25 added. This can be compared to the Gardner test Example 1, an improvement of the cleaning effect can be achieved.
  • Table 1 The Composition and results are shown in Table 1.
  • Example 1 As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water hectorite SKS-21 added. This can be compared to the Gardner test Example 1, an improvement of the cleaning effect can be achieved. The Composition and results are shown in Table 1.
  • Example 1 As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water Klebosol 30 V 25 and with the cumenesulfonate TexCare SRC-1 dispersion added. This can be in the Gardner test compared to Examples 1 to 3 an improvement of the cleaning effect can be achieved. The composition and the results are shown in Table 1.
  • a tile / bathroom cleaner was made by adding isopropanol and water mixed together. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 with vigorous stirring and finally citric acid monohydrate admixed. The detergency was tested using the Gardner test. The composition and the results are shown in Table 1.
  • Example 5 As in Example 5, a tile / bathroom cleaner was made. It was also with Klebosol 20 H 12 was added to the water. This can be seen in the Gardner test in the Compared to Example 5 an improvement of the cleaning effect can be achieved.
  • the composition and the results are shown in Table 1.
  • Example 5 As in Example 5, a tile / bathroom cleaner was made. It was also with Add to the water Klebosol 20 H 12 and with the Citric Acid Finish CT 34 E. This can be in the Gardner test compared to Examples 5 and 6 a Improvement of the cleaning effect can be achieved. The composition and the results are shown in Table 1.
  • a hand dishwashing detergent was prepared by using Hostapur SAS 60 Water and Klebosol 30 R 12 was mixed. Then Genagen CAB 818, Genapol UD 080 and Genapol ZRO liquid mixed with slow stirring. The Composition is listed in Table 2.
  • a window cleaner was made by using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide and Isopropanol mixed with stirring. The composition is in Table 2 listed.
  • a window cleaner was made by using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide, isopropanol and finish CT 34 E while stirring. The composition is in table 2 listed.
  • An all-purpose cleaner was made by using Genapol UD 080 with Hostapur SAS 60 was mixed. Then water, Klebosol 30 R 12 and propylene glycol n-butyl ether mixed with stirring. The composition is in Table 2 listed.
  • a flow / bath cleaner was made by adding isopropanol with water was mixed. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 and finally Klebosol 30H25 mixed with stirring. The Composition is listed in Table 2.
  • a cleaner for car washes was manufactured by Genapol UD 110 and Genapol UD 50 were successively dissolved in water. Then, Klebosol became 30 R 12 mixed. The composition is listed in Table 2.
  • a desiccant for car washes was made by successively butyldiglycol, acetic acid, conc., Genamin LAP 100 D and Praepagen 4317 were mixed. Then water and Klebosol 30 H 25 were added.
  • the Composition is listed in Table 2.
  • a machine dishwashing rinse was made by successively Citric acid, cumene sulfonate, Genapol 2908 and Klebosol 30 H 25 in water were solved. According to the general rule implementation of Machine dishwashing tests were dishes with a commercial Rinsed tablet-dishwashing detergent. The rinse aid was the above formulation used. This procedure of cleaning and rinsing was repeated repeated and the dishes are then scrapped. The composition and the Results are listed in Table 3.
  • Example 16 As in Example 16, a machine dishwashing rinse aid is prepared. additionally Klebosol 30 H 25 is mixed in. According to the general rule implementation The machine dishwashing tests were dishes twice with a rinsed with commercially available tablet-dishwashing detergent and with the rinse aid treated. The use of silica sol gives clear advantages for the Cleaning effect. The composition and the results are in Table 3 listed.
  • Example 19 The composition is listed in Table 4.
  • a liquid detergent is prepared by stirring vigorously Alkylbenzenesulfonate, citric acid, Genapol 3070, soap, water, silicone oil, Phosphonate, polyglycol ether and Klebosol 30 V 50 mixes.
  • the composition is listed in Table 4.
  • a powder detergent is prepared by adding in a Ploughshare mixer Fa. Lödige Antifoam, phyllosilicate, soda, Sokalan CP5 and Zeolite A and Genapol 3070 sprayed on. The remaining components are mixed in for a short time. The composition is listed in Table 4.
  • a fabric softener is prepared by stirring at 50 to 60 ° C First Lapnite RD and then Praepagen WK are dissolved in water.
  • the Composition is listed in Table 4.
  • a fabric softener is prepared by dissolving molten triethanolamine diesterquat (85%) in preheated water at 50 ° C, then stirring Genapol UD 088 and cooling the solution. Finally, TexCare SRC-1 dispersion and Klebosol 30 V 50 are stirred in.
  • Genagen CAB 818 10 Genamin LAP 100 D 2 Genapol LRO liquid 0.5 0.5 Genapol O 020 5 Genapol DU 080 3 9 0.5 Genapol DU 110 10 Genapol DU 50 3 Genapol X 080 2 Genapol ZRO liquid 22.9 Hoechst wax KST 4 Hordaphos CC MS 1 Hostapur SAS 60 42.7 8.3 3 isopropanol 29 29 3 Praepagen 4317 10 Praepagen WKT 11 Propylene glycol n-butyl ether 3 spindle oil 6 water 19.4 69 68 75.7 88.5 86 59.2 57 Klebosol 30 R 12 2 2 1 5 Klebosol 30 H 25 1 5 Klebosol 30 N 12 1 1 Finish CT 34 E 1 dosage 1: 1000 1: 1000 1: 500 example 16 17 Components [%] See citric acid 3 3 Cumene sulphonate, 40% 8th 8th Genapol 2908 14 14 water 75 74 Klebosol 30 H 25

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Description

Wasch- und Reinigungsmittel, enthaltend mikrodisperse silikathaltige Partikel und ein hydrophobierendes AgensWashing and cleaning compositions containing microdisperse silicate-containing particles and a hydrophobizing agent

Die Erfindung betrifft Wasch- und Reinigungsmittel, enthaltend silikathaltige, mikrodisperse hydrophile Partikel, und ein hydrophobierendes Agens mit hohem Schmutzablösevermögen und geringer Wiederanschmutzneigung der zu reinigenden Oberflächen.The invention relates to detergents and cleaners containing silicate-containing, microdispersed hydrophilic particles, and a hydrophobizing agent having high soil release capacity and less Resistant to soiling of the surfaces to be cleaned.

In WO 99/00457 ist eine Fassadenbeschichtung beschrieben, die die Verschmutzungsneigung von Fassaden verringert.In WO 99/00457 a facade coating is described which the Pollution tendency of facades reduced.

In EP 252 708 wird gefunden, dass der Zusatz von kolloider Kieselsäure zu Klarspülmitteln die Abtrocknungszeit verringert.In EP 252 708 it is found that the addition of colloidal silica to Rinse aids reduces the drying time.

EP 368 559 beschreibt den Einsatz von fein verteilter Kieselsäure als Abrasionsmittel.EP 368 559 describes the use of finely divided silica as Abrasion agents.

DE 2 809 371 beschreibt den Einsatz von Polydimethylsiloxan und kolloider Kieselsäure, die als Abrasiv wirkt.DE 2 809 371 describes the use of polydimethylsiloxane and colloids Silica, which acts as an abrasive.

Die vorgenannten Schriften beziehen sich auf die abrasive Wirkung von kolloidaler Kieselsäure und ihre verdickende Wirkung in einer Formulierung.The aforementioned documents relate to the abrasive action of colloidal Silica and its thickening effect in one formulation.

Überraschenderweise wurde nun gefunden, dass der Zusatz von mikrodispersen, hydrophilen silikathaltigen Partikeln zu Wasch- und Reinigungsmitteln die Schmutzablösung erleichtert, die Reinigungswirkung erhöht und die Wiederanschmutzung der so behandelten Oberflächen verringert.Surprisingly, it has now been found that the addition of microdispersed, hydrophilic silicate-containing particles to detergents and cleaners the Facilitates soil removal, increases the cleaning effect and the Reduced soiling of the thus treated surfaces.

Die silikathaltigen Partikeln wirken als Oberflächenbeschichtungsmittel, die bei der Anlagerung an die Oberflächen den Schmutz verdrängen und gleichzeitig durch die Beschichtung der Oberflächen deren Wiederanschmutzung erschweren. Bei der wiederholten Anwendung der Wasch- und Reinigungsmittel tritt der Effekt verstärkt auf.The silicate-containing particles act as surface coating agents used in the Adhering to the surfaces displace the dirt and at the same time through the Coating the surfaces makes their re-soiling difficult. In the repeated use of detergents and cleaners, the effect occurs amplified on.

