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EP1006000A1 - Procédé d'impression d'étiquette pour materiaux d'imagerie thermique directe comprenant un sel d'argent organique - Google Patents

Procédé d'impression d'étiquette pour materiaux d'imagerie thermique directe comprenant un sel d'argent organique Download PDF

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Publication number
EP1006000A1
EP1006000A1 EP98204013A EP98204013A EP1006000A1 EP 1006000 A1 EP1006000 A1 EP 1006000A1 EP 98204013 A EP98204013 A EP 98204013A EP 98204013 A EP98204013 A EP 98204013A EP 1006000 A1 EP1006000 A1 EP 1006000A1
Authority
EP
European Patent Office
Prior art keywords
label
imaging material
printing
column
elongated imaging
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98204013A
Other languages
German (de)
English (en)
Inventor
designation of the inventor has not yet been filed The
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Agfa Gevaert NV
Esselte NV
Original Assignee
Agfa Gevaert NV
Esselte NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agfa Gevaert NV, Esselte NV filed Critical Agfa Gevaert NV
Priority to EP98204013A priority Critical patent/EP1006000A1/fr
Priority to JP2000585071A priority patent/JP2002531291A/ja
Priority to DE69905757T priority patent/DE69905757T2/de
Priority to PCT/EP1999/009163 priority patent/WO2000032403A1/fr
Priority to EP99964507A priority patent/EP1135258B1/fr
Priority to US09/452,061 priority patent/US6244766B1/en
Publication of EP1006000A1 publication Critical patent/EP1006000A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
    • G03C1/498—Photothermographic systems, e.g. dry silver
    • G03C1/4989—Photothermographic systems, e.g. dry silver characterised by a thermal imaging step, with or without exposure to light, e.g. with a thermal head, using a laser
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J15/00—Devices or arrangements of selective printing mechanisms, e.g. ink-jet printers or thermal printers, specially adapted for supporting or handling copy material in continuous form, e.g. webs
    • B41J15/04—Supporting, feeding, or guiding devices; Mountings for web rolls or spindles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/315—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material
    • B41J2/32—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material using thermal heads
    • B41J2/35—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material using thermal heads providing current or voltage to the thermal head
    • B41J2/355—Control circuits for heating-element selection
    • B41J2/36—Print density control
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J3/00—Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed
    • B41J3/407—Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed for marking on special material
    • B41J3/4075—Tape printers; Label printers
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
    • G03C1/498—Photothermographic systems, e.g. dry silver
    • G03C1/49881—Photothermographic systems, e.g. dry silver characterised by the process or the apparatus

Definitions

  • the present invention concerns a label-printing process for the printing of direct thermal imaging material based on organic silver salts.
  • Thermal imaging or thermography is a recording process wherein images are generated by the use of thermal energy.
  • direct thermal printing a visible image pattern is produced by image-wise heating of a recording material containing matter that by chemical or physical process changes colour or optical density.
  • Most of the direct thermal recording materials are of the chemical type. On heating to a certain conversion temperature, an irreversible chemical reaction takes place and a coloured image is produced.
  • Label-printing by means of thermography is known with tapes on the basis of monosheet materials such as leuco-dye systems, as disclosed in US-P 4,370,370, EP-A 479 578 and EP-A 754 564, diazo systems, as disclosed in JP 60-01077A, or two-sheet thermal dye transfer systems, such as disclosed in EP-A 656 264 and US-P 4,943,555.
  • monosheet materials such as leuco-dye systems, as disclosed in US-P 4,370,370, EP-A 479 578 and EP-A 754 564, diazo systems, as disclosed in JP 60-01077A, or two-sheet thermal dye transfer systems, such as disclosed in EP-A 656 264 and US-P 4,943,555.
  • thermal printing image signals are converted into electric pulses and then through a driver circuit selectively transferred to a thermal printhead.
  • the thermal printhead consists of microscopic heat resistor elements, which convert the electrical energy into heat via the Joule effect.
  • the electric pulses thus converted into thermal signals manifest themselves as heat transferred to the surface of the thermographic material wherein the chemical reaction resulting in colour development takes place.
  • Such thermal printheads may be used in contact or close proximity with the recording layer.
  • EP-A-322 918, EP-A-322 919 and EP-A-0267 890 are disclosed in EP-A-322 918, EP-A-322 919 and EP-A-0267 890. These printers each include a printing device having a cassette bay for receiving a cassette or tape holding case.
  • the tape holding case houses an ink ribbon and a substrate tape, the latter comprising an upper imaging layer secured to a backing layer by adhesive.
  • the tape holding case houses an ink ribbon, a transparent imaging tape and a double-sided adhesive tape which is secured at one of its adhesive coated sides to the image tape after printing and which has a backing layer peelable from its other adhesive coated side. With both these apparatus, the image transfer medium (ink ribbon) and an imaging tape (substrate) are in the same cassette.
  • Labels produced with monosheet thermographic materials based on leuco-dyas have a well-known propensity to fade when exposed to light and thermal dye transfer systems are expensive to assemble and produce waste due to the disposal of the donor lint resulting in ecological objections.
  • a label-printing process for obtaining a desired optical density and a desired colour tone with an elongated imaging material comprising the steps of:
  • An apparatus for the printing of labels according to the above-described label-printing process is also provided by the present invention.
  • a label is a sheet material which is attachable to an object and contains information, the sheet material having two edges parallel to one another and ⁇ 12 cm apart (see examples in Figs. 1-4).
  • Perceptible printed characters are composed of printed dots each dot representing a print pixel.
  • a so-called label-line LL comprises at least one line of perceptible characters (e.g. text, symbols ...) on a label. Examples of a label-line LL are: “A”, “ABC123”, “1998.08.12”, “Preliminary proposal! (some other examples are illustrated in Figs. 3-4)
  • a label-line LL may be parallel or non-parallel to the direction of transportation (indicated by arrow Y in Figs. 2, 3, 6, 9) of the elongated imaging material.
  • the label-line LL On a landscape label, for example, the label-line LL is substantially parallel to and on a portrait label the label-line LL is substantially perpendicular to the direction of transportation.
