EP1141629B1 - Pulsed combustion device and method - Google Patents
Pulsed combustion device and method Download PDFInfo
- Publication number
- EP1141629B1 EP1141629B1 EP99968404A EP99968404A EP1141629B1 EP 1141629 B1 EP1141629 B1 EP 1141629B1 EP 99968404 A EP99968404 A EP 99968404A EP 99968404 A EP99968404 A EP 99968404A EP 1141629 B1 EP1141629 B1 EP 1141629B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- combustion chamber
- oxidant
- combustion
- pulsed
- fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 116
- 238000000034 method Methods 0.000 title claims description 13
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 27
- 239000007800 oxidant agent Substances 0.000 claims abstract description 25
- 230000001590 oxidative effect Effects 0.000 claims abstract description 25
- 239000000446 fuel Substances 0.000 claims abstract description 22
- 239000012530 fluid Substances 0.000 claims abstract description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 64
- 239000003345 natural gas Substances 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- 239000000567 combustion gas Substances 0.000 claims description 5
- 239000003079 shale oil Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 230000002708 enhancing effect Effects 0.000 claims 1
- 230000001939 inductive effect Effects 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- 230000001172 regenerating effect Effects 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 2
- 238000005094 computer simulation Methods 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 230000010349 pulsation Effects 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C15/00—Apparatus in which combustion takes place in pulses influenced by acoustic resonance in a gas mass
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B36/00—Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones
- E21B36/02—Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones using burners
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04F—PUMPING OF FLUID BY DIRECT CONTACT OF ANOTHER FLUID OR BY USING INERTIA OF FLUID TO BE PUMPED; SIPHONS
- F04F1/00—Pumps using positively or negatively pressurised fluid medium acting directly on the liquid to be pumped
- F04F1/06—Pumps using positively or negatively pressurised fluid medium acting directly on the liquid to be pumped the fluid medium acting on the surface of the liquid to be pumped
- F04F1/16—Pumps using positively or negatively pressurised fluid medium acting directly on the liquid to be pumped the fluid medium acting on the surface of the liquid to be pumped characterised by the fluid medium being suddenly pressurised, e.g. by explosion
Definitions
- the invention relates to a pulsed combustion device comprising the features of the preamble of claim 1 and to a method of using such a device in a natural gas production well and to a method of using the device for heating an underground formation.
- Pulsed combustion devices are known, for example from US patent Nos. 2,899,287; 2,860,484 and 5,044,930, from European patent Nos. 550401 and 636229 and from International patent application PCT/EP93/00961.
- the known devices generally comprise a combustion chamber having an open downstream end and an upstream end which is periodically closable by a one-way valve.
- European patent No. 636229 and International patent application PCT/EP93/00961 disclose downhole pulsed combustor devices that have cylindrical combustion chambers into which small quantities of air are periodically injected to ignite a fraction of the volume of natural gas in the chamber so as to enhance the flow of natural gas to the wellhead.
- a disadvantage of these known devices is that they require complex procedures to start up and control the pulsed combustion process and that they have a rather low pumping efficiency.
- the pulsed combustion device disclosed in US patent No. 2,860,484 can be used to generate driving and/or heat energy.
- the known device comprises a tubular combustion chamber having an upstream end which is equipped with a non-return valve and an open downstream end which defines a tailpipe section which is slightly narrower than the rest of the combustion chamber.
- the combustion chamber is arranged co-axially within a tube in which another non-return valve is arranged upstream of the combustion chamber.
- the second non-return valve is closed periodically by high pressure fronts which are reflected from the downstream end of the combustion chamber back through the annulus surrounding the chamber.
- US patent No. 2,899,287 discloses a pulsed combustor which comprises either a single tubular combustion chamber or two parallel tubular combustion chambers.
- each combustion chamber has an open tailpipe having a slightly smaller internal diameter than the rest of the combustion chamber and a fuel injection pump which injects accurately defined quantities of fuel into each combustion chamber to control the combustion process.
- the known device has a single combustion chamber then it is equipped with a mechanical non-return valve and if it has two parallel combustion chambers then it is equipped with a pair of aerodynamic non-return valves.
- These aerodynamic valves comprise U-shaped regenerative tube systems, which have an inlet close to the downstream end of the combustion chamber and which convey combustion gas pressure pulses back to the inlet and which tend to adjust themselves into phase-opposition.
- a disadvantage of the pulsed combustor known from US patent 2,899,287 is that it is not suitable for downhole use since it is not feasible to install downhole a fuel injection pump which remains stable over a period of several years and there is no room available to install two parallel combustion chambers with associated non-return valves and a U-shaped regenerative tube system.
- French patent No. 1252585 discloses another oscillating heating device with a Helmholz oscillator and a U-shaped regenerative tube between the downstream and the upstream end of the combustion chamber, which is not suitable for use in a well because of the lack of space available for such a U-shaped regenerative tube.
