EP1073353A1 - Borste, verfahren zu ihrer herstellung und gerät mit einer solchen borste - Google Patents
Borste, verfahren zu ihrer herstellung und gerät mit einer solchen borsteInfo
- Publication number
- EP1073353A1 EP1073353A1 EP99923408A EP99923408A EP1073353A1 EP 1073353 A1 EP1073353 A1 EP 1073353A1 EP 99923408 A EP99923408 A EP 99923408A EP 99923408 A EP99923408 A EP 99923408A EP 1073353 A1 EP1073353 A1 EP 1073353A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- bristle
- rubber
- core
- elastic layer
- profiled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/02—Bristles details
- A46D1/023—Bristles with at least a core and at least a partial sheath
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/02—Bristles details
- A46D1/0238—Bristles with non-round cross-section
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/02—Bristles details
- A46D1/0246—Hollow bristles
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/02—Bristles details
- A46D1/0261—Roughness structure on the bristle surface
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B2200/00—Brushes characterized by their functions, uses or applications
- A46B2200/10—For human or animal care
- A46B2200/1066—Toothbrush for cleaning the teeth or dentures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2922—Nonlinear [e.g., crimped, coiled, etc.]
- Y10T428/2924—Composite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
- Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
Definitions
- the invention relates to a bristle consisting of a core made of a comparatively hard, flexible plastic and at least one layer made of a rubber-elastic plastic.
- the invention further relates to a method for producing such bristles and devices which are equipped with such bristles.
- bristles Regardless of the particular use of a brush, bristles have some basic requirements.
- brushes for oral and personal care must be sufficiently soft to avoid injuries, while abrasive technical brushes should have hard and rough bristles.
- Other technical brushes, such as car wash brushes, on the other hand must be smooth and smooth. This also applies to polishing brushes.
- Brushes or brushes that are used to apply media must have relatively narrow bristles for storing the medium, while in other applications, single bristles or bundles of bristles are desired.
- a bristle is proposed in (21), which consists of an extruded, relatively rigid core made of PA (polyamide) or high-density PE (polyethylene) and a soft thermoplastic layer made of natural or synthetic rubber.
- This well-known bristle is designed for toothbrushes, whereby the soft rubber-elastic coating is primarily intended to ensure gentle treatment of the teeth and gums, while the stiff core ensures the necessary strength properties of the bristle.
- such a bristle does not meet the requirements for cleaning because its surface is too smooth. It is also not suitable for applying media to an object.
- Ol X rö - ⁇ ß -H ⁇ N ti ⁇ ß rß CQ ⁇ rö X 0 --ti Ol X ⁇ X ⁇ SH -H
- the core can be formed from one or more monofilaments.
- the former version is recommended for tooth and body brushes, the latter version for technical brushes, especially for car wash brushes.
- the bristles have to be limp in order to optimally create the contour of the surface to be cleaned and to gently clean the surface. These bristles wear out very quickly from the free end.
- Bristles usually have a circular cross section.
- any other bristle cross section can also be realized by the core having a shape that deviates from the circular shape
- Cross-section e.g. a narrow rectangular or cross-shaped or star-shaped cross-section.
- the rubber-elastic layer can then nevertheless have a circular cross section, so that it has a different thickness and can be embossed, for example, in the thicker areas. Instead, it can also have a cross section that follows the cross section of the core, so that profiles of the same depth can be produced regardless of the location of the embossing, the core again acting as an abutment here.
- the entire bristle made of core and rubber-elastic layer can be corrugated transversely to the direction of extension of the bristle.
- the core is obtained through a surface structure on the core that acts as an adhesion promoter.
- the invention proposes a method in which the core and the rubber-elastic layer are co-extruded as a strand and the rubber-elastic layer is profiled by stamping against the core while the strand is running.
- Another variant of the method is that the core and the rubber-elastic layer are co-extruded as an endless strand, the strand is wound and the rubber-elastic layer is passed through when the strand is being unwound
- Embossing is profiled against the core.
- the embossing can take place at the manufacturer of the bristle material or only at the brush manufacturer.
- This process can also be recommended if the rubber-elastic layer consists of a slowly cross-linking elastomer and the embossing process should only be carried out after the cross-linking reaction has ended.