  • Each label-line may be composed of a plurality of printing-lines PL. Examples of a printing-line PL are "-----------" and "-- ---- -".
  • a printing-line PL is printed by a column C of heating elements Hi.
  • the printing-line PL is substantially parallel to the column C; but the printing-line PL may be parallel or non-parallel to a label-line LL.
  • Each printing-line is generated by a printing cycle of activation pulses in which all heating elements of a column can be activated at least once.
  • the time taken to print a printing-line PL is a line-time LT.
  • Each activation pulse may either have an "off-state” (corresponding to a logical zero “0”) or an "on-state” (corresponding to a logical one "1").
  • a line-duty-cycle ⁇ is the ratio of activation time to total line time for the heating elements which can be activated in producing a printing-line.
  • a printing-line may comprise several printing-sublines.
  • Each printing-subline SL takes a time-slice or a time-step or a column-time (being the time wherein all heating elements of at least one section of a column can be activated once).
  • a column-duty-cycle ⁇ is the ratio of the sum of all activation-times during a column-time of all heating elements of a printing-subline divided by the column-time.
  • Substantially light-insensitive means not intentionally light sensitive.
  • Aqueous includes mixtures of water with water-miscible organic solvents such as alcohols e.g. methanol, ethanol, 2-propanol, butanol, iso-amyl alcohol etc.; glycols e.g. ethylene glycol; glycerine; N-methyl pyrrolidone; methoxypropanol; and ketones e.g. 2-propanone and 2-butanone etc.
  • alcohols e.g. methanol, ethanol, 2-propanol, butanol, iso-amyl alcohol etc.
  • glycols e.g. ethylene glycol
  • glycerine glycerine
  • N-methyl pyrrolidone methoxypropanol
  • ketones e.g. 2-propanone and 2-butanone etc.
  • the dot energy can be obtained at any heating power and concomitantly varying heating pulse-length.
  • this dot energy can be supplied to one or more heating elements activated to produce the dot with a particular image density i.e. the heating power (i.e. drive voltage) applied to the one or more heating elements, in one or more heat pulses and the duration of the one or more pulses.
  • the heating power be as low as possible and the column-duty-cycle ⁇ is as high as possible.
  • INVENTION EXAMPLES 1 to 11 show that the image density increases with increasing dot energy up to a maximum image density.
  • the dot energy corresponding to this maximum image density has been found to be dependent upon the choice of reducing agent for a particular organic silver salt, the choice of toning agent and the ratio of binder to organic silver salt in the thermosensitive element. At still higher energies the image density decreases with further increase in dot energy.
  • the image density potential of the material has been found mainly to depend upon the coverage of substantially light-insensitive organic silver salt.
  • the range of heat energy for the formation of an image dot is 50 to 200 mJ/mm 2 , with 50 to 150 mJ/mm 2 of heating element surface area being preferred and 50 to 120 mJ/m 2 of heating element surface area being particularly preferred.
  • the label-printing process preferably comprises the further step of selecting the supply-voltage which determines the heating power, the column-time and/or the column-duty-cycle ⁇ for obtaining the optical density and the colour tone with the selected elongated imaging material.
  • the operating temperature of common thermal printheads is in the range of 300 to 400°C and the heating time per picture element (pixel) may be less than 1.0ms, the pressure contact of the thermal printhead with the recording material being e.g. 200-1000g/cm 2 to ensure a good transfer of heat.
  • Activation of the heating elements can be power-modulated or pulse-length modulated at constant power.
  • Image-wise heating of the thermographic material can also be carried out using an electrically resistive ribbon incorporated into the material. Image- or pattern-wise heating of the thermographic material may also proceed by means of pixel-wise modulated ultra-sound.
  • the energisable heating elements are grouped in at least two sections S.
  • the printhead consists of more than one column of energisable heating elements.
  • the energising of the heating elements printing-line by printing-line is carried out section by section.
  • the heating power is as low as possible and the column-duty-cycle ⁇ is as high as possible in achieving a particular heat energy for the formation of the image dot.
  • Possible embodiments of the invention having the same effect of lowering the power and increasing the duty cycle comprise e.g.: reducing the voltage and increasing the duty cycle while keeping the column-time constant; reducing the voltage and increasing the column-time while keeping the duty cycle constant; and reducing the voltage, increasing the duty cycle and increasing the column-time.
  • a configuration memory contains characteristics of at least one elongated imaging material relating to a range of available column-times, to a range of available transportation speeds, to a range of available voltages.
  • the configuration memory contains characteristics of at least one elongated imaging material including the characteristics of an elongated imaging material requiring a maximal available voltage, to a minimal available column-duty cycle ⁇ , and to a predefined transportation speed.
  • the column is at an angle to the transport direction of between 0 and 100°, with an angle between 90 and 99° being particularly preferred.
  • the thermal head is powered by a DC energy source, with the DC energy source being one or more batteries being particularly preferred.
  • selection of the supply-voltage, the column-time and/or the column-duty-cycle ⁇ for obtaining the optical density and the colour tone with the selected elongated imaging material includes the steps of:
  • Figure 1.1 shows a label 1.
  • a length of an elongated imaging material e.g. 20 mm
  • a tab cut defines the finished label.
  • a tab cut is performed at a series of locations. This provides the possibility of printing a continuous elongated imaging material with a series of labels 1 separated by individual tab cuts (e.g. with the printed position 2 centralised as shown in Figure 1.2).
  • the printhead PH (5) for such a label-printing apparatus comprises a plurality of heating elements 30 which are selectively activated, i.e. heated.
  • the printhead 5 comprises a column 35 of heating elements 30 which has a height which generally corresponds to the maximum width of the image capable of being printed. All of the heating elements are arranged so as to be capable of being activated simultaneously, if necessary.
  • the printhead 5 is provided with an array of a plurality of heating elements, the array generally being directed perpendicular to the feeding direction Y (6) of the elongated imaging material 3, the elongated imaging material being imagewise heated by the printhead PH.