Wesentlich für die silikathaltigen Partikel ist ihre Fähigkeit in wässriger Dispersion und/oder beim Aufbringen auf Oberflächen hinreichend kleine Teilchen zu bilden. Mikrodispers bezieht sich auf die Teilchengröße der silikathaltigen Partikel. Partikel, die in Lösung bzw. beim Aufbringen auf Oberflächen keine hinreichend kleinen oder gar keine Partikel bilden, eignen sich nicht für die Erfindung.Essential for the silicate-containing particles is their ability in aqueous dispersion and / or to form sufficiently small particles when applied to surfaces. Microdispers refers to the particle size of the silicate-containing particles. Particle, in solution or when applied to surfaces not sufficiently small or do not form particles at all, are not suitable for the invention.

Gegenstand der Erfindung ist ein Wasch- und Reinigungsmittel, dadurch gekennzeichnet, dass es mikrodisperse, hydrophile silikathaltige Partikel mit einer Teilchengröße von 1 bis 500 nm, bevorzugt 9 bis 50 nm, wobei es sich bei den Partikeln um kolloidale Kieselgele, kolloidale Kieselsoie, Hectorite, Saponite oder Mischungen derselben handelt sowie zusätzlich mindestens ein hydrophobierendes Agens enthält, wobei es sich bei den hydrophobierenden Agenzien um Silicone, Siliconöle, Fluorsiliconöle, Soil-release-Polymere, kationische Tenside und/oder organische Fluorverbindungen handelt.The invention relates to a washing and cleaning agent, characterized characterized in that it comprises microdisperse, hydrophilic silicate-containing particles having a Particle size of 1 to 500 nm, preferably 9 to 50 nm, wherein the Particles around colloidal silica gels, colloidal silica, hectorites, saponites or Mixtures thereof and additionally at least one hydrophobicizing Agent, where the hydrophobizing agents are silicones, Silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and / or organic fluorine compounds is.

Bevorzugt sind die Partikel an ihrer Oberfläche elektrisch geladen.The particles are preferably electrically charged on their surface.

Bevorzugt beträgt das Gewichts-Verhältnis von silicathaltigen Partikeln zu hydrophobierenden Agenzien 100 zu 1 bis 1 zu 100, bezogen auf Aktivsubstanz.Preferably, the weight ratio of silicate-containing particles to hydrophobizing agents 100 to 1 to 1 to 100, based on the active substance.

Bevorzugt enthält das Wasch- und Reinigungsmittel 0,01 bis 10 Gew.-% silicathaltige Partikel, 0,01 bis 10 Gew.-% hydrophobierende Agenzien und 80 bis 99,8 Gew.-% sonstige Waschmittel-/Reinigungsmittelinhaltsstoffe.The washing and cleaning agent preferably contains 0.01 to 10% by weight. silicate-containing particles, 0.01 to 10 wt .-% hydrophobizing agents and 80 bis 99.8% by weight of other detergent / cleaner ingredients.

Bevorzugt enthält das Wasch- und Reinigungsmittel auch 0,01 bis 10 Gew.-% silicathaltige Partikel, 0,01 bis 10 Gew.-% hydrophobierende Agenzien, 0,5 bis 60 Gew.-% grenzflächenaktive Stoffe und 20 bis 99,48 Gew.-% sonstige Waschmittelinhaltsstoffe.Preferably, the washing and cleaning agent also contains 0.01 to 10 wt .-% silicate-containing particles, 0.01 to 10% by weight of hydrophobing agents, 0.5 to 60 Wt .-% surfactants and 20 to 99.48 wt .-% other Detergent ingredients.

Bevorzugt enthält das Wasch- und Reinigungsmittel auch 0,01 bis 10 Gew.-% silicathaltige Partikel, 0,5 bis 60 Gew.-% grenzflächenaktive Stoffe und 30 bis 99,49 Gew.-% sonstige Waschmittel-/Reinigungsmittelinhaltsstoffe.Preferably, the washing and cleaning agent also contains 0.01 to 10 wt .-% silicate-containing particles, 0.5 to 60% by weight of surfactants and 30 to 99.49 % By weight of other detergent / cleaning agent ingredients.

Bevorzugt enthält das Wasch- und Reinigungsmittel weiterhin Builder, Cobuilder, Alkalilieferanten, anionische, nichtionische, zwitterionische und nichtionische Tenside, Antischaummittel, Dispergatoren, Komplexbildner, Bleichmittel, Bleichaktivatoren und -katalysatoren und/oder Enzyme.The washing and cleaning agent preferably also contains builders, cobuilders, Suppliers of alkali, anionic, nonionic, zwitterionic and nonionic Surfactants, antifoaming agents, dispersants, complexing agents, bleaching agents, Bleach activators and catalysts and / or enzymes.

Bevorzugt handelt es sich bei dem Wasch- und Reinigungsmittel um Vollwaschmittel, Compact-Vollwaschmittel, Compact-Colorwaschmittel, Vollwaschmittel geringer Schüttdichte, Spezialwaschmittel, wie Wäschenach-behandlungsmittel, Wäscheweichmacher, Fleckensalze, Bleichbooster, Gardinenwaschmittel, Wollwaschmittel, Baukasten-Waschmittel und gewerbliche Waschmittel.The washing and cleaning agent is preferably a heavy-duty detergent, Compact heavy-duty detergent, Compact color detergent, heavy-duty detergent low bulk density, special detergents, such as laundry after-treatment, Fabric softeners, stain salts, bleach boosters, curtain washes, Wool detergents, building block detergents and industrial detergents.

Bevorzugt handelt es sich bei dem Wasch- und Reinigungsmittel auch um Reinigungsmittel für harte Oberflächen, z.B. Fassaden-, Glas-, Metall, Fenster-, Fußboden- und Teppichbodenreiniger.Preferably, the washing and cleaning agent is also about Hard surface cleaning agents, e.g. Facade, glass, metal, window, Floor and carpet cleaner.

Bevorzugt handelt es sich bei dem Wasch- und Reinigungsmittel aber auch um Handgeschirrspülmittel, Maschinengeschirreiniger, Maschinengeschirrspülmittel und Klarspüler.Preferably, however, the washing and cleaning agent is also um Hand dishwashing detergents, machine dishwashing detergents, machine dishwashing detergents and Rinse aid.

Die Erfindung betrifft auch die Verwendung von mikrodispersen, hydrophilen silikathaltigen Partikeln mit einer Teilchengröße von 1 bis 500 nm, bevorzugt 9 bis 50 nm, wobei es sich bei den Partikeln um kolloidale Kieselgele, kolloidale Kieselsole, Hectorite, Saponite oder Mischungen derselben handelt sowie zusätzlich mindestens ein hydrophobierendes Agens, wobei es sich bei den hydrophobierenden Agenzien um Silicone, Siliconöle, Fluorsiliconöle, Soil-release-Polymere, kationische Tenside und/oder organische Fluorverbindungen handelt als Oberflächenbeschichtungsmittel zur Schmutzablösung und Verringerung der Wiederanschmutzneigung in Wasch- und Reinigungsmitteln.
Bevorzugt sind bei der vorgenannten Verwendung die Partikel an ihrer Oberfläche elektrisch geladen. The invention also relates to the use of microdispersed, hydrophilic silicate-containing particles having a particle size of 1 to 500 nm, preferably 9 to 50 nm, wherein the particles are colloidal silica gels, colloidal silica sols, hectorites, saponites or mixtures thereof and additionally at least a hydrophobizing agent, wherein the hydrophobizing agents are silicones, silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and / or organic fluoro-compounds as surface-coating agents for soil release and reducing the tendency to re-soak in detergents and cleaners.
In the above-mentioned use, the particles are preferably electrically charged on their surface.

In einer bevorzugten Ausführungsform sind die silikathaltigen Partikel an der Oberfläche ionisch geladen. Durch die elektrische Aufladung wird der Schmutz besser abgelöst und die Wiederanschmutzung erschwert. Bevorzugt sind die silikathaltigen Partikel negativ geladen.In a preferred embodiment, the silicate-containing particles on the Surface ionically charged. By the electrical charge is the dirt better detached and the re-soiling more difficult. Preferred are the silicate-containing particles negatively charged.

Besonders bevorzugt als silikathaltige Partikel sind kolloide Kleselsole, die von der Firma Clariant GmbH als ®Klebosol und von der Firma Bayer als ®Baykisol vertrieben werden. Weiterhin besonders geeignet sind auch die synthetischen Tonminerale Hectorit und Saponit der Firmen Laporte (®Laponite-Typen), Südchemie (®Optigel) und Clariant GmbH (®SKS-20 und ®SKS-21).Particularly preferred as silicate-containing particles are colloidal Kleselsole that of the Clariant GmbH as ®Klebosol and from Bayer as ®Baykisol to be expelled. Also particularly suitable are the synthetic Clay mineral hectorite and saponite from Laporte (®Laponite types), Südchemie (®Optigel) and Clariant GmbH (®SKS-20 and ®SKS-21).