- the rubber-elastic layer is preferably profiled by means of stamping tools which act against one another and against the core, the stamping tools being able to produce different profiles. It is also possible to provide only one-sided profiling, in which case the embossing tool works together with an unprofiled counter-tool.
- a soft plastic can be applied to the profiled strand on the occasion of the production of the bristle material or before the bristles are cut to length, by extrusion, dipping, spraying or shrinking on a film, for example to smooth the profile.
- the core and the rubber-elastic layer are co-extruded as a strand, the bristle is then cut to length from the strand and the rubber-elastic layer is then profiled against the core by embossing.
- the film-like layer can be applied before or after cutting to length by dipping, spraying or shrinking on a film.
- the bristle designed according to the invention can be used for devices of all kinds.
- such a bristle can be used directly as an interdental cleaner, either in the form of a stick or similar to a dental floss.
- a brush is equipped with a plurality of bristles designed according to the invention, the bristles being able to be provided in separate arrangements.
- a brush can have bristles with differently profiled, rubber-elastic layers.
- 1 has a core 2 made of a o CU ⁇ ß X
- ß ro rH PJ ß rß 0 - X Oi HX ü XH ß XI ⁇ ß rH H ß> -H ß Ti ß X -H -H ß f ⁇ ⁇ MX ⁇ • 4H ⁇ Ti ß EH S CQ -H ⁇ - H SH ⁇ ⁇ u ß t ti CQ ⁇ X 4H X ⁇ ß ⁇ ß X EH CN 0 rH ⁇ X rH CQ -H
- Layer 3 has a circular cross-section. It is therefore the thinnest in the region of the ends of the bars of the cross section 10. This forms sharply defined abutments against which the profile - as indicated by the arrows 11 - can be embossed particularly well.
- the bristle 1 in turn has a core 2 with a circular cross section.
- the rubber-elastic layer 3 enveloping it is embossed with a wave profile 12.
- FIG. 7 shows an embodiment modified compared to FIG. 1, in that the core 2 consists of four monofilaments 13, which can be in parallel or twisted.
- the rubber-elastic layer 3 in turn surrounds the core 2 with a circular cross section and has the embossed profile on its jacket.
- the core 2 has an elongated cross section.
- the rubber-elastic layer 3 is provided with a constant thickness, so that it follows the cross section of the core 2 and a ribbon-shaped bristle is obtained, which is provided, for example, only on its narrow sides with an embossed profile 4 similar to that in FIG. 3.
- the bristle according to FIG. 9 again has a core 2 and a rubber-elastic layer 3 with a profile 4 obtained by embossing.
- the bristle 14 according to FIG. 9 is corrugated transversely to the longitudinal extent.
Landscapes
- Brushes (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
- Laminated Bodies (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Artificial Filaments (AREA)
- Pens And Brushes (AREA)
- Cosmetics (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19818345A DE19818345A1 (de) | 1998-04-24 | 1998-04-24 | Borste, Verfahren zu ihrer Herstellung und Gerät mit einer solchen Borste |
DE19818345 | 1998-04-24 | ||
PCT/EP1999/002403 WO1999055195A1 (de) | 1998-04-24 | 1999-04-09 | Borste, verfahren zu ihrer herstellung und gerät mit einer solchen borste |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1073353A1 true EP1073353A1 (de) | 2001-02-07 |
