EP1155635A1 - Assembly for storage and application of a liquid powder - Google Patents
Assembly for storage and application of a liquid powder Download PDFInfo
- Publication number
- EP1155635A1 EP1155635A1 EP01401082A EP01401082A EP1155635A1 EP 1155635 A1 EP1155635 A1 EP 1155635A1 EP 01401082 A EP01401082 A EP 01401082A EP 01401082 A EP01401082 A EP 01401082A EP 1155635 A1 EP1155635 A1 EP 1155635A1
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- EP
- European Patent Office
- Prior art keywords
- assembly
- composition
- applicator
- application
- reservoir
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
- A45D34/04—Appliances specially adapted for applying liquid, e.g. using roller or ball
- A45D34/041—Appliances specially adapted for applying liquid, e.g. using roller or ball using a roller, a disc or a ball
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D34/00—Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
- A45D34/04—Appliances specially adapted for applying liquid, e.g. using roller or ball
- A45D34/042—Appliances specially adapted for applying liquid, e.g. using roller or ball using a brush or the like
- A45D34/045—Appliances specially adapted for applying liquid, e.g. using roller or ball using a brush or the like connected to the cap of the container
- A45D34/046—Appliances specially adapted for applying liquid, e.g. using roller or ball using a brush or the like connected to the cap of the container comprising a wiper
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- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D2200/00—Details not otherwise provided for in A45D
- A45D2200/10—Details of applicators
- A45D2200/1009—Applicators comprising a pad, tissue, sponge, or the like
- A45D2200/1018—Applicators comprising a pad, tissue, sponge, or the like comprising a pad, i.e. a cushion-like mass of soft material, with or without gripping means
Definitions
- the present invention relates to the packaging and distribution of a composition in the form of a powder, as used in particular in the make-up and / or care of the skin and mucous membranes, and particularly in the field of face and skin makeup products, such as eyeshadows, blushes, face powders and body.
- Such powders include a) a "dry" phase or pulverulent, optionally comprising a binder, and generally consisting of base of pigments and / or nacres and / or fillers and / or glitter, and / or mixing them, and b) a phase, which can in particular act as a binding phase, and containing, inside micro-capsules, vesicles, micro-sponges, waxes porous, or any other structure capable of storing a fluid, such as water, propylene glycol, oil, gel, or an O / W or W / O emulsion, and releasing said fluid, especially in response to pressure.
- a fluid such as water, propylene glycol, oil, gel, or an O / W or W / O emulsion
- the whitening powder contains , in addition to the ingredients with a whitening effect, 0.1 to 7% by weight of trimethylsiloxylated silicic acid in anhydrous form, having a specific surface of at least 80 m 2 / g, and a degree of hydrophobicity of at least 50 %.
- the water retained by the silicic acid in anhydrous form is released by spreading and pressing the powder against the surface to be treated, so that the powder literally liquefies.
- Such powders especially when they are in a continuous aqueous phase, moisturize the skin and do not provide a tightening or drying effect. They have an excellent dispersion of pigments.
- the composition obtained is also very homogeneous, and remains so even after application to the skin, and this for several hours.
- compositions also have excellent cosmetic properties: they adhere enough to the skin but not too much; they are very soft, and apply easily. They do not transfer nor do they migrate in the folds of the skin.
- such powders are packaged in a receptacle topped a sieve through which the powder is brought to pass, the sampling by means of an applicator, in the form of a puff, which is put in engagement with the powder on the sieve so as to withdraw the powder.
- an applicator in the form of a puff
- the pulverulent phase tends to "fly" during application.
- the particles containing the fluid can agglomerate with the pulverulent compounds to form a kind of heterogeneous and unstable paste which use as a makeup product is not possible
- an assembly for the conditioning and application of a composition in particular a cosmetic composition
- said composition composition being placed inside a tank and being formed at least in part, of particles containing at least one fluid
- said assembly comprising a applicator formed by a gripping element and an application element with at least part of which the composition in the tank is intended to come in contact, said applicator being configured so that, during a movement, along a substantially predetermined path, of the applicator by report to said reservoir, at least the part of the application element with which the composition has been brought into contact, passes through a compacting member, and comes into engagement with at least a portion of it, the pressure acting between the application element and said portion (s) of the member compaction during said engagement, favoring the anchoring of the composition on said application element.
- the particles containing at least one fluid are particles formed of a hollow or porous structure, capable of storing a certain quantity of said fluid, and to release it, in response to sufficient pressure, corresponding in particular to the pressure resulting from the application of the composition on the surface to be treated.
- both phases forming said particles (“solid” phase forming the container, and the fluid phase contained within the "solid” phase) remain individualized, one being contained within the other.
- the liquid is expelled from the structure that contains it, and is released on the surface to be treated. The liquid thus released can be brought into contact, if necessary, with a powdery phase to promote spreading and staying on the skin.
- the fluid can be contained inside vesicles, micro- or nano-capsules, micro-sponges, microspheres, or any other porous structure.
- the fluid may in particular be water, a gel, an oil, polypropylene glycol, a O / W or W / O emulsion.
- liquid phase the phase consisting of the particles containing the fluid, in whatever form, will be referred to as the "liquid phase".
- the sentence liquid of the composition promotes, if necessary, the attachment of the phase pulverulent on the surface to be treated, and also promotes its spreading. She can be advantageously used as a vehicle for at least one active principle, especially for skin care. It also gives a fresh effect on the skin.
- the pressure applied by the compaction on the application element remains substantially the same throughout of the service life of the system, and can be set to be strong enough to allow adequate anchoring of the product on the applicator, and low enough not to cause early release of the fluid stored.
- this also results in a homogeneous spreading of the composition taken from the effective part of the application element, which spread homogeneous promotes spreading of the product on the surface to be treated, in particular the skin.
- the predetermined path is in a direction other than a direction perpendicular to the application surface, so as to limit the crushing of the powder on the applicator.
- one causes a relative displacement between the compacting member and the application surface, substantially in the plane of the application surface or in a plane tangential to the surface of application.
- said compacting member is fixedly mounted in the vicinity a tank opening.
- the substantially predetermined movement of the applicator relative to the tank can be a rotational movement around an axis, or a movement of translation substantially along an axis.
- the application element is preferably, on at least part of its surface, covered with a flock coating.
- flocking can consist of fibers of cotton or rayon.
- the fibers can be of length and / or of section, and / or different in nature, depending on the application characteristics wanted.
- all or part of said element application is made in particular of closed cell foam, open or semi open, in thermoplastic or vulcanized elastomer, in particular in polyester, polyethylene or polyvinyl chloride elastomer, in sintered form, especially metal or ceramic, or felt.
- the assembly according to the invention is preferably configured so that a volume air is formed between a free surface of the composition, and the compaction.
- the assembly is configured so that, before the first use, the composition occupies only half the height of the container.
- Such a volume makes it possible in particular, by agitating the assembly, to homogenize the product contained in the tank, especially when the product contains particles with different densities, and possibly ensuring bringing the product into contact with the application element in the event that this the latter is not "immersed" in the product.
- the application element is disposed between said free surface of the composition and the compacting member, bringing the application element into contact with the composition made in particular by agitating the whole. This avoids the compacting in the reservoir of the composition by the application element.
- the application element is of cross section circular, and mounted in rotation inside a casing surmounting the reservoir, said casing constituting said compacting member, and having at least two openings, a first opening arranged opposite the tank and through from which, in a first angular position, a segment of the element of application emerges so as to be brought into contact with the composition, said segment of the application element being able to pass from said first position to a second position in which it emerges through a second opening leading to the outside of the tank so as to allow the application of all or part of the composition with which it was put contact in the first position, said first and second openings being separated by at least a portion of the housing with which, passing from the first to second position, said segment is engaged for cause the composition to be applied to all or part of the surface to anchor of said segment.
- the transition from the first to the second position is done by a rotation of the applicator element about an axis perpendicular to its section transverse.
- the applicator can be actuated from the outside by the user.
- the actuating device consists of at least one thumb wheel fixed to one end of the axis of rotation and arranged at least partially at the outside of the housing.
- the compacting member consists of a element formed from at least one foam material, and disposed in the vicinity an opening of the reservoir, said element being traversed by at least one slot or a passage so that it can be crossed by said application element.
- the application element may be integral with a first end of a rod, a second end of the rod, opposite the first being integral with an element able on the one hand to form a gripping member for said application element, and secondly, when said applicator is mounted on the reservoir, to be closed off sealing said opening.
- the edge (s) delimiting said slot or said passage are substantially contiguous.
- said application element in the mounted position of the applicator on the reservoir, said application element is located between the compacting member and a bottom of the tank, preferably between the compacting member and the free surface of the composition, a portion of said rod being disposed in said passage or said slot, said rod being configured so that said rod portion does not compress not sensibly said foam element.
- the foam may be a foam formed at least in part of cells open or semi-open, in particular a foam of an elastomer, in particular polyurethane or polyether.
- the foam comprises so generally at least 5% open cells, cells with a diameter of preferably between 5 ⁇ m and 3 mm.
- the height of the foam block 11 is typically between 1.5 mm and 80 mm.
- the foam block can be stiffened at its periphery and on at least part of its height, in particular to prevent it from compressing during the introduction of the applicator in the container.
- the compacting member can be formed by the union of two half-cylinders full of foam, held against each other by the neck of the container and defining between them a slit which can open when the element passes of application.
- the compacting member can be produced by winding a strip of foam on itself, defining a central recess for the passage of the application element.
