Classifications

• • G—PHYSICS
  • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
  • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
  • G03G7/00—Selection of materials for use in image-receiving members, i.e. for reversal by physical contact; Manufacture thereof
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
  • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
  • D21H21/16—Sizing or water-repelling agents
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
  • D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
  • D21H17/72—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic material
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
  • D21H17/03—Non-macromolecular organic compounds
  • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
  • D21H17/14—Carboxylic acids; Derivatives thereof
  • D21H17/15—Polycarboxylic acids, e.g. maleic acid
  • D21H17/16—Addition products thereof with hydrocarbons
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
  • D21H17/03—Non-macromolecular organic compounds
  • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
  • D21H17/17—Ketenes, e.g. ketene dimers
• • G—PHYSICS
  • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
  • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
  • G03G7/00—Selection of materials for use in image-receiving members, i.e. for reversal by physical contact; Manufacture thereof
  • G03G7/006—Substrates for image-receiving members; Image-receiving members comprising only one layer
  • G03G7/0073—Organic components thereof

Definitions

• This invention relates to processes for using alkaline sized paper in high speed converting or reprographic operations .
• AKD's containing one ⁇ -lactone ring (also known as 2-oxetanone ring)
• ⁇ -lactone ring also known as 2-oxetanone ring
• Other ketene dimers such as the alkenyl-based ketene dimer (Aquapel® 421, available from Hercules Incorporated, Wilmington, DE , U.S.A.), have also been used commercially.
• ASA-based sizing agents are prepared by the reaction of maleic anhydride with olefins containing from about 14 to about 22 carbon atoms .
• ASA and AKD sizing agents are commercially successful, they have disadvantages. On the paper machine, ASA frequently causes deposits that can result in paper web breaks and holes in the paper. ASA addition levels above 2.0-2.5 lb/ton of paper generally lead to unacceptable paper machine runnability, and paper quality problems. However, addition levels greater than 2.0- .5 lb/ton often are required to size paper grades made with high levels of filler. Finally, because ASA cannot be shipped and stored in emulsion form for long periods of time, the papermaker must prepare the emulsion immediately before use.
• alkaline fine paper Both types of sizing agent, particularly the AKD type, have been associated with handling problems in the typical high-speed conversion operations required for the current uses of fine paper made under alkaline conditions (referred to as alkaline fine paper) .
• the problems include reduced operating speed in forms presses and other converting machines, double feeds or jams in high-speed copiers, and registration errors on printing and envelope-folding equipment that operate at high speeds.
• 2-oxetanone sizing agents that are not solid at 35°C have been introduced (e.g., Precis® 2000 sizing agent available from Hercules Incorporated, Wilmington, DE) to address the problem of handling problems in high-speed conversion operations .
• Such billowing involves a divergence of the paper path from the straight line between the rolls, which is two inches (5 cm) above the base plate, causing registration errors and dropped folds in the stacker.
• the rate of billowing during steady-state running time is measured as the billowing height in inches above the straight paper path after 600 seconds of running time and multiplied by 10,000.
• Typical alkaline AKD sized fine paper at size addition levels higher than 2.2 lbs. per ton (1 kg per 0.9 metric ton) of paper often shows an unacceptable rate-of-billowing, typically of the order of 20 to 80.
• Paper handling rates on other high-speed converting machinery such as the Hamilton- Stevens continuous forms press , or the Winkler & Dunnebier CH envelope folder also provide numerical measures of convertibility.
• European Patent Application No. 0 629 741 Al discloses paper sized with 2-oxetanone sizing agent that is a mixture of alkyl ketene dimer and 2-oxetanone multimers of various molecular weights.
• the paper exhibits levels of sizing comparable to those obtained with current alkyl ketene dimer and alkenyl succinic anhydride sizes, and gives improved performance in high speed converting and reprographic machines .
• U.S. Patent No.5 , 685 , 815 , and European Patent Application No.O 666 368 disclose paper that is sized with 2-oxetanone sizing agent and that does not encounter machine feed problems in high speed converting or reprographic machines.
• the 2-oxetanone sizing agent is liquid below 35°C and is prepared from fatty acids having structural irregularities in their hydrocarbon chains such as carbon- carbon double bonds and chain branching.