EP1073353B1 EP1073353B1 (de) | 2002-06-12 |
Family
ID=7865672
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99923408A Expired - Lifetime EP1073353B1 (de) | 1998-04-24 | 1999-04-09 | Borste, verfahren zu ihrer herstellung und gerät mit einer solchen borste |
Country Status (15)
Country | Link |
---|---|
US (1) | US6391445B1 (de) |
EP (1) | EP1073353B1 (de) |
JP (1) | JP4311878B2 (de) |
KR (1) | KR100602584B1 (de) |
CN (1) | CN1115121C (de) |
AR (1) | AR015016A1 (de) |
AU (1) | AU746808B2 (de) |
BR (1) | BR9909857A (de) |
CA (1) | CA2328770A1 (de) |
DE (2) | DE19818345A1 (de) |
EG (1) | EG22279A (de) |
ES (1) | ES2178438T3 (de) |
PL (1) | PL193087B1 (de) |
RU (1) | RU2205581C2 (de) |
WO (1) | WO1999055195A1 (de) |
Families Citing this family (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6440557B1 (en) | 1999-07-08 | 2002-08-27 | E. I. Du Pont De Nemours & Co. | Brush filaments |
DE19932376A1 (de) | 1999-07-13 | 2001-01-18 | Coronet Werke Gmbh | Borste für Zahnbürsten und Zahnbürste mit solchen Borsten |
DE19932368A1 (de) * | 1999-07-13 | 2001-02-08 | Pedex & Co Gmbh | Verfahren zur Herstellung von mehrschichtigem Borstenmaterial, mehrschichtige Borste und deren Verwendung |
US6553604B1 (en) | 2000-03-16 | 2003-04-29 | Gillette Canada Company | Toothbrush |
DE10017167A1 (de) * | 2000-04-07 | 2001-10-11 | Pedex & Co Gmbh | Verfahren und Vorrichtung zur Herstellung von Filamenten aus Kunststoff, insbesondere Kunststoffborsten, und danach hergestellte Borste |
DE10017306A1 (de) | 2000-04-09 | 2001-10-11 | Pedex & Co Gmbh | Verfahren zur Herstellung von Borsten zum Applizieren von Medien |
DE10033256A1 (de) * | 2000-07-10 | 2002-01-24 | Coronet Werke Gmbh | Verfahren und Vorrichtung zur Herstellung von Borstenwaren sowie Borstenware |
DE10046536A1 (de) * | 2000-09-19 | 2002-03-28 | Coronet Werke Gmbh | Verfahren zur Herstellung von Borstenwaren |
DE10115556A1 (de) | 2001-03-28 | 2002-10-02 | Pedex & Co Gmbh | Thermoplastisches Monofilament für Borsten |
AU2008200512B2 (en) * | 2003-03-14 | 2011-07-14 | The Gillette Company Llc | Toothbrush head |
US20040177462A1 (en) * | 2003-03-14 | 2004-09-16 | The Gillette Company | Toothbrush head |
US20060272112A9 (en) | 2003-03-14 | 2006-12-07 | The Gillette Company | Toothbrush |
US7941886B2 (en) | 2003-09-19 | 2011-05-17 | Braun Gmbh | Toothbrushes |
US20050130540A1 (en) * | 2003-12-15 | 2005-06-16 | Nordson Corporation | Multicomponent spunbond filaments having a melt-processable superabsorbent polymer core |
DE102005027982B4 (de) * | 2005-06-16 | 2007-09-06 | Braun Gmbh | Interdentalbürste und Interdentalreiniger |
DE102006027756A1 (de) | 2006-06-16 | 2007-12-20 | Braun Gmbh | Zahnbürste sowie Zahnbürstenkopf und Zahnputzborste hierfür |
US20090240284A1 (en) * | 2008-03-24 | 2009-09-24 | David Scott Randol | Stabilization rods |
EP2225966A1 (de) | 2009-03-04 | 2010-09-08 | Braun GmbH | Zahnbürstenborste und Verfahren zur Herstellung einer solchen Borste |
US8602776B2 (en) | 2009-11-05 | 2013-12-10 | Wilkie J. Stadeker | Devices and methods for improved interdental cleaning and therapy |
US20150150366A1 (en) * | 2012-06-05 | 2015-06-04 | Lg Household & Healthcare Ltd. | Toothbrush bristles having tip with double structure and toothbrush comprising same |
DE102012018467B4 (de) * | 2012-09-19 | 2017-08-03 | Rusi Cosmetic Gmbh & Co. Kg | Verfahren zur Herstellung eines Applikators für kosmetische Produkte und ein Applikator |
