EP1142706B1 - "Direct-to-plate" lithographisches Druckverfahren mit automatischer Platten-beschichtung und -reinigung - Google Patents
"Direct-to-plate" lithographisches Druckverfahren mit automatischer Platten-beschichtung und -reinigung Download PDFInfo
- Publication number
- EP1142706B1 EP1142706B1 EP00203968A EP00203968A EP1142706B1 EP 1142706 B1 EP1142706 B1 EP 1142706B1 EP 00203968 A EP00203968 A EP 00203968A EP 00203968 A EP00203968 A EP 00203968A EP 1142706 B1 EP1142706 B1 EP 1142706B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- press
- printing
- transferring
- transferring means
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000007639 printing Methods 0.000 title claims description 126
- 238000000576 coating method Methods 0.000 title claims description 96
- 238000004140 cleaning Methods 0.000 title claims description 90
- 239000011248 coating agent Substances 0.000 title claims description 90
- 238000000034 method Methods 0.000 title claims description 66
- 239000000463 material Substances 0.000 claims description 95
- 239000000758 substrate Substances 0.000 claims description 72
- 238000003384 imaging method Methods 0.000 claims description 43
- 238000012545 processing Methods 0.000 claims description 28
- 239000007788 liquid Substances 0.000 claims description 25
- 239000002245 particle Substances 0.000 claims description 25
- 230000002209 hydrophobic effect Effects 0.000 claims description 17
- 239000011230 binding agent Substances 0.000 claims description 15
- 229920001169 thermoplastic Polymers 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 8
- 239000008346 aqueous phase Substances 0.000 claims description 3
- 239000012074 organic phase Substances 0.000 claims description 3
- 230000005660 hydrophilic surface Effects 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 53
- 229920000642 polymer Polymers 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 9
- 239000002253 acid Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- 238000002679 ablation Methods 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 239000008119 colloidal silica Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- -1 sulfonated aliphatic aldehyde Chemical class 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000005345 coagulation Methods 0.000 description 5
- 230000015271 coagulation Effects 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 230000007246 mechanism Effects 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- 238000005452 bending Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000004581 coalescence Methods 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 239000002985 plastic film Substances 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229920001940 conductive polymer Polymers 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229920001600 hydrophobic polymer Polymers 0.000 description 2
- 238000007641 inkjet printing Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 239000004373 Pullulan Substances 0.000 description 1
- 229920001218 Pullulan Polymers 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000007754 air knife coating Methods 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910003439 heavy metal oxide Inorganic materials 0.000 description 1
- 229920001480 hydrophilic copolymer Polymers 0.000 description 1
- 229910001506 inorganic fluoride Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- FOKLVOHHYNATHU-UHFFFAOYSA-N oxan-2-ylmethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1CCCCO1 FOKLVOHHYNATHU-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920006290 polyethylene naphthalate film Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000007763 reverse roll coating Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000007767 slide coating Methods 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
- 238000001931 thermography Methods 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5022—Organic solvents containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C1/00—Forme preparation
- B41C1/10—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme
- B41C1/1008—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by removal or destruction of lithographic material on the lithographic support, e.g. by laser or spark ablation; by the use of materials rendered soluble or insoluble by heat exposure, e.g. by heat produced from a light to heat transforming system; by on-the-press exposure or on-the-press development, e.g. by the fountain of photolithographic materials
- B41C1/1025—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by removal or destruction of lithographic material on the lithographic support, e.g. by laser or spark ablation; by the use of materials rendered soluble or insoluble by heat exposure, e.g. by heat produced from a light to heat transforming system; by on-the-press exposure or on-the-press development, e.g. by the fountain of photolithographic materials using materials comprising a polymeric matrix containing a polymeric particulate material, e.g. hydrophobic heat coalescing particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C2210/00—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
- B41C2210/08—Developable by water or the fountain solution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
- B41C2210/00—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
- B41C2210/24—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation characterised by a macromolecular compound or binder obtained by reactions involving carbon-to-carbon unsaturated bonds, e.g. acrylics, vinyl polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N3/00—Preparing for use and conserving printing surfaces
- B41N3/006—Cleaning, washing, rinsing or reclaiming of printing formes other than intaglio formes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/263—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3218—Alkanolamines or alkanolimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3263—Amides or imides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3281—Heterocyclic compounds
Definitions
- the present invention relates to a direct-to-plate lithographic printing method wherein a substrate is coated in an off-press coating apparatus, exposed either on- or off-press and then recycled in an off-press cleaning apparatus.
- Lithographic printing presses use a so-called printing master such as a printing plate which is mounted on a cylinder of the printing press.
- the master carries a lithographic image on its surface and a print is obtained by applying ink to said image and then transferring the ink from the master onto a receiver material, which is typically paper.
- ink as well as an aqueous fountain solution also called dampening liquid
- the lithographic image which consists of oleophilic (or hydrophobic, i.e. ink-accepting, water-repelling) areas as well as hydrophilic (or oleophobic, i.e. water-accepting, ink-repelling) areas.
- so-called driographic printing the lithographic image consists of ink-accepting and ink-abhesive (ink-repelling) areas and during driographic printing, only ink is supplied to the master.
- Printing masters are generally obtained by the so-called computer-to-film method wherein various pre-press steps such as typeface selection, scanning, color separation, screening, trapping, layout and imposition are accomplished digitally and each color selection is transferred to graphic arts film using an image-setter.
- the film can be used as a mask for the exposure of an imaging material called plate precursor and after plate processing, a printing plate is obtained which can be used as a master.
- EP-A 698 488 A computer-to-press method that is characterized by most of the above advantages has been disclosed in EP-A 698 488.
- An oleophilic substance is image-wise transferred from a foil to a rotary press cylinder by melting said substance locally with a laser beam.
- the strip-shaped transfer foil has a narrow width compared to the cylinder and is translated along a path which is parallel to the axis of the cylinder while being held in close contact with the surface of the cylinder so as to build up a complete image on that surface gradually.
- this system is rather slow and requires a long down-time of the printing press, thereby reducing its productivity.
- EP-A 802 457 describes an on-press coating method wherein an aqueous liquid, comprising a hydrophilic binder, a compound capable of converting light to heat and hydrophobic thermoplastic polymer particles, is coated on the plate cylinder so as to form a uniform, continuous layer thereon. Upon image-wise exposure, areas of the coated layer are converted into an hydrophobic phase, thereby defining the printing areas of the printing master.
- the press run can be started immediately after exposure without any additional treatment because the layer is processed by interaction with the fountain and ink that are supplied to the cylinder during the press run. So the wet chemical processing of these materials is 'hidden' to the user and accomplished during the first runs of the printing press.