• U.S. Patent 5,725,731 discloses sizing compositions for fine paper that does not encounter machine feed problems in high-speed converting.
• the sizing compositions are not solid at 35°C and comprise a mixture of 2-oxetanone compounds that are the reaction product of a mixture of saturated and unsaturated fatty acids .
• U.S. Patent No. 5,407,537 teaches a method for using synthetic reactive sizing compounds which eliminates the use of an emulsifier and reduces hydrolysis of the sizing compound during its residence period in the process water.
• the preferred synthetic reactive sizing compounds are alkenyl succinic anhydrides where the alkenyl group has 8-16 carbon atoms. The possibility of using mixtures of alkenyl succinic anhydrides and alkyl ketene dimers is disclosed. U.K.
• Patent Application GB 2,252,984 A discloses a sizing composition that is a blend of from 3 to 50 wt.% alkyl ketene dimer and 97 to 50 wt.% alkyl or alkenyl cyclic acid anhydride.
• Swedish Patent Application No. 893,906 discloses packaging board for fluid sized with combinations of alkyl ketene dimer and alkenyl succinic anhydride.
• alkyl ketene dimers disclosed in U.S. Patent No. 5,407,537, U.K. Patent Application GB 2,252,984 A and Swedish Patent Application No. 893,906 are solid alkyl ketene dimers .
• alkaline fine paper that provides improved handling performance in typical converting and reprographic operations.
• the levels of sizing development must be comparable to that obtained with the current furnish levels of 2-oxetanone or ASA for alkaline fine paper.
• This invention relates to a process for using paper in high speed converting or reprographics operations, comprising the steps of providing paper sized under alkaline conditions with alkenyl succinic anhydride (ASA) and
• ASA alkenyl succinic anhydride
• the 2-oxetanone sizing agent comprises at least one 2-oxetanone compound that is the reaction product of a reaction mixture comprising unsaturated monocarboxylic fatty acid, where the term "fatty acid” is used for convenience to mean a fatty acid or fatty acid halide.
• the invention in another embodiment, relates to a process for making paper under alkaline conditions comprising the steps of providing sizing agent comprising alkenyl succinic anhydride (ASA) and 2-oxetanone that is not solid at 35°C, and sizing the paper with the sizing agent.
• ASA alkenyl succinic anhydride
• Figures 1 and 2 are graphs of the level of natural aged sizing obtained at several addition levels with (a) 2- oxetanone that is not solid at 35°C, (b) alkenyl succinic anhydride (ASA) and (c) blends of ASA and 2-oxetanone that is not solid at 35°C.
• fatty acid will be used for convenience to mean a fatty acid or fatty acid halide.
• fatty acids are converted to acid halides, preferably chlorides, in the first step of making 2-oxetanone compounds, and that the invention may be practiced by starting with fatty acids or with fatty acids already converted to their acid halide.
• fatty acid generally refers either to pure fatty acids or fatty acid halides, or to a blend or mixture of fatty acids or fatty acid halides since fatty acids are generally derived from natural sources and thus are normally blends or mixtures .
• 2-oxetanones of this invention are disclosed in
• the 2-oxetanones which may be a blend of 2-oxetanones, are not solid at 35°C (not substantially crystalline, semicrystalline or waxy solids, i.e., they flow on heating without heat of fusion).
• the 2-oxetanones are not solid at 25°C, and more preferably not solid even at 20°C. Even more preferably, the 2-oxetanones are liquid at 35°C, more preferably liquid at 25°C, and most preferably liquid at 20°C.
• the 2-oxetanones in accordance with this invention are a mixture of compounds of the following general class:
• n is preferably 0 to 6, more preferably 0 to 3, and most preferably 0;
• R and R" which can be the same or different, are saturated or unsaturated, straight chain or branched alkyl groups having 8 to 24 carbon atoms;
• R' is a saturated or unsaturated, straight chain or branched alkyl group having 2 to 40 carbon atoms, preferably 4 to 32 carbon atoms; and wherein at least 25% of the R and R" groups in the mixture of compounds is unsaturated.