- the compacting member can also be made by superimposing several plain foam washers different, made in foams with cell densities increasing as we get closer to the outlet of the container, the whole being traversed by an axial recess for the passage of the application element.
- the compacting member can be retained in many ways in the container.
- the foam block can be simply glued or welded on its periphery to the wall of the container.
- compositions according to the invention preferably comprise a phase pulverulent, mixed with the liquid phase, and can be formed of pigments and / or nacres and / or fillers and / or glitter usually used in cosmetic compositions, and / or their mixtures.
- the particles forming the pulverulent phase can also be coated with a binder.
- pigments we must understand white or colored particles, mineral or organic, insoluble in the medium, intended to color and / or opacify the composition.
- the pigments can be white or colored, mineral and / or organic, of size usual or nanometric. Mention may be made, among the pigments and nanopigments minerals, titanium, zirconium or cerium dioxides, as well as oxides zinc, iron or chromium, nanotitanes, nanozincs, ferric blue. Among the organic pigments, there may be mentioned carbon black, and lacquers such as calcium, barium, aluminum or zirconium salts, dyes acids such as halo-acid, azo or anthraquinone dyes.
- the pigments can in particular be coated with silicone compounds such as as polydimethylsiloxanes and / or by polymers, in particular polyethylenes.
- silicone compounds such as as polydimethylsiloxanes and / or by polymers, in particular polyethylenes.
- the fillers can be mineral or synthetic, lamellar or not lamellar. Mention may be made of talc, mica, silica, kaolin, nylon powders, poly- ⁇ -alanine and polyethylene, Teflon, lauroyl-lysine, starch, nitride boron, bismuth oxychloride, polymer powders tetrafluoroethylene, polymethylmethacrylate powders, powders polyurethane, polystyrene powders, polyester powders, synthetic hollow microspheres such as Expancel (Nobel Industrie), micro sponges such as polytrap (Dow Corning) and resin microbeads silicone (Tospearls from TOSHIBA, for example), zinc oxides and titanium, zirconium or cerium oxides, precipitated calcium carbonate, magnesium carbonate and hydrocarbon, hydroxyapatite, hollow silica microspheres (Silica Beads from the company MAPRECOS), glass or ceramic microcapsules; metallic
- compositions according to the invention can also comprise flakes.
- the powder of the invention can also comprise any additive commonly used in the relevant field of antioxidants, essential oils, preservatives, neutralizers, W / O or O / W surfactants, vitamins, anti-wrinkle active ingredients.
- the fluid in the liquid phase is in the form of water, polypropylene glycol, oils, especially essential oils, gel, especially particles cubic gel, water in oil emulsion (W / O) or oil in water (O / W).
- the fluid can be contained in vesicles or microcapsules, the walls of which are in particular made of epoxy, polyethylene, gelatin or polyester, or in micro sponges or microspheres.
- the fluid can also be contained in porous waxes such as polyacrylates.
- the fluid especially in the case of water, can be contained in a structure anhydrous of the type described in patent application EP-A-0 855 177, to which was previously referred to.
- the phase "liquid” includes an aqueous dispersion of vesicles consisting of lipid phase membrane encapsulating an aqueous phase.
- the vesicles usable according to the present invention can also be provided with a lamellar liquid crystal coating.
- the composition contains at least one active ingredient.
- an asset can be hydrophilic, lipophilic, or a mixture of both.
- the liquid phase represents from 1 to 50%, and preferably from 2 to 30%, and more preferably from 5 to 20% by weight of the composition.
- the applicator assembly shown in Figures 1 to 3 is designated in its together by reference 1. It consists of a tank 2, a casing 3 and a removable cover 4. The casing 3 rotates around a spindle 6 a disc applicator 5.
- the reservoir 2 is a cylinder of almost rectangular cross section by two parallel parallel side walls 21 and forming an opening 99 at its the top part.
- the edge of the tank is provided with a fixing device 22 by breakdown, cooperating with a corresponding device 35 of the casing 3.
- the reservoir contains a powder P for making up the cheeks, of the type described previously.
- the liquid phase comprises wax microcapsules containing water.
- the casing 3 is constituted by an envelope 31 whose side walls are in line with those of tank 2.
- a cylindrical space is provided, of circular section coaxial with the disc applicator 5 and axis 6, having dimensions allowing it to closely fit the shape of the applicator disc 5.
- an interior opening 32 is made which places the reservoir 2 in communication with the inner cylindrical space of the casing 31 of the casing 3.
- This opening 32 includes notches, formed in the flat side walls of the envelope 31, which have a trapezoidal shape. All around the opening 32, the edge 32a has the shape of a bevel inclined from the outside towards the inside.
- the casing 3 has an outer opening 33 of form rectangular.
- these windows 34a, 34b consist of two sections of different diameters, separated by a shoulder, the section of smaller diameter opening into space cylindrical with circular section.
- a device for fixing the cover 4 consisting of a breakdown device 36 cooperating with a device corresponding 41 of the cover 4.
- the applicator disc 5 is, in the embodiment shown in Figures 1 to 3, entirely in flexible, fully flocked foam. It is provided in its center a circular opening 51 for the passage of the axis 6.
- the disc 5 has dimensions such that, when mounted in the casing 3, a segment 52 emerges of the casing 3 through the opening 33 and that a segment 53 of the disc is disposed in the opening 32 to the right of the trapezoidal notches.
- the axis 6 consists of two elements 6a and 6b which fit into each other. Each of these elements is made up of three successive sections decreasing: a dial 61a, 61b of circular cross section, a flange 62a, 62b of circular cross section and a rod 63a, 63b.
- Rod 63a of the element 6a is solid and has, in cross section, a square shape. She fits into the hollow rod 63b which has an imprint having a section square corresponding to that of the rod 63a.
- the fixing of the rod 63a in the rod 63b is done by a double rib system 64a and breakdown groove 64b.
- the flanges 62a and 62b carry axial pins 65a and 65b which sink into the flexible foam constituting the disc 5 and which prevent any relative rotation of the disc 5 relative to axis 6 when the assembly is mounted.
- the flanges 62a and 62b are partially arranged in the section of smaller diameter of the windows 34a and 34b.
- the knobs 61a and 61b are partially arranged at the outside of the windows 34a, 34b in the section of larger diameter of said windows and rest on the shoulder between the two diameter sections different from windows 34a and 34b.
- the cover 4 is fixed on the upper part of the casing 3, so as to protect the segment 52 of the applicator member 5 emerging from the opening 33 of the casing 3; the cover 4 has on its faces extending the parallel walls 21 of the tank 2 of the notches 42 in an arc of circle in which the knobs 61a, 61b in the closed position of the cover 4.
- Set 1 works as follows.
- the user wishes to withdraw for example a powder P contained in the reservoir 2, it removes the cover and returns the assembly 1, or shakes it vigorously, so that the powder P comes in contact with segment 53 of disc 5.
- it turns one of the knobs 61a or 61b by half a turn, in one direction or the other, so that the part of the disc forming the segment 53 takes the place corresponding to the segment 52 in the opening 33.
- the powder is compacted by the edges inclined 32a, between which the disc is driven, then thereafter by the surface inside of the casing 31.
- the product is thus compacted on the applicator 5 and is evenly distributed over segment 53, a small amount of liquid possibly having been released during this compaction on the applicator.
- the pulverulent phase does not fly.
- the user serves as the segment emerging from the casing 3 as an applicator.
- the liquid contained in the wax microcapsules is released, and mixes with the pulverulent phase, which gives an impression of freshness on the skin, and promotes spreading and hold powder on the skin.
- the contact between the disc 5 and the edge of the opening 32 is sufficiently tight so that the powder does not risk escaping from the tank during storage and when returns the assembly to bring the product into contact with segment 53 of the disk.
- FIG. 4 shows a device 100 according to a second example for carrying out the invention.
- This device of axis X, comprises a container 188 and a applicator 189.
- the container 188 is formed by assembling a part lower 190 and an upper part 191.
- the lower part 190 has a central tubular wall 192 closed below by an attached bottom 193 and surmounted by a neck 154.
- the neck 154 ends in a flange 195 forming radially projecting inward.
- the powder P is contained inside the tubular wall 192, and on its surface free disposed substantially halfway up the tubular wall 192.
- the phase powder consists of pigments and fillers for making up lips.
- the liquid phase is formed on the basis of polypropylene glycol retained in wax micro-capsules melting at low temperature.
- the upper part 191 of the container 188 has a central tubular wall 196 extended radially outwards, near its end upper, by an external skirt 197 which is rounded down and on the surface internal of which snaps the external skirt 194 of the lower part 190.
- the tubular central wall 196 then engages sealingly on the neck 154 of the tubular part 192.
- a hoop 198 molded with the upper part 191 of the container, is articulated on the outer skirt 197 by means of bridges of material 199 forming hinges.
- the central tubular wall 196 has, at the connection of the outer skirt 197, a recess 150 inwards, extended upwards by a collar 101 delimiting an opening 121.
- the applicator 189 comprises a gripping member 102, extended downward by a rod 103 provided at its lower end of an application element 104.
- the application element 104 is made of an elastomeric pallet, with an ovoid longitudinal section, and shaped tapered towards its free end. Application element 104 is covered with a flock coating.
- the gripping member 102 is formed by the assembly of an external body 105, of ogival shape, open at its end lower part and an internal part 106 fitted into the external body 105 and having a hollow housing 107 in which a spherical head 108 is retained formed at the upper end of the rod 103, so as to constitute a ball joint.
- the external body 105 of the gripping 102 adjusts to the collar 101.