- the coating can be removed from the plate cylinder by an on-press cleaning step.
- on-press coating, on-press exposure and on-press cleaning of the master attract attention because, contrary to conventional lithographic printing, they can be carried out without specialized training or experience.
- Such presses function more or less like a desktop computer printer and require less human intervention than conventional presses.
- a problem associated with the on-press coating, exposure and cleaning methods is that the wet coating and cleaning steps involve a risk of damaging or contaminating the optics and electronics of the integrated image-setter.
- the method produces an insufficient coating quality, characterized by a low consistency and a high frequency of coating artifacts, because the printing press is a hostile environment to the application of defect-free coatings due to paper dust, ink misting, and temperature or humidity variations.
- the quality of the wet-coating step can only be improved by installing a complex and sophisticated coating apparatus on the press, which is difficult to achieve due to space and cost limitations.
- the press is not printing and the press down-time needs to be minimized in order to be economically viable.
- This object is realized by a method using a printing press that is mechanically coupled to an off-press coating and an off-press cleaning apparatus as defined in the independent claims.
- a substrate is coated off-press in the coating apparatus, subsequently mechanically transferred to the press, and after the pressrun, the used printing master is mechanically transferred to a cleaning apparatus where the coating is removed from the substrate, which can then be used again in a next cycle of coating, printing and cleaning.
- the method of the present invention enables a fully-automated workflow of coating, exposure, printing and cleaning wherein the press down-time is minimal and which can be carried out without special skills.
- the press down-time is minimal because during a pressrun, the imaging material(s) of the next print job can be coated in the coating apparatus and the material(s) of the previous print job can be cleaned in the cleaning apparatus while the press is printing.
- a single coating and/or a single cleaning apparatus can be combined with a multi-color printing press which requires more than one printing master.
- the exposure step can be carried out on-press, offering the benefit of obtaining a prefect registration of the masters in multi-color presses immediately after exposure, or off-press so as to obtain a even lesser press down-time.
- the method of the invention comprises five essential steps :
- the exposure apparatus can be integrated in the press (such an embodiment is shown in Fig. 1), or integrated in the coating apparatus, so as to form together with the coating apparatus a plate-making apparatus that is capable of coating a substrate and exposing the thus obtained imaging material (Fig. 3), or be a separate apparatus that is mechanically coupled between the coating apparatus and the printing apparatus (Fig. 2).
- the mechanical transferring means between the coating apparatus and the exposure apparatus and between the exposure apparatus and the printing press should be light-tight, unless the exposure apparatus is mechanically coupled to a processing apparatus wherein the exposed imaging material is processed so as to form a printing master which is no longer sensitive to daylight.
- the steps of coating and exposing can be carried out in a single apparatus, such as the plate-making apparatus defined above.
- Such plate-making apparatus may comprise different sections for cleaning and coating and then it is preferred that the apparatus further comprises internal means for mechanically transferring the substrate from the cleaning section to the coating section.
- the coating apparatus and the cleaning apparatus may be separate apparatuses.
- the recycled substrate is transferred between steps (d) and (a) from the cleaning apparatus to the coating apparatus either manually, i.e. by an operator who carries the material from one apparatus to another, but preferably mechanically by transferring means which couple the cleaning apparatus to the coating apparatus.
- the recycled substrate is preferably shielded from the environment so as to avoid contamination or damage of its surface.
- Transferring means which transfer the substrate between step (d) and (a) preferably shield the substrate from dust, so as to avoid pinholes and other artifacts in the recoated image-recording layer.
- the coating apparatus, the exposure apparatus and the cleaning apparatus are all integrated in a single apparatus wherein steps (d), (a) and (b) can be performed sequentially.
- This embodiment requires less extensive transferring means (a-b) and (d-a) or no such transferring means at all, e.g. by mounting a printing master on the external surface of a rotating drum and cleaning the master by means of a cleaning head which travels over the master in the axial direction of the drum which rotates in the angular direction, then coating the recycled substrate by means of a coating head (travelling in a similar way over the substrate) and finally exposing the coated layer by means of e.g. a laser head.
- the cleaning head, the coating head and the laser head may be coupled to one another, so as to form a multi-functional head which enables to perform the steps of cleaning, coating and exposing in a single pass of the multi-functional head over the substrate. More details and other methods of coating, cleaning and exposing are given below.
- the plate-making apparatus may contain a coating section, an exposure section and a cleaning section with internal mechanical means for transferring the material between the different sections of the apparatus.
- a plate-making apparatus may handle three materials at once by the simultaneous operation of all sections : coating a substrate, exposing an image-recording material and cleaning a printing master.
- a stacking apparatus in the transferring means (a-b) between cleaning and coating, (b-c) between coating and exposure, (c-d) between exposure and printing, and/or (d-a) between printing and cleaning, especially when the printing press is a multi-color press comprising a plurality of color stations (the number of color stations typically ranges from 2 to 6, or even 12 in case of six-color duplex printing).
- a stacking apparatus enables to coat, expose and/or clean materials for all the color stations with a single coating, exposure and/or cleaning apparatus, because the stacking apparatus acts as a buffer for temporary storage between one apparatus and the next apparatus in the cycle.
- a stacking apparatus may be integrated inside an apparatus, either at the entry and/or the exit thereof, rather than in the transferring means between two apparatuses.
- Particularly preferred methods of the present invention use the following configurations : (i) a coating and a cleaning apparatus which are both coupled to a multi-color digital press (containing an integrated exposure apparatus in each color station) via a stacking apparatus ( Figure 1); (ii) a coating apparatus which is mechanically coupled to an exposure apparatus (and optional processor), the exposure apparatus also being mechanically coupled to a multi-color printing press via a stacking apparatus; and a cleaning apparatus that is mechanically coupled to the press via a stacking apparatus ( Figure 2); and (iii) a plate-making apparatus coupled to an exposure apparatus (with optional processor), which is coupled to a multi-color printing press via a stacking apparatus ( Figure 3).
- a digital four-color press for printing the basic colors Cyan (C), Magenta (M), Yellow (Y) and Black (K), is combined with a single plate-making apparatus via a stacking apparatus.
- the plate-making apparatus first prepares an imaging material for e.g. the C color station and that material is then transferred to the stacking apparatus which temporarily stores the material while the printing press is running a previous print job. Subsequently, the material for another color selection, e.g. M, is coated and also stored in the stacking apparatus. Similarly, the imaging materials for the Y and K stations are prepared and stored in the stacking apparatus until the previous press run is finished.