Die silikathaltigen Partikel werden gleichzeitig mit hydrophobierenden Agenzien verwendet, was die Schmutzablösung verstärkt und die Wiederanschmutzneigung verringert.The silicate-containing particles become simultaneously used with hydrophobizing agents, which enhances soiling and reduces the re-pollution propensity.

Bevorzugte hydrophobierende Agenzien sind Silicone, Siliconöle und/oder Fluorsiliconöle, z.B. die Antischaumemulsionen ®SE36 und ®SE39, das Antischaummittel ®S850 und die Antischaumpulver ®ASP 8, ®ASP 15, ®ASP16, ®ASP 20 und ®ASP30 der Firma Wacker.Preferred hydrophobizing agents are silicones, silicone oils and / or Fluorosilicone oils, e.g. the antifoam emulsions ®SE36 and ®SE39, the Antifoam ®S850 and the antifoam powders ®ASP 8, ®ASP 15, ®ASP16, ® ASP 20 and ® ASP 30 from Wacker.

Weiterhin bevorzugt geeignet sind Polyorganosiloxane, wie z.B. Polydimethylsiloxane, Polysiloxane, alkylmodifizierte Siloxane und aminofunktionelle Siloxane, besonders bevorzugt ®Finish CT 34 E (Siliconweichmacher-Emulsionen der Firma Wacker).Also preferred are polyorganosiloxanes, e.g. polydimethylsiloxanes Polysiloxanes, alkyl-modified siloxanes and amino-functional siloxanes, particularly preferred ®Fish CT 34 E (silicone softener emulsions of the company Wacker).

Weiterhin geeignet als hydrophobierende Agenzien sind sogenannte Soil-release-Polymere, z.B. Polymere der Phthalsäure und/oder der Terephthalsäure bzw. deren Derivaten, insbesondere oligomere Terephthalatester, Polymere aus Ethylenterephthalaten und Polyethylenglykolterephthalaten oder auch anionische und/oder nichtionische Derivate derselben.
Als hydrophobierende Agenzien weiterhin geeignet sind kationische Tenside bestehend aus quaternären Mono-(C8-C16)-N-Alkyl oder -Alkenyl Ammoniumsalzen, deren N-Positionen mit Methyl-, Hydroxymethyl- oder Hydroxypropylgruppen besetzt sind. Besonders bevorzugt sind Distearyldimethylammoniumchlorid, Ditalgdimethylammoniumchlorid, Diethanolamindiesterquat, Triethanolamindiesterquat und Alkylhydroxyethyldimethylammoniumchlorid.Also suitable as hydrophobizing agents are so-called soil release polymers, for example polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular oligomeric terephthalate esters, polymers of ethylene terephthalates and polyethylene glycol terephthalates or else anionic and / or nonionic derivatives thereof.
Also suitable as hydrophobizing agents are cationic surfactants consisting of mono- (C 8 -C 16 ) -N-alkyl or alkenyl quaternary ammonium salts whose N-positions are occupied by methyl, hydroxymethyl or hydroxypropyl groups. Particularly preferred are distearyldimethylammonium chloride, ditallowdimethylammonium chloride, diethanolamine diester quat, triethanolamine diester quat and alkylhydroxyethyldimethylammonium chloride.

Als hydrophobierenden Agenzien ebenfalls geeignet sind Fluorverbindungen, z.B. die der Firma 3M.Also suitable as hydrophobizing agents are fluoro compounds, e.g. the company 3M.

Bevorzugt enthalten die Wasch- und Reinigungsmittel 0,01 bis 10 Gew.-%, besonders bevorzugt 0,1 bis 5 Gew.-%an silikathaltigen Partikeln.The detergents and cleaners preferably contain from 0.01 to 10% by weight, particularly preferably 0.1 to 5 wt .-% of silicate-containing particles.

Bevorzugt sind auch Konzentrate, die bis zu 80 Gew.-% an silikathaltigen Partikeln enthalten. In den Wasch- und Reinigungsmitteln beträgt das Gewichtsverhältnis von Wasser zu silikathaltigen Partikeln zwischen 10000 zu 1 und 1:4.Also preferred are concentrates containing up to 80 wt .-% of silicate-containing particles contain. In the detergents and cleaning agents, the weight ratio of Water to silicate-containing particles between 10000 to 1 and 1: 4.

Als nichtionische Tenside sind Alkylalkoxylate, Gluconamide und Alkylpolyglycoside besonders bevorzugt.Nonionic surfactants are alkyl alkoxylates, gluconamides and alkylpolyglycosides particularly preferred.

Unter den Alkylalkoxylaten werden bevorzugt ethoxylierte Alkohole, bevorzugt primäre Alkohole, mit bevorzugt 8 bis 22 C-Atomen und bevorzugt 1 bis 80 EO-Einheiten pro Mol Alkohol, eingesetzt, wobei der Alkoholrest linear oder bevorzugt in 2-Stellung methylverzweigt ist oder lineare und methylverzweigte Reste im Gemisch enthält, so wie dies üblicherweise in Oxoalkoholresten der Fall ist. Zu den bevorzugten ethoxylierten Alkoholen gehören beispielsweise C11-Alkohole mit 3, 5, 7, 8 und 11 EO-Einheiten, (C12-C15)-Alkohole mit 3, 6, 7, 8, 10 bzw. 13 EO-Einheiten, (C14-C15)-Alkohole mit 4, 7 bzw. 8 EO-Einheiten, (C16-C18)-Alkohole mit 8, 11, 15, 20, 25, 50 bzw. 80 EO-Einheiten und Mischungen derselben. Die angegebenen Ethoxylierungsgrade stellen statistische Mittelwerte dar, die für ein spezielles Produkt eine ganze oder eine gebrochene Zahl sein können. Zusätzlich zu diesen können auch Fettalkohol-EO/PO-Addukte eingesetzt werden, wie z.B. die ®Genapol-Typen 3970, 2909 und 2822 der Fa. Clariant GmbH.
Weitere geeignete Tenside sind Polyhydroxyfettsäureamide der Formel R2-CO-N(R3)-Z, in der R2CO für einen aliphatischen Acylrest mit 6 bis 22 Kohlenstoffatomen, R3 für Wasserstoff, einen Alkyl oder Hydroxyalkylrest mit 1 bis 4 Kohlenstoffatomen und Z für einen linearen oder verzweigten Polyhydroxyalkylrest mit 3 bis 10 Kohlenstoffatomen und 3 bis 10 Hydroxylgruppen steht.
Bevorzugt können Alkylglykoside der allgemeinen Formel RO(G)x eingesetzt werden, in der R einen primären geradkettigen oder methylverzweigten, insbesondere in 2-Stellung methylverzweigten aliphatischen Rest mit 8 bis 22, vorzugsweise 12 bis 18 Kohlenstoffatomen, bedeutet und G für eine Glykoseeinheit mit 5 oder 6 Kohlenstoffatomen, vorzugsweise für Glucose, steht. Der Oligomerisierungsgrad x, der die Verteilung von Monoglykosiden und Oligoglykosiden angibt, ist eine beliebige Zahl zwischen 1 und 10; vorzugsweise liegt x bei 1,2 bis 1,4.Among the alkyl alkoxylates are preferably ethoxylated alcohols, preferably primary alcohols, preferably having 8 to 22 carbon atoms and preferably 1 to 80 EO units per mole of alcohol used, wherein the alcohol radical is linear or preferably methyl-branched in the 2-position or linear and methyl branched Contains radicals in the mixture, as is usually the case in Oxoalkoholresten. The preferred ethoxylated alcohols include, for example, C 11 alcohols having 3, 5, 7, 8 and 11 EO units, (C 12 -C 15 ) alcohols having 3, 6, 7, 8, 10 and 13 EO units, respectively , (C 14 -C 15 ) -alcohols having 4, 7 or 8 EO units, (C 16 -C 18 ) -alcohols having 8, 11, 15, 20, 25, 50 or 80 EO units and mixtures the same. The degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number. In addition to these, it is also possible to use fatty alcohol EO / PO adducts, for example the ®Genapol types 3970, 2909 and 2822 from Clariant GmbH.
Further suitable surfactants are polyhydroxy fatty acid amides of the formula R 2 -CO-N (R 3 ) -Z, in which R 2 CO is an aliphatic acyl radical having 6 to 22 carbon atoms, R 3 is hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and Z is a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
Preference is given to using alkyl glycosides of the general formula RO (G) x in which R is a primary straight-chain or methyl-branched, in particular 2-methyl-branched, aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms, and G is a glycose unit having 5 or 6 carbon atoms, preferably glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4.