- the seal on closing is obtained by the tightening of the internal part 106 against the upper end edge of the neck 101.
- the rod 103 of the applicator 189 widens at its lower end 109 to form a housing for fixing the application element 104, consisting in the example described by a felt tip.
- a block of polyurethane foam 110 is housed inside the tubular wall central 196, being retained axially at its lower end by the flange internal 195 and at its upper end by the hook 100.
- the block of foam is traversed by an axial passage 120.
- the user shakes the assembly 100, so as to bring the powder P in contact with the application element 104, arranged at a distance from the free surface of the powder.
- the product is deposited both on the applicator and on the bottom wall foam block 110.
- the element application is brought through the foam block 110, via the passage 120, along a path substantially along the X axis, imposed by the configuration of all. In doing so, the powder present on the application element 110 is pressed between the applicator surface and the foam block, thereby improving the powder hold on the applicator.
- the lower wall of the foam block is driven by the application element 104, and rises in inward part of the foam block, causing transfer to the powder applicator present on said lower face.
- the powder is firmly anchored on the applicator. She does not fly.
- the pressure applied by the applicator on the skin releases the trapped liquid in the micro-capsules of wax, which liquid gives a pleasant feeling of fresh and soft, and helps promote spreading and good hold of the powder on the skin.
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Abstract
Description
La présente invention a trait au conditionnement et à la distribution d'une composition sous forme d'une poudre, telle qu'utilisée notamment dans le domaine du maquillage et/ou du soin de la peau et des muqueuses, et en particulier dans le domaine des produits de maquillage du visage et de la peau, tels que les fards à paupières, les fards à joues, les poudres du visage et du corps.The present invention relates to the packaging and distribution of a composition in the form of a powder, as used in particular in the make-up and / or care of the skin and mucous membranes, and particularly in the field of face and skin makeup products, such as eyeshadows, blushes, face powders and body.
Récemment, sont apparues sur le marché, des poudres qualifiées parfois de "poudres liquides". De telles poudres incluent a) une phase "sèche" ou pulvérulente, comprenant éventuellement un liant, et constituée généralement à base de pigments et/ou de nacres et/ou de charges et/ou de paillettes, et/ou de leur mélange, et b) une phase, pouvant notamment faire office de phase liante, et contenant, à l'intérieur de micro-capsules, vésicules, microéponges, cires poreuses, ou toute autre structure apte à emmagasiner un fluide, tel que de l'eau, du propylène glycol, de l'huile, un gel, ou encore une émulsion H/E ou E/H, et à libérer ledit fluide, notamment en réponse à une pression. A l'application, en étalant et en pressant la poudre contre la peau, par exemple via un applicateur, le liquide contenu dans les vésicules ou micro-capsules est libéré, ce qui provoque une agréable sensation de fraícheur à l'application.Recently, powders sometimes appearing on the market have appeared "liquid powders". Such powders include a) a "dry" phase or pulverulent, optionally comprising a binder, and generally consisting of base of pigments and / or nacres and / or fillers and / or glitter, and / or mixing them, and b) a phase, which can in particular act as a binding phase, and containing, inside micro-capsules, vesicles, micro-sponges, waxes porous, or any other structure capable of storing a fluid, such as water, propylene glycol, oil, gel, or an O / W or W / O emulsion, and releasing said fluid, especially in response to pressure. On application, in spreading and pressing the powder against the skin, for example via an applicator, the liquid in the vesicles or microcapsules is released, causing a pleasant feeling of freshness on application.
Un exemple d'une telle structure apte à emmagasiner de l'eau est décrite dans le contexte d'une poudre blanchissante, faisant l'objet de la demande de brevet EP-A-0 855 177. Selon cette demande, la poudre blanchissante contient, outre les ingrédients à effet blanchissant, 0,1 à 7% en poids d'acide silicique trimethylsiloxylé sous forme anhydre, ayant une surface spécifique d'au moins 80 m2/g, et un degré d'hydrophobicité d'au moins 50%. Ainsi, l'eau retenue par l'acide silicique sous forme anhydre est libérée en étalant et pressant la poudre contre la surface à traiter, de sorte que la poudre se liquéfie littéralement.An example of such a structure capable of storing water is described in the context of a whitening powder, which is the subject of patent application EP-A-0 855 177. According to this request, the whitening powder contains , in addition to the ingredients with a whitening effect, 0.1 to 7% by weight of trimethylsiloxylated silicic acid in anhydrous form, having a specific surface of at least 80 m 2 / g, and a degree of hydrophobicity of at least 50 %. Thus, the water retained by the silicic acid in anhydrous form is released by spreading and pressing the powder against the surface to be treated, so that the powder literally liquefies.
De telles poudres, notamment lorsqu'elles sont à phase aqueuse continue, hydratent la peau et ne procurent pas d'effet de tiraillement ou de dessèchement. Elle présentent une excellente dispersion des pigments. La composition obtenue est en outre très homogène, et elle le reste même après application sur la peau, et ce pendant plusieurs heures.Such powders, especially when they are in a continuous aqueous phase, moisturize the skin and do not provide a tightening or drying effect. They have an excellent dispersion of pigments. The composition obtained is also very homogeneous, and remains so even after application to the skin, and this for several hours.
De telles compositions présentent en outre d'excellentes propriétés cosmétiques : elles adhèrent suffisamment à la peau mais pas trop ; elles sont très douces, et s'appliquent facilement. Elles ne se transfèrent pas et ne migrent pas non plus dans les plis de la peau.Such compositions also have excellent cosmetic properties: they adhere enough to the skin but not too much; they are very soft, and apply easily. They do not transfer nor do they migrate in the folds of the skin.
Un problème qui se pose avec ces poudres tient essentiellement à leur manipulation, et à leur application notamment au moyen d'un applicateur. En effet, avec ce type de poudre, lors du prélèvement de la poudre, la pression exercée par l'applicateur sur le produit ne doit pas trop élevée de manière à ne pas libérer le fluide de manière anticipée. En revanche, elle doit être suffisante pour permettre l'ancrage du produit sur l'applicateur. En outre, un prélèvement dosé du produit ne peut pas se faire. A problem which arises with these powders is essentially due to their handling, and their application in particular by means of an applicator. Indeed, with this type of powder, when removing the powder, the pressure exerted by the applicator on the product should not be too high so as not to release the fluid in advance. However, it must be sufficient to allow anchoring the product on the applicator. In addition, a metered sample of the product does not can't be done.
Typiquement, de telles poudres sont conditionnées dans un réceptacle surmonté d'un tamis au travers de laquelle la poudre est amenée à passer, le prélèvement se faisant au moyen d'un applicateur, sous forme d'une houppette, qui est mis en engagement avec la poudre sur le tamis de manière à prélever la poudre. En raison de la difficulté à doser la pression exercée sur la poudre via l'applicateur, il se produit souvent un compactage de la poudre sur le tamis, provoquant un encrassement des pores de ce dernier.Typically, such powders are packaged in a receptacle topped a sieve through which the powder is brought to pass, the sampling by means of an applicator, in the form of a puff, which is put in engagement with the powder on the sieve so as to withdraw the powder. In because of the difficulty in metering the pressure exerted on the powder via the applicator, it compaction of the powder on the sieve often occurs, causing clogging of the pores of the latter.
De plus, la phase pulvérulente a tendance à "voler" lors de l'application.In addition, the pulverulent phase tends to "fly" during application.
Enfin, lorsque le prélèvement d'une telle composition s'effectue dans certaines conditions, les particules contenant le fluide peuvent s'agglomérer avec les composés pulvérulents pour former une sorte de pâte hétérogène et instable dont l'utilisation en tant que produit de maquillage est impossibleFinally, when the withdrawal of such a composition is carried out in certain conditions, the particles containing the fluid can agglomerate with the pulverulent compounds to form a kind of heterogeneous and unstable paste which use as a makeup product is not possible
Aussi, est-ce un des objets de l'invention que de réaliser un ensemble de conditionnement et d'application d'une composition formée au moins en partie de particules contenant un fluide, et résolvant en tout ou partie, les problèmes discutés ci-avant en référence à certains dispositifs conventionnels,It is therefore one of the objects of the invention to produce a set of conditioning and application of a composition formed at least in part from particles containing a fluid, and solving all or part of the problems discussed above with reference to certain conventional devices,
C'est en particulier un objet de l'invention que de fournir un tel ensemble qui permette une application aisée, dosée et homogène d'un tel produit, évitant notamment les phénomènes de compactage ou de libération anticipée du fluide, évoqués ci-avant.It is in particular an object of the invention to provide such an assembly which allows easy, metered and homogeneous application of such a product, avoiding in particular the phenomena of compaction or early release of the fluid, mentioned above.
D'autres objets encore apparaítront dans la description détaillée qui suit.Still other objects will appear in the detailed description which follows.
De manière tout à fait inattendue, la demanderesse a découvert que lorsqu'une telle composition était conditionnée et distribuée au moyen d'un ensemble présentant des caractéristiques particulières, la manipulation d'une telle composition, et en particulier son prélèvement et son étalement, se fait de manière beaucoup plus satisfaisante.Quite unexpectedly, the plaintiff discovered that when a such composition was packaged and distributed by means of a set having particular characteristics, the handling of such composition, and in particular its sampling and spreading, is done so much more satisfying.