- the used printing masters are removed from the press and mechanically transferred to the plate-making apparatus for cleaning (also preferably via an intermediate stacking apparatus present in the plate-unloading means), and finally, the materials for the next print job are mechanically transferred from the stacking apparatus to the respective color stations C, M, Y and K, where they are exposed by the integrated exposure apparatus.
- the printing system that can be used in the present invention comprises a coating apparatus and a cleaning apparatus, which are integrated in configuration (iii), and an off-press exposure apparatus.
- the stacking apparatus between the exposure apparatus and the multi-color press and the plate-loading means between the exposure apparatus and the press are preferably equipped with some intelligence, e.g. driven by a microcomputer, to ensure that each color selection arrives at the correct color station.
- a single stacking apparatus handles the image-recording materials prepared by the plate-making apparatus (or the exposed materials in case of off-press exposure) as well as the used printing masters which need to be transferred back to the plate-making apparatus for cleaning.
- the coating apparatus prepares an imaging material for the C color station and that material is then transferred to a stacking system which temporarily stores the material while the printing press is running a previous print job. Subsequently, the material for the M station is coated and also stored in the stacking apparatus. Similarly, the imaging materials for the Y and K stations are prepared and stored in the stacking system until the pressrun is finished.
- C Cyan
- M Magenta
- Y Yellow
- K Black
- the used printing masters are removed from the press and mechanically transferred to the cleaning apparatus (also preferably via an intermediate stacking apparatus present in the transferring means (d-a)), and finally, the materials for the next print job are mechanically transferred from the stacking apparatus to the respective color stations C, M, Y and K, where they are exposed by the integrated exposure apparatus.
- a single stacking apparatus handles the image-recording materials prepared by the coating apparatus (or the exposed materials in case of an off-press exposure apparatus) as well as the used printing masters which need to be transferred to the cleaning apparatus.
- n*5 substrates (n being the number of color stations, which may typically range from 2 to 6 or even 12 in case of single-pass duplex printing) : n printing masters used in a previous print job (i-1) which are being cleaned in the cleaning apparatus; n printing masters used in the printing press during print job (i); n exposed image-recording materials for the next print job (i+1) which are stored in the stacking apparatus between the exposure apparatus and the printing apparatus; n image-recording materials which are being exposed in the exposure apparatus for print job (i+2); and n substrates which are being coated in the coating apparatus for print job (i+3).
- n materials are present in an apparatus
- this may be understood as one material which is being processed (coated, exposed, cleaned) in that apparatus and n-1 materials that are being stored in an internal stacking unit of that apparatus, e.g. a stacking unit present in the entry or the exit section of that apparatus.
- the substrate used in the methods of the present invention may have any affinity for ink and/or an ink-abhesive fluid such as dampening liquid.
- a driographic material can be obtained by providing an ink-abhesive substrate with an ink-accepting image-recording layer, or an image-recording layer which becomes ink-accepting after exposure, and optional processing.
- a driographic material can also be obtained by providing an ink-accepting substrate with an ink-abhesive image-recording layer, or an image-recording layer which becomes ink-abhesive after exposure, and optional processing.
- a conventional lithographic material can be obtained by providing a hydrophilic substrate with a hydrophobic image-recording layer, or an image-recording layer which becomes hydrophobic after exposure and optional processing.
- a conventional lithographic material can also be obtained by providing a hydrophobic substrate with a hydrophilic image-recording layer, or an image-recording layer which becomes hydrophilic after exposure and optional processing.
- the affinity of the substrate for ink or for an ink-abhesive fluid is irrelevant, more particularly when the substrate is coated with a so-called switchable image-recording layer, which can be switched from one ink affinity to another and remains on the substrate after exposure and optional processing in the exposed as well as the non-exposed areas.
- the printing as well as the non-printing areas are mainly defined by the coated layer and not by the substrate. More details about switchable layers, more particularly switchable polymers, are given in the section "imaging material" below.
- the substrate may be a sheet-like material such as a plate or it may be a cylindrical element such as a sleeve.
- the printing plate may be soldered in a cylindrical form, e.g. by means of a laser.
- Such cylindrical printing plate can be slid on the print cylinder of a printing press instead of being mounted thereon such as a conventional printing plate. More details on sleeves are given in e.g. "Grafisch Nieuws" , 15, 1995, page 4-6.
- the substrate may be an aluminum support.
- a particularly preferred substrate is an electrochemically grained and anodized aluminum support.
- the anodized aluminum support may be treated to improve the hydrophilic properties of its surface.
- the aluminum support may be silicated by treating its surface with a sodium silicate solution at elevated temperature, e.g. 95°C.
- a phosphate treatment may be applied which involves treating the aluminum oxide surface with a phosphate solution that may further contain an inorganic fluoride.
- the aluminum oxide surface may be rinsed with a citric acid or citrate solution. This treatment may be carried out at room temperature or may be carried out at a slightly elevated temperature of about 30 to 50°C.
- a further interesting treatment involves rinsing the aluminum oxide surface with a bicarbonate solution.
- the aluminum oxide surface may be treated with polyvinylphosphonic acid, polyvinylmethylphosphonic acid, phosphoric acid esters of polyvinyl alcohol, polyvinylsulfonic acid, polyvinylbenzenesulfonic acid, sulfuric acid esters of polyvinyl alcohol, and acetals of polyvinyl alcohols formed by reaction with a sulfonated aliphatic aldehyde It is further evident that one or more of these post treatments may be carried out alone or in combination.
- the substrate can also be a flexible support, which is provided with a hydrophilic layer, hereinafter called 'base layer'.
- the flexible support is e.g. paper, plastic film or aluminum.
- plastic film are polyethylene terephthalate film, polyethylene naphthalate film, cellulose acetate film, polystyrene film, polycarbonate film, etc.
- the plastic film support may be opaque or transparent.
- the base layer is preferably a cross-linked hydrophilic layer obtained from a hydrophilic binder cross-linked with a hardening agent such as formaldehyde, glyoxal, polyisocyanate or a hydrolyzed tetra-alkylorthosilicate.
- a hardening agent such as formaldehyde, glyoxal, polyisocyanate or a hydrolyzed tetra-alkylorthosilicate.
- the thickness of the hydrophilic base layer may vary in the range of 0.2 to 25 ⁇ m and is preferably 1 to 10 ⁇ m.
- the hydrophilic binder for use in the base layer is e.g. a hydrophilic (co)polymer such as homopolymers and copolymers of vinyl alcohol, acrylamide, methylol acrylamide, methylol methacrylamide, acrylate acid, methacrylate acid, hydroxyethyl acrylate, hydroxyethyl methacrylate or maleic anhydride/vinylmethylether copolymers.