- the pulsed combustion device comprises a substantially tubular combustion chamber having an upstream and a downstream end, separate fuel and oxidant supply conduits for supplying fuel and oxidant to the combustion chamber, one of said conduits having a fluid discharge port debouching into the combustion chamber between the upstream and downstream ends thereof, the other of said conduits having a fluid discharge port located at the upstream end of the chamber which discharge port is equipped with return flow limitation means which limit flow of combustion fluids from the combustion chamber into the fluid supply conduit, characterised in that the combustion chamber is shaped as a Helmholz resonator having a tailpipe section near the downstream end of which the smallest cross-sectional area is between 0.15 and 0.30 times the average cross-sectional area of the other parts of the combustion chamber.
- the tailpipe and the other parts of the combustion chamber have a cylindrical or conical shape.
- the pulsed combustor according to the invention is used to compress natural gas downhole in a gas production well, as defined in claim 6, then it is installed inside a production tubing by means of a pair of expandable packers and air or another oxidant such as oxygen is fed to the device via a supply conduit in the casing-tubing annulus, which conduit is connected to an orifice in the production tubing which is located between the two packers.
- the air or oxidant is then allowed to flow into the combustion chamber from the annular space between the packers via an oxidant supply port which debouches into the combustion chamber between the upstream and downstream end thereof.
- the return flow limitation means comprise one or more flapper-type discharge or non-return valves.
- the pulsed combustor device according to the invention is used to heat the underground formation which surrounds the wellbore in which one or more pulsed combustion devices are operated.
- the method according to claim 7 comprises feeding fuel and oxidant to each pulsed combustor device via fuel and oxidant supply conduits which extend from the wellhead into the well and repeatedly allowing in each pulsed combustor device the oxidant to react with a fraction of the fuel fed into the combustion chamber thereby generating a high pressure wave front which is inhibited at the upstream end of each combustion chamber by the return flow limitation means and which is enhanced at the downstream end of said chamber by the tailpipe section. At the downstream end of the tailpipe section the high pressure wave front is reflected and followed by a low pressure wave front which induces oxidant and fuel to flow into the combustion chamber.
- the return flow limitation means of the heater device comprise one or more aerovalves which do not comprise any movable parts or a regenerative tube system extending between the downstream and upstream ends of the combustion chamber.
- a string of pulsed combustor devices is suspended from the wellhead from the oxidant and fuel supply conduits such that the devices are axially spaced in the well.
- Such a string of axially spaced pulsed combustion devices is particularly suitable to heat underground shale or heavy oil reservoirs such that the reservoir temperature in the region of the wellbore is between 600 and 800 K.
- the pulsed combustor device is able to operate in a stable manner at such high temperatures over periods of many years and provides a cost-effective alternative to existing electrical and catalytic flameless combustion downhole heating devices.
- a pulsed combustor device 1 which is located in a production tubing 2 in a natural gas production well 3 which traverses an underground formation 4.
- the pulsed combustor device 1 is sealingly secured inside the production tubing 2 by means of a pair of expandable packers 5.
- Air or another oxidant represented in the drawing as O 2
- O 2 Air or another oxidant, represented in the drawing as O 2
- an air supply tube 6 which extends from the wellhead (not shown) through the tubing/casing annulus to an orifice 7 in the tubing 2 between the packers 5.
- the air flows from the orifice 7 via annular spaces 8 to a series of air discharge ports 9 which debouch into a combustion chamber 10 of the device 1 at a location between an upstream end 11 and a downstream end 12 of said chamber 10.
- a series of flapper-type discharge or non-return valves 13 is arranged at the upstream end 11 of the combustion chamber 10 which valves allow natural gas, represented in the drawing as CH 4 , to flow from the production tubing 2 below the device into the combustion chamber 10, but which prevent natural gas and/or combustion products, represented in the drawing as CO 2 + H 2 O to flow back from the combustion chamber 10 into the production tubing 2 below the device 1.
- the combustion chamber 10 is shaped as a Helmholz resonator wherein the chamber 10 is provided with a narrow and elongated tailpipe 15 which has a smallest diameter D T , which preferably is between 0.3 and 0.5 times the average diameter D C of the cylindrical lower part of the combustion chamber.
- D T /D C ratio is optimal since the highest pressure fluctuations and the highest massflow of natural gas through the device 1 are achieved at lowest fuel consumption as will be explained in more detail with reference to Fig. 3.
- the device 1 of Fig. 1 is equipped with a glow plug 16 to which electrical power is supplied via a power cable 17.
- the glow plug 16 is continuously activated during operation of the device 1 and is generally not switched off when the device 1 has reached its normal operating temperature since if the device 1 is used as a downhole gas compressor its operating temperature is maintained at such a low level that there is no spontaneous combustion of the natural gas.
- the frequency of the pulsed combustion process is dictated by the Helmholz effect and is typically between 10 and 50 cycles per second.
- a high pressure wave front is generated which is followed by a low pressure wave front.
