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EP1044625B1 - Applying capsule and applicator assembly with such a capsule - Google Patents

Applying capsule and applicator assembly with such a capsule Download PDF

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Publication number
EP1044625B1
EP1044625B1 EP00400488A EP00400488A EP1044625B1 EP 1044625 B1 EP1044625 B1 EP 1044625B1 EP 00400488 A EP00400488 A EP 00400488A EP 00400488 A EP00400488 A EP 00400488A EP 1044625 B1 EP1044625 B1 EP 1044625B1
Authority
EP
European Patent Office
Prior art keywords
product
applicator
cap
application
orifice
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP00400488A
Other languages
German (de)
French (fr)
Other versions
EP1044625A1 (en
Inventor
Jean-Louis H. Gueret
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LOreal SA filed Critical LOreal SA
Publication of EP1044625A1 publication Critical patent/EP1044625A1/en
Application granted granted Critical
Publication of EP1044625B1 publication Critical patent/EP1044625B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers for dispensing liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant
    • B65D83/28Nozzles, nozzle fittings or accessories specially adapted therefor
    • B65D83/285Nozzles, nozzle fittings or accessories specially adapted therefor for applying the content, e.g. brushes or pads
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D33/00Containers or accessories specially adapted for handling powdery toiletry or cosmetic substances
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • A45D34/04Appliances specially adapted for applying liquid, e.g. using roller or ball
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00Details not otherwise provided for in A45D
    • A45D2200/10Details of applicators
    • A45D2200/1009Applicators comprising a pad, tissue, sponge, or the like
    • A45D2200/1018Applicators comprising a pad, tissue, sponge, or the like comprising a pad, i.e. a cushion-like mass of soft material, with or without gripping means