- the hydrophilicity of the (co)polymer or (co)polymer mixture used is preferably the same as or higher than the hydrophilicity of polyvinyl acetate hydrolyzed to at least an extent of 60% by weight, preferably 80% by weight.
- the amount of hardening agent, in particular tetraalkyl orthosilicate, is preferably at least 0.2 parts per part by weight of hydrophilic binder, more preferably between 0.5 and 5 parts by weight, most preferably between 1 parts and 3 parts by weight.
- the hydrophilic base layer may also contain substances that increase the mechanical strength and the porosity of the layer.
- colloidal silica may be used.
- the colloidal silica employed may be in the form of any commercially available water dispersion of colloidal silica for example having an average particle size up to 40 nm, e.g. 20 nm.
- inert particles of larger size than the colloidal silica may be added e.g. silica prepared according to Stöber as described in J. Colloid and Interface Sci., Vol. 26, 1968, pages 62 to 69 or alumina particles or particles having an average diameter of at least 100 nm which are particles of titanium dioxide or other heavy metal oxides.
- the surface of the hydrophilic base layer is given a uniform rough texture consisting of microscopic hills and valleys, which serve as storage places for water in background areas.
- hydrophilic base layers for use in accordance with the present invention are disclosed in EP-A- 601 240, GB-P- 1 419 512, FR-P- 2 300 354, US-P- 3 971 660 , and US-P- 4 284 705 .
- the amount of silica in the adhesion improving layer is between 200 mg/m 2 and 750 mg/m 2 .
- the ratio of silica to hydrophilic binder is preferably more than 1 and the surface area of the colloidal silica is preferably at least 300 m 2 /gram, more preferably at least 500 m 2 /gram.
- the imaging material consists of at least one image-recording layer provided on the substrate. Preferably, only a single layer is provided on the substrate.
- the material may be light- or heat-sensitive, the latter being preferred because of daylight-stability.
- any known direct-to-plate technology is suitable, especially in the embodiment using an off-press exposure apparatus.
- the exposure apparatus can be coupled to or may comprise a processor.
- Known materials which require processing are e.g. light-sensitive plates such as photopolymer plates and silver diffusion transfer plates, or heat-sensitive (so-called thermal) plates which rely on e.g. heat-induced solubilisation of a polymer layer or heat-induced release of an acid which triggers cross-linking of a polymer layer (insolubilisation).
- Highly preferred imaging materials for use in the present invention have an image-recording layer which does not require any processing so that a printing master is obtained immediately after exposure. This is especially advantageous in the embodiment using on-press exposure.
- the material may be processed on-press, e.g. by supplying an aqueous liquid, fountain and/or ink (so-called 'hidden processing').
- Non-ablative processless plates comprise e.g. switchable polymers (e.g.
- EP 924 102 which can be image-wise converted from a hydrophobic state to a hydrophilic state (WO92/09934; EP 652 483) or vice-versa (US 4,081,572; EP 200,488, EP 924 065).
- Other examples of processless plates are based on the thermally induced rupture of microcapsules and the subsequent reaction of the microencapsulated oleophilic materials (isocyanates) with functional (hydroxyl-)groups on cross-linked hydrophilic binders (US 5,569,573; EP 646 476; WO94/2395; WO98/29258).
- a most preferred composition of the imaging layer relies on the heat-induced coalescence of hydrophobic thermoplastic polymer particles in a hydrophilic binder, as described in e.g. EP 770 494; EP 770 495; EP 770 497; EP 773 112; EP 774 364; and EP 849 090.
- These materials are especially designed for on-press ("hidden") processing by ink and/or fountain.
- the coalesced polymer particles define a hydrophobic, printing area and do not dissolve in ink or fountain whereas the unexposed layer readily dissolves in ink and/or fountain.
- the components (thermoplastic polymer latex and hydrophilic binder) of the latter embodiment will now be described in more detail.
- Hydrophobic thermoplastic polymer particles preferably have a coagulation temperature above 35°C and more preferably above 50°C. Coagulation may result from softening or melting of the thermoplastic polymer particles under the influence of heat. There is no specific upper limit to the coagulation temperature of the thermoplastic hydrophobic polymer particles, however the temperature should be sufficiently below the decomposition of the polymer particles. Preferably the coagulation temperature is at least 10°C below the temperature at which the decomposition of the polymer particles occurs. Specific examples of hydrophobic polymer particles are e.g.
- the weight average molecular weight of the polymers may range from 5,000 to 1,000,000g/mol.
- the hydrophobic particles may have a particle size from 0.01 ⁇ m to 50 ⁇ m, more preferably between 0.05 ⁇ m and 10 ⁇ m and most preferably between 0.05 ⁇ m and 2 ⁇ m.
- the amount of hydrophobic thermoplastic polymer particles contained in the image forming layer is preferably between 20% by weight and 65% by weight and more preferably between 25% by weight and 55% by weight and most preferably between 30% by weight and 45% by weight.
- the polymer particles are present as a dispersion in an aqueous coating liquid of the image forming layer and may be prepared by the methods disclosed in US 3,476,937. Another method especially suitable for preparing an aqueous dispersion of the thermoplastic polymer particles comprises:
- Suitable hydrophilic binders are for example synthetic homo or copolymers such as a polyvinylalcohol, a poly(meth)acrylic acid, a poly (meth) acrylamide, a polyhydroxyethyl (meth) acrylate, a polyvinylmethylether or natural binders such as gelatin, a polysacharide such as e.g. dextran, pullulan, cellulose, arabic gum, alginic acid.
- a polysacharide such as e.g. dextran, pullulan, cellulose, arabic gum, alginic acid.
- the imaging layer based on heat-induced polymer latex coalescence is preferably an infrared-sensitive layer containing one or more compounds that are capable of converting infrared light into heat.
- Particularly useful compounds are for example infrared dyes, carbon black, metal carbides, borides, nitrides, carbonitrides, bronze-structured oxides, and conductive polymer dispersions such as polypyrrole, polyaniline or polythiophene-based conductive polymer dispersions.
- the coating apparatus comprises means for applying an image-recording layer on the substrate. For obtaining the right coating thickness, it may be necessary to repeat the coating several times on the same substrate.
- the coating can be applied by heat- or friction-induced transfer from a donor material as described in EP 1 048 458, or by powder coating, e.g. as described in EP-A 974 455 and EP-A 1 097 811, or by coating a liquid solution according to any known coating method, e.g. spin-coating, dip coating, rod coating, blade coating, air knife coating, gravure coating, reverse roll coating, extrusion coating, slide coating and curtain coating.
- any known coating method e.g. spin-coating, dip coating, rod coating, blade coating, air knife coating, gravure coating, reverse roll coating, extrusion coating, slide coating and curtain coating.