  • the column is at an angle to the transport direction of between 0 and 100°, with an angle between 90 and 99° being particularly preferred. This is illustrated, non restrictively, in Fig. 2 by a column direction (ref. 9) which is indicated as V or V'.
  • the selective activation of the heating elements of the printhead may produce normal image 12 as shown in Fig. 3.1 (as well as in Figs. 1.2 and 4.1 to 4.10), or reversed image 13 such as shown in Fig. 3.2.
  • the reversed image is obtained by turning the normal image 180 degrees with respect to a line 11 parallel to the elongated imaging material feeding direction indicated by an arrow Y in Fig. 3.2.
  • a label-line LL having a direction indicated by arrow U (8 in Fig. 2), may be parallel or non-parallel to the direction of transportation Y (6) of the elongated imaging material.
  • label-line-direction U is substantially parallel to the transport-direction Y
  • label-line-direction U is substantially perpendicular to the transport-direction Y.
  • Fig 3.1 is a schematic view of a printed label in which normal character images 12 have been printed
  • Fig 3.2 is a schematic view of a printed label in which reversed character images 13 have been printed.
  • Fig. 4.1 to 4.10 show several examples of labels with up to 4 label-lines (21 - 24). From Fig. 4, it is clear that e.g. one (small or medium or large) text, or two (small or medium) texts or even four (small) texts may be printed at the same time on an elongated imaging material 3.
  • a printhead 5 comprising e.g. 30 heating elements each (about) 0.142 mm long along the printhead and 0.016 mm apart, would result in a total "printing height" of (about) 4.7 mm.
  • the discrepancy between the label-height of e.g. 12 mm versus the printing height of 4.7 mm leaves a non-printed area or free margin of about 4 mm unprinted on either side. Free margins are also left in the case of label heights of e.g. 6 mm, 9 mm, 19 mm, or 32 mm, or even 120 mm.
  • the electronic control of the heating elements varies as a function of the required size and style of the printed labels. Possible variations are the heights of the characters (normal or medium, small, large), the widths of the characters (normal, wide, extra wide), the fonts of the characters (normal, bold, outline, italic, boxed, underlined, shadowed, inverted), text alignment (to the left, the middle, the right), portrait or landscape labels.
  • one set of characters is used with e.g. a single dot for a narrow font; two dots side by side in the transport direction Y for a normal font; and four dots in a row in the transport direction for a wide font.
  • two printing heights may be used: the full height for capitals and numbers, and a standard height.
  • an algorithm is used to generate boxing, underlining etc. Any other print sizes require a different printhead configuration.
  • Figure 5.0 is a schematic of a cassette bay 40 in a label-printing apparatus 150.
  • the cassette bay 40 accommodates a thermal printhead 5 and a platen roll 44 which together define a print location P in a manner which is known in the art.
  • the printhead 5 is pivotable about a pivot point 48 so that it can be brought into contact with the platen roll 44 and moved away from the platen roll to enable a cassette to be removed and replaced.
  • a cassette inserted into the cassette bay is denoted by reference numeral 50.
  • the cassette contains a spool 52 of elongated imaging material to be printed which comprises a thermosensitive element.
  • the elongated imaging material 3 to be printed is guided by a guide mechanism, which is not shown, through the cassette, exiting the cassette shortly after having passed the print location through an outlet O to be routed to a cutting location C.
  • the elongated imaging material to be printed passes through the print location P with its imaging layer 31 in contact with the printhead.
  • the platen roll 44 is driven so that as it rotates it guides the elongated imaging material 3 to be printed through the print location P during printing. As this occurs, the material is printed and fed out from the print location P to the cutting location C.
  • the cutting location C is provided adjacent to the wall of the cassette close to the print location P. Since the imaging material is pulled out of the cassette by driving the platen roll, there is no need for a further elongated imaging material advance mechanism.
  • the cutting location C is arranged close to the print location P.
  • the portion of the wall of the cassette where the cutting location C is defined is denoted by reference numeral 62.
  • a slot 64 is defined in this wall portion 62. The elongated imaging material to be printed is transported from the print location P to the cutting location C, where it is supported by facing wall portions on either side of the slot 64.
  • the label-printing apparatus 150 includes a cutting mechanism denoted by reference numeral 60.
  • This cutting mechanism 60 includes a cutter transport member which carries a blade 66. The blade severs the elongated imaging material 3 and then enters the slot 69.
  • Figure 5.0 shows the cutting mechanism in its ready-to-cut state, that is with the blade above the elongated imaging material . This permits the free leading edge of the elongated imaging material to be driven through the cutting location C without the risk of catching on it or being deflected by it.
  • a preferred embodiment of the present invention comprises selecting the supply-voltage, the column-time and/or the column-duty-cycle ⁇ for obtaining a desired optical density with a selected imaging material. Such selection could be achieved by switching port lines on the microprocessor to change the control reference voltage of feed back path to the power supply. Alternatively some sort of variable voltage regulator could be used. A mating feature in a cassette could operate a micro-switch which would change the voltage such as shown in Figures 5.1 and 5.2.
  • FIG 5.1 a partial diagrammatic section along line I-II in Figure 5.0 is shown.
  • reference numeral 80 denotes the floor of the cassette receiving bay 40.
  • Reference numeral 50 denotes a cassette of the type shown in Figure 5.0 which contains an elongated imaging material containing a substantially light-insensitive organic silver salt, 3.
  • Reference numeral 82 denotes a switch and reference numeral 84 an actuating part of the switch 82.
  • the switch 82 may be a standard low cost two position slide switch, conveniently mounted below the cassette bay floor 80, so that the actuating part 84 protrudes above the cassette bay floor 80 through a slot 86.
  • the actuating part 84 of the switch 82 is shown in a first position in Figure 5.1.
  • This position is the position for the elongated imaging material containing a substantially light-insensitive organic silver salt, 3.
  • the cassette 50 holding the elongated imaging material containing a substantially light-insensitive organic silver salt, 3, has a recess 88 in its underside which is located to accommodate the actuating part of the switch 82 when it is in the elongated imaging material containing a substantially light-insensitive organic silver salt printing mode position.