Definitions

  • the present invention relates to an applicator capsule for use in the context of a separate and / or combined application of two products which contain individually packaged assets or compounds.
  • a makeup base in the form of a cream, a gel or a milk
  • a separate product especially in the form of a compacted powder or free, and comprising fillers or colored pigments
  • said separated product can be chosen from a plurality of powders containing pigments of different colors, so as to be able to choose the color and / or the appearance of his makeup.
  • a moisturizing or soothing base in the form of a milk or a cream
  • a separate product in particular in the form of a powder or cream, containing a filter for protection against UV radiation, and which can be chosen from a plurality of powders containing filters with different protection indices, so as to be able to adapt the protection of its skin to its needs.
  • an applicator capsule forming a unit for applying a specific product, suitable for use in combination with an auxiliary container containing a product having an action complementary to the action specific product contained in the applicator capsule.
  • EP 0 374 339 discloses a container containing a liquid product, the container being equipped with a pump on which is mounted a support carrying an applicator.
  • the carrier is mounted to move relative to the container to actuate the pump and charge the applicator with product.
  • the set is intended to apply a single product.
  • EP 0 263 329 also describes a container containing a first product, on which is fixed an applicator for applying the first product.
  • the applicator is protected by a cap in which is housed a second product in the form of a solid loaf which comes into contact with the applicator when the cap is mounted on the container.
  • an applicator capsule comprising a support, having means capable of allowing the fixing of the capsule removably on a container, containing a first product, an application member, in particular under as a resiliently compressible element, mounted on the support and adapted to convey said first product, from an orifice, formed in the support, to an application face of said applicator member, a cap removably covering said application member, the cap being mounted on the support, and the applicator capsule comprising a second product disposed in the bottom of the cap, in particular in the form of a solid cake or a powder, said application surface being suitable, in the mounted position of the cap, to be placed elastically on said second product.
  • a unit which contains a specific product, in particular delitable, and which can be mounted on a container containing a product capable of promoting the disintegration of the specific product, the two products being kept separate from one another. and being, for a combined application, metered to the application face of the applicator member.
  • the product contained in the cap does not contaminate the product contained in the container.
  • An application member of a given capsule is never brought into contact with a second product other than that contained in the capsule to which it is dedicated.
  • the product contained in the container is intended to be dispensed under pressure, in particular by means of a pump, a piston, or a propellant.
  • the application face of the applicator member is, at least before use, elastically constrained in abutment against the free surface of the product contained in the cap, which, with certain products, is sufficient to ensure proper loading of said application face with said product.
  • the loading of the application face with the second product can be promoted by rotating the application face bearing against said free surface of the product contained in the cap.
  • the product may be cast, hot or cold, or compacted, directly in the bottom of the cap, or in a cup mounted in said bottom.
  • Means, in particular in the form of fins or other attachment means, may be provided for, in the event that the product is poured into the cap, allow the product, when it solidifies, to hang in the bottom of the cap.
  • means in particular in the form of a grid or a perforated frame, can be provided to maintain said second product in the bottom of said cap.
  • the second product can be separated from the bottom of the cap by an elastically deformable member, in particular a foam block or a spring.
  • an elastically deformable member in particular a foam block or a spring.
  • Such a member allows at least to participate in the elastic bearing of the application surface on the second product, in particular, when the applicator member is made of a material weakly, if at all, elastically compressible.
  • the intermediate element is a foam, in particular with open cells, it allows anchoring of the product in the bottom of the cap, when the product is cast in liquid form.
  • the bottom of the cap may be movable axially, in particular by elastic deformation. This feature makes it possible to recharge the applicator with the second product without having to completely mount the cap on the support, especially in the case where the cap is screwed onto the support.
  • the mobility of the bottom may result from an elastic deformation of said bottom, especially when this is configured as a membrane of elastically deformable material. Alternatively, such mobility can result from a simple sliding assembly of the bottom, the latter being forced in the high position, under the effect of the elastic compression of the applicator member when the cap is mounted on its support.
  • the cap may optionally be mounted in a sealed manner on the support of the capsule.
  • said applicator member consists of a block of a porous material capable of absorbing said first product and of conveying it from said orifice to said application face. It may especially consist of an open-cell foam or semi-open, or a felt. The application face of the applicator member may be covered with a flocking.
  • the applicator member comprises a plurality of "natural" passages formed between the fibers, or by the pores of the material, which communicate with each other. Such natural passages are particularly suitable when the product contained in the container is liquid.
  • At least one "artificial" passage in the form of one or more channels extending, in particular axially, from the support up to to the application face, so as to transport the product contained in the container to the application face.
  • the applicator member may consist of an elastically compressible element, in particular in the form of a bellows, and on which is mounted an application surface, in particular in the form of a foam, a woven fabric or a nonwoven, which surface may optionally be flocked or not.
  • the application surface may be relatively smooth or have reliefs capable of having a massage action when applied to the skin.
  • valve-type opening / closing means are provided for selectively releasing, respectively, closing said orifice, able to be placed in communication with the container containing the first product.
  • liquid contained in the applicator member formed in particular of a mixture of the first and second product
  • the applicator capsule especially when the applicator member consists of an absorbent material, may contain a sufficient quantity of said first product, to constitute an autonomous application unit, which can be used independently of the container. containing the first product, throughout the day.
  • said opening / closing means are mounted so as to release said orifice in response to a sufficient pressure exerted on said application face, elastic return means being provided for, in the absence sufficient pressure on said application face, constrain the opening / closing means in the closed position.
  • said opening / closing means are mounted so as to disengage said orifice in response to a sufficient pressure exerted on the opposite side of the support member to the applicator member, said opening / closing means being biased in the closed position when said pressure ceases.
  • pressure may be exerted on the flexible or deformable walls of the container, or on a piston bottom, and on which the user can press to cause the release of a dose of said first product.
  • Said fixing means of the capsule to the container may be in particular of the snap type, screwing, or self-tightening assembly, in particular on a pump rod or valve.
  • a combined application set is also made, especially on the skin, of a first and a second product, said application assembly comprising a container containing a first product, and suitable to allow the distribution under pressure, and at least one capsule according to the above, each of the capsules containing a second product.
  • the container may be in the form of a container surmounted by a pump, especially without air intake, or a valve, a tube or a bottle with deformable walls, or a bottle bottom forming piston.
  • the second product is a makeup product, each of the capsules containing a different second product, and in particular, of different color and / or appearance.
  • the second product is a product for protection against UV radiation, each of the capsules containing a second product with a different protection index.
  • each of the capsules comprises a different application member, in particular allowing different application characteristics.
  • foams having different hardnesses or absorption capacities particularly as a function of the surface to be treated.
  • the first product may be in the form of a liquid, a cream, or a gel.
  • the applicator capsule 1 shown in the embodiment of FIG. 1A comprises a support 2 made of a thermoplastic material, such as a polypropylene or polyethylene.
  • the support 2 comprises a cylindrical lateral skirt 3 of X axis, whose inner surface is provided with a thread 4 adapted to cooperate with a corresponding thread provided on a container on which the capsule 1 is intended to be mounted.
  • the lateral skirt 3 has at one of its ends closed by a transverse wall 5, pierced at its center with an orifice 6.
  • the orifice 6 is flanked by a collar 7 having a frustoconical profile, and which, as will be seen later, provides a skirt for forming tightness when the capsule 1 is mounted on a container.
  • the transverse wall 5 On the opposite side to the cylindrical side skirt 3, the transverse wall 5 carries a skirt 8, the outer surface of which forms a rib 9 able to cooperate by snapping with a groove 10 formed on the inner surface of a cap 11, so as to allow the reversible mounting of the cap 11 on the support 2. According to a variant, the cap 11 could be screwed onto the skirt 8.
  • an applicator member 20 On the transverse wall 5, on the side opposite the skirt 3, is mounted an applicator member 20, under form of an open cell foam block, especially polyurethane, polyester, polyether, NBR, SBR, PVC, or PVA.
  • the foam block 20 is mounted by gluing, latching or welding on the support 2.
  • the foam block 20 is pierced at its center with an axial channel 24 opening on the one hand on the orifice 6 of the support 2 and on the other hand on the application face 21.
  • the application member 20 may be formed of a stack of several foam blocks, including having different hardness characteristics, depending on the desired application characteristics.
  • the application member may be formed of several foam rings concentric, artificial passages for the product to be conveyed on the application surface 21, which can be arranged at the annular interface between the foam blocks.
  • the foam block 20, and in particular the application face 21, may be covered with a flocking (not shown).
  • a free powder P2 in particular a makeup powder comprising pigments of a given color, which powder is kept in the bottom via a screen or a grid 23.
  • the grid 23 can be maintained by breakdown in the cap, in particular in support on a shoulder.
  • the foam 20 In the mounted position of the cap 11 on the support 2, the foam 20 is compressed, so that the application face 21 bears elastically against the grid 23.
  • the application face 21 In this mounted position of the cap, the application face 21 is loaded. naturally powdered, especially by capillarity, through the holes of the grid 23.
  • the amount of powder transferred to the application face 21 can be further improved by rotating the cap 11 relative to the support 2.
  • Such a capsule may, as shown in Figure 2B, be screwed on a bottle 101, consisting of a body 102 of low height, and one end of which forms a neck provided with a thread 103.
  • the neck ends with a transverse wall 104, pierced with an orifice 105, of profile adapted to receive the frustoconical sealing skirt 7 of the capsule 1.
  • a movable piston bottom 106 Inside the body 102, is disposed a movable piston bottom 106, and able to slide from sealingly bearing against the inner walls of the body 102.
  • the piston 106 defines with the body 102, a variable volume containing a product P1 in the form of a cream, in particular a colorless makeup base.
  • the capsule 1 forms with the bottle 101, a set of application 100 whose operation will now be discussed.
  • Such an assembly 100 may further comprise a plurality of capsules 1, identical to the capsule discussed with reference to Figure 1A, and each containing a powder P2 of a different color.
  • the user first chooses the capsule 1 containing the powder of the color it desires. She puts the capsule on the bottle 101. Before the opening of the cap 11, or after this opening, the user presses the piston 106 so as to raise a certain amount of cream P1 in the axial channel 24 of the applicator member 20, which is thus loaded at once. cream P1, especially inside the channel 24, and colored powder P2 on the application face 21.
  • cream P1 especially inside the channel 24, and colored powder P2 on the application face 21.
  • the smearing performed by the application member 20 causes the homogeneous mixture of the powder and the cream, at the interface between the application face 21 and the skin.
  • the applicator capsule 1 is mounted on the valve stem of a pressurized container 33, via the self-clamping sleeve 30.
  • the free end of the lateral skirt 3 of the support 2 is remote from the container 33 so as to to be able to allow the actuation of the valve 32, in response to an axial bearing force exerted on the cap 11, which actuation causes the release of a dose of the liquid P1 contained in the pressurized container.
  • the product P1 rises in the applicator member via the pores of the applicator member 20, and this up to the application face 21, which bears elastically on the free surface of the product P2.
  • the product P2 disintegrates on the surface and is transferred onto the application face 21 of the member 20. After opening of the cap 11, the application face 20 is moved on the skin so as to apply the product it carries. surface.
  • the pressurized container is used in the manner of a handle for the applicator member 20.
  • the support 2 bears on its face opposite to the applicator member 20 an outer lateral skirt 3, forming an outer covering, and an inner skirt 40 whose inner surface comprises a threading 41, adapted to cooperate with a thread formed on the neck of a flexible-walled tube.
  • the applicator member 20 consists of a block of a soft elastomeric material pierced at its center with an axial channel 24 identical to that of the embodiment of FIG. 1A.
  • materials that can be used to form the applicator member mention may be made of silicone elastomers, nitrile, butyl, latex, polypropylene polyethylene, or polyurethane.
  • the product P2 contained in the cap 11 is of the same type as that of the embodiment of FIG. 1B, and consists of a compacted powder containing colored pigments.
  • the applicator capsule 1 is represented, in FIG. 2A, in its position mounted on application assembly 100 formed of a flexible-walled tube 111, containing in particular a cosmetic milk.
  • the cap 11 is transparent in color, so that the user can see from the outside, the color of the product P2 contained in the applicator capsule 1.
  • the tube may be made of polypropylene or polyethylene.
  • the milk contained in the tube serves as a makeup base and also facilitates the disintegration of the compacted powder contained in the cap 11 of the applicator capsule.
  • the orifice 6 of the support 2 is selectively closed by a valve 42, able to move away from the edge of the transverse wall 5 delimiting the orifice 6, under the pressure of the product P1 contained in the tube 111, in response to a force exerted by the user on the walls of the tube 111, and to come back on the rigid seat formed by said edge when the pressure of the product P1 ceases.
  • the elasticity of the applicator member, in combination with the depression prevailing inside the tube promotes the return bearing on its seat, of the valve 42 when the pressure of the product P1 ceases.
  • valve 42 is particularly advantageous in that it allows the user, after loading the product applicator P1, to disassemble the applicator capsule, and put it in her purse to use it so autonomous throughout the day, the valve 42 preventing any flow of product via the orifice 6.
  • FIG. 1D differs from the applicator capsule of FIG. 1A in that the product P1, with which it is intended to be used in combination, is in liquid form, and is conveyed from port 6 to at the application face 21, via the pores of the open cell foam forming the applicator member 20.
  • the orifice 6 formed in the transverse wall 5 of the support 2 is closed off by a frustoconical valve 50, and adapted to come selectively in tight abutment on a seat of frustoconical shape formed by the edge of the transverse wall 5, delimiting the orifice 6.
  • the valve 50 is constrained in the closed position by a spring 51 disposed on the side of the support, opposite to the application member 20.
  • valve 50 On the side of the applicator member 20, the valve 50 has a lug 52 projecting inside the foam forming the applicator member 20, so as to facilitate the opening of the valve 50 in response to a pressure ex ercée on the application face 21 when it bears on a surface to be treated.
  • the pressing force generated by the compression of the applicator member inside the capsule is not sufficient to cause the valve 50 to open.
  • the remainder of the capsule conforms to the applicator capsule.
  • the applicator capsule of FIG. 1D is shown in FIG. 2C, in the mounted position on an application set 100, formed of a flexible-walled bottle 121 containing a moisturizing milk, and having an orifice 122.
  • the product P2 contained in FIG. the applicator capsule 1 is a free powder containing a sunscreen.
  • the user mounts on the bottle the applicator capsule 1 containing the powder having the desired sun protection factor. It removes the cap 11 and puts the application face 21 covered with powder P2, resting on the surface to be treated, so as to cause the opening of the valve 50. It then exerts pressure on the walls of the bottle. to cause the exit of the product P1 through the orifice 6, and its transport on the application face 21 via the pores of the foam forming the applicator member. The The mixture is then spread by moving the application face adequately on the surface to be treated. By releasing the pressure of the application face 21 on the surface to be treated, the valve 50 closes under the restoring force of the spring 51. Again, the presence of the valve, allows the applicator capsule, after being energized in product P1, especially at the beginning of the day, to be used independently during the rest of the day.
  • a container containing a product P1 can be associated with a plurality of applicator capsules containing the same product P2, but comprising an applicator member having characteristics, in particular of hardness, flexibility, or absorption, different.
  • the user chooses the applicator capsule comprising the application member to obtain, particularly depending on the area of the body to be treated, the desired application characteristics.
  • the form of the applicator member may be any, depending on the surfaces to be treated.
  • the applicator capsule may, in position mounted on a given container, be arranged in the axis of the container, or in a different axis, depending on the desired gesture.
  • the embodiment of Figure 1E differs from the previous embodiment in that the cap 11 is screwed onto the support 2 by means of a thread 60 of the cap 11, adapted to cooperate with a corresponding thread 61 formed on the skirt 8 of the support 2.
  • the cap 11 is thus mounted in a perfectly sealed manner on the support 2.
  • the bottom 63 of the cap 11 is made in the form of an elastically deformable membrane 64, which can be bi-injected with the cap 11.
  • the diaphragm 64 carries a cup 65 in which is compacted the product P2. In the storage position, the application surface 21 is kept at a distance from the free surface of the product P2.
  • the user exerts an axial pressure on the elastically deformable membrane 64 so as to put the surface 21 in elastic contact with the free surface of the product P2, thus allowing the loading of said application surface with said P2 product.
  • the movable bottom 63 By releasing the pressure exerted on the movable bottom 63, it returns by elastic return in its initial position.
  • the user then unscrews the cap 11, and presses the application surface 21 on the skin, so as to cause the opening of the valve 50.
  • By exerting pressure on the walls of the container which can be of the type shown in Figure 2C, it causes the exit of the product P1 which is conveyed on the application surface 21 through the pores of the material forming the application member 20.
  • the product P1 is applied in a mixture with the product P2.
  • FIG. 1F differs from that of FIG. 1A, mainly in that the product P2 is separated from the bottom 73 of the cap 11 by a block of foam 70 mounted, in particular by gluing, in the bottom of the cap.
  • a block of foam improves the elasticity of the contact between the application surface 21 and the free surface of the product P2, especially when the applicator member 20 has little or no elasticity (felt).
  • an open cell foam block 70 this allows the product P2 to be anchored in the pores of the foam, when the product is cast in liquid form.
  • the operation of the capsule 1 according to this embodiment is identical to that of the embodiment of FIG. 1A.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Coating Apparatus (AREA)
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Description

La présente invention a trait à une capsule applicatrice destinée à être utilisée dans le contexte d'une application séparée et/ou combinée de deux produits qui contiennent des actifs ou composés conditionnés séparément.The present invention relates to an applicator capsule for use in the context of a separate and / or combined application of two products which contain individually packaged assets or compounds.