- Both wavefronts are enhanced by the Helmholz effect so that a maximum amount of natural gas is sucked into the chamber 10 when the low pressure wave front reaches the upstream end thereof and also a maximum amount of natural gas and combustion gases are pressed via the tailpipe 15 through the downstream end of the chamber 10 as a result of the high pressure wave front.
- the divergent shape of the tailpipe 15 further enhances the mass flow through the combustion chamber.
- the device 1 is used as a downhole compressor in a natural gas production well only a relatively small amount of air or other oxidant, such as pure oxygen, is supplied to the combustion chamber such that less than 10% of the natural gas flowing through the production tubing 2 is combusted.
- a relatively small amount of air or other oxidant such as pure oxygen
- FIG. 2 there is shown a heat injection well 20 which traverses an underground shale or heavy oil bearing formation 21.
- the devices 22 are suspended from a central methane injection tube 23 which passes through the centre of each of the devices 22.
- An air injection tube 24 is connected to an air inlet chamber 25 of each device 22 via an orifice 26.
- the air inlet chamber 25 is connected to the combustion chamber 27 via a number of aerovalves 28, which allow air to flow up from the air inlet into the combustion chamber but which inhibit combustion gas to flow back from the combustion into the air inlet chamber.
- methane (CH 4 ) or another fuel is injected via the methane injection tube 23 and a series of methane discharge ports 29 into the combustion chambers 27.
- air is injected into the chambers 27 via the aerovalves 28 which causes at the elevated temperature in the combustion chambers 27 a pulsed combustion process to take place.
- the combustion process is only assisted by a glow plug (not shown) during start-up, whereas during normal operation spontaneous combustion of the methane occurs in the combustion chambers as a result of the prevailing pressure and temperature in the chambers 27.
- cross-sectional area of the tailpipe is represented as AT and the cross-sectional area of the upstream part 32 of the combustion chamber as A C .
- the cross-sectional area A M of the methane injection tube 23 at the centre of the devices 22 does not count as part of the cross-sectional areas A T and A C of the tail pipes and upstream parts 32 of the combustion chambers 22.
- the ratio A T /A C is selected between 0.15 and 0.25 on the basis of the following analysis.
- thermoacoustical pulsations in a pulse combustor may be studied by linear analysis of the one-dimensional conservation equations for mass, momentum and energy. It was found that the pulsations get the more damped,
- the standard geometry ratio between the cross-sectional areas of the tail pipe and the other parts of the combustion chamber deviates from common dimensions of pulse combustors in industrial and scientific applications.
- a set of computer simulations has been done to investigate whether a change in the cross-sectional area ratio A T /A C can improve the performance of the pulse combustor.
- the minimum tail pipe diameter is the only parameter that is changed in these simulations.
- Fig. 3 shows that an optimal tail pipe cross-sectional area does indeed exist for a given compression ratio at which the combusted fraction of methane is minimal.
- a minimal methane combustion at a given compression rate is a clear indication that the pulsed combustion process performs in an optimal manner.
- Fig. 3 indicates that an optimum A T /A C ratio is between 0.15 and 0.25.
- the string of devices 22 may extend along the entire depth of the shale oil formation. If required the heat injection well 20 may be inclined or horizontal and may be an open or a cased hole.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Mining & Mineral Resources (AREA)
- General Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Fluidized-Bed Combustion And Resonant Combustion (AREA)
Abstract
Description
- The invention relates to a pulsed combustion device comprising the features of the preamble of claim 1 and to a method of using such a device in a natural gas production well and to a method of using the device for heating an underground formation.
- Pulsed combustion devices are known, for example from US patent Nos. 2,899,287; 2,860,484 and 5,044,930, from European patent Nos. 550401 and 636229 and from International patent application PCT/EP93/00961.
- The known devices generally comprise a combustion chamber having an open downstream end and an upstream end which is periodically closable by a one-way valve.
- European patent No. 636229 and International patent application PCT/EP93/00961 disclose downhole pulsed combustor devices that have cylindrical combustion chambers into which small quantities of air are periodically injected to ignite a fraction of the volume of natural gas in the chamber so as to enhance the flow of natural gas to the wellhead.
- A disadvantage of these known devices is that they require complex procedures to start up and control the pulsed combustion process and that they have a rather low pumping efficiency.
- The pulsed combustion device disclosed in US patent No. 2,860,484 can be used to generate driving and/or heat energy. The known device comprises a tubular combustion chamber having an upstream end which is equipped with a non-return valve and an open downstream end which defines a tailpipe section which is slightly narrower than the rest of the combustion chamber. The combustion chamber is arranged co-axially within a tube in which another non-return valve is arranged upstream of the combustion chamber. The second non-return valve is closed periodically by high pressure fronts which are reflected from the downstream end of the combustion chamber back through the annulus surrounding the chamber. The presence of two non-return valves which must open and close sequentially is not attractive for downhole use since varying wear, friction and pollution of the valves can easily result in an incorrect and out of phase opening and/or closing of the two valves which may eventually result in stalling of the device.