Bevorzugt sind auch alkoxylierte, vorzugsweise ethoxylierte oder ethoxylierte und propoxylierte, Fettsäurealkylester, vorzugsweise mit 1 bis 4 Kohlenstoffatomen in der Alkylkette, insbesondere Fettsäuremethylester, wie sie beispielsweise in der japanischen Patentanmeldung JP 58/217598 beschrieben sind, oder vorzugsweise solche wie sie nach dem in der internationalen Patentanmeldung WO A 90/13533 beschriebenen Verfahren hergestellt werden.Also preferred are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated, fatty acid alkyl esters, preferably having 1 to 4 carbon atoms in the alkyl chain, in particular fatty acid methyl ester, as described for example in the Japanese Patent Application JP 58/217598, or preferably such as those described in International patent application WO A 90/13533 be prepared described methods.

Als anionische Tenside vom Sulfonat-Typ kommen vorzugsweise die bekannten (C9-C13)-Alkylbenzolsulfonate, alpha-Olefinsulfonate und Alkansulfonate in Betracht. Geeignet sind auch Ester von Sulfofettsäuren bzw. die Disalze der alpha-Sulfofettsäuren. Weitere geeignete anionische Tenside sind sulfierte Fettsäureglycerinester, welche Mono-, Di- und Triester sowie deren Gemische darstellen, wie sie bei der Herstellung durch Veresterung durch 1 Mol Monoglycerin mit 1 bis 3 Mol Fettsäure oder bei der Umesterung von Triglyceriden mit 0,3 bis 2 Mol Glycerin erhalten werden. Als Alkylsulfate eignen sich insbesondere die Schwefelsäuremonoester der (C12-C18)-Fettalkohole, wie Lauryl-, Myristyl-, Cetyl- oder Stearylalkohol, und die aus Kokosöl, Palm- und Palmkernöl gewonnenen Fettalkoholgemische, die zusätzlich noch Anteile an ungesättigten Alkoholen, z.B. Oleylalkohol, enthalten können.Suitable anionic surfactants of the sulfonate type are preferably the known (C 9 -C 13 ) -alkylbenzenesulfonates, alpha-olefinsulfonates and alkanesulfonates. Also suitable are esters of sulfo fatty acids or the disalts of the alpha-sulfo fatty acids. Other suitable anionic surfactants are sulfated Fettsäureglycerinester which mono-, di- and triesters and mixtures thereof, as in the preparation by esterification by 1 mole of monoglycerol with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 Mole of glycerol can be obtained. Particularly suitable as alkyl sulfates are the sulfuric acid monoesters of (C 12 -C 18 ) -fatty alcohols, such as lauryl, myristyl, cetyl or stearyl alcohol, and the fatty alcohol mixtures obtained from coconut oil, palm and palm kernel oil, which additionally contain portions of unsaturated alcohols, For example, oleyl alcohol may contain.

Als weitere anionische Tenside kommen insbesondere Seifen in Betracht. Geeignet sind gesättigte Fettsäureseifen, wie die Salze der Laurinsäure, Myristinsäure, Palmitinsäure, Stearinsäure, hydrierten Erucasäure und Behensäure, sowie insbesondere aus natürlichen Fettsäuren, z.B. Kokos-, Palmkern- oder Talgfettsäuren, abgeleitete Seifengemische. Die anionischen Tenside können in Form ihrer Natrium-, Kalium- oder Ammoniumsalze, sowie als lösliche Salze organischer Basen, wie Mono-, Di- oder Triethanolamin, vorliegen. Vorzugsweise liegen die anionischen Tenside in Form ihrer Natrium- oder Kaliumsalze, insbesondere in Form der Natriumsalze, vor.As further anionic surfactants are particularly soaps into consideration. Suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, Palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, as well especially from natural fatty acids, e.g. Coconut, palm kernel or Tallow fatty acids, derived soap mixtures. The anionic surfactants can be used in Form their sodium, potassium or ammonium salts, as well as soluble salts organic bases, such as mono-, di- or triethanolamine. Preferably the anionic surfactants are in the form of their sodium or potassium salts, especially in the form of the sodium salts.

Bei den Buildem handelt es sich bevorzugt um kristalline Aluminosilikate, Alkalicarbonate, Alkaliortho-, Alkalipyro- und Alkalipolyphosphate, kristalline Schichtsilikate, kristalline Alkalisilikate ohne Schichtstruktur und/oder röntgenamorphe Alkalisilikate.The buildem are preferably crystalline aluminosilicates, Alkali metal carbonates, alkali ortho, alkali pyro and alkali polyphosphates, crystalline Phyllosilicates, crystalline alkali metal silicates without layer structure and / or X-ray amorphous alkali silicates.

Bei den Cobuildem handelt es sich bevorzugt um monomere, oligomere, polymere oder copolymere Carbonsäuren.The co-builders are preferably monomeric, oligomeric, polymeric or copolymeric carboxylic acids.

Bei den Bleichsystemen handelt es sich bevorzugt um Aktivchlorträger und/oder organische oder anorganische Aktivsauerstoffträger, Bleichaktivatoren (z.B. TAED), Bleichkatalysatoren, Enzyme zur Entfernung von Verfärbungen, Perborate und/oder Percarbonate.The bleaching systems are preferably active chlorine carriers and / or organic or inorganic active oxygen carriers, bleach activators (e.g., TAED), Bleach catalysts, removal of discoloration, perborates and / or Percarbonates.

Bei den pH-Regulatoren handelt es sich bevorzugt um Soda, Zitronensäure, Natriumcitrat und/oder Bicarbonat.The pH regulators are preferably soda, citric acid, Sodium citrate and / or bicarbonate.

Schließlich können die Wasch- und Reinigungsmittel gegebenenfalls noch Enzyme, wie z.B. Proteasen, Amylasen, Lipasen und Cellulaseen, enthalten.Finally, the detergents and cleaners may also contain enzymes, such as. Proteases, amylases, lipases and cellulases.

Die Wasch- und Reinigungsmittel können zur Behandlung von Faser- und Textiloberflächen, aber auch zur Behandlung harter Oberflächen aus den verschiedensten Materialien, z.B. Metallen, Glas, Keramiken, Kunststoffen etc., eingesetzt werden.The detergents and cleaners can be used to treat fiber and fiber Textile surfaces, but also for the treatment of hard surfaces from the various materials, e.g. Metals, glass, ceramics, plastics etc., be used.

Weiterhin bevorzugte Reinigungsmitteln sind Automobil- und Lackreiniger für die manuelle Anwendung und für die automatische Anwendung in Waschstraßen. Further preferred cleaning agents are automotive and paint cleaners for the manual application and for automatic use in car washes.

Die nachfolgenden Beispiele dienen der Erläuterung der Erfindung, ohne sie jedoch einzuschränken. Die Zusammensetzungen der erfindungsgemäßen Mittel werden dabei in Gewichtsprozent angegeben.The following examples serve to illustrate the invention, but without it limit. The compositions of the agents according to the invention are specified in percent by weight.

Durchführung des Gardnertests:Carrying out the Gardner test:

Der Gardnertest ist ein Reinigungstest für harte Oberflächen, vorwiegend Fußböden etc.. Dabei weren Probestreifen (maximal 45cm lang und 5-6 cm breit) mit der Untersuchungslösung behandelt, getrocknet und dann angeschmutzt. Zur Untersuchung des Reinigungsprozesses werden 10 g der Reinigungslösung auf den Streifen gegeben und ein Stück Wischtuch an einer Halterung befestigt. Das Tuch wird mittels Spannseilen, über einen Exzenter angetrieben, auf dem präparierten Probenstreifen hin- und herbewegt. Die Anzahl der Wischbewegungen wird an einem Zählwerk abgelesen. Ausgewertet wird die Anzahl der Wischbewegungen bis zur absoluten Sauberkeit, oder nach maximal 50 Wischbewegungen die Benotung des Reinigungsergebnisses auf der Skala von 1 (sauber) bis 5.
Die Bewertung 50/3 bedeutet hierbei, daß nach der Maximalanzahl von 50 Wischgängen die Abmusterung die Note 3 auf der Skala von 1 bis 5 ergab.
Die Bewertung 5/1 bedeutet hierbei, daß schon nach 5 Wischgängen die Abmusterung die Note 1 (sauber) auf der Skala von 1 bis 5 ergab.The Gardnertest is a cleaning test for hard surfaces, mainly floors etc .. Here are test strips (maximum 45cm long and 5-6 cm wide) treated with the test solution, dried and then soiled. To investigate the cleaning process, add 10 g of the cleaning solution to the strip and attach a piece of wipe to a holder. The cloth is driven by tensioning cables, driven by an eccentric, back and forth on the prepared sample strip. The number of swipes is read on a counter. The number of wiping movements is evaluated up to the absolute cleanliness, or after a maximum of 50 wiping movements the rating of the cleaning result on the scale of 1 (clean) to 5.
The rating 50/3 means here that after the maximum number of 50 wipes the matching gave the grade 3 on the scale of 1 to 5.
The rating 5/1 means here that after only 5 wipes the matching gave the grade 1 (clean) on the scale from 1 to 5.