Ainsi, par exemple dans le cadre du maquillage, du corps ou des cheveux, il est souhaitable de pouvoir disposer d'une base de maquillage sous forme d'une crème, d'un gel ou d'un lait, et que l'utilisatrice peut associer avec un produit séparé, notamment sous forme d'une poudre compactée ou libre, et comportant des charges ou pigments colorés, ledit produit séparé pouvant être choisi parmi une pluralité de poudres contenant des pigments de différentes couleurs, de manière à pouvoir choisir la couleur et/ou l'aspect de son maquillage.Thus, for example in the context of makeup, body or hair, it is desirable to have a makeup base in the form of a cream, a gel or a milk, and that the user can associate with a separate product, especially in the form of a compacted powder or free, and comprising fillers or colored pigments, said separated product can be chosen from a plurality of powders containing pigments of different colors, so as to be able to choose the color and / or the appearance of his makeup.

De même, dans le domaine de la protection solaire, il peut être souhaitable de pouvoir disposer d'une base hydratante ou apaisante, sous forme d'un lait ou d'une crème, et que l'utilisatrice peut associer avec un produit séparé, sous forme notamment d'une poudre ou crème, contenant un filtre de protection contre les rayonnements UV, et pouvant être choisi parmi une pluralité de poudres contenant des filtres à indices de protection différents, de manière à pouvoir adapter la protection de sa peau à ses besoins. Ainsi, pour les premiers jours d'exposition au soleil, il est souhaitable d'utiliser un produit à fort indice de protection, puis, au fil des jours, il est possible d'utiliser des produits à indice de protection plus faible.Similarly, in the field of sun protection, it may be desirable to have a moisturizing or soothing base, in the form of a milk or a cream, and that the user can associate with a separate product, in particular in the form of a powder or cream, containing a filter for protection against UV radiation, and which can be chosen from a plurality of powders containing filters with different protection indices, so as to be able to adapt the protection of its skin to its needs. Thus, for the first days of exposure to the sun, it is desirable to use a product with a high degree of protection, then, over the days, it is possible to use products with a lower protection factor.

Aussi, est-ce un des objets de l'invention que de fournir une capsule applicatrice formant une unité d'application d'un produit spécifique, apte à être utilisée en combinaison avec un récipient auxiliaire contenant un produit à action complémentaire de l'action du produit spécifique contenu dans la capsule applicatrice.Also, is it an object of the invention to provide an applicator capsule forming a unit for applying a specific product, suitable for use in combination with an auxiliary container containing a product having an action complementary to the action specific product contained in the applicator capsule.

Le document EP 0 374 339 décrit un récipient contenant un produit liquide, le récipient étant équipé d'une pompe sur laquelle est monté un support portant un applicateur. Le support est monté de manière à pouvoir se déplacer par rapport au récipient afin d'actionner la pompe et charger l'applicateur en produit. L'ensemble est prévu pour appliquer un seul produit.EP 0 374 339 discloses a container containing a liquid product, the container being equipped with a pump on which is mounted a support carrying an applicator. The carrier is mounted to move relative to the container to actuate the pump and charge the applicator with product. The set is intended to apply a single product.

Le document EP 0 263 329 décrit par ailleurs un récipient contenant un premier produit, sur lequel est fixé un applicateur pour appliquer le premier produit. L'applicateur est protégé par un capuchon dans lequel est logé un second produit sous forme d'un pain solide qui vient au contact de l'applicateur lorsque le capuchon est monté sur le récipient.EP 0 263 329 also describes a container containing a first product, on which is fixed an applicator for applying the first product. The applicator is protected by a cap in which is housed a second product in the form of a solid loaf which comes into contact with the applicator when the cap is mounted on the container.

C'est un autre objet de l'invention que de fournir une unité d'application autonome contenant un produit spécifique, un organe d'application, et un organe de montage sur un récipient contenant le produit à utiliser en combinaison avec ledit produit spécifique.It is another object of the invention to provide an autonomous application unit containing a specific product, an applicator member, and a mounting member on a container containing the product to be used in combination with said specific product.

D'autres objets encore apparaîtront dans la description détaillée qui suit.Still other objects will appear in the following detailed description.

Selon l'invention, ces objets sont atteints en réalisant une capsule applicatrice, comportant un support, présentant des moyens aptes à permettre la fixation de la capsule de manière amovible sur un récipient, contenant un premier produit, un organe d'application, notamment sous forme d'un élément compressible élastiquement, monté sur le support et apte à acheminer ledit premier produit, depuis un orifice, ménagé dans le support, jusqu'à une face d'application dudit organe d'application, un capuchon recouvrant de façon amovible ledit organe d'application, le capuchon étant monté sur le support, et la capsule applicatrice comportant un second produit disposé dans le fond du capuchon, notamment sous forme d'un pain solide ou d'une poudre, ladite surface d'application étant apte, en position montée du capuchon, à être mise en appui élastique sur ledit second produit.According to the invention, these objects are achieved by producing an applicator capsule, comprising a support, having means capable of allowing the fixing of the capsule removably on a container, containing a first product, an application member, in particular under as a resiliently compressible element, mounted on the support and adapted to convey said first product, from an orifice, formed in the support, to an application face of said applicator member, a cap removably covering said application member, the cap being mounted on the support, and the applicator capsule comprising a second product disposed in the bottom of the cap, in particular in the form of a solid cake or a powder, said application surface being suitable, in the mounted position of the cap, to be placed elastically on said second product.

On réalise ainsi par exemple, une unité qui contient un produit spécifique, notamment délitable, et qui peut être montée sur un récipient contenant un produit apte à favoriser le délitage du produit spécifique, les deux produits étant maintenus séparés l'un de l'autre, et étant, en vue d'une application combinée, amenés de façon dosée sur la face d'application de l'organe d'application. Le produit contenu dans le capuchon ne vient pas souiller le produit contenu dans le récipient. Un organe d'application d'une capsule donnée n'est jamais mis en contact avec un second produit autre que celui contenu dans la capsule auquel il est dédié. De préférence, le produit contenu dans le récipient est destiné à être distribué sous pression, notamment au moyen d'une pompe, d'un piston, ou d'un gaz propulseur.For example, a unit is produced which contains a specific product, in particular delitable, and which can be mounted on a container containing a product capable of promoting the disintegration of the specific product, the two products being kept separate from one another. and being, for a combined application, metered to the application face of the applicator member. The product contained in the cap does not contaminate the product contained in the container. An application member of a given capsule is never brought into contact with a second product other than that contained in the capsule to which it is dedicated. Preferably, the product contained in the container is intended to be dispensed under pressure, in particular by means of a pump, a piston, or a propellant.

La face d'application de l'organe d'application est, au moins avant utilisation, contrainte élastiquement en appui contre la surface libre du produit contenu dans le capuchon, ce qui, avec certains produits, est suffisant pour assurer un bon chargement de ladite face d'application avec ledit produit. Toutefois, le chargement de la face d'application avec le second produit peut être favorisé en entraînant en rotation la face d'application en appui contre ladite surface libre du produit contenu dans le capuchon.The application face of the applicator member is, at least before use, elastically constrained in abutment against the free surface of the product contained in the cap, which, with certain products, is sufficient to ensure proper loading of said application face with said product. However, the loading of the application face with the second product can be promoted by rotating the application face bearing against said free surface of the product contained in the cap.

Le produit peut être coulé, à chaud ou à froid, ou compacté, directement dans le fond du capuchon, ou dans une cupule montée dans ledit fond. Des moyens, notamment sous forme d'ailettes ou autres moyens d'accrochage, peuvent être prévus pour, dans l'hypothèse où le produit est coulé dans le capuchon, permettre au produit, lorsqu'il se solidifie, de s'accrocher dans le fond du capuchon.The product may be cast, hot or cold, or compacted, directly in the bottom of the cap, or in a cup mounted in said bottom. Means, in particular in the form of fins or other attachment means, may be provided for, in the event that the product is poured into the cap, allow the product, when it solidifies, to hang in the bottom of the cap.

Dans le cas d'un produit sous forme d'une poudre libre ou d'une crème, des moyens, notamment sous forme d'une grille ou d'une trame ajourée, peuvent être prévus pour maintenir ledit second produit dans le fond dudit capuchon.In the case of a product in the form of a loose powder or a cream, means, in particular in the form of a grid or a perforated frame, can be provided to maintain said second product in the bottom of said cap. .