- An overview of these coating techniques can be found in the book "Modern Coating and Drying Technology", Edward Cohen and Edgar B. Gutoff Editors, VCH publishers, Inc, New York, NY, 1992.
- a coating solution is sprayed on the substrate by means of a head comprising a spray nozzle.
- Preferred values of the spraying parameters have been defined in EP-A 1 084 830 and EP-A 1 084 862.
- the substrate is mounted on the external surface of a drum and the spray head translates along the substrate in the axial direction while the drum is rotating in the angular direction.
- Coating by spraying or jetting are the preferred techniques for applying a layer of the most preferred composition of the imaging layer, based on heat-induced coalescense of thermoplastic polymer particles in a hydrophilic binder, referred to above.
- the imaging material is image-wise exposed by an off-press exposure apparatus and subsequently mounted on a print cylinder of a printing press.
- the imaging material is exposed on-press by an integrated exposure apparatus while being mounted on the print cylinder.
- the imaging materials used in the present invention are exposed to heat or to light, e.g. by means of a thermal head, LEDs or a laser head.
- a thermal head e.g., LEDs or a laser head.
- one or more lasers such as He/Ne or Ar lasers are used.
- the light used for the exposure is not visible light so that daylight-stable materials can be used, e.g.
- UV (laser) light or a laser emitting near infrared light having a wavelength in the range from about 700 to about 1500 nm is used, e.g. a semiconductor laser diode, a Nd:YAG or a Nd:YLF laser.
- the required laser power depends on the sensitivity of the image-recording layer, the pixel dwell time of the laser beam, which is determined by the spot diameter (typical value of modern plate-setters at 1/e 2 of maximum intensity : 10-25 ⁇ m), the scan speed and the resolution of the exposure apparatus (i.e. the number of addressable pixels per unit of linear distance, often expressed in dots per inch or dpi; typical value : 1000-4000 dpi).
- ITD plate-setters are typically characterised by a very high scan speed up to 500 m/sec and may require a laser power of several Watts.
- the known plate-setters can be used as an off-press exposure apparatus in the present invention. This offers the benefit of reduced press down-time.
- XTD plate-setter configurations can also be used for on-press exposure, offering the benefit of immediate registration in a multi-color press. More technical details of on-press exposure apparatuses are described in e.g. US 5,174,205 and US 5,163,368.
- the need for a processor depends on the choice of the imaging material.
- Materials which require processing are preferably used in an off-press exposure apparatus, which may be mechanically coupled to or may comprise a processing apparatus. More preferably, processless materials are used or materials which can be processed on-press by supplying ink and/or fountain to the image-recording layer.
- the materials which rely on heat-induced coalescence of hydrophobic thermoplastic polymer particles in a hydrophilic binder, as discussed above in the section "imaging material”, are preferred examples which allow such 'hidden on-press processing' by ink and/or fountain.
- Such materials can be mounted on the press and, then, while the print cylinder with the imaging element mounted thereon rotates, the dampener rollers that supply dampening liquid are dropped on the imaging element and subsequent thereto the ink rollers are dropped. Generally, after about 10 revolutions of the print cylinder the first clear and useful prints are obtained.
- the ink rollers and dampener rollers may be dropped simultaneously or the ink rollers may be dropped first.
- Suitable dampening liquids that can be used in connection with such materials are aqueous liquids generally having an acidic pH and comprising an alcohol such as isopropanol.
- an image-wise exposed imaging material to remove ablation debris
- a cotton pad or sponge soaked with water e.g. a cotton pad or sponge soaked with water
- the results from (optical) measurements carried out on the lithographic image of the printing master can be used for correction of the registration of the masters in a multi-color press or for adjusting the ink keys of the press.
- the ink-accepting areas of the used printing master are removed from the substrate by cleaning means.
- the cleaning step is preferably characterised by a low risk of deteriorating the lithographic surface of the substrate, yet also by an effective removal of the ink-accepting areas, which may be a difficult compromise to achieve.
- the cleaning means may be means for treating the surface of the substrate scan-wise, e.g. a laser head for cleaning by ablation or a cleaning head comprising a nozzle for jetting or spraying a cleaning liquid on the substrate.
- the cleaning can be done in dip-tanks holding a cleaning liquid wherein the printing master is dipped.
- the above means for cleaning can be combined with means for ultrasound treatment or mechanical cleaning means.
- Suitable mechanical means for cleaning the substrate are e.g. means for scraping the substrate, means for rubbing the substrate, e.g. a rotating brush, a cloth or another absorbing medium, which may be moistened with a cleaning liquid, or means for jetting water or a volatile medium such as air, a solvent or dry ice pellets.
- a preferred cleaning liquid should be sufficiently effective, e.g. should be able to avoid the appearance of any ghost image after several cycles (preferably >10, most preferably >20) of coating, exposing, printing and cleaning.
- Other preferred characteristics of the cleaning liquid are a low volatile organic content to avoid environmental contamination and inertness towards the hardware of the plate-making apparatus, e.g. it is preferably a liquid which does not affect rubber, seals or other materials used in the plate-making apparatus.
- Suitable cleaning liquid compositions which comply with the above requirements have been disclosed in EP-A 1 118 470, EP-A-1 118 471 and EP-A-1 118 472.
- the cleaning liquid is preferably an emulsion of an organic liquid in an aqueous liquid.
- the preparation of this emulsion is preferably carried out in the plate-making apparatus, which may comprise means for mixing an organic liquid with an aqueous liquid so as to form said emulsion, e.g. by stirring a mixture of a cyclic organic compound containing at least one double bond, an alcohol, water and an emulsifying agent.
- the plate-making apparatus also comprises means for separating the emulsion (after use) into an organic phase and an aqueous phase, e.g. by heating the emulsion to induce phase-separation.
- the recycled water thus obtained can be used for preparing fresh emulsion or for rinsing the substrate after cleaning or prior to recoating.
- the cleaning apparatus preferably also comprises means for rinsing the substrate after the cleaning step, e.g. means for supplying, e.g. spraying or jetting, water or an aqueous solution onto the substrate.
- the plate can then be dried by e.g. hot air, vacuum extraction or an absorbing medium such as a cloth.
- the transferring means comprise a mechanism that is capable of moving, transporting or conveying the substrate, the imaging material or the used printing master from one apparatus to another. Such mechanisms are known in the art and widely used in plate-handling equipment.
- the transferring means may comprise conveyor belts, grippers, suction caps, rollers, chains, etc.
- the transferring means are preferably light-tight, i.e. capable of transferring the material while it is kept shielded from light (the same specification is valid for any other apparatus used in the present invention).