• the 2-oxetanones may comprise a mixture of 2-oxetanone compounds that are the reaction product of a reaction mixture comprising unsaturated monocarboxylic fatty acids.
• the reaction mixture may further comprise saturated monocarboxylic fatty acids and dicarboxylic acids.
• the reaction mixture for preparing the mixture of 2-oxetanone compounds comprises at least 25 wt% unsaturated monocarboxylic fatty acids, and more preferably at least 70 wt% unsaturated monocarboxylic fatty acids.
• the unsaturated monocarboxylic fatty acids included in the reaction mixture for preparation of 2-oxetanone compounds preferably have 10-26 carbon atoms, more preferably 14-22 carbon atoms, and most preferably 16-18 carbon atoms.
• These acids include, for example, oleic, linoleic, dodecenoic, tetradecenoic (myristoleic) , hexadecenoic (palmitoleic) , octadecadienoic (linolelaidic) , octadecatrienoic (linolenic) , eicosenoic (gadoleic) , eicosatetraenoic (arachidonic) , cis-13-docosenoic (erucic) , trans-13-docosenoic (brassidic) , and docosapentaenoic (clupanodonic) acids, and their acid halides
• One or more of the monocarboxylic acids may be used.
• Preferred unsaturated monocarboxylic fatty acids are oleic, linoleic, linolenic and palmitoleic acids, and their acid halides.
• Most preferred unsaturated monocarboxylic fatty acids are oleic and linoleic acids, and their acid halides.
• the saturated monocarboxylic fatty acids used to prepare the 2-oxetanone compounds used in this invention preferably have 10-26 carbon atoms, more preferably 14-22 carbon atoms, and most preferably 16-18 carbon atoms.
• These acids include, for example, stearic, isostearic, myristic, palmitic, margaric, pentadecanoic, de ⁇ anoic, undecanoic, dodecanoic, tridecanoic, nonadecanoic, arachidic and behenic acids, and their halides, preferably chlorides.
• One or more of the saturated monocarboxylic fatty acids may be used.
• Preferred acids are palmitic and stearic.
• the alkyl dicarboxylic acids used to prepare the 2-oxetanone compounds for use in this invention preferably have 6-44 carbon atoms, and more preferably 9-10, 22 or 36 carbon atoms.
• dicarboxylic acids include, for example, sebacic, azelaic, 1 , 10-dodecanedioic, suberic, brazylic, docosanedioic acids, and C 36 dimer acids, e.g. EMPOL 1008 available from Henkel-Emery, Cincinnati, Ohio, U.S.A, and their halides, preferably chlorides.
• EMPOL 1008 available from Henkel-Emery, Cincinnati, Ohio, U.S.A
• halides preferably chlorides.
• One or more of these dicarboxylic acids can be used.
• Dicarboxylic acids with 9-10 carbon atoms are more preferred.
• the most preferred dicarboxylic acids are sebacic and azelaic acids.
• the maximum mole ratio of dicarboxylic acid to monocarboxylic acid is preferably about 5.
• a more preferred maximum is about 4, and the most preferred maximum is about 2.
• the mixture of 2-oxetanone compounds may be prepared using methods known for the preparation of standard ketene dimers.
• acid halides preferably, acid chlorides
• PC1 3 or another halogenating, preferably chlorinating, agent are then converted to ketenes in the presence of tertiary amines (including trialkyl amines and cyclic alkyl amines) , preferably triethylamine.
• tertiary amines including trialkyl amines and cyclic alkyl amines
• the ketene moieties then dimerize to form the 2-oxetanones.
• ASA alkenyl succinic anhydrides
• Liquid ASA's which are preferred in the processes of this invention, are usually made in a two-step process starting with an alpha olefin. The olefin is first isomerized by randomly moving the double bond from the alpha position. In the second step the isomerized olefin is reacted with an excess of maleic anhydride to give the final ASA structure as indicated in the following reaction scheme.
• ASA Olefin Anhydride Anhydride
• ASA's that are solid at room temperature may be produced.
• the starting alpha olefin is preferably in the C-14 to C-22 range and may be linear or branched.
• the ASA's be prepared by reaction of maleic anhydride with olefins containing 14-18 carbon atoms. Typical structures found in ASA's are disclosed in U.S. Patent 4,040,900, which is incorporated herein by reference in its entirety.