- US patent No. 2,899,287 discloses a pulsed combustor which comprises either a single tubular combustion chamber or two parallel tubular combustion chambers. In each case each combustion chamber has an open tailpipe having a slightly smaller internal diameter than the rest of the combustion chamber and a fuel injection pump which injects accurately defined quantities of fuel into each combustion chamber to control the combustion process.
- If the known device has a single combustion chamber then it is equipped with a mechanical non-return valve and if it has two parallel combustion chambers then it is equipped with a pair of aerodynamic non-return valves. These aerodynamic valves comprise U-shaped regenerative tube systems, which have an inlet close to the downstream end of the combustion chamber and which convey combustion gas pressure pulses back to the inlet and which tend to adjust themselves into phase-opposition.
- A disadvantage of the pulsed combustor known from US patent 2,899,287 is that it is not suitable for downhole use since it is not feasible to install downhole a fuel injection pump which remains stable over a period of several years and there is no room available to install two parallel combustion chambers with associated non-return valves and a U-shaped regenerative tube system.
- French patent No. 1252585 discloses another oscillating heating device with a Helmholz oscillator and a U-shaped regenerative tube between the downstream and the upstream end of the combustion chamber, which is not suitable for use in a well because of the lack of space available for such a U-shaped regenerative tube.
- It is an object of the present invention to provide a pulsed combustion device and method which are able to operate safely and efficiently under varying downhole conditions and which comprise a minimum of wear prone components so that only minimal maintenance and inspection is required.
- The pulsed combustion device according to the invention thereto comprises a substantially tubular combustion chamber having an upstream and a downstream end, separate fuel and oxidant supply conduits for supplying fuel and oxidant to the combustion chamber, one of said conduits having a fluid discharge port debouching into the combustion chamber between the upstream and downstream ends thereof, the other of said conduits having a fluid discharge port located at the upstream end of the chamber which discharge port is equipped with return flow limitation means which limit flow of combustion fluids from the combustion chamber into the fluid supply conduit, characterised in that the combustion chamber is shaped as a Helmholz resonator having a tailpipe section near the downstream end of which the smallest cross-sectional area is between 0.15 and 0.30 times the average cross-sectional area of the other parts of the combustion chamber.
- It has been found that by properly shaping the combustion chamber as a Helmholz resonator the pulsed combustor device becomes self-aspiring and discharging without requiring a U-shaped regenerative tube.
- Preferably the tailpipe and the other parts of the combustion chamber have a cylindrical or conical shape.
- Experiments revealed that the above combustion chamber geometry is optimal since it transmits a significant part of the pressure fluctuations from inside the combustion chamber to the outlet of the tailpipe without destroying the pulse combustion process.
- If the pulsed combustor according to the invention is used to compress natural gas downhole in a gas production well, as defined in
claim 6, then it is installed inside a production tubing by means of a pair of expandable packers and air or another oxidant such as oxygen is fed to the device via a supply conduit in the casing-tubing annulus, which conduit is connected to an orifice in the production tubing which is located between the two packers. The air or oxidant is then allowed to flow into the combustion chamber from the annular space between the packers via an oxidant supply port which debouches into the combustion chamber between the upstream and downstream end thereof. - In that case it is preferred that the return flow limitation means comprise one or more flapper-type discharge or non-return valves.
- Alternatively, the pulsed combustor device according to the invention is used to heat the underground formation which surrounds the wellbore in which one or more pulsed combustion devices are operated.
- In that case the method according to
claim 7 comprises feeding fuel and oxidant to each pulsed combustor device via fuel and oxidant supply conduits which extend from the wellhead into the well and repeatedly allowing in each pulsed combustor device the oxidant to react with a fraction of the fuel fed into the combustion chamber thereby generating a high pressure wave front which is inhibited at the upstream end of each combustion chamber by the return flow limitation means and which is enhanced at the downstream end of said chamber by the tailpipe section. At the downstream end of the tailpipe section the high pressure wave front is reflected and followed by a low pressure wave front which induces oxidant and fuel to flow into the combustion chamber. - It is preferred that the return flow limitation means of the heater device comprise one or more aerovalves which do not comprise any movable parts or a regenerative tube system extending between the downstream and upstream ends of the combustion chamber.
- Preferably a string of pulsed combustor devices is suspended from the wellhead from the oxidant and fuel supply conduits such that the devices are axially spaced in the well.
- Such a string of axially spaced pulsed combustion devices is particularly suitable to heat underground shale or heavy oil reservoirs such that the reservoir temperature in the region of the wellbore is between 600 and 800 K.
- Experiments have revealed that the pulsed combustor device is able to operate in a stable manner at such high temperatures over periods of many years and provides a cost-effective alternative to existing electrical and catalytic flameless combustion downhole heating devices.