Als Oberflächen wurden Keramik-Wandfließen und PVC-Bodenplatten eingesetzt. Als Anschmutzungen wurden Edding permanent Stift, Signierkreidestift und Bleistift (Graphit) verwendet.Ceramic wall tiles and PVC floor tiles were used as surfaces. As stains were Edding permanent pen, marking pencil and pencil (Graphite) used.

Durchführung der Maschinengeschirrreinigertests:Carrying out the machine dishwashing tests:

Anlehnend an IEC-Norm 436 und IKW-Methode wurden Tests in 4 Haushaltsgeschirrspülmaschinen (2 Miele G 688 SC und 2 Bosch 6902) bei 55°C Spültemperatur und 20g Dosierung durchgeführt.Based on IEC standard 436 and the IKW method, tests were carried out in 4 Domestic dishwashers (2 Miele G 688 SC and 2 Bosch 6902) at 55 ° C Rinsing temperature and 20g dosage performed.

Die Anschmutzungen waren:The stains were:

  • a) Haferflocken auf Porzellan-Suppenteller und Metall-Suppenlöffel, bei 80°C 2 Stunden lang eingetrocknet. Nach dem Reinigungsgang wurde das Spülgut mit Jod-Jodkali-Lösung angefärbt und visuell anhand eines Fotokataloges und einer Scala von 0 (schmutzig) bis 10 (sauber) abgemustert. Die Suppenlöffel werden visuell anhand einer Scala von 0 bis 10 abgemustert.a) Oatmeal on porcelain soup plates and metal soup spoons, at 80 ° C Dried for 2 hours. After the cleaning cycle, the dishes were with Iodine-iodide solution stained and visually using a photo catalog and a Scala graded from 0 (dirty) to 10 (clean). The soup spoons are going to be visually scrapped using a scale from 0 to 10.
  • b) Ei auf Dessert-Teller, bei 80°C 2 Stunden lang eingetrocknet. Nach dem Reinigungsgang wurde das Spülgut visuell anhand einer Scala von 0 bis 10 abgemustert.b) Egg on dessert plate, dried at 80 ° C for 2 hours. After this Cleaning cycle, the dishes were visually based on a scale from 0 to 10 paid off.
  • c) Hackfleisch auf Essteller, bei 80°C 2 Stunden lang eingetrocknet. Nach dem Reinigungsgang wurde das Spülgut visuell anhand einer Scala von 0 bis 10 abgemustert.c) Minced meat on plates, dried at 80 ° C for 2 hours. After this Cleaning cycle, the dishes were visually based on a scale from 0 to 10 paid off.
  • d) Hackfleisch auf Essteller, bei 120°C 2 Stunden lang eingetrocknet. Nach dem Reinigungsgang wurde das Spülgut visuell anhand einer Scala von 0 bis 10 abgemustert.d) Minced meat on plates, dried at 120 ° C for 2 hours. To During the cleaning cycle, the dishes were visually scored from 0 to 10 paid off.
  • e) Spinat auf Dessert-Teller, bei 80°C 2 Stunden lang eingetrocknet. Nach dem Reinigungsgang wurde das Spülgut visuell anhand einer Scala von 0 bis 10 abgemustert.e) spinach on dessert plate, dried at 80 ° C for 2 hours. After this Cleaning cycle, the dishes were visually based on a scale from 0 to 10 paid off.
  • f) Tee auf Porzellantassen, bei 80°C 2 Stunden lang eingetrocknet. Nach dem Reinigungsgang wurde das Spülgut visuell anhand eines Fotokataloges und einer Scala von 0 bis 10 abgemustert.f) Tea on porcelain cups, dried at 80 ° C for 2 hours. After this Cleaning cycle, the dishes were visually based on a photo catalog and a Scala graded from 0 to 10.
  • g) Milch auf Becherglasinnenwand, in einem Mikrowellenofen und bei 80°C 2 Stunden lang eingetrocknet. Nach dem Reinigungsgang wurde das Spülgut visuell anhand eines Fotokataloges und einer Scala von 0 bis 10 abgemustert.g) Milk on beaker inner wall, in a microwave oven and at 80 ° C Dried for 2 hours. After the cleaning cycle, the dishes were visually graded on the basis of a photo catalog and a scale from 0 to 10.

    • Die Messwerte wurden arithmetisch zu einem Durchschnitt gemittelt und auf einen Maßstab von 0 bis 100 % gespreizt.The measurements were arithmetically averaged and averaged Scale spread from 0 to 100%.

    Beispiel 1 (Vergleich):Example 1 (comparison):

    Es wurde ein Allzweckreiniger hergestellt, indem Genapol UD 080 und Hostapur SAS 60 miteinander gemischt wurden. Dann wurde Wasser und schließlich Cumolsulfonat zugemischt. Mit Hilfe des Gardnertests wurde die Reinigungswirkung untersucht. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.An all-purpose cleaner was made by Genapol UD 080 and Hostapur SAS 60 were mixed together. Then there was water and finally Added cumene sulfonate. With the help of the Gardnertests was the cleaning effect examined. The composition and the results are shown in Table 1.

    Beispiel 2Example 2

    Wie in Beispiel 1 wurde ein Allzweckreiniger hergestellt. Außerdem wurde mit dem Wasser Klebosol 30 V 25 zugefügt. Dadurch kann im Gardner-Test im Vergleich zu Beispiel 1 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water Klebosol 30 V 25 added. This can be compared to the Gardner test Example 1, an improvement of the cleaning effect can be achieved. The Composition and results are shown in Table 1.

    Beispiel 3Example 3

    Wie in Beispiel 1 wurde ein Allzweckreiniger hergestellt. Außerdem wurde mit dem Wasser Hectorit SKS-21 zugefügt. Dadurch kann im Gardner-Test im Vergleich zu Beispiel 1 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water hectorite SKS-21 added. This can be compared to the Gardner test Example 1, an improvement of the cleaning effect can be achieved. The Composition and results are shown in Table 1.

    Beispiel 4Example 4

    Wie in Beispiel 1 wurde ein Allzweckreiniger hergestellt. Außerdem wurde mit dem Wasser Klebosol 30 V 25 und mit dem Cumolsulfonat TexCare SRC-1 Dispersion zugefügt. Dadurch kann im Gardner-Test im Vergleich zu den Beispielen 1 bis 3 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water Klebosol 30 V 25 and with the cumenesulfonate TexCare SRC-1 dispersion added. This can be in the Gardner test compared to Examples 1 to 3 an improvement of the cleaning effect can be achieved. The composition and the results are shown in Table 1.

    Beispiel 5 (Vergleich)Example 5 (comparison)

    Es wurde ein Fliesen-/Badreiniger hergestellt, indem Isopropanol und Wasser miteinander gemischt wurden. Dann wurden Genapol UD 080, Hordaphos CC MS und Hostapur SAS 60 unter starkem Rühren und zuletzt Zitronensäuremonohydrat zugemischt. Mit Hilfe des Gardner-Tests wurde die Reinigungswirkung untersucht. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.A tile / bathroom cleaner was made by adding isopropanol and water mixed together. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 with vigorous stirring and finally citric acid monohydrate admixed. The detergency was tested using the Gardner test. The composition and the results are shown in Table 1.

    Beispiel 6Example 6

    Wie in Beispiel 5 wurde ein Fliesen-/Badreiniger hergestellt. Außerdem wurde mit dem Wasser Klebosol 20 H 12 zugefügt. Dadurch kann im Gardner-Test im Vergleich zu Beispiel 5 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 5, a tile / bathroom cleaner was made. It was also with Klebosol 20 H 12 was added to the water. This can be seen in the Gardner test in the Compared to Example 5 an improvement of the cleaning effect can be achieved. The composition and the results are shown in Table 1.

    Beispiel 7Example 7

    Wie in Beispiel 5 wurde ein Fliesen-/Badreiniger hergestellt. Außerdem wurde mit dem Wasser Klebosol 20 H 12 und mit der Zitronensäure Finish CT 34 E zugefügt. Dadurch kann im Gardner-Test im Vergleich zu den Beispielen 5 und 6 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 5, a tile / bathroom cleaner was made. It was also with Add to the water Klebosol 20 H 12 and with the Citric Acid Finish CT 34 E. This can be in the Gardner test compared to Examples 5 and 6 a Improvement of the cleaning effect can be achieved. The composition and the results are shown in Table 1.

    Beispiel 8Example 8

    Es wurde ein Handgeschirrspülmittel hergestellt, indem Hostapur SAS 60 mit Wasser und Klebosol 30 R 12 gemischt wurde. Dann wurden Genagen CAB 818, Genapol UD 080 und Genapol ZRO liquid unter langsamem Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A hand dishwashing detergent was prepared by using Hostapur SAS 60 Water and Klebosol 30 R 12 was mixed. Then Genagen CAB 818, Genapol UD 080 and Genapol ZRO liquid mixed with slow stirring. The Composition is listed in Table 2.