• ASA's are commercially available from Albemarle Corporation, Baton Rouge, La.
• Representative starting olefins for reaction with maleic anhydride to prepare ASA's for use in this invention include: octadecene, tetradecene, hexadecene, eicodecene, 2- n-hexyl-1-octene, 2-n-octyl-l-dodecene, 2-n-octyl-l-decene, 2-n-dodecyl-l-octene, 2-n-octyl-l-octene, 2-n-octyl-l- nonene, 2-n-hexyl-l-decene and 2-n-heptyl-l-octene.
• the maximum weight ratio of 2-oxetanone to ASA is preferably about 9:1. More preferably the maximum is about 4:1, and most preferably about 2:1.
• the minimum ratio of 2-oxetanone to ASA is preferably about 9:1. More preferably the maximum is about 4:1, and most preferably about 2:1.
• ASA is preferably about 1:9. More preferably the minimum is about 1:4, and most preferably about 1:2.
• the sizes of this invention are utilized in the form of dispersions or emulsions, which can be prepared by methods well known in the art. It is preferred that the sizes be utilized as internal sizing agents, i.e., added to the paper pulp slurry before sheet formation .
• the ASA and 2-oxetanone sizing components may be preblended before addition, or added separately.
• the paper of this invention is preferably sized at a total size (i.e., ASA plus 2-oxetanone) addition rate of at least 0.5 lb (0.2 kg), more preferably at least about 1.5 lb (0.8 kg) , and most preferably at least about 2.2 lb/ton (1 kg/0.9 metric tons) or higher. It may be, for example, in the form of continuous forms bond paper, perforated continuous forms paper, adding machine paper, or envelope- making paper, as well as converted products, such as copy paper and envelopes.
• the alkaline paper made according to the process of this invention contains a water soluble inorganic salt of an alkali metal, preferably sodium chloride (NaCl) .
• an alkali metal preferably sodium chloride (NaCl)
• the paper of this invention will often be made without NaCl as well.
• the paper of this invention has a higher level of natural aged sizing (sizing after aging for 7 days at room temperature) than does paper sized with an equivalent amount of 2-oxetanone that is not solid at 35°C.
• the paper is produced with a lower level of paper machine deposits than paper produced at equal levels of sizing using ASA size.
• the process of this invention is also an improvement over the process where the paper is sized utilizing ASA and solid alkyl ketene dimers.
• solid alkyl ketene dimer When solid alkyl ketene dimer is used, special equipment must be employed to melt the alkyl ketene dimer in order to prepare aqueous dispersions. This melting step is not necessary for use of liquid 2-oxetanone.
• the paper of this invention does not encounter significant machine-feed problems on high speed converting machines or in reprographic operations.
• the paper according to this invention can be made into a roll of continuous forms bond paper having a basis weight of about 15 to 24 lb/1300 ft 2 (6.8 to 10.9 kg/121 m 2 ) and that is sized at an addition rate of at least about 1.5 lb/ton (0.68 kg/0.9 metric ton), and that is then capable of running on the IBM Model 3800 high speed, continuous-forms laser printer with no significant machine feed problems.
• the preferred paper that can be made into sheets of 8 1/2 x 11 inch (21.6 cm x 28 cm) reprographic cut paper having a basis weight of about 15-24 lb/1300 ft 2 (6.8 to 10.9 kg/121 m 2 ) , is capable of running on a high speed laser printer or copier.
• the paper When the paper is sized at a total size (i.e., ASA plus 2-oxetanone) addition rate that is preferably at least about 1.5 lb/ton (0.68 kg/0.9 metric ton), and more preferably at least about 2.2 lb/ton (1 kg/0.9 metric ton), it is capable of running on the IBM model 3825 high-speed copier without causing misfeeds or jams at a rate of more than 5 in 10,000 sheets, preferably at a rate of no more than 1 in 10,000 sheets.
• paper sized with standard AKD has a much higher rate of double feeds on the IBM 3825 high speed copier (14 double feeds in 14,250 sheets) . In conventional copy-machine operation, 10 double feeds in 10,000 is unacceptable. A machine manufacturer considers 1 double feed in 10,000 sheets to be unacceptable.