- the means used for mechanically transferring a material to the printing press preferably contain a mechanism which mounts the material on the plate cylinder.
- the means used for mechanically transferring the used printing master from the press to the cleaning apparatus preferably contain a mechanism which removes the printing master from the plate cylinder. Plates are normally fixed to the cylinder by clamps, whereas sleeves are slid over the cylinder.
- the stacking apparatus The stacking apparatus
- the stacking apparatus acts as a buffer for temporary storage of a substrate, an imaging material or a printing master between one apparatus and the next apparatus in the cycle.
- a stacking apparatus may be used in the means for mechanical transfer means from the coating apparatus to the exposure apparatus (which may be on-press or off-press), from an off-press exposure apparatus to the press and from the press to the cleaning apparatus.
- the stacking apparatus When used in the means for mechanically transferring a material to a multi-color press, the stacking apparatus is preferably driven by a system that directs the right color selection at the right time to the right color station of the press.
- the stacking apparatus may also comprise means for adjusting and controlling the temperature and/or humidity in the apparatus and should be light-tight when handling light-sensitive materials.
- the stacking apparatus between the off-press exposure apparatus and the press or between the coating apparatus and a digital press may also comprise means for bending and/or punching the substrate so that the material is ready for being mounted on the printing press. Also means for de-bending the substrate may be included in the stacking apparatus between the press and the cleaning apparatus. Such means for bending and de-bending may also be included in another apparatus of the present invention.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Printing Plates And Materials Therefor (AREA)
- Manufacture Or Reproduction Of Printing Formes (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Claims (22)
- Ein lithografisches Druckverfahren mit direkter Druckplattenbebilderung, in dem eine mittels Übertragungsmitteln (a-b) mechanisch an eine On-Press-Belichtungsvorrichtung gekuppelte Off-Press-Beschichtungsvorrichtung und eine mittels Übertragungsmitteln (c-d) mechanisch an die Druckpresse gekuppelte Off-Press-Reinigungsvorrichtung verwendet werden,
wobei das Verfahren durch folgende Schritte gekennzeichnet ist :(a) Herstellung eines Bilderzeugungsmaterials, indem ein Substrat mittels der Beschichtungsvorrichtung mit einer Bildaufzeichnungsschicht beschichtet und das Bilderzeugungsmaterial mittels der Übertragungsmittel (a-b) von der Beschichtungsvorrichtung zur Belichtungsvorrichtung überführt wird,(b) Herstellung eines ein lithografisches Bild tragenden Druckmasters, indem die Bildaufzeichnungsschicht mittels der Belichtungsvorrichtung belichtet oder mit Wärme beaufschlagt und die belichtete bzw. erwärmte Bildaufzeichnungsschicht wahlweise entwickelt wird,(c) Anbringen von Druckfarbe auf das lithografische Bild und Übertragung der Druckfarbe vom lithografischen Bild auf Papier oder ein anderes Empfangsmaterial mittels der Druckpresse und Überführen des Druckmasters von der Druckpresse zur Reinigungsvorrichtung mittels der Übertragungsmittel (c-d),(d) Entfernen des lithografischen Bildes vom Substrat in der Reinigungsvorrichtung, wobei ein wieder verwertbares Substrat erhalten wird,(e) Verwendung des wieder verwertbar gemachten Substrats in einem nächsten, aus den Schritten (a), (b) und (c) und gegebenenfalls auch (d) und (e) gekennzeichneten Zyklus. - Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass die Druckpresse mehrere Farbstationen enthält, die je eine mittels der Übertragungsmittel (a-b) an die gleiche Beschichtungsvorrichtung gekuppelte Belichtungsvorrichtung enthalten.
- Verfahren nach Anspruch 2, dadurch gekennzeichnet, dass die Übertragungsmittel (a-b) eine mechanisch an die Beschichtungsvorrichtung und an jede Belichtungsvorrichtung gekuppelte Stapelvorrichtung enthalten.
- Verfahren nach Anspruch 2 oder 3, dadurch gekennzeichnet, dass jede Farbstation mittels der Übertragungsmittel (c-d) an die gleiche Reinigungsvorrichtung gekuppelt ist.
- Verfahren nach Anspruch 4, dadurch gekennzeichnet, dass die Übertragungsmittel (c-d) eine mechanisch an die Reinigungsvorrichtung und an jede Farbstation gekuppelte Stapelvorrichtung enthalten.
- Ein lithografisches Druckverfahren mit direkter Druckplattenbebilderung, in dem eine mittels Übertragungsmitteln (a-b) mechanisch an eine Off-Press-Belichtungsvorrichtung gekuppelte Off-Press-Beschichtungsvorrichtung, wobei die Belichtungsvorrichtung mittels Übertragungsmitteln (b-c) mechanisch an eine Druckpresse gekuppelt ist, und eine mittels Übertragungsmitteln (c-d) mechanisch an die Druckpresse gekuppelte Off-Press-Reinigungsvorrichtung verwendet werden,
wobei das Verfahren durch folgende Schritte gekennzeichnet ist :(a) Herstellung eines Bilderzeugungsmaterials, indem ein Substrat mittels der Beschichtungsvorrichtung mit einer Bildaufzeichnungsschicht beschichtet und das Bilderzeugungsmaterial mittels der Übertragungsmittel (a-b) von der Beschichtungsvorrichtung zur Belichtungsvorrichtung überführt wird,(b) Herstellung eines ein lithografisches Bild tragenden Druckmasters, indem die Bildaufzeichnungsschicht mittels der Belichtungsvorrichtung belichtet oder mit Wärme beaufschlagt und die belichtete bzw. erwärmte Bildaufzeichnungsschicht wahlweise entwickelt wird, und Übertragung des Druckmasters von der Belichtungsvorrichtung zur Druckpresse mittels der Übertragungsmittel (b-c),(c) Anbringen von Druckfarbe auf das lithografische Bild und Übertragung der Druckfarbe vom lithografischen Bild auf Papier oder ein anderes Empfangsmaterial mittels der Druckpresse und Überführen des Druckmasters von der Druckpresse zur Reinigungsvorrichtung mittels der Übertragungsmittel (c-d),(d) Entfernen des lithografischen Bildes vom Substrat in der Reinigungsvorrichtung, wobei ein wieder verwertbares Substrat erhalten wird,(e) Verwendung des wieder verwertbar gemachten Substrats in einem nächsten, aus den Schritten (a), (b) und (c) und gegebenenfalls auch (d) und (e) gekennzeichneten Zyklus. - Verfahren nach Anspruch 6, dadurch gekennzeichnet, dass die Druckpresse mehrere Farbstationen enthält, die je mittels der Übertragungsmittel (b-c) an die gleiche Belichtungsvorrichtung gekuppelt sind.