Selon l'invention, ces objets sont atteints en réalisant un ensemble pour le conditionnement et l'application d'une composition, notamment cosmétique, ladite composition étant disposée à l'intérieur d'un réservoir et étant formée au moins en partie, de particules contenant au moins un fluide, ledit ensemble comprenant un applicateur formé d'un élément de préhension et d'un élément d'application avec au moins une partie duquel la composition dans le réservoir est destinée à venir en contact, ledit applicateur étant configuré de telle sorte que, lors d'un mouvement, selon un trajet sensiblement prédéterminé, de l'applicateur par rapport audit réservoir, au moins la partie de l'élément d'application avec laquelle la composition a été mise en contact, traverse un organe de compactage, et vienne en engagement avec au moins une portion de ce dernier, la pression s'exerçant entre l'élément d'application et ladite (ou lesdites) portion(s) de l'organe de compactage lors de ladite mise en engagement, favorisant l'ancrage de la composition sur ledit élément d'application. According to the invention, these objects are achieved by producing an assembly for the conditioning and application of a composition, in particular a cosmetic composition, said composition composition being placed inside a tank and being formed at least in part, of particles containing at least one fluid, said assembly comprising a applicator formed by a gripping element and an application element with at least part of which the composition in the tank is intended to come in contact, said applicator being configured so that, during a movement, along a substantially predetermined path, of the applicator by report to said reservoir, at least the part of the application element with which the composition has been brought into contact, passes through a compacting member, and comes into engagement with at least a portion of it, the pressure acting between the application element and said portion (s) of the member compaction during said engagement, favoring the anchoring of the composition on said application element.
Selon la présente invention, les particules contenant au moins un fluide sont des particules formées d'une structure creuse ou poreuse, apte à emmagasiner une certaine quantité dudit fluide, et à le libérer, en réponse à une pression suffisante, correspondant notamment à la pression résultant de l'application de la composition sur la surface à traiter. En d'autres termes, dans le réservoir qui les contient (éventuellement en mélange avec une phase pulvérulente), les deux phases formant lesdites particules (phase "solide" formant le contenant, et la phase fluide contenue à l'intérieur de la phase "solide") restent individualisées, l'une étant contenue à l'intérieur de l'autre. En revanche, en réponse à ladite pression, le liquide est chassé de la structure qui le contient, et est libéré sur la surface à traiter. Le liquide ainsi libéré peut être mis en contact, le cas échéant, avec une phase pulvérulente pour en favoriser l'étalement et la tenue sur la peau.According to the present invention, the particles containing at least one fluid are particles formed of a hollow or porous structure, capable of storing a certain quantity of said fluid, and to release it, in response to sufficient pressure, corresponding in particular to the pressure resulting from the application of the composition on the surface to be treated. In other words, in the reservoir that contains (possibly mixed with a pulverulent phase), both phases forming said particles ("solid" phase forming the container, and the fluid phase contained within the "solid" phase) remain individualized, one being contained within the other. However, in response to said pressure, the liquid is expelled from the structure that contains it, and is released on the surface to be treated. The liquid thus released can be brought into contact, if necessary, with a powdery phase to promote spreading and staying on the skin.
Le fluide peut être contenu à l'intérieur de vésicules, de micro- ou nano-capsules, de microéponges, de microsphères, ou toute autre structure poreuse. Le fluide peut être notamment de l'eau, un gel, une huile, du polypropylène glycol, une émulsion H/E ou E/H.The fluid can be contained inside vesicles, micro- or nano-capsules, micro-sponges, microspheres, or any other porous structure. The fluid may in particular be water, a gel, an oil, polypropylene glycol, a O / W or W / O emulsion.
Dans la suite de la description, la phase constituée des particules contenant le fluide, sous quelque forme que ce soit, sera qualifiée de "phase liquide". La phase liquide de la composition favorise, le cas échéant, l'accrochage de la phase pulvérulente sur la surface à traiter, et en favorise également l'étalement. Elle peut être utilisée avantageusement comme véhicule d'au moins un principe actif, notamment pour le soin de la peau. Elle permet en outre de conférer un effet frais sur la peau.In the following description, the phase consisting of the particles containing the fluid, in whatever form, will be referred to as the "liquid phase". The sentence liquid of the composition promotes, if necessary, the attachment of the phase pulverulent on the surface to be treated, and also promotes its spreading. She can be advantageously used as a vehicle for at least one active principle, especially for skin care. It also gives a fresh effect on the skin.
Du trajet prédéterminé de l'élément d'application traversant l'organe de compactage applicateur, il résulte que la pression appliquée par l'organe de compactage sur l'élément d'application reste sensiblement la même tout au long de la durée de vie du système, et peut être paramétrée de manière à être suffisamment forte pour permettre un ancrage adéquat du produit sur l'applicateur, et suffisamment faible pour ne pas provoquer de libération anticipée du fluide emmagasiné. Au passage de l'élément d'application au travers de l'organe de compactage, il en résulte en outre un étalement homogène de la composition prélevée sur la partie effective de l'élément d'application, lequel étalement homogène favorise l'étalement du produit sur la surface à traiter, notamment la peau.Of the predetermined path of the applicator element passing through the compaction of the applicator, it follows that the pressure applied by the compaction on the application element remains substantially the same throughout of the service life of the system, and can be set to be strong enough to allow adequate anchoring of the product on the applicator, and low enough not to cause early release of the fluid stored. When the applicator element passes through the compaction, this also results in a homogeneous spreading of the composition taken from the effective part of the application element, which spread homogeneous promotes spreading of the product on the surface to be treated, in particular the skin.
De préférence, le trajet prédéterminé est de direction autre qu'une direction perpendiculaire à la surface d'application, de manière à limiter l'écrasement de la poudre sur l'applicateur. Ainsi, de préférence, on provoque un déplacement relatif entre l'organe de compactage et la surface d'application, sensiblement dans le plan de la surface d'application ou dans un plan tangentiel à la surface d'application.Preferably, the predetermined path is in a direction other than a direction perpendicular to the application surface, so as to limit the crushing of the powder on the applicator. Thus, preferably, one causes a relative displacement between the compacting member and the application surface, substantially in the plane of the application surface or in a plane tangential to the surface of application.
Avantageusement, ledit organe de compactage est monté fixement au voisinage d'une ouverture du réservoir. Advantageously, said compacting member is fixedly mounted in the vicinity a tank opening.
Le mouvement sensiblement prédéterminé de l'applicateur par rapport au réservoir peut être un mouvement de rotation autour d'un axe, ou un mouvement de translation sensiblement le long d'un axe.The substantially predetermined movement of the applicator relative to the tank can be a rotational movement around an axis, or a movement of translation substantially along an axis.
L'élément d'application est de préférence, sur au moins une partie de sa surface, recouvert d'un revêtement de flocage. Un tel flocage peut être constitué de fibres de coton ou de rayonne. Les fibres peuvent être de longueur et/ou de section, et/ou de nature différentes, en fonction des caractéristiques d'application recherchée.The application element is preferably, on at least part of its surface, covered with a flock coating. Such flocking can consist of fibers of cotton or rayon. The fibers can be of length and / or of section, and / or different in nature, depending on the application characteristics wanted.
Selon un mode de réalisation avantageux, tout ou partie dudit élément d'application est réalisé notamment en mousse à cellules fermées, ouvertes ou semi ouvertes, en élastomère thermoplastique ou vulcanisé, notamment en élastomère de polyester, de polyéthylène ou de chlorure de polyvinyle, en fritté, notamment de métal ou de céramique, ou en feutre.According to an advantageous embodiment, all or part of said element application is made in particular of closed cell foam, open or semi open, in thermoplastic or vulcanized elastomer, in particular in polyester, polyethylene or polyvinyl chloride elastomer, in sintered form, especially metal or ceramic, or felt.
L'ensemble selon l'invention est de préférence configuré de sorte qu'un volume d'air soit formé entre une surface libre de la composition, et l'organe de compactage. A titre indication, l'ensemble est configuré de sorte que, avant la première utilisation, la composition occupe seulement la moitié de la hauteur du récipient. Un tel volume permet notamment, en agitant l'ensemble, d'homogénéiser le produit contenu dans le réservoir, notamment lorsque le produit contient des particules ayant des densités différentes, et éventuellement d'assurer la mise en contact du produit avec l'élément d'application dans l'hypothèse où ce dernier n'est pas "immergé" dans le produit.The assembly according to the invention is preferably configured so that a volume air is formed between a free surface of the composition, and the compaction. As an indication, the assembly is configured so that, before the first use, the composition occupies only half the height of the container. Such a volume makes it possible in particular, by agitating the assembly, to homogenize the product contained in the tank, especially when the product contains particles with different densities, and possibly ensuring bringing the product into contact with the application element in the event that this the latter is not "immersed" in the product.
De préférence, dans une position montée de l'applicateur sur le réservoir, l'élément d'application est disposé entre ladite surface libre de la composition et l'organe de compactage, la mise en contact de l'élément d'application avec la composition se faisant notamment en agitant l'ensemble. On évite ainsi le compactage dans le réservoir de la composition par l'élément d'application.Preferably, in a position mounted by the applicator on the reservoir, the application element is disposed between said free surface of the composition and the compacting member, bringing the application element into contact with the composition made in particular by agitating the whole. This avoids the compacting in the reservoir of the composition by the application element.