• the paper of this invention in the form of a roll of continuous forms bond paper having a basis weight of about 15-24 lb/1300 ft 2 (6.8 to 10.9 kg/121 m 2 ) can be converted to a standard perforated continuous form on a continuous forms press at a press speed of about 1300 to 2000 feet (390 m to 600 m) per minute or more.
• the preferred paper according to the invention in the form of a roll of continuous forms bond paper having a basis weight of about 15-24 lb/1300 ft 2 (6.8 to 10.9 kg/121 m 2 ) , and that is sized at an addition rate of at least about 2.2 lb/ton (1 kg per 0.9 metric ton) can be converted to a standard perforated continuous form on the Hamilton-Stevens continuous forms press at a press speed of at least about 1775 feet (541 m) per minute, preferably at least about 1900 feet (579 m) per minute .
• the paper of this invention can also be made into a roll of envelope paper having a basis weight of about 15-24 lb/1300 ft 2 (6.8 to 10.9 kg/121 m 2 ) that is sized at an addition rate of at least about 2.2 lb/ton (1 kg/0.9 metric ton) .
• the paper can be converted into at least about 900 envelopes per minute, preferably at least about 1000 per minute on a Winkler & Dunnebier CH envelope folder.
• the paper of this invention can be run at a speed of at least about 58 sheets per minute on a high speed sheet-fed copier (IBM 3825) with less than 1 in 10,000 double feeds or jams .
• the paper of this invention is capable of running on a high speed, continuous-forms laser printer with a rate of billowing at least about 10% less, preferably about 20% less, than that produced when running on the same printer, a roll of continuous forms bond paper having the same basis weight and sized at the same level with an AKD size made from a mixture of stearic and palmitic acids, after 10 minutes of running time.
• the paper of this invention is capable of running on a high speed sheet-fed copier (IBM 3825) at a speed of about 58 sheets per minute with at least about 50% fewer, preferably about 70% fewer, double feeds or jams than the number of double feeds or jams caused when running on the same copier, sheets of paper having the same basis weight and sized at the same level with an AKD size made from a mixture of stearic and palmitic acids.
• the paper of this invention is also capable of being converted to a standard perforated continuous form on a continuous forms press at a press speed at least 3% higher, preferably at least 5% higher, than paper having the same basis weight and sized at the same level with an AKD size made from a mixture of stearic and palmitic acids.
• Paper for evaluation on the IBM 3800 was prepared on a pilot paper machine.
• the pulp furnish (three parts Southern hardwood kraft pulp and one part Southern softwood kraft pulp) was refined to 425 ml Canadian Standard Freeness (C.S.F.) using a double disk refiner.
• the pH, alkalinity and hardness of the papermaking stock were adjusted using the appropriate amounts of H 2 S0 4 , NaHC0 3 , NaOH, and CaCl 2 to pH 7.8-8.0, alkalinity 150-200 ppm, and hardness 100 ppm.
• the 2-oxetanone compounds were prepared by methods used conventionally to prepare commercial 2-oxetanone compounds i.e., acid chlorides from a mixture of fatty acids are formed using a conventional chlorination agent, and then the acid chlorides are dehydrochlorinated in the presence of a suitable base.
• ASA was Alkenylsuccinic Anhydride C16C18, obtained from Albemarle Corp. , Baton Rouge, LA.
• Emulsions of the ASA/2-oxetanone blends were prepared immediately before use by methods described by C.E. Farley & R.B. Wasser, in "The Sizing of Paper (Second Edition)", edited by W.F. Reynolds, Tappi Press, 1989, pages 51-62, which is incorporated herein by reference in its entirety.
• the emulsions were prepared using Stalok 400 cationic starch (available from A.E. Staley Manufacturing Co., Decatur IL) at a level of 3 : 1 starch to sizing agent.
