EP1186057A1 - Photovoltaische generatoren mit licht-kaskade und veränderung des elektromagnetischen flusses - Google Patents
Photovoltaische generatoren mit licht-kaskade und veränderung des elektromagnetischen flussesInfo
- Publication number
- EP1186057A1 EP1186057A1 EP00920845A EP00920845A EP1186057A1 EP 1186057 A1 EP1186057 A1 EP 1186057A1 EP 00920845 A EP00920845 A EP 00920845A EP 00920845 A EP00920845 A EP 00920845A EP 1186057 A1 EP1186057 A1 EP 1186057A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- matrix
- photovoltaic
- wavelengths
- generator according
- photovoltaic generator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000004907 flux Effects 0.000 title 1
- 239000011159 matrix material Substances 0.000 claims abstract description 27
- 238000010521 absorption reaction Methods 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 claims abstract description 8
- 239000011149 active material Substances 0.000 claims abstract description 7
- 230000035945 sensitivity Effects 0.000 claims abstract description 6
- 239000002019 doping agent Substances 0.000 claims description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 4
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 4
- 238000005286 illumination Methods 0.000 claims description 3
- 230000005540 biological transmission Effects 0.000 claims description 2
- 230000001186 cumulative effect Effects 0.000 claims description 2
- 230000003595 spectral effect Effects 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- -1 perylene imide Chemical class 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/40—Optical elements or arrangements
- H10F77/42—Optical elements or arrangements directly associated or integrated with photovoltaic cells, e.g. light-reflecting means or light-concentrating means
- H10F77/45—Wavelength conversion means, e.g. by using luminescent material, fluorescent concentrators or up-conversion arrangements
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F19/00—Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/52—PV systems with concentrators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S136/00—Batteries: thermoelectric and photoelectric
- Y10S136/291—Applications
Definitions
- the present invention relates to the field of photovoltaic conversion.
- Electric generators comprising photovoltaic cells are known in the prior art. These cells are formed by semiconductor barriers delivering an electrical signal depending on the light intensity illuminating their surface. Various works have been carried out to improve the yield of such cells.
- a first series of works concerns the improvement of the cells themselves, by the production of monocrystalline cells for example. These improvements result in cells whose manufacturing cost is extremely high.
- US patent US5813238 also describes a solar collector having long-lasting fluorescent properties comprising a polymer matrix, a dye, and a stabilizer.
- the polymer matrix is composed of polycarbonate and the dye is chosen from the group consisting essentially of thioxanthone, perylene imide and / or thioindigoide compounds.
- This patent proposes also to position reflective elements so that the collected sunlight can be directed to a solar cell.
- US Patent US4367367 describes a collector adapted to concentrate solar energy on a photoelectric cell comprising at least one fluorescent dopant. The cell is fixed to an edge of the collector, which is coated with a reflective coating.
- the US patent US4395582 also describes a solar converter comprising a substrate doped with photoactive combinations called “light cascades”, to improve the quality of the light spectrum illuminating the photoelectric cells.
- the object of the invention is to provide an improved photovoltaic generator, having a high efficiency for a small footprint.
- the invention relates, in its most general sense, to a photovoltaic generator comprising at least one photovoltaic cell and a transparent matrix deposited with at least one optically active material having an absorption wavelength ⁇ a and a length d re-emission wave ⁇ r , the optically active material being chosen so that ⁇ a corresponds to a range of lower sensitivity of the photovoltaic cell than ⁇ r , the matrix comprising a reflective coating, characterized in that the matrix present on the surface input a dichroic filter substantially reflecting wavelengths greater than about 950 nm, and substantially transparent for wavelengths less than 950 nm, and on the surface opposite to the input surface a reflective coating for the lengths wave greater than 400 nm, the photovoltaic cell being included in the transparent matrix.
- the matrix is formed by a strip of polymethyl methacrylate doped with light cascades.
- the entry surface of the matrix is coated with an interference layer having a maximum transmission rate for wavelengths between 330 and 900 nm and a maximum reflection rate for wavelengths greater than 950 nm.
- the surface opposite to the entry surface of the matrix is coated with a diffusing reflecting layer having a maximum reflection rate for wavelengths between 300 and 600 nm, a rate of significant absorption for wavelengths of the order of 600 nm and a significant diffusion rate for wavelengths of approximately 950 nm.
- the lateral zones of the matrix are coated with a reflecting layer.
- the generator according to the invention comprises a plurality of photovoltaic cells arranged in planes substantially perpendicular to the input surface.
- the invention will be better understood on reading the description which follows, referring to the appended drawings where: the single figure represents a perspective view of a second embodiment.
- the single figure shows a sectional view of a generator according to the invention. It consists of a rectangular block (1) forming a transparent polymethyl methacrylate (PMMA) matrix.