    Beispiel 9Example 9

    Es wurde ein Fensterreiniger hergestellt, indem Genapol LRO liquid mit Wasser und Klebosol 30 N 12 gemischt wurde. Dann wurden Ammoniumhydroxid und Isopropanol unter Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A window cleaner was made by using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide and Isopropanol mixed with stirring. The composition is in Table 2 listed.

    Beispiel 10Example 10

    Es wurde ein Fensterreiniger hergestellt, indem Genapol LRO liquid mit Wasser und Klebosol 30 N 12 gemischt wurde. Dann wurden Ammoniumhydroxid, Isopropanol und Finish CT 34 E unter Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A window cleaner was made by using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide, isopropanol and finish CT 34 E while stirring. The composition is in table 2 listed.

    Beispiel 11Example 11

    Es wurde ein Allzweckreiniger hergestellt, indem Genapol UD 080 mit Hostapur SAS 60 gemischt wurde. Dann wurden Wasser, Klebosol 30 R 12 und Propylenglykol n-Butylether unter Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt. An all-purpose cleaner was made by using Genapol UD 080 with Hostapur SAS 60 was mixed. Then water, Klebosol 30 R 12 and propylene glycol n-butyl ether mixed with stirring. The composition is in Table 2 listed.

    Beispiel 12Example 12

    Es wurde ein Fließen-/Badreiniger hergestellt, indem Isopropanol mit Wasser gemischt wurde. Dann wurden Genapol UD 080, Hordaphos CC MS und Hostapur SAS 60 und zum Schluss Klebosol 30H25 unter Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A flow / bath cleaner was made by adding isopropanol with water was mixed. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 and finally Klebosol 30H25 mixed with stirring. The Composition is listed in Table 2.

    Beispiel 13Example 13

    Es wurde ein Reiniger für Autowaschanlagen hergestellt, indem Genapol UD 110 und Genapol UD 50 nacheinander in Wasser gelöst wurden. Dann wurde Klebosol 30 R 12 zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A cleaner for car washes was manufactured by Genapol UD 110 and Genapol UD 50 were successively dissolved in water. Then, Klebosol became 30 R 12 mixed. The composition is listed in Table 2.

    Beispiel 14Example 14

    Es wurde ein Trocknungsmittel für Autowaschanlagen hergestellt, indem nacheinander Butyldiglykol, Essigsäure, conc., Genamin LAP 100 D und Praepagen 4317 gemischt wurden. Dann wurde Wasser und Klebosol 30 H 25 zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A desiccant for car washes was made by successively butyldiglycol, acetic acid, conc., Genamin LAP 100 D and Praepagen 4317 were mixed. Then water and Klebosol 30 H 25 were added. The Composition is listed in Table 2.

    Beispiel 15Example 15

    Es wurde ein Heißwachs für Autowaschanlagen hergestellt, indem nacheinander Balsamterpentinöl, Spindelöl, Butyldiglykol, Genapol X 080 und Hoechst-Wachs KST gemischt wurden. Dann wurden Praepagen WKT, Wasser und Klebosol 30 H 25 zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.It was made a hot wax for car washes by successively Balsam turpentine, spindle oil, butyl diglycol, Genapol X 080 and Hoechst wax KST were mixed. Then were preks WKT, water and Klebosol 30 H 25 mixed. The composition is listed in Table 2.

    Beispiel 16Example 16

    Es wurde ein Maschinengeschirrreinerklarspüler hergestellt, indem nacheinander Zitronensäure, Cumolsulfonat, Genapol 2908 und Klebosol 30 H 25 in Wasser gelöst wurden. Nach der allgemeinen Vorschrift Durchführung der Maschinengeschirrreinigertests wurde Geschirr mit einem handelsüblichen Tabletten-Geschirrreiniger gespült. Als Klarspüler wurde obige Formulierung eingesetzt. Diese Prozedur aus Reinigen und Klarspülen wurde noch einmal wiederholt und das Geschirr danach abgemustert. Die Zusammensetzung und die Ergebnisse sind in Tabelle 3 aufgeführt. A machine dishwashing rinse was made by successively Citric acid, cumene sulfonate, Genapol 2908 and Klebosol 30 H 25 in water were solved. According to the general rule implementation of Machine dishwashing tests were dishes with a commercial Rinsed tablet-dishwashing detergent. The rinse aid was the above formulation used. This procedure of cleaning and rinsing was repeated repeated and the dishes are then scrapped. The composition and the Results are listed in Table 3.

    Beispiel 17Example 17

    Wie in Beispiel 16 wird ein Maschinengeschirrreinerklarspüler hergestellt. Zusätzlich wird Klebosol 30 H 25 untergemischt. Nach der allgemeinen Vorschrift Durchführung der Maschinengeschirrreinigertests wurde Geschirr zweimal mit einem handelsüblichen Tabletten-Geschirrreiniger gespült und mit dem Klarspüler behandelt. Die Verwendung von Kieselsol ergibt klare Vorteile für die Reinigungswirkung. Die Zusammensetzung und die Ergebnisse sind in Tabelle 3 aufgeführt.As in Example 16, a machine dishwashing rinse aid is prepared. additionally Klebosol 30 H 25 is mixed in. According to the general rule implementation The machine dishwashing tests were dishes twice with a rinsed with commercially available tablet-dishwashing detergent and with the rinse aid treated. The use of silica sol gives clear advantages for the Cleaning effect. The composition and the results are in Table 3 listed.

    Beispiel 18Example 18

    In einem Pflugscharmischer der Fa. Lödige wird ein pulverförmiger Maschinengeschirreiniger dadurch hergestellt dass die festen Komponenten, außer Enzyme, Bleiche und Parfüm, vorgelegt und gut gemischt werden. Dann werden das Alkylethoxylat und das Klebosol 30 V 50 aufgesprüht. Enzyme, Parfüm und Bleichsystem werden zum Schluss untergemischt. Die Zusammensetzung ist in Tabelle 4 aufgeführt.In a ploughshare mixer Fa. Lödige is a powdered Machinery dishes made by the fact that the solid components, except Enzymes, bleach and perfume, are submitted and mixed well. Then that will be Alkyl ethoxylate and the Klebosol 30 V 50 sprayed on. Enzymes, perfume and Bleach system are finally mixed in. The composition is in Table 4 listed.

    Beispiel 19 Die Zusammensetzung ist in Tabelle 4 aufgeführt.Example 19 The composition is listed in Table 4. Beispiel 20Example 20

    Ein Flüssigwaschmittel wird dadurch hergestellt, dass man unter kräftigem Rühren Alkylbenzolsulfonat, Zitronensäure, Genapol 3070, Seife, Wasser, Siliconöl, Phosphonat, Polyglykolether und Klebosol 30 V 50 mischt. Die Zusammensetzung ist in Tabelle 4 aufgeführt.A liquid detergent is prepared by stirring vigorously Alkylbenzenesulfonate, citric acid, Genapol 3070, soap, water, silicone oil, Phosphonate, polyglycol ether and Klebosol 30 V 50 mixes. The composition is listed in Table 4.

    Beispiel 21Example 21

    Ein Pulverwaschmittel wird dadurch hergestellt, dass man in einem Pflugscharmischer der Fa. Lödige Antischaum, Schichtsilicat, Soda, Sokalan CP5 und Zeolith A mischt und Genapol 3070 aufsprüht. Die restlichen Komponenten werden kurz untergemischt. Die Zusammensetzung ist in Tabelle 4 aufgeführt. A powder detergent is prepared by adding in a Ploughshare mixer Fa. Lödige Antifoam, phyllosilicate, soda, Sokalan CP5 and Zeolite A and Genapol 3070 sprayed on. The remaining components are mixed in for a short time. The composition is listed in Table 4.

    Beispiel 22Example 22

    Ein Wäscheweichspüler wird dadurch hergestellt, dass bei 50 bis 60°C unter Rühren zunähst Lapnite RD und danach Praepagen WK in Wasser gelöst werden. Die Zusammensetzung ist in Tabelle 4 aufgeführt.A fabric softener is prepared by stirring at 50 to 60 ° C First Lapnite RD and then Praepagen WK are dissolved in water. The Composition is listed in Table 4.