Selon un mode de réalisation, l'élément d'application est de section transversale circulaire, et monté en rotation à l'intérieur d'un carter surmontant le réservoir, ledit carter constituant ledit organe de compactage, et présentant au moins deux ouvertures, une première ouverture disposée en regard du réservoir et au travers de laquelle, dans une première position angulaire, un segment de l'élément d'application émerge de manière à être mis en contact avec la composition, ledit segment de l'élément d'application étant apte à passer de ladite première position à une seconde position dans laquelle il émerge au travers d'une seconde ouverture débouchant sur l'extérieur du réservoir de manière à permettre l'application de tout ou partie de la composition avec laquelle il a été mis au contact dans la première position, lesdites première et seconde ouvertures étant séparées par au moins une portion du carter avec laquelle, en passant de la première à la seconde position, ledit segment est mis en engagement pour provoquer l'ancrage de la composition à appliquer sur tout ou partie de la surface dudit segment.According to one embodiment, the application element is of cross section circular, and mounted in rotation inside a casing surmounting the reservoir, said casing constituting said compacting member, and having at least two openings, a first opening arranged opposite the tank and through from which, in a first angular position, a segment of the element of application emerges so as to be brought into contact with the composition, said segment of the application element being able to pass from said first position to a second position in which it emerges through a second opening leading to the outside of the tank so as to allow the application of all or part of the composition with which it was put contact in the first position, said first and second openings being separated by at least a portion of the housing with which, passing from the first to second position, said segment is engaged for cause the composition to be applied to all or part of the surface to anchor of said segment.
Un tel dispositif est décrit en détail dans le brevet français FR 2 701 364. Such a device is described in detail in
Avantageusement, le passage de la première à la seconde position se fait par une rotation de l'élément d'application autour d'un axe perpendiculaire à sa section transversale. L'applicateur peut être actionné de l'extérieur par l'utilisateur. de préférence, le dispositif d'actionnement est constitué par au moins une molette fixée à une extrémité de l'axe de rotation et disposée au moins partiellement à l'extérieur du carter.Advantageously, the transition from the first to the second position is done by a rotation of the applicator element about an axis perpendicular to its section transverse. The applicator can be actuated from the outside by the user. of preferably, the actuating device consists of at least one thumb wheel fixed to one end of the axis of rotation and arranged at least partially at the outside of the housing.
Selon un autre mode de réalisation, l'organe de compactage est constitué d'un élément formé à partir d'au moins un matériau en mousse, et disposé au voisinage d'une ouverture du réservoir, ledit élément étant traversé par au moins une fente ou un passage de manière à pouvoir être traversé par ledit élément d'application. Un tel dispositif est décrit en détail dans la demande de brevet WO 97/31553.According to another embodiment, the compacting member consists of a element formed from at least one foam material, and disposed in the vicinity an opening of the reservoir, said element being traversed by at least one slot or a passage so that it can be crossed by said application element. Such a device is described in detail in patent application WO 97/31553.
L'élément d'application peut être solidaire d'une première extrémité d'une tige, une seconde extrémité de la tige, opposée à la première étant solidaire d'un élément apte d'une part à former un organe de préhension pour ledit élément d'application, et d'autre part, lorsque ledit applicateur est monté sur le réservoir, à obturer de manière étanche ladite ouverture.The application element may be integral with a first end of a rod, a second end of the rod, opposite the first being integral with an element able on the one hand to form a gripping member for said application element, and secondly, when said applicator is mounted on the reservoir, to be closed off sealing said opening.
De préférence, en l'absence de l'applicateur, le (ou les) bord(s) délimitant ladite fente ou ledit passage sont sensiblement jointifs.Preferably, in the absence of the applicator, the edge (s) delimiting said slot or said passage are substantially contiguous.
De préférence encore, en position montée de l'applicateur sur le réservoir, ledit élément d'application se situe entre l'organe de compactage et un fond du réservoir, de préférence entre l'organe de compactage et la surface libre de la composition, une portion de ladite tige étant disposée dans ledit passage ou ladite fente, ladite tige étant configurée de sorte que ladite portion de tige ne comprime pas de manière sensible ledit élément en mousse.More preferably still, in the mounted position of the applicator on the reservoir, said application element is located between the compacting member and a bottom of the tank, preferably between the compacting member and the free surface of the composition, a portion of said rod being disposed in said passage or said slot, said rod being configured so that said rod portion does not compress not sensibly said foam element.
La mousse est peut être une mousse formée au moins en partie de cellules ouvertes ou semi ouvertes, notamment une mousse d'un élastomère, notamment de polyuréthane ou de polyéther. De préférence, la mousse comporte de façon générale au moins 5% de cellules ouvertes, les cellules ayant un diamètre de préférence compris entre 5 µm et 3 mm. La hauteur du bloc de mousse 11 est typiquement comprise entre 1,5 mm et 80 mm.The foam may be a foam formed at least in part of cells open or semi-open, in particular a foam of an elastomer, in particular polyurethane or polyether. Preferably, the foam comprises so generally at least 5% open cells, cells with a diameter of preferably between 5 µm and 3 mm. The height of the foam block 11 is typically between 1.5 mm and 80 mm.
Le bloc de mousse peut être rigidifié à sa périphérie et sur au moins une partie de sa hauteur, notamment pour l'empêcher de se comprimer lors de l'introduction de l'applicateur dans le récipient.The foam block can be stiffened at its periphery and on at least part of its height, in particular to prevent it from compressing during the introduction of the applicator in the container.
L'organe de compactage peut être formé par la réunion de deux demi-cylindres pleins en mousse, maintenus l'un contre l'autre par le col du récipient et définissant entre eux une fente pouvant s'ouvrir au passage de l'élément d'application .The compacting member can be formed by the union of two half-cylinders full of foam, held against each other by the neck of the container and defining between them a slit which can open when the element passes of application.
En variante encore, l'organe de compactage peut être réalisé par l'enroulement d'une bande de mousse sur elle-même, définissant un évidement central pour le passage de l'élément d'application. L'organe de compactage peut également être réalisé par la superposition de plusieurs rondelles en mousses de natures différentes, réalisées dans des mousses présentant des densités de cellules croissantes à mesure que l'on se rapproche de la sortie du récipient, l'ensemble étant traversé par un évidement axial pour le passage de l'élément d'application.In another variant, the compacting member can be produced by winding a strip of foam on itself, defining a central recess for the passage of the application element. The compacting member can also be made by superimposing several plain foam washers different, made in foams with cell densities increasing as we get closer to the outlet of the container, the whole being traversed by an axial recess for the passage of the application element.
L'organe de compactage peut être retenu de nombreuses manières dans le récipient. Le bloc de mousse peut être simplement collé ou soudé à sa périphérie à la paroi du récipient.The compacting member can be retained in many ways in the container. The foam block can be simply glued or welded on its periphery to the wall of the container.
Les compositions selon l'invention comprennent de préférence une phase pulvérulente, en mélange avec la phase liquide, et pouvant être formée de pigments et/ou de nacres et/ou de charges et/ou de paillettes habituellement utilisés dans les compositions cosmétiques, et/ou de leurs mélanges. Les particules formant la phase pulvérulente peuvent en outre être enrobées d'un liant.The compositions according to the invention preferably comprise a phase pulverulent, mixed with the liquid phase, and can be formed of pigments and / or nacres and / or fillers and / or glitter usually used in cosmetic compositions, and / or their mixtures. The particles forming the pulverulent phase can also be coated with a binder.
Par pigments, il faut comprendre des particules blanches ou colorées, minérales ou organiques, insolubles dans le milieu, destinées à colorer et/ou opacifier la composition.By pigments, we must understand white or colored particles, mineral or organic, insoluble in the medium, intended to color and / or opacify the composition.
Les pigments peuvent blancs ou colorés, minéraux et/ou organiques, de taille usuelle ou nanométrique. On peut citer, parmi les pigments et les nanopigments minéraux, les dioxydes de titane, de zirconium ou de cérium, ainsi que les oxydes de zinc, de fer ou de chrome, les nanotitanes, les nanozincs, le bleu ferrique. Parmi les pigments organiques, on peut citer le noir de carbone, et les laques comme les sels de calcium, de baryum, d'aluminium ou de zirconium, de colorants acides tels que les colorants halogéno-acides, azoïques ou anthraquinoniques.The pigments can be white or colored, mineral and / or organic, of size usual or nanometric. Mention may be made, among the pigments and nanopigments minerals, titanium, zirconium or cerium dioxides, as well as oxides zinc, iron or chromium, nanotitanes, nanozincs, ferric blue. Among the organic pigments, there may be mentioned carbon black, and lacquers such as calcium, barium, aluminum or zirconium salts, dyes acids such as halo-acid, azo or anthraquinone dyes.
Les pigments peuvent notamment être enrobés par des composés siliconés tels que des polydiméthylsiloxanes et/ou par des polymères, notamment des polyéthylènes. On peut ainsi citer les pigments SA ou SI vendus par la société Maprecos.The pigments can in particular be coated with silicone compounds such as as polydimethylsiloxanes and / or by polymers, in particular polyethylenes. We can thus cite the pigments SA or SI sold by the company Maprecos.
Par charges, il faut comprendre des particules incolores ou blanches, minérales ou de synthèse, lamellaires ou non lamellaires, destinées à donner du corps ou de la rigidité à la composition, et/ou de la douceur, de la matité et de l'uniformité au maquillage.By charges, it is necessary to understand colorless or white, mineral particles or synthetic, lamellar or non-lamellar, intended to give body or stiffness in composition, and / or softness, mattness and uniformity in makeup.