- PMMA polymethyl methacrylate
- These light cascades have the effect of mainly absorbing the wavelengths corresponding to the ranges of low sensitivity of the photovoltaic cells, and of high energy of the solar spectrum, and of shifting the energy towards wavelengths corresponding to ranges of high sensitivity of photovoltaic cells.
- absorption takes place between 360 and 600 nm
- re-emission takes place around 600 nm.
- the input surface (2) of the matrix is coated with a dichroic interference filter reflecting radiation of wavelength greater than 950 nm, and transparent for wavelengths between 330 nm and 900 nm.
- the opposite surface (3) as well as the lateral faces (4, 5, 6) are coated with a white reflector having an absorption peak around 600 nm and a reemission peak around 950 nm.
- the matrix (1) also comprises a plurality of photovoltaic cells (7) arranged in planes (8 to 10) perpendicular to the entry surface (2).
- the cells are encapsulated in the matrix at the time of manufacture.
- Such a configuration makes it possible to increase the efficiency of the generator by a factor of 11 compared to a generator according to the state of the art, having an identical input surface.
- the ratio between the input surface SI and the cumulative surface S2 of the photovoltaic cells is of the order of 100.
- the cells are glued to certain lateral faces of the parallelepiped block.
- This dopant may be, for example, a rare earth, in particular a rare earth oxysulfide, and more particularly the product sold under the trade name of "LUMILUX Green UCZ" or the product "LUMILUX IR CD 142" from the company RIEDEL from HA ⁇ N.
Landscapes
- Photovoltaic Devices (AREA)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9904914A FR2792460B1 (fr) | 1999-04-19 | 1999-04-19 | Generateurs photovoltaiques a cascade lumineuse et variation de flux electromagnetique |
FR9904914 | 1999-04-19 | ||
FR9906113A FR2792461B3 (fr) | 1999-04-19 | 1999-05-12 | Generateurs photovoltaiques a cascade lumineuse et variation de flux elecromomagnetique |
FR9906113 | 1999-05-12 | ||
PCT/FR2000/001027 WO2000063975A1 (fr) | 1999-04-19 | 2000-04-19 | Generateurs photovoltaiques a cascade lumineuse et variation de flux electromagnetique |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1186057A1 true EP1186057A1 (de) | 2002-03-13 |
Family
ID=26234920
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00920845A Withdrawn EP1186057A1 (de) | 1999-04-19 | 2000-04-19 | Photovoltaische generatoren mit licht-kaskade und veränderung des elektromagnetischen flusses |
Country Status (4)
Country | Link |
---|---|
US (1) | US6570083B2 (de) |
EP (1) | EP1186057A1 (de) |
FR (1) | FR2792461B3 (de) |
WO (1) | WO2000063975A1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI508314B (zh) * | 2008-12-12 | 2015-11-11 | Koninkl Philips Electronics Nv | 發光光伏打發電機及用於光伏打發電機的波導 |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AUPS123302A0 (en) * | 2002-03-19 | 2002-04-18 | Unisearch Limited | Luminance conversion and application to photovoltaic energy conversion |
US8475033B2 (en) * | 2005-02-16 | 2013-07-02 | Koninklijke Philips Electronics N.V. | Luminescent object comprising aligned polymers having a specific pretilt angle |
WO2007123998A2 (en) * | 2006-04-19 | 2007-11-01 | Massachusetts Institute Of Technology | Light emitting devices |
WO2008110567A1 (en) | 2007-03-13 | 2008-09-18 | Basf Se | Photovoltaic modules with improved quantum efficiency |
US20080257400A1 (en) * | 2007-04-17 | 2008-10-23 | Mignon George V | Holographically enhanced photovoltaic (hepv) solar module |
US20080309217A1 (en) * | 2007-05-18 | 2008-12-18 | Mulder Carlijn L | Organic light emitting devices |
JP2010531067A (ja) * | 2007-06-22 | 2010-09-16 | ウルトラドッツ・インコーポレイテッド | スペクトルコンセントレータの使用で効率が高められたソーラーモジュール |
DE102007045546B3 (de) * | 2007-09-24 | 2009-01-08 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Solarelement mit gesteigerter Effizienz und Verfahren zur Effizienzsteigerung |
EP2203943A4 (de) * | 2007-10-12 | 2015-10-14 | Omnipv Inc | Solarmodule mit vergrösserten wirkungsgraden durch verwendung von spektralen konzentratoren |
US20090229652A1 (en) * | 2008-01-14 | 2009-09-17 | Mapel Jonathan K | Hybrid solar concentrator |