- The invention will be described in more detail with reference to the accompanying drawings in which:
- Fig. 1 is a longitudinal sectional view of a pulsed combustor device according to the invention in a production tubing of a natural gas production well;
- Fig. 2 is a longitudinal sectional view of two pulsed combustor devices according to the invention which are used to heat an underground formation; and
- Fig. 3 is a graph in which the fraction of combusted methane is plotted against the ratio AT/AC between the minimum cross-sectional areas of the tail pipe and other parts of the combustion chamber.
-
- Referring to Fig. 1 there is shown a pulsed combustor device 1 which is located in a
production tubing 2 in a naturalgas production well 3 which traverses an underground formation 4. - The pulsed combustor device 1 is sealingly secured inside the
production tubing 2 by means of a pair ofexpandable packers 5. - Air or another oxidant, represented in the drawing as O2, is fed to the device 1 via an
air supply tube 6 which extends from the wellhead (not shown) through the tubing/casing annulus to anorifice 7 in thetubing 2 between thepackers 5. - The air flows from the
orifice 7 viaannular spaces 8 to a series of air discharge ports 9 which debouch into acombustion chamber 10 of the device 1 at a location between anupstream end 11 and adownstream end 12 of saidchamber 10. - A series of flapper-type discharge or
non-return valves 13 is arranged at theupstream end 11 of thecombustion chamber 10 which valves allow natural gas, represented in the drawing as CH4, to flow from theproduction tubing 2 below the device into thecombustion chamber 10, but which prevent natural gas and/or combustion products, represented in the drawing as CO2 + H2O to flow back from thecombustion chamber 10 into theproduction tubing 2 below the device 1. - In accordance with the present invention the
combustion chamber 10 is shaped as a Helmholz resonator wherein thechamber 10 is provided with a narrow andelongated tailpipe 15 which has a smallest diameter DT, which preferably is between 0.3 and 0.5 times the average diameter DC of the cylindrical lower part of the combustion chamber. Experiments and computer calculations have indicated that this DT/DC ratio is optimal since the highest pressure fluctuations and the highest massflow of natural gas through the device 1 are achieved at lowest fuel consumption as will be explained in more detail with reference to Fig. 3. - The device 1 of Fig. 1 is equipped with a
glow plug 16 to which electrical power is supplied via apower cable 17. Theglow plug 16 is continuously activated during operation of the device 1 and is generally not switched off when the device 1 has reached its normal operating temperature since if the device 1 is used as a downhole gas compressor its operating temperature is maintained at such a low level that there is no spontaneous combustion of the natural gas. - During normal operation of the device 1 pulsed combustion takes place in the
combustion chamber 10. - The frequency of the pulsed combustion process is dictated by the Helmholz effect and is typically between 10 and 50 cycles per second.
- During each cycle a high pressure wave front is generated which is followed by a low pressure wave front. Both wavefronts are enhanced by the Helmholz effect so that a maximum amount of natural gas is sucked into the
chamber 10 when the low pressure wave front reaches the upstream end thereof and also a maximum amount of natural gas and combustion gases are pressed via thetailpipe 15 through the downstream end of thechamber 10 as a result of the high pressure wave front. The divergent shape of thetailpipe 15 further enhances the mass flow through the combustion chamber. - If the device 1 is used as a downhole compressor in a natural gas production well only a relatively small amount of air or other oxidant, such as pure oxygen, is supplied to the combustion chamber such that less than 10% of the natural gas flowing through the
production tubing 2 is combusted. The presence of a small fraction of combustion gases only provides insignificant pollution of the produced natural gas. - Referring to Fig. 2 there is shown a heat injection well 20 which traverses an underground shale or heavy
oil bearing formation 21. - In the well 20 a string of pulsed combustion devices 22 according to the invention is suspended.