  • the switch 82 is connected to the microprocessor chip 170 via input 90. This input 90 indicates to the microprocessor chip 170 the position of the actuating part 84 of the switch 82.
  • the microprocessor chip 170 uses this information to determine whether the label-printing apparatus is in the elongated imaging material containing a substantially light-insensitive organic silver salt position or the mode for another type of elongated imaging material, for example one based on leuco dyes.
  • the actuating part 84 of the switch 82 is movable into a second position which is indicative of a mode for the printing of this other type of thermographic material. This is shown in Figure 5.2. In the position for this other type of thermographic material, it is identified that a cassette containing this other type of thermographic material is present. Thus a cassette housing this other type of thermographic material would have a recess located in a position to accommodate the actuating part 84 in its position for this other type of thermographic material. However, this is not illustrated.
  • Figure 5.2 does illustrate how the actuating member 84 of the switch 82 prevents an incorrect cassette form being inserted, with reference numeral 50 denoting a cassette as shown in Figure 5.1 having an elongated imaging material containing a substantially light-insensitive organic silver salt 3 and a recess 88 in a location intended to accommodate the actuating part 84 in its first position.
  • the label-printing apparatus 150 it is possible to identify whether or not the label-printing apparatus 150 should operate in the mode for printing an elongated imaging material containing a substantially light-insensitive organic silver salt or the mode for printing another thermographic material and it can also prevent a user from inserting the incorrect type of material.
  • Figures 5.3 and 5.4 illustrate an alternative way in which a specific thermal printing mode can be selected. Showing a diagrammatic section along line I-II in Figure 5.0.
  • reference numeral 50 denotes a cassette which contains an elongated imaging material containing a substantially light-sensitive organic silver salt
  • reference numeral 81 denotes the floor of the cassette receiving bay 50.
  • the cassette 50 has a recess 100 which is arranged to accommodate an actuating member 102 of a switch 82.
  • the actuating member 102 is resiliently supported by a spring 104 which biases actuating member 102 away from a base member 106. By consequence, no electrical contact is made between actuating member 102 and base member 106.
  • reference numeral 51 denotes a cassette containing another type of elongated imaging material (e.g. based on leuco dyes).
  • This cassette 51 does not have a recess and accordingly, the actuating member 102 is pushed downwardly towards base member 106. A contact 108 on actuating member 102 is thus in contact with a contact 110 on base member 106.
  • This provides a signal to the microprocessor indicating the presence and the type of the cassette (referred to as 50 or 51). And by consequence, the microprocessor can modify the operation of the printhead (see also Fig. 12).
  • FIG 6 a schematic shows how the thermal printing apparatus 150 operates in accordance with the present invention.
  • This apparatus is capable of printing one line of pixels at a time on an elongated imaging material including a support and a thermosensitive element comprising an organic silver salt, which is generally in the form of a sheet.
  • the elongated imaging material is mounted on a rotatable platen roll 44, driven by a drive mechanism (not shown) which continuously advances the platen roll and the elongated imaging material 3 past a stationary thermal printhead 5.
  • This printhead presses against the platen roll and receives the output of the driver circuits.
  • the thermal printhead normally includes a plurality of heating elements equal in number to the number of pixels in the image data present in a line memory (not shown).
  • the imagewise heating of the heating element is performed on a line by line basis, with the heating resistors geometrically juxtaposed each along another and with gradual construction of the output density.
  • Each of these resistors is capable of being energised by heating pulses, the energy of which is controlled in accordance with the required density of the corresponding picture element.
  • the output energy increases as the value of the required density increases, resulting in an increase of the optical density of the hardcopy image on the imaging element .
  • a lower value of input image data causes the heating energy to be decreased, giving an image with a lower optical density.
  • Figure 7 is a detailed cross section of a printhead 5, indicated as part PH in Figure 2 and containing a heat sink mounting 71, a temperature sensor 72, a bonding layer 73, a ceramic substrate 74, a glazen bead 75, a heating element 76 and a wear resistant layer 77.
  • the printhead may be produced using thick film or thin film technology.
  • the printhead PH is a thermal printhead 5 comprising a column 35 of a plurality of heating elements 30, H i .
  • the printhead is preferably only one heating element wide (W) and the column extends in a direction perpendicular to the lengthwise direction of the elongated imaging material .
  • the height H of the column of heating elements is preferably equal to the maximum width of the elongated imaging material to be printed with the label-printing apparatus . Where more than one width of elongated imaging material is used, the printhead column will generally have a height equal to the largest width of elongated imaging material to be printed.
  • the heating elements of the printhead are preferentially divided into three sections Sa, Sb and Sc as can be seen from Figure 8. Each section of heating elements may be activated in succession; in this example, the maximum number of heating elements of the printhead activated at any one time is equal to one third of the total number of heating elements.
  • heating element-width is e.g. 115 ⁇ m
  • element-height is e.g. 142 ⁇ m with a free distance of 16 ⁇ m, resulting in a height-pitch of 158 ⁇ m.
  • the (vertical or height or) longitudinal resolution is 160 dpi, this being consistent with an element-pitch of 158 ⁇ m.
  • the resolution is 320dpi in the transport direction and 160dpi in the lateral direction.
  • each heating element is activated a fourth number of times (e.g. 2) within a printing cycle(or line time).
  • FIG. 10.1 shows a strobe pulse timing for the printhead operating in a direct thermal printing mode.
  • Each section Sa, Sb, Sc of the printhead is strobed (or activated) e.g. twice in succession for each set of print information.
  • two out of the three sections Sa, Sb, Sc of the printhead are strobed or activated at any one time.
  • Line VSa represents activation of the first section Sa of the printhead
  • line VSb represents the activation of the second section Sb of the printhead
  • line Vsc represents the activation of the third section Sc of the printhead.
  • those heating elements which are to be activated are activated twice in succession for the same set of print information.
  • Each pulse or activation period lasts for a time period T (e.g. 1.53 ms) with a period of time T' (e.g. 2.30 ms) between the first and second activations of the selected heating elements of the first section Sa of the printhead.