Le second produit peut être séparé du fond du capuchon par un organe élastiquement déformable, notamment un bloc de mousse ou un ressort. Un tel organe permet au moins de participer la mise en appui élastique de la surface d'application sur le second produit, en particulier, lorsque l'organe d'application est réalisé en un matériau faiblement , voire pas du tout, compressible élastiquement. Dans le cas où l'élément intermédiaire est une mousse, en particulier à cellules ouvertes, celle ci permet l'ancrage du produit dans le fond du capuchon, lorsque le produit est coulé sous forme liquide.The second product can be separated from the bottom of the cap by an elastically deformable member, in particular a foam block or a spring. Such a member allows at least to participate in the elastic bearing of the application surface on the second product, in particular, when the applicator member is made of a material weakly, if at all, elastically compressible. In the case where the intermediate element is a foam, in particular with open cells, it allows anchoring of the product in the bottom of the cap, when the product is cast in liquid form.

Le fond du capuchon peut être mobile axialement, notamment par déformation élastique. Cette caractéristique permet de pouvoir recharger l'applicateur avec le second produit sans avoir à complètement remonter le capuchon sur le support, notamment dans le cas où le capuchon est vissé sur le support. La mobilité du fond peut résulter d'une déformation élastique dudit fond, notamment lorsque celui-ci est configuré sous forme d'une membrane en matériau élastiquement déformable. Alternativement, une telle mobilité peut résulter d'un simple montage à coulisse du fond, celui-ci étant contraint en position haute, sous l'effet de la compression élastique de l'organe d'application lorsque le capuchon est monté sur son support. Le capuchon pourra éventuellement être monté de façon étanche sur le support de la capsule.The bottom of the cap may be movable axially, in particular by elastic deformation. This feature makes it possible to recharge the applicator with the second product without having to completely mount the cap on the support, especially in the case where the cap is screwed onto the support. The mobility of the bottom may result from an elastic deformation of said bottom, especially when this is configured as a membrane of elastically deformable material. Alternatively, such mobility can result from a simple sliding assembly of the bottom, the latter being forced in the high position, under the effect of the elastic compression of the applicator member when the cap is mounted on its support. The cap may optionally be mounted in a sealed manner on the support of the capsule.

Avantageusement, ledit organe d'application est constitué d'un bloc d'un matériau poreux, apte à absorber ledit premier produit et à l'acheminer depuis ledit orifice jusqu'à ladite face d'application. Il peut notamment être constitué d'une mousse à cellules ouvertes ou semi ouvertes, ou d'un feutre. La face d'application de l'organe d'application peut être recouverte d'un flocage. Dans le cas d'un tel produit absorbant, notamment dans le cas d'un feutre ou d'une mousse à cellules ouvertes ou semi ouvertes, l'organe d'application comprend une pluralité de passages "naturels" formés entre les fibres, ou par les pores du matériau, lesquels communiquent entre eux. De tels passages naturels sont particulièrement adaptés lorsque le produit contenu dans le récipient est liquide. Dans le cas d'un produit plus visqueux, ou dans le cas d'un matériau non poreux, on peut réaliser au moins un passage "artificiel" sous forme d'un ou plusieurs canaux s'étendant, notamment axialement, depuis le support jusqu'à la face d'application, de manière à transporter le produit contenu dans le récipient jusqu'à la face d'application.Advantageously, said applicator member consists of a block of a porous material capable of absorbing said first product and of conveying it from said orifice to said application face. It may especially consist of an open-cell foam or semi-open, or a felt. The application face of the applicator member may be covered with a flocking. In the case of such an absorbent product, especially in the case of an open or semi open-celled felt or foam, the applicator member comprises a plurality of "natural" passages formed between the fibers, or by the pores of the material, which communicate with each other. Such natural passages are particularly suitable when the product contained in the container is liquid. In the case of a more viscous product, or in the case of a non-porous material, it is possible to produce at least one "artificial" passage in the form of one or more channels extending, in particular axially, from the support up to to the application face, so as to transport the product contained in the container to the application face.

L'organe d'application peut être constitué d'un élément compressible élastiquement, notamment sous forme d'un soufflet, et sur lequel est monté une surface d'application, notamment sous forme d'une mousse, d'un tissé ou d'un non tissé, laquelle surface peut éventuellement être floquée ou non. La surface d'application peut être relativement lisse ou présenter des reliefs aptes à avoir une action de massage lorsqu'ils sont appliqués sur la peau.The applicator member may consist of an elastically compressible element, in particular in the form of a bellows, and on which is mounted an application surface, in particular in the form of a foam, a woven fabric or a nonwoven, which surface may optionally be flocked or not. The application surface may be relatively smooth or have reliefs capable of having a massage action when applied to the skin.

De préférence, au voisinage dudit orifice, des moyens d'ouverture/fermeture, de type à clapet ou à valve, sont prévus pour, sélectivement, dégager, respectivement, obturer ledit orifice, apte à être mis en communication avec le récipient contenant le premier produit. Ainsi, on évite que du liquide contenu dans l'organe d'application (formé notamment d'un mélange du premier et du second produit) ne puisse redescendre, via ledit orifice, dans le récipient contenant le premier produit. En outre, la capsule applicatrice, notamment lorsque l'organe d'application est constitué d'un matériau absorbant, peut contenir une quantité suffisante dudit premier produit, pour constituer une unité d'application autonome, qui peut être utilisée de manière indépendante du récipient contenant le premier produit, tout au long de la journée.Preferably, in the vicinity of said orifice, valve-type opening / closing means are provided for selectively releasing, respectively, closing said orifice, able to be placed in communication with the container containing the first product. Thus, it is avoided that liquid contained in the applicator member (formed in particular of a mixture of the first and second product) can not descend through said orifice into the container containing the first product. In addition, the applicator capsule, especially when the applicator member consists of an absorbent material, may contain a sufficient quantity of said first product, to constitute an autonomous application unit, which can be used independently of the container. containing the first product, throughout the day.

Selon un mode de réalisation spécifique, lesdits moyens d'ouverture/fermeture sont montés de manière à dégager ledit orifice en réponse à une pression suffisante exercée sur ladite face d'application, des moyens de rappel élastique étant prévus, pour, en l'absence de pression suffisante sur ladite face d'application, contraindre les moyens d'ouverture/fermeture en position fermée. Ainsi, le transport du premier produit sur la face d'application, en vue d'y être mélangé avec le second produit, ne se fait qu'en position d'application, lorsque la face d'application est mise en appui sur la surface à traiter. Ainsi, on améliore encore la séparation entre le premier produit contenu dans le récipient, et le second produit contenu dans la capsule.According to a specific embodiment, said opening / closing means are mounted so as to release said orifice in response to a sufficient pressure exerted on said application face, elastic return means being provided for, in the absence sufficient pressure on said application face, constrain the opening / closing means in the closed position. Thus, the transport of the first product on the application face, in order to be mixed with the second product, is only in the application position, when the application face is pressed on the surface treat. Thus, the separation between the first product contained in the container and the second product contained in the capsule is further improved.

Alternativement, lesdits moyens d'ouverture/fermeture sont montés de manière à dégager ledit orifice en réponse à une pression suffisante exercée du côté du support opposé à l'organe d'application, lesdits moyens d'ouverture/fermeture étant rappelés en position de fermeture lorsque cesse ladite pression. Une telle pression peut être exercée sur les parois souples ou déformables du récipient, ou sur un fond formant piston, et sur lequel l'utilisatrice peut appuyer pour provoquer la sortie d'une dose dudit premier produit.Alternatively, said opening / closing means are mounted so as to disengage said orifice in response to a sufficient pressure exerted on the opposite side of the support member to the applicator member, said opening / closing means being biased in the closed position when said pressure ceases. Such pressure may be exerted on the flexible or deformable walls of the container, or on a piston bottom, and on which the user can press to cause the release of a dose of said first product.

Lesdits moyens de fixation de la capsule au récipient peuvent être notamment du type à encliquetage, vissage, ou montage auto-serrant, notamment sur une tige de pompe ou de valve.Said fixing means of the capsule to the container may be in particular of the snap type, screwing, or self-tightening assembly, in particular on a pump rod or valve.

Selon un autre aspect de l'invention, on réalise également un ensemble d'application combinée, notamment sur la peau, d'un premier et d'un second produit, ledit ensemble d'application comportant un récipient contenant un premier produit, et apte à en permettre la distribution sous pression, et au moins une capsule selon ce qui précède, chacune des capsules contenant un second produit.According to another aspect of the invention, a combined application set is also made, especially on the skin, of a first and a second product, said application assembly comprising a container containing a first product, and suitable to allow the distribution under pressure, and at least one capsule according to the above, each of the capsules containing a second product.

Le récipient peut être sous forme notamment d'un récipient surmonté d'une pompe, notamment sans reprise d'air, ou d'une valve, d'un tube ou d'un flacon à parois déformables, ou d'un flacon à fond formant piston.The container may be in the form of a container surmounted by a pump, especially without air intake, or a valve, a tube or a bottle with deformable walls, or a bottle bottom forming piston.

A titre d'exemple avantageux, le second produit est un produit de maquillage, chacune des capsules contenant un second produit différent, et notamment, de couleur et/ou d'aspect différents.As an advantageous example, the second product is a makeup product, each of the capsules containing a different second product, and in particular, of different color and / or appearance.