- The devices 22 are suspended from a central
methane injection tube 23 which passes through the centre of each of the devices 22. Anair injection tube 24 is connected to anair inlet chamber 25 of each device 22 via anorifice 26. - The
air inlet chamber 25 is connected to thecombustion chamber 27 via a number ofaerovalves 28, which allow air to flow up from the air inlet into the combustion chamber but which inhibit combustion gas to flow back from the combustion into the air inlet chamber. - During normal operation of the devices 22 methane (CH4) or another fuel is injected via the
methane injection tube 23 and a series ofmethane discharge ports 29 into thecombustion chambers 27. At the same time air is injected into thechambers 27 via theaerovalves 28 which causes at the elevated temperature in the combustion chambers 27 a pulsed combustion process to take place. - If the devices 22 are used as heaters the combustion process is only assisted by a glow plug (not shown) during start-up, whereas during normal operation spontaneous combustion of the methane occurs in the combustion chambers as a result of the prevailing pressure and temperature in the
chambers 27. - During each combustion cycle high and low pressure wave fronts develop in the combustion chambers 22 at a frequency which is dictated by the Helmholz effect, which is induced by the presence of a
tailpipe 30 at thedownstream end 31 of each combustion chamber which is relatively narrow compared to theupstream part 32 of each combustion chamber. - In the example shown the cross-sectional area of the tailpipe is represented as AT and the cross-sectional area of the
upstream part 32 of the combustion chamber as AC. - It will be understood that the cross-sectional area AM of the
methane injection tube 23 at the centre of the devices 22 does not count as part of the cross-sectional areas AT and AC of the tail pipes andupstream parts 32 of the combustion chambers 22. In the example shown the ratio AT/AC is selected between 0.15 and 0.25 on the basis of the following analysis. - Experiments revealed that the onset of thermoacoustical pulsations in a pulse combustor may be studied by linear analysis of the one-dimensional conservation equations for mass, momentum and energy. It was found that the pulsations get the more damped,
- a) the larger the gas velocity through the
combustion chamber 27 is; - b) the shorter the
upstream part 32 of the combustion chamber is relative to the length of thetail pipe 30; - c) the smaller the diameter of the
tail pipe 30 is relative to that of theupstream part 32 of the combustion chamber. -
- On the other hand it has been found that the pressure build up in the
combustion chamber 27 is the larger, the more closed-off thecombustion chamber 27 is. So there must be an optimum tail pipe diameter at which the highest pressure fluctuations are achieved. - The standard geometry ratio between the cross-sectional areas of the tail pipe and the other parts of the combustion chamber deviates from common dimensions of pulse combustors in industrial and scientific applications. A set of computer simulations has been done to investigate whether a change in the cross-sectional area ratio AT/AC can improve the performance of the pulse combustor. The minimum tail pipe diameter is the only parameter that is changed in these simulations.
- The results of these computer simulations and experiments are shown in Fig. 3.
- Fig. 3 shows that an optimal tail pipe cross-sectional area does indeed exist for a given compression ratio at which the combusted fraction of methane is minimal. A minimal methane combustion at a given compression rate is a clear indication that the pulsed combustion process performs in an optimal manner. Fig. 3 indicates that an optimum AT/AC ratio is between 0.15 and 0.25.
- Also for the heater assembly shown in Fig. 2 it is important to have an optimal compression ratio since this ensures a stable operation of the device 22.
- The string of devices 22 may extend along the entire depth of the shale oil formation. If required the heat injection well 20 may be inclined or horizontal and may be an open or a cased hole.
Claims (10)
- A pulsed combustion device (1,22) for use in an underground borehole (3,20), the device comprising a substantially tubular combustion chamber (10,27) having an upstream (11) and a downstream end (12), separate fuel and oxidant supply conduits (2,23,6,24) for supplying fuel and oxidant to the combustion chamber, one of said conduits having a fluid discharge port (9,29) debouching into the combustion chamber between the upstream and downstream ends (11,12) thereof, the other of said conduits (2,24) having a fluid discharge port located at the upstream end (11) of the chamber (10,27), which discharge port is equipped with return flow limitation means (13,28) which limit flow of combustion fluids from the combustion chamber (10,27) into the fluid supply conduit (2,24), characterised in that the combustion chamber is shaped as a Helmholz resonator having a tailpipe section (15,30) near the downstream end (12) of which the smallest cross-sectional area is between 0.15 and 0.30 times the average cross-sectional area of the other parts of the combustion chamber (10,27).
- The pulsed combustion device of claim 1 wherein the tailpipe (15,30) and the other parts of the combustion chamber (10,27) have a cylindrical or conical shape.
- The pulsed combustor device of claim 2 wherein the tailpipe (15,30) has a tapered divergent conical shape and the other parts of the combustion chamber (10,27) have a substantially cylindrical shape.
- The pulsed combustor device of claim 1 wherein the return flow limitation means comprise one or more discharge or non-return valves (13).
- The pulsed combustor device of claim 1 wherein the return flow limitation means comprise one or more aerovalves (28) which do not have movable parts.
- A method of enhancing fluid flow in a natural gas production well (3), the method comprising installing a pulsed combustor device (1) according to claim 4 in the well production tubing (2) such that a seal (5) is created between the outer surface of the combustion chamber (10) and the inner surface of the production tubing (2), injecting an oxidant through the supply conduit (6) which has a fluid discharge port (9) which debouches into the combustion chamber (10) between the upstream and downstream ends (11,12) thereof, allowing the oxidant to react with a fraction of the natural gas present in the combustion chamber (10) thereby generating a high pressure wave front which is inhibited at the upstream end of the combustion chamber by the return flow limitation means (13) and which is enhanced at the downstream end (12) of the combustion chamber by the tailpipe section (15) thereby inducing the mixture and combustion gases to flow up through the production tubing (2), which high pressure wave front is followed by a low pressure wave front which induces natural gas to flow into the combustion chamber via the return flow limitation means (13); characterised in that the combustion chamber is shaped as a Helmholz resonator having a tailpipe section (15,30) near the downstream end (12) of which the smallest cross-sectional area is between 0.15 and 0.30 times the average cross-sectional area of the other parts of the combustion chamber (10,27).