• the wet presses were set at 40 psi(2.8 kg/cm 2 ) gauge. A dryer profile that gave 1-2% moisture at the size press and 4-6% moisture at the reel was used (77 feet (23.4 m) per minute). Approximately 35 lb/ton (15.9 kg/0.9 metric ton) of an oxidized corn starch, Stayco C (A.E. Staley Manufacturing Co., Decatur IL) , and 1 lb/ton (0.45 kg/0.9 metric ton) of NaCl were added at the size press (130°F
• a 35-minute roll of paper was collected and converted on a commercial forms press to two boxes of standard 8 1/2" x 11" (21.6 x 28 cm) forms. Samples were also collected before and after each 35 minute roll for testing natural aged sizing and basis weight (46 lb/3000 ft 2 , 20.8 kg/279 m 2 ) , and smoothness testing. The converted paper was allowed to equilibrate in the printer room for at least one day prior to evaluation. Each box of paper allowed a 10-14 minute (220 feet (66.7 m) per minute) evaluation on the IBM 3800. All samples were tested in duplicate. A standard acid fine paper was run for at least two minutes between each evaluation to reestablish initial machine conditions.
• the Hercules Size Test is a standard test in the industry for measuring the degree of sizing. This method employs an aqueous dye solution as the penetrant to permit optical detection of the liquid front as it moves through the sheet. The apparatus determines the time required for the reflectance of the sheet surface not in contact with the penetrant to drop to a predetermined percentage of its original reflectance. All HST testing data reported measure the seconds to 80% reflection with 1% formic acid ink mixed with naphthol green B dye unless otherwise noted. The use of formic acid ink is a more severe test than neutral ink and tends to give faster test times. High HST values are better than low values .
• Example 1 In this example a 1:1 blend of 2-oxetanone and alkenyl succinic anhydride was evaluated for sizing efficiency at several addition levels. For comparison, samples of 2-oxetanone and ASA alone were run under the same conditions .
• the 2-oxetanone was prepared by the usual procedures using Emersol-221 as the feedstock.
• Emersol-221 available from Henkel-Emery, Cincinnati, OH, had the following composition: oleic acid 73% linoleic acid 8 palmitoleic acid 6 myristoleic acid 3 linolenic acid 1 saturated fatty acids 9.
• the ASA was Alkenylsuccinic Anhydride C16C18, obtained from Albemarle Corp. , Baton Rouge, LA.
• the evaluation data are in Table 1 and presented graphically in Figure 1.
• the data indicate that the natural-aged sizing for the ASA/2-oxetanone blends is less than that of ASA alone but greater than that for 2-oxetanone alone at equivalent size addition levels.
• Example 2 In this example blends of 2-oxetanone and alkenyl succinic anhydride at two ratios were evaluated for sizing efficiency at several addition levels. For comparison, samples of 2-oxetanone sizing agent alone and ASA alone were run under the same conditions. The 2-oxetanone and ASA were the same as those used in Example 1.
• Example 3 In this example blends of 2-oxetanone and ASA at 3 ratios were tested for their effects on the runnability of a difficult to convert grade of alkaline fine paper on the IBM 3800.
• a comparative experiment, 3A utilizes Hercon® 70 sizing agent, a dispersion containing alkyl ketene dimer prepared from a mixture of palmitic and stearic acids, available from Hercules Incorporated, Wilmington, DE . The materials utilized in the remainder of the experiments were as described in Example 1.
• the evaluation data are in Table 3. The data show that the 2-oxetanone/ASA blends at all 3 ratios tested produced paper that ran on the IBM 3800 with good to very good runnability. Moreover, at the 3.0 lb/ton addition level all three ratios tested produced paper that ran on the IBM 3800 with runnability better than that of paper made with Hercon® 70.

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• 1998
  • 1998-06-12 RU RU2001101269/12A patent/RU2202019C2/ru not_active IP Right Cessation
  • 1998-06-12 EP EP98926320A patent/EP1099141A1/en not_active Withdrawn
  • 1998-06-12 CN CNB988141132A patent/CN1188750C/zh not_active Expired - Fee Related
  • 1998-06-12 JP JP2000553871A patent/JP2002517638A/ja active Pending
  • 1998-06-12 WO PCT/US1998/011597 patent/WO1999064934A1/en not_active Application Discontinuation
  • 1998-06-12 BR BRPI9815903-8A patent/BR9815903B1/pt not_active IP Right Cessation
  • 1998-06-12 CA CA002334178A patent/CA2334178A1/en not_active Abandoned
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