  • T time period
  • T' period of time
  • the heating elements of the second section Sb of the printhead are also to be activated; they are also activated twice, in succession for each set of print information.
  • the second strobe pulse for the first section Sa coincides with the first strobe pulse for the second section Sb of the printhead.
  • the two activation periods or strobe pulses for the second section Sb of the printhead are each equal in length to the activation periods of the strobe pulses for the first section Sa.
  • the two activation periods or strobe pulses for the second section Sb of the printhead are each equal in length to the activation periods of the strobe pulses for the first section Sa.
  • the first activation period or strobe pulse for the third section Sc coincides with the second activation period or strobe pulse for the second section Sb of the printhead.
  • the activation periods (strobe pulses) for the third section of the printhead are the sane length as those of the first and second sections Sa and Sb.
  • the second strobe pulse of the third section Sc coincides with the first strobe pulse of the first section Sa.
  • Fig. 10.2 activation pulses are shown according to the present invention.
  • the supply voltage and column-time and/or column-duty-cycle ⁇ are such as to produce a heat energy for the formation of an image dot in the range of 50 to 200mJ/mm 2 of heating element surface area.
  • a label-printing process is provided for printing labels from a monosheet elongated imaging material which have excellent light stability and image tone.
  • Fig 11 shows a label-printing apparatus 150.
  • the label-printing apparatus comprises a keyboard 154 which has a plurality of data entry keys and in particular comprises a plurality of numbered, lettered and punctuation keys 156 for inputting data to be printed as a label and function keys 158 for editing the input data. These function keys may, for example, change the size or font of the input data.
  • the keyboard also comprises a print key 160 which is operated when it is desired that a label be printed together with elongated imaging material feeding keys 162.
  • the keyboard has an on/off key 164 for switching the label-printing apparatus on and off.
  • a cursor can be moved over a display 168 by means of cursor keys.
  • the label-printing apparatus 150 also has a liquid crystal display 168 (e.g. a LCD) which displays the data as it is entered.
  • a liquid crystal display 168 e.g. a LCD
  • the display allows the user to view all or part of the label to be printed which facilitates the editing of the label prior to its printing. Additionally, the display can also display messages to the user, for example error messages or an indication that the print key should be pressed.
  • the display is driven by a display driver which can be seen in Figure 12.
  • Figure 12 shows the basic control circuitry for controlling the label-printing apparatus 150 comprising a microprocessor chip 170 having a read only memory (ROM) 172, a microprocessor 174, and random access memory capacity indicated diagrammatically by RAM 176.
  • the ROM stores data defining the characters and/or symbols which can be selected via the keyboard 154.
  • the ROM may also store various algorithms. For example, an algorithm for reconstructing the font data may be stored where data compression techniques have been used and/or sizing or print style algorithms may be stored so that print information for the desired size and/or style of characters etc. can be generated.
  • the microprocessor is controlled by software stored in the ROM and when so controlled acts as a controller.
  • the microprocessor chip 174 is connected to receive label data input from the keyboard 154.
  • the microprocessor chip outputs data to drive the display 168 via the display driver 174 to display the image to be printed on the label (or a part thereof) and/or a message or instructions for the user.
  • the microprocessor chip also outputs data to drive the printhead 5 which prints an image onto the elongated imaging material thereby forming a label 1.
  • the microprocessor chip also receives an input which indicates whether the label-printing apparatus is to operate in a first mode (e.g.
  • a printing mode for printing with an elongated imaging material containing a substantially light-insensitive organic silver salt or in a second mode (e.g. a printing mode for printing a leuco-dye based elongated imaging material).
  • This input may be connected to a switch 82 having one position when the first printing mode is to be selected and a different position when the second printing mode is to be selected.
  • the microprocessor chip is arranged to generate print information to control the operation of the printhead.
  • This print information is generated from the data input by the user via the keyboard in accordance with the data stored in the ROM and any stored algorithms.
  • the related character code is stored in the edit buffer in RAM at the cursor location.
  • each character code in the edit buffer in RAM is read in turn and used to extract the related print data stored in ROM for each character.
  • the print data are then manipulated to define the print information. This manipulation may involve the application of one or more stored algorithms.
  • This print information comprises a plurality of set of print information. Each set of print information corresponds to a column of data. These columns of data are applied in succession to the printhead.
  • Each column of data is supplied twice to the printhead.
  • Each column of data defines the status of each heating element in the printhead, i.e. whether each heating element is on or off.
  • the printhead is divided into two sections or more, e.g. three sections (indicated as Sa, Sb, Sc). In that case, each set of print information would relate to one section of the printhead only.
  • the microprocessor chip also controls the motor 41 for driving the elongated imaging material through the label-printing apparatus.
  • the microprocessor chip may also control the cutting mechanism 60 to allow lengths of elongated imaging material to be cut after an image has been printed to define the labels.
  • the cutting mechanism may be manually operable.
  • Data relating to each character or symbol etc., printable on the elongated imaging material 3 is stored in the ROM 172.
  • the data stored in the ROM could be in the form of a 'n' dot font data which represents each character by a 'n x m' bit map (in case of none square characters), a 'n x n' bit map (in case of square characters), or as an outline font (Bezier characters).
  • the font data are stored in a simple, compressed form in order to reduce the required storage capacity.
  • the characters are stored in a form representing sticks (rectangles) and portions of curves.
  • Mirror functions can also be used.
  • information on the size and position of the rectangles, respectively of the widths i.e.
  • the label-printing apparatus 150 allows labels 1 to be composed and displayed on the display using the various keys.
  • the ROM 172 stores information relating to alphanumeric characters and the like which are associated with respective keys 156, as well as functions associated with the function keys 158.
  • data concerning the associated character or the like is retrieved from the ROM 142 and then stored in the RAM 176.
  • the data stored in the RAM may be in the form of a code which identifies the character.
  • the microprocessor 174 in accordance with the data stored in the RAM, generates pixel data which is transmitted in one form column by column to activate the printhead and in another form to be displayed on the display.
  • Data concerning a function may be retrieved from the ROM in response to activation of one or more of the function keys 158. These data may take the form of a flag.