A titre d'exemple encore, le second produit est un produit de protection contre les rayonnements UV, chacune des capsules contenant un second produit à indice de protection différent.By way of example again, the second product is a product for protection against UV radiation, each of the capsules containing a second product with a different protection index.

Selon une autre alternative, chacune des capsules comprend un organe d'application différent, permettant notamment des caractéristiques d'application différentes. On peut à cet effet, utiliser, notamment en fonction de la surface à traiter, des mousses ayant des duretés, ou capacités d'absorption différentes.According to another alternative, each of the capsules comprises a different application member, in particular allowing different application characteristics. To this end, it is possible to use foams having different hardnesses or absorption capacities, particularly as a function of the surface to be treated.

Le premier produit peut être sous forme d'un liquide, d'une crème, ou d'un gel.The first product may be in the form of a liquid, a cream, or a gel.

L'invention consiste, mises à part les dispositions exposées ci-dessus, en un certain nombre d'autres dispositions qui seront explicitées ci-après, à propos d'exemples de réalisation non limitatifs, décrits en référence aux figures annexées, parmi lesquelles :

  • les figures 1A-1F illustrent de façon schématique six modes de réalisation de la capsule applicatrice selon l'invention; et
  • les figures 2A-2C illustrent trois modes de réalisation d'un ensemble d'application monté selon la présente invention.
The invention consists, apart from the arrangements described above, in a certain number of other arrangements which will be explained below, with reference to nonlimiting exemplary embodiments, described with reference to the appended figures, among which:
  • FIGS. 1A-1F schematically illustrate six embodiments of the applicator capsule according to the invention; and
  • Figures 2A-2C illustrate three embodiments of an application assembly mounted according to the present invention.

La capsule applicatrice 1 représentée dans le mode de réalisation de la figure 1A, comprend un support 2, en un matériau thermoplastique, tel qu'un polypropylène ou polyéthylène. Le support 2 comporte une jupe latérale cylindrique 3 d'axe X, dont la surface interne est pourvue d'un filetage 4 apte à coopérer avec un filetage correspondant prévu sur un récipient sur lequel la capsule 1 est destinée à être montée. La jupe latérale 3 a l'une de ses extrémités fermée par une paroi transversale 5, percée en son centre d'un orifice 6. Du côté de la paroi tournée vers la jupe cylindrique 3, l'orifice 6 est bordé d'une collerette 7 présentant un profil tronconique, et qui, comme on le verra par la suite, réalise une jupe destinée à former étanchéité lorsque la capsule 1 est montée sur un récipient.The applicator capsule 1 shown in the embodiment of FIG. 1A comprises a support 2 made of a thermoplastic material, such as a polypropylene or polyethylene. The support 2 comprises a cylindrical lateral skirt 3 of X axis, whose inner surface is provided with a thread 4 adapted to cooperate with a corresponding thread provided on a container on which the capsule 1 is intended to be mounted. The lateral skirt 3 has at one of its ends closed by a transverse wall 5, pierced at its center with an orifice 6. At the side of the wall facing the cylindrical skirt 3, the orifice 6 is flanked by a collar 7 having a frustoconical profile, and which, as will be seen later, provides a skirt for forming tightness when the capsule 1 is mounted on a container.

Du côté opposé à la jupe latérale cylindrique 3, la paroi transversale 5 porte une jupe 8 dont la surface extérieure forme une nervure 9 apte à coopérer par claquage avec une gorge 10 formée sur la surface interne d'un capuchon 11, de manière à permettre le montage réversible du capuchon 11 sur le support 2. Selon une variante, le capuchon 11 pourrait être vissé sur la jupe 8. Sur la paroi transversale 5, du côté opposé à la jupe 3, est monté un organe d'application 20, sous forme d'un bloc de mousse à cellules ouvertes, notamment en polyuréthanne, polyester, polyéther, NBR, SBR, PVC, ou PVA. Le bloc de mousse 20 est monté par collage, encliquetage ou par soudure sur le support 2. Une face 21 de l'organe d'application 20, opposée au support 2, forme une face d'application. Le bloc de mousse 20, est percé en son centre d'un canal axial 24 débouchant d'une part sur l'orifice 6 du support 2 et, d'autre part sur la face d'application 21. L'organe d'application 20 peut être formé d'un empilement de plusieurs blocs de mousse, ayant notamment des caractéristiques de dureté différentes, en fonction des caractéristiques d'application recherchées. De même l'organe d'application peut être formé de plusieurs anneaux de mousse concentriques, des passages artificiels, pour le produit à acheminer sur la surface d'application 21, pouvant être aménagés à l'interface annulaire entre les blocs de mousse. Le bloc de mousse 20, et notamment la face d'application 21, peut être recouvert d'un flocage (non représenté).On the opposite side to the cylindrical side skirt 3, the transverse wall 5 carries a skirt 8, the outer surface of which forms a rib 9 able to cooperate by snapping with a groove 10 formed on the inner surface of a cap 11, so as to allow the reversible mounting of the cap 11 on the support 2. According to a variant, the cap 11 could be screwed onto the skirt 8. On the transverse wall 5, on the side opposite the skirt 3, is mounted an applicator member 20, under form of an open cell foam block, especially polyurethane, polyester, polyether, NBR, SBR, PVC, or PVA. The foam block 20 is mounted by gluing, latching or welding on the support 2. A face 21 of the applicator member 20, opposite the support 2, forms an application face. The foam block 20 is pierced at its center with an axial channel 24 opening on the one hand on the orifice 6 of the support 2 and on the other hand on the application face 21. The application member 20 may be formed of a stack of several foam blocks, including having different hardness characteristics, depending on the desired application characteristics. Similarly, the application member may be formed of several foam rings concentric, artificial passages for the product to be conveyed on the application surface 21, which can be arranged at the annular interface between the foam blocks. The foam block 20, and in particular the application face 21, may be covered with a flocking (not shown).

Dans le fond du capuchon 11, est disposée une poudre libre P2, notamment une poudre de maquillage comportant des pigments d'une couleur donnée, laquelle poudre est maintenue dans le fond via un tamis ou une grille 23. La grille 23 peut être maintenue par claquage dans le capuchon, notamment en appui sur un épaulement. En position montée du capuchon 11 sur le support 2, la mousse 20 est comprimée, de sorte que la face d'application 21 soit en appui élastique contre la grille 23. Dans cette position montée du capuchon, la face d'application 21 se charge naturellement en poudre, notamment par capillarité, via les trous de la grille 23. La quantité de poudre transférée sur la face d'application 21 peut encore être améliorée en faisant tourner le capuchon 11 par rapport au support 2.In the bottom of the cap 11 is disposed a free powder P2, in particular a makeup powder comprising pigments of a given color, which powder is kept in the bottom via a screen or a grid 23. The grid 23 can be maintained by breakdown in the cap, in particular in support on a shoulder. In the mounted position of the cap 11 on the support 2, the foam 20 is compressed, so that the application face 21 bears elastically against the grid 23. In this mounted position of the cap, the application face 21 is loaded. naturally powdered, especially by capillarity, through the holes of the grid 23. The amount of powder transferred to the application face 21 can be further improved by rotating the cap 11 relative to the support 2.

Une telle capsule peut, ainsi que représentée à la figure 2B, être vissée sur un flacon 101, constitué d'un corps 102 de faible hauteur, et dont une extrémité forme un col pourvu d'un filetage 103. Le col se termine par une paroi transversale 104, percée d'un orifice 105, de profil adapté pour recevoir la jupe d'étanchéité tronconique 7 de la capsule 1. A l'intérieur du corps 102, est disposé un fond mobile formant piston 106, et apte à coulisser de façon étanche en appui contre les parois intérieures du corps 102. Le piston 106 délimite avec le corps 102, un volume variable contenant un produit P1 sous forme d'une crème, notamment une base de maquillage incolore. Ainsi montée, la capsule 1 forme avec le flacon 101, un ensemble d'application 100 dont le fonctionnement va maintenant être discuté. Un tel ensemble 100 peut comprendre en outre une pluralité de capsules 1, identiques à la capsule discutée en référence à la figure 1A, et contenant chacune une poudre P2 d'une couleur différente.Such a capsule may, as shown in Figure 2B, be screwed on a bottle 101, consisting of a body 102 of low height, and one end of which forms a neck provided with a thread 103. The neck ends with a transverse wall 104, pierced with an orifice 105, of profile adapted to receive the frustoconical sealing skirt 7 of the capsule 1. Inside the body 102, is disposed a movable piston bottom 106, and able to slide from sealingly bearing against the inner walls of the body 102. The piston 106 defines with the body 102, a variable volume containing a product P1 in the form of a cream, in particular a colorless makeup base. Thus mounted, the capsule 1 forms with the bottle 101, a set of application 100 whose operation will now be discussed. Such an assembly 100 may further comprise a plurality of capsules 1, identical to the capsule discussed with reference to Figure 1A, and each containing a powder P2 of a different color.