DE102012018466A1 (de) * | 2012-09-19 | 2014-03-20 | Rusi Cosmetic Gmbh & Co. Kg | Verfahren zur Herstellung eines Applikators für kosmetische Produkte |
KR101427039B1 (ko) | 2013-03-14 | 2014-08-05 | 이정희 | 모노필라멘트(칫솔모) 표면 미세돌기 성형 사각금형형 장치 |
CN103806114A (zh) * | 2014-03-06 | 2014-05-21 | 安徽环美刷业有限公司 | 扫雪车专用刷丝及其生产设备和生产方法 |
US9986820B2 (en) * | 2014-06-11 | 2018-06-05 | The Procter & Gamble Company | Filament having unique tip and surface characteristics |
BR112017001131A2 (pt) * | 2014-07-31 | 2017-11-14 | Geka Gmbh | aplicador de núcleo de fio com cerdas de fibra côncava biseladas |
FR3028153B1 (fr) * | 2014-11-06 | 2018-05-04 | L'oreal | Applicateur cosmetique comportant des fibres. |
AU2015401762B2 (en) | 2015-07-07 | 2019-03-14 | Colgate-Palmolive Company | Oral care implement and monofilament bristle for use with the same |
CN106073145A (zh) * | 2016-06-27 | 2016-11-09 | 徐涵 | 一种新型牙刷刷丝及其制备工艺 |
CN106235604B (zh) * | 2016-08-31 | 2018-03-23 | 王文康 | 一种牙刷及其制造工艺 |
DE202018001075U1 (de) | 2018-02-19 | 2018-03-28 | Semen Zaitchik | Bürste, insbesondere Zahnbürste deren Putzelemente die fraktalen Charakteristiken aufweisen |
DE202018101427U1 (de) * | 2018-03-14 | 2019-06-17 | Geka Gmbh | Applikator mit rundum verripptem, borstenbildendem Filament |
CN110403347A (zh) * | 2019-06-27 | 2019-11-05 | 安徽省忆德工业刷制造有限公司 | 一种耐磨的环卫刷刷丝及其生产方法 |
US12161219B2 (en) | 2021-02-03 | 2024-12-10 | Judson Smith | Cleaning bristle brushes and cleaning systems using same |
DE102023106400A1 (de) * | 2023-03-14 | 2024-09-19 | Jan Heinz | Verfahren und Vorrichtung zum abrasiven Bodenabtrag im Tiefbau mittels rotierender Kunststofflamellen |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE32963C (de) | sächsische Webstuhlfabrik (Louis Schönherr) in Chemnitz. Vom ly. März 1885 ab. — S, 2739 | Schützenwechsel-Einrichtung für mehr als vierzellige Kasten | ||
DE1073434B (de) | 1960-01-21 | Roman Dietsche K.G., Aftersteg (Schwarzw.) | Kunstborste | |
DE322089C (de) | 1919-02-01 | 1920-06-19 | Wilhelm Bentz | Zahnreinigungsmittel in Buerstenform |
US2110371A (en) | 1935-05-08 | 1938-03-08 | Hat Corp | Product and process for the manufacture thereof |
US2317485A (en) | 1940-04-27 | 1943-04-27 | Pepsodent Co | Brush |
US2642705A (en) | 1951-04-19 | 1953-06-23 | James L Jensen | Polishing and sanding device |
DE1014964B (de) | 1952-02-12 | 1957-09-05 | Johann Christian Gerster | Kuenstliche Borste und deren Herstellungsverfahren |
US3090061A (en) | 1961-02-01 | 1963-05-21 | Osborn Mfg Co | Brush and brush material |
GB992346A (en) * | 1961-08-11 | 1965-05-19 | Osborn Mfg Co | Process and apparatus for coating wire and the like |
DE1140901B (de) | 1961-09-16 | 1962-12-13 | Walter Herdling | Buerstenborste |
US3325845A (en) | 1965-02-26 | 1967-06-20 | Int Playtex Corp | Nylon bristle resembling natural bristle |
US3613143A (en) | 1970-11-12 | 1971-10-19 | Indiana University Foundation | Brush with abrasive-impregnated bristles |
US3689118A (en) * | 1971-01-06 | 1972-09-05 | Sherwin Williams Co | Method of brush bristle manufacture |
US4263691A (en) | 1979-03-07 | 1981-04-28 | Seree Pakarnseree | Brush |
US4373541A (en) | 1979-08-07 | 1983-02-15 | Nishioka Gary J | Bristle structure for brushes and brush assembly |
DE3116189A1 (de) | 1981-04-23 | 1982-12-23 | Bodo 2000 Hamburg Jesse | Profilierte borsten fuer zahnbuersten und buersten aller art |