  • the pixel data are generated by the microprocessor 174 and sent to the printhead 5 and the display 168 will take into account the data relating to one or more functions stored in the RAM 176.
  • the keys 156, 158 of the keyboard have predetermined functions associated therewith which causes predetermined data associated with that function to be retrieved from ROM 172.
  • Fig. 13 is a data flowchart of a label-printing apparatus 150 according to the present invention.
  • Fig. 14 is a logic data timing diagram of a label-printing apparatus 150 according tot the present invention.
  • LATCH 188 and STROBE 194 are active HIGH and negated LOW.
  • Data is transferred serially from the microprocessor 174 by means of synchronous clocking using DATA (ref. 182) and CLOCK (184).
  • DATA ref. 182
  • CLOCK synchronous clocking
  • LATCH (188) is used to capture the new data (ref. 182) in the incoming register 186 and to store them temporarily in DATA LATCH AND HOLD MEANS 190. From now on, these data are available to the appropriate logical gates indicated as STROBE GATING 192. Then the STROBE signal 194 is asserted for the required duration.
  • the output drivers 196 here e.g. FET-transistors
  • STROBE 194 is asserted for the required duration.
  • the output drivers 196 here e.g. FET-transistors
  • STROBE 194 are turned on when STROBE 194, or more precisely STROBE GATING 192, is asserted causing current to flow through the resistive heating element 39 (e.g. R1 to R30) of the printhead from the VPH voltage rail 198. If the data 182 is LOW, the associated strobe gating 192 and hence the associated driver 196 does not turn on.
  • the time-length of the data train 182 (e.g. in a range smaller than 1 ms) of generally is much smaller than the time-length of the strobe 194 (e.g. in a range greater than 1 ms), and hence smaller than the heating of the heating elements 39 or than the output of dots 200.
  • a LATCH-signal 188 is given after the receipt of all new data 182 (see time span ta) and after the ending of a STROBE-signal 194 (see time-span tb).
  • the next STROBE-signal 194 starts some time after the ending of a foregoing LATCH-signal 188 (see time-span tc).
  • the output drivers 196 may be part of the print head, or (as illustrated in Fig. 12) may be part of a separated integrated circuit IC on the printed circuit board PCB.
  • the monosheet direct thermal imaging materials used in the present invention include a support, a thermosensitive element and an attaching layer and are characterised in that the thermosensitive element contains a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith and a binder.
  • the attaching layer is the outermost layer on the same side of the support as the thermosensitive element or the outermost layer on the side of the support not provided with the thermosensitive layer and in contact with the surface of the second object to which it is to be attached under the conditions of attachment provides adhesion.
  • adhesion is a co-operative effect between the attaching layer and the surface of the second object and is influenced by the conditions of attachment. Therefore the choice of attaching layer is dependent upon the surface of the object to which it is to be attached and the conditions under which attachment takes place.
  • the support of the imaging layer may be further provided with a dyed or pigmented transparent layer to provide a coloured background for the image on the label.
  • the instant invention concerns the use of a direct thermal material including a support and a thermosensitive element containing a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith and a binder for the production of labels.
  • the thermosensitive element may comprise a layer system in which the ingredients may be dispersed in different layers, with the proviso that the substantially light-insensitive organic silver salt and the reducing agent are in thermal working relationship with one another i.e. during the thermal development process the reducing agent must be present in such a way that it is able to diffuse to the substantially light-insensitive organic silver salt particles so that reduction of the substantially light-insensitive organic silver salt can take place.
  • the thermosensitive element may be coated onto a support in sheet- or web-form from an organic solvent or from an aqueous medium.
  • Preferred substantially light-insensitive organic silver salts for use in the thermosensitive element of the elongated imaging material used in the present invention are silver salts of aliphatic carboxylic acids known as fatty acids, wherein the aliphatic carbon chain has preferably at least 12 C-atoms, which silver salts are also called "silver soaps". Combinations of different organic silver salts may also be used in the imaging materials of the present invention.
  • Suitable organic reducing agents for the reduction of the substantially light-insensitive organic silver salts are organic compounds containing at least one active hydrogen atom linked to O, N or C, such as is the case with: catechol; hydroquinone; aminophenols; METOLTM; p-phenylenediamines; alkoxynaphthols, e.g. 4-methoxy-1-naphthol described in US-P 3,094,417; pyrolidin-3-one type reducing agents, e.g.
  • PHENIDONETM pyrazolin-5-ones; indan-1,3-dione derivatives; hydroxytetrone acids; hydroxytetronimides; hydroxylamine derivatives such as for example described in US-P 4,082,901; hydrazine derivatives; and reductones e.g. ascorbic acid; see also US-P 3,074,809, 3,080,254, 3,094,417 and 3,887,378.
  • thermographic element contains a 3,4-dihydroxyphenyl compound with ethyl 3,4-dihydroxybenzoate, butyl 3,4-dihydroxybenzoate and 3,4-dihydroxybenzoic acid being particularly preferred.
  • thermosensitive element of the elongated imaging material used in the present invention may be coated onto a support in sheet-or web-form from an organic solvent containing the binder dissolved therein or may be applied from an aqueous medium using water-soluble or water-dispersible binders.
  • Suitable binders for coating from an organic solvent are all kinds of natural, modified natural or synthetic resins or mixtures of such resins, wherein the organic heavy metal salt can be dispersed homogeneously or mixtures thereof.
  • Suitable water-soluble film-forming binders are: polyvinyl alcohol, polyacrylamide, polymethacrylamide, polyacrylic acid, polymethacrylic acid, polyethyleneglycol, polyvinylpyrrolidone, proteinaceous binders such as gelatin modified gelatins such as phthaloyl gelatin, polysaccharides, such as starch, gum arabic and dextrin and water-soluble cellulose derivatives.
  • Suitable water-dispersible binders are any water-insoluble polymer.
  • the binder to organic silver salt weight ratio is preferably in the range of 0.2 to 6, and the thickness of the recording layer is preferably in the range of 1 to 50 ⁇ m.
  • the weight ratio influences the gradation of the image, it increasing with decreasing weight ratio.