L'utilisatrice choisit en premier lieu la capsule 1 contenant la poudre de la couleur qu'elle désire. Elle monte la capsule sur le flacon 101. Préalablement à l'ouverture du capuchon 11, ou postérieurement à cette ouverture, l'utilisatrice appuie sur le piston 106 de manière à faire monter une certaine quantité de crème P1 dans le canal axial 24 de l'organe d'application 20, lequel est ainsi chargé à la fois en crème P1, notamment à l'intérieur du canal 24, et en poudre colorée P2 sur la face d'application 21. Avec le mode de réalisation de la capsule selon la figure 1A, il est à noter que, en fonction de la viscosité du produit P1, et de la compression de la mousse formant l'organe d'application 20, la montée du produit P1 dans le canal 24, peut résulter de la simple dépression provoquée par l'expansion de la mousse de l'organe d'application 20, à l'ouverture du capuchon 11.The user first chooses the capsule 1 containing the powder of the color it desires. She puts the capsule on the bottle 101. Before the opening of the cap 11, or after this opening, the user presses the piston 106 so as to raise a certain amount of cream P1 in the axial channel 24 of the applicator member 20, which is thus loaded at once. cream P1, especially inside the channel 24, and colored powder P2 on the application face 21. With the embodiment of the capsule according to Figure 1A, it should be noted that, depending on the viscosity product P1, and compression of the foam forming the application member 20, the rise of the product P1 in the channel 24, may result from the simple depression caused by the expansion of the foam of the organ of application 20, at the opening of the cap 11.

L'utilisatrice applique alors la face d'application 21 sur la surface à traiter, notamment le visage, et la déplace en appui léger sur la peau, notamment, par des petits mouvements circulaires. L'estompage réalisé par l'organe d'application 20 provoque le mélange homogène de la poudre et de la crème, à l'interface entre la face d'application 21 et la peau. Le cas échéant, l'utilisatrice peut rajouter de la crème P1 au mélange, en appuyant à nouveau sur le piston 106. De la même manière, elle peut également enrichir le mélange en poudre colorée, en remettant la face d'application 21 en contact avec la grille 23. Après application, elle remonte le capuchon 11 sur le support 2.The user then applies the application face 21 to the surface to be treated, especially the face, and moves it lightly on the skin, in particular by small circular movements. The smearing performed by the application member 20 causes the homogeneous mixture of the powder and the cream, at the interface between the application face 21 and the skin. If necessary, the user can add cream P1 to the mixture, by pressing the piston 106 again. In the same way, it can also enrich the colored powder mixture, by putting the application face 21 in contact with each other. with the grid 23. After application, it raises the cap 11 on the support 2.

Pour maquiller une autre partie du corps ou du visage en une autre couleur, elle dévisse la capsule 1 du flacon 101, et remonte sur le récipient 101, une capsule 1 contenant une poudre P2 ayant la couleur désirée. Elle procède à nouveau de la manière indiquée précédemment. Ainsi, la face d'application 21 d'un organe d'application donné 20 est en contact avec une seule poudre d'une seule couleur, ce qui permet d'éviter d'avoir à nettoyer l'organe d'application entre deux applications de deux couleurs différentes. La crème P1 à l'intérieur du récipient 101 n'est jamais souillée par la poudre P2 contenue dans le fond des capsules applicatrice 1.To make up another part of the body or face in another color, it unscrews the capsule 1 of the bottle 101, and goes back on the container 101, a capsule 1 containing a powder P2 having the desired color. It proceeds again as previously indicated. Thus, the application face 21 of a given application member 20 is in contact with a single powder of a single color, which makes it possible to avoid having to clean the applicator member between two applications. of two different colors. The cream P1 inside the container 101 is never contaminated by the powder P2 contained in the bottom of the applicator capsules 1.

Le mode de réalisation de la figure 1B se distingue du mode de réalisation de la figure 1A en ce que :

  • le produit P2, est sous forme d'un pain solide, obtenu par coulage à chaud ou à froid, dans le fond du capuchon 11, d'une composition liquide, notamment à base de plâtre, et qui va se solidifier en refroidissant. Des moyens d'accrochage (non représentés) assurent l'ancrage du produit P2 dans le fond du capuchon 11. Ainsi, la face d'application 21 de l'organe d'application 20 est directement en appui élastique sur la surface libre du produit P2.
  • l'organe d'application 20 est constitué d'un bloc de mousse à cellules ouvertes, ne présentant pas un canal axial du type de celui 24 présent dans le bloc de mousse du mode de réalisation précédent. La porosité du matériau est suffisante pour assurer le transport d'un liquide depuis l'orifice 6 jusqu'à la face d'application 21.
  • la paroi transversale 5 du support 2 forme du côté opposé à l'organe d'application 20, un manchon 30 apte à permettre un montage auto serrant sur la tige émergeante 31 d'une valve 32 équipant un récipient pressurisé 33, contenant une composition liquide P1 apte à permettre le délitage du produit P2. La composition P1 remonte sur la surface d'application via les pores du bloc de mousse à cellules ouvertes formant l'organe d'application 20.
The embodiment of FIG. 1B differs from the embodiment of FIG. 1A in that:
  • the product P2 is in the form of a solid cake, obtained by hot or cold casting, in the bottom of the cap 11, of a liquid composition, especially based on plaster, and which will solidify on cooling. Fastening means (not shown) ensure the anchoring of the product P2 in the bottom of the cap 11. Thus, the application face 21 of the applicator member 20 is directly in elastic support on the free surface of the product P2.
  • the applicator member 20 consists of an open cell foam block, not having an axial channel of the type of that present in the foam block of the previous embodiment. The porosity of the material is sufficient to ensure the transport of a liquid from the orifice 6 to the application face 21.
  • the transverse wall 5 of the support 2 forms on the opposite side to the applicator member 20, a sleeve 30 adapted to allow self-tightening mounting on the emergent rod 31 of a valve 32 fitted to a pressurized container 33, containing a liquid composition P1 able to allow the disintegration of the product P2. The composition P1 rises on the application surface via the pores of the open cell foam block forming the applicator member 20.

A l'utilisation, la capsule applicatrice 1 est montée sur la tige de valve d'un récipient pressurisé 33, via le manchon auto serrant 30. L'extrémité libre de la jupe latérale 3 du support 2 est à distance du récipient 33 de manière à pouvoir permettre l'actionnement de la valve 32, en réponse à une force d'appui axiale exercée sur le capuchon 11, lequel actionnement provoque la sortie d'une dose du liquide P1 contenu dans le récipient pressurisé. Le produit P1 remonte dans l'organe d'application via les pores de l'organe d'application 20, et ce jusqu'à la face d'application 21, laquelle est en appui élastique sur la surface libre du produit P2. Le produit P2 se délite en surface et est transféré sur la face d'application 21 de l'organe 20. Après ouverture du capuchon 11, la face d'application 20 est déplacée sur la peau de manière à appliquer le produit qu'elle porte en surface. Le récipient pressurisé est utilisé à la manière d'un manche pour l'organe d'application 20.In use, the applicator capsule 1 is mounted on the valve stem of a pressurized container 33, via the self-clamping sleeve 30. The free end of the lateral skirt 3 of the support 2 is remote from the container 33 so as to to be able to allow the actuation of the valve 32, in response to an axial bearing force exerted on the cap 11, which actuation causes the release of a dose of the liquid P1 contained in the pressurized container. The product P1 rises in the applicator member via the pores of the applicator member 20, and this up to the application face 21, which bears elastically on the free surface of the product P2. The product P2 disintegrates on the surface and is transferred onto the application face 21 of the member 20. After opening of the cap 11, the application face 20 is moved on the skin so as to apply the product it carries. surface. The pressurized container is used in the manner of a handle for the applicator member 20.

Dans le mode de réalisation de la figure 1C, le support 2 porte sur sa face opposée à l'organe d'application 20 une jupe latérale extérieure 3, formant habillage extérieur, et une jupe interne 40 dont la surface intérieure comporte un filetage 41, apte à coopérer avec un filetage ménagé sur la col d'un tube à parois souples. L'organe d'application 20 est constitué d'un bloc d'un matériau élastomérique mou, percé en son centre d'un canal axial 24 identique à celui du mode de réalisation de la figure 1A. A titre d'exemples de matériaux pouvant être utilisés pour former l'organe d'application, on peut citer les élastomères de silicone, de nitrile, de butyle, de latex, de polyéthylène de polypropylène, ou de polyuréthanne. Le produit P2 contenu dans le capuchon 11 est du même type que celui du mode de réalisation de la figure 1B, et est constitué d'une poudre compactée contenant des pigments colorés.In the embodiment of FIG. 1C, the support 2 bears on its face opposite to the applicator member 20 an outer lateral skirt 3, forming an outer covering, and an inner skirt 40 whose inner surface comprises a threading 41, adapted to cooperate with a thread formed on the neck of a flexible-walled tube. The applicator member 20 consists of a block of a soft elastomeric material pierced at its center with an axial channel 24 identical to that of the embodiment of FIG. 1A. As examples of materials that can be used to form the applicator member, mention may be made of silicone elastomers, nitrile, butyl, latex, polypropylene polyethylene, or polyurethane. The product P2 contained in the cap 11 is of the same type as that of the embodiment of FIG. 1B, and consists of a compacted powder containing colored pigments.