Les charges peuvent être minérales ou de synthèse, lamellaires ou non lamellaires. On peut citer le talc, le mica, la silice, le kaolin, les poudres de Nylon, de poly-β-alanine et de polyéthylène, le Téflon, la lauroyl-lysine, l'amidon, le nitrure de bore, l'oxychlorure de bismuth, les poudres de polymères de tétrafluoroéthylène, les poudres de polyméthylméthacrylate, les poudres de polyuréthanne, les poudres de polystyrène, les poudres de polyester, les microsphères creuses synthétiques telles que l'Expancel (Nobel Industrie), les microéponges comme le polytrap (Dow Corning) et les microbilles de résine de silicone (Tospearls de la Société TOSHIBA, par exemple), les oxydes de zinc et de titane, les oxydes de zirconium ou de cérium, le carbonate de calcium précipité, le carbonate et l'hydrocarbonate de magnésium, l'hydroxyapatite, les microsphères de silice creuses (Silica Beads de la Société MAPRECOS), les microcapsules de verre ou de céramique ; les savons métalliques dérivés d'acides organiques carboxyliques ayant de 8 à 22 atomes de carbone, de préférence de 12 à 18 atomes de carbone, par exemple le stéarate de zinc, de magnésium ou de lithium, le laurate de zinc, le myristate de magnésium.The fillers can be mineral or synthetic, lamellar or not lamellar. Mention may be made of talc, mica, silica, kaolin, nylon powders, poly-β-alanine and polyethylene, Teflon, lauroyl-lysine, starch, nitride boron, bismuth oxychloride, polymer powders tetrafluoroethylene, polymethylmethacrylate powders, powders polyurethane, polystyrene powders, polyester powders, synthetic hollow microspheres such as Expancel (Nobel Industrie), micro sponges such as polytrap (Dow Corning) and resin microbeads silicone (Tospearls from TOSHIBA, for example), zinc oxides and titanium, zirconium or cerium oxides, precipitated calcium carbonate, magnesium carbonate and hydrocarbon, hydroxyapatite, hollow silica microspheres (Silica Beads from the company MAPRECOS), glass or ceramic microcapsules; metallic soaps derived from acids carboxylic organic having from 8 to 22 carbon atoms, preferably of 12 to 18 carbon atoms, for example zinc stearate, magnesium or lithium, zinc laurate, magnesium myristate.
Par nacres, il faut comprendre des particules irisées qui réfléchissent la lumière.By pearlescent, we must understand iridescent particles that reflect light.
Parmi les nacres envisageables, on peut citer la nacre naturelle, le mica recouvert d'oxyde de titane, d'oxyde de fer, de pigment naturel ou d'oxychlorure de bismuth ainsi que le mica titane coloré.Among the possible nacres, one can cite natural mother-of-pearl, covered mica titanium oxide, iron oxide, natural pigment or bismuth oxychloride as well as colored titanium mica.
Les compositions selon l'invention peuvent également comprendre des paillettes.The compositions according to the invention can also comprise flakes.
La poudre de l'invention peut comprendre, en outre, tout additif usuellement utilisé dans le domaine concerné des antioxydants, des huiles essentielles, des conservateurs, des neutralisants, des tensio-actifs E/H ou H/E, des vitamines, des actifs antirides.The powder of the invention can also comprise any additive commonly used in the relevant field of antioxidants, essential oils, preservatives, neutralizers, W / O or O / W surfactants, vitamins, anti-wrinkle active ingredients.
Le fluide contenu dans la phase liquide est sous forme d'eau, de polypropylène glycol, d'huiles, notamment d'huiles essentielles, de gel, notamment des particules de gel cubique, d'émulsion eau dans huile (E/H) ou huile dans eau (H/E).The fluid in the liquid phase is in the form of water, polypropylene glycol, oils, especially essential oils, gel, especially particles cubic gel, water in oil emulsion (W / O) or oil in water (O / W).
Le fluide peut être contenu dans des vésicules ou micro-capsules, dont les parois sont notamment en epoxy, en polyéthylène, en gélatine ou en polyester, ou dans des microéponges ou microsphères. Le fluide peut être également contenu des cires poreuses telles que des polyacrylates.The fluid can be contained in vesicles or microcapsules, the walls of which are in particular made of epoxy, polyethylene, gelatin or polyester, or in micro sponges or microspheres. The fluid can also be contained in porous waxes such as polyacrylates.
Le fluide, notamment lorsqu'il s'agit d'eau, peut être contenu dans une structure anhydre du type de celle décrite dans la demande de brevet EP-A-0 855 177, à laquelle il a été fait référence précédemment. A titre d'exemple encore, la phase "liquide" comprend une dispersion aqueuse de vésicules constituées par une membrane de phase lipidique encapsulant une phase aqueuse. Les vésicules utilisables selon la présente invention peuvent également être pourvus d'un enrobage cristal liquide lamellaire.The fluid, especially in the case of water, can be contained in a structure anhydrous of the type described in patent application EP-A-0 855 177, to which was previously referred to. As another example, the phase "liquid" includes an aqueous dispersion of vesicles consisting of lipid phase membrane encapsulating an aqueous phase. The vesicles usable according to the present invention can also be provided with a lamellar liquid crystal coating.
De préférence, la composition contient au moins un actif. Un tel actif peut être hydrophile, lipophile, ou un mélange des deux.Preferably, the composition contains at least one active ingredient. Such an asset can be hydrophilic, lipophilic, or a mixture of both.
Parmi les différents principes actifs pouvant être incorporés, on peut notamment citer :
- les agents antioxydants ou anti-radicaux libres tels que les protéines et les enzymes, la lactoperoxydase et la lactoferrine, les peptides et leurs dérivés, les séquestrants, les flavonoïdes, la chlorophylline, l'éthoxyquine, la guanosine, les tocophérols et leurs dérivés, le palmitate d'ascorbyle, et le β-carotène, la vitamine E et ses dérivés, la vitamine C et ses dérivés, la vitamine A et ses dérivés,
- les agents hydratants ou humectants tels que l'acide hyaluronique et son sel de sodium, le β-glycérophosphate, le glycérol, le sorbitol, le panthénol,
- les filtres UV tels que les produits commercialisés sous les dénominations de « Eusolex 232 »® par la Société MERCK, de « Parsol 1789 »® et de « Parsol MCX »® par la Société GIVAUDAN-ROURE, de « Mexoryl SX »® par la Société CHIMEX et de « UVINUL T150 »® par la Société BASF,
- les kératolytiques tels que les enzymes protéolytiques, l'acide salicylique et ses dérivés tels que l'acide n-dodécanoyl-5 salicylique, et l'acide rétinoïque et ses dérivés,
- les accélérateurs de bronzage tels que la caféine, et les dérivés de tyrosine tels que le tyrosinate de glucose et le sel disodique de la N-L-malyl tyrosine,
- les dépigmentants tels que l'acide kojique, l'acide glycolique, la vitamine C et notamment l'ascorbyle phosphate de magnésium, et l'arbutine et ses dérivés,
- les colorants naturels tels que les matières colorantes extraites de végétaux comme la chlorophylline et le β-carotène ou extraites d'animaux comme le carmin de cochenille, et le caramel,
- les auto-bronzants tels que la dihydroxyacétone, et les indoles,
- les liporégulateurs tels que le γ-orizanol, l'extrait de Centella asiatica contenant de la génine et de l'acide asiatique, la caféine, et la théophylline,
- les agents anti-vieillissement et anti-rides tels que les hydroxyacides comme l'acide glycolique, l'acide n-octanoyl salicylique, le rétinol et ses dérivés comme l'acétate, le palmitate et le propionate de rétinol, et les rétinoïdes,
- les agents anti-inflammatoires et cicatrisants tels que l'acide 18 β-glycyrrhétinique et ses sels comme notamment son sel d'ammonium, l'α-bisabolol, les corticoïdes, l'extrait de Centella asiatica, l'aloe vera
- les antibactériens et antifongiques tels que le chlorure de benzalkonium, la chlorhexidine, l'hexetidine, et l'hexamidine,
- les insectifuges tels que les diéthyl et diméthyltoluamides,
- les déodorants tels que l'hexachlorophène, et le triclosan produit commercialisé sous la dénomination de « Irgasan DP 300 »® par la Société CIBAGEIGY.
- les agents conditionneurs pour peau tels que les polymères cationiques et les cations.
- antioxidants or anti-free radical agents such as proteins and enzymes, lactoperoxidase and lactoferrin, peptides and their derivatives, sequestrants, flavonoids, chlorophyllin, ethoxyquin, guanosine, tocopherols and their derivatives, ascorbyle palmitate, and β-carotene, vitamin E and its derivatives, vitamin C and its derivatives, vitamin A and its derivatives,
- moisturizing or humectants such as hyaluronic acid and its sodium salt, β-glycerophosphate, glycerol, sorbitol, panthenol,
- UV filters such as the products marketed under the names of "Eusolex 232" ® by the company MERCK, of "Parsol 1789" ® and of "Parsol MCX" ® by the company GIVAUDAN-ROURE, of "Mexoryl SX" ® by the CHIMEX and "UVINUL T150" ® by BASF,
- keratolytics such as proteolytic enzymes, salicylic acid and its derivatives such as n-dodecanoyl-5 salicylic acid, and retinoic acid and its derivatives,
- tanning accelerators such as caffeine, and tyrosine derivatives such as glucose tyrosinate and the disodium salt of NL-malyl tyrosine,
- depigmenters such as kojic acid, glycolic acid, vitamin C and in particular magnesium ascorbyle phosphate, and arbutin and its derivatives,
- natural dyes such as coloring matters extracted from plants such as chlorophyllin and β-carotene or extracted from animals such as cochineal carmine, and caramel,
- self-tanners such as dihydroxyacetone, and indoles,
- liporegulators such as γ-orizanol, Centella asiatica extract containing genine and Asian acid, caffeine, and theophylline,
- anti-aging and anti-wrinkle agents such as hydroxy acids such as glycolic acid, n-octanoyl salicylic acid, retinol and its derivatives such as acetate, palmitate and retinol propionate, and retinoids,
- anti-inflammatory and healing agents such as 18 β-glycyrrhetinic acid and its salts such as in particular its ammonium salt, α-bisabolol, corticoids, Centella asiatica extract , aloe vera
- antibacterials and antifungals such as benzalkonium chloride, chlorhexidine, hexetidine, and hexamidine,
- insect repellents such as diethyl and dimethyltoluamides,
- deodorants such as hexachlorophene, and triclosan product marketed under the name of "Irgasan DP 300" ® by the company CIBAGEIGY.