US8304645B2 (en) * | 2008-08-19 | 2012-11-06 | Sabic Innovative Plastics Ip B.V. | Luminescent solar collector |
US8299354B2 (en) * | 2008-08-19 | 2012-10-30 | Sabic Innovative Plastics Ip B.V. | Luminescent solar collector |
US8314325B2 (en) * | 2008-08-19 | 2012-11-20 | Sabic Innovative Plastics Ip B.V. | Luminescent solar collector |
US8304647B2 (en) * | 2008-08-19 | 2012-11-06 | Sabic Innovative Plastics Ip B.V. | Luminescent solar collector |
US20100126566A1 (en) * | 2008-11-21 | 2010-05-27 | Lightwave Power, Inc. | Surface plasmon wavelength converter |
US20100139749A1 (en) * | 2009-01-22 | 2010-06-10 | Covalent Solar, Inc. | Solar concentrators and materials for use therein |
FR2942075B1 (fr) | 2009-02-12 | 2011-08-05 | Physique Du Rayonnement Et De La Lumiere Lprl Lab De | Generateurs opto pv 3d |
EP2224163A1 (de) * | 2009-02-27 | 2010-09-01 | Reddy Solutions | Beleuchtungsanordnung zur Lichtumwandlung und -verteilung |
DE102009002386A1 (de) * | 2009-04-15 | 2010-10-21 | Evonik Degussa Gmbh | Fluoreszenzkonversionssolarzelle - Herstellung im Spritzgussverfahren |
US9929296B1 (en) * | 2009-12-22 | 2018-03-27 | Sunpower Corporation | Edge reflector or refractor for bifacial solar module |
FR2993409B1 (fr) * | 2012-07-16 | 2015-04-10 | Physique Du Rayonnement Et De La Lumiere Lab De | Revetement optiquement actif pour l'amelioration du rendement de conversion photosolaire |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2246078B1 (de) * | 1973-06-15 | 1978-03-17 | Rech Innov Conv Bric Bureau | |
FR2346858A1 (fr) * | 1976-03-31 | 1977-10-28 | Gravisse Philippe | Dispositif amplificateur d'energie rayonnante |
DE2620115C2 (de) * | 1976-05-06 | 1983-08-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V., 8000 München | Vorrichtung zur Umwandlung von Lichtenergie in elektrische Energie |
DE2737847A1 (de) * | 1977-08-23 | 1979-03-08 | Fraunhofer Ges Forschung | Vorrichtung mit lumineszenz-lichtkonzentratoren zur umwandlung von solarenergie |
FR2419525A1 (fr) * | 1978-03-09 | 1979-10-05 | Gravisse Philippe | Concentrateur de rayonnement solaire |
DE2926191A1 (de) * | 1978-07-04 | 1980-01-17 | Yissum Res Dev Co | Sonnenkollektor |
JPS6382326A (ja) * | 1986-09-26 | 1988-04-13 | Kanagawa Pref Gov | 紫外線センサ用素子 |
FR2697352B1 (fr) * | 1992-10-26 | 1995-01-13 | Physique Rayon Lumie Lab | Concentrateur d'énergie électromagnétique à changement de fréquence constituant entre autre une iode électromagnétique. |
WO1995017015A1 (en) * | 1993-12-14 | 1995-06-22 | Citizen Watch Co., Ltd. | Solar battery device |
FR2792460B1 (fr) * | 1999-04-19 | 2001-11-30 | Biocube | Generateurs photovoltaiques a cascade lumineuse et variation de flux electromagnetique |
FR2795248B1 (fr) * | 1999-06-21 | 2004-11-12 | Lprl Laboratoire De Physique D | Source monochromatique comprenant un materiau optiquement actif |
-
1999
- 1999-05-12 FR FR9906113A patent/FR2792461B3/fr not_active Expired - Lifetime
-
2000
- 2000-04-19 EP EP00920845A patent/EP1186057A1/de not_active Withdrawn
- 2000-04-19 WO PCT/FR2000/001027 patent/WO2000063975A1/fr not_active Application Discontinuation
-
2001
- 2001-10-01 US US09/968,274 patent/US6570083B2/en not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO0063975A1 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI508314B (zh) * | 2008-12-12 | 2015-11-11 | Koninkl Philips Electronics Nv | 發光光伏打發電機及用於光伏打發電機的波導 |
Also Published As
Publication number | Publication date |
---|---|
FR2792461B3 (fr) | 2001-06-29 |
FR2792461A1 (fr) | 2000-10-20 |
US20020074035A1 (en) | 2002-06-20 |
WO2000063975A1 (fr) | 2000-10-26 |
US6570083B2 (en) | 2003-05-27 |
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Legal Events
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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17P | Request for examination filed |
Effective date: 20011016 |
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AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
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STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
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18D | Application deemed to be withdrawn |
Effective date: 20021101 |