La capsule applicatrice 1 selon ce mode de réalisation est représentée, à la figure 2A, dans sa position montée sur ensemble d'application 100 formé d'un tube à parois souples 111, contenant en particulier un lait cosmétique. De préférence, le capuchon 11 est de couleur transparente, de manière à ce que l'utilisatrice puisse voir depuis l'extérieur, la couleur du produit P2 contenu dans la capsule applicatrice 1. Le tube peut être réalisé en polypropylène ou polyéthylène. Le lait contenu dans le tube sert de base de maquillage et facilite également le délitage de la poudre compactée contenue dans le capuchon 11 de la capsule applicatrice.The applicator capsule 1 according to this embodiment is represented, in FIG. 2A, in its position mounted on application assembly 100 formed of a flexible-walled tube 111, containing in particular a cosmetic milk. Preferably, the cap 11 is transparent in color, so that the user can see from the outside, the color of the product P2 contained in the applicator capsule 1. The tube may be made of polypropylene or polyethylene. The milk contained in the tube serves as a makeup base and also facilitates the disintegration of the compacted powder contained in the cap 11 of the applicator capsule.

L'orifice 6 du support 2 est obturé sélectivement par un clapet 42, apte à s'écarter du bord de la paroi transversale 5 délimitant l'orifice 6, sous la pression du produit P1 contenu dans le tube 111, en réponse à une force exercée par l'utilisatrice sur les parois du tube 111, et à revenir en appui sur le siège rigide formé par ledit bord lorsque cesse la pression du produit P1. L'élasticité de l'organe d'application, en combinaison avec la dépression régnant à l'intérieur du tube, favorise le retour en appui sur son siège, du clapet 42 lorsque cesse la pression du produit P1. La présence du clapet 42 est particulièrement avantageuse en ce qu'elle permet à l'utilisatrice, après avoir chargé l'applicateur de produit P1, de démonter la capsule applicatrice, et de la mettre dans son sac à main pour l'utiliser de façon autonome tout au long de la journée, le clapet 42 empêchant tout écoulement de produit via l'orifice 6.The orifice 6 of the support 2 is selectively closed by a valve 42, able to move away from the edge of the transverse wall 5 delimiting the orifice 6, under the pressure of the product P1 contained in the tube 111, in response to a force exerted by the user on the walls of the tube 111, and to come back on the rigid seat formed by said edge when the pressure of the product P1 ceases. The elasticity of the applicator member, in combination with the depression prevailing inside the tube, promotes the return bearing on its seat, of the valve 42 when the pressure of the product P1 ceases. The presence of the valve 42 is particularly advantageous in that it allows the user, after loading the product applicator P1, to disassemble the applicator capsule, and put it in her purse to use it so autonomous throughout the day, the valve 42 preventing any flow of product via the orifice 6.

Le mode de réalisation de la figure 1D diffère de la capsule applicatrice de la figure 1A en ce que le produit P1, avec lequel elle est destinée à être utilisée en combinaison, est sous forme liquide, et est acheminé depuis l'orifice 6 jusqu'à la face d'application 21, via les pores de la mousse à cellules ouvertes formant l'organe d'application 20. L'orifice 6 formé dans la paroi transversale 5 du support 2 est obturé par une valve 50 de forme tronconique, et apte à venir sélectivement en appui étanche sur un siège de forme tronconique formé par le bord de la paroi transversale 5, délimitant l'orifice 6. La valve 50 est contrainte en position fermée par un ressort 51 disposé du côté du support, opposé à l'organe d'application 20. Du côté de l'organe d'application 20, la valve 50 présente un ergot 52 faisant saillie à l'intérieur de la mousse formant l'organe d'application 20, de manière à faciliter l'ouverture de la valve 50 en réponse à une pression exercée sur la face d'application 21 lors de sa mise en appui sur une surface à traiter. La force d'appui générée par la compression de l'organe d'application à l'intérieur de la capsule n'est pas suffisante pour provoquer l'ouverture de la valve 50. Le reste de la capsule est conforme à la capsule applicatrice de la figure 1A.The embodiment of FIG. 1D differs from the applicator capsule of FIG. 1A in that the product P1, with which it is intended to be used in combination, is in liquid form, and is conveyed from port 6 to at the application face 21, via the pores of the open cell foam forming the applicator member 20. The orifice 6 formed in the transverse wall 5 of the support 2 is closed off by a frustoconical valve 50, and adapted to come selectively in tight abutment on a seat of frustoconical shape formed by the edge of the transverse wall 5, delimiting the orifice 6. The valve 50 is constrained in the closed position by a spring 51 disposed on the side of the support, opposite to the application member 20. On the side of the applicator member 20, the valve 50 has a lug 52 projecting inside the foam forming the applicator member 20, so as to facilitate the opening of the valve 50 in response to a pressure ex ercée on the application face 21 when it bears on a surface to be treated. The pressing force generated by the compression of the applicator member inside the capsule is not sufficient to cause the valve 50 to open. The remainder of the capsule conforms to the applicator capsule. Figure 1A.

La capsule applicatrice de la figure 1D est représentée à la figure 2C, en position montée sur un ensemble d'application 100, formé d'un flacon à parois souples 121 contenant un lait hydratant, et présentant un orifice 122. Le produit P2 contenu dans la capsule applicatrice 1 est une poudre libre contenant un filtre solaire.The applicator capsule of FIG. 1D is shown in FIG. 2C, in the mounted position on an application set 100, formed of a flexible-walled bottle 121 containing a moisturizing milk, and having an orifice 122. The product P2 contained in FIG. the applicator capsule 1 is a free powder containing a sunscreen.

Lors de l'application, l'utilisatrice monte sur le flacon la capsule applicatrice 1 contenant la poudre ayant l'indice de protection solaire désiré. Elle retire le capuchon 11 et met la face d'application 21 recouverte de poudre P2, en appui sur la surface à traiter, de manière à provoquer l'ouverture de la valve 50. Elle exerce alors une pression sur les parois du flacon de manière à provoquer la sortie du produit P1 au travers de l'orifice 6, et son transport sur la face d'application 21 via les pores de la mousse formant l'organe d'application. Le mélange est alors étalé en déplaçant la face d'application de manière adéquate sur la surface à traiter. En relâchant la pression de la face d'application 21 sur la surface à traiter, la valve 50 se referme sous la force de rappel du ressort 51. A nouveau, la présence de la valve, permet à la capsule applicatrice, après avoir été alimentée en produit P1, notamment en début de journée, d'être utilisée de manière autonome pendant le reste de la journée.During the application, the user mounts on the bottle the applicator capsule 1 containing the powder having the desired sun protection factor. It removes the cap 11 and puts the application face 21 covered with powder P2, resting on the surface to be treated, so as to cause the opening of the valve 50. It then exerts pressure on the walls of the bottle. to cause the exit of the product P1 through the orifice 6, and its transport on the application face 21 via the pores of the foam forming the applicator member. The The mixture is then spread by moving the application face adequately on the surface to be treated. By releasing the pressure of the application face 21 on the surface to be treated, the valve 50 closes under the restoring force of the spring 51. Again, the presence of the valve, allows the applicator capsule, after being energized in product P1, especially at the beginning of the day, to be used independently during the rest of the day.

Selon une variante de l'invention, on peut associer un récipient contenant un produit P1, à une pluralité de capsules applicatrices contenant le même produit P2, mais comportant un organe d'application ayant des caractéristiques, notamment de dureté, de souplesse, ou d'absorption, différentes. Ainsi l'utilisatrice choisit la capsule applicatrice comportant l'organe d'application lui permettant d'obtenir, notamment en fonction de la zone du corps à traiter, les caractéristiques d'application recherchées. La forme de l'organe d'application peut être quelconque, en fonction des surfaces à traiter. La capsule applicatrice peut, en position montée sur un récipient donné, être disposée dans l'axe du récipient, ou dans un axe différent, en fonction de la gestuelle recherchée.According to one variant of the invention, a container containing a product P1 can be associated with a plurality of applicator capsules containing the same product P2, but comprising an applicator member having characteristics, in particular of hardness, flexibility, or absorption, different. Thus the user chooses the applicator capsule comprising the application member to obtain, particularly depending on the area of the body to be treated, the desired application characteristics. The form of the applicator member may be any, depending on the surfaces to be treated. The applicator capsule may, in position mounted on a given container, be arranged in the axis of the container, or in a different axis, depending on the desired gesture.