- Verfahren nach Anspruch 7, dadurch gekennzeichnet, dass die Übertragungsmittel (b-c) eine mechanisch an die Belichtungsvorrichtung und an jede Farbstation gekuppelte Stapelvorrichtung enthalten.
- Verfahren nach Anspruch 7 oder 8, dadurch gekennzeichnet, dass jede Farbstation mittels der Übertragungsmittel (c-d) an die gleiche Reinigungsvorrichtung gekuppelt ist.
- Verfahren nach Anspruch 9, dadurch gekennzeichnet, dass die Übertragungsmittel (c-d) eine mechanisch an die Reinigungsvorrichtung und an jede Farbstation gekuppelte Stapelvorrichtung enthalten.
- Ein lithografisches Druckverfahren mit direkter Druckplattenbebilderung, in dem folgende Vorrichtungen verwendet werden : eine Off-Press-Beschichtungsvorrichtung, eine Off-Press-Belichtungsvorrichtung, die zusammen mit der Beschichtungsvorrichtung in der gleichen Vorrichtung integriert ist, wobei diese Einheit als Plattenherstellungsvorrichtung definiert wird, die mittels Übertragungsmitteln (b-c) mechanisch an eine Druckpresse gekuppelt ist, und eine mittels Übertragungsmitteln (c-d) mechanisch an die Druckpresse gekuppelte Off-Press-Reinigungsvorrichtung,
wobei das Verfahren durch folgende Schritte gekennzeichnet ist :(a) Herstellung eines Bilderzeugungsmaterials, indem ein Substrat mittels der Beschichtungsvorrichtung mit einer Bildaufzeichnungsschicht beschichtet wird,(b) Herstellung eines ein lithografisches Bild tragenden Druckmasters, indem die Bildaufzeichnungsschicht mittels der Belichtungsvorrichtung belichtet oder mit Wärme beaufschlagt und die belichtete bzw. erwärmte Bildaufzeichnungsschicht wahlweise entwickelt wird, und Übertragung des Druckmasters von der Plattenherstellungsvorrichtung zur Druckpresse mittels der Übertragungsmittel (b-c),(c) Anbringen von Druckfarbe auf das lithografische Bild und Übertragung der Druckfarbe vom lithografischen Bild auf Papier oder ein anderes Empfangsmaterial mittels der Druckpresse und Überführen des Druckmasters von der Druckpresse zur Reinigungsvorrichtung mittels der Übertragungsmittel (c-d),(d) Entfernen des lithografischen Bildes vom Substrat in der Reinigungsvorrichtung, wobei ein wieder verwertbares Substrat erhalten wird,(e) Verwendung des wieder verwertbar gemachten Substrats in einem nächsten, aus den Schritten (a), (b) und (c) und gegebenenfalls auch (d) und (e) gekennzeichneten Zyklus. - Verfahren nach Anspruch 11, dadurch gekennzeichnet, dass die Druckpresse mehrere Farbstationen enthält, die je mittels der Übertragungsmittel (b-c) an die gleiche Plattenherstellungsvorrichtung gekuppelt sind.
- Verfahren nach Anspruch 12, dadurch gekennzeichnet, dass die Übertragungsmittel (b-c) eine mechanisch an die Plattenherstellungsvorrichtung und an jede Farbstation gekuppelte Stapelvorrichtung enthalten.
- Verfahren nach Anspruch 12 oder 13, dadurch gekennzeichnet, dass jede Farbstation mittels der Übertragungsmittel (c-d) an die gleiche Reinigungsvorrichtung gekuppelt ist.
- Verfahren nach Anspruch 14, dadurch gekennzeichnet, dass die Übertragungsmittel (c-d) eine mechanisch an die Reinigungsvorrichtung und an jede Farbstation gekuppelte Stapelvorrichtung enthalten.
- Verfahren nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, dass die Beschichtungsvorrichtung und die Reinigungsvorrichtung in einer Plattenherstellungsvorrichtung integriert sind.
- Verfahren nach einem der Ansprüche 1 bis 15, dadurch gekennzeichnet, dass die Reinigungsvorrichtung mittels der Übertragungsmittel (d-a) an die Beschichtungsvorrichtung gekuppelt ist und das Substrat zwischen den Schritten (d) und (a) mittels der Übertragungsmittel (d-a) von der Reinigungsvorrichtung zur Beschichtungsvorrichtung überführt wird.
- Verfahren nach Anspruch 17, dadurch gekennzeichnet, dass die Übertragungsmittel (d-a) eine an die Beschichtungsvorrichtung und die Reinigungsvorrichtung gekuppelte Stapelvorrichtung enthalten.
- Verfahren nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, dass das Substrat eine hydrophile Oberfläche aufweist und die Bildaufzeichnungsschicht negativarbeitend ist und hydrophobe thermoplastische Polymerteilchen und ein hydrophiles Bindemittel enthält.
- Verfahren nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, dass während Schritt (d) eine Reinigungsflüssigkeit auf das lithografische Bild angebracht wird, wobei es sich um eine Emulsion einer organischen Phase in einer wässrigen Phase handelt.
- Verfahren nach Anspruch 20, dadurch gekennzeichnet, dass die Reinigungsvorrichtung ein Mittel enthält, mit dem die Emulsion durch Vermischen einer organischen Flüssigkeit mit einer wässrigen Flüssigkeit angefertigt wird.