- A method of heating an underground formation, the method comprising lowering into a well (30) traversing the formation (21) at least one pulsed combustor device (22) according to claim 1 into the well, feeding fuel and oxidant to each pulsed combustor device via fuel and oxidant supply conduits (23,24) which extend from the wellhead into the well and repeatedly allowing in each pulsed combustor device (23,24) the oxidant to react with a fraction of the fuel fed into the combustion chamber (27) thereby generating a high pressure wave front which is inhibited at the upstream end of each combustion chamber by the return flow limitation means (28) and which is enhanced at the downstream end of said chamber by the tailpipe section (30), which high pressure wave front is followed by a low pressure wave front which induces oxidant and fuel to flow into the combustion chamber (27); characterised in that the combustion chamber is shaped as a Helmholz resonator having a tailpipe section (15,30) near the downstream end (12) of which the smallest cross-sectional area is between 0.15 and 0.30 times the average cross-sectional area of the other parts of the combustion chamber (10,27).
- The method of claim 7 wherein a string of pulsed combustor devices (22) is suspended from the wellhead from the oxidant and fuel supply conduits (23,24) such that the devices (22) are axially spaced in the well (20).
- The method of claim 8 wherein fuel in the form of methane is fed to each of the devices via a methane supply conduit (23) which passes through the centre of the combustion chamber (27) and tailpipe (30) of at least one pulsed combustor device (22) and methane is injected into the combustion chamber of each device via a methane discharge port (29) located between the upstream and downstream ends of the chamber (27) whereas oxidant is supplied via an oxidant discharge port (26) at the upstream end of the combustion chamber (27).
- The method of claim 7 wherein the underground formation (21) contains shale oil and the pulsed combustor devices (22) are operated such that the shale oil containing formation (21) in the region of the well (20) is between 600 and 800 K.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP99968404A EP1141629B1 (en) | 1998-12-30 | 1999-12-29 | Pulsed combustion device and method |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP98310784 | 1998-12-30 | ||
EP98310784 | 1998-12-30 | ||
EP99968404A EP1141629B1 (en) | 1998-12-30 | 1999-12-29 | Pulsed combustion device and method |
PCT/EP1999/010499 WO2000040898A1 (en) | 1998-12-30 | 1999-12-29 | Pulsed combustion device and method |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1141629A1 EP1141629A1 (en) | 2001-10-10 |
EP1141629B1 true EP1141629B1 (en) | 2004-09-15 |
Family
ID=8235233
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99968404A Expired - Lifetime EP1141629B1 (en) | 1998-12-30 | 1999-12-29 | Pulsed combustion device and method |
Country Status (18)
Country | Link |
---|---|
EP (1) | EP1141629B1 (en) |
CN (1) | CN1158472C (en) |
AR (1) | AR023360A1 (en) |
AT (1) | ATE276481T1 (en) |
AU (1) | AU747930B2 (en) |
BR (1) | BR9916720A (en) |
CA (1) | CA2356425C (en) |
DE (1) | DE69920269D1 (en) |
EA (1) | EA002434B1 (en) |
GC (1) | GC0000118A (en) |
HU (1) | HUP0104947A3 (en) |
ID (1) | ID29049A (en) |
IL (1) | IL143926A0 (en) |
NO (1) | NO321554B1 (en) |
NZ (1) | NZ512564A (en) |
OA (1) | OA11815A (en) |
TR (1) | TR200101890T2 (en) |
WO (1) | WO2000040898A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104595928B (en) * | 2015-01-23 | 2020-02-14 | 北京华清燃气轮机与煤气化联合循环工程技术有限公司 | Acoustic flame tube of diffusion combustion chamber |
CN109945189B (en) * | 2019-03-20 | 2023-09-05 | 中国矿业大学 | A low-concentration gas pulsating burner with improved main pipe |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1252585A (en) * | 1960-04-04 | 1961-01-27 | Egerspacher J | Turbine installation, in particular heating device, comprising an oscillating burner |
US5059404A (en) * | 1989-02-14 | 1991-10-22 | Manufacturing And Technology Conversion International, Inc. | Indirectly heated thermochemical reactor apparatus and processes |
JP2726487B2 (en) * | 1989-03-31 | 1998-03-11 | 株式会社東芝 | Pulse burner |
DE69315829T2 (en) * | 1992-04-22 | 1998-04-09 | Shell Int Research | METHOD AND DEVICE FOR COMPRESSING A FLAMMABLE GAS FLOWING A PIPE |
-
1999
- 1999-12-23 AR ARP990106720A patent/AR023360A1/en not_active Application Discontinuation
- 1999-12-25 GC GCP1999463 patent/GC0000118A/en active
- 1999-12-29 HU HU0104947A patent/HUP0104947A3/en unknown
- 1999-12-29 CA CA002356425A patent/CA2356425C/en not_active Expired - Fee Related
- 1999-12-29 DE DE69920269T patent/DE69920269D1/en not_active Expired - Lifetime
- 1999-12-29 OA OA1200100176A patent/OA11815A/en unknown
- 1999-12-29 WO PCT/EP1999/010499 patent/WO2000040898A1/en active IP Right Grant
- 1999-12-29 AT AT99968404T patent/ATE276481T1/en not_active IP Right Cessation
- 1999-12-29 CN CNB998152803A patent/CN1158472C/en not_active Expired - Fee Related