Le mode de réalisation de la figure 1E diffère du mode de réalisation précédent en ce que le capuchon 11 est vissé sur le support 2 au moyen d'un filetage 60 du capuchon 11, apte à coopérer avec un filetage correspondant 61 réalisé sur la jupe 8 du support 2. Le capuchon 11 est ainsi monté de façon parfaitement étanche sur le support 2. Le fond 63 du capuchon 11 est réalisé sous forme d'une membrane élastiquement déformable 64, laquelle peut être bi-injectée avec le capuchon 11. La membrane 64 porte une cupule 65 dans laquelle est compacté le produit P2. En position de stockage, la surface d'application 21 est maintenue à distance de la surface libre du produit P2. En vue d'une application, l'utilisatrice exerce une pression axiale sur la membrane élastiquement déformable 64 de manière à mettre la surface 21 en contact élastique avec la surface libre du produit P2, permettant ainsi le chargement de ladite surface d'application avec ledit produit P2. En relâchant la pression exercée sur le fond mobile 63, celui-ci revient par rappel élastique dans sa position initiale. L'utilisatrice dévisse alors le capuchon 11, et appuie la surface d'application 21 sur la peau, de manière à provoquer l'ouverture de la valve 50. En exerçant une pression sur les parois du récipient, lequel peut être du type de celui représenté à la figure 2C, elle provoque la sortie du produit P1 qui est acheminé sur la surface d'application 21 au travers des pores du matériau formant l'organe d'application 20. A l'application, le produit P1 est appliqué en mélange avec le produit P2.The embodiment of Figure 1E differs from the previous embodiment in that the cap 11 is screwed onto the support 2 by means of a thread 60 of the cap 11, adapted to cooperate with a corresponding thread 61 formed on the skirt 8 of the support 2. The cap 11 is thus mounted in a perfectly sealed manner on the support 2. The bottom 63 of the cap 11 is made in the form of an elastically deformable membrane 64, which can be bi-injected with the cap 11. The diaphragm 64 carries a cup 65 in which is compacted the product P2. In the storage position, the application surface 21 is kept at a distance from the free surface of the product P2. For an application, the user exerts an axial pressure on the elastically deformable membrane 64 so as to put the surface 21 in elastic contact with the free surface of the product P2, thus allowing the loading of said application surface with said P2 product. By releasing the pressure exerted on the movable bottom 63, it returns by elastic return in its initial position. The user then unscrews the cap 11, and presses the application surface 21 on the skin, so as to cause the opening of the valve 50. By exerting pressure on the walls of the container, which can be of the type shown in Figure 2C, it causes the exit of the product P1 which is conveyed on the application surface 21 through the pores of the material forming the application member 20. At the application, the product P1 is applied in a mixture with the product P2.

Le mode de réalisation de la figure 1F diffère de celui de la figure 1A, principalement en ce que le produit P2 est séparé du fond 73 du capuchon 11 par un bloc de mousse 70, monté, notamment par collage, dans le fond du capuchon. Un tel bloc de mousse permet d'améliorer l'élasticité du contact entre la surface d'application 21 et la surface libre du produit P2, notamment lorsque l'organe d'application 20 présente peu ou pas d'élasticité (feutre). En outre, en utilisant un bloc de mousse à cellules ouvertes 70, cela permet l'ancrage du produit P2 dans les pores de la mousse, lorsque le produit est coulé sous forme liquide. Le fonctionnement de la capsule 1 selon ce mode de réalisation est identique à celui du mode de réalisation de la figure 1A.The embodiment of FIG. 1F differs from that of FIG. 1A, mainly in that the product P2 is separated from the bottom 73 of the cap 11 by a block of foam 70 mounted, in particular by gluing, in the bottom of the cap. Such a block of foam improves the elasticity of the contact between the application surface 21 and the free surface of the product P2, especially when the applicator member 20 has little or no elasticity (felt). In addition, by using an open cell foam block 70, this allows the product P2 to be anchored in the pores of the foam, when the product is cast in liquid form. The operation of the capsule 1 according to this embodiment is identical to that of the embodiment of FIG. 1A.

Dans la description détaillée qui précède, il a été fait référence à des modes de réalisation préférés de l'invention. Il est évident que des variantes peuvent y être apportées sans s'écarter de l'invention telle que revendiquée ci-après.In the foregoing detailed description, reference has been made to preferred embodiments of the invention. It is obvious that variations can be made without departing from the invention as claimed hereinafter.

Claims (17)

  1. Applicator cap (1) comprising:
    - a support (2) which has means (4, 30, 41) capable of allowing the cap (1) to be fitted removably onto a container (101, 111, 121) containing a first product (P1),
    - an applicator member (20), particularly in the form of an elastically compressible element, mounted on the support (2) and capable of conveying the said product (P1) from an orifice (6) formed in the support (2) as far as an application face (21) of the said applicator member (20),
    - a lid (11) covering removably the said applicator member (20), the lid (11) being fitted on the support (2),
    characterized in that the applicator cap (1) comprises a second product (P2) arranged in the closed end of the cap (11), particularly a product in the form of a solid cake or powder, the said application surface (21) being capable, when the lid (11) is fitted, of being pressed elastically against the said second product (P2).
  2. Applicator cap according to Claim 1, characterized in that the second product (P2) is poured or compacted into the closed end of the lid (11) or into a cup (65) mounted in the said closed end.
  3. Applicator cap according to Claim 1 or 2, characterized in that the second product (P2) is separated from the closed end of the lid (11) by an elastically deformable member (70), particularly a block of foam or a spring.
  4. Applicator cap according to any one of Claims 1 to 3, characterized in that the closed end (64) of the lid (11) can move axially, particularly by elastic deformation.
  5. Applicator cap according to any one of Claims 1 to 4, characterized in that means, particularly in the form of a grating (23) or perforated mesh, are provided to keep the said second product (P2) in the closed end of the said lid (11).
  6. Applicator cap according to any one of Claims 1 to 5, characterized in that the said applicator member (20) consists of a block of a porous material, particularly an open-cell or semi-open-cell foam or a felt, the said material being capable of absorbing the said first product and of conveying it from the said orifice (6) as far as the said application face (21).
  7. Applicator cap according to any one of Claims 1 to 6, characterized in that a passage, in the form of a duct (24), is formed in the said applicator member (20) and extends, particularly axially, from the said orifice (6) of the support (2) as far as the said application face (21).
  8. Applicator cap according to any one of Claims 1 to 7, characterized in that, near the said orifice (6) there are opening/closing means (42, 50) of the shutter or valve type intended for selectively uncovering or closing off the said orifice (6).
  9. Applicator cap according to Claim 8, characterized in that the said opening/closing means (50) are mounted in such a way as to uncover the said orifice (6) in response to sufficient pressure exerted on the said application face (21), elastic return means (51) being provided to force the opening/closing means (50) into the closed position in the absence of sufficient pressure on the said application face (21).
  10. Applicator cap according to Claim 9, characterized in that the said opening/closing means (42) are mounted in such a way as to uncover the said orifice (6) in response to sufficient pressure exerted on the opposite side of the support (2) to the applicator member (20), the said opening/closing means (42) being forced into the closed position when the said pressure ceases.
  11. Applicator cap according to any one of Claims 1 to 10, characterized in that the said means (4, 30, 41) for fitting the cap (1) on the container (101, 111, 121) are particularly of the snap-fastening, screw-fastening or push-fit type, particularly for mounting on a pump or valve stem (31).
  12. Assembly (100) for the combined application, particularly to the skin, of a first product (P1) and of a second product (P2), the said applicator assembly (100) comprising a container (33, 101, 111, 121) containing a first product (P1) and capable of allowing it to be dispensed under pressure, and at least one cap (1) according to any one of the preceding claims, each of the caps (1) containing a second product (P2).
  13. Combined applicator assembly according to the preceding claim, characterized in that the container (33, 101, 111, 121) is particularly in the form of a container surmounted by a pump, particularly of the airless type, or by a valve (32), of a tube or bottle with deformable walls (111, 121) or of a bottle, the bottom of which forms a piston (101).
  14. Combined applicator assembly according to Claim 12 or 13, characterized in that the second product (P2) is a make-up product, each of the caps (1) containing a second product, particularly of different colour and/or appearance.
  15. Combined applicator assembly according to Claim 12 or 13, characterized in that the second product (P2) is a product affording protection against UV radiation, each of the caps (1) containing a second product (P2) with a different protection factor.
  16. Applicator assembly according to Claim 12 or 13, characterized in that each of the caps (1) comprises a different applicator member (20), particularly permitting different application characteristics.
  17. Combined applicator assembly according to any one of Claims 12 to 16, characterized in that the first product (P1) is in the form of a liquid, a cream or a gel.
EP00400488A 1999-04-16 2000-02-23 Applying capsule and applicator assembly with such a capsule Expired - Lifetime EP1044625B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9904816 1999-04-16
FR9904816A FR2792296B1 (en) 1999-04-16 1999-04-16 APPLICATOR CAPSULE AND APPLICATION ASSEMBLY PROVIDED WITH SUCH APPLICATOR CAPSULE

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EP1044625A1 EP1044625A1 (en) 2000-10-18
EP1044625B1 true EP1044625B1 (en) 2006-10-11

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US (2) US6334727B1 (en)
EP (1) EP1044625B1 (en)
JP (1) JP3292722B2 (en)
CN (1) CN100387168C (en)
AR (1) AR018987A1 (en)
AT (1) ATE341965T1 (en)
BR (1) BR0001106A (en)
CA (1) CA2304401C (en)
DE (1) DE60031193T2 (en)
ES (1) ES2272242T3 (en)
FR (1) FR2792296B1 (en)
MX (1) MXPA00003158A (en)

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FR2792296A1 (en) 2000-10-20
US6604879B2 (en) 2003-08-12
MXPA00003158A (en) 2002-03-08
DE60031193T2 (en) 2007-08-23
CN100387168C (en) 2008-05-14
ATE341965T1 (en) 2006-11-15
DE60031193D1 (en) 2006-11-23
CN1270786A (en) 2000-10-25
CA2304401C (en) 2004-05-18
JP3292722B2 (en) 2002-06-17
FR2792296B1 (en) 2001-06-01
US20020076256A1 (en) 2002-06-20
AR018987A1 (en) 2001-12-12
ES2272242T3 (en) 2007-05-01
US6334727B1 (en) 2002-01-01
EP1044625A1 (en) 2000-10-18
JP2000325859A (en) 2000-11-28
CA2304401A1 (en) 2000-10-16
BR0001106A (en) 2001-07-24

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