- Verfahren nach Anspruch 20 oder 21, dadurch gekennzeichnet, dass die Reinigungsvorrichtung ein Mittel zur Abtrennung der organischen Phase von der wässrigen Phase enthält.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00203968A EP1142706B1 (de) | 2000-01-18 | 2000-11-14 | "Direct-to-plate" lithographisches Druckverfahren mit automatischer Platten-beschichtung und -reinigung |
US10/007,911 US6694881B2 (en) | 2000-11-14 | 2001-11-08 | Direct-to-plate lithographic printing method using automatic plate-coating and cleaning |
JP2001347275A JP4607395B2 (ja) | 2000-11-14 | 2001-11-13 | 自動的な版コーテイングおよび版クリーニングを用いるダイレクト−ツー−プレート平版印刷方法 |
CA 2361908 CA2361908A1 (en) | 2000-11-14 | 2001-11-13 | Direct-to-plate lithographic printing method using automatic plate-coating and -cleaning |
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00200176 | 2000-01-18 | ||
EP00200178A EP1118472B1 (de) | 2000-01-18 | 2000-01-18 | Flachdruckverfahren mit einem wiederverwendbaren Druckplattenträger |
EP00200176A EP1118470B1 (de) | 2000-01-18 | 2000-01-18 | Flachdruckverfahren mit einer wiederverwendbaren Trägeroberfläche |
EP00200177 | 2000-01-18 | ||
EP00200178 | 2000-01-18 | ||
EP00200177A EP1118471B1 (de) | 2000-01-18 | 2000-01-18 | Flachdruckverfahren mit einer wiederverwendbaren Trägeroberfläche |
EP00203968A EP1142706B1 (de) | 2000-01-18 | 2000-11-14 | "Direct-to-plate" lithographisches Druckverfahren mit automatischer Platten-beschichtung und -reinigung |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1142706A2 EP1142706A2 (de) | 2001-10-10 |
EP1142706A3 EP1142706A3 (de) | 2001-12-19 |
EP1142706B1 true EP1142706B1 (de) | 2005-09-07 |
Family
ID=27439986
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00203968A Expired - Lifetime EP1142706B1 (de) | 2000-01-18 | 2000-11-14 | "Direct-to-plate" lithographisches Druckverfahren mit automatischer Platten-beschichtung und -reinigung |
Country Status (1)
Country | Link |
---|---|
EP (1) | EP1142706B1 (de) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1228871A1 (de) * | 2001-02-06 | 2002-08-07 | Agfa-Gevaert | Gerät zur Oberflächenreinigung |
WO2002087882A1 (fr) * | 2001-04-26 | 2002-11-07 | Mitsubishi Chemical Corporation | Methode et dispositif de traitement et d'impression regeneratifs |
DE10311514B4 (de) * | 2003-03-17 | 2005-10-06 | Heidelberger Druckmaschinen Ag | Verfahren zum Betreiben eines Offset-Druckwerks und Offset-Druckwerk |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5449474A (en) * | 1992-02-21 | 1995-09-12 | Inland Technology, Inc. | Low toxicity solvent composition |
DE4442574C2 (de) * | 1994-11-30 | 1996-11-28 | Koenig & Bauer Albert Ag | Verfahren und Vorrichtung zur Bereitstellung einer Druckplatte |
EP0802457A1 (de) * | 1996-04-16 | 1997-10-22 | Agfa-Gevaert N.V. | Herstellungs- und Bildaufzeichnungsverfahren für Flachdruckplatten |
US5870954A (en) * | 1998-01-22 | 1999-02-16 | Presstek, Inc. | Retractable cleaning system for lithographic printing plates |
EP0940252A1 (de) * | 1998-03-03 | 1999-09-08 | Agfa-Gevaert N.V. | Rotationsdruckmaschine mit einer eingebauten Bildherstellungsvorrichtung bestehend aus einem hohlen, transparenten Belichtungszylinder |
-
2000
- 2000-11-14 EP EP00203968A patent/EP1142706B1/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP1142706A3 (de) | 2001-12-19 |
EP1142706A2 (de) | 2001-10-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6748864B2 (en) | Apparatus for automatic plate coating and cleaning | |
US20030224259A1 (en) | Method of lithographic printing from a reusable aluminum support | |
EP1118472B1 (de) | Flachdruckverfahren mit einem wiederverwendbaren Druckplattenträger | |
US6694881B2 (en) | Direct-to-plate lithographic printing method using automatic plate-coating and cleaning | |
EP1118471B1 (de) | Flachdruckverfahren mit einer wiederverwendbaren Trägeroberfläche | |
EP1243413B1 (de) | Verfahren zur Herstellung einer negativarbeitenden, wärmeempfindlichen, lithographischen Druckplattenvorstufe | |
US6487970B2 (en) | Method of lithographic printing with a reusable substrate | |
EP1142706B1 (de) | "Direct-to-plate" lithographisches Druckverfahren mit automatischer Platten-beschichtung und -reinigung | |
EP1118473B1 (de) | Vorrichtung für die automatische Beschichtung und Reinigung lithographischer Druckplatten | |
EP1118470B1 (de) | Flachdruckverfahren mit einer wiederverwendbaren Trägeroberfläche | |
US6484638B2 (en) | Method of offset printing with a reusable substrate | |
EP1048458B1 (de) | Verfahren zur Herstellung einer lithographischen Druckplatte | |
EP1243411B1 (de) | Tintenstrahlbeschichtungsverfahren für eine Bildaufzeichnungsschicht | |
US6190828B1 (en) | Method for making a lithographic printing master | |
JP4607395B2 (ja) | 自動的な版コーテイングおよび版クリーニングを用いるダイレクト−ツー−プレート平版印刷方法 | |
CA2361905A1 (en) | Apparatus for automatic plate-coating and-cleaning | |
US6820552B2 (en) | Cleaning method for recycling a printing substrate by laser ablation | |
US6460458B2 (en) | Method of planographic printing with a reusable substrate | |
EP1228871A1 (de) | Gerät zur Oberflächenreinigung | |
EP1188579B1 (de) | Flachdruckverfahren mit einer wiederverwendbaren Trägeroberfläche | |
EP1188578B1 (de) | Flachdruckverfahren mit wiederverwendbaren Trägeroberflächen | |
EP1232877B1 (de) | Reinigungsverfahren zur Wiederverwendung eines Druckträgers durch Laserablation | |
US20020136983A1 (en) | Method of coating an image-recording layer by valve-jet | |
EP1243410A1 (de) | Verfahren zur Herstellung eines wärmeempfindlichen Vorläufers für eine Flachdruckplatte | |
DE60007953T2 (de) | Vorrichtung für die automatische Beschichtung und Reinigung lithographischer Druckplatten |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR Kind code of ref document: A2 Designated state(s): DE FR GB |
|
AX | Request for extension of the european patent |
Free format text: AL;LT;LV;MK;RO;SI |
|
PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR |
|
AX | Request for extension of the european patent |
Free format text: AL;LT;LV;MK;RO;SI |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: GOEDEWEECK, RUDI Inventor name: VERSCHUEREN, ERIC |
|
17P | Request for examination filed |
Effective date: 20020619 |
|
AKX | Designation fees paid |
Free format text: DE FR GB |
|
17Q | First examination report despatched |
Effective date: 20040902 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): DE FR GB |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REF | Corresponds to: |
Ref document number: 60022470 Country of ref document: DE Date of ref document: 20051013 Kind code of ref document: P |
|
ET | Fr: translation filed | ||
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20060608 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: 732E |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: TP |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20101019 Year of fee payment: 11 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20101007 Year of fee payment: 11 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20101012 Year of fee payment: 11 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20111114 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20120731 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 60022470 Country of ref document: DE Effective date: 20120601 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20111114 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20111130 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20120601 |