- 1999-12-29 NZ NZ512564A patent/NZ512564A/en unknown
- 1999-12-29 ID IDW00200101409A patent/ID29049A/en unknown
- 1999-12-29 BR BR9916720-4A patent/BR9916720A/en active Search and Examination
- 1999-12-29 IL IL14392699A patent/IL143926A0/en unknown
- 1999-12-29 AU AU25405/00A patent/AU747930B2/en not_active Ceased
- 1999-12-29 TR TR2001/01890T patent/TR200101890T2/en unknown
- 1999-12-29 EA EA200100724A patent/EA002434B1/en not_active IP Right Cessation
- 1999-12-29 EP EP99968404A patent/EP1141629B1/en not_active Expired - Lifetime
-
2001
- 2001-06-29 NO NO20013261A patent/NO321554B1/en unknown
Also Published As
Publication number | Publication date |
---|---|
AR023360A1 (en) | 2002-09-04 |
CN1158472C (en) | 2004-07-21 |
CA2356425C (en) | 2009-01-27 |
CA2356425A1 (en) | 2000-07-13 |
CN1332836A (en) | 2002-01-23 |
GC0000118A (en) | 2005-06-29 |
AU2540500A (en) | 2000-07-24 |
ID29049A (en) | 2001-07-26 |
NO20013261L (en) | 2001-08-22 |
DE69920269D1 (en) | 2004-10-21 |
HUP0104947A2 (en) | 2002-04-29 |
ATE276481T1 (en) | 2004-10-15 |
IL143926A0 (en) | 2002-04-21 |
TR200101890T2 (en) | 2001-11-21 |
EP1141629A1 (en) | 2001-10-10 |
NO20013261D0 (en) | 2001-06-29 |
AU747930B2 (en) | 2002-05-30 |
OA11815A (en) | 2005-08-16 |
WO2000040898A1 (en) | 2000-07-13 |
NO321554B1 (en) | 2006-05-29 |
EA002434B1 (en) | 2002-04-25 |
EA200100724A1 (en) | 2001-12-24 |
HUP0104947A3 (en) | 2002-05-28 |
NZ512564A (en) | 2002-12-20 |
BR9916720A (en) | 2001-12-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2818692C (en) | Combustion thermal generator and systems and methods for enhanced oil recovery | |
US20130161007A1 (en) | Pulse detonation tool, method and system for formation fracturing | |
US8950471B2 (en) | Method of operation of a downhole gas generator with multiple combustion chambers | |
US20090008096A1 (en) | Treating Subterranean Zones | |
NO331937B1 (en) | Oil wells and methods to facilitate and stabilize production | |
EP1141629B1 (en) | Pulsed combustion device and method | |
MXPA01006764A (en) | Pulsed combustion device and method | |
WO2014022831A1 (en) | Downhole gas generator with multiple combustion chambers and method of operation | |
US6044907A (en) | Two phase heat generation system and method | |
EP0636228B1 (en) | Compressing combustible gas flowing through a conduit | |
RU2410535C1 (en) | Development method of high-viscosity oil deposit | |
US20230383942A1 (en) | Steam generator tool | |
EA047906B1 (en) | STEAM GENERATOR TOOL | |
CN103313798B (en) | Combustion heat generator and the system and method for the oil exploitation for strengthening | |
CA2716614A1 (en) | Direct fired conductive subterranean heating system | |
RU98123120A (en) | METHOD FOR INCREASING EFFICIENCY OF THERMOCHEMICAL TREATMENT OF WELLS AND BOTTOM ZONES |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20010618 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
|
AX | Request for extension of the european patent |
Free format text: AL;LT;LV;MK;RO;SI |
|
17Q | First examination report despatched |
Effective date: 20030821 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20040915 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED. Effective date: 20040915 Ref country code: FR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20040915 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20040915 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20040915 Ref country code: CH Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20040915 Ref country code: BE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20040915 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20040915 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REF | Corresponds to: |
Ref document number: 69920269 Country of ref document: DE Date of ref document: 20041021 Kind code of ref document: P |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20041215 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20041215 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20041215 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20041216 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20041226 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20041229 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20041230 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20041231 |
|
LTIE | Lt: invalidation of european patent or patent extension |
Effective date: 20040915 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20050616 |
|
EN | Fr: translation not filed | ||
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050215 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20071228 Year of fee payment: 9 |
|
NLV4 | Nl: lapsed or anulled due to non-payment of the annual fee |
Effective date: 20090701 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20090701 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20171227 Year of fee payment: 19 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20181229 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181229 |