  • binders or mixtures thereof may be used in conjunction with waxes or "heat solvents” also called “thermal solvents” or “thermosolvents” improving the reaction speed of the redox-reaction at elevated temperature.
  • heat solvent in this invention is meant a non-hydrolyzable organic material which is in a solid state in the recording layer at temperatures below 50°C, but becomes a plasticizer for the recording layer where thermally heated and/or a liquid solvent for at least one of the redox-reactants.
  • the elongated imaging material used in the present invention may contain one or more toning agents.
  • the toning agents should be in thermal working relationship with the substantially light-insensitive organic silver salt and reducing agents during thermal processing. Any known toning agent from thermography or photothermography may be used.
  • stabilizers and antifoggants may be incorporated into the elongated imaging material used in the present invention.
  • Suitable stabilizers compounds are unsaturated carbocyclic or heterocyclic compounds substituted with a -SA group where A is hydrogen, a counterion to compensate the negative charge of the thiolate group or a group forming a symmetrical or an asymmetrical disulfide.
  • A is hydrogen, a counterion to compensate the negative charge of the thiolate group or a group forming a symmetrical or an asymmetrical disulfide.
  • for use in the present invention may be further substituted, which substitution also includes the atoms necessary to form an annulated unsaturated carbocyclic or heterocyclic ring system.
  • Preferred stablizer compounds used in the present invention have an unsaturated 5- or 6-membered ring.
  • Particularly suitable compounds are represented by general formula I : where Q are the necessary atoms to form a 5- or 6-membered aromatic heterocyclic ring, A is selected from hydrogen, a counterion to compensate the negative charge of the thiolate group or a group forming a symmetrical or an asymmetrical disulfide.
  • the elongated imaging material used in the present invention may contain one or more surfactants, which may be anionic, non-ionic or cationic surfactants and/or one or more dispersants.
  • Suitable dispersants are natural polymeric substances, synthetic polymeric substances and finely divided powders, for example finely divided non-metallic inorganic powders such as silica.
  • the support of the elongated imaging material used in the present invention may be transparent or translucent and is preferably a thin flexible carrier made transparent resin film, e.g. made of a cellulose ester, e.g. cellulose triacetate, polypropylene, polycarbonate or polyester, e.g. polyethylene terephthalate.
  • the support may be in sheet, ribbon or web form and subbed if needs be to improve the adherence to the thereon coated thermosensitive element.
  • the support may be dyed or pigmented to provide a transparent coloured background for the image.
  • thermosensitive element In a preferred embodiment of the present invention a protective layer is provided for the thermosensitive element. In general this protects the thermosensitive element from atmospheric humidity and from surface damage by scratching etc. and prevents direct contact of printheads or heat sources with the recording layers.
  • Protective layers for thermosensitive elements which come into contact with and have to be transported past a heat source under pressure, have to exhibit resistance to local deformation and good slipping characteristics during transport past the heat source during heating.
  • a slipping layer being the outermost layer, may comprise a dissolved lubricating material and/or particulate material, e.g. talc particles, optionally protruding from the outermost layer. Examples of suitable lubricating materials are a surface active agent, a liquid lubricant, a solid lubricant or mixtures thereof, with or without a polymeric binder.
  • any layer of the elongated imaging material used in the present invention may proceed by any coating technique e.g. such as described in Modern Coating and Drying Technology, edited by Edward D. Cohen and Edgar B. Gutoff, (1992) VCH Publishers Inc., 220 East 23rd Street, Suite 909 New York, NY 10010, USA. Coating may proceed from aqueous or solvent media with overcoating of dried, partially dried or undried layers.
  • the label-printing apparatus used for these experiments was a thermal head printer, the thermal head having a nominal resistance of 102.6 ohms and 115 ⁇ m by 142 ⁇ m heating elements. It printed with a line time of 11.5ms, was powered by six 1.5 volt batteries and had a DC-motor driven drum transport at a process speed of 7.3mm/s.
  • BROTHER P-TOUCH TYPETM M-K231 black on white leuco-dye-based elongated imaging material with an opaque white backing layer was printed with three heating pulses evenly distributed over the line time at the voltages and pulse times given in table 1.
  • the image density D vis and the CIELAB L*, a* and b* values determined in refection according to ASTM Norm E308 of the resulting prints are given in table 1 below.
  • the lightfastness of a print produced with the BROTHER P-TOUCH TYPETM M-K231 leuco dye-based elongated imaging material was evaluated according to DIN 54 024 of August 1983 for the determination of lightfastness of colourings and prints, which is equivalent to the ISO-document 38/1 N 767, pages 59-73, with an Atlas Material Testing Technology BV, D-63558 Gelnhausen, Germany, SUNTESTTM CPS apparatus.
  • the print is exposed to artificial sunlight through a glass filter together with standardized pigmented cloth samples and exposed to different doses of artificial sunlight as determined by the fading of the standardized pigmented cloth samples and expressed as numbers on the International Wool-scale.
  • thermosensitive element Preparation of the thermosensitive element
  • thermosensitive element with the composition:
  • thermosensitive element Overcoating of thermosensitive element with a protective layer
  • thermosensitive element was overcoated with a protective layer with the composition: PIOLOFORMTM LL4160, a polyvinyl butyral from WACKER CHEMIE 1.539 g/m 2 BAYSILONTM MA, a silicone oil from BAYER 0.006 g/m 2 MICRODOLTM SUPER, a talc from Norwegian Talc AS 0.092 g/m 2 TINUVINTM 320 from CIBA-GEIGY 0.229 g/m 2 TEGOGLIDETM 410 from Goldschmidt 0.02 g/m 2 DESMODURTM N100, a hexamethylene diisocyanate from BAYER 0.154 g/m 2
  • thermographic printer used in these experiments was also a thermal head printer, but had a thermal head with a nominal resistance of 1850 ohms, had 85 ⁇ m by 85 ⁇ m heating elements, printed with a line time of 11.5ms and the thermographic material was transported at a process speed of 7.36 mm/s.
  • the number of heating pulses, printhead voltages and pulse times were completely variable.