- skin conditioning agents such as cationic polymers and cations.
A titre indicatif, la phase liquide représente de 1 à 50%, et de préférence de 2 à 30%, et de préférence encore de 5 à 20% en poids de la composition.As an indication, the liquid phase represents from 1 to 50%, and preferably from 2 to 30%, and more preferably from 5 to 20% by weight of the composition.
L'invention consiste, mises à part les dispositions exposées ci-dessus, en un certain nombre d'autres dispositions qui seront explicitées ci-après, à propos d'exemples de réalisation non limitatifs, décrits en référence aux figures annexées, parmi lesquelles :
- les figures 1-3 illustrent un ensemble selon un premier mode de réalisation de l'invention ; et
- la figure 4 illustre un ensemble selon un second mode de réalisation de l'invention.
- Figures 1-3 illustrate an assembly according to a first embodiment of the invention; and
- FIG. 4 illustrates an assembly according to a second embodiment of the invention.
L'ensemble applicateur représenté sur les figures 1 à 3 est désigné dans son
ensemble par la référence 1. Il se compose d'un réservoir 2, d'un carter 3 et d'un
couvercle amovible 4. Le carter 3 porte à rotation autour d'un axe 6 un disque
applicateur 5. Le réservoir 2 est un cylindre de section quasi rectangulaire limité
par deux parois latérales parallèles planes 21 et formant une ouverture 99 à sa
partie supérieure. Le bord du réservoir est muni d'un dispositif de fixation 22 par
claquage, coopérant avec un dispositif 35 correspondant du carter 3. Le réservoir
contient une poudre P pour le maquillage des joues, du type de celles décrites
précédemment. Dans cet exemple particulier, la phase liquide comprend des
micro-capsules de cire contenant de l'eau. The applicator assembly shown in Figures 1 to 3 is designated in its
together by reference 1. It consists of a
Le carter 3 est constitué par une enveloppe 31 dont les parois latérales
extérieures sont dans le prolongement de celles du réservoir 2 . Dans ce carter 3
est ménagé un espace cylindrique, à section circulaire coaxial avec le disque
applicateur 5 et l'axe 6, ayant des dimensions lui permettant d'épouser étroitement
la forme du disque applicateur 5. Sur le bord inférieur de l'enveloppe 31 du carter,
est ménagée une ouverture 32 intérieure qui met le réservoir 2 en communication
avec l'espace cylindrique intérieur de l'enveloppe 31 du carter 3. Cette ouverture
32 comporte des échancrures, ménagées dans les parois latérales planes de
l'enveloppe 31, qui ont une forme trapézoïdale. Sur tout le pourtour de l'ouverture
32, le bord 32a a la forme d'un biseau incliné de l'extérieur vers l'intérieur. A sa
partie supérieure, le carter 3 présente une ouverture 33 extérieure de forme
rectangulaire. Dans l'enveloppe 31 sont ménagées deux fenêtres circulaires 34a
et 34b pour le passage et la fixation de l'axe de rotation 6 du disque applicateur 5,
comme expliqué ci-après. A l'intérieur de la paroi de l'enveloppe 31, ces fenêtres
34a, 34b sont constituées de deux sections de diamètres différents, séparées par
un épaulement, la section de plus faible diamètre débouchant dans l'espace
cylindrique à section circulaire. Sur la partie supérieure du carter, autour de
l'ouverture extérieure 33, est prévu un dispositif de fixation du couvercle 4
constitué d'un dispositif de claquage 36 coopérant avec un dispositif
correspondant 41 du couvercle 4.The
Le disque applicateur 5 est, dans le mode de réalisation représenté aux figures 1
à 3, entièrement en mousse souple entièrement floquée. Il est muni en son centre
d'une ouverture circulaire 51 pour le passage de l'axe 6. Le disque 5 a des
dimensions telles que, lorsqu'il est monté dans le carter 3, un segment 52 émerge
du carter 3 à travers l'ouverture 33 et qu'un segment 53 du disque est disposé
dans l'ouverture 32 au droit des échancrures trapézoïdales.The
L'axe 6 est constitué de deux éléments 6a et 6b s'emboítant l'un dans l'autre.
Chacun de ces éléments est formé de trois parties successives de section
décroissante : une molette 61a, 61b de section transversale circulaire, un flasque
62a, 62b de section transversale circulaire et une tige 63a, 63b. La tige 63a de
l'élément 6a est pleine et a, en section transversale, une forme carrée. Elle
s'emboíte dans la tige 63b creuse qui comporte une empreinte ayant une section
carrée correspondant à celle de la tige 63a. La fixation de la tige 63a dans la tige
63b se fait par un système double à nervure 64a et rainure 64b de claquage. Les
flasques 62a et 62b portent des picots axiaux 65a et 65b qui s'enfoncent dans la
mousse souple constituant le disque 5 et qui empêchent toute rotation relative du
disque 5 par rapport à l'axe 6 lorsque l'ensemble est monté. Les flasques 62a et
62b sont partiellement disposés dans la section de plus faible diamètre des
fenêtres 34a et 34b. Les molettes 61a et 61b sont partiellement disposées à
l'extérieur des fenêtres 34a, 34b dans la section de plus grand diamètre desdites
fenêtres et s'appuient sur l'épaulement entre les deux sections de diamètre
différent des fenêtre 34a et 34b. Ainsi, lorsque les deux éléments 6a, 6b sont
emboítés, l'axe 6 est positionné et retenu axialement ; les molettes 61a et 61b
sont munies extérieurement de quatre crans 66a facilitant l'action manuelle de
l'utilisateur sur chacune des molettes.The
Le couvercle 4 est fixé sur la partie supérieure du carter 3, de façon à protéger le
segment 52 de l'organe applicateur 5 émergeant de l'ouverture 33 du carter 3 ; le
couvercle 4 présente sur ses faces prolongeant les parois parallèles 21 du
réservoir 2 des échancrures 42 en arc de cercle dans lesquels prennent place les
molettes 61a, 61b en position de fermeture du couvercle 4.The cover 4 is fixed on the upper part of the
L'ensemble 1 fonctionne de la façon suivante. Lorsque l'utilisateur désire prélever
par exemple une poudre P contenue dans le réservoir 2, il enlève le couvercle et
retourne l'ensemble 1, ou l'agite vigoureusement, pour que la poudre P vienne en
contact avec le segment 53 du disque 5. Ensuite, il fait tourner l'une des molettes
61a ou 61b d'un demi-tour, dans un sens ou dans l'autre, de façon que la partie du
disque formant le segment 53 prenne la place correspondante au segment 52
dans l'ouverture 33. Pendant la rotation, la poudre est tassée par les bords
inclinés 32a, entre lesquels le disque est entraíné, puis ensuite par la surface
intérieure de l'enveloppe 31. Le produit est ainsi compacté sur l'applicateur 5 et
est réparti de façon homogène sur le segment 53, une faible quantité de liquide
ayant pu éventuellement, lors de ce compactage, être libérée sur l'applicateur. Au
final, la phase pulvérulente ne vole pas. Pour appliquer la poudre, l'utilisateur se
sert du segment émergeant du carter 3 comme applicateur.Set 1 works as follows. When the user wishes to withdraw
for example a powder P contained in the
A l'application, en pressant l'applicateur sur la peau, le liquide contenu dans les micro-capsules de cire est libéré, et se mélange avec la phase pulvérulente, ce qui confère une impression de fraícheur sur la peau, et favorise l'étalement et la tenue de la poudre sur la peau.On application, by pressing the applicator on the skin, the liquid contained in the wax microcapsules is released, and mixes with the pulverulent phase, which gives an impression of freshness on the skin, and promotes spreading and hold powder on the skin.