    Beispiel 23Example 23

    Ein Wäscheweichspüler wird dadurch hergestellt, dass bei 50°C geschmolzenes Triethanolamin diesterquat (85 %) in vorgeheiztes Wasser gelöst wird, dann wird Genapol UD 088 eingerührt und die Lösung abgekühlt. Zum Schluss wird TexCare SRC-1 Dispersion und Klebosol 30 V 50 eingerührt. Beispiel 1 2 3 4 5 6 7 Komponenten [%] Vgl Vgl Citronensäure monohydrat 3 3 3 Cumolsulfonat 2 2 2 2 Genapol UD 080 9 9 9 9 0,5 0,5 0,5 Hordaphos CC MS 1 1 1 Hostapur SAS 60 8,3 8,3 8,3 8,3 3 3 3 Isopropanol 5 5 5 Propylenglykol n-Butylether 3 3 3 3 Wasser 77,7 76,7 76,7 75,7 87,5 86,5 86 Klebosol 30 V 25 1 1 Klebosol 20 H 12 1 1 Hectorit SKS-21 1 TexCare SRC-1 Dispersion 1 Finish CT 34 E 0,5 Dosierung 10g 10g 10g 10g 10g 10g 10g Edding permanent/PVC Fliese 50/5 50/3,5 50/3,5 50/3 - - - Signierkreide/PVC Fliese 50/3 50/2,5 50/2,5 50/2 - - - Graphit/PVCFließe 5/1 2/1 3/1 2/1 - - - Edding permanent/Keramik- - - - - 50/4 50/2 50/1 Wandfliese Signierkreide/Keramlk-Wandfliese - - - - 50/2 50/1 50/1 Beispiel 8 9 10 11 12 13 14 15 Komponenten [%] Ammoniumhydroxid (w= 25 %) 0,5 0,5 Balsamterpentinöl 2 Butyldiglycol 18 13 Citronensäure monohydrat 3 Cumolsulphonat 2 Essigsäure, conc. 0,8 Genagen CAB 818 10 Genamin LAP 100 D 2 Genapol LRO liquid 0,5 0,5 Genapol O 020 5 Genapol DU 080 3 9 0,5 Genapol DU 110 10 Genapol DU 50 3 Genapol X 080 2 Genapol ZRO liquid 22,9 Hoechst-Wachs KST 4 Hordaphos CC MS 1 Hostapur SAS 60 42,7 8,3 3 Isopropanol 29 29 3 Praepagen 4317 10 Praepagen WKT 11 Propylenglycol n-butylether 3 Spindelöl 6 Wasser 19,4 69 68 75,7 88,5 86 59,2 57 Klebosol 30 R 12 2 2 1 5 Klebosol 30 H 25 1 5 Klebosol 30 N 12 1 1 Finish CT 34 E 1 Dosierung 1:1000 1:1000 1:500 Beispiel 16 17 Komponenten [%] Vgl Citronensäure 3 3 Cumolsulfonat, 40 % 8 8 Genapol 2908 14 14 Wasser 75 74 Klebosol 30 H 25 0 1 Dosierung g/cycle 3g 3g Reinigungswirkung % 75 90 Beispiel 18 19 20 21 22 23 Komponenten [%] Alkylbenzolsulfonat 25 9 Antischaum 1 Citrat th 35 Citronensäure 2 Cumolsulfonat, 40 % Genapol 2822 1,5 1,5 Genapol 2908 Genapol 3070 9 8 Genapol UD 088 0,5 Makrophos 1018 47 Parfüm 0,3 0,3 Peractive AC White 5 2 Peractive AN 5 Perborat mh - 10 18 Percarbonat 10 - Praepagen WK 6,7 Savinase 6.0 TW 1,5 1,5 1,5 Schichtsilicat 5 5,2 15 Seife 5 1,5 Soda 31,7 25,5 12,5 Sokalan CP45 7,5 3,5 Sokalan CP5 6 Termamyl 120T 1,5 1,5 Termamyl 60T 1,5 TexCare SRC-1 Dispersion 4 Triethanolamin diesterquat (85 %) 5,5 Wasser 40 93,2 89 Zeolith A 20 Wacker Siliconöl 1 Phosphonat 1 Polyglycolether 15 Klebosol 30 V 50 1 2 2 1 1 Laponite RD 0,1 Dosierung g/cycle 20g 20g 130g 20g 5-7g 5-7g A fabric softener is prepared by dissolving molten triethanolamine diesterquat (85%) in preheated water at 50 ° C, then stirring Genapol UD 088 and cooling the solution. Finally, TexCare SRC-1 dispersion and Klebosol 30 V 50 are stirred in. example 1 2 3 4 5 6 7 Components [%] See See Citric acid monohydrate 3 3 3 cumene 2 2 2 2 Genapol UD 080 9 9 9 9 0.5 0.5 0.5 Hordaphos CC MS 1 1 1 Hostapur SAS 60 8.3 8.3 8.3 8.3 3 3 3 isopropanol 5 5 5 Propylene glycol n-butyl ether 3 3 3 3 water 77.7 76.7 76.7 75.7 87.5 86.5 86 Klebosol 30 V 25 1 1 Klebosol 20H 12 1 1 Hectorite SKS-21 1 TexCare SRC-1 dispersion 1 Finish CT 34 E 0.5 dosage 10g 10g 10g 10g 10g 10g 10g Edding permanent / PVC tile 50/5 50 / 3.5 50 / 3.5 50/3 - - - Signed chalk / PVC tile 50/3 50 / 2.5 50 / 2.5 50/2 - - - Graphite / PVCFließe 1.5 1.2 1.3 1.2 - - - Edding permanent / ceramic - - - - 50/4 50/2 50/1 wall tile Crayons / Keramlk wall tile - - - - 50/2 50/1 50/1 example 8th 9 10 11 12 13 14 15 Components [%] Ammonium hydroxide (w = 25%) 0.5 0.5 Gum 2 diglycol 18 13 Citric acid monohydrate 3 Cumolsulphonat 2 Acetic acid, conc. 0.8 Genagen CAB 818 10 Genamin LAP 100 D 2 Genapol LRO liquid 0.5 0.5 Genapol O 020 5 Genapol DU 080 3 9 0.5 Genapol DU 110 10 Genapol DU 50 3 Genapol X 080 2 Genapol ZRO liquid 22.9 Hoechst wax KST 4 Hordaphos CC MS 1 Hostapur SAS 60 42.7 8.3 3 isopropanol 29 29 3 Praepagen 4317 10 Praepagen WKT 11 Propylene glycol n-butyl ether 3 spindle oil 6 water 19.4 69 68 75.7 88.5 86 59.2 57 Klebosol 30 R 12 2 2 1 5 Klebosol 30 H 25 1 5 Klebosol 30 N 12 1 1 Finish CT 34 E 1 dosage 1: 1000 1: 1000 1: 500 example 16 17 Components [%] See citric acid 3 3 Cumene sulphonate, 40% 8th 8th Genapol 2908 14 14 water 75 74 Klebosol 30 H 25 0 1 Dosage g / cycle 3g 3g Cleaning effect% 75 90 example 18 19 20 21 22 23 Components [%] alkylbenzenesulfonate 25 9 antifoam 1 Citrate th 35 citric acid 2 Cumene sulphonate, 40% Genapol 2822 1.5 1.5 Genapol 2908 Genapol 3070 9 8th Genapol UD 088 0.5 Macrophos 1018 47 Perfume 0.3 0.3 Peractive AC White 5 2 Peractive AN 5 Perborate mh - 10 18 percarbonate 10 - Praepagen WK 6.7 Savinase 6.0 TW 1.5 1.5 1.5 layered 5 5.2 15 Soap 5 1.5 soda 31.7 25.5 12.5 Sokalan CP45 7.5 3.5 Sokalan CP5 6 Termamyl 120T 1.5 1.5 Termamyl 60T 1.5 TexCare SRC-1 dispersion 4 Triethanolamine diesterquat (85%) 5.5 water 40 93.2 89 Zeolite A 20 Wacker silicone oil 1 phosphonate 1 polyglycol 15 Klebosol 30 V 50 1 2 2 1 1 Laponite RD 0.1 Dosage g / cycle 20g 20g 130g 20g 5-7g 5-7g

    Liste der verwendeten Substanzen:List of substances used:

    Alkylbenzolsulfonatalkylbenzenesulfonate
    Marlon ARL, Fa. HülsMarlon ARL, Fa. Huls
    Ammoniumhydroxid (w= 25 %)Ammonium hydroxide (w = 25%)
    Fa. Riedel de HaenFa. Riedel de Haen
    Antischaumantifoam
    Fa. WackerFa. Wacker
    BalsamterpentinölGum
    --
    Butyldiglycoldiglycol
    Fa. MerckFa. Merck
    Citronensäurecitric acid
    Fa. JungbunzlauerFa. Jungbunzlauer
    Citronensäure monohydratCitric acid monohydrate
    Fa. JungbunzlauerFa. Jungbunzlauer
    Cumol sulphonatCumene sulphonate
    Fa.CondeaFa.Condea
    Essigsäure, conc.Acetic acid, conc.
    Fa. Riedel de HaenFa. Riedel de Haen
    Finish CT 34 EFinish CT 34 E
    Fa. WackerFa. Wacker
    Genagen CAB 818Genagen CAB 818
    Fa. ClariantFa. Clariant
    Genamin LAP 100 DGenamin LAP 100 D
    Fa. ClariantFa. Clariant
    Genapol 2822Genapol 2822
    Fa. ClariantFa. Clariant
    Genapol 2908Genapol 2908
    Fa. ClariantFa. Clariant
    Genapol 3070Genapol 3070
    Fa. ClariantFa. Clariant
    Genapol LRO liquidGenapol LRO liquid
    Fa. ClariantFa. Clariant
    Genapol O 020Genapol O 020
    Fa. ClariantFa. Clariant
    Genapol UD 080Genapol UD 080
    Fa. ClariantFa. Clariant
    Genapol UD 088Genapol UD 088
    Fa. ClariantFa. Clariant
    Genapol UD 110Genapol UD 110
    Fa. ClariantFa. Clariant
    Genapol UD 50Genapol UD 50
    Fa. ClariantFa. Clariant
    Genapol X 080Genapol X 080
    Fa. ClariantFa. Clariant
    Genapol ZRO liquidGenapol ZRO liquid
    Fa. ClariantFa. Clariant
    Hectorit SKS-21Hectorite SKS-21
    Fa. ClariantFa. Clariant
    Hoechst-Wachs KSTHoechst wax KST
    Fa. ClariantFa. Clariant
    Hordaphos CC MSHordaphos CC MS
    Fa. ClariantFa. Clariant
    Hostapur SAS 60Hostapur SAS 60
    Fa. ClariantFa. Clariant
    Isopropanolisopropanol
    Fa. Riedel de HaenFa. Riedel de Haen
    Klebosol 20 H 12Klebosol 20H 12
    Fa. ClariantFa. Clariant
    Klebosol 30 H 25Klebosol 30 H 25
    Fa. ClariantFa. Clariant
    Klebosol 30 N 12Klebosol 30 N 12
    Fa. Clariant Fa. Clariant
    Klebosol 30 R 12Klebosol 30 R 12
    Fa. ClariantFa. Clariant
    Klebosol 30 V 25Klebosol 30 V 25
    Fa. ClariantFa. Clariant
    Klebosol 30 V 50Klebosol 30 V 50
    Fa. ClariantFa. Clariant
    Laponite RDLaponite RD
    Fa. LaporteFa. Laporte
    Makrophos 1018Macrophos 1018
    Fa. BK GiuliniFa. BK Giulini
    ParfümPerfume
    Citronenparfüm 78122D, Fa OrissaCitron perfume 78122D, Fa Orissa
    Peractive AC WhitePeractive AC White
    Fa. ClariantFa. Clariant
    Peractive ANPeractive AN
    Fa. ClariantFa. Clariant
    Perborat mhPerborate mh
    Fa. DegussaDegussa
    Percarbonatpercarbonate
    Oxyper C, Fa. Solvay InteroxOxyper C, Solvay Interox
    Phosphonatphosphonate
    Dequest 2041, Fa. MonsantoDequest 2041, Monsanto
    Polyglycoletherpolyglycol
    Fa. ClariantFa. Clariant
    Praepagen 4317Praepagen 4317
    Fa. ClariantFa. Clariant
    Praepagen WKPraepagen WK
    Fa. ClariantFa. Clariant
    Praepagen WKTPraepagen WKT
    Fa. ClariantFa. Clariant
    Propylenglycol n-butyletherPropylene glycol n-butyl ether
    Fa. MerckFa. Merck
    Savinase 6.0 TWSavinase 6.0 TW
    Fa. Solvay EnzymesFa. Solvay Enzymes
    Schichtsilicatlayered
    Fa. ClariantFa. Clariant
    SeifeSoap
    Liga Grundseife HM11ELeague Soap HM11E
    Sodasoda
    Schwersoda, Fa. Matthes&WeberSchwersoda, Fa. Matthes & Weber
    Sokalan CP45Sokalan CP45
    Fa. BASFFa. BASF
    Sokalan CP5Sokalan CP5
    Fa. BASFFa. BASF
    Spindelölspindle oil
    --
    Termamyl 120TTermamyl 120T
    Fa. Solvay EnzymesFa. Solvay Enzymes
    Termamyl 60TTermamyl 60T
    Fa. Solvay EnzymesFa. Solvay Enzymes
    TexCare SRC-1 DispersionTexCare SRC-1 dispersion
    Fa. ClariantFa. Clariant
    Triethanolamin diesterquatTriethanolamine diesterquat
    Fa. ClariantFa. Clariant
    Wacker SiliconölWacker silicone oil
    Fa. WackerFa. Wacker
    Wasserwater
    --
    Zeolith AZeolite A
    Wessalith P, Fa. DegussaWessalith P, Degussa

    Claims (12)

    1. A laundry detergent or cleaner comprising microdisperse, hydrophilic silicate-containing particle with a particle size of from 1 to 500 nm, preferably 9 to 50 nm, the particles being colloidal silica gels, colloidal silica sols, hectorites, saponites or mixtures thereof as well as additionally at least one hydrophobicizing agent, the hydrophobicizing agents being silicones, silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and/or organic fluorine compounds.
    2. The laundry detergent or cleaner as claimed in claim 1, wherein the surface of the particles is electrically charged.
    3. The laundry detergent or cleaner as claimed in claim 1 and/or 2, wherein the weight ratio of silicate-containing particles to hydrophobicizing agents is 100:1 to 1:100, based on active substance.
    4. The laundry detergent or cleaner as claimed in one or more of claims 1 to 3, which comprises 0.01 to 10% by weight of silicate-containing particles, 0.01 to 10% by weight of hydrophobicizing agents and 80 to 99.8% by weight of other laundry detergent/cleaner ingredients.
    5. The laundry detergent or cleaner as claimed in one or more of claims 1 to 3, which comprises 0.01 to 10% by weight of silicate-containing particles, 0.01 to 10% by weight of hydrophobicizing agents, 0.5 to 60% by weight of interface-active substances and 20 to 99.48% by weight of other laundry detergent ingredients.
    6. The laundry detergent or cleaner as claimed in one or more of claims 1 to 3, which comprises 0.01 to 10% by weight of silicate-containing particles, 0.5 to 60% by weight of interface-active substances and 30 to 99.49% by weight of other laundry detergent/cleaner ingredients.
    7. The laundry detergent or cleaner as claimed in one or more of claims 1 to 6, which further comprises builders, cobuilders, alkali suppliers, anionic, zwitterionic and nonionic surfactants, antifoams, dispersants, complexing agents, bleaches, bleach activators and bleach catalysts and/or enzymes.
    8. The laundry detergent or cleaner as claimed in one or more of claims 1 to 7, in the form of a heavy-duty detergent, compact heavy-duty detergent, compact color detergent, heavy-duty detergent of low bulk density, special detergent, such as laundry after-treatment composition, laundry softener, stain-removal salts, bleach booster, net curtain detergent, wool detergent, modular detergent or industrial detergent.
    9. The laundry detergent or cleaner as claimed in one or more of claims 1 to 7, in the form of a cleaner for hard surfaces, e.g. facade, glass, metal, window, floor or carpet cleaner.
    10. The laundry detergent or cleaner as claimed in claim 9, in the form of a hand dishwashing detergent, machine dishwashing detergent, machine dishwashing cleaner or rinse aid.
    11. The use of microdisperse, hydrophilic silicate-containing particles with a particle size of from 1 to 500 nm, preferably 9 to 50 nm, the particles being colloidal silica gels, colloidal silica sols, hectorites, saponites or mixtures thereof as well as additionally at least one hydrophobicizing agent, the hydrophobicizing agents being silicones, silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and/or organic fluorine compounds as surface-coating agents for releasing soil and reducing the tendency for resoiling in laundry detergents and cleaners.
    12. The use as claimed in claim 11, wherein the surface of the particles is electrically charged.
    EP01128892A 2000-12-12 2001-12-05 Detergent composition comprising microdispersed particles containing silicate Revoked EP1215276B1 (en)

    Applications Claiming Priority (2)

    Application Number Priority Date Filing Date Title
    DE10061897 2000-12-12
    DE10061897A DE10061897A1 (en) 2000-12-12 2000-12-12 Washing or cleaning composition, useful for fabrics or hard surfaces, contains microdisperse, hydrophilic silicate particles that improve soil removal and prevent resoiling

    Publications (2)

    Publication Number Publication Date
    EP1215276A1 EP1215276A1 (en) 2002-06-19
    EP1215276B1 true EP1215276B1 (en) 2005-08-03

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    EP01128892A Revoked EP1215276B1 (en) 2000-12-12 2001-12-05 Detergent composition comprising microdispersed particles containing silicate

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    EP (1) EP1215276B1 (en)
    JP (1) JP2002285194A (en)
    DE (2) DE10061897A1 (en)

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    JP2002285194A (en) 2002-10-03
    DE50106965D1 (en) 2005-09-08
    US6784149B2 (en) 2004-08-31
    EP1215276A1 (en) 2002-06-19
    US20020111287A1 (en) 2002-08-15
    DE10061897A1 (en) 2002-06-13

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