  • Colour neutrality on the basis of CIELAB-values corresponds to a* and b* values of zero, with a negative a*-value indicating a greenish image-tone becoming greener as a* becomes more negative, a positive a*-value indicating a reddish image-tone becoming redder as a* becomes more positive, a negative b*-value indicating a bluish image-tone becoming bluer as b* becomes more negative and a positive b*-value indicating a yellowish image-tone becoming more yellow as b* becomes more positive.
  • the direct thermal elongated imaging material used in the experiments of INVENTION EXAMPLES 12 to 33 was produced by coating the thermosensitive element overcoated with a protective layer used in INVENTION EXAMPLES 1 to 11 and coating the opposite side of the support to that coated with the thermosensitive element and its protective layer sequentially with a 5.5g/m 2 coating of a white acrylic water-based ink pigmented with titanium dioxide having an optical density of 0.38 and overcoating with a white pressure sensitive water-based dispersion to a coating weight of 26g/m 2 , the two layers together having an optical density of 0.65.
  • the second layer was then pressure laminated with the silicone-coated side of 65g/m 2 glassine-based paper coated with a silicone layer, which acts as a release foil.
  • the label-printing apparatus used for the printing experiments of COMPARATIVE EXAMPLES 1 to 11 was used in the printing experiments of INVENTION EXAMPLES 12 to 33 in which a direct thermal elongated imaging material produced as described above was printed with three heating pulses evenly distributed over the line time at the voltages and pulse times given in table 4.
  • the image density D vis and the CIELAB L*, a* and b* values determined in refection according to ASTM Norm E308 of the resulting prints are given in table 4 below.
  • L*, a* and b* were also found to be dependent upon the dot energy, L* increasing with increasing dot energy, indicating decreasing optical density, and a* and b* increasing with increasing dot energy from values in the region of zero indicating colour neutrality at lower dot energies to increasingly less neutral colour tone with increasing dot energy.

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EP98204013A 1998-11-30 1998-11-30 Procédé d'impression d'étiquette pour materiaux d'imagerie thermique directe comprenant un sel d'argent organique Withdrawn EP1006000A1 (fr)

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EP98204013A EP1006000A1 (fr) 1998-11-30 1998-11-30 Procédé d'impression d'étiquette pour materiaux d'imagerie thermique directe comprenant un sel d'argent organique
JP2000585071A JP2002531291A (ja) 1998-11-30 1999-11-23 有機性銀塩を含んだ実質的に感光性をもたない細長い描画材料に対するラベル・プリント法
DE69905757T DE69905757T2 (de) 1998-11-30 1999-11-23 Etikettendruckverfahren für direkte thermische aufzeichnungsmaterialien mit organischem silbersalz
PCT/EP1999/009163 WO2000032403A1 (fr) 1998-11-30 1999-11-23 Procede d'impression d'etiquettes utilisant des materiaux d'imagerie allonges sensiblement insensibles a la lumiere, notamment un sel organique d'argent
EP99964507A EP1135258B1 (fr) 1998-11-30 1999-11-23 Procede d'impression d'etiquettes utilisant des materiaux d'imagerie allonges sensiblement insensibles a la lumiere, notamment un sel organique d'argent
US09/452,061 US6244766B1 (en) 1998-11-30 1999-11-30 Label-printing process for substantially light-insensitive elongated materials including an organic silver salt

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EP1226950A1 (fr) * 2001-01-29 2002-07-31 ZIH Corporation Imprimante thermique avec élement de protection de la tête d'impression
WO2005000586A2 (fr) * 2003-06-27 2005-01-06 Dymo Appareil d'impression sur ruban et cassette a ruban
US7023460B2 (en) 2002-11-13 2006-04-04 Agfa Gevaert Thermal head printer and process for printing substantially light-insensitive recording material
CN100564048C (zh) * 2003-06-27 2009-12-02 迪默公司 带式打印设备和带盒
EP4023449A1 (fr) * 2020-12-31 2022-07-06 Bizerba SE & Co. KG Procédé de thermique directe multicolore et imprimante pour impression thermique directe multicolore
US12128692B2 (en) 2020-12-31 2024-10-29 Bizerba SE & Co. KG Method for creating control data for multi-color direct thermal printing

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EP1234677B1 (fr) 2001-01-25 2004-06-09 Agfa-Gevaert Procédé d'impression par transfert thermique
GB0412969D0 (en) 2004-06-10 2004-07-14 Esselte Thermal laser printing

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1226950A1 (fr) * 2001-01-29 2002-07-31 ZIH Corporation Imprimante thermique avec élement de protection de la tête d'impression
US6583803B2 (en) 2001-01-29 2003-06-24 Zih Corporation Thermal printer with sacrificial member
US7023460B2 (en) 2002-11-13 2006-04-04 Agfa Gevaert Thermal head printer and process for printing substantially light-insensitive recording material
WO2005000586A2 (fr) * 2003-06-27 2005-01-06 Dymo Appareil d'impression sur ruban et cassette a ruban
WO2005000586A3 (fr) * 2003-06-27 2005-05-12 Esselte Appareil d'impression sur ruban et cassette a ruban
CN100564048C (zh) * 2003-06-27 2009-12-02 迪默公司 带式打印设备和带盒
EP4023449A1 (fr) * 2020-12-31 2022-07-06 Bizerba SE & Co. KG Procédé de thermique directe multicolore et imprimante pour impression thermique directe multicolore
US11731446B2 (en) 2020-12-31 2023-08-22 Bizerba SE & Co. KG Method for multi-color direct thermal printing and printer for multi-color direct thermal printing
US12128692B2 (en) 2020-12-31 2024-10-29 Bizerba SE & Co. KG Method for creating control data for multi-color direct thermal printing

Also Published As

Publication number Publication date
JP2002531291A (ja) 2002-09-24
EP1135258A1 (fr) 2001-09-26
DE69905757D1 (de) 2003-04-10
DE69905757T2 (de) 2003-12-18
WO2000032403A1 (fr) 2000-06-08
EP1135258B1 (fr) 2003-03-05

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