Grâce à l'élasticité de la périphérie du disque 5 en mousse, le contact entre le
disque 5 et le bord de l'ouverture 32 est suffisamment étanche pour que la poudre
ne risque pas de s'échapper du réservoir au cours du stockage et quand on
retourne l'ensemble pour mettre le produit en contact avec le segment 53 du
disque.Thanks to the elasticity of the periphery of the
On a représenté sur la figure 4 un dispositif 100 conforme à un second exemple
de réalisation de l'invention. Ce dispositif, d'axe X, comporte un récipient 188 et un
applicateur 189. Le récipient 188 est formé par l'assemblage d'une partie
inférieure 190 et d'une partie supérieure 191. La partie inférieure 190 présente une
paroi tubulaire centrale 192 fermée inférieurement par un fond rapporté 193 et
surmontée par un goulot 154. Le goulot 154 se termine par un rebord 195 formant
radialement saillie vers l'intérieur.FIG. 4 shows a
La poudre P est contenue à l'intérieur de la paroi tubulaire 192, et à sa surface
libre disposée sensiblement à mi-hauteur de la paroi tubulaire 192. La phase
pulvérulente est constituée de pigments et de charges pour le maquillage des
lèvres. La phase liquide est formé à base de polypropylène glycol retenu dans des
micro-capsules de cire fondant à basse température.The powder P is contained inside the
La partie supérieure 191 du récipient 188 comporte une paroi tubulaire centrale
196 prolongée radialement vers l'extérieur, au voisinage de son extrémité
supérieure, par une jupe externe 197 qui est arrondie vers le bas et sur la surface
interne de laquelle s'encliquette la jupe externe 194 de la partie inférieure 190. La
paroi centrale tubulaire 196 s'engage alors de façon étanche sur le col 154 de la
partie tubulaire 192. The
Un arceau 198, venu de moulage avec la partie supérieure 191 du récipient,
s'articule sur la jupe externe 197 au moyen de ponts de matière 199 formant
charnières. La paroi centrale tubulaire 196 présente, au niveau du raccordement
de la jupe externe 197, un décrochement 150 vers l'intérieur, prolongé vers le haut
par un col 101 délimitant une ouverture 121. L'applicateur 189 comporte un
organe de préhension 102, prolongé vers le bas par une tige 103 munie à son
extrémité inférieure d'un élément d'application 104. L'élément d'application 104 est
constitué d'une palette en élastomère, de section longitudinale ovoïde, et de forme
effilée en direction de son extrémité libre. L'élément d'application 104 est
recouvert d'un revêtement de flocage. L'organe de préhension 102 est formé par
l'assemblage d'un corps externe 105, de forme ogivale, ouvert à son extrémité
inférieure et d'une partie interne 106 emmanchée dans le corps externe 105 et
présentant un logement creux 107 dans lequel est retenue une tête sphérique 108
formée à l'extrémité supérieure de la tige 103, de manière à constituer une rotule.A hoop 198, molded with the
En position de fermeture du récipient 188, le corps externe 105 de l'organe de
préhension 102 s'ajuste sur le col 101. L'étanchéité à la fermeture est obtenue par
le serrage de la partie interne 106 contre la tranche d'extrémité supérieure du col
101. La tige 103 de l'applicateur 189 s'élargit à son extrémité inférieure 109 pour
former un logement servant à la fixation de l'élément d'application 104, constitué
dans l'exemple décrit par une pointe en feutre.In the closed position of the
Un bloc de mousse de polyuréthanne 110 est logé à l'intérieur de la paroi tubulaire
centrale 196, en étant retenu axialement à son extrémité inférieure par le rebord
interne 195 et à son extrémité supérieure par le décrochement 100. Le bloc de
mousse est traversé par un passage axial 120.A block of
A l'application, l'utilisatrice agite l'ensemble 100, de manière à amener la poudre P
au contact de l'élément d'application 104, disposé à distance de la surface libre de
la poudre. Le produit se dépose à la fois sur l'applicateur, et sur la paroi inférieure
du bloc de mousse 110. En extrayant l'applicateur 189 du réservoir 188, l'élément
d'application est amené à traverser le bloc de mousse 110, via le passage 120,
selon un trajet sensiblement selon l'axe X, imposé par la configuration de
l'ensemble. Ce faisant, la poudre présente sur l'élément d'application 110 est
pressée entre la surface de l'applicateur et le bloc de mousse, améliorant ainsi la
tenue de la poudre sur l'applicateur. En outre, lors de l'extraction de l'élément
d'application 104, via le passage 120 du bloc de mousse 110, la paroi inférieure
du bloc de mousse est entraínée par l'élément d'application 104, et remonte en
partie vers l'intérieur du bloc de mousse, provoquant ainsi le transfert sur
l'applicateur de la poudre présente sur ladite face inférieure.Upon application, the user shakes the
A la sortie de l'élément d'application 104, la poudre est solidement ancrée sur
l'applicateur. Elle ne vole pas. Lors de l'application sur la peau, la pression
exercée par l'applicateur sur la peau, provoque la libération du liquide enfermé
dans les micro-capsules de cire, lequel liquide procure une agréable sensation de
frais et de douceur, et contribue à favoriser l'étalement et la bonne tenue de la
poudre sur la peau. At the exit of the
Dans la description détaillée qui précède, il a été fait référence à des modes de réalisation préférés de l'invention. Il est évident que des variantes peuvent y être apportées sans s'écarter de l'esprit de l'invention telle que revendiquée ci-après.In the foregoing detailed description, reference has been made to modes of preferred embodiments of the invention. Obviously there may be variations made without departing from the spirit of the invention as claimed below.
Claims (23)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0006449A FR2808980B1 (en) | 2000-05-19 | 2000-05-19 | SET FOR PACKAGING AND APPLYING LIQUID POWDER |
FR0006449 | 2000-05-19 |
Publications (2)
Publication Number | Publication Date |
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EP1155635A1 true EP1155635A1 (en) | 2001-11-21 |
EP1155635B1 EP1155635B1 (en) | 2006-06-21 |
Family
ID=8850427
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01401082A Expired - Lifetime EP1155635B1 (en) | 2000-05-19 | 2001-04-26 | Assembly for storage and application of a liquid powder |
Country Status (12)
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US (1) | US6682244B2 (en) |
EP (1) | EP1155635B1 (en) |
JP (1) | JP2002058532A (en) |
CN (1) | CN1162308C (en) |
AR (1) | AR028102A1 (en) |
AT (1) | ATE330504T1 (en) |
BR (1) | BR0102628A (en) |
CA (1) | CA2348125C (en) |
DE (1) | DE60120831T2 (en) |
ES (1) | ES2266130T3 (en) |
FR (1) | FR2808980B1 (en) |
MX (1) | MXPA01005041A (en) |
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-
2000
- 2000-05-19 FR FR0006449A patent/FR2808980B1/en not_active Expired - Fee Related
-
2001
- 2001-04-26 AT AT01401082T patent/ATE330504T1/en not_active IP Right Cessation
- 2001-04-26 DE DE60120831T patent/DE60120831T2/en not_active Expired - Lifetime
- 2001-04-26 ES ES01401082T patent/ES2266130T3/en not_active Expired - Lifetime
- 2001-04-26 EP EP01401082A patent/EP1155635B1/en not_active Expired - Lifetime
- 2001-05-15 BR BR0102628-3A patent/BR0102628A/en not_active Application Discontinuation
- 2001-05-17 AR ARP010102338A patent/AR028102A1/en not_active Application Discontinuation
- 2001-05-17 CA CA002348125A patent/CA2348125C/en not_active Expired - Fee Related
- 2001-05-18 US US09/859,444 patent/US6682244B2/en not_active Expired - Fee Related
- 2001-05-18 MX MXPA01005041A patent/MXPA01005041A/en active IP Right Grant
- 2001-05-18 CN CNB011220058A patent/CN1162308C/en not_active Expired - Fee Related
- 2001-05-21 JP JP2001151739A patent/JP2002058532A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2701364A1 (en) | 1993-02-10 | 1994-08-19 | Oreal | Applicator assembly for a makeup product. |
FR2745272A1 (en) * | 1996-02-28 | 1997-08-29 | Oreal | PACKAGING AND APPLICATION DEVICE AND CHARGING ELEMENT FOR SUCH A DEVICE |
WO1997031553A1 (en) | 1996-02-28 | 1997-09-04 | L'oreal | Packaging and application device, and reloading element therefor |
EP0855177A2 (en) | 1997-01-24 | 1998-07-29 | Kose Corporation | Whitening powder |
WO1999001052A1 (en) * | 1997-07-02 | 1999-01-14 | Henlopen Manufacturing Co., Inc. | Applicator for liquid material |
EP0933039A1 (en) * | 1998-01-30 | 1999-08-04 | L'oreal | Film-forming composition application device |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2943896A1 (en) * | 2009-04-01 | 2010-10-08 | Oreal | "ROLL-ON" HAS HIGH SALICYLIC ACID CONTENT. |
EP2437631A2 (en) * | 2009-06-04 | 2012-04-11 | ELC Management LLC | Metal clad ceramic cosmetic applicator |
EP2437631A4 (en) * | 2009-06-04 | 2013-06-19 | Elc Man Llc | Metal clad ceramic cosmetic applicator |
US8573874B2 (en) | 2009-06-04 | 2013-11-05 | Elc Management, Llc | Metal clad ceramic cosmetic applicator |
DE202017107121U1 (en) | 2017-11-23 | 2017-12-13 | Irene Unger | Active agent for application around the eyes to combat fatigue |
Also Published As
Publication number | Publication date |
---|---|
ES2266130T3 (en) | 2007-03-01 |
JP2002058532A (en) | 2002-02-26 |
CN1324749A (en) | 2001-12-05 |
CA2348125C (en) | 2006-07-18 |
CN1162308C (en) | 2004-08-18 |
DE60120831D1 (en) | 2006-08-03 |
MXPA01005041A (en) | 2003-08-20 |
FR2808980A1 (en) | 2001-11-23 |
CA2348125A1 (en) | 2001-11-19 |
AR028102A1 (en) | 2003-04-23 |
DE60120831T2 (en) | 2006-12-28 |
US6682244B2 (en) | 2004-01-27 |
US20020021932A1 (en) | 2002-02-21 |
BR0102628A (en) | 2002-01-02 |
FR2808980B1 (en) | 2002-12-20 |
ATE330504T1 (en) | 2006-07-15 |
EP1155635B1 (en) | 2006-06-21 |
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