DE8300846U1 (de) | 1983-01-14 | 1985-01-31 | Pedex & Co. GmbH, 6948 Wald-Michelbach | Kunststoffborste |
FR2546097A1 (fr) | 1983-02-22 | 1984-11-23 | Freselle Christian | Fibre diamantee |
JPS6021966A (ja) | 1983-07-12 | 1985-02-04 | カネボウ株式会社 | 研摩用纎維の製造方法 |
US5137039A (en) | 1991-03-04 | 1992-08-11 | Focus Development Corporation, Inc. | Tooth cleaning device |
DE3717475A1 (de) | 1987-05-23 | 1988-12-08 | Schlerf Coronet Werke | Borstenware und verfahren zu ihrer herstellung |
DE8809217U1 (de) | 1988-07-19 | 1988-09-01 | Georg Karl geka-brush GmbH, 8809 Bechhofen | Reinigungsgerät für Zahnzwischenräume |
TW307801B (de) | 1992-03-19 | 1997-06-11 | Minnesota Mining & Mfg | |
TW222668B (de) * | 1992-03-19 | 1994-04-21 | Minnesota Mining & Mfg | |
US5678275A (en) | 1995-06-30 | 1997-10-21 | Derfner; Nitza | Toothbrush with bristles having intermediate roughened portion |
DE19533815A1 (de) | 1995-09-13 | 1997-03-20 | Coronet Werke Gmbh | Zahnbürste und Verfahren zu ihrer Herstellung |
US6058541A (en) * | 1996-07-03 | 2000-05-09 | Gillette Canada Inc. | Crimped bristle toothbrush |
US6296934B1 (en) * | 1999-03-12 | 2001-10-02 | E.I. Du Pont De Nemours And Company | Glitter containing filaments for use in brushes |
-
1998
- 1998-04-24 DE DE19818345A patent/DE19818345A1/de not_active Withdrawn
-
1999
- 1999-04-09 WO PCT/EP1999/002403 patent/WO1999055195A1/de active IP Right Grant
- 1999-04-09 US US09/673,355 patent/US6391445B1/en not_active Expired - Lifetime
- 1999-04-09 CN CN99805416A patent/CN1115121C/zh not_active Expired - Lifetime
- 1999-04-09 AU AU40302/99A patent/AU746808B2/en not_active Ceased
- 1999-04-09 PL PL343632A patent/PL193087B1/pl not_active IP Right Cessation
- 1999-04-09 DE DE59901741T patent/DE59901741D1/de not_active Expired - Lifetime
- 1999-04-09 RU RU2000129509/12A patent/RU2205581C2/ru not_active IP Right Cessation
- 1999-04-09 JP JP2000545407A patent/JP4311878B2/ja not_active Expired - Fee Related
- 1999-04-09 KR KR1020007011846A patent/KR100602584B1/ko not_active Expired - Fee Related
- 1999-04-09 CA CA002328770A patent/CA2328770A1/en not_active Abandoned
- 1999-04-09 BR BR9909857-1A patent/BR9909857A/pt not_active IP Right Cessation
- 1999-04-09 EP EP99923408A patent/EP1073353B1/de not_active Expired - Lifetime
- 1999-04-09 ES ES99923408T patent/ES2178438T3/es not_active Expired - Lifetime
- 1999-04-22 EG EG45399A patent/EG22279A/xx active
- 1999-04-23 AR ARP990101890A patent/AR015016A1/es active IP Right Grant
Non-Patent Citations (1)
Title |
---|
See references of WO9955195A1 * |
Also Published As
Publication number | Publication date |
---|---|
JP2002512824A (ja) | 2002-05-08 |
KR20010043001A (ko) | 2001-05-25 |
KR100602584B1 (ko) | 2006-07-19 |
CA2328770A1 (en) | 1999-11-04 |
BR9909857A (pt) | 2000-12-19 |
AR015016A1 (es) | 2001-04-11 |
CN1298284A (zh) | 2001-06-06 |
AU4030299A (en) | 1999-11-16 |
CN1115121C (zh) | 2003-07-23 |
WO1999055195A1 (de) | 1999-11-04 |
US6391445B1 (en) | 2002-05-21 |
ES2178438T3 (es) | 2002-12-16 |
DE19818345A1 (de) | 1999-10-28 |
DE59901741D1 (de) | 2002-07-18 |
EP1073353B1 (de) | 2002-06-12 |
PL343632A1 (en) | 2001-08-27 |
RU2205581C2 (ru) | 2003-06-10 |
EG22279A (en) | 2002-12-31 |
PL193087B1 (pl) | 2007-01-31 |
AU746808B2 (en) | 2002-05-02 |
JP4311878B2 (ja) | 2009